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USGS2006

Biomonitoring of Environmental Status and Trends (BEST) Program: Environmental contaminants, health indicators, and reproductive biomarkers in fish from the Colorado River basin

Seven fish species were collected from 14 sites on rivers in the Colorado River Basin (CDRB) from August to October 2003. Spatial trends in the concentrations of accumulative contaminants were documented and contaminant effects on the fish were assessed. Sites were located on the mainstem of the Colorado River and on the Yampa, Green, Gunnison, San Juan, and Gila Rivers. Common carp (Cyprinus carpio), black bass (Micropterus sp.), and channel catfish (Ictalurus punctatus) were the targeted species. Fish were field-examined for external and internal anomalies, selected organs were weighed to compute somatic indices, and tissue and fluid samples were preserved for fish health and reproductive biomarker analyses. Composite samples of whole fish, grouped by species and gender, from each site were analyzed for organochlorine and elemental contaminants using performance-based and instrumental methods. 2,3,7,8-tetrachlorodibenzo-p-dioxin-like activity (TCDD-EQ) was measured using the H4IIE rat hepatoma cell bioassay. Selenium (Se) and mercury (Hg) concentrations were elevated throughout the CDRB, and pesticides concentrations were greatest in fish from agricultural areas in the Lower Colorado River and Gila River. Selenium concentrations exceeded toxicity thresholds for fish (>1.0 ?g/g ww) at all sites except from the Gila River at Hayden, Arizona. Mercury concentrations were elevated (>0.1 ?g/g ww) in fish from the Yampa River at Lay, Colorado; the Green River at Ouray National Wildlife Refuge (NWR), Utah and San Rafael, Utah; the San Juan River at Hogback Diversion, New Mexico; and the Colorado River at Gold Bar Canyon, Utah, Needles, California, and Imperial Dam, Arizona. Concentrations of p,p'-DDE were relatively high in fish from Arlington, Arizona (>1.0 ?g/g ww) and Phoenix, Arizona (>0.5 ?g/g ww). Concentrations of other banned pesticides including toxaphene, total chlordanes, and dieldrin were also greatest at these two sites but did not exceed toxicity thresholds. Current-use or unlisted pesticides such as dacthal, endosulfan, '-HCH, and methoxychlor were also greatest in fish from Gila River. Total polychlorinated biphenyls (PCBs; >0.11 ?g/g ww) and TCDD-EQs (>5 pg/g ww) exceeded wildlife guidelines in fish from the Gila River at Phoenix, Arizona. Hepatic ethoxyresorufin O-deethylase (EROD) activity was also relatively high in carp from the Gila River at Phoenix, Arizona and in bass from the Green River at Ouray NWR, Utah. Altered biomarkers were noted in fish throughout the CDRB. Fish from some stations responded to chronic contaminant exposure as indicated by fish health and reproductive biomarker results. Multiple fish health indicators including altered body and organ weights and high health assessment index scores may be associated with elevated Se concentrations in fish from the Colorado River at Loma, Colorado and Needles, California. Although grossly visible external or internal lesions were found on most fish from some sites, histopathological analysis determined many of these to be inflammatory responses associated with parasites. Edema, exophthalmos, and cataracts were noted in fish from sites with elevated Se concentrations. Reproductive biomarkers including gonad development and maturation, vitellogenin concentrations, and steroid hormone concentrations were anomalous in fish from the Gila River at Hayden and Phoenix, Arizona. In addition, intersex fish were found at seven of 14 sites. The intersex condition was identified in smallmouth bass (M. dolomieu), largemouth bass (M. salmoides), channel catfish, and carp and may indicate exposure to endocrine disrupting compounds. Seven of ten male smallmouth bass from the Yampa River at Lay, Colorado were intersex. Male carp, bass, and channel catfish with low concentrations of vitellogenin were common in the CDRB. Comparatively high vitellogenin concentrations (>0.2 mg/mL) were measured in male fish from the Green River at Ouray NWR, Utah and the Colorado River at Im

Scientific Investigations Report↗

USGS2006

Environmental contaminants and biomarker responses in fish from the Columbia River and its tributaries: spatial and temporal trends

Fish were collected from 16 sites on rivers in the Columbia River Basin (CRB) from September 1997 to April 1998 to document temporal and spatial trends in the concentrations of accumulative contaminants and to assess contaminant effects on the fish. Sites were located on the mainstem of the Columbia River and on the Snake, Willamette, Yakima, Salmon, and Flathead Rivers. Common carp (Cyprinus carpio), black bass (Micropterus sp.), and largescale sucker (Catostomus macrocheilus) were the targeted species. Fish were field-examined for external and internal lesions, selected organs were weighed to compute somatic indices, and tissue and fluid samples were preserved for fish health and reproductive biomarker analyses. Composite samples of whole fish, grouped by species and gender, from each site were analyzed for organochlorine and elemental contaminants using instrumental methods and for 2,3,7,8-tetrachloro dibenzo-p-dioxin-like activity (TCDD-EQ) using the H4IIE rat hepatoma cell bioassay. Overall, pesticide concentrations were greatest in fish from lower CRB sites and elemental concentrations were greatest in fish from upper CRB sites. These patterns reflected land uses. Lead (Pb) concentrations in fish from the Columbia River at Northport and Grand Coulee, Washington (WA) exceeded fish and wildlife toxicity thresholds (> 0.4 ??g/g). Selenium (Se) concentrations in fish from the Salmon River at Riggins, Idaho (ID), the Columbia River at Vernita Bridge, WA, and the Yakima River at Granger, WA exceeded toxicity thresholds for piscivorous wildlife (> 0.6 ??g/g). Mercury (Hg) concentrations in fish were elevated throughout the basin but were greatest (> 0.4 ??g/g) in predatory fish from the Salmon River at Riggins, ID, the Yakima River at Granger, WA, and the Columbia River at Warrendale, Oregon (OR). Residues of p,p???-DDE were greatest (> 0.8 ??g/g) in fish from agricultural areas of the Snake, Yakima, and Columbia River basins but were not detected in upper CRB fish. Other organochlorine pesticides did not exceed toxicity thresholds in fish or were detected infrequently. Total polychlorinated biphenyls (PCBs; > 0.11 ??g/g) and TCDD-EQs (> 5 pg/g) exceeded wildlife guidelines in fish from the middle and lower CRB, and ethoxyresorufin O-deethylase (EROD) activity was also elevated at many of the same sites. Temporal trend analysis indicated decreasing or stable concentrations of Pb, Se, Hg, p,p???-DDE, and PCBs at most sites where historical data were available. Altered biomarkers were noted in fish throughout the CRB. Fish from some stations had responded to chronic contaminant exposure as indicated by fish health and reproductive biomarker results. Although most fish from some sites had grossly visible external or internal lesions, histopathological analysis determined these to be inflammatory responses associated with helminth or myxosporidian parasites. Many largescale sucker from the Columbia River at Northport and Grand Coulee, WA had external lesions and enlarged spleens, which were likely associated with infections. Intersex male smallmouth bass (Micropterus dolomieu) were found in the Snake River at Lewiston, ID and the Columbia River at Warrendale, OR. Male bass, carp, and largescale sucker containing low concentrations of vitellogenin were common in the CRB, and comparatively high concentrations (> 0.3 mg/mL) were measured in male fish from the Flathead River at Creston, Montana, the Snake River at Ice Harbor Dam, WA, and the Columbia River at Vernita Bridge, WA and Warrendale, OR. Results from our study and other investigations indicate that continued monitoring in the CRB is warranted to identify consistently degraded sites and those with emerging problems. ?? 2005 Elsevier B.V. All rights reserved.

