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At least 451 records · Page 25Linked to original sources
USGS1993

Accessory minerals and subduction zone metasomatism: a geochemical comparison of two mélanges (Washington and California, U.S.A.)

The ability of a subducted slab or subducted sediment to contribute many incompatible trace elements to arc source regions may depend on the stabilities of accessory minerals within these rocks, which can only be studied indirectly. In contrast, the role of accessory minerals in lower- T and - P metasomatic processes within paleo-subduction zones can be studied directly in subduction-zone metamorphic terranes. The Gee Point-Iron Mountain locality of the Shuksan Metamorphic Suite, North Cascades, Washington State, is a high- T mélange of metamafic blocks in a matrix of meta-ultramafic rocks. This mélange is similar in geologic setting and petrology to the upper part of an unnamed amphibolite unit of the Catalina Schist, Santa Catalina Island, southern California. Both are interpreted as shear zones between mantle and slab rocks that formed during the early stages of subduction. Some garnet amphibolite blocks from the Gee Point-Iron Mountain locality display trace-element enrichments similar to those in counterparts from the Catalina Schist. Some Catalina blocks are highly enriched in Th, rare-earth elements (REE), the high-field-strength elements Ti, Nb, Ta, Zr and Hf (HFSE), U and Sr compared to mid-ocean ridge basalt (MORB), and to other garnet amphibolite blocks in the same unit. Textural and geochemical data indicate that accessory minerals of metamorphic origin control the enrichment of Th, REE and HFSE in blocks from both areas. The Mg-rich rinds around blocks and the meta-ultramafic matrix from both mélanges are highly enriched in a large number of trace elements compared to harzburgites, dunites and serpentinites. Evidence for recrystallization or formation of accessory minerals in the former rocks suggests that these minerals control some of the trace-element enrichments. Data from the Gee Point and Catalina mélanges suggest that the accessory minerals titanite, rutile, apatite, zircon and REE-rich epidote play a significant role in the enrichment of trace elements in both mafic and ultramafic rocks during subduction-related fluid-rock interaction. Mobilization of incompatible elements, and deposition of such elements in the accessory minerals of mafic and ultramafic rocks may be fairly common in fluid-rich metamorphic environments in subduction zones.

Chemical Geology↗
USGS1994

East Mariana Basin tholeiites: Cretaceous intraplate basalts or rift basalts related to the Ontong Java plume?

Studies of seafloor magnetic anomaly patterns suggest the presence of Jurassic oceanic crust in a large area in the western Pacific that includes the East Mariana, Nauru and Pigafetta Basins. Sampling of the igneous crust in this area by the Deep Sea Drilling Program (DSDP) and the Ocean Drilling Program (ODP) allows direct evaluation of the age and petrogenesis of this crust. ODP Leg 129 drilled a 51 m sequence of basalt pillows and massive flows in the central East Mariana Basin. 40 Ar 39 Ar "> 40Ar39Ar ages determined in this study for two Leg 129 basalts average 114.6 ± 3.2 Ma. This age is in agreement with the Albian-late Aptian paleontologic age of the overlying sediments, but is distinctively younger than the Jurassic age predicted by magnetic anomaly patterns in the basin. Compositionally, the East Mariana Basin basalts are uniformly low-K tholeiites that are depleted in highly incompatible elements compared to moderately incompatible ones, which is typical of mid-ocean ridge basalts (MORB) erupted near hotspots. The Sr, Nd and Pb isotopic compositions of the tholeiites ( 87 Sr 86 Sr init = 0.70360–0.70374 "> 87Sr86Srinit= 0.70360–0.70374 ; 143 Nd 144 Nd init = 0.512769–0.512790 "> 143Nd144Ndinit= 0.512769–0.512790 ; 206 Pb 204 Pb meas = 18.355–18.386 "> 206Pb204Pbmeas= 18.355–18.386 ) also overlap with some Indian Ocean Ridge MORB, although they are distinct from the isotopic compositions of Jurassic basalts drilled in the Pigafetta Basin, the oldest Pacific MORB. The isotopic compositions of the East Mariana Basin tholeiites are also similar to those of intraplate basalts, and in particular, to the isotopic signature of basalts from the nearby Ontong Java and Manihiki Plateaus. The East Mariana Basin tholeiites also share many petrologic and isotopic characteristics with the oceanic basement drilled in the Nauru Basin at DSDP Site 462. In addition, the new 110.8 ± 1.0 Ma 40 Ar 39 Ar "> 40Ar39Ar age for two flows from the bottom of Site 462 in the Nauru Basin is indistinguishable from the age of the East Mariana Basin flows. Thus, while magnetic anomaly patterns predict that the igneous basement in the Nauru and East Mariana Basins is Jurassic in age, the geochemical and chronological results discussed here suggest that the basement formed during a Cretaceous rifting event within the Jurassic crust. This magmatic and tectonic event was created by the widespread volcanism responsible for the genesis of the large oceanic plateaus of the western Pacific.

