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USGS2008

Water quality, hydrology, and simulated response to changes in phosphorus loading of Butternut Lake, Price and Ashland Counties, Wisconsin, with special emphasis on the effects of internal phosphorus loading in a polymictic lake

Butternut Lake is a 393-hectare, eutrophic to hypereutrophic lake in northcentral Wisconsin. After only minor improvements in water quality were observed following several actions taken to reduce the nutrient inputs to the lake, a detailed study was conducted from 2002 to 2007 by the U.S. Geological Survey to better understand how the lake functions. The goals of this study were to describe the water quality and hydrology of the lake, quantify external and internal sources of phosphorus, and determine the effects of past and future changes in phosphorus inputs on the water quality of the lake. Since the early 1970s, the water quality of Butternut Lake has changed little in response to nutrient reductions from the watershed. The largest changes were in near-surface total phosphorus concentrations: August concentrations decreased from about 0.09 milligrams per liter (mg/L) to about 0.05 mg/L, but average summer concentrations decreased only from about 0.055—0.060 mg/L to about 0.045 mg/L. Since the early 1970s, only small changes were observed in chlorophyll a concentrations and water clarity (Secchi depths). All major water and phosphorus sources, including the internal release of phosphorus from the sediments (internal loading), were measured directly, and minor sources were estimated to construct detailed water and phosphorus budgets for the lake during monitoring years (MY) 2003 and 2004. During these years, Butternut Creek, Spiller Creek, direct precipitation, small tributaries and near-lake drainage area, and ground water contributed about 62, 20, 8, 7, and 3 percent of the inflow, respectively. The average annual load of phosphorus to the lake was 2,540 kilograms (kg), of which 1,590 kg came from external sources (63 percent) and 945 kg came from the sediments in the lake (37 percent). Of the total external sources, Butternut Creek, Spiller Creek, small tributaries and near-lake drainage area, septic systems, precipitation, and ground water contributed about 63, 23, 9, 3, 1, and 1 percent, respectively. Because of the high internal phosphorus loading, the eutrophication models used in this study were unable to simulate the observed water-quality characteristics in the lake without incorporating this source of phosphorus. However, when internal loading of phosphorus was added to the BATHTUB model, it accurately simulated the average water-quality characteristics measured in MY 2003 and 2004. Model simulations demonstrated a relatively linear response between in-lake total phosphorus concentrations and external phosphorus loading; however, the changes in concentrations were smaller than the changes in external phosphorus loadings (about 25—40 percent of the change in phosphorus loading). Changes in chlorophyll a concentrations, the percentage of days with algal blooms, and Secchi depths were nonlinear and had a greater response to reductions in phosphorus loading than to increases in phosphorus loading. A 50-percent reduction in external phosphorus loading caused an 18-percent decrease in chlorophyll a concentrations, a 41-percent decrease in the percentage of days with algal blooms, and a 12-percent increase in Secchi depth. When the additional internal phosphorus loading was removed from model simulations, all of these constituents showed a much greater response to changes in external phosphorus loading. Because of Butternut Lake's morphometry, it is polymictic, which means it mixes frequently and does not develop stable thermal stratification throughout the summer. This characteristic makes it more vulnerable than dimictic lakes, which mix in spring and fall and develop stable thermal stratification during summer, to the high internal phosphorus loading that has resulted from historically high, nonnatural, external phosphorus loading. In polymictic lakes, the phosphorus released from the sediments is mixed into the upper part of the lake throughout summer. Once Butternut Lake became hypereutrophic (very productive), it became very difficult to alter its trophic state through reductions in external phosphorus loading because the high internal loading does not respond quickly to reductions in external nutrient loading. For Butternut Lake to become significantly less productive (change to a borderline mesotrophic/eutrophic state) a combined approach to reduce or eliminate internal phosphorus loading and reduce the external phosphorus loading by about 50 percent is needed.

Wisconsin↗

USGS2018

Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

Groundwater quality in the approximately 7,820-square-kilometer (km 2 ) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km 2 ), Pajaro Valley (360 km 2 ), Salinas Valley (2,000 km 2 ), and Highlands (5,250 km 2 ). This study had two primary components: the status assessment and the understanding assessment . The first primary component of this study—the status assessment —assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment —identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system. Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low. Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids. Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA ( N -nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit. Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions. Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems. Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater. The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater. The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater. Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater. The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however. Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture. Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

California↗

USGS2011

Status and understanding of groundwater quality in the San Diego Drainages Hydrogeologic Province, 2004: California GAMA Priority Basin Project

Groundwater quality in the approximately 3,900-square-mile (mi 2 ) San Diego Drainages Hydrogeologic Province (hereinafter San Diego) study unit was investigated from May through July 2004 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in southwestern California in the counties of San Diego, Riverside, and Orange. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA San Diego study was designed to provide a statistically robust assessment of untreated-groundwater quality within the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 58 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as the primary aquifers) were defined by the depth interval of the wells listed in the California Department of Public Health (CDPH) database for the San Diego study unit. The San Diego study unit consisted of four study areas: Temecula Valley (140 mi 2 ), Warner Valley (34 mi 2 ), Alluvial Basins (166 mi 2 ), and Hard Rock (850 mi 2 ). The quality of groundwater in shallow or deep water-bearing zones may differ from that in the primary aquifers. For example, shallow groundwater may be more vulnerable to surficial contamination than groundwater in deep water-bearing zones. This study had two components: the status assessment and the understanding assessment. The first component of this study-the status assessment of the current quality of the groundwater resource-was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the San Diego study unit, not the treated drinking water delivered to consumers by water purveyors. The second component of this study-the understanding assessment-identified the natural and human factors that affect groundwater quality by evaluating land use, well construction, and geochemical conditions of the aquifer. Results from these evaluations were used to help explain the occurrence and distribution of selected constituents in the study unit. Relative-concentrations (sample concentration divided by benchmark concentration) were used as the primary metric for relating concentrations of constituents in groundwater samples to water-quality benchmarks for those constituents that have Federal and (or) California benchmarks. For organic and special-interest constituents, relative-concentrations were classified as high (> 1.0), moderate (> 0.1 and ≤1.0), and low (≤0.1). For inorganic constituents, relative concentrations were classified as high (> 1.0), moderate (> 0.5 and ≤1.0), and low (≤0.5). Grid-based and spatially weighted approaches were then used to evaluate the proportion of the primary aquifers (aquifer-scale proportions) with high, moderate, and low relative-concentrations for individual compounds and classes of constituents. One or more of the inorganic constituents with health-based benchmarks were high (relative to those benchmarks) in 17.6 percent of the primary aquifers in the Temecula Valley, Warner Valley, and Alluvial Basins study areas (hereinafter also collectively referred to as the Alluvial Fill study areas because they are composed of alluvial fill aquifers), and in 25.0 percent of the Hard Rock study area. Inorganic constituents with health-based benchmarks that were frequently detected at high relative-concentrations included vanadium (V), arsenic (As), and boron (B). Vanadium and As concentrations were not significantly correlated to either urban or agricultural land use indicating natural sources as the primary contributors of these constituents to groundwater. The positive correlation of B concentration to urban land-use was significant which indicates that anthropogenic activities are a contributing source of B to groundwater. The correlation of V, As and B concentrations to pH was positive, indicating that in alkaline groundwater these constituents are being desorbed from, or being inhibited from adsorbing to, particle surfaces. Inorganic constituents with aesthetic benchmarks that were detected at high relative-concentrations include manganese (Mn), iron (Fe), and total dissolved solids (TDS). In the Alluvial Fill study areas, Mn and TDS were detected at high relative-concentrations in 13.7 percent of the primary aquifers, and Fe in 6.9 percent. In the Hard Rock study area, Mn was detected at high relative-concentrations in 33.3 percent of the primary aquifers, and TDS in 16.7 percent; Fe was not detected at high relative-concentrations. Total dissolved solids concentrations were significantly correlated to agricultural land use suggesting that agricultural practices are a contributing source of TDS to groundwater. Manganese and Fe concentrations were highest in groundwater with low dissolved oxygen and pH indicating that the reductive dissolution of oxyhydroxides may be an important mechanism for the mobilization of Mn and Fe in groundwater. TDS concentrations were highest in shallow wells and in modern (< 50 yrs) groundwater which indicates anthropogenic activities as a source of TDS concentrations in groundwater. The relative-concentrations of organic constituents with health-based benchmarks were high in 3.0 percent of the primary aquifers in the Alluvial Fill study areas. A single detection in the Alluvial Basins study area of the discontinued gasoline oxygenate methyl tert-butyl ether (MTBE) was the only organic constituent detected at a high relative-concentration; high relative-concentrations of these constituents were not detected in the Hard Rock study area. Twelve of 88 VOCs and 14 of 123 pesticides and pesticide degradates analyzed in grid wells were detected. Chloroform was the only VOC detected in more than 10 percent of the grid wells. The herbicides simazine, atrazine, and prometon were each detected in greater than 10 percent of the grid wells. Perchlorate was detected in 22 percent of the grid wells sampled. The understanding assessment showed a significant correlation of trihalomethanes (THMs) and solvents to urban land-use, indicating that detections of these constituents are more likely to occur in groundwater underlying urbanized areas of the study unit. MTBE concentrations were negatively correlated to the distance from the nearest leaking underground fuel tank, indicating that point sources are the most significant contributing factor for MTBE concentrations to groundwater in the study unit. The positive correlation of THM and herbicide concentrations to modern groundwater was significant, as was the negative correlation of herbicide concentrations to pH and anoxic groundwater. The negative correlation of herbicides to pH and anoxic groundwater was likely due to the fact that these constituents were detected more frequently in shallow wells where groundwater conditions tend to be oxic with relatively low pH.

