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At least 451 records · Page 25Linked to original sources
USGS1996

Physical, chemical, and biological characteristics of the Charlotte Harbor basin and estuarine system in southwestern Florida: A summary of the 1982-89 U.S. Geological Survey Charlotte Harbor assessment and other studies

The Charlotte Harbor estuarine system, having a surface area of about 270 square miles, averages about 7 feet in depth and is connected to deep water of the Gulf of Mexico through several passes and inlets between barrier islands. Three major rivers flow into the estuary--the Peace, the Myakka, and the Caloosahatchee. Freshwater and tidal flushing transport nutrients and other constituents from the basin through the estuary into the gulf. Flushing characteristics were evaluated using a two-dimensional hydrodynamic model. The model indicated that the time required to flush injected dye (simulated) from some subareas of the harbor was longer for reduced freshwater inflow than for typical freshwater inflow. After 30 days of simulation of reduced freshwater inflow, 42 percent of the dye injected into the upper harbor remained in the upper harbor, compared to 28 percent for typical freshwater inflow. The Charlotte Harbor estuary is usually well mixed or partially mixed in the vertical, but vertical salinity stratification does occur, primarily during late summer when freshwater inflows are greatest. A box model was developed that incorporated vertically averaged salinities to account indirectly for three-dimensional transport processes associated with vertical stratification. The box model predicts that under high (7,592 cubic feet per second) and average (2,470 cubic feet per second) freshwater inflows from the Peace and Myakka Rivers, 50 percent of the original water (present at the start of the model run) would be flushed from the northern part of the estuarine system into the Gulf of Mexico in 10 days and 20 days, respectively. The distribution of plant nutrients in the Charlotte Harbor Estuary is affected by nutrient inputs, freshwater and tidal flushing, mixing, and recycling processes in the estuary. The distributions of total phosphorus and orthophosphate are affected mainly by river input and physical mixing. The distribution of ammonia nitrogen is variable and is related more to recycling within the estuary than to input from the rivers. Ammonia concentrations increase in deeper water, probably in response to vertical salinity stratification and low concentrations of dissolved oxygen that foster regeneration of ammonia from bottom sediments. The distribution of nitrite plus nitrate nitrogen is nonconservative--concentrations are high in the rivers and decrease more rapidly in the estuary than expected due to dilution with sea water, probably because of phytoplankton uptake. Phytoplankton productivity and biomass are usually greatest during late summer near the mouths of the tidal rivers when freshwater inflow and nutrient loading are greatest. The highly colored freshwater runoff reduces light penetration and phytoplankton productivity in regions of the estuary where salinity is less than about 10 parts per thousand, but the nutrient-rich, colored water is diluted by seawater at midsalinities (10-20 parts per thousand) so that availability of light increases and inorganic nitrogen concentrations are still high enough to stimulate productivity and growth of phytoplankton. In much of the estuary, salinity is greater than 20 parts per thousand, and availability of inorganic nitrogen, not light, limits productivity and growth. Although the Charlotte Harbor estuarine system is relatively undisturbed, much of its basin has been altered by human activities. Streamflow decreased substantially during 1931-84 in parts of the Peace River, probably because of ground-water withdrawals in the basin. Nutrient concentrations generally increased in the rivers during 1970-85, because of an increase in the flow of wastewater and agricultural runoff. The concentrations of phosphorus are naturally high in the Peace River because of extensive phosphate deposits in the basin. The phosphate deposits also are relatively rich in radionuclides of the uranium-238 series, including radium-226. In the upper basin, these deposits are exposed in the riverbed. Extensive phosphate mining and processing have exposed additional deposits to surface runoff. Periodic spills of phosphate sediments (slimes) have contributed additional phosphorus and radium-226 to the river and estuary. A single spill can contribute a phosphorus load equal to the annual loading in the Peace River at Arcadia. The projected increase in population in the basin by the year 2020 would generate an additional 60 million gallons per day of domestic wastewater over that generated during 1980, which would increase nitrogen loading in the basin by more than 3 tons per day. Intensified agricultural and industrial developments, particularly expanding citrus production and phosphate mining, could generate additional loads of nutrients and a variety of inorganic and organic contaminants. Increased inputs of nutrients, particularly nitrogen, could encourage growth and increase abundance of phytoplankton and benthic and epiphytic algae. If water were less colored as a result of reduced freshwater inflow, undesirable algal growth could be exacerbated because of increased availability of light. Increased abundance of phytoplankton and other algae could likely change dissolved-oxygen concentrations in the estuary, resulting in greater day-to-night fluctuations and the possible depletion of dissolved oxygen in deep water. At the present time, near-anaerobic conditions occur for days or weeks in the deep water (more than 9 feet) of the northern harbor during late summer. These conditions could become more persistent with time and over wider areas, if phytoplankton and other algae increase in abundance and in their contribution to benthic oxygen demand. An increased abundance of phytoplankton and other algae also would reduce light penetration and adversely affect seagrasses.

