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At least 469 records · Page 26Linked to original sources
USGS2003

Surface-water quality assessment of the North Fork Red River basin upstream from Lake Altus, Oklahoma, 2002

Elevated salinity in the North Fork Red River is a major concern of the Bureau of Reclamation W. C. Austin Project at Lake Altus. Understanding the relation between surface-water runoff, ground-water discharge, and surface-water quality is important for maintaining the beneficial use of water in the North Fork Red River basin. Agricultural practices, petroleum production, and natural dissolution of salt-bearing bedrock have the potential to influence the quality of nearby surface water. The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, sampled stream discharge and water chemistry at 19 stations on the North Fork Red River and tributaries. To characterize surface-water resources of the basin in a systematic manner, samples were collected synoptically during receding streamflow conditions during July 8-11, 2002. Together, sulfate and chloride usually constitute greater than half of the dissolved solids. Concentrations of sulfate ranged from 87.1 to 3,450 milligrams per liter. The minimum value was measured at McClellan Creek near Back (07301220), and the maximum value was measured at Bronco Creek near Twitty (07301303). Concentrations of chloride ranged from 33.2 to 786 milligrams per liter. The minimum value was measured at a North Fork Red River tributary (unnamed) near Twitty (07301310), and the maximum value was measured at the North Fork Red River near Back (07301190), the most upstream sample station.

Open-File Report↗
USGS1982

Chloride Concentration in Water from the Upper Permeable Zone of the Tertiary Limestone Aquifer System, Southeastern United States

INTRODUCTION The tertiary limestone aquifer system of the southeastern United States is a sequence of carbonate rocks referred to as the Floridan aquifer in Florida and the principal artesian aquifer in Georgia, Alabama, and South Carolina. More than 3 billion gallons of water are pumped daily from the limestone aquifer; and the system is the principal source of municipal, industrial, and agricultural water supply in south Georgia and most of Florida. The aquifer system includes units of Paleocene to early Miocene age that combine to form a continuous carbonate sequence that is hydraulically connected in varying degrees. In a small area near Brunswick, Ga., a thin sequence of rocks of Late Cretaceous age is part of the system. In and directly downdip from much of the outcrop area, the system consists of one continuous permeable unit. Further downdip the aquifer system generally consists of two major permeable zones separated by a less-permeable unit of highly variable hydraulic properties (very leaky to virtually nonleaky). Conditions for the system vary from unconfined to confined depending upon whether the argillaceous Miocene and younger rocks that form the upper confining unit have been removed by erosion. This report is one of a series of preliminary products depicting the hydrogeologic framework, water chemistry, and hydrology of the aquifer system. The map shows the distribution of chloride ions in water from the upper permeable zone of the limestone aquifer system. The upper permeable zone consists of several formations, primarily the Tampa, Suwannee, Ocala, and Avon Park Limestones (Miller 1981a, b). Chloride concentrations of water within the upper permeable zone vary from nearly zero in recharge areas to many thousands of milligrams per liter (mg/L) in coastal discharge areas. Where the aquifer system discharges into the sea, the upper permeable zone contains increasing amounts of seawater. In these areas, wells that fully penetrate the upper permeable zone will yield water with chloride concentrations that approach that of seawater, about 19500 mg/L.

Open-File Report↗
USGS1989

Hydrogeochemical survey of groundwater for selected areas in the Arabian Shield and in cover rocks, Kingdom of Saudi Arabia

In the spring of 1984, a hydrogeochemical survey was conducted in the Kingdom of Saudi Arabia to test ground water as a sampling medium in exploration for mineral deposits. Eighty-one water samples (mostly from wells) were collected. The samples were analysed for the presence and concentration of major cations and anions, as well as a suite of trace elements. Most of the water samples contained high concentrations of dissolved salts. The majority of the samples showed no significant amounts of the trace elements. A few well-water samples contained moderately anomalous concentrations of zinc, molybdenum, and uranium. These anomalies could be due to salinity effects, contamination, or the proximity of mineral sources. This survey has established some baseline water-chemistry data, especially for the trace metals, which to date have not been reported in ground water in the Kingdom of Saudi Arabia.

