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At least 469 records · Page 26Linked to original sources

Depositional environment and organic matter accumulation of Upper Ordovician–Lower Silurian marine shale in the Upper Yangtze Platform, South China

The main controlling factors of organic matter accumulation in the Upper Ordovician Wufeng–Lower Silurian Longmaxi Formations are complex and remain highly controversial. This study investigates the vertical variation of total organic carbon (TOC) content as well as major and trace element concentrations of four Ordovician–Silurian transition sections from the Upper Yangtze Platform of South China to reconstruct the paleoenvironment of these deposits and to improve our understanding of those factors that have influenced organic matter accumulation in these deposits. The residual TOC content of the Wufeng Formation averages 3.2% and ranges from 0.12 to 6.0%. The overlying lower Longmaxi Formation displays higher TOC content (avg. 4.4%), followed upsection by consistent and lower values that average 1.6% in the upper Longmaxi Formation. The concentration and covariation of redox-sensitive trace elements (Mo, U and V) suggest that organic-rich intervals of the Wufeng Formation accumulated under predominantly anoxic conditions. Organic-rich horizons of the lower Longmaxi Formation were deposited under strongly anoxic to euxinic conditions, whereas organic-poor intervals of the upper Longmaxi Formation accumulated under suboxic conditions. Positive correlations between redox proxies and TOC contents suggest that organic matter accumulation was predominantly controlled by preservation. Barium excess (Ba xs ) values indicate high paleoproductivity throughout the entire depositional sequence, with an increase in the lower Longmaxi Formation. Increased productivity may have been induced by enhanced P recycling, as evidenced by elevated C org /P tot ratios. Mo–U covariation and Mo/TOC values reveal that the Wufeng Formation was deposited under extremely restricted conditions, whereas the Longmaxi Formation accumulated under moderately restricted conditions. During the Late Ordovician, the extremely restricted nature of ocean circulation on the Upper Yangtze Platform in tandem with enhanced stratification of the water column promoted anoxic conditions favorable for the preservation of organic matter. During Early Silurian time, organic matter accumulation was principally controlled by changes in sea level, which affected terrigenous flux, redox conditions, and the degree of nutrition recycling.

Upper Yangtze Platform

Effects of age and environment on stable carbon isotope ratios in tree rings of riparian Populus

Stable carbon isotopes of riparian tree rings are enabling improved reconstruction of past climate variability, but this advance is limited by difficulty distinguishing the effects of tree age from those of climate. We investigated relative influence of age and climate trends in genus Populus, which dominates floodplain forests in Europe, Asia and North America. We related precipitation and river flow to annual variation in stable carbon isotope ratio (δ13C) in trees with a broad distribution of ages spanning two hundred years. On the floodplain of the lightly regulated Little Missouri River, North Dakota, USA, we examined a total of 845 rings from seven specimens of cottonwood tree (Populus deltoides W. Bartram ex Marshall ssp. monilifera [Aiton] Eckenwalder). Cottonwood δ13C decreased from pith to bark in whole wood, but this trend was almost completely eliminated in purified cellulose. The δ13C offset between whole wood and cellulose increased from pith to bark, consistent with trends of decreasing cellulose and increasing hemicellulose as a proportion of whole wood. While annual ring width was correlated with monthly precipitation from April through June, δ13C showed strong correlations only in June and July, suggesting that these complementary proxies allow resolution of seasonal variation in water availability. We conclude that past climate can be reconstructed from δ13C of purified cellulose from cottonwood without detrending for tree age.

Palaeogeography, Palaeoclimatology, Palaeoecology

Microbial-sized, carboxylate-modified microspheres as surrogate tracers in a variety of subsurface environments: An overview

Since 1986, fluorescent carboxylate-modified polystyrene/latex microspheres (FCM) have been co-injected into aquifers along with conservative tracers and viruses, bacteria, and (or) protozoa. Use of FCM has resulted in new information about subsurface transport behaviors of microorganisms in fractured crystalline rock, karst limestone, soils, and granular aquifers. FCM have been used as surrogates for oocysts of the pathogenic protist Cryptosporidium parvum in karst limestone and granular drinking-water aquifers. The advantages of FCM in subsurface transport studies are that they are safe in tracer applications, negatively charged, easy to detect, chemically inert, and available in wide range of sizes. The limitations of FCM are that the quantities needed for some field transport studies can be prohibitively expensive and that their surface characteristics may not match the microorganisms of interest. These limitations may be ameliorated, in part by using chemically modified FCM so that their surface characteristics are a better match to that of the organisms. Also, more sensitive methods of detection may allow using smaller quantities of FCM. To assess how the transport behaviors of FCM and pathogens might compare at the field scale, it is helpful to conduct side-by-side comparisons of their transport behaviors using the geologic media and site-specific conditions that characterize the field site.