California↗

USGS2024

Status and understanding of groundwater quality in the Mojave Basin Domestic-Supply Aquifer study unit, 2018—California GAMA Priority Basin Project

Groundwater quality in the western part of the Mojave Desert in San Bernardino County, California, was investigated in 2018 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The Mojave Basin Domestic-Supply Aquifer study unit (MOBS) region was divided into two study areas—floodplain and regional—to assess differences between the two major aquifers used for drinking water supply in the area. This assessment characterized the quality of ambient groundwater and not the quality of treated drinking water. The study included three components: (1) a status assessment, which characterized the quality of groundwater resources used for domestic drinking-water supply in the floodplain and regional study areas; (2) a brief understanding assessment, which evaluated factors that could potentially affect the quality of groundwater used by domestic wells in the region; and (3) a comparative assessment between the groundwater resources used by domestic wells and public-supply wells in the two study areas. The domestic-well assessment was based on data collected by the U.S. Geological Survey from 48 domestic wells in January–May 2018. The public-supply assessment was based on data for samples from 322 public-supply wells in 2008–18, either collected by the U.S. Geological Survey or compiled from the California State Water Resources Control Boards Division of Drinking Water publicly available database. Concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks typically used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. Relative concentrations, defined as the measured concentration divided by the benchmark concentration, were classified as high (greater than 1.0), moderate (greater than 0.5 for inorganic constituents or 0.1 for organic and special-interest constituents, and not high), or low (concentrations lower than moderate). The floodplain and regional study areas were divided into 15 and 35 grid cells, respectively, and grid-based methods were used to compute the areal proportions of the two study areas with high, moderate, or low relative concentrations of individual constituents and classes of constituents. For the domestic-supply assessment, one or more inorganic constituents with health-based benchmarks were detected at high relative concentrations in 58 percent of the regional study area and 13 percent of the floodplain study area. The inorganic constituents with health-based benchmarks detected at high relative concentrations in the regional study area were arsenic, chromium and hexavalent chromium, fluoride, adjusted gross alpha particle activity, uranium, molybdenum, strontium, and nitrate; only arsenic was detected at high relative concentrations in the floodplain study area. One or more inorganic constituents with secondary maximum contaminant level benchmarks were detected at high concentrations in 15 and 6.7 percent of the regional and floodplain study areas, respectively. The constituents detected at high relative concentrations in the regional study area were total dissolved solids, chloride, sulfate, and iron; only total dissolved solids and sulfate were detected at high relative concentrations in the floodplain study area. Organic constituents were not detected at moderate or high relative concentrations in either the regional or floodplain study areas. Volatile organic compounds were detected at low relative concentrations in 21 and 27 percent of the regional and floodplain study areas, respectively, and pesticides were detected at low relative concentrations in 9.1 and 20 percent of the regional and floodplain study areas, respectively. The only individual organic constituent detected in more than 10 percent of either study area was the trihalomethane trichloromethane. Total coliform bacteria were detected in 15 and 27 percent of the grid wells in the regional and floodplain study areas, respectively. The greater prevalence of high relative concentrations of many inorganic constituents in the regional study area compared to the floodplain area likely indicates the greater diversity of geologic material at depth in aquifer material and generally finer-grained alluvium compared to the floodplain study area combined with generally older groundwater that has had more contact time with aquifer materials. In general, trace element concentrations (1) increased with increasing groundwater age, (2) increased with distance from recharge sources in the mountains, and (3) increased with closer proximity to some types of geological units. In general, groundwater from domestic wells in the floodplain study area is young, with most samples containing a component of modern groundwater based on tritium and unadjusted carbon-14 activities, whereas groundwater from domestic wells in the regional study area generally is old, with most samples having unadjusted carbon-14 ages of 5,000–40,000 years. Public-supply wells in MOBS generally were deeper than domestic wells and presumably are in contact with older, more weathered alluvium that may have more mobile trace elements, such as arsenic or uranium. However, only 26 percent of the public-supply regional study area had high relative concentrations of inorganic constituents, compared to 58 percent for the domestic regional study area. The percentages of the public-supply and domestic floodplain study areas with high relative concentrations of inorganic constituents were 11 and 13 percent, respectively. The ages of groundwater used by public-supply and domestic wells in each study area were similar, which was not expected given the greater depth of the public-supply wells. Three potential factors may contribute to these results: (1) greater spatial footprint of domestic well network, which may result in domestic wells pumping groundwater from fractured bedrock or mineralized areas not used by public-supply wells; (2) greater pumping rates in public-supply wells, resulting in more water being withdrawn from coarse-grained, heterogeneous alluvium than finer-grained layers, which may have higher concentrations of (or more mobile) inorganic constituents; and (3) a greater degree of well management with public-supply wells, which may include pausing use of or decommissioning wells if treating or blending water is not feasible to lower constituent concentrations.