Open-File Report↗
USGS2007

Hydrogeology of the Coconino Plateau and adjacent areas, Coconino and Yavapai Counties, Arizona

Two large, regional ground-water flow systems occur in the Coconino Plateau and adjacent areas: the C aquifer and the Redwall-Muav aquifer. The C aquifer occurs mainly in the eastern and southern parts of the 10,300-square-mile Coconino Plateau study area, and the Redwall-Muav aquifer underlies the entire study area. The C aquifer is a water-table aquifer for most of its occurrence with depths to water that range from a few hundred feet to more than 1,500 feet. In the western part of the Coconino Plateau study area, the C aquifer is dry except for small localized perched water-bearing zones decoupled from the C aquifer to the east. The Redwall-Muav aquifer underlies the C aquifer and ranges from at least 3,000 feet below land surface in the western part of the Coconino Plateau study area to more than 3,200 feet below land surface in the eastern part of the study area. The Redwall-Muav aquifer is a confined aquifer for most of its occurrence with hydraulic heads of several hundred to more than 500 feet above the top of the aquifer in the western part of the study area and more than 2,000 feet above the top of the aquifer in the eastern part of the study area near Flagstaff. In the eastern and northeast parts of the area, the C aquifer and the Redwall-Muav aquifer are in partial hydraulic connection through faults and other fractures. The water discharging from the two aquifers on the Coconino Plateau study area is generally of good quality for most intended uses. Water from sites in the lower Little Colorado River Canyon had high concentrations of most trace elements relative to other springs, rivers, and streams in the study area. Concentrations of barium, arsenic, uranium, and lead, and gross alpha radioactivity were greater than U.S. Environmental Protection Agency Maximum Contaminant Levels for drinking water at some sites. Ground water discharging to most springs, streams, and wells on the Coconino Plateau and in adjacent areas is a calcium magnesium bicarbonate type and has low concentrations of the major dissolved constituents. Ground water discharging from the Redwall-Muav aquifer to springs in the lower Little Colorado River Canyon is a mixture of water from the C aquifer and the Redwall-Muav aquifer and is a sodium chloride type with high concentrations of most major dissolved constituents. Concentrations of sulfate and chloride in ground water discharging from the Redwall-Muav aquifer at springs near the south rim of Grand Canyon increase toward the west. Water samples from the Verde River above Mormon Pocket had higher concentrations of most dissolved constituents than samples from springs that discharge from the Redwall-Muav aquifer at Mormon Pocket and in Sycamore Canyon. Water-chemistry data from C aquifer wells and springs in the Flagstaff area indicate that ground-water ages in the aquifer range from 7,000 years to modern and that samples were a mix of younger and older waters. Ground-water ages for the Redwall-Muav aquifer are estimated to range from 22,600 to 7,500 years, and low tritium values indicate that this water is older than water discharging from the C aquifer. Tritium and carbon-14 results indicate that ground water discharging at most springs and streams is a mixture of young and old ground waters, likely resulting from multiple flow paths and multiple recharge areas. Ground-water withdrawals in the study area increased from about 4,000 acre-feet per year prior to 1975, to about 20,000 acre-feet per year in 2003. About two-thirds of the water withdrawn is from the C aquifer and about one-third is from the Redwall-Muav aquifer. In the study area, most development of the C aquifer has occurred near Flagstaff. Development of the Redwall-Muav aquifer is more extensive in Verde Valley where water-bearing zones of the aquifer are closer to land surface. In recent years, however, development of the Redwall-Muav aquifer in the study area has increased in response to population growth and the atten

Scientific Investigations Report↗
USGS1982

Chloride Concentration in Water from the Upper Permeable Zone of the Tertiary Limestone Aquifer System, Southeastern United States

INTRODUCTION The tertiary limestone aquifer system of the southeastern United States is a sequence of carbonate rocks referred to as the Floridan aquifer in Florida and the principal artesian aquifer in Georgia, Alabama, and South Carolina. More than 3 billion gallons of water are pumped daily from the limestone aquifer; and the system is the principal source of municipal, industrial, and agricultural water supply in south Georgia and most of Florida. The aquifer system includes units of Paleocene to early Miocene age that combine to form a continuous carbonate sequence that is hydraulically connected in varying degrees. In a small area near Brunswick, Ga., a thin sequence of rocks of Late Cretaceous age is part of the system. In and directly downdip from much of the outcrop area, the system consists of one continuous permeable unit. Further downdip the aquifer system generally consists of two major permeable zones separated by a less-permeable unit of highly variable hydraulic properties (very leaky to virtually nonleaky). Conditions for the system vary from unconfined to confined depending upon whether the argillaceous Miocene and younger rocks that form the upper confining unit have been removed by erosion. This report is one of a series of preliminary products depicting the hydrogeologic framework, water chemistry, and hydrology of the aquifer system. The map shows the distribution of chloride ions in water from the upper permeable zone of the limestone aquifer system. The upper permeable zone consists of several formations, primarily the Tampa, Suwannee, Ocala, and Avon Park Limestones (Miller 1981a, b). Chloride concentrations of water within the upper permeable zone vary from nearly zero in recharge areas to many thousands of milligrams per liter (mg/L) in coastal discharge areas. Where the aquifer system discharges into the sea, the upper permeable zone contains increasing amounts of seawater. In these areas, wells that fully penetrate the upper permeable zone will yield water with chloride concentrations that approach that of seawater, about 19500 mg/L.