Procedia Earth and Planetary Science

Landscape response to deglaciation in a high relief, monsoon-influenced alpine environment, Langtang Himal, Nepal

Significant glacial fluctuations and rapid paraglacial reworking of glacigenic sediments characterize the Middle and Late Holocene of the Langtang Khola Valley, Central Nepal Himalaya. Geomorphic mapping and beryllium-10 cosmogenic radionuclide (CRN) dating of moraines and paraglacial fans were undertaken to test the existing paraglacial fan, terrace and moraine chronologies. The new dating compares favorably with prior studies that utilized radiocarbon, adding additional support to the assumption that fan and terrace formation are strongly linked to deglaciation. Fan and terrace denudation rates are so rapid in this region, averaging ∼33 mm/yr, that no depositional landforms older than 5 ka are preserved within 250 m of the valley floor. In this region, high rates of denudation during the Late Quaternary are driven by a combination of rapid tectonic uplift, numerous glacial fluctuations and intense weathering driven by an active monsoon climate. Extensive reworking of glacigenic sediments in Langtang during the latter half of the Holocene is consistent with studies completed in other areas of the Himalaya that are strongly influenced by the monsoon.

Langtang Himal

Mid-Wisconsinan environments on the eastern Great Plains

Few sites on the eastern Great Plains contain paleobotanical records for the mid-Wisconsin. We report on four sites, two stream cutbanks and two quarry exposures, ranging in age from >50 to ???23.4 ka. The oldest site at >50 ka contains a suite of macrofossils from prairie and disturbed ground habitats, with no representation of trees, indicating an open prairie. By ???38 ka the assemblages include aquatic, wetland, mudflat, and prairie elements with rare specimens of Populus, Betula cf. papyrifera, Salix and at the most northerly site, Picea. This assemblage suggests a prairie/parkland with interspersed marshes, cooler temperatures and increased moisture. Populus and Salix continued to be represented from ???36 to ???29 ka, but the only other taxon was Carex. A hiatus may be present at some time during this interval. After ???29 ka, Picea became dominant on the uplands and it was joined by sedges in local wetlands. At sites near riverine loess sources, loess accumulation began to fill in the wetlands and organic deposition ceased some time after 29 ka. ?? 2009 Elsevier Ltd. All rights reserved.

Quaternary Science Reviews

Energetic constraints and the paradox of a diffusing population in a heterogeneous environment

Previous mathematical analyses have shown that, for certain parameter ranges, a population, described by logistic equations on a set of connected patches, and diffusing among them, can reach a higher equilibrium total population when the local carrying capacities are heterogeneously distributed across patches, than when carrying capacities having the same total sum are homogeneously distributed across the patches. It is shown here that this apparently paradoxical result is explained when the resultant differences in energy inputs to the whole multi-patch system are taken into account. We examine both Pearl–Verhulst and Original Verhulst logistic models and show that, when total input of energy or limiting resource, is constrained to be the same in the homogeneous and heterogeneous cases, the total population in the heterogeneous patches can never reach an asymptotic equilibrium that is greater than the sum of the carrying capacities over the homogeneous patches. We further show that, when the dynamics of the limiting resources are explicitly modeled, as in a chemostat model, the paradoxical result of the logistic models does not occur. These results have implications concerning the use of some ubiquitous equations of population ecology in modeling populations in space.

Theoretical Population Biology

Movers and stayers: Novel assemblages in changing environments

How species will respond to ongoing climate and other change is of increasing concern. Most attention is given to how species move or are moved, but many species stay. Understanding the dynamics of new species combinations is essential for successful conservation in a changing climate. Increased attention to species movement in response to environmental change highlights the need to consider changes in species distributions and altered biological assemblages. Such changes are well known from paleoecological studies, but have accelerated with ongoing pervasive human influence. In addition to species that move, some species will stay put, leading to an array of novel interactions. Species show a variety of responses that can allow movement or persistence. Conservation and restoration actions have traditionally focused on maintaining or returning species in particular places, but increasingly also include interventions that facilitate movement. Approaches are required that incorporate the fluidity of biotic assemblages into the goals set and interventions deployed.