California↗

USGS2010

Hydrology, water quality, and response to changes in phosphorus loading of Minocqua and Kawaguesaga Lakes, Oneida County, Wisconsin, with special emphasis on effects of urbanization

Minocqua and Kawaguesaga Lakes are 1,318- and 690-acre interconnected lakes in the popular recreation area of north-central Wisconsin. The lakes are the lower end of a complex chain of lakes in Oneida and Vilas Counties, Wis. There is concern that increased stormwater runoff from rapidly growing residential/commercial developments and impervious surfaces from the urbanized areas of the Town of Minocqua and Woodruff, as well as increased effluent from septic systems around their heavily developed shoreline has increased nutrient loading to the lakes. Maintaining the quality of the lakes to sustain the tourist-based economy of the towns and the area was a concern raised by the Minocqua/Kawaguesaga Lakes Protection Association. Following several small studies, a detailed study during 2006 and 2007 was done by the U.S. Geological Survey, in cooperation with the Minocqua/Kawaguesaga Lakes Protection Association through the Town of Minocqua to describe the hydrology and water quality of the lakes, quantify the sources of phosphorus including those associated with urban development and to better understand the present and future effects of phosphorus loading on the water quality of the lakes. The water quality of Minocqua and Kawaguesaga Lakes appears to have improved since 1963, when a new sewage-treatment plant was constructed and its discharge was bypassed around the lakes, resulting in a decrease in phosphorus loading to the lakes. Since the mid-1980s, the water quality of the lakes has changed little in response to fluctuations in phosphorus loading from the watershed. From 1986 to 2009, summer average concentrations of near-surface total phosphorus in the main East Basin of Minocqua Lake fluctuated from 0.009 mg/L to 0.027 mg/L but generally remained less than 0.022 mg/L, indicating that the lake is mesotrophic. Phosphorus concentrations from 1988 through 1996, however, were lower than the long-term average, possibly the result of an extended drought in the area. Water‑quality data for Kawaguesaga Lake had a similar pattern to that of Minocqua Lake. Summer average chlorophyll a concentrations and Secchi depths also indicate that the lakes generally are mesotrophic but occasionally borderline eutrophic, with no long-term trends. During the study, major water and phosphorus sources were measured directly, and minor sources were estimated to construct detailed water and phosphorus budgets for the lakes for monitoring years (MY) 2006 and 2007. During these years, the Minocqua Thoroughfare contributed about 38 percent of the total inflow to the lakes, and Tomahawk Thoroughfare contributed 34 percent; near-lake inflow, precipitation, and groundwater contributed about 1, 16, and 11 percent of the total inflow, respectively. Water leaves the lakes primarily through the Tomahawk River outlet (83 percent) or by evaporation (14 percent), with minor outflow to groundwater. Total input of phosphorus to both lakes was about 3,440 pounds in MY 2006 and 2,200 pounds in MY 2007. The largest sources of phosphorus entering the lakes were the Minocqua and Tomahawk Thoroughfares, which delivered about 39 and 26 percent of the total, respectively. The near-lake drainage area, containing most of the urban and residential developments, disproportionately accounted for about 12 percent of the total phosphorus input but only about 1 percent of the total water input (estimated with WinSLAMM). The next largest contributions were from septic systems and precipitation, each contributing about 10 percent, whereas groundwater delivered about 4 percent of the total phosphorus input. Empirical lake water-quality models within BATHTUB were used to simulate the response of Minocqua and Kawaguesaga Lakes to 19 phosphorus-loading scenarios. These scenarios included the current base years (2006–07) for which lake water quality and loading were known, nine general increases or decreases in phosphorus loading from controllable external sources (inputs from the tributaries and nearshore areas around the lakes and input from septic systems), and nine scenarios corresponding to future changes in phosphorus loading from residential and urban development, referred to as “2030 buildout,” and removal of septic system inputs. The 2030 buildout scenario with existing stormwater controls resulted in a degradation in water quality: phosphorus concentrations increased by about 0.001 mg/L, chlorophyll a concentrations increased by 0.2–0.8 μg/L, and Secchi depths decreased slightly. The largest degradation in water quality was estimated to occur in Kawaguesaga Lake. If 2030 buildout occurred with implementation of best management practices to achieve a 50-percent reduction in loading from near-lake drainages, it is possible that water quality would change very little from existing conditions. Numerous noncontributing areas exist within the watershed that help minimize surface runoff and nutrient loading to the lakes; however, if future development included extending or connecting drainage from these areas into the lakes, loading to the lakes could greatly increase and cause a degradation in the water quality of the lakes. Simulations of removal of phosphorus loading from septic systems around Minocqua Lake improved the water quality of the lakes: in simulations for that scenario, phosphorus concentrations decreased by about 0.001 mg/L, chlorophyll a concentrations decreased by 0.5–0.7 μg/L, and Secchi depths increased by 0.3–0.7 ft. If all controllable external phosphorus loading could be reduced by 50 percent, the lakes would become oligotrophic with respect to phosphorus concentration but would still remain mesotrophic with respect to chlorophyll a concentration and Secchi depth. Improvements in the water quality of the lakes are likely only with a combination of management actions that decrease inputs from the developed near-lake drainage areas and from septic systems.

Wisconsin↗

USGS2010

Hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River, Nebraska— With special emphasis on the Niobrara National Scenic River