Water-Resources Investigations Report↗
USGS1997

Ground-water development and the effects on ground-water levels and water quality in the town of Atherton, San Mateo County, California

The installation of at least 100 residential wells in the town of Atherton, California, during the 198792 drought has raised concerns about the increased potential for land subsidence and salt water intrusion. Data were collected and monitor ing networks were established to assess current processes and to monitor future conditions affect ing these processes. Data include recorded pump age, recorded operation time, and measured pumpage rates from 38 wells; water levels from 49 wells; water chemistry samples from 20 wells, and land-surface elevation data from 22 survey sites, including one National Geodetic Survey estab lished bench mark. Geologic, lithologic, climato logic, well construction, well location, and historical information obtained from available reports and local, state, and Federal agencies were used in this assessment. Estimates of annual residential pumpage from 269 assumed active residential wells in the study area indicate that the average annual total pumping rate is between 395 and 570 acre-feet per year. The nine assumed active institutional wells are estimated to pump a total of about 200 acre- feet per year, or 35 to 50 percent of the total resi dential pumpage. Assuming that 510 acre-feet per year is the best estimate of annual residential pumpage, total pumpage of 710 acre-feet per year would represent about 19 percent of the study area's total water supply, as estimated. Depth-to-water-level measurements in wells during April 1993 through September 1995 typically ranged from less than 20 feet below land surface nearest to San Francisco Bay to more than 70 feet below land surface in upslope areas near exposed bedrock, depending on the season. This range, which is relatively high historically, is attributed to above normal rainfall between 1993 and 1995. Water levels expressed as hydraulic heads indicate the presence of three different hydrologic subareas on the basis of hydraulic-head contour configurations and flow direction. That all measured hydraulic heads in the study area from April 1993 through September 1995 were above sea level indicates that saltwater intrusion was unlikely during this period. The chemistry of 20 well-water samples is characterized as a calcium magnesium carbonate bicarbonate type water. There is no evidence of saltwater intrusion from San Francisco Bay; how ever, water samples from wells nearest the bay and bedrock assemblages indicate a greater concentra tion of dissolved constituents and salinity. Dissolved-solids concentrations of water samples from wells in these areas exceeded 1,000 milli grams per liter, and several samples contained a substantial fraction of sodium and chloride. Water hardness for the 20 wells sampled averaged 471 milligrams per liter as calcium carbonate, which is classified as very hard. One well sample exceeded the primary maximum contaminant level for drinking water in nitrate, several wells exceeded the secondary maximum contaminant level for chloride and sulfate, and all wells sampled exceeded the secondary maximum contaminant level for total dissolved solids. Land-subsidence and the resultant damage because of excessive ground-water pumping, in combination with periodic drought, have a well- documented history in the south San Francisco Bay area. Land-elevation surveying data from 1934 to 1967 indicate that subsidence ranged from 0.1 to approximately 0.5 foot in the vicinity of the study area. It could not be determined from land- surface elevation surveying data from 1993 whether subsidence is currently occurring in the study area.

Water-Resources Investigations Report↗
USGS2001

Aircraft and runway deicers at General Mitchell International Airport, Milwaukee, Wisconsin, USA. 1. Biochemical oxygen demand and dissolved oxygen in receiving streams

Aircraft and runway deicers are used during cold weather at many of the world's airports to facilitate safe air travel. Propylene glycol-, ethylene glycol-, and urea-based deicers are known to have very high biochemical oxygen demand. At General Mitchell International Airport (GMIA) in Milwaukee, Wisconsin, USA, deicer application, water chemistry, and dissolved oxygen (DO) data were collected for two deicing seasons in order to evaluate and define premanagement water quality parameters prior to the implementation of a glycol management program. Calculations using stream-monitoring data during a controlled release of deicer provided an estimate of 0.8/d for the first-order decay rate constant, substantially higher than published laboratory test results. For eight precipitation events with deicing activities, between 2.4 and 99% of propylene and ethylene glycol applied to aircraft was delivered directly to receiving streams. The percentage of glycol runoff during an event increased with increasing storm-flow volume. Elevated concentrations of glycol and biochemical oxygen demand were measured downstream from the airport. However, the frequency of low DO concentrations in the receiving streams is comparable with that at an upstream reference site. This is possibly due to slowed bacteria metabolism at low water temperatures, short travel times, and dilution from downstream tributaries.