Trends in Ecology and Evolution

Provenance, age, and environment of mid-Wisconsinan slackwater lake sediment in the St. Louis Metro East area, USA

Valleys tributary to the Mississippi River contain fossiliferous slackwater lake sediment (Equality Formation) deposited in response to aggradation of the Mississippi River valley during the last glaciation. In the St. Louis Metro East area, the lower part of the Equality Formation is primarily laminated, fossiliferous silt and clay deposited from about 44,150 to 24,310 14C yr B.P. The upper Equality Formation is primarily very fine sand to silt deposited from about 21,200 to 17,000 14C yr B.P. Among the four cores that sample this succession in the St. Louis Metro East area, core MNK-3 (38.64EN, 90.01EW) was selected for detailed study. Three sources are distinguished by the following characteristics: (1) gray smectite-quartz-Se-rich, feldspar-poor material of the Des Moines, Wadena, and James lobes; (2) reddish brown kaolinite-Cu-Fe-rich sediment of the Superior and Rainy lobes; and (3) brown illite-dolomite-Sr-rich sediment of the Lake Michigan and Green Bay lobes. The earliest sediments (44,150 to 41,700 14C yr B.P.) were derived from the central and western provenances and are chronocorrelative with the lower Roxana Silt. A hiatus occurred from about 41,700 to 29,030 14C yr B.P. when much of the middle Roxana Silt (Meadow Member) was deposited on adjacent uplands. The youngest sediment includes evidence of heightened activity of the Superior Lobe at about 29,000 14C yr B.P., the Lake Michigan and Green Bay lobes from about 25,000 to 24,000 14C yr B.P., and the Wadena-Des Moines-James lobes at about 21,000 14C yr B.P. ?? 2005 Society. Published by University of Washington. All rights reserved.

Quaternary Research

Modern accumulation rates and a sediment budget for the Eel shelf: a flood-dominated depositional environment

The northern California continental margin is periodically impacted by geologically significant storms, which have a marked influence on terrigenous sediment supply, flood deposition, and long-term accumulation of fine-grained sediment on the Eel shelf. Accumulation of Eel River muds on the adjacent shelf was investigated using 210Pb and 137Cs geochronologies, in order to understand the fate of sediment discharged by the Eel River and to relate patterns of net sediment accumulation (100-yr time scale) to sediment dynamics. 210Pb data demonstrate that modern accumulation of river mud occurs from the 50-m isobath seaward. Across-shelf accumulation rates decrease from maximum mid-shelf values of 0.6–1.7 g cm2 yr1 to values of 0.2–0.4 g cm2 yr1 at the shelf break, with a spatially weighted mean of 0.5 g cm2 yr1 (0.4 cm=yr) for the entire shelf. 210Pbxs sediment-depth profiles from the region of highest accumulation rate are characterized by subsurface intervals of low and uniform activity, which are produced by flood deposition. In some cores, particular 210Pbxs activity intervals may be associated with major Eel River floods of 1955, 1964, and 1974. It is postulated that, because of the coincidence of high-river-flow events and southerly winds during cyclonic winter storms, net northward transport allows for preferential deposition of fine-grained sediment north of the river mouth. Over the past ¾100 years, fluvial sediment input combined with marine dispersal processes have produced a mid-shelf depocenter, evident by both the spatial distribution of 210Pb accumulation rates and by clay-rich flood layers partially preserved in shelf deposits. A fine-grained sediment budget for the dispersal system, based on hydrological data and 210Pb geochronologies, demonstrates that a maximum of ¾20% (3 ð 109 kg=yr) of the mean annual supply of fluvial mud (14 ð 109 kg=yr) is trapped on the shelf. The results of this study demonstrate that: (1) short-term sedimentation processes associated with floods can influence sediment accumulation on longer time scales; and (2) a major fraction of fine-grained sediment supplied to tectonically active margins by flood-prone mountainous rivers bypasses narrow continental shelves.

Marine Geology

Heavy-mineral provenance in an estuarine environment, Willapa Bay, Washington, USA: palaeogeographic implications and estuarine evolution