Columbia River Basin↗

USGS2002

Challenges in observational seismology

Earthquake seismology became a quantitative scientific discipline after instruments were developed to record seismic waves in the late 19th century ( Dewey and Byerly, 1969 ; Chapter 1 by Agnew). Earthquake seismology is essentially based on field observations. The great progress made in the past several decades was primarily due to increasingly plentiful and high-quality data that are readily distributed. Our ability to collect, process, and analyze earthquake data has been accelerated by advances in electronics, communications, computers, and software (see Chapter 85 edited by Snoke and Garcia-Fernandez). Instrumental observation of earthquakes has been carried out for a little over 100 years by seismic stations and networks of various sizes, from local to global scales (see Chapter 87 edited by Lahr and van Eck). The observed data have been used, for example, (1) to compute the source parameters of earthquakes, (2) to determine the physical properties of the Earth's interior, (3) to test the theory of plate tectonics , (4) to map active faults, (5) to infer the nature of damaging ground shaking, and (6) to carry out seismic hazard analysis. Construction of a satisfactory theory of the earthquake process has not yet been achieved within the context of physical laws. Good progress, however, has been made in building a physical foundation of the earthquake source process, partly as a result of research directed toward earthquake prediction. This chapter is intended for a general audience. Technical details are not given, but relevant references and chapters in this Handbook are referred to. The first part of this chapter presents a brief overview of the observational aspects of earthquake seismology, concentrating on instrumental observations of seismic waves generated by earthquakes (i.e., seismic monitoring), and readers are referred to Chapter 49 by Musson and Cecic for noninstrumental observations. A few key developments and practices are summarized by taking a general view, since many national and regional developments have been chronicled in national and institutional reports (see Chapter 79 edited by Kisslinger). In the latter part of this chapter, the nature of seismic monitoring and some challenges in observational seismology are discussed from a personal perspective. Comments of a technical or philosophical nature are given in the Notes at the end of the chapter, and they are referenced by superscript numbers in the text.

International Geophysics↗

USGS2007

Natural gases in ground water near Tioga Junction, Tioga County, north-central Pennsylvania: Occurrence and use of isotopes to determine origins, 2005

In January 2001, State oil and gas inspectors noted bubbles of natural gas in well water during a complaint investigation near Tioga Junction, Tioga County, north-central Pa. By 2004, the gas occurrence in ground water and accumulation in homes was a safety concern; inspectors were taking action to plug abandoned gas wells and collect gas samples. The origins of the natural-gas problems in ground water were investigated by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection, in wells throughout an area of about 50 mi2, using compositional and isotopic characteristics of methane and ethane in gas and water wells. This report presents the results for gas-well and water-well samples collected from October 2004 to September 2005. Ground water for rural-domestic supply and other uses near Tioga Junction is from two aquifer systems in and adjacent to the Tioga River valley. An unconsolidated aquifer of outwash sand and gravel of Quaternary age underlies the main river valley and extends into the valleys of tributaries. Fine-grained lacustrine sediments separate shallow and deep water-bearing zones of the outwash. Outwash-aquifer wells are seldom deeper than 100 ft. The river-valley sediments and uplands adjacent to the valley are underlain by a fractured-bedrock aquifer in siliciclastic rocks of Paleozoic age. Most bedrock-aquifer wells produce water from the Lock Haven Formation at depths of 250 ft or less. A review of previous geologic investigations was used to establish the structural framework and identify four plausible origins for natural gas. The Sabinsville Anticline, trending southwest to northeast, is the major structural feature in the Devonian bedrock. The anticline, a structural trap for a reservoir of deep native gas in the Oriskany Sandstone (Devonian) (origin 1) at depths of about 3,900 ft, was explored and tapped by numerous wells from 1930-60. The gas reservoir in the vicinity of Tioga Junction, depleted of native gas, was converted to the Tioga gas-storage field for injection and withdrawal of non-native gases (origin 2). Devonian shale gas (shallow native gas) also has been reported in the area (origin 3). Gas might also originate from microbial degradation of buried organic material in the outwash deposits (origin 4). An inventory of combustible-gas concentrations in headspaces of water samples from 91 wells showed 49 wells had water containing combustible gases at volume fractions of 0.1 percent or more. Well depth was a factor in the observed occurrence of combustible gas for the 62 bedrock wells inventoried. As well-depth range increased from less than 50 ft to 51-150 ft to greater than 151 ft, the percentage of bedrock-aquifer wells with combustible gas increased. Wells with high concentrations of combustible gas occurred in clusters; the largest cluster was near the eastern boundary of the gas-storage field. A subsequent detailed gas-sampling effort focused on 39 water wells with the highest concentrations of combustible gas (12 representing the outwash aquifer and 27 from the bedrock aquifer) and 8 selected gas wells. Three wells producing native gas from the Oriskany Sandstone and five wells (two observation wells and three injection/withdrawal wells) with non-native gas from the gas-storage field were sampled twice. Chemical composition, stable carbon and hydrogen isotopes of methane (13CCH4 and DCH4), and stable carbon isotopes of ethane (13CC2H6) were analyzed. No samples could be collected to document the composition of microbial gas originating in the outwash deposits (outwash or 'drift' gas) or of native natural gas originating solely in Devonian shale at depths shallower than the Oriskany Sandstone, although two of the storage-field observation wells sampled reportedly yielded some Devonian shale gas. Literature values for outwash or 'drift' gas and Devonian shale gases were used to supplement the data collection. Non-native gases fr

Pennsylvania↗

USGS1995

Cerro Prieto geothermal field, Mexico; chemical analyses and other data for 58 samples collected in 1977-1979

This report releases the results of selected chemical analyses by the USGS of fluids collected from geothennal power production wells at the Cerro Prieto Geothennal Field, Mexico. Cerro Prieto, the world's largest producing hot-water geothennal field, is located 32 km southeast of Mexicali, Baja California. Comision Federal de Electricidad de Mexico (CFE) gave permission for, and assisted in, sample collection. Data collection and reported analyses was made by the U.S. Geological Survey. Data collected in 1977 and 1978 where published previously by Ball and Jenne (1983) which was about half the data given here. This report also includes samples collected in 1979 which were not previously released. These activities, including this data release, are supported by the U.S. Department of Energy. Analyses given in the following section were made by James W. Ball and E.A. Jenne. The data have been reviewed with the assistance of Cathy Janik, USGS, Menlo Park. Some, but not all, details from Ball and Jenne (1983) concerning collection, and preservation and analytical procedures are repeated here. Nehring and Trusdell (1977) also provide an outline of some of the issues involved in the difficult task of collecting samples from geothermal wells. The initial intent of the study was to provide basic data for use in determining how these fluids should be managed either in disposal or in reinjection. Some of the hot, corrosive brines were separated as two-phase (water and steam) samples under pressure using a coiled condenser tube submerged in an ice/water mixture (called "condensed" samples). It is not known if these were total flow samples. Other samples were collected from the brine sampling valve of the separators (called "flashed" samples). Analyses given in the following section area sorted by (1) well number, (2) date, and (3) sample type(s). Analysis was by a Spectraspan III d.c. argon plasma emission spectrometer with a Spectraject III torch (Ball and Jenne, 1983). Elements were determined in two groups using interchangeable cassettes. Group one included B, Mn, Cu, Zn, Si, Zr, Be, Mn, Sr, Ti, Ca, Fe, Ba, K, Na, Rb, and Al. Group two included As, Se, Bi, Zn, Cd, Sb, Cu, Ni, Hg, Mo, Co, Cr, Fe, V, Tl, Li, and Pb. Ball and Jenne (1983) noted that analysis of B, Ca, Mg, Ba, and Sr generally gave precise results. Movement of the plasma or grating was observed to affect sensitivity over short time periods even while the instrument was carefully standardized and optimized. Sensitivity was also a function of sample concentration. All samples at the time of analysis contained a white precipitate (perhaps colloidal silica) thus the reported concentrations may not accurately represent the concentrations present at the time of collection (Ball and Jenne, 1983). Additional details about specific elements are given in the section on "Evaluation of data" (Bliss, this volume) following the data table.