Florida↗
USGS2014

Methane oxidation linked to chlorite dismutation

We examined the potential for CH 4 oxidation to be coupled with oxygen derived from the dissimilatory reduction of perchlorate, chlorate, or via chlorite (ClO − 2 ) dismutation. Although dissimilatory reduction of ClO − 4 and ClO − 3 could be inferred from the accumulation of chloride ions either in spent media or in soil slurries prepared from exposed freshwater lake sediment, neither of these oxyanions evoked methane oxidation when added to either anaerobic mixed cultures or soil enriched in methanotrophs. In contrast, ClO − 2 amendment elicited such activity. Methane (0.2 kPa) was completely removed within several days from the headspace of cell suspensions of Dechloromonas agitata CKB incubated with either Methylococcus capsulatus Bath or Methylomicrobium album BG8 in the presence of 5 mM ClO − 2 . We also observed complete removal of 0.2 kPa CH 4 in bottles containing soil enriched in methanotrophs when co-incubated with D. agitata CKB and 10 mM ClO − 2 . However, to be effective these experiments required physical separation of soil from D. agitata CKB to allow for the partitioning of O 2 liberated from chlorite dismutation into the shared headspace. Although a link between ClO − 2 and CH 4 consumption was established in soils and cultures, no upstream connection with either ClO − 4 or ClO − 3 was discerned. This result suggests that the release of O 2 during enzymatic perchlorate reduction was negligible, and that the oxygen produced was unavailable to the aerobic methanotrophs.

Frontiers in Microbiology↗
USGS2013

A combined radio- and stable-isotopic study of a California coastal aquifer system

Stable and radioactive tracers were utilized in concert to characterize geochemical processes in a complex coastal groundwater system and to provide constraints on the kinetics of rock/water interactions. Groundwater samples from wells within the Dominguez Gap region of Los Angeles County, California were analyzed for a suite of major cations (Na + , K + , Mg 2+ , Ca 2+ ) and anions (Cl − , SO 4 2− ), silica, alkalinity, select trace elements (Ba, B, Sr), dissolved oxygen, stable isotopes of hydrogen (δD), oxygen (δ 18 O), dissolved inorganic carbon (δ 13 C DIC ), and radioactive isotopes ( 3 H, 222 Rn and 223,224,226,228 Ra). In the study area, groundwater may consist of a complex mixture of native groundwater, intruded seawater, non-native injected water, and oil-field brine water. In some wells, Cl − concentrations attained seawater-like values and in conjunction with isotopically heavier δ 18 O values, these tracers provide information on the extent of seawater intrusion and/or mixing with oil-field brines. Groundwater 3 H above 1 tritium unit (TU) was observed only in a few select wells close to the Dominguez Gap area and most other well groundwater was aged pre-1952. Based on an initial 14 C value for the study site of 90 percent modern carbon (pmc), groundwater age estimates likely extend beyond 20 kyr before present and confirm deep circulation of some native groundwater through multiple aquifers. Enriched values of groundwater δ 13 C DIC in the absence of SO 4 2− imply enhanced anaerobic microbial methanogenesis. While secular equilibrium was observed for 234 U/ 238 U (activity ratios ~1) in host matrices, strong isotopic fractionation in these groundwater samples can be used to obtain information of adsorption/desorption kinetics. Calculated Ra residence times are short, and the associated desorption rate constant is about three orders of magnitude slower than that of the adsorption rate constant. Combined stable- and radio-isotopic results provide unique insights into aquifer characteristics, such as geochemical cycling, rock/water interactions, and subsurface transport and mixing.