Modern sediments from representative localities in Willapa Bay, Washington, comprise two principal heavy-mineral suites. One contains approximately equivalent amounts of hornblende, orthopyroxene, and clinopyroxene; this is derived from the Columbia River, which discharges into the Pacific Ocean a short distance south of the bay. The other suite, dominated by clinopyroxene, is restricted to sands of rivers flowing into the bay from the east. The heavy-mineral distributions within the bay suggest that sand discharged from the Columbia River, borne north by longshore transport and carried into the bay by tidal currents, accounts for nearly all of the sand within the interior of Willapa Bay today. Pleistocene deposits on the east side of the bay contain three heavy-mineral assemblages, two of which are identical to the modern assemblages described above. These assemblages reflect the relative influence of tidal and fluvial processes on the Late Pleistocene deposits (100,000–200,000 BP. Amino acid racemization in Quaternary shell deposits at Willapa Bay, Washington. Geochimica et Cosmochimica Acta 43, 1505–1520). They are also consistent with those processes inferred on the basis of sedimentary structures and stratigraphic relations in about two-thirds of the samples examined. Anomalies can be explained by recycling of sand from older deposits. The persistence of the two heavy-mineral suites suggests that the pattern of estuarine sedimentation in Late Pleistocene deposits closely resembled that of the modern bay. The third heavy-mineral suite is enriched in epidote and occurs in a few older Pleistocene units. On the north side of the bay, the association of this suite with southwest-directed foresets in cross-bedded gravel indicates derivation from the northeast, perhaps from an area of glacial outwash. The presence of this suite in ancient estuarine sands exposed on the northeast side of the bay suggests that input from this northerly source may have intermittently dominated Willapa Bay deposition in the past.

Washington

Block coals from Indiana: Inferences on changing depositional environment

Significant differences in coal petrography, palynology and coal quality were found between the Lower Block and Upper Block Coal Members (Brazil Formation, Pennsylvanian) in Daviess County, Indiana. The Lower Block Coal Member ranges in thickness from 51 to 74 cm and the Upper Block Coal Member ranges from 20 to 65 cm. Average sulfur content and ash yield of the Lower Block coal (0.98%, 7.65%) are lower than in the Upper Block coal. Megascopically, the coals show distinct differences. The Lower Block is a banded coal with numerous thin fusain horizons and a thin clay parting in the lower third of the seam. The Upper Block coal has a dulling-upward trend, with a bright clarain found at the base that grades into a clarain and then into a durain in the upper portion of the seam. Vitrinite content of the Lower Block coal ranges from 63% to 78%, with the highest vitrinite content found in the middle portion of the seam. In the Upper Block coal, vitrinite content ranges from 40% to 83%, with the highest values found in the lower part of the seam. Ash yield is higher in the upper part of the Upper Block coal, reaching up to 40%. The Lower Block coal is dominated by lycopod trees and tree ferns. The Upper Block coal shows marked differences in spore assemblages between lower and upper parts of the seam. The lower half is dominated by large lycopod trees and tree ferns, similar to the Lower Block coal. The upper half is dominated by small lycopods, mainly Densosporites and Radiizonates. These differences between the Lower Block and Upper Block Coal Members are significant correlation tools applicable to mining exploration and chronostratigraphy. (C) 2000 Elsevier Science B.V. All rights reserved.Significant differences in coal petrography, palynology and coal quality were found between the Lower Block and Upper Block Coal Members (Brazil Formation, Pennsylvanian) in Daviess County, Indiana. The Lower Block Coal Member ranges in thickness from 51 to 74 cm and the Upper Block Coal Member ranges from 20 to 65 cm. Average sulfur content and ash yield of the Lower Block coal (0.98%, 7.65%) are lower than in the Upper Block coal. Megascopically, the coals show distinct differences. The Lower Block is a banded coal with numerous thin fusain horizons and a thin clay parting in the lower third of the seam. The Upper Block coal has a dulling-upward trend, with a bright clarain found at the base that grades into a clarain and then into a durain in the upper portion of the seam. Vitrinite content of the Lower Block coal ranges from 63% to 78%, with the highest vitrinite content found in the middle portion of the seam. In the Upper Block coal, vitrinite content ranges from 40% to 83%, with the highest values found in the lower part of the seam. Ash yield is higher in the upper part of the Upper Block coal, reaching up to 40%. The Lower Block coal is dominated by lycopod trees and tree ferns. The Upper Block coal shows marked differences in spore assemblages between lower and upper parts of the seam. The lower half is dominated by large lycopod trees and tree ferns, similar to the Lower Block coal. The upper half is dominated by small lycopods, mainly Densosporites and Radiizonates. These differences between the Lower Block and Upper Block Coal members are significant correlation tools applicable to mining exploration and chronostratigraphy.