Open-File Report↗

USGS2005

Occurrence of fecal-indicator bacteria and protocols for identification of fecal-contamination sources in selected reaches of the West Branch Brandywine Creek, Chester County, Pennsylvania

The presence of fecal-indicator bacteria indicates the potential presence of pathogens originating from the fecal matter of warm-blooded animals. These pathogens are responsible for numerous human diseases ranging from common diarrhea to meningitis and polio. The detection of fecal-indicator bacteria and interpretation of the resultant data are, therefore, of great importance to water-resource managers. Current (2005) techniques used to assess fecal contamination within the fluvial environment primarily assess samples collected from the water column, either as grab samples or as depth- and (or) width-integrated samples. However, current research indicates approximately 99 percent of all bacteria within nature exist as attached, or sessile, bacteria. Because of this condition, most current techniques for the detection of fecal contamination, which utilize bacteria, assess only about 1 percent of the total bacteria within the fluvial system and are, therefore, problematic. Evaluation of the environmental factors affecting the occurrence and distribution of bacteria within the fluvial system, as well as the evaluation and modification of alternative approaches that effectively quantify the larger population of sessile bacteria within fluvial sediments, will present water-resource managers with more effective tools to assess, prevent, and (or) eliminate sources of fecal contamination within pristine and impaired watersheds. Two stream reaches on the West Branch Brandywine Creek in the Coatesville, Pa., region were studied between September 2002 and August 2003. The effects of sediment particle size, climatic conditions, aquatic growth, environmental chemistry, impervious surfaces, sediment and soil filtration, and dams on observed bacteria concentrations were evaluated. Alternative approaches were assessed to better detect geographic sources of fecal contamination including the use of turbidity as a surrogate for bacteria, the modification and implementation of sandbag bacteria samplers, and the use of optical brighteners. For the purposes of this report, sources of bacteria were defined as geographic locations where elevated concentrations of bacteria are observed within, or expected to enter, the main branch of the West Branch Brandywine Creek. Biologic sources (for example, waterfowl) were noted where applicable; however, no specific study of biologic sources (such as bacterial source tracking) was conducted. Data indicated that specific bacterial populations within fluvial sediments could be related to specific particle-size ranges. This relation is likely the result of the reduced porosity and permeability associated with finer sediments and the ability of specific bacteria to tolerate particular environments. Escherichia coli (E. coli) showed a higher median concentration (2,160 colonies per gram of saturated sediment) in the 0.125 to 0.5-millimeter size range of natural sediments than in other ranges, and enterococcus bacteria showed a higher median concentration (61,830 colonies per gram of saturated sediment) in the 0.062 to 0.25-millimeter size range of natural sediments than in other ranges. There were insufficient data to assess the particle-size relation to fecal coliform bacteria and (or) fecal streptococcus bacteria. Climatic conditions were shown to affect bacteria concentrations in both the water column and fluvial sediments. Drought conditions in 2002 resulted in lower overall bacteria concentrations than the more typically wet year of 2003. E. coli concentrations in fluvial sediment along the Coatesville study reach in 2002 had a median concentration of 92 colonies per gram of saturated sediment; in 2003, the median concentration had risen to 4,752 colonies per gram of saturated sediment. Symbiotic relations between bacteria and aquatic growth were likely responsible for increased bacteria concentrations observed within an impoundment area on the Coatesville study reach. This reach showed evidence of elevated aquatic growth and sharp increases in E. coli concentrations from upstream to downstream through the impoundment area in both 2002 and 2003. In 2003, E. coli concentrations within the waters column increased from 940 colonies per 100 milliliters upstream to 6,000 colonies per 100 milliliters at the dam crest. Given that these bacteria likely resulted from natural bacterial regrowth, the use of E. coli as an indicator of fecal contamination was severely impaired. Variable environmental conditions along the West Branch Brandywine Creek made the common field-chemical parameters of specific conductance, temperature, pH, and dissolved oxygen ineffective and (or) impossible to use for the determination of inputs of fecal contamination. Extreme variations in chemical gradients commonly were related to the urban/industrial signature of the watershed. For example, during base-flow sampling in 2002, specific-conductance values exceeding 1,000 microsiemens per centimeter observed in effluent from a local steel mill. This effluent raised the specific conductance within the West Branch Brandywine from just above 200 microsiemens per centimeter upstream from the outfall to just below 500 microsiemens per centimeter downstream from the outfall. These chemical gradients also, likely, had an effect on the initial colonization of bacteria, the formation of biofilms, and the persistence of certain types of bacteria along the study reach. Data collected in 2003 indicated that nutrients increased during both base-flow and stormflow conditions along the Coatesville study reach. For example, during base-flow sampling in 2003, 20 pounds of phosphorus was shown to enter the West Branch Brandywine Creek along the Coatesville study reach. The largest contributors to this base-flow nutrient load were likely two wastewater-treatment facilities adjacent to the study reach. During stormflow sampling in 2003, 480 pounds of phosphorus was shown to enter the West Branch Brandywine Creek along the Coatesville study reach. Data, along with other research, indicated the largest contributor to this stormflow nutrient load was likely remobilized sediment originating from a large dam impoundment. These elevated nutrient concentrations were considered sufficient to promote accelerated aquatic growth along the reach. Data collected in 2003 showed that wastewater constituents entered the West Branch Brandywine Creek largely from urban storm-sewer systems. Samples from the primary storm sewer for the city of Coatesville had detections for 20 of 69 wastewater constituents. These constituents included both strong and weak indicators of fecal contamination and generally indicated the storm-sewer system along the Coatesville study reach was a likely source of fecal-indicator bacteria and fecal contamination under base-flow conditions. By comparison, 5 constituents were detected in samples from the upstream end of the reach, and 10 constituents were detected in samples from the downstream end of the reach. During stormflow, numbers of detections were similar along the entire length of the study reach-five in samples from the upstream end, eight in samples from the center of the reach, and seven in samples from the downstream end of the reach. These data indicate that point sources (such as culverts and pipes, septic systems, and wastewater-treatment facilities) are not likely the origin of bacteria contamination during stormflow. The bacteria concentrations observed during stormflow events probably result from remobilized sessile bacteria stored within fluvial sediments. In this case, these bacteria should not be considered indicators of current fecal contamination. Impervious surfaces were found to increase bacteria concentrations along the West Branch Brandywine Creek because contaminated runoff from impervious areas generally flows into, and is concentrated within, the confines of the local storm-sewer system. During 2002, storm-sewer outfalls draining impervious areas were associated with all major locations of elevated bacterial concentrations (greater than 1,200 colonies per gram of saturated sediment) in fluvial sediments. During 2003, wetter conditions and overall bacteria concentrations higher than in 2002 resulted in point sources of bacterial contamination becoming less pronounced; however, the storm-sewer system, draining adjacent impervious areas, was still observed to be the primary source of bacteria along the reach. Where stormwater and (or) other runoff from these areas was allowed to infiltrate and (or) flow through wetland and riparian buffers, bacteria concentrations were not observed to be elevated above background levels commonly observed throughout similar areas of the same reach. Two run-of-the-river dams along the Coatesville study reach were evaluated for their effects on observed bacterial concentrations. These dams were shown to have greater or lesser effects on bacterial concentrations depending on the size of the structure and the capacity of the structure to impede flows. The smaller upstream dam had an approximate height of 3 feet and showed little observed effect on measured turbidity values; these data indicated that the dam did not effectively impede the flow of water or sediment within the West Branch Brandywine Creek. Consequently, this small dam did not show any observed effect on bacterial concentrations either upstream or downstream of the structure. The larger dam, near the middle of the reach, had an approximate height of 20 feet and showed greater effects on both turbidity and bacteria concentrations. The capacity of the larger dam to impede flows, combined with nutrients entering the reach, resulted in increased biologic activity throughout the impoundment area. Within this larger impoundment, enterococcus bacteria populations were observed to decrease sharply and E. coli bacteria populations were observed to increase sharply as flow approached the dam crest. All bacteria levels were then observed to drop to background levels, in both the water column and fluvial sediment, immediately downstream from the dam crest. Additional study is required to determine the cause for this rapid die off. Turbidity was assessed as a potential surrogate for E. coli bacteria. Regression analysis indicated higher turbidity levels usually can indicate higher concentrations of bacteria (R2 = 0.67), but the relation was too sporadic on the West Branch Brandywine Creek to use turbidity as a surrogate for estimated bacteria concentrations. Evaluation of data from individual base-flow and stormflow events resulted in variable and generally poor statistical relations between E. coli bacteria and turbidity (R2 values ranged from 0.02 to 0.94). Sandbag samplers were used in 2003 to determine their suitability for the assessment of fecal contamination. Sandbag samplers rely on the ability of bacteria to attach to surfaces and use the larger sessile bacteria populations instead of the more commonly used planktonic bacteria populations. E. coli bacteria concentrations observed in the sandbag samplers, after 1 week in place, were similar to those found within natural sediments collected concurrently. Enterococcus bacteria concentrations within the same sandbag samplers were not similar, and were generally lower, than those observed within the natural sediments. This discrepancy was likely because sand within the samplers was sieved to a size that was likely too coarse for enterococcus bacteria to persist. Optical-brightener samplers were installed along with each sandbag sampler. Optical brighteners are additives used in common household detergents; therefore, detection of optical brighteners, along with elevated fecal-indicator bacteria concentrations, strongly indicates a link to humans. Positive results for optical brighteners were detected only at the outfalls of two sewage-treatment facilities; because of treatment of the effluent from these facilities, these samples did not have elevated bacteria concentrations. The lack of additional positive results was largely because this method is not sensitive to low concentrations of optical brighteners.