The Niobrara River is an ecologically and economically important resource in Nebraska. The Nebraska Department of Natural Resources’ recent designation of the hydraulically connected surface- and groundwater resources of the Niobrara River Basin as “fully appropriated” has emphasized the importance of understanding linkages between the physical and ecological dynamics of the Niobrara River so it can be sustainably managed. In cooperation with the Nebraska Game and Parks Commission, the U.S. Geological Survey investigated the hydrogeomorphic and hydraulic attributes of the Niobrara River in northern Nebraska. This report presents the results of an analysis of hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River and its valley for the approximately 330-mile reach from Dunlap Diversion Dam to its confluence with the Missouri River. Two spatial scales were used to examine and quantify the hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River: a basin scale and a reach scale. At the basin scale, digital spatial data and hydrologic data were analyzed to (1) test for differences between 36 previously determined longitudinal hydrogeomorphic segments; (2) quantitatively describe the hydrogeomorphic characteristics of the river and its valley; and (3) evaluate differences in hydraulic microhabitat over a range of flow regimes among three fluvial geomorphic provinces. The statistical analysis of hydrogeomorphic segments resulted in reclassification rates of 3 to 28 percent of the segments for the four descriptive geomorphic elements. The reassignment of classes by discriminant analysis resulted in a reduction from 36 to 25 total hydrogeomorphic segments because several adjoining segments shared the same ultimate class assignments. Virtually all of the segment mergers were in the Canyons and Restricted Bottoms (CRB) fluvial geomorphic province. The most frequent classes among hydrogeomorphic segments, and the dominant classes per unit length of river, are: a width-restricted valley confinement condition, sinuous-planview pattern, irregular channel width, and an alternate bar configuration. The Niobrara River in the study area flows through a diversity of fluvial geomorphic settings in its traverse across northern Nebraska. In the Meandering Bottoms (MB) fluvial geomorphic province, river discharge magnitudes are low, and the valley exerts little control on the channel-planview pattern. Within the CRB province, the river flows over a diversity of geologic formations, and the valley and river narrow and expand in approximate synchronicity. In the Braided Bottoms (BB) fluvial geomorphic province, the river primarily flows over Cretaceous Pierre Shale, the valley and channel are persistently wide, and the channel slope is generally uniform. The existence of vegetated islands and consequent multithread channel environments, indicated by a higher braided index, mostly coincided with reaches having gentler slopes and less unit stream power. Longitudinal hydrology curves indicate that the flow of the Niobrara River likely is dominated by groundwater as far downstream as Norden. Unit stream power values in the study area vary between 0 and almost 2 pounds per foot per second. Within the MB province, unit stream power steadily increases as the Niobrara gains discharge from groundwater inflow, and the channel slope steepens. The combination of steep slopes, a constrained channel width, and persistent flow within the CRB province results in unit stream power values that are between three and five times greater than those in less confined segments with comparable or greater discharges. With the exception of hydrogeomorphic segment 3, which is affected by Spencer Dam, unit stream power values in the BB province are generally uniform. Channel sinuosity values in the study area varied generally between 1 and 2.5, but with locally higher values measured in the MB province and at the entrenched bedrock meanders of hydrogeomorphic segment 18 in the CRB province. The differences in channel morphology and hydraulic geometries between fluvial geomorphic provinces are evident in the types, relative abundance, and response of hydraulic microhabitats to changing discharges. The four gaging stations chosen for hydraulic microhabitat analysis are distributed among three different fluvial geomorphic provinces. In the MB province, the smaller channel and lower discharges resulted in the dominance of shallow and intermediate-depth hydraulic environments with the vast majority of hydraulic microhabitat restricted to shallow categories even during upper-decile discharges. In the CRB province, intermediate depth hydraulic conditions, particularly intermediate-swift, dominate over all ranges of discharge. Hydraulic microhabitat conditions were most diverse in the BB province, with most hydraulic microhabitat categories present over the entire range of discharges analyzed. The calculated differences in hydraulic microhabitat distributions, abundance, and adjustments between streamflow-gaging stations were the result of differences in physical structure of the channel and subsequent channel hydraulic geometry. At the reach scale, field measurements made in water years 2008 and 2009 in four study reaches within the Scenic Reach were used to (1) characterize the elevation and geomorphic processes associated with fluvial landforms, (2) build hydraulic geometry relations, (3) examine flow hydraulics over a range of discharges, and (4) examine the types and responses of hydraulic microhabitats to a range of flow magnitudes. Four landform groups were identified and named in order of increasing elevation: low flood plains, intermediate flood plains, low terraces, and high terraces. The terraces were poorly characterized because the surveys did not extend across the full width of the alluvial valley bottom. The two lowest fluvial landforms are likely active in the modern hydroclimatic regime. Sediment samples obtained in the study reaches indicate that the primary bed material in the active channel ranged in size from coarse silt to coarse sand. Grain-size distributions from samples also indicate that the bed of the Niobrara River among the study reaches coarsens and has increasing grainsize variability in the downstream direction. Values of at-a-station hydraulic geometry exponents indicate that the Niobrara River in the study reaches adjusts its geometry to changing discharges primarily through increases in flow depth and velocity. Relations at one cross section indicated that, at least locally, changes in width were also an important channel adjustment mechanism. Hydraulic behavior over the range of flows measured was not consistent among all study reaches, but two general modes of hydraulic behavior were observed in the reaches with substantial coverage of the bed by fine sediment. At the Sunny Brook and Muleshoe study reaches, average boundary-shear stress remained approximately constant, and hydraulic resistance decreased, for discharges below 900 cubic feet per second (ft 3 /s). Above 900 ft 3 /s, average boundary shear stress and hydraulic resistance both increased. The Rock Barn study reach did not exhibit the same two-mode hydraulic behavior observed at the Sunny Brook and Muleshoe reaches. The coincident increase in boundary shear stress above 900 ft 3 /s observed at the Sunny Brook and Muleshoe study reaches represents a potential hydraulic threshold above which bedload transport rates were likely to increase markedly. No consistent bed-adjustment pattern (scour or fill) was identified in the study reaches over the range of flows or over the measurement season. Analysis of hydraulic microhabitats over the range of discharges measured at the study reaches indicates that some percentage of most habitat niche categories was available for at least one discharge condition, but the majority of hydraulic habitat available was within the intermediate-swift and deepswift habitat niche categories. Deep-swift conditions dominated nearly all study reaches under all measured discharge conditions. Slight differences in habitat distributions were observed between the study reaches with substantial coverage of the bed by fine sediment—Sunny Brook, Muleshoe, and Rock Barn—and the bedrock-dominated reach, Crooked Creek. Although the four study reaches occupy three different hydrogeomorphic segments, the types, relative abundance, and response of hydraulic microhabitat niche distributions to changing discharge conditions generally were similar among all reaches.

Nebraska↗

USGS2022

Response of Green Lake, Wisconsin, to changes in phosphorus loading, with special emphasis on near-surface total phosphorus concentrations and metalimnetic dissolved oxygen minima

Green Lake is the deepest natural inland lake in Wisconsin, with a maximum depth of about 72 meters. In the early 1900s, the lake was believed to have very good water quality (low nutrient concentrations and good water clarity) with low dissolved oxygen (DO) concentrations occurring in only the deepest part of the lake. Because of increased phosphorus (P) inputs from anthropogenic activities in its watershed, total phosphorus (TP) concentrations in the lake have increased; these changes have led to increased algal production and low DO concentrations not only in the deepest areas but also in the middle of the water column (metalimnion). The U.S. Geological Survey has routinely monitored the lake since 2004 and its tributaries since 1988. Results from this monitoring led the Wisconsin Department of Natural Resources (WDNR) to list the lake as impaired because of low DO concentrations in the metalimnion, and they identified elevated TP concentrations as the cause of impairment. As part of this study by the U.S. Geological Survey, in cooperation with the Green Lake Sanitary District, the lake and its tributaries were comprehensively sampled in 2017–18 to augment ongoing monitoring that would further describe the low DO concentrations in the lake (especially in the metalimnion). Empirical and process-driven water-quality models were then used to determine the causes of the low DO concentrations and the magnitudes of P-load reductions needed to improve the water quality of the lake enough to meet multiple water-quality goals, including the WDNR’s criteria for TP and DO. Data from previous studies showed that DO concentrations in the metalimnion decreased slightly as summer progressed in the early 1900s but, since the late 1970s, have typically dropped below 5 milligrams per liter (mg/L), which is the WDNR criterion for impairment. During 2014–18 (the baseline period for this study), the near-surface geometric mean TP concentration during June–September in the east side of the lake was 0.020 mg/L and in the west side was 0.016 mg/L (both were above the 0.015-mg/L WDNR criterion for the lake), and the metalimnetic DO minimum concentrations (MOMs) measured in August ranged from 1.0 to 4.7 mg/L. The degradation in water quality was assumed to have been caused by excessive P inputs to the lake; therefore, the TP inputs to the lake were estimated. The mean annual external P load during 2014–18 was estimated to be 8,980 kilograms per year (kg/yr), of which monitored and unmonitored tributary inputs contributed 84 percent, atmospheric inputs contributed 8 percent, waterfowl contributed 7 percent, and septic systems contributed 1 percent. During fall turnover, internal sediment recycling contributed an additional 7,040 kilograms that increased TP concentrations in shallow areas of the lake by about 0.020 mg/L. The elevated TP concentrations then persisted until the following spring. On an annual basis, however, there was a net deposition of P to the bottom sediments. Empirical models were used to describe how the near-surface water quality of Green Lake would be expected to respond to changes in external P loading. Predictions from the models showed a relatively linear response between P loading and TP and chlorophyll- a (Chl- a ) concentrations in the lake, with the changes in TP and Chl- a concentrations being less on a percentage basis (50–60 percent for TP and 30–70 percent for Chl- a ) than the changes in P loading. Mean summer water clarity, quantified by Secchi disk depths, had a greater response to decreases in P loading than to increases in P loading. Based on these relations, external P loading to the lake would need to be decreased from 8,980 kg/yr to about 5,460 kg/yr for the geometric mean June–September TP concentration in the east side of the lake, with higher TP concentrations than in the west side, to reach the WDNR criterion of 0.015 mg/L. This reduction of 3,520 kg/yr is equivalent to a 46-percent reduction in the potentially controllable external P sources (all external sources except for precipitation, atmospheric deposition, and waterfowl) from those measured during water years 2014–18. The total external P loading would need to decrease to 7,680 kg/yr (a 17-percent reduction in potentially controllable external P sources) for near-surface June–September TP concentrations in the west side of the lake to reach 0.015 mg/L. Total external P loading would need to decrease to 3,870–5,320 kg/yr for the lake to be classified as oligotrophic, with a near-surface June–September TP concentration of 0.012 mg/L. Results from the hydrodynamic water-quality model GLM–AED (General Lake Model coupled to the Aquatic Ecodynamics modeling library) indicated that MOMs are driven by external P loading and internal sediment recycling that lead to high TP concentrations during spring and early summer, which in turn lead to high phytoplankton production, high metabolism and respiration, and ultimately DO consumption in the upper, warmer areas of the metalimnion. GLM–AED results indicated that settling of organic material during summer might be slowed by the colder, denser, and more viscous water in the metalimnion and thus increase DO consumption. Based on empirical evidence from a comparison of MOMs with various meteorological, hydrologic, water quality, and in-lake physical factors, MOMs were lower during summers, when metalimnetic water temperatures were warmer, near-surface Chl- a and TP concentrations were higher, and Secchi depths were lower. GLM–AED results indicated that the external P load would need to be reduced to about 4,060 kg/yr, a 57-percent reduction from that measured in 2014–18, to eliminate the occurrence of MOMs less than 5 mg/L during more than 75 percent of the years (the target provided by the WDNR). Large reductions in external P loading are expected to have an immediate effect on the near-surface TP concentrations and metalimnetic DO concentrations in Green Lake; however, it may take several years for the full effects of the external-load reduction to be observed because internal sediment recycling is an important source of P for the following spring.