Earth and Planetary Science Letters↗
USGS1955

Composition and origin of basaltic magma of the Hawaiian Islands

Silica-saturated basaltic magma is the source of the voluminous lava flows, erupted frequently and rapidly in the primitive shield-building stage of activity, that form the bulk of each Hawaiian volcano. This magma may be available in batches that differ slightly in free silica content from batch to batch both at the same and at different volcanoes; differentiation by fractionation of olivine does not occur within this primitive magma. Silica-deficient basaltic magma, enriched in alkali, is the source of commonly porphyritic lava flows erupted less frequently and in relatively negligible volume during a declining and decadent stage of activity at some Hawaiian volcanoes. Differentiation by fractionation of olivine, plagioclase and augite is evident among these lavas, but does not account for the silica deficiency or the alkali enrichment. Most of the data of Hawaiian volcanism and petrology can be explained by a hypothesis that batches of magma are melted from crystalline paridotite by a recurrent process (distortion of the equatorial bulge by forced and free nutational stresses) that accomplishes the melting only of the plagioclase and pyroxene component but not the excess olivine and more refractory components within a zone of fixed and limited depth. Eruption exhausts the supply of meltable magma under a given locality and, in the absence of more violent melting processes, leaves a stratum of crystalline refractory components.

Hawaii↗
USGS1967

Borate mineral assemblages in the system Na2O-CaO-MgO-B2O3-H2O

The significant known hydrated borate mineral assemblages (principally of the western United States) in the system Na 2 O-CaO-MgO-B 2 O 3- H 2 O are expressible in three ternary composition diagrams. Phase rule interpretation of the diagrams is consistent with observation, if the activity of H 2 O is generally considered to be determined by the geologic environment. The absence of conflicting tie-lines on a diagram indicates that the several mineral assemblages of the diagram were formed under relatively narrow ranges of temperature and pressure. The known structural as well as empirical formulas for the minerals are listed, and the more recent (since 1960) crystal structure findings are discussed briefly. Schematic Gibbs free energy-composition diagrams based on known solubility-temperature relations in the systems Na 2 B 4 O 7 -H 2 O and Na 2 B 4 O 7 -NaCl-H 2 O, are highly useful in the interpretation and prediction of the stability relations in these systems; in particular these diagrams indicate clearly that tincalconite, although geologically important, is everywhere a metastable phase. Crystal-chemical considerations indicate that the same thermodynamic and kinetic behavior observed in the Na 2 B 4 O 7 -H 2 O system will hold in the Ca 2 B 6 O 11 -H 2 O system. This conclusion is confirmed by the petrologic evidence. The chemical relations among the mineral assemblages of a ternary diagram are expressed by a schematic “activity-activity” diagram. These activity-activity diagrams permit the tracing-out of the paragenetic sequences as a function of changing cation and H 2 O activities.

Geochimica et Cosmochimica Acta↗
USGS1978

Silicate liquid immiscibility in magmas and in the system K2O-FeO-AI2O3-SiO2: An example of serendipity