Pennsylvania↗

USGS2012

Archive of digital boomer subbottom data collected during USGS cruise 05FGS01 offshore east-central Florida, July 17-29, 2005

In July of 2005, the U.S. Geological Survey (USGS), in cooperation with the Florida Geological Survey (FGS), conducted a geophysical survey of the Atlantic Ocean offshore of Florida's east coast from Flagler Beach to Daytona Beach. This report serves as an archive of unprocessed digital boomer subbottom data, trackline maps, navigation files, Geographic Information System (GIS) files, Field Activity Collection System (FACS) logs and formal Federal Geographic Data Committee (FGDC) metadata. Filtered and gained (showing a relative increase in signal amplitude) digital images of the seismic profiles are also provided. Refer to the Acronyms page for expansions of acronyms and abbreviations used in this report. The USGS Saint Petersburg Coastal and Marine Science Center (SPCMSC) assigns a unique identifier to each cruise or field activity. For example, 05FGS01 tells us the data were collected in 2005 for cooperative work with the FGS and the data were collected during the first field activity for that project in that calendar year. Refer to http://walrus.wr.usgs.gov/infobank/programs/html/definition/activity.html for a detailed description of the method used to assign the field activity ID. The boomer subbottom processing system consists of an acoustic energy source that is made up of capacitors charged to a high voltage and discharged through a transducer in the water. The transducer is towed on a sled floating on the water surface and when discharged emits a short acoustic pulse, or shot, which propagates through the water column and shallow stratrigraphy below. The acoustic energy is reflected at density boundaries (such as the seafloor or sediment layers beneath the seafloor), detected by the receiver (a hydrophone streamer), and recorded by a PC-based seismic acquisition system. This process is repeated at timed intervals (for example, 0.5 s) and recorded for specific intervals of time (for example, 100 ms). In this way, a two-dimensional (2-D) vertical image of the shallow geologic structure beneath the ship track is produced. Figure 1 displays the acquisition geometry. Refer to table 1 for a summary of acquisition parameters and table 2 for trackline statistics. The archived trace data are in standard Society of Exploration Geophysicists (SEG) SEG Y format (Barry and others, 1975), except an ASCII format is used for the first 3,200 bytes of the card image header instead of the standard EBCDIC format. For a detailed description about the recorded trace headers, refer to the SEG Y Format page. The SEG Y files may be downloaded and processed with commercial or public domain software such as Seismic Unix (Cohen and Stockwell, 2005). See the How To Download SEG Y Data page for download instructions. The printable profiles provided here are GIF images that were processed and gained using SU software; refer to the Software page for links to example SU processing scripts. The processed SEG Y data were also exported to Chesapeake Technology, Inc. (CTI) SonarWeb software to produce a geospatially interactive version of the profile that allows the user to obtain a geographic location and depth from the profile for a given cursor position; this information is displayed in the status bar of the browser. Please note that clicking on the profile image switches it to "Expanded View" (a compressed image of the entire line) and cursor tracking is not available in this mode.

Florida↗

USGS2019

Determination of study reporting limits for pesticide constituent data for the California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project, 2004–2018—Part 1: National Water Quality Schedules 2003, 2032, or 2033, and 2060

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) is a long-term cooperative project designed to assess the quality of groundwater resources used for public and domestic drinking water supplies in the State of California, to monitor and evaluate changes to that quality, to investigate the human and natural factors controlling water quality, and to improve the availability of comprehensive groundwater quality data and information. Between May 18, 2004, and May 3, 2018, the GAMA-PBP collected 3001 groundwater samples for analysis of pesticide constituents by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL)(note that ‘pesticide constituents’ includes parent compounds and degradates). Of these samples, 2994 were analyzed for pesticide constituents on schedules 2003, 2032, or 2033 (65 to 84 constituents), and 840 were analyzed for pesticide constituents on schedule 2060 (58 constituents). The original dataset reported by the NWQL to the USGS National Water Information System (NWIS) database contained a total of 2,688 detections of 78 pesticide constituents and 253,825 non-detections. In this original dataset, 33 percent of the 3,001 samples analyzed had reported detections of one or more pesticide constituents. This report describes the GAMA-PBP data-quality objectives for pesticide data, the procedures used to establish study reporting limits, and use of those reporting limits to censor the data from the NWQL so that the final data published by the GAMA-PBP meet these data-quality objectives. The final GAMA-PBP dataset for samples collected from May 2004 to May 2018, after censoring, had a total of 1,632 detections of 37 pesticide constituents. In the final GAMA-PBP dataset, 25 percent of the 3,001 samples analyzed had detections of one or more pesticide constituents. The presence of pesticides in groundwater is commonly evaluated by calculating detection frequencies. Detection frequencies for pesticides are sensitive to detection limits and method performance for concentrations near those limits; therefore, the two primary data quality issues addressed in the GAMA-PBP data-quality objectives for pesticides are (1) establishing criteria for classifying data from the laboratory as detections or non-detections for the purpose of data reporting by the project and (2) accounting for changes in analytical methods or method performance over time. The GAMA-PBP addresses these issues by developing study reporting limits that are used as the boundary between detections and non-detections for the reporting of GAMA-PBP results. These reporting limits are defined from method detection limits (MDLs) provided by the NWQL, unless examination of results from laboratory set blanks (LSBs) and GAMA-PBP field blanks indicates that a higher concentration censoring limit is warranted. The GAMA-PBP selected the MDL as the primary choice for defining study reporting limits for consistency with U.S. Environmental Protection Agency (EPA) guidelines for reporting detections of pesticides and other organic constituents. A five-step procedure is used to develop study reporting limits and censor the GAMA-PBP dataset accordingly. The effect of the censoring at each step is described to provide information about the relative effect of each step on the overall censoring of the dataset. Steps 1 and 2 can be implemented at the time the data are received, whereas steps 3−5 require information accumulated over an extended period. Step 1: Reject results that were most likely the result of specific contamination instances attributable to unusual field or laboratory conditions during sample collection or processing. Two such instances were identified, leading to rejection of 25 detections, which were assigned a data-quality indicator code of “Q” for “reviewed and rejected” in the NWIS database. Step 2: Use the NWQL MDLs in effect at the time each sample was analyzed as the reporting limit. A total of 506 detections were censored on this basis. Step 3: Use the maximum MDL established by the NWQL during July 2004–August 2018 (MDLmax) as the reporting limit. The rationale for using the MDLmax as the reporting limit is based primarily on the observation that the concentrations of MDLs generally increased over time. A total of 438 detections were censored on this basis. Step 4: Use the LSBs to identify periods of greater potential laboratory contamination bias and define raised reporting limits to be used during those periods. These periods were defined by using a moving average detection frequency approach. For consistency with the NWQL procedures for defining raised reporting limits on the basis of detections in LSBs, the raised reporting limits were defined as equal to three times the highest concentration measured in an LSB during the period. A total of 25 detections in groundwater samples analyzed during periods of increased laboratory contamination bias were censored. Step 5: Use the LSBs and field blanks to identify potential contamination bias from field or laboratory processes outside of the time periods identified in step 4. The NWQL protocols were used to define the MDLs from blanks analyzed outside of the periods identified in step 4. If an MDL defined from blanks was greater than the MDLmax, the MDL defined from blanks was used to censor the data. One constituent had a study reporting limit defined on this basis, and a total of 62 detections in groundwater samples were censored. As of 2019, the USGS NWIS database does not have the capability to store both the original value reported by the NWQL and the final value published by the GAMA-PBP that reflects application of the quality-control censoring described in this report. In the interim, while this capability is developed, the 1,031 results censored in steps 2−5 are blocked from public release in NWIS, and the GAMA-PBP has published the original and final values in a USGS data release accompanying this report. The entire GAMA-PBP final dataset for pesticide constituents on schedules 2003, 2032, or 2033, or on schedule 2060 is publicly available in that USGS data release, through the USGS GAMA-PBP public web portal, and through the California State Water Resources Control Board GAMA public groundwater information system.