Wisconsin↗

USGS2012

Water quality, hydrology, and simulated response to changes in phosphorus loading of Mercer Lake, Iron County, Wisconsin, with special emphasis on the effects of wastewater discharges

Mercer Lake is a relatively shallow drainage lake in north-central Wisconsin. The area near the lake has gone through many changes over the past century, including urbanization and industrial development. To try to improve the water quality of the lake, actions have been taken, such as removal of the lumber mill and diversion of all effluent from the sewage treatment plant away from the lake; however, it is uncertain how these actions have affected water quality. Mercer Lake area residents and authorities would like to continue to try to improve the water quality of the lake; however, they would like to place their efforts in the actions that will have the most beneficial effects. To provide a better understanding of the factors affecting the water quality of Mercer Lake, a detailed study of the lake and its watershed was conducted by the U.S. Geological Survey in collaboration with the Mercer Lake Association. The purposes of the study were to describe the water quality of the lake and the composition of its sediments; quantify the sources of water and phosphorus loading to the lake, including sources associated with wastewater discharges; and evaluate the effects of past and future changes in phosphorus inputs on the water quality of the lake using eutrophication models (models that simulate changes in phosphorus and algae concentrations and water clarity in the lake). Based on analyses of sediment cores and monitoring data collected from the lake, the water quality of Mercer Lake appears to have degraded as a result of the activities in its watershed over the past 100 years. The water quality appears to have improved, however, since a sewage treatment plant was constructed in 1965 and its effluent was routed away from the lake in 1995. Since 2000, when a more consistent monitoring program began, the water quality of the lake appears to have changed very little. During the two monitoring years (MY) 2008-09, the average summer near-surface concentration of total phosphorus was 0.023 mg/L, indicating the lake is borderline mesotrophic-eutrophic, or has moderate to high concentrations of phosphorus, whereas the average summer chlorophyll a concentration was 3.3 mg/L and water clarity, as measured with a Secchi depth, was 10.4 ft, both indicating mesotrophic conditions or that the lake has a moderate amount of algae and water clarity. Although actions have been taken to eliminate the wastewater discharges, the bottom sediment still has slightly elevated concentrations of several pollutants from wastewater discharges, lumber operations, and roadway drainage, and a few naturally occurring metals (such as iron). None of the concentrations, however, were high enough above the defined thresholds to be of concern. Based on nitrogen to phosphorus ratios, the productivity (algal growth) in Mercer Lake should typically be limited by phosphorus; therefore, understanding the phosphorus input to the lake is important when management efforts to improve or prevent degradation of the lake water quality are considered. Total inputs of phosphorus to Mercer Lake were directly estimated for MY 2008-09 at about 340 lb/yr and for a recent year with more typical hydrology at about 475 lb/yr. During these years, the largest sources of phosphorus were from Little Turtle Inlet, which contributed about 45 percent, and the drainage area near the lake containing the adjacent urban and residential developments, which contributed about 24 percent. Prior to 1965, when there was no sewage treatment plant and septic systems and other untreated systems contributed nutrients to the watershed, phosphorus loadings were estimated to be about 71 percent higher than during around 2009. In 1965, a sewage treatment plant was built, but its effluent was released in the downstream end of the lake. Depending on various assumptions on how much effluent was retained in the lake, phosphorus inputs from wastewater may have ranged from 0 to 342 lb. Future highway and stormwater improvements have been identified in the Mercer Infrastructure Improvement Project, and if they are done with the proposed best management practices, then phosphorus inputs to the lake may decrease by about 40 lb. Eutrophication models [Canfield and Bachman model (1981) and Carlson Trophic State Index equations (1977)] were used to predict how the water quality of Mercer Lake should respond to changes in phosphorus loading. A relatively linear response was found between phosphorus loading and phosphorus and chlorophyll a concentrations in the lake, with changes in phosphorus concentrations being slightly less (about 80 percent) and changes in chlorophyll a concentrations being slightly more (about 120 percent) than the changes in phosphorus loadings to the lake. Water clarity, indicated by Secchi depths, responded more to decreases in phosphorus loading than to increases in loading. Results from the eutrophication models indicated that the lake should have been negatively affected by the wastewater discharges. Prior to 1965, when there was no sewage treatment plant effluent and inputs from the septic systems and other untreated systems were thought to be high, the lake should have been eutrophic; near the surface, average phosphorus concentrations were almost 0.035 mg/L, chlorophyll a concentrations were about 7 μg/L, and Secchi depths were about 6 ft, which agreed with the shallower Secchi depths during this time estimated from the sediment-core analysis. The models indicated that between 1965 and 1995, when the lake retained some of the effluent from the new sewage treatment plant, water quality should have been between the conditions estimated prior to 1965 and what was expected during typical hydrologic conditions around MY 2008-09. The models also indicated that if the future Mercer Infrastructure Improvement Project is conducted with the best management practices as proposed, the water quality in the lake could improve slightly from that measured during 2006-10. Because of the small amount of phosphorus that is presently input into Mercer Lake any additional phosphorus added to the lake could degrade water quality; therefore, management actions can usefully focus on minimizing future phosphorus inputs. Phosphorus released from the sediments of a degraded lake often delays its response to decreases in external phosphorus loading, especially in shallow, frequently mixed systems. Mercer Lake, however, remains stratified throughout most of the summer, and phosphorus released from the sediments represents only about 6 percent, or a small fraction, of the total phosphorus load to the lake. Therefore, the phosphorus trapped in the sediments should minimally affect the long-term water quality of the lake and should not delay the response in its productivity to future changes in nutrient loading from its watershed.