Wisconsin↗
USGS2023

Shallow and local or deep and regional? Inferring source groundwater characteristics across mainstem riverbank discharge faces

Riverbank groundwater discharge faces are spatially extensive areas of preferential seepage that are exposed to air at low river flow. Some conceptual hydrologic models indicate discharge faces represent the spatial convergence of highly variable age and length groundwater flowpaths, while others indicate greater consistency in source groundwater characteristics. Our detailed field investigation of preferential discharge points nested across mainstem riverbank discharge faces was accomplished by: (1) leveraging new temperature-based recursive estimation (extended Kalman Filter) modelling methodology to evaluate seasonal, diurnal, and event-driven groundwater flux patterns, (2) developing a multi-parameter toolkit based on readily measured attributes to classify the general source groundwater flowpath depth and flowpath length scale, and, (3) assessing whether preferential flow points across discharge faces tend to represent common or convergent groundwater sources. Five major groundwater discharge faces were mapped along the Farmington River, CT, United States using thermal infrared imagery. We then installed vertical temperature profilers directly into 39 preferential discharge points for 4.5 months to track vertical discharge flux patterns. Monthly water chemistry was also collected at the discharge points along with one spatial synoptic of stable isotopes of water and dissolved radon gas. We found pervasive evidence of shallow groundwater sources at the upstream discharge faces along a wide valley section with deep bedrock, as primarily evidenced by pronounced diurnal discharge flux patterns. Discharge flux seasonal trends and bank storage transitions during large river flow events provided further indication of shallow, local sources. In contrast, downstream discharge faces associated with near surface cross cutting bedrock exhibited deep and regional source flowpath characteristics such as more stable discharge patterns and temperatures. However, many neighbouring points across discharge faces had similar discharge flux patterns that differed in chloride and radon concentrations, indicating the additional effects of localized flowpath heterogeneity overprinting on larger scale flowpath characteristics.

Connecticut↗
USGS2018

VS2DRTI: Simulating heat and reactive solute transport in variably saturated porous media

Variably saturated groundwater flow, heat transport, and solute transport are important processes in environmental phenomena, such as the natural evolution of water chemistry of aquifers and streams, the storage of radioactive waste in a geologic repository, the contamination of water resources from acid-rock drainage, and the geologic sequestration of carbon dioxide. Up to now, our ability to simulate these processes simultaneously with fully coupled reactive transport models has been limited to complex and often difficult-to-use models. To address the need for a simple and easy-to-use model, the VS2DRTI software package has been developed for simulating water flow, heat transport, and reactive solute transport through variably saturated porous media. The underlying numerical model, VS2DRT, was created by coupling the flow and transport capabilities of the VS2DT and VS2DH models with the equilibrium and kinetic reaction capabilities of PhreeqcRM. Flow capabilities include two-dimensional, constant-density, variably saturated flow; transport capabilities include both heat and multicomponent solute transport; and the reaction capabilities are a complete implementation of geochemical reactions of PHREEQC. The graphical user interface includes a preprocessor for building simulations and a postprocessor for visual display of simulation results. To demonstrate the simulation of multiple processes, the model is applied to a hypothetical example of injection of heated waste water to an aquifer with temperature-dependent cation exchange. VS2DRTI is freely available public domain software.