California↗
USGS2013

Net primary productivity of subalpine meadows in Yosemite National Park in relation to climate variability

Subalpine meadows are some of the most ecologically important components of mountain landscapes, and primary productivity is important to the maintenance of meadow functions. Understanding how changes in primary productivity are associated with variability in moisture and temperature will become increasingly important with current and anticipated changes in climate. Our objective was to describe patterns and variability in aboveground live vascular plant biomass in relation to climatic factors. We harvested aboveground biomass at peak growth from four 64-m 2 plots each in xeric, mesic, and hydric meadows annually from 1994 to 2000. Data from nearby weather stations provided independent variables of spring snow water content, snow-free date, and thawing degree days for a cumulative index of available energy. We assembled these climatic variables into a set of mixed effects analysis of covariance models to evaluate their relationships with annual aboveground net primary productivity (ANPP), and we used an information theoretic approach to compare the quality of fit among candidate models. ANPP in the xeric meadow was negatively related to snow water content and thawing degree days and in the mesic meadow was negatively related to snow water content. Relationships between ANPP and these 2 covariates in the hydric meadow were not significant. Increasing snow water content may limit ANPP in these meadows if anaerobic conditions delay microbial activity and nutrient availability. Increased thawing degree days may limit ANPP in xeric meadows by prematurely depleting soil moisture. Large within-year variation of ANPP in the hydric meadow limited sensitivity to the climatic variables. These relationships suggest that, under projected warmer and drier conditions, ANPP will increase in mesic meadows but remain unchanged in xeric meadows because declines associated with increased temperatures would offset the increases from decreased snow water content.

Western North American Naturalist↗
USGS2009

The application of induced polarization techniques to detect metal-bearing offshore anthropogenic waste and unexploded ordnance

Raw sewage and industrial waste have been dumped into sensitive estuaries, bays, and sounds for centuries. The full extents of the resulting sludge deposits are largely unknown, because they move in response to tidal and long‐shore currents, and because they are often buried by younger inert sediments. USGS field and laboratory measurements of toxic mine waste and organic effluent samples suggest that anthropogenic wastes typically contain finely‐divided metal and metal‐sulfide particles. The anoxic environment provided by anthropogenic wastes promotes the growth of anaerobic bacteria, creating a self‐reducing environment. We suggest that the finely‐divided metal and metal‐sulfide particles are the products of bacterial reduction and precipitation. The fine‐grained metallic precipitates are ideal targets for a surface‐effect electrochemical detection methodology called Induced Polarization (IP). A USGS‐patented (1998/2001) marine IP streamer technology has recently been commercialized and used to map “black smoker” sulfide deposits and their disseminated halos in the Bismarck Sea (2005), and titanium‐sand deposits offshore of South Africa (2007). The marine induced polarization system can do this mapping in three dimensions, more rapidly (it is towed at 3 knots), and with far higher resolution that land‐based measurements or vibracoring. Laboratory‐scale studies at the USGS suggest that anthropogenic wastes may display a specific multi‐frequency IP spectral signature that may be applicable to waste‐deposit mapping.