California↗

USGS1973

Petrology of Newberry Volcano, central Oregon

Note: This paper is dedicated to Aaron and Elizabeth Waters on the occasion of Dr. Waters' retirement. The eastern flank of the central and southern Cascade Mountains is bordered by a belt of shield volcanoes that appears to be a subprovince of the Oregon high-alumina plateau basalt petrologic province. Most of the volcanoes in this belt are low shields in which differentiation from the parent high-alumina basalt magma has been relatively slight, but several are large complex shield centers where differentiation has been extreme. The location of these large centers, and of some of the smaller volcanoes as well, was largely determined by intersecting concentrations of faults and fault-fissures of three regional fault systems. One of the largest of the complex volcanic centers is Newberry Volcano in central Oregon, a shield volcano with a big caldera at its summit. The stratigraphy of the caldera walls and of features on the caldera floor at Newberry allows detailed interpretation of the history of the younger parts of the volcano and caldera. The formation of Newberry Caldera was apparently a slow process controlled largely by faulting along the three regional fault systems. The magma conduits were probably a gridlike plexus of intersecting dikes and fissures, with larger “magma pockets” at the grid intersections. The magma was trapped in shallow chambers and periodically released by faulting. The entrapment of the magma allowed differentiation in the shallow chambers. The stratigraphy and petrology of the wall sequence also allows determination of the relative time at which the caldera had grown large enough to hold a caldera lake. On differentiation plots, chemical analyses of the Newberry rocks show two trends: rocks erupted before the presence of a lake in the caldera trend toward slight iron enrichment, whereas rocks erupted after water was present in the caldera generally trend toward alkali enrichment. These different trends are attributed to differences in the oxygen fugacity of the magma which, in turn, are related to the presence or absence of large volumes of water in the caldera lake. The interpretation is supported by field, petrographic, petrologic, chemical, trace-element, and isotopic data. Plots of existing data for the Medicine Lake Highland Volcano, another large complex shield center in the belt, show the same type of two-trend relation as those of Newberry Volcano.

Oregon↗

USGS2008

Archive of digitized analog boomer seismic reflection data collected from Lake Pontchartrain, Louisiana, to Mobile Bay, Alabama, during cruises onboard the R/V ERDA-1, June and August 1992

In June and August of 1992, the U.S. Geological Survey (USGS) conducted geophysical surveys to investigate the shallow geologic framework from Lake Pontchartrain, Louisiana, to Mobile Bay, Alabama. This work was conducted onboard the Argonne National Laboratory's R/V ERDA-1 as part of the Mississippi/Alabama Pollution Project. This report is part of a series to digitally archive the legacy analog data collected from the Mississippi-Alabama SHelf (MASH). The MASH data rescue project is a cooperative effort by the USGS and the Minerals Management Service (MMS). A standardized naming convention was established to allow for better management of scanned trackline images within the MASH data rescue project. Each cruise received a unique field activity ID based on the year the data were collected, the first two digits of the survey vessel name, and the number of cruises made (to date) by that vessel that year (i.e. 92ER2 represents the second cruise made by the R/V ERDA-1 in 1992.) The new field activity IDs 92ER2 and 92ER4 presented in this report were originally referred to as ERDA 92-2 and ERDA 92-4 at the USGS in St. Petersburg, FL, and 92010 and 92037 at the USGS in Woods Hole, MA. A table showing the naming convention lineage for cruise IDs in the MASH data rescue series is included as a PDF. This report serves as an archive of high resolution scanned Tagged Image File Format (TIFF) and Graphics Interchange Format (GIF) images of the original boomer paper records, navigation files, trackline maps, Geographic Information System (GIS) files, cruise logs, and formal Federal Geographic Data Committee (FGDC) metadata for cruises 92ER2 and 92ER4. The boomer system uses an acoustic energy source called a plate, which consists of capacitors charged to a high voltage and discharged through a transducer in the water. The source is towed on a sled, at sea level, and when discharged emits a short acoustic pulse, or shot, which propagates through the water and sediment column. The acoustic energy is reflected at density boundaries (such as the seafloor or sediment layers beneath the seafloor), detected by the hydrophone receiver, and the amplitude of the reflected energy is recorded by an Edward P. Curley Lab (EPC) thermal plotter. This process is repeated at timed intervals (for example, 0.5 s) and recorded for specific intervals of time (for example, 100 ms). The timed intervals are also referred to as the shot interval or fire rate. On analog records, the recorded interval is referred to as the sweep, which is the amount of time the recorder stylus takes to sweep from the top of the record to the bottom of the record, thereby recording the amplitude of the reflected energy of one shot. In this way, consecutive recorded shots produce a two-dimensional (2-D) vertical image of the shallow geologic structure beneath the ship track. Many of the geophysical data collected by the USGS prior to the late 1990s were recorded in analog format and stored as paper copies. Scientists onboard made hand-written annotations onto these records to note latitude and longitude, time, line number, course heading, and geographic points of reference. Each paper roll typically contained numerous survey lines and could reach more than 90 ft in length. All rolls are stored at the USGS FISC-St. Petersburg, FL. To preserve the integrity of these records and improve accessibility, analog holdings were converted to digital files.

Alabama, Louisiana, Mississippi↗

USGS1934

Zoning of ore deposits in and adjoining the Leadville District, Colorado

The ore deposits in the heart of the Leadville district , Colorado , are divisible, as shown by Emmons, Irving, and Loughlin,2 into two main classes on the basis of mineral composition: "contact-metamorphic" silicates accompanied by iron oxides, which adjoin an obscure igneous stock, and mixed sulphides accompanied by manganosiderite and quartz gangue, which cut the "contact-metamorphic" deposits and form a broad zone extending for 2 1/2 miles to the west and for shorter distances in other directions. A detailed consideration of the mineralogy of the mixed sulphide ore deposits clearly shows that they in turn are divisible into groups, referred to as hotter and intermediate mesothermal deposits . These groups, however, because of complications in structural control, are not ideally arranged from the standpoint of zoning .Emmons, Irving, and Loughlin noted that barite was a conspicuous gangue mineral in certain outlying deposits on the west slope of the Mosquito Range. The junior author during 1928-1931 had an opportunity to study the outlying deposits over an area of twenty square miles, which includes mines near the heads of Iowa Gulch and Empire Gulch, and the Weston Pass district (Fig. 1), and found that these baritic deposits form a somewhat distinct outer zone in which the primary ore consists of galena and light-colored zinc blende, with small amounts of silver and practically no gold, in a gangue of barite, jasperoid, and crystalline quartz. There is also recognized a still more remote though poorly defined zone in which the same sulphides are present but jasperoid is less conspicuous and barite is practically absent, whereas dolomite is the characteristic gangue mineral. The deposits in these two outer zones are fissure-fillings and comparatively small replacement bodies. They contrast strongly with the sulphide deposits in the heart of the Leadville district and are assigned to the outer mesothermal and epithermal zones. As they have not been described before, general features of these deposits are given in some detail, followed by their relations to the deposits within the Leadville district . Analogies are also drawn with similar deposits in other districts. In the preparation of this paper the authors have been impressed with the confusion that may result from too simple a conception of zoning . For a proper conception of Leadville , the geologist must have sufficient regard for structural conditions, must make due allowance for successive stages of mineral deposition within a small block of ground or even within a single ore shoot, and must also allow for the reactions between minerals formed at an early stage and solutions introduced during a late stage. The effects of such complications in the Leadville district might give the impression that certain minerals found in one of the inner zones were formed at relatively high temperatures, but close study of paragenesis indicates late deposition at relatively low temperatures. Again, as already stated, there is sufficient inconsistency in the distribution of certain varieties of deposits to give a confused impression of zonal arrangement unless the influence of structure on the circulation of ore -forming solutions is appreciated. The field facts give a far more complex picture than might be anticipated from a simple statement of the theory of zoning .