Groundwater↗
USGS2014

Otolith microchemistry of tropical diadromous fishes: spatial and migratory dynamics

Otolith microchemistry was applied to quantify migratory variation and the proportion of native Caribbean stream fishes that undergo full or partial marine migration. Strontium and barium water chemistry in four Puerto Rico, U.S.A., rivers was clearly related to a salinity gradient; however, variation in water barium, and thus fish otoliths, was also dependent on river basin. Strontium was the most accurate index of longitudinal migration in tropical diadromous fish otoliths. Among the four species examined, bigmouth sleeper Gobiomorus dormitor , mountain mullet Agonostomus monticola , sirajo goby Sicydium spp. and river goby Awaous banana , most individuals were fully amphidromous, but 9-12% were semi-amphidromous as recruits, having never experienced marine or estuarine conditions in early life stages and showing no evidence of marine elemental signatures in their otolith core. Populations of one species, G. dormitor , may have contained a small contingent of semi-amphidromous adults, migratory individuals that periodically occupied marine or estuarine habitats (4%); however, adult migratory elemental signatures may have been confounded with those related to diet and physiology. These findings indicate the plasticity of migratory strategies of tropical diadromous fishes, which may be more variable than simple categorization might suggest.

Journal of Fish Biology↗
USGS2016

Linking silicate weathering to riverine geochemistry—A case study from a mountainous tropical setting in west-central Panama

Chemical analyses from 71 watersheds across an ∼450 km transect in west-central Panama provide insight into controls on weathering and rates of chemical denudation and CO 2 consumption across an igneous arc terrain in the tropics. Stream and river compositions across this region of Panama are generally dilute, having a total dissolved solute value = 118 ± 91 mg/L, with bicarbonate and silica being the predominant dissolved species. Solute, stable isotope, and radiogenic isotope compositions are consistent with dissolution of igneous rocks present in Panama by meteoric precipitation, with geochemical signatures of rivers largely acquired in their upstream regions. Comparison of a headwater basin with its entire watershed observed considerably more runoff production from the high-elevation upstream portion of the catchment than in its much more spatially extensive downstream region. Rock alteration profiles document that weathering proceeds primarily by dissolution of feldspar and pyroxene, with base cations effectively leached in the following sequence: Na > Ca > Mg > K. Control on water chemistry by bedrock lithology is indicated through a linking of elevated ([Na + K]/[Ca + Mg]) ratios in waters to a high proportion of catchment area silicic bedrock and low ratios to mafic bedrock. Sr-isotope ratios are dominated by basement-derived Sr, with only very minor, if any, contribution from other sources. Cation weathering of Ca sil + Mg sil + Na + K spans about an order in magnitude, from 3 to 32 tons/km 2 /yr. Strong positive correlations of chemical denudation and CO 2 consumption are observed with precipitation, mean watershed elevation, extent of land surface forest cover, and physical erosion rate.

Chagras and Pacora watersheds↗
USGS2004

Age and source of water in springs associated with the Jacksonville Thrust Fault Complex, Calhoun County, Alabama

Water from wells and springs accounts for more than 90 percent of the public water supply in Calhoun County, Alabama. Springs associated with the Jacksonville Thrust Fault Complex are used for public water supply for the cities of Anniston and Jacksonville. The largest ground-water supply is Coldwater Spring, the primary source of water for Anniston, Alabama. The average discharge of Coldwater Spring is about 32 million gallons per day, and the variability of discharge is about 75 percent. Water-quality samples were collected from 6 springs and 15 wells in Calhoun County from November 2001 to January 2003. The pH of the ground water typically was greater than 6.0, and specific conductance was less than 300 microsiemens per centimeter. The water chemistry was dominated by calcium, carbonate, and bicarbonate ions. The hydrogen and oxygen isotopic composition of the water samples indicates the occurrence of a low-temperature, water-rock weathering reaction known as silicate hydrolysis. The residence time of the ground water, or ground-water age, was estimated by using analysis of chlorofluorocarbon, sulfur hexafluoride, and regression modeling. Estimated ground-water ages ranged from less than 10 to approximately 40 years, with a median age of about 18 years. The Spearman rho test was used to identify statistically significant covariance among selected physical properties and constituents in the ground water. The alkalinity, specific conductance, and dissolved solids increased as age increased; these correlations reflect common changes in ground-water quality that occur with increasing residence time and support the accuracy of the age estimates. The concentration of sodium and chloride increased as age increased; the correlation of these constituents is interpreted to indicate natural sources for chloride and sodium. The concentration of silica increased as the concentration of potassium increased; this correlation, in addition to the isotopic data, is evidence that silicate hydrolysis of clay minerals occurred. The geochemical modeling program NETPATH was used to investigate possible mixing scenarios that could yield the chemical composition of water collected from springs associated with the Jacksonville Thrust Fault Complex. The results of NETPATH modeling suggest that the primary source of water in Coldwater Spring is a deep aquifer, and only small amounts of rainwater from nearby sources are discharged from the spring. Starting with Piedmont Sports Spring and moving southwest along a conceptual ground-water flow path that parallels the Jacksonville Thrust Fault Complex, NETPATH simulated the observed water quality of each spring, in succession, by mixing rainwater and water from the spring just to the northeast of the spring being modeled. The percentage of rainwater and ground water needed to simulate the quality of water flowing from the springs ranged from 1 to 25 percent rainwater and 75 to 99 percent ground water.