The concept of silicate liquid immiscibility was invoked early in the history of petrology to explain certain pairs of compositionally divergent rocks, but. as a result of papers by Greig ( Am. J. Sci. 13 , 1–44, 133–154) and Bowen ( The Evolution of the Igneous Rocks ), it fell into disfavor for many years. The discovery of immiscibility in geologically reasonable temperature ranges and compositions in experimental work on the system K 2 O-FeO-Al 2 O 3 -SiO 2 , and of evidence for immiscibility in a variety of lunar and terrestrial rocks, has reinstated the process. Phase equilibria in the high-silica corner of the tetrahedron representing the system K 2 O- FeO-Al 2 O 3 -SiO 2 are presented, in the form of constant FeO sections through the tetrahedron, at 10% increments. Those sections, showing the tentative relationships of the primary phase volumes, are based on 5631 quenching runs on 519 compositions, made in metallic iron containers in pure nitrogen. Thirteen crystalline compounds are involved, of which at least six show two or more crystal modifica-tions. Two separate phase volumes, in each of which two immiscible liquids, one iron-rich and the other iron-poor, are present at the liquidus. One of these volumes is entirely within the quaternary system, astride the 1:1 K 2 O:Al 2 O 3 plane. No quaternary compounds as such have been found, but evidence does point toward at least partial quaternary solid solution, with rapidly lowering liquidus temperatures, from K 2 O·Al 2 O 3 · 2SiO 2 (‘potash nepheline’, kalsilite. kaliophilite) to the isostructural compound K 2 O·FeO·3SiO 2 , and from K 2 O·Al 2 O 3 ·4SiO 2 (leucite) to the isostructural compound K 2 O·FeO·5SiO 2 , Both of these series apparently involve substitution, in tetrahedral coordination. of a ferrous iron and a silicon ion for two aluminum ions. Some of the ‘impurities’ found in analyses of the natural phases may reflect these substitutions. As a result of the geometry of the immiscibility volume located entirely within the quaternary system, compositions near it show a number of phase changes and large amounts of crystallization with small temperature changes, generally in the range 1100–1150 C. Similar low-temperature, high-alkali immiscibility was discovered in a few exploratory runs in the equivalent systems with Rb or Cs substituting for K. But not in those with Li or Na. A review of the compositions and general behavior of systems involving immiscibility, both stable and metastable, and of the evidence for natural immiscibility. indicates that it may be a much more common feature than generally thought. Several examples of natural immiscibility are detailed; most yield a felsic. alkali-aluminosilicate melt and a mafic melt. from a wide variety of generally basaltic parental magmas, both under- and over saturated. Unfortunately, the best line of evidence for immiscibility in terrestrial rocks, a sharply defined meniscus between two compositionally disparate glasses, is by its very nature self-destructing, since it is effectively eliminated by either crystallization or gravitative separation and coalescence into separate magmas. Verification of operation of the exosolutionor ‘splitting’ process on a large scale will probably require careful study of isotopic and trace element partitioning in both laboratory and field.

Geochimica et Cosmochimica Acta↗
USGS1982

Origin and evolution of the Nakhla meteorite inferred from the Sm-Nd and U-Pb systematics and REE, Ba, Sr, Rb and K abundances

Analyses of Sm-Nd and U-Th-Pb systematics, REE, Ba, Sr, Rb and K concentrations were carried out for whole rock and mineral separates from the Nakhla meteorite. The 1.26 ±.07 b . y . Sm-Nd age obtained in this work is in good agreement with those previously obtained by the Rb-Sr and Ar-Ar methods. The high initial ϵ Nd value of +16 suggests that Nakhla was derived from a light REE-depleted, old planetary mantle source. U-Th-Pb data, after correction for pre-analytical terrestrial Pb contamination assuming an age of 1.26 b.y., suggest that the age of the Nakhla source is ⩽4.33 b.y. The agreement in the age determined by three independent radiometric methods and the high initial ϵ Nd value strongly suggest that the 1.3 b.y. age dates one thorough igneous event in the parent body which not only reset these isotopic systems but also established the chemical and petrologic characteristics observed for the Nakhla meteorite. Using a three-stage Sm-Nd evolution model in combination with LIL element data and estimated partition coefficients, we have tested partial melting and fractional crystallization models to estimate LIL element abundances in a possible Nakhla source. Our model calculations suggest that partial melting of the light REE-depleted source followed by extensive fractional crystallization (⩾50%) of the partial melt could account for the REE abundances in the Nakhla constituent minerals. The estimated source is depleted in the light REE, Ba, Rb and K and therefore may resemble the MORB source in the earth's upper mantle or the upper 60–300 km of the moon. The significantly younger age of Nakhla than the youngest lunar rock; the young differentiation age inferred from the U-Th-Pb data, and the estimated LIL element abundances (including those of K, U and Th) in the source suggest that the Nakhla meteorite may have been derived from a relatively large, well-differentiated planetary body such as Mars.