Colorado↗

USGS1956

Summary of reconnaissance for radioactive deposits in Alaska, 1945-1954, and an appraisal of Alaskan uranium possibilities

In the period 1945-1954 over 100 investigations for radioactive source materials were made in Alaska. The nature of these investigations ranged from field examinations of individual prospects or the laboratory analysis of significantly radioactive samples submitted by prospectors to reconnaissance studies of large districts. In this period no deposits of uranium or thorium that would warrant commercial exploitation were discovered. The investigations, however, disclosed that radioactive materials occur in widely scattered areas of Alaska and in widely diverse environments. Many igneous rocks throughout Alaska are weakly radioactive because of uranium- and thorium-bearing accessory minerals, such as allanite, apatite, monazite, sphene, xenotime, and zircon; more rarely the radioactivity of these rocks is due to thorianite or thorite and their uranoan varieties. The felsic rocks, for example, granites and syenites, are generally more radioactive than the mafic igneous rocks. Pegmatites, locally, have also proved to be radioactive, but they have little commercial significance. No primary uranium oxide minerals have been found yet in Alaskan vein deposits, except, perhaps, for a mineral tentatively identified as pitchblende in the Hyder district of southeastern Alaska. However, certain occurrences of secondary uranium minerals, chiefly those of the uranite group, on the Seward Peninsula, in the Russian Mountains, and in the vicinity of Kodiak suggest that pitchblende-type ores may occur at depth beneath zones of alteration. Thorite-bearing veins have been discovered on Prince of Wales Island in southeastern Alaska. Although no deposits or carnotite-type minerals have been found in Alaska, several samples containing such minerals have been submitted by Alaskan prospectors. Efforts to locate the deposits from which these minerals were obtained have been unsuccessful, but review of available geologic data suggests that several Alaskan areas are potentially favorable for carnotite-type deposits. The chief of these areas is the Alaska Peninsula-Cook Inlet area which encompasses most of the reported occurrences of the prospectors' carnotite-type samples. Alaska is also potentially favorable for the occurrence of large bodies of the very low-grade uraniferous sedimentary rocks, such as phosphorites and black shales. This type of deposit, however, has not received much study because of the emphasis on the search for bonanza-type high-grade ores. Uraniferous phosphorites similar to those of Idaho, Montana, and Wyoming occur in northern Alaska on the north flank of the Brooks Range; black shales comparable to the uraniferous shales of the Chattanooga formation of southeastern United States have been noted along the Yukon River near the international boundary. Placer deposits in Alaska have some small potential for the production of the radioactive elements as byproducts of gold- and tin-placer mining. the placer area believed to have the relatively greatest potential in Alaska lies in the Kahiltna River valley where concentrates are known to contain such commercial minerals as ilmenite, cassiterite, platinum, and gold in addition to uranothorianite and monazite. The possibilities of the natural fluids--water and petroleum--have not yet been tested in Alaska to any great extent. Studies of fluids are in progress to determine whether they may be used to discover and define areas potentially favorable for the occurrence of uraniferous lodes.

Alaska↗

USGS2011

Geologic map of the Ganiki Planitia quadrangle (V-14), Venus

The Ganiki Planitia (V-14) quadrangle on Venus, which extends from 25° N. to 50° N. and from 180° E. to 210° E., derives its name from the extensive suite of plains that dominates the geology of the northern part of the region. With a surface area of nearly 6.5 x 10 6 km 2 (roughly two-thirds that of the United States), the quadrangle is located northwest of the Beta-Atla-Themis volcanic zone and southeast of the Atalanta Planitia lowlands, areas proposed to be the result of large scale mantle upwelling and downwelling, respectively. The region immediately south of Ganiki Planitia is dominated by Atla Regio, a major volcanic rise beneath which localized upwelling appears to be ongoing, whereas the area just to the north is dominated by the orderly system of north-trending deformation belts that characterize Vinmara Planitia. The Ganiki Planitia quadrangle thus lies at the intersection between several physiographic regions where extensive mantle flow-induced tectonic and volcanic processes are thought to have occurred. The geology of the V-14 quadrangle is characterized by a complex array of volcanic, tectonic, and impact-derived features. There are eleven impact craters with diameters from 4 to 64 km, as well as four diffuse 'splotch' features interpreted to be the product of near-surface bolide explosions. Tectonic activity has produced heavily deformed tesserae, belts of complex deformation and rifts as well as a distributed system of fractures and wrinkle ridges. Volcanic activity has produced extensive regional plains deposits, and in the northwest corner of the quadrangle these plains host the initial (or terminal) 700 km of the Baltis Vallis canali, an enigmatic volcanic feature with a net length of ~7,000 km that is the longest channel on Venus. Major volcanic centers in V-14 include eight large volcanoes and eight coronae; all but one of these sixteen features was noted during a previous global survey. The V-14 quadrangle contains an abundance of minor volcanic features including individual shield volcanoes and localized fissure eruptions as well as many small annular structures and domes, which often serve as the source for local lava flows. The topographic and geophysical characteristics of the Ganiki Planitia quadrangle are less complex than the surface geology, but they yield equally valuable information about the region’s formation and evolution. Referenced to the mean planetary radius of 6051.84 km, the average elevation in the quadrangle is -0.26±0.86 km (2σ) with a full range of -2.58 km to 1.85 km. The highest 2.5 percent of elevations in the quadrangle (above 0.60 km) are associated primarily with the major tessera blocks and the peaks of a few volcanic edifices, whereas the lowest 2.5 percent (below -1.12 km) mostly occur within corona interiors and in the northwest corner of the quadrangle where the plains begin to merge into the Atalanta Planitia lowlands. At the ~4.6 km/pixel scale of the topography data, the mean point-to-point topographic slope is 0.63° and topographic slopes greater than 2° cover less than 5 percent of the region. Overall, the topography of the Ganiki Planitia quadrangle can be characterized as flat, low lying, and nearly devoid of abrupt topographic variation. Complementing this gentle topography, the geoid anomaly has a generally linear gradient that decreases north-northwest from a high of ~20 m at the southern edge of the quadrangle (the northern border of the Atla Regio anomaly) to a low of -30 to -40 m along the northern edge (Konopliv and others, 1999). The vertical component of the gravity anomaly varies from ~50 mGal to -40 mGal, and integrated analysis of the gravity and topography data indicates that dynamically supported regions and areas of thickened crust are both present within the quadrangle. Because the Ganiki Planitia quadrangle is a plains-dominated lowland area that lies between several major physiographic provinces (namely, Atla Regio, Atalanta Planitia, and Vinmara Planitia), a geologic map of the region may yield insight into a wide array of important problems in Venusian geology. The current mapping effort and analysis complements previous efforts to characterize aspects of the region’s geology, for example stratigraphy near parabolic halo crater sites, volcanic plains emplacement, wrinkle ridges, volcanic feature distribution, volcano deformation, coronae characteristics, lithospheric flexure, and various features along a 30±7.58° N. geotraverse. Our current research focuses on addressing four specific questions. Has the dominant style of volcanic expression within the quadrangle varied in a systematic fashion over time? Does the tectonic deformation within the quadrangle record significant regional patterns that vary spatially or temporally, and if so what are the scales, orientations and sources of the stress fields driving this deformation? If mantle upwelling and downwelling have played a significant role in the formation of Atla Regio and Atalanta Planitia as has been proposed, does the geology of Ganiki Planitia record evidence of northwest-directed lateral mantle flow connecting the two sites? Finally, can integration of the tectonic and volcanic histories preserved within the quadrangle help constrain competing resurfacing models for Venus?