Scientific Investigations Report↗
USGS2007

Factors Affecting Spatial and Temporal Variability in Nutrient and Pesticide Concentrations in the Surficial Aquifer on the Delmarva Peninsula

Water quality in the unconfined, unconsolidated surficial aquifer on the Delmarva Peninsula is influenced by the availability of soluble ions from natural and human sources, and by geochemical factors that affect the mobility and fate of these ions within the aquifer. Ground-water samples were collected from 60 wells completed in the surficial aquifer of the peninsula in 2001 and analyzed for major ions, nutrients, and selected pesticides and degradation products. Analytical results were compared to similar data from a subset of sampled wells in 1988, as well as to land use, soils, geology, depth, and other potential explanatory variables to demonstrate the effects of natural and human factors on water quality in the unconfined surficial aquifer. This study was conducted as part of the National Water-Quality Assessment Program of the U.S. Geological Survey, which is designed (in part) to describe the status and trends in ground-water quality and to provide an understanding of natural and human factors that affect ground-water chemistry in different parts of the United States. Results of this study may be useful for water-resources managers tasked with addressing water-quality issues of local and regional importance because the surficial aquifer on the Delmarva Peninsula is a major source of water for domestic and public supply and provides the majority of flow in local streams. Human impacts are apparent in ground-water quality throughout the surficial aquifer. The surficial aquifer on the Delmarva Peninsula is generally sandy and very permeable with well-oxygenated ground water. Dissolved constituents found throughout various depths of the unconfined aquifer are likely derived from the predominantly agricultural practices on the peninsula, although effects of road salt, mineral dissolution, and other natural and human influences are also apparent in some areas. Nitrate occurred at concentrations exceeding natural levels in many areas, and commonly exceeded 10 milligrams per liter (as nitrogen). In addition to land use in the aquifer recharge area, concentrations of nitrate in ground water are related to regional patterns in soil drainage that affect underlying aquifer redox conditions. Over the peninsula, nitrate concentrations are not related to recharge date of the water, but are positively correlated with depth in shallow wells screened beneath agricultural areas. Nitrate concentrations increased in oxic areas (dissolved oxygen greater than 1 milligram per liter) of the deeper part of the surficial aquifer used for domestic supply by an average of about 2 milligrams per liter between 1988 and 2001, although no changes were apparent in shallower parts of the aquifer over that same period. Water in the surficial aquifer generally flows from land-surface recharge to surface-water discharge areas in less than 30 years. As a result, the entire flow system in the surficial aquifer has likely been affected by human activities on and near the land surface over the past several decades. Pesticide compounds occurred widely at low levels throughout the surficial aquifer. The most commonly used herbicides (metolachlor, alachlor, and atrazine) were the most commonly detected. These pesticides primarily occurred in ground water in the form of degradation products. The widespread occurrence of these and other pesticide compounds reflects their abundant use as well as chemical properties and aquifer characteristics that allow their movement into ground water. Mixtures of pesticides are common. Most samples contained at least 3 different compounds; several samples contained as many as 11. Pesticide concentrations in the surficial aquifer are relatively high beneath recharge areas with well-drained soils in the shallow part of the aquifer and in oxic environments throughout the surficial aquifer. Concentrations are generally below existing drinking-water standards, although standards are not available for all of the pesticide compound

Scientific Investigations Report↗
USGS2010

Characterization of water quality and biological communities, Fish Creek, Teton County, Wyoming, 2007-08