Geochimica et Cosmochimica Acta↗
USGS1983

T-XCO2 stability relations and phase equilibria of a calcic carbonate scapolite

At a total pressure of 5 kb, calcic, Cl-free scapolite (Me 83 ) is stable relative to plagioclase-bearing assemblages at T ≧ 625°C "> T ≧ 625°C , X CO 2 ≧ 0.12 "> X CO2 ≧ 0.12 . With decreasing temperature, scapolite breaks down to plagioclase + calcite. Scapolite is replaced by plagioclase + grossular + cancrinite + CO 2 in the presence of H 2 O-rich fluids. The stable coexistence of scapolite and calcite, an assemblage typical of most natural occurrences of calcic scapolite, is limited by the reaction: scapolite + calcite → grossular + cancrinite + CO 2 , which occurs at 750°C, X CO 2 = 0.46; 700°C, X CO 2 = 0.33; 650°C, X CO 2 = 0.18, for the chosen bulk composition. Generalization of the experimental results to encompass the complete range of fully carbonated scapolite compositions indicates that mizzonite (Me 75 ) has the largest T - X CO 2 stability field. For scapolite more calcic than mizzonite, stable growth is restricted to conditions of increasingly higher temperature and X CO 2 . The experimental results are consistent with various petrologic features of scapolite-bearing rocks, particularly scapolite-clinopyroxene granulites, and indicate that such rocks were formed in the presence of CO 2 -rich fluids.

Geochimica et Cosmochimica Acta↗
USGS1991

The Estherville mesosiderite: U Pb, Rb Sr, and Sm Nd isotopic study of a polymict breccia

A systematic U Pb, Sm Nd, and Rb Sr isotopic study shows that the Estherville mesosiderite was formed between 4.56 and 4.43 Ga. Observed isotopic heterogeneity is in agreement with multiple generations of meteoritic impacts described in other mesosiderites. At least part of the Estherville silicate fraction was formed early in solar system history as indicated by the Pb-Pb (4555 ± 35 Ma), U Pb (4560 ± 31 Ma), Rb Sr (4542 ± 203 Ma), and Sm Nd (4533 ± 94 Ma) ages. Mesosiderites therefore present not only petrological but also geochronological similarities with eucrites. The Pb isotopic composition of the metal phase plots on the same isochron as the silicates, indicating formation and subsequent mixing with silicates early in the history of the solar system. This is consistent with previous observations indicating that iron was reduced during the silicate-magmatic stage, most likely a consequence of mixing with metal. In addition to these more-ancient portions of the Estherville breccia, other parts were formed later as suggested by the Pb-Pb (4422 ± 50 Ma) and U Pb (4437 ± 11 Ma) ages observed in a second group of leaches and residues. This age is similar to some cumulate eucrite ages and may represent the formation of a second mesosiderite component. The Sm Nd and the Rb Sr ages obtained on Estherville show large errors that may be a consequence of the mixing between the 4.56 and 4.43 Ga endmembers. Estherville, like most mesosiderites, was affected by a major heating event around 3.5-3.7 Ga as shown by the Ar-Ar ages ( Bogard et al., 1990). This heating event partially disturbed the Rb Sr isotopic system (Rb Sr metamorphic ages range between 3.81 and 4.08 Ga).

Geochimica et Cosmochimica Acta↗
USGS1990

Mineralogy and geochemistry of altered rocks associated with Lemitar carbonatites, central New Mexico, U.S.A.

The intrusion of more than 100 Cambrian-Ordovician carbonatite dikes caused minor alteration of Proterozoic granitic and mafic rocks in the Lemitar Mountains, although hematization, carbonatization and fenitization caused extensive alteration locally. Ampibolites within 15-20 m of the carbonatite dike contacts were highly altered by carbonatization. Locally the Lemitar diorite/gabbro adjacent to some carbonatites were altered in a thin, discontinuous zone by sodic-potassic fenitization. The granite at Polvadera Peak was locally altered by potassic fenitization. Most of the altered rocks have been further altered by hematization and carbonatization. The altered rocks show increases in loss on ignition and in one or more the elements Ca, K, Na and Al. Only granitic fenites in the Lemitar Mountains lost silica and some diorite/gabbro fenites gained silica. Petrologic and geochemical studies clearly indicate that the types and degree of alteration differ notably in different rock types. The fenitizing fluids were oxidizing, slightly acidic, high in volatiles (especially CO2) and possibly fairly low in alkali elements. ?? 1990.