Wisconsin↗

USGS2013

Hydrology and water quality of Shell Lake, Washburn County, Wisconsin, with special emphasis on the effects of diversion and changes in water level on the water quality of a shallow terminal lake

Shell Lake is a relatively shallow terminal lake (tributaries but no outlets) in northwestern Wisconsin that has experienced approximately 10 feet (ft) of water-level fluctuation over more than 70 years of record and extensive flooding of nearshore areas starting in the early 2000s. The City of Shell Lake (City) received a permit from the Wisconsin Department of Natural Resources in 2002 to divert water from the lake to a nearby river in order to lower water levels and reduce flooding. Previous studies suggested that water-level fluctuations were driven by long-term cycles in precipitation, evaporation, and runoff, although questions about the lake’s connection with the groundwater system remained. The permit required that the City evaluate assumptions about lake/groundwater interactions made in previous studies and evaluate the effects of the water diversion on water levels in Shell Lake and other nearby lakes. Therefore, a cooperative study between the City and U.S. Geological Survey (USGS) was initiated to improve the understanding of the hydrogeology of the area and evaluate potential effects of the diversion on water levels in Shell Lake, the surrounding groundwater system, and nearby lakes. Concerns over deteriorating water quality in the lake, possibly associated with changes in water level, prompted an additional cooperative project between the City and the USGS to evaluate efeffects of changes in nutrient loading associated with changes in water levels on the water quality of Shell Lake. Numerical models were used to evaluate how the hydrology and water quality responded to diversion of water from the lake and historical changes in the watershed. The groundwater-flow model MODFLOW was used to simulate groundwater movement in the area around Shell Lake, including groundwater/surface-water interactions. Simulated results from the MODFLOW model indicate that groundwater flows generally northward in the area around Shell Lake, with flow locally converging toward the lake. Total groundwater inflow to Shell Lake is small (approximately 5 percent of the water budget) compared with water entering the lake from precipitation (83 percent) and surface-water runoff (13 percent). The MODFLOW model also was used to simulate average annual hydrologic conditions from 1949 to 2009, including effects of the removal of 3 billion gallons of water during 2003–5. The maximum decline in simulated average annual water levels for Shell Lake due to the diversion alone was 3.3 ft at the end of the diversion process in 2005. Model simulations also indicate that although water level continued to decline through 2009 in response to local weather patterns (local drought), the effects of the diversion decreased after the diversion ceased; that is, after 4 years of recovery (2006–9), drawdown attributable to the diversion alone decreased by about 0.6 ft because of increased groundwater inflow and decreased lake-water outflow to groundwater caused by the artificially lower lake level. A delayed response in drawdown of less than 0.5 ft was transmitted through the groundwater-flow system to upgradient lakes. This relatively small effect on upgradient lakes is attributed in part to extensive layers of shallow clay that limit lake/groundwater interaction in the area. Data collected in the lake indicated that Shell Lake is polymictic (characterized by frequent deep mixing) and that its productivity is limited by the amount of phosphorus in the lake. The lake was typically classified as oligotrophic-mesotrophic in June, mesotrophic in July, and mesotrophic-eutrophic in August. In polymictic lakes like Shell Lake, phosphorus released from the sediments is not trapped near the bottom of the lake but is intermittently released to the shallow water, resulting in deteriorating water quality as summer progresses. Because the productivity of Shell Lake is limited by phosphorus, the sources of phosphorus to the lake were quantified, and the response in water quality to changes in phosphorus inputs were evaluated by means of eutrophication models. During 2009, the total input of phosphorus to Shell Lake was 1,730 pounds (lb), of which 1,320 lb came from external sources (76 percent) and 414 lb came from internal loading from sediments in the lake (24 percent). The largest external source was from surface-water runoff, which delivered about 52 percent of the total phosphorus load compared with about 13 percent of the water input. The second largest source was from precipitation (wetfall and dryfall), which delivered 19 percent of the load compared to about 83 percent of the water input. Contributions from septic systems and groundwater accounted for about 3 and 2 percent, respectively. Increased runoff raises water levels in the lake but does not necessarily increase phosphorus loading because phosphorus concentrations in the tributaries decline during increased flow, possibly because of shorter retention times in upstream wetlands. Phosphorus loading to the lake in 2009 represented what occurred after a series of dry years; therefore, this information was combined with data from 2011, a wet year, to estimate phosphorus loading during a range of hydrologic conditions by estimating loading from each component of the phosphorus budget for each year from 1949 to 2011. Comparisons of historical water-quality records with historical water levels and applications of a hydrodynamic model (Dynamic Lake Model, DLM) and empirical eutrophication models were used to understand how changes in water level and the coinciding changes in phosphorus loading affect the water quality of Shell Lake. DLM simulations indicate that large changes in water level (approximately 10 ft) affect the persistence of stratification in the lake. During periods with low water levels, the lake is a well-mixed, polymictic system, with water quality degrading slightly as summer progresses. During periods with high water levels, the lake is more stratified, and phosphorus from internal loading is trapped in the hypolimnion and released later in summer, which results in more extreme seasonality in water quality and better clarity in early summer. Results of eutrophication model simulations using a range in external phosphorus inputs illustrate how water quality in Shell Lake (phosphorus and chlorophyll a concentrations and Secchi depths) responds to changes in external phosphorus loading. Results indicate that a 50-percent reduction in external loading from that measured in 2009 would be required to change phosphorus concentrations from 0.018 milligram per liter (mg/L) (measured in 2009) to 0.012 mg/L (estimated for the mid-1800s from analysis of diatoms in sediment cores). Such reductions in phosphorus loading cannot be accomplished by targeting septic systems or internal loading alone because septic systems contribute only about 3 percent of the phosphorus input to the lake, and internal loading from the sediments of Shell Lake contributes only about 25 percent of phosphorus input. Complete elimination of phosphorus from septic systems and internal loading would decrease the phosphorus concentrations in the lake by 0.003–0.004 mg/L. Therefore, reducing phosphorus concentration in the lake more than by 0.004 mg/L requires decreasing phosphorus loading from surface-water contributions, primarily runoff to the lake. Reconstructed changes in water quality from 1860 to 2010, based on changes in the diatom communities archived in the sediments and eutrophication model simulations, suggest that anthropogenic changes in the watershed (sawmill construction in 1881; the establishment of the village of Shell Lake; and land-use changes in the 1920s, including increased agriculture) had a much larger effect on water quality than the natural changes associated with fluctuations in water level. Although the effects of natural changes in water level on water quality appear to be small, changes in water level do have a modest effect on water quality, primarily manifested as small improvements during higher water levels. Fluctuations in water level, however, have a larger effect on the seasonality of water-quality patterns, with better water quality, especially increased Secchi depths, in early summer during years with high water levels.