Fish Creek, a tributary to the Snake River, is about 25 river kilometers long and is located in Teton County in western Wyoming near the town of Wilson. Public concern about nuisance growths of aquatic plants in Fish Creek have been increasing in recent years. To address this concern, the U.S. Geological Survey conducted a study in cooperation with the Teton Conservation District to characterize the water quality and biological communities in Fish Creek. Water-quality samples were collected for analyses of physical properties and water chemistry (nutrients, nitrate isotopes, and wastewater chemicals) between March 2007 and October 2008 from seven surface-water sites and three groundwater wells. During this same period, aquatic plant and macroinvertebrate samples were collected and habitat characteristics were measured at the surface-water sites. The main objectives of this study were to (1) evaluate nutrient concentrations (that influence biological indicators of eutrophication) and potential sources of nutrients by using stable isotope analysis and other indicator chemicals (such as caffeine and disinfectants) that could provide evidence of anthropogenic sources, such as wastewater or septic tank contamination in Fish Creek and adjacent groundwater, and (2) characterize the algal, macrophyte, and macroinvertebrate communities and habitat of Fish Creek. Nitrate was the dominant species of dissolved nitrogen present in all samples and was the only bioavailable species detected at concentrations greater than the laboratory reporting level in all surface-water samples. Average concentrations of dissolved nitrate in surface water were largest in samples collected from the two sites with seasonal flow near Teton Village and decreased downstream; the smallest concentration was at downstream site A-Wck. Concentrations of dissolved nitrate in groundwater were consistently greater than concentrations in corresponding surface-water sites during the same sampling event. Orthophosphate was the primary dissolved species of phosphorus present in all surface-water and groundwater samples. The average concentration of dissolved orthophosphate in surface water was largest in samples collected from near Teton Village; samples from all other sites had similar average concentrations. Concentrations of dissolved orthophosphate in groundwater also were typically greater than concentrations in corresponding surface-water sites during the same sampling event. The aquatic plant communities in Fish Creek typically were composed of a mixture of macrophytes, macroalgae, microalgae, and moss. The composition of the aquatic plant community in Fish Creek appeared to shift in the downstream direction in 2007. On average, the proportion of macrophytes ranged from about 1 percent at site A-R1U, the most upstream site, to 54 percent of the plant community at site A-R6D, the farthest downstream site sampled during 2007. The downstream increase in macrophytes was accompanied by a downstream decrease in microalgae. The average proportion of microalgae ranged from 80 percent at site A-R1U to 24 percent at site A-R6D. The proportion of the macroalgae Cladophora in the aquatic plant community was relatively high at sites A-Wck and A-R3D in both 2007 and 2008.

Scientific Investigations Report↗
USGS1976

Chemical quality of ground water in the Tehama-Colusa Canal service area, Sacramento Valley, California

The Tehama-Colusa Canal Service Area consists of about 450 square miles of irrigable land located on the west side of the Sacramento Valley, Calif. Upon the completion of the Tehama-Colusa Canal, it is expected that most of the service area will switch from passive forms of agriculture (dry farming and grazing) to intensive irrigated farming. Importation and application of surface water may affect the chemical quality of native ground water. This study documents the chemical quality of native ground water before large-scale importation and application of surface water provide the potential of altering the ground-water chemistry. Analyses of samples from 222 wells show that most of the area is underlain by ground water of a quality suitable for most agricultural and domestic uses. In the vicinities of College City-Arbuckle and the city of Williams, boron, chloride, sodium, and dissolved solids may be a threat to future agricultural activities where boron- or chloride-sensitive crops would be grown. The source of degraded ground water in the two areas is local intermittent streams that drain areas having numerous saline springs and seeps. (Woodard-USGS)

California↗
USGS1998

Estimated predevelopment discharge to streams from the High Plains Aquifer in northwestern Oklahoma, southwestern Kansas, and northwestern Texas

A study of the High Plains aquifer in Okla homa was initiated in 1996 to: (1) provide the information needed by the Oklahoma Water Resources Board to manage the quantity of water produced from the aquifer; and (2) provide base line water-chemistry data. The approach used to meet the first objective is to develop a digital ground-water flow model. The model will be cali brated, in part, by comparing simulated and esti mated predevelopment discharge from the aquifer to streams and cross-boundary flow. This report presents the estimated predevelopment discharge to streams from the High Plains aquifer. Streamflow data were the primary source of information used to estimate predevelopment dis charge from the High Plains aquifer. Data from 30 streamflow stations between the Arkansas and Canadian Rivers were considered in the analysis, and winter low-flow frequencies for 7-, 14-, and 30-day periods were determined for 25 stations. The 14-day low flow with a recurrence interval of 2 years was the primary value used to estimate pre development discharge from the aquifer. The streams that drain the eastern part of the High Plains aquifer in Kansas (generally east of 99.5 longitude) are estimated to have had large predevelopment discharge from the aquifer, and most of them received discharge from near their headwaters. For streams with more than one streamflow gage, the upper perennial reaches appeared to have gained more discharge from the aquifer than the lower reaches. The total predevel opment discharge from the aquifer in this area to several streams is estimated to have been about 312 cubic feet per second, not including discharge that probably went directly to the Arkansas River. The Cimarron River and its tributaries are estimated to have gained about 78 cubic feet per second, but nearly one-half that amount was lost in the lower reaches of the river. The cause of the loss in the lower reaches is unknown. The Beaver River and its tributaries are estimated to have gained a net of about 10 cubic feet per second above Wolf Creek with the upper reaches gaining more than the lower reaches. Wolf Creek is estimated to have gained 30 cubic feet per second over its total length.