LITHOS↗
USGS1991

Shoreline deposits and diagenesis resulting from two Late Pleistocene highstands near +5 and +6 metres, Durban, South Africa

In exposures of Pleistocene rocks on the east coast of South Africa, eight sedimentary facies were distinguished on the basis of petrology, grain size, internal structures and field relationships. These are interpreted as deposits of surf zone, breaker zone, swash zone, backbeach, boulder beach and dune environments. Three phases of deposition and diagenesis are recognized. As a result of the stabilising effect of pre-existing coastal facies, the deposits from successive sea level stands are stacked vertically in a narrow coast-normal strip. Early cementation prevented erosion of the deposits during subsequent transgressions. Deposition of subsequent facies took place on an existing coastal dune (Facies 1). A terrace was cut into this dune at a sea level 4.5 to 5 m above present. At this sea level, clastic shoreline sediments were deposited which make up the main sedimentary sequence exposed (Facies 2–7). The steep swash zone, coarse grain size, and comparison with modern conditions in the study area indicate clastic deposition on a high-energy, wave-dominated, microtidal coastline. Vertical stacking of progressively shallower water facies indicates progradation associated with slightly regressive conditions, prior to stranding of the succession above sea level. During a subsequent transgression to 5.5 or 6 m above present sea level, a second terrace was cut across the existing facies, which by then were partly lithified. A boulder beach (Facies 8) deposited on this terrace is indicative of high wave energy and a rocky coastline, formed by existing cemented coastal facies. Comparison with dated deposits from other parts of the South African coast suggest a Late Pleistocene age for Facies 2–8. Deposition was terminated by subsequent regression and continuing low sea levels during the remainder of the Pleistocene. Cementation of the facies took place almost entirely by carbonate precipitation. The presence of isopachous fibrous cements suggests early cementation of Facies 1, 2, 3 and 4 under marine conditions, initially as aragonite which has since inverted to calcite. Facies 5, 6 and 7 are cemented only by equant calcite spar, evidence of cementation in the meteoric phreatic and vadose zones. Lowering of the water table during regression caused the remaining pore space in Facies 1, 2, 3 and 4 to be filled with equant calcite spar. Decementation in a 130 cm wide zone is attributed to water table shifts associated with the later transgression which deposited Facies 8. The vertical stacking of the two depositional sequences may be attributed to rapid cementation of Facies 2, 3, 4, 5, 6 and 7 under humid, subtropical conditions. This lithified sequence then acted as a focus for deposition of coarse-grained shoreline facies (Facies 8) during the subsequent transgression.

Marine Geology↗
USGS1991

Middle to late Cenozoic magmatism of the southeastern Colorado Plateau and central Rio Grande rift (New Mexico and Arizona, U.S.A.): A model for continental rifting

The region of the present Rio Grande rift and southeastern Colorado Plateau underwent lithospheric extension during middle to late Cenozoic deformation affecting the entire southwestern U.S. Lithospheric mantle was disrupted, and in many regions displaced or replaced by asthenospheric mantle at depths from which basaltic magmas were derived and erupted to the surface. Study of the igneous rocks erupted or intruded during this deformation yields insights into processes of magmatism associated with extension of continental lithosphere. Magmatic rocks associated with an early (late Oligocene-early Miocene) ductile phase of extension are dominantly basaltic andesites and related, calc-alkaline intermediate to silicic derivative rocks. Mafic magmas were probably derived from isotopically “enriched” lithospheric mantle. Igneous rocks associated with a later (middle Miocene-Holocene), more brittle phase of extension include widespread basaltic rocks and localized central volcanoes of intermediate to silicic composition. Isotopic compositions of mafic rocks, which include both tholeiitic and alkalic basalts, correlate strongly with tectonic setting and lithospheric structure. Basalts erupted in areas of greatest crustal extension, such as the central and southern rift and Basin and Range province, were derived from isotopically “depleted” (correlated with “asthenospheric”) mantle. Also, isotopic compositions of Pliocene to Holocene basalts are slightly more depleted than those of Miocene basalts, suggesting that subcrustal lithospheric mantle was thinned during late Miocene extension. Intermediate rocks of the central volcanoes formed by a complex combination of processes, probably dominated by fractional crystallization and by assimilation of upper and lower crust in isolated, small magma chambers. The petrologic, geochemical, and isotopic data are compatible with a model, derived first from geophysical data, whereby lithosphere is thinned beneath the central rift and southeastern Colorado Plateau, with greatest thinning centered beneath the axis of the rift. A lithospheric model involving uniform-sense simple shear does not appear compatible with the data as presently understood.