Scientific Investigations Map↗

USGS1987

Results of a workshop concerning assessment of the functions of bottomland hardwoods

The U.S. Environmental Protection Agency (EPA) is authorized under Section 404 of the Clean Water Act (33 U.S.C. 1344) to participate in the regulation of the discharge of dredged or fill material into waters of the United States. This regulatory authority is exercised in partnership with the U.S. Army Corps of Engineers, which has responsibility for permit issuance, and in consultation with the U.S. Fish and Wildlife Service and the National Marine Fisheries Service. Through amendments to the original statute, a series of legal actions and court decisions, and the development of operating guidance among the responsible agencies, Section 404 has evolved into the primary mechanism afforded Federal authorities for the protection of wetlands. EPA recognizes the importance of wetlands in achieving the goals of the Clean Water Act, which are to protect and maintain the chemical, physical, and biological integrity of the Nation’s waters. EPA Administrator Lee Thomas has identified wetlands protection as among the highest of Agency priorities. EPA recognizes that bottomland hardwood (BLH) wetlands have vital and unique attributes that, if lost, would severely impact the physical, chemical, and biological integrity of the Nation's waters. As part of a broad program to better protect the Nation's wetlands, EPA has therefore identified bottomland hardwood wetlands as a priority resource requiring special attention on a national basis. Recognizing the importance of implementing an effective, nationally consistent, and scientifically defensible regulatory program, EPA, in October 1984, issued Interim Operating Guidance to its field personnel for implementing the Section 404 regulatory program in bottomland hardwood wetlands. With the goal of improving and finalizing that guidance, EPA is sponsoring a series of workshops designed to answer key questions concerning BLH wetlands, based on the best scientific and technical information currently available. The first two workshops were directed toward summarizing existing scientific and technical knowledge concerning the functions of BLH ecosystems, the characteristics that are important to each function, and the impact of various development activities on those characteristics. The first workshop, which was held in St. Francisville, Louisiana, in December, 1984, examined a wetland zonation concept as a framework for gaining a greater understanding of BLH structure and function. The workshop set out to determine whether characterization of BLH resources as a series of relatively distinct zones, defined by concomitant variation in hydrologic regime, soils, and vegetation, might provide the basis for a useful and scientifically sound regulatory framework. For examp1e, if certain zones are of particular importance to one or more wetland functions that the Clean Water Act was intended to protect, then the zonation concept might be useful from the perspective of how various activities should be regulated. Discussions during the first workshop, however, indicated that the zonation concept provides, at best, only an incomplete picture of the structure and function of BLH ecosystems. In many cases, BLH functions are not limited to or closely correlated with particular zones and, furthermore, many factors other than zone are important determinants of BLH functions. With these responses in mind, the second workshop, held at Lake Lanier, Georgia, in July, 1985, was designed to elicit information on two questions. First, if zones are not an adequate framework for understanding the functions of BLH systems, what characteristics (predictors) can be used to assess the extent to which a particular site performs these functions? And second, what are the impacts of various development activities that often occur in BLH ecosystems on those characteristics and thus on the functions themselves? At the second workshop, individual workgroups dealing with particular subject areas (e.g., hydrology, water quality, fisheries, wildlife, ecosystem processes, and cultural/recreational/economic resources) were able to identify site characteristics that are important determinants of the performance of various functions. For example, the Hydrology Workgroup identified flood storage as one of three major hydrologic functions that BLH ecosystems perform. The workgroup then identified the most important characteristic (e.g., surface area of the site, soil saturation, and others) that determine flood storage and the likely impact of several common activities (e.g., conversion to soybean production and levee construction) on these characteristics. Some of the workgroups also provided estimates of the aggregate impact of activities, acting through all of the characteristics, on certain functions. The workgroups also identified key characteristics that could be used to identify high-value wetlands for various functions. In addition, the workgroups pointed out a number of topics needing further examination and discussion. First, all of the workgroups identified the need to develop the technical basis and information sources to address the problem of cumulative impacts in the regulatory process. Second, most of the workgroups noted the important of contextual variables in assessing the function of a particular site. For example, the location of a BLH site in relationship to other tracts of habitat is an important variable for many wildlife species. Similarly, the extent to which a site retains or transforms contaminants is depended not only on the characteristics of the site, but also on its position in a watershed relative to contaminant inputs. And finally, several of the workgroups pointed out that assessing the impact of an activity on a function is not as simple as "adding up" the impact on individual characteristics, but may depend instead on complex interactions among characteristics. Addressing these questions, as summarized in the objectives and discussions that follow, was the focus of the third workshop, the results of which are described in this report.

Report↗

USGS1984

Types of damage that could result from a great earthquake in the New Madrid, Missouri, seismic zone

In the winter of 1811–1812 a series of three great earthquakes occurred in the New Madrid seismic zone. In addition to the three principal shocks, at least 15 other earthquakes, I o ≥ VIII, occurred within a year of the first large earthquake on December 16, 1811. The three main shocks were felt over the entire eastern United States. They were strong enough to cause minor damage as far away as Indiana and Ohio on the north, the Carolinas on the east, and southern Mississippi on the south. They were strong enough to cause severe or structural damage in parts of Missouri, Illinois, Indiana, Kentucky, Tennessee, Mississippi, and Arkansas. The section of this poster titled "Seismic history of the New Madrid region" describes what happened in the epicentral region. Fortunately, few people lived in the severely shaken area in 1811; that is not the case today. What would happen if a series of earthquakes as large and numerous as the "New Madrid" earthquakes were to occur in the New Madrid seismic zone today? Photographs 1-10 show typical damage to structures that occurred during various earthquakes in the United States. Structural damage to buildings in the Modified Mercalli intensity scale, a scale used for assigning numbers to earthquake effects, begins at intensity VIII. Minor or architectural damage (cracked plaster, windows, and chimneys) occurs at intensities VI and VII, and effects on people and small objects predominate at intensities below VI (earthquake felt, direction and duration noted, dishes broken). Photographs 1-10 illustrate damage caused by intensity VIII and above. None of the damage shown in these photographs occurred in earthquakes larger than the 1811–1812 New Madrid shocks, and most of the examples are from considerably smaller shocks. Photographs 1-4 and 7 show damage to masonry buildings, mostly old and unreinforced, none designed to be earthquake resistant. How many such buildings are in use in your community? Photographs 5 and 6 show damage to modern structures close to the epicenter of a magnitude 6.5 earthquake, a small shock compared to the magnitudes (8.4–8.7) of the New Madrid earthquakes. Photographs 8–10 are typical of damage that can occur at large distances from great earthquakes. Tall buildings are particularly susceptible to ground motions with relatively long periods (greater than 1 second), while short, rigid buildings are generally more likely to be damaged by ground motions with periods of less than 1 second. Shorter period ground motions attenuate more rapidly with distance from the epicenter than do the longer period motions. The 1811-1812 earthquakes produced extensive ground effects. Earthquakes can cause many different kinds of ground effects, ranging from minor fissures, slumps, and rockslides to major landslides and disturbances of the ground surface. Photographs 1117 show typical earthquake ground effects and the kinds of damage they can cause to manmade structures. Is another earthquake as large as the 1811-1812 shocks really likely to occur in New Madrid seismic zone? Great earthquakes such as the 1811-1812 series are estimated to occur in the zone on the average every 500 years. However, earthquakes strong enough to cause structural damage (VIII in the Modified Mercalli intensity scale) are estimated to occur in the seismic zone on the average every 50 years. The last such shock occurred in 1843. How do you prepare for a possible earthquake and what do you do if one occurs? The section on "Earthquake safety tips" explains what to do before, during, and after an earthquake. Want to know more? See "Sources of additional information." Other reports of interest are listed in "References cited."