Water-Resources Investigations Report↗
USGS2017

The response of soil and stream chemistry to decreases in acid deposition in the Catskill Mountains, New York, USA

The Catskill Mountains have been adversely impacted by decades of acid deposition, however, since the early 1990s, levels have decreased sharply as a result of decreases in emissions of sulfur dioxide and nitrogen oxides. This study examines trends in acid deposition, stream-water chemistry, and soil chemistry in the southeastern Catskill Mountains. We measured significant reductions in acid deposition and improvement in stream-water quality in 5 streams included in this study from 1992 to 2014. The largest, most significant trends were for sulfate (SO 4 2− ) concentrations (mean trend of −2.5 μeq L −1 yr −1 ); hydrogen ion (H + ) and inorganic monomeric aluminum (Al im ) also decreased significantly (mean trends of −0.3 μeq L −1 yr −1 for H + and −0.1 μeq L −1 yr −1 for Al im for the 3 most acidic sites). Acid neutralizing capacity (ANC) increased by a mean of 0.65 μeq L −1 yr −1 for all 5 sites, which was 4 fold less than the decrease in SO 4 2− concentrations. These upward trends in ANC were limited by coincident decreases in base cations (−1.3 μeq L −1 yr −1 for calcium + magnesium). No significant trends were detected in stream-water nitrate (NO 3 − ) concentrations despite significant decreasing trends in NO 3 − wet deposition. We measured no recovery in soil chemistry which we attributed to an initially low soil buffering capacity that has been further depleted by decades of acid deposition. Tightly coupled decreasing trends in stream-water silicon (Si) (−0.2 μeq L −1 yr −1 ) and base cations suggest a decrease in the soil mineral weathering rate. We hypothesize that a decrease in the ionic strength of soil water and shallow groundwater may be the principal driver of this apparent decrease in the weathering rate. A decreasing weathering rate would help to explain the slow recovery of stream pH and ANC as well as that of soil base cations.

New York↗
USGS2026

Streamflow, water quality, and energy development characteristics and water-quality trends for selected sites in the Green River and Muddy Creek drainage basins, southwestern Wyoming, water years 2006–16

Energy resource development in southwestern Wyoming has been rapidly expanding since the early 2000s to include innovative technologies for extracting oil and gas and enhancing renewable energy. In response to concerns about the potential negative effects of energy development on natural resources, the Wyoming Landscape Conservation Initiative was created to implement a long-term, science-based program of assessing, conserving, and enhancing fish and wildlife habitats while facilitating responsible energy development through local collaborations and partnerships. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, began monitoring streamflow and water quality as part of this initiative in 2006 at four U.S. Geological Survey streamgages within the Green River and Muddy Creek drainage basins to characterize the effects of energy development on streamflow and water quality in these areas. To quantify changes in water quality metrics, trend analyses for the 2006–16 water years were calculated and related to drainage basin characteristics including energy development (wells per square mile). Effects of energy development on water quality varied by watershed and the variability was driven primarily by the runoff efficiency and the geochemistry of the drainage basin. The New Fork River water chemistry was a calcium-bicarbonate type with low ionic strength and showed no statistically significant trends in water quality despite increased energy development. The Green River experienced moderate energy development, with significant upward trends in magnesium and alkalinity, indicating low sensitivity to development. Muddy Creek near Dad had minimal energy development and complex hydrogeochemical characteristics, showing mixed trends in water quality constituents. Muddy Creek near Baggs experienced moderate energy development, with significant upward trends in several water quality indicators indicating a response to the land disturbance associated with development. Overall, geochemistry and runoff efficiency influenced the vulnerability of water quality to energy development activities, highlighting the importance of drainage basin physical characteristics on vulnerability to development.

Scientific Investigations Report↗