Arizona, New Mexico↗
USGS1994

40Ar/39Ar thermochronologic constraints on the tectonothermal evolution of the northern East Humboldt Range metamorphic core complex, Nevada

The northern East Humboldt Range (NEHR) of northeastern Nevada exposes a suite of complexly deformed migmatitic, upper amphibolite-facies rocks in the footwall of the Ruby Mountains-East Humboldt Range (RM-EHR) detachment fault. New 40 Ar/ 39 Ar data on hornblende, muscovite, biotite, and potassium feldspar help constrain the kinematic and thermal evolution of this terrain during Tertiary extensional exhumation. Hornblende samples from relatively high structural levels yield discordant age spectra that suggest initial cooling during early Tertiary time (63–49 Ma). When coupled with petrological constraints indicating a strongly decompressional P-T-t path above 550°C, the hornblende data suggest that exhumation of the RM-EHR may have initiated in early Tertiary time, approximately coincident with the initial phases of unroofing in the Wood Hills immediately to the east and with the end of thrusting in the late Mesozoic to early Tertiary Sevier orogenic belt of eastern Nevada and western Utah. This temporal coincidence suggests that gravitational collapse of tectonically thickened crust in the internal zone of the Sevier belt could have driven the initial phases of unroofing. Thermal history during the final stage of exhumation of the NEHR is constrained by discordant hornblende cooling ages of 36-29 Ma from deep structural levels and biotite, muscovite, and potassium feldspar cooling ages of 27-21 Ma from a range of structural levels. Comparison of muscovite, biotite, and potassium feldspar cooling ages with previously published fission-track cooling ages implies very rapid cooling rates at temperatures below the closure temperature for muscovite (270°–350°C), but time gaps of > 7 m.y. between hornblende and mica cooling ages suggest that cooling at higher temperatures was more gradual. In addition, comparison of 40 Ar 39 Ar mica cooling ages with previously published fission-track apatite cooling ages suggests pronounced thermal gradients between the NEHR and adjacent areas during latest Oligocene to earliest Miocene time. Such thermal gradients could be readily explained if the RM-EHR detachment fault dipped > 30° between the 300°C and 100°C isotherms. Finally, 40 Ar 39 Ar biotite cooling ages increase southward through the East Humboldt Range, compatible with northward extrapolation of a previously recognized pattern of WNW-younging biotite cooling ages from the Ruby Mountains. A simple model involving the propagation of footwall uplift in the direction of tectonic transport beneath an initially listric normal fault can explain the principle features of the Oligocène to Miocene thermochronologic data set for the RM-EHR.

Nevada↗
USGS1976

Q-mode factor analysis of compositional data

An extended form of the method of Q-mode factor analysis may be used if the rows of the data matrix sum to a constant. The constant row-sum provides a means for scaling the factor model to conform to the units of the original data in such forms as proportions, percentages, or parts per million. The scale factors for an m-factor model are used to derive composition scores and loadings, which lead to the same reproduced data regardless of the choice of reference axes (end-members). Factor-variance diagrams may be constructed to show the proportion of the variance that will be accounted for in each compositional variable by models containing various numbers of end-members. The method may be used to develop a petrologic mixing model by searching for end-members that are geologically plausible. ?? 1976.

Computers & Geosciences↗
USGS1977

The U.S. geological survey rass-statpac system for management and statistical reduction of geochemical data

RASS is an acronym for Rock Analysis Storage System and STATPAC, for Statistical Package. The RASS and STATPAC computer programs are integrated into the RASS-STATPAC system for the management and statistical reduction of geochemical data. The system, in its present form, has been in use for more than 9 yr by scores of U.S. Geological Survey geologists, geochemists, and other scientists engaged in a broad range of geologic and geochemical investigations. The principal advantage of the system is the flexibility afforded the user both in data searches and retrievals and in the manner of statistical treatment of data. The statistical programs provide for most types of statistical reduction normally used in geochemistry and petrology, but also contain bridges to other program systems for statistical processing and automatic plotting. ?? 1977.