Wisconsin↗

USGS2008

Occurrence of organic compounds and trace elements in the upper Passaic and Elizabeth Rivers and their tributaries in New Jersey, July 2003 to February 2004: Phase II of the New Jersey toxics reduction workplan for New York-New Jersey Harbor

Samples of surface water and suspended sediment were collected from the Passaic and Elizabeth Rivers and their tributaries in New Jersey from July 2003 to February 2004 to determine the concentrations of selected chlorinated organic and inorganic constituents. This sampling and analysis was conducted as Phase II of the New York-New Jersey Harbor Estuary Workplan—Contaminant Assessment and Reduction Program (CARP), which is overseen by the New Jersey Department of Environmental Protection. Phase II of the New Jersey Workplan was conducted to define upstream tributary and point sources of contaminants in those rivers sampled during Phase I work, with special emphasis on the Passaic and Elizabeth Rivers. Samples were collected from three groups of tributaries: (1) the Second, Third, and Saddle Rivers; (2) the Pompton and upper Passaic Rivers; and (3) the West Branch and main stem of the Elizabeth River. The Second, Third, and Saddle Rivers were sampled near their confluence with the tidal Passaic River, but at locations not affected by tidal flooding. The Pompton and upper Passaic Rivers were sampled immediately upstream from their confluence at Two Bridges, N.J. The West Branch and the main stem of the Elizabeth River were sampled just upstream from their confluence at Hillside, N.J. All tributaries were sampled during low-flow discharge conditions using the protocols and analytical methods for organic constituents used in low-flow sampling in Phase I. Grab samples of streamflow also were collected at each site and were analyzed for trace elements (mercury, methylmercury, cadmium, and lead) and for suspended sediment, particulate organic carbon, and dissolved organic carbon. The measured concentrations and available historical suspended-sediment and stream-discharge data (where available) were used to estimate average annual loads of suspended sediment and organic compounds in these rivers. Total suspended-sediment loads for 1975–2000 were estimated using rating curves developed from historical U.S. Geological Survey (USGS) suspended-sediment and discharge data, where available. Average annual loads of suspended sediment, in millions of kilograms per year (Mkg/yr), were estimated to be 0.190 for the Second River, 0.23 for the Third River, 1.00 for the Saddle River, 1.76 for the Pompton River, and 7.40 for the upper Passaic River. On the basis of the available discharge records, the upper Passaic River was estimated to provide approximately 60 percent of the water and 80 percent of the total suspended-sediment load at the Passaic River head-of-tide, whereas the Pompton River provided roughly 20 percent of the total suspended-sediment load estimated at the head-of-tide. The combined suspended-sediment loads of the upper Passaic and Pompton Rivers (9.2 Mkg/yr), however, represent only 40 percent of the average annual suspended-sediment load estimated for the head-of-tide (23 Mkg/yr) at Little Falls, N.J. The difference between the combined suspended-sediment loads of the tributaries and the estimated load at Little Falls represents either sediment trapped upriver from the dam at Little Falls, additional inputs of suspended sediment downstream from the tributary confluence, or uncertainty in the suspended-sediment and discharge data that were used. The concentrations of total suspended sediment-bound polychlorinated biphenyls (PCBs) in the tributaries to the Passaic River were 194 ng/g (nanograms per gram) in the Second River, 575 ng/g in the Third River, 2,320 ng/g in the Saddle River, 200 ng/g in the Pompton River, and 87 ng/g in the upper Passic River. The dissolved PCB concentrations in the tributaries were 563 pg/L (picograms per liter) in the Second River, 2,510 pg/L in the Third River, 2,270 pg/L in the Saddle River, 887 pg/L in the Pompton River, and 1,000 pg/L in the upper Passaic River. Combined with the sediment loads and discharge, these concentrations resulted in annual loads of suspended sediment-bound PCBs, in grams per year (g/yr), of 37 in the Second River; 132 in the Third River; 2,320 in the Saddle River; 352 in the Pompton River; and 644 in the upper Passaic River. Annual loads of dissolved PCBs, in grams per year, are 9.2 in the Second River; 47 in the Third River; 212 in the Saddle River; 349 in the Pompton River; and 549 in the upper Passaic River. Concentrations of total suspended sediment-bound polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-p-difurans (PCDD/PCDFs) were 6,000 pg/g (picograms per gram) in the Second River; 11,300 pg/g in the Third River; 37,700 pg/g in the Saddle River; 7,140 pg/g in the Pompton River; and 9,640 pg/g in the upper Passaic River. Total toxic equivalence quotients (TEQs), which included PCDD/PCDFs and coplanar PCBs, ranged from 2.7 pg/g in the Second River to 132 pg/g (as 2,3,7,8-TCDD) in the Saddle River. Average annual loads of PCDD/PCDFs were from 1.1 g/yr in the Second River to 71 g/yr in the upper Passaic River. The load of TEQs (as 2,3,7,8-TCDD) from PCDD/PCDFs and coplanar PCBs in the tributaries were 0.5 mg/yr (milligrams per year) in the Second River, 5.8 mg/yr in the Third River, 130 mg/yr in the Saddle River, 46 mg/yr in the Pompton River, and 100 mg/yr in the upper Passaic River. These loads represent an addition to the TEQ load estimated to cross the head-of-tide of 0.1 percent by the Second River, 0.7 percent by the Third River, and 15 percent by the Saddle River. Loads of sediment-bound trace elements mercury, methylmercury, lead, and cadmium were calculated using concentrations obtained from grab samples, which were assumed to represent average annual concentrations in these rivers. Loads of sediment-bound mercury were estimated to be 1,200 g/yr in the Second River; 130 g/yr in the Third River; 4,200 g/yr in the Saddle River; 3,400 g/yr in the Pompton River; and 6,500 g/yr in the upper Passaic River. Loads of sediment-bound lead were estimated to be 56 kg/yr (kilograms per year) in the Second River; 89 kg/yr in the Third River; 1,140 kg/yr in the Saddle River; 310 kg/yr in the Pompton River; and 1,040 kg/yr in the upper Passaic River. Loads of sediment-bound cadmium were estimated to be 1 kg/yr in the Second River; 0.59 kg/yr in the Third River; 60 kg/yr in the Saddle River; 16 kg/yr in the Pompton River; and 11 kg/yr in the upper Passaic River. These loads indicate the importance of the sediment-bound contributions of organic compounds and trace elements to the upper Passaic and Saddle Rivers. Concentrations of suspended sediment-bound PCBs in the main stem and the West Branch of the Elizabeth River were 806 ng/g and 3,100 ng/g, respectively, representing loads of 40 g/yr and 1,150 g/yr, respectively. These loads were estimated using assumed discharge conditions. Concentrations of suspended sediment-bound PCDD/PCDFs were 7,270 pg/g and 9,980 pg/g in the main stem and West Branch, respectively, representing average annual loads of 0.36 g/yr and 3.7 g/yr, respectively. Total TEQ loads (sum of PCDD/PCDFs and PCBs) were 2.1 mg/yr (as 2,3,7,8-TCDD) in the main stem and 34 mg/yr in the West Branch, respectively. These load estimates, however, were directly related to the assumed annual discharge for the two branches. Long-term measurement of stream discharge and suspended-sediment concentrations would be needed to verify these loads. On the basis of the concentrations measured in this work, it appears that the West Branch is the principal source of PCBs, PCDD/PCDFs, total TEQs, and metals to the main stem of the Elizabeth River. Additional sources of these constituents may exist between the confluence and the head-of-tide.