Conference Paper

Modern marine sediments as a natural analog to the chemically stressed environment of a landfill

Chemical reactions that occur in landfills are analogous to those reactions that occur in marine sediments. Lateral zonation of C, N, S, O, H, Fe and Mn species in landfills is similar to the vertical zonation of these species in marine sediments and results from the following reaction sequence: (1) oxidation of C, N and S species in the presence of dissolved free oxygen to HCO 3 - , NO 3 - and SO 4 2 ; (2) after consumption of molecular oxygen, then NO 3 - is reduced, and Fe and Mn are solubilized; (3) SO 4 2- is reduced to sulfide; and (4) organic compounds become the source of oxygen, and CH 4 and NH 4 + are formed as fermentation products. In a landfill in Delaware the oxidation potential increases down-gradient and the redox zones in the reducing plume are characterized by: CH 4 , NH 4 + ,Fe 2+ . Mn 2+ , HCO 3 - and NO 3 - . Lack of SO 4 2- at that landfill eliminates the sulfide zone. Although it has not been observed at landfills, mineral alteration should result in precipitation of pyrite and/or siderite downgradient. Controls on the pH of leachate are the relative rates of production of HCO 3 - , NH 4 + and CH 4 . Production of methane by fermentation at landfills results in 13 C isotope fractionation and the accumulation of isotopically heavy σ CO 2 (+10 to +18 0 / 00 PDB). Isotope measurements may be useful to determine the extent of CO 2 reduction in landfills and extent of dilution downgradient. The boundaries of reaction zones in stressed aquifers are determined by head distribution and flow velocity. Thus, if the groundwater flow is rapid relative to reaction rates, redox zones will develop downgradient. Where groundwater flow velocities are low the zones will overlap to the extent that they may be indeterminate.

Journal of Hydrology

Analysis of the nucleoprotein gene identifies three distinct lineages of viral haemorrhagic septicemia virus within the European marine environment

A ribonuclease (RNase) protection assay (RPA) has been used to detect nucleotide sequence variation within the nucleoprotein gene of 39 viral haemorrhagic septicaemia virus (VHSV) isolates of European marine origin. The classification of VHSV isolates based on RPA cleavage patterns permitted the identification of ten distinct groups of viruses based on differences at the molecular level. The nucleotide sequence of representatives of each of these groupings was determined and subjected to phylogenetic analysis. This revealed grouping of the European marine isolates of VHSV into three genotypes circulating within distinct geographic areas. A fourth genotype was identified comprising isolates originating from North America. Phylogenetic analyses indicated that VHSV isolates recovered from wild caught fish around the British Isles were genetically related to isolates responsible for losses in farmed turbot. Furthermore, a relationship between naturally occurring marine isolates and VHSV isolates causing mortality among rainbow trout in continental Europe was demonstrated.

British Isles

Dispersal ecology of lodgepole pine (Pinus contorta Dougl.) in its native environment as related to Swedish forestry

Lodgepole pine (Pinus contorta Dougl.) covers extensive areas of the mountains of western North America. It has evolved into four subspecies, each adapted to slightly different environmental conditions. All are adapted to reproduce following fire. Subspecies latifolia is the most extensive and economically important in North America. Serotiny is common in this subspecies, but trees bearing nonserotinous cones can be found in most stands, sometimes constituting more that 70% of the trees. Cone crops are produced yearly and seed loss to seed predators, insects and diseases are minimal. Germination and establishment occurs across a broad range of conditions allowing lodgepole pine to grow on poor sites as well as highly productive sites. These characteristics give lodgepole pine the ability to be highly invasive in new areas of suitable habitat.

North America

Dairy-impacted wastewater is a source of iodinated disinfection byproducts in the environment

Iodinated disinfection byproducts (DBPs) are among the most toxic DBPs, but they are not typically measured in treated water. Iodinated DBPs can be toxic to humans, and they also have the potential to affect aquatic communities. Because of the specific use of iodine and iodine-containing compounds in dairies, such livestock operations can be a potential source of iodinated DBPs in corresponding receiving water bodies. DBPs [trihalomethanes (THMs), including iodinated THMs] were measured within dairy processing facilities (milking and cheese manufacturing) and surface waters that receive dairy-impacted effluents [either directly from the dairy or through wastewater treatment plants (WWTPs)] in three areas of the United States (California, New York, and Wisconsin). Iodo-THMs comprised 15−29% of the total THMs in surface water near WWTP effluents that were impacted by dairy waste and 0−100% of the total THMs in samples from dairy processing facilities.

California, New York, Wisconsin

Persistence of 2,6-Dichlorobenzonitrile in aquatic environments

In two experiments 2,6-dichlorobenzonitrile was added to aquatic systems, and the residue levels were followed for about 6 months. A granular formulation applied to a farm pond at 0.6 p.p.m. produced highest residues in water and fish about 2 weeks following treatment whereas vegetation and soil samples had the highest levels within 1 or 2 days. Residues were still measurable after 188 days. In ponds treated with a wettable powder formulation at 10, 20, and 40 p.p.m., residues in water and fish were highest within 3 days after treatment. The concentration in water 11 days after treatment was about 2% of the three-day level. Fish whole-body residues dropped nearly as fast but were still measurable at 112 days.

Book chapter