Computers & Geosciences↗
USGS1982

Recommended procedures and techniques for the petrographic description of bituminous coals

Modern coal petrology requires rapid and precise description of great numbers of coal core or bench samples in order to acquire the information required to understand and predict vertical and lateral variation of coal quality for correlation with coal-bed thickness, depositional environment, suitability for technological uses, etc. Procedures for coal description vary in accordance with the objectives of the description. To achieve our aim of acquiring the maximum amount of quantitative information within the shortest period of time, we have adopted a combined megascopic-microscopic procedure. Megascopic analysis is used to identify the distinctive lithologies present, and microscopic analysis is required only to describe representative examples of the mixed lithologies observed. This procedure greatly decreases the number of microscopic analyses needed for adequate description of a sample. For quantitative megascopic description of coal microlithotypes, microlithotype assemblages, and lithotypes, we use (V) for vitrite or vitrain, (E) for liptite, (I) for inertite or fusain, (M) for mineral layers or lenses other than iron sulfide, (S) for iron sulfide, and (X 1 ), (X 2 ), etc. for mixed lithologies. Microscopic description is expressed in terms of V representing the vitrinite maceral group, E the exinite group, I the inertinite group, and M mineral components. volume percentages are expressed as subscripts. Thus (V) 20 (V 80 E 10 I 5 M 5 ) 80 indicates a lithotype or assemblage of microlithotypes consisting of 20 vol. % vitrite and 80% of a mixed lithology having a modal maceral composition V 80 E 10 I 5 M 5 . This bulk composition can alternatively be recalculated and described as V 84 E 8 I 4 M 4 . To generate these quantitative data rapidly and accurately, we utilize an automated image analysis system (AIAS). Plots of VEIM data on easily constructed ternary diagrams provide readily comprehended illustrations of the range of modal composition of the lithologic units making up a given coal bed. The use of bulk-specific-gravity determinations is alo recommended for identification and characterization of the distinctive lithologic units. The availability of an AIAS also enhances the capability to acquire textural information. Ranges of size of maceral and mineral grains can be quickly and precisely determined by use of an AIAS. We assume that shape characteristics of coal particles can also be readily evaluated by automated image analysis, although this evaluation has not yet been attempted in our laboratory. Definitive data on the particulate mineral content of coal constitute another important segment of petrographic description. Characterization of mineral content may be accomplished by optical identification, electron microprobe analysis, X-ray diffraction, and scanning and transmission electron microscopy. Individual mineral grains in place in polished blocks or polished this sections, or separated from the coal matrix by sink-float methods are studied by analytical techniques appropriate to the conditions of sampling.

International Journal of Coal Geology↗
USGS1982

Origin and distribution of tonsteins in late permian coal seams of Southwestern China

We have surveyed the areal and stratigraphic distribution of tonsteins in Late Permian coalfields of southwestern China over an area of several hundred thousand square kilometers. We studied the relationship between tonstein distribution and sedimentary environment. Based on mineralogical and petrographic data, we have concluded that these tonsteins originated as air-fall volcanic ashes. Following accumulation in the peat swamps, in situ alteration of the vitric and lithic components took place under acidic conditions, leading to the formation of kaolinite. Based on petrologic, mineralogic, and chemical analytical data, we have determined that the application of mineralogic and geochemical criteria for tonsteins may be useful in correlating coal beds, predicting coal qualities and reconstructing related sedimentary paleoenvironmental conditions.

International Journal of Coal Geology↗
USGS1993

Geologic and geomorphic controls of coal development in some Tertiary Rocky Mountain basins, USA

Previous investigations have not well defined the controls on the development of minable coals in fluvial environments. This study was undertaken to provide a clearer understanding of these controls, particularly in of the lower Tertiary coal-bearing deposits of the Raton and Powder River basins in the Rocky Mountain region of the United States. In this region, large amounts of coals accumulated in swamps formed in the flow-through fluvial systems that infilled these intermontane basins. Extrabasinal and intrabasinal tectonism partly controlled the stratigraphic and facies distributions of minable coal deposits. The regional accumulation of coals was favored by the rapid basin subsidence coupled with minimal uplift of the source area. During these events, coals developed in swamps associated with anastomosed and meandering fluvial systems and alluvial fans. The extensive and high rate of sediment input from these fluvial systems promoted the formation of ombrotrophic, raised swamps, which produced low ash and anomalously thick coals. The petrology and palynology of these coals, and the paleobotany of the associated sediments, suggest that ombrotrophic, raised swamps were common in the Powder River Basin, where the climate during the early Tertiary was paratropical. The paleoecology of these swamps is identical to that of the modern ombrotrophic, raised swamps of the Baram and Mahakam Rivers of Borneo.

International Journal of Coal Geology↗