New Jersey, New York↗

USGS2010

Pesticides in groundwater in the Anacostia River and Rock Creek watersheds in Washington, D.C., 2005 and 2008

The U.S. Geological Survey (USGS), in cooperation with the District Department of the Environment, conducted a groundwater-quality investigation to (a) determine the presence, concentrations, and distribution of selected pesticides in groundwater, and (b) assess the presence of pesticides in groundwater in relation to selected landscape, hydrogeologic, and groundwater-quality characteristics in the shallow groundwater underlying the Anacostia River and Rock Creek watersheds in Washington, D.C. With one exception, well depths were 100 feet or less below land surface. The USGS obtained or compiled ancillary data and information on land use (2001), subsurface sediments, and groundwater samples from 17 wells in the lower Anacostia River watershed from September through December 2005, and from 14 wells in the lower Anacostia River and lower Rock Creek watersheds from August through September 2008. Twenty-seven pesticide compounds, reflecting at least 19 different types of pesticides, were detected in the groundwater samples obtained in 2005 and 2008. No fungicides were detected. In relation to the pesticides detected, degradate compounds were as or more likely to be detected than applied (parent) compounds. The detected pesticides chiefly reflected herbicides commonly used in urban settings for non-specific weed control or insecticides used for nonspecific haustellate insects (insects with specialized mouthparts for sucking liquid) or termite-specific control. Detected pesticides included a combination of pesticides currently (2008) in use, banned or under highly restricted use, and some that had replaced the banned or restricted-use pesticides. The presence of banned and restricted-use pesticides illustrates their continued persistence and resistance to complete degradation in the environment. The presence of the replacement pesticides indicates the susceptibility of the surficial aquifer to contamination irrespective of the changes in the pesticides used. A preliminary review of the data collected in 2005 and 2008 indicated that differences in the surficial geology, land use (as a surrogate for pesticide use), and above-average precipitation for most of 2004 through 2008, as well as differences in the number and performance of USGS laboratory methods used, could have led to more pesticides detected in groundwater samples collected in 2008 than in groundwater samples collected in 2005. Thus, although data from both years of collection were used for interpretive analysis, emphasis was placed on the analysis of the data obtained in 2008. The presence of pesticides in shallow groundwater (less than approximately 100 ft (feet), or 30 m (meters), below land surface) indicated at least the upper surficial aquifer in Washington, D.C. was susceptible to contamination. One or more herbicides or insecticides were detected in groundwater samples collected from 50 percent of the shallow wells sampled in 2005, and from 62 percent of the shallow wells sampled in 2008. Differences among types of pesticides in shallow groundwater were apparent. The most frequently detected class of herbicides was the s-triazine compounds—atrazine, simazine, or prometon, or the atrazine-degradate compounds—2-chloro-4-ethylamino-6-amino-s-triazine (desethylatrazine or CIAT) and 2-chloro-4-isopropylamino-6-amino-s-triazine (hydroxyatrazine or OIET). The next most frequently detected classes of herbicides were the chloroacetanilides, including metolachlor and acetochlor, and the ureic herbicides, including diuron (and degradate, 3,4-dichloroaniline), fluometuron, metsulfuron methyl, sulfameturon, bromacil, and tebuthiuron. Insecticides also were detected, but less frequently than herbicides, with one or more insecticides present in groundwater samples from 38 percent of shallow wells sampled in 2008. Detected insecticides included parent or degradate compounds commonly used for either nonspecific or haustellate (sucking) insects, including chlorpyrifos and dichlorodiphenyldichloroethane (p,p’-DDD; a degradate of dichlorodiphenyltrichloroethane, DDT), and for termite control, including dieldrin, chlordane, heptachlor epoxide, (a degradate of heptachlor), fipronil, and the sulfone and sulfide degradates of fipronil. The concentrations of individual pesticides in shallow groundwater in both years were low. Maximum concentrations were no greater than a few tenths of a microgram per liter (μg/L); typical concentrations often were less than 0.1 μg/L. Multiple pesticides, however, commonly were present in groundwater. For example, in 2008, approximately 88 percent (7 of 8) of the wells that yielded a sample with at least one detectable pesticide contained five or more pesticides. The highest number of detections occurred in a groundwater sample from well WE Ca 32, which is located in a highly developed urban area; this sample contained 15 different pesticide residues. In relation to human and aquatic health, no pesticide concentration in either 2005 or 2008 exceeded Federal drinking-water standards. Groundwater samples from a few sites, however, contained levels of chiefly banned or restricted-use pesticides that exceeded other human-health and (or) aquatic-health guidelines. For example, concentrations of dieldrin in 2008 groundwater samples from three wells—WE Ca 32 (0.028 μg/L), WE Ba 11 (0.016 μg/L), and WW Ac 8 (0.014 μg/L)—fell within the range of concern for 2004 Federally approved non-regulatory USGS Health-Based Assessment benchmarks (0.002 to 0.2 μg/L), and exceeded earlier (1999) Federal criteria for drinking water (0.000052 μg/L). Other individual compounds whose concentrations exceeded 1999 Federal guidelines for samples from one or more of these three sites, or another site, included p,p’-DDD, dichlorodiphenyldichloroethylene (p,p’-DDE; another degradate of DDT), chlordane, and heptachlor epoxide. Pesticide concentrations in groundwater also were compared to three aquatic-health guidelines for freshwater (United States, Great Lakes, or Canada). One or more of these guidelines were exceeded in groundwater samples obtained in 2005 or 2008 for one or more of the compounds chlordane, dieldrin, heptachlor epoxide, p,p’-DDE, p,p’-DDD, and chlorpyrifos. The spatial distribution of pesticides in the shallow groundwater appeared to be related, in part, to land use, a surrogate for pesticide use. Although most of the wells sampled in this study are in parklands or other relatively open and accessible space, multiple pesticides most often were detected in 2008 groundwater samples collected from wells where a considerable percentage (in excess of 60 percent) of the land within a 500-m radius is developed space (residential, commercial, or other urban infrastructure). Insecticides were detected in wells surrounded by at least 50 percent, and most commonly by more than 80 percent, development. Well WE Ca 32, the site associated with the highest number of pesticide residues in groundwater (8 herbicides and 7 insecticides), is in a small residential park, where 99 percent of the surrounding land is well-maintained residential and commercial development. The vertical distribution of detected pesticides in shallow groundwater appeared to be related, in part, to depth below land surface, surficial-bedrock type, and differences in the chemistry of shallow groundwater. Pesticides were detected at relatively shallow depths in wells that may not have fully penetrated the shallow aquifer. For wells in which at least one pesticide was detected, the median depth below land surface to the top of the well screen was 5.8 m, and the maximum depth was 8.5 m. Among the types of surficial materials in which wells were completed—alluvium, terrace deposits, or Potomac Formation sub- or outcrops in the Coastal Plain Province, and saprolite or fractured bedrock (Laurel and Sykesville Formations) underlying saprolite in the Piedmont Province—no pesticides were detected in groundwater associated with wells completed in the alluvium or fractured bedrock. Detections occurred in some but not all wells completed in the other surficial materials. Overall, the pattern in occurrence appeared related to the local permeability of these sediments and groundwater chemistry. Groundwater with multiple pesticide detections tended to occur in permeable sediments (absent any appreciable overlying clay, silt, or clay-silt layers), in conjunction with other common urban contaminants (elevated chloride in excess of tens to hundreds of milligrams per liter (mg/L), and oxic, rather than reduced, groundwater as evidenced by elevated (in excess of 5 mg/L) concentrations of nitrate). The results of this investigation were compared to results from two other similar and recent studies on pesticide occurrence in the shallow aquifer. These included a study in the nearby Maryland and Delaware Coastal Plain Physiographic Province and one in the Maryland and Virginia Piedmont Physiographic Province. Results from these studies were similar to the current study in relation to (a) the types, frequencies, concentrations, and mixtures of pesticides detected; (b) compounds that exceeded human-and aquatic-health criteria; and (c) the occurrence and distribution of pesticides within the surficial aquifer in relation to depths, sediment types, and groundwater chemistries.

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