New Madrid seismic zone↗

USGS2012

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth↗

USGS1978

Reconnaissance engineering geology of the Petersburg area, southeastern Alaska, with emphasis on geologic hazards

A program to study the engineering geology of most larger Alaska coastal communities and to evaluate their earthquake and other geologic hazards was started following the 1964 Alaska earthquake; this report about the Petersburg area is a product of that program. Field-study methods were of a reconnaissance nature, and thus, interpretations in the report are tentative. Landscape of the northern end of Mitkof Island on which Petersburg is situated is characterized by a gently sloping, muskeg-covered terrain, with altitudes mostly less than 30 m. In contrast, much of the rest of the island is composed of mountainous terrain with many steep valleys. During the Pleistocene Epoch, the Petersburg area presumably was covered by ice several times; glaciers deeply eroded many valleys on Mitkof Island and adjacent areas. The last major deglaciation probably was largely completed by 12,000 years ago. Delayed rebound of the earth's crust, after the melting of large amounts of ice, permitted extensive inundation of land in the Petersburg area. Subsequently, emergence has elevated marine deposits to a present-day altitude of at least 65 m and probably to 75 m. Bedrock in the Petersburg map area is composed of relatively hard metamorphic rocks, chiefly phyllite and probably some graywacke. Rocks are of Middle(?) Jurassic to Early Cretaceous age. Five types of surficial geologic material of Quaternary age were recognized: (1) mixed deposits consisting of diamicton, silt-clay, and sand or sandy pebble gravel, (2) alluvial deposits, (3) shore and delta deposits, (4) organic deposits, and (5) artificial fill. Geologic structure in southeastern Alaska is complex because several cycles of tectonic deformation since at least early Paelozoic time have affected different parts of the region. The latest of the major tectonic events in southeastern Alaska occurred in Tertiary time, with some minor activity continuing into the Quaternary Period. Along the outer coast of southeastern Alaska, active strike-slip movement is occurring along the Chichagof-Baranof and Queen Charlotte faults. A segment of the prominent Coast-Range lineament, part of which may be a fault, lies 18 km northeast of Petersburg. Many earthquakes occur along the outer coast of southeastern Alaska. Most of these shocks are associated with movements along the Chichagof-Baranof, Queen Charlotte, and Transition faults. A few small earthquakes occur in the region between the outer coast and the southern part of the Coast Mountains. 0nly a few earthquakes have been recorded as felt at Petersburg; these shocks and others possibly felt in the Petersburg region are tabulated. Among the recorded earthquakes the highest intensity (about V-VI) as the magnitude 7.1 earthquake of October 24, 1927, that occurred probably along the Chichagof-Baranof fault, and about 225 km northwest of Petersburg; damage was reported as minor. Other large earthquakes along the Chichagof-Baranof fault that affected or probably affected the Petersburg area in a minor way occurred on August 22, 1949 (magnitude 8.1) and on July 30, 1972 (magnitude 7.25). From a consideration of the tectonics and earthquake history of the region, earthquakes similar to the 1927, 1949, and 1972 shocks are expected to recur on segments of the Chichagof-Baranof or Queen Charlotte faults. The closest of these fault segments is about 170 km southwest from Petersburg. The likelihood of destructive earthquakes being generated along faults closer to Petersburg is unknown. A very generalized discussion of possible geologic effects that could occur in the area during a postulated, theoretically reasonable worst case earthquake of magnitude 8 occurring along the outer coast about 170 km southwest from Petersburg notes that ground shaking probably would be strongest on organic deposits and least on bedrock and on firm, compact diamicton. Among other effects that could happen are: (1) liquefaction of some of the few delta and alluvial

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USGS2015

Geochemical, modal, and geochronologic data for 1.4 Ga A-type granitoid intrusions of the conterminous United States

Introduction The purpose of this report is to present available geochemical, modal, and geochronologic data for approximately 1.4 billion year (Ga) A-type granitoid intrusions of the United States and to make those data available to ongoing petrogenetic investigations of these rocks. A-type granites, as originally defined by Loiselle and Wones (1979), are iron-enriched granitoids (synonymous with the ferroan granitoids of Frost and Frost, 2011) that occur in an anorogenic, within-continent setting. Relative to other granitic rocks, A-type granites have high FeO*/(FeO*+MgO), high K 2 O and K 2 O/Na 2 O, are metaluminous to weakly peraluminous, and are enriched in incompatible trace elements. Loiselle and Wones (1979) further suggested that A-type granites are relatively anhydrous. Anderson (1983) provides an early compilation of data for the products of 1.4 Ga magmatism in North America and notes the spatial and temporal association of a trio of rock types, which includes gabbro to anorthosite, intermediate composition mangerite, and granitic rapakivi rocks. In North America, the majority of known A-type intrusions were emplaced between 1.5 and 1.3 Ga and are predominantly of the granitic variety (Anderson, 1983). This report addresses the broadly Mesoproterozoic-age granitic rocks of the conterminous United States. Constituents of this group of intrusive rocks were defined using a variety of spatial, compositional, and geochronologic metrics. Thomas and others (2012) provided an updated synthesis, largely based on new isotopic and geochronologic data (for example, Fisher and others, 2010), for the large-scale geologic and tectonic evolution of the eastern United States. Their findings suggest that the basement rocks of the central and southern Appalachian region are allochthonous relative to the remainder of Laurentia and were accreted along the Grenville front between 1.25 and 1.0 Ga. Accordingly, Mesoproterozoic rocks east of the Grenville front and south of the approximate latitude of New York City do not represent North American magmatism. Consequently, geochemical, modal, and geochronologic data for these rocks are not included in the compilation described herein. Further, the structural styles and compositions of granitoid rocks east of the Grenville front, mostly highly deformed gneissic rocks, are dissimilar to those characteristic of the A-type granitoid rocks described herein. A variety of compositional and age information further characterizes the 1.4 Ga A-type granitoid rocks in the conterminous United States. Most samples included in this compilation have felsic compositions, although some extend to intermediate compositions. SiO2 contents range from 56 to almost 78 weight percent, and median and mean SiO2 contents are 72.0 and 71.1 weight percent, respectively. The majority of these rocks for which modal data are available are composed of monzogranite (Streckeisen, 1976), although the dataset also contains many samples composed of granodiorite and syenogranite. A smaller group of the granitoid rocks in this dataset are composed of quartz monzodiorite and quartz monzonite, and a very small subset of samples is composed of alkali-feldspar granite, tonalite, alkali-feldspar quartz syenite, and quartz syenite (fig. 1). Many of the 1.4 Ga granitoid rocks are further characterized by medium- to coarse-grain size and are also conspicuously porphyritic; alkali feldspar phenocrysts or megacrysts (2–10 cm), often with rapakivi overgrowths, are a common feature of many of these rocks (Anderson, 1983; Anderson and Bender, 1989; Anderson and Cullers, 1978; Condie and Budding, 1979). The age of A-type magmatism in North America ranges from about 1.8 to 1.0 Ga, although Anderson (1983) suggests that more than 70 percent (by volume) of A-type magmatism in this region occurred between 1.49 and 1.41 Ga. In the conterminous United States, ages of A-type granitoid rocks are restricted to the period between about 1.49 and 1.33 Ga (Anderson, 1983; Bauer and Pollock, 1993; Bickford and Mose, 1975; Bickford, Harrower, and others, 1981; Bickford and others, 1989; Dewane and Van Schmus, 2007; Hoppe and others, 1983; Peterman and Hedge, 1968; Van Schmus and Bickford, 1981; Van Schmus and others, 1975). Using these recognition criteria, we identified A-type granitoid intrusions of the conterminous United States; for those intrusions, we compiled available geochemical, modal, isotopic (Sr and Nd) and geochronologic data for inclusion in the databases described herein. The significance of 1.4 Ga granitoid rocks relative to the geologic evolution of the conterminous United States remains unclear, despite Anderson’s (1983) compilation and synthesis of compositional data pertinent to these rocks. The large-volume magmatic events indicated by these rocks, as well as their broad geographic distribution, tectonic significance, and association with mineral deposits, underscore their importance. The broad distribution of these rocks, from the northern mid-continent to the southwestern United States (in New Mexico, Arizona, California, and southernmost Nevada), throughout the Rocky Mountains in New Mexico and Colorado (and sporadically in southern Wyoming and central Idaho), and beneath much of the Plains region (as indicated by drilling), has led to the large-scale tectonic and magmatic processes responsible for genesis of the associated magmas being actively studied. In addition, Kisvarsanyi (1972) suggests that iron-copper deposits in the St. Francois Mountains of southeastern Missouri are petrogenetically associated with 1.4 Ga A-type granitoids that occur in that region. Similarly, Dall’Agnol and others (2012) summarize important global associations between A-type granitoid rocks and a variety of important ore deposit types, particularly tin, high-field-strength elements (Zr, Hf, Nb, Ta), rare-earth elements, and iron oxide-copper-gold deposits. Consequently, the need to better understand relations between A-type granitoid rocks, tectonic setting, and magma petrogenesis, as well as their genetic associations with important types of ore deposits, suggests that developing a definitive geochemical, modal, and geochronologic database for these rocks in the conterminous United States is of considerable value.

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