Conference Paper↗
USGS2003

Methanogenic activity in plankton samples and fish intestines A mechanism for in situ methanogenesis in oceanic surface waters

When plankton samples were incubated anaerobically with a cysteine-sulfide reducing agent, pronounced methane evolution occurred. This activity was inhibited by air, CHCl 3 , C 2 H 2 , and 2-bromoethanesulfonic acid. Adding [ 14 C]CO 3 2− resulted in accumulation of [ 14 C]CH 4 . Portions of the digestive tracts of three fishes were incubated in methanogenic media, and two of the samples showed the presence of methanogenic bacteria.

Limnology and Oceanography↗
USGS1999

Oxidation of ammonia and methane in an alkaline, saline lake

The oxidation of ammonia (NH 3 ) and methane (CH 4 ) was investigated in an alkaline saline lake, Mono Lake, California (U.S.A.). Ammonia oxidation was examined in April and July 1995 by comparing dark 14 CO 2 fixation rates in the presence or absence of methyl fluoride (MeF), an inhibitor of NH 3 oxidation. Ammonia oxidizer‐mediated dark 14 CO 2 fixation rates were similar in surface (5–7 m) and oxycline (11–15 m) waters, ranging between 70–340 and 89–186 nM d −1 , respectively, or 1–7% of primary production by phytoplankton. Ammonia oxidation rates ranged between 580–2,830 nM d −1 in surface waters and 732–1,548 nM d −1 in oxycline waters. Methane oxidation was examined using a 14 CH 4 tracer technique in July 1994, April 1995, and July 1995. Methane oxidation rates were consistently higher in July, and rates in oxycline and anaerobic bottom waters (0.5–37 and 7–48 nM d −1 , respectively) were 10‐fold higher than those in aerobic surface waters (0.04–3.8 nM d −1 ). The majority of CH 4 oxidation, in terms of integrated activity, occurred within anoxic bottom waters. Water column oxidation reduced the potential lake‐atmosphere CH 4 flux by a factor of two to three. Measured oxidation rates and water column concentrations were used to estimate the biological turnover times of NH 3 and CH 4 . The NH 3 pool turns over rapidly, on time scales of 0.8 d in surface waters and 10 d within the oxycline, while CH 4 is cycled on 10 3 ‐d time scales in surface waters and 10 −2 time scales within oxycline and bottom waters. Our data suggest an important role for NH 3 oxidation in alkaline, saline lakes since the process converts volatile NH 3 to soluble NO 2 − , thereby reducing loss via lake‐atmosphere exchange and maintaining nitrogen in a form that is readily available to phyto‐plankton.

Limnology and Oceanography↗
USGS2016

Methane and sulfate dynamics in sediments from mangrove-dominated tropical coastal lagoons, Yucatan, Mexico

Porewater profiles in sediment cores from mangrove-dominated coastal lagoons (Celestún and Chelem) on the Yucatán Peninsula, Mexico, reveal the widespread coexistence of dissolved methane and sulfate. This observation is interesting since dissolved methane in porewaters is typically oxidized anaerobically by sulfate. To explain the observations we used a numerical transport-reaction model that was constrained by the field observations. The model suggests that methane in the upper sediments is produced in the sulfate reduction zone at rates ranging between 0.012 and 31 mmol m −2 d − 1 , concurrent with sulfate reduction rates between 1.1 and 24 mmol SO 4 2− m −2 d −1 . These processes are supported by high organic matter content in the sediment and the use of non-competitive substrates by methanogenic microorganisms. Indeed sediment slurry incubation experiments show that non-competitive substrates such as trimethylamine (TMA) and methanol can be utilized for microbial methanogenesis at the study sites. The model also indicates that a significant fraction of methane is transported to the sulfate reduction zone from deeper zones within the sedimentary column by rising bubbles and gas dissolution. The shallow depths of methane production and the fast rising methane gas bubbles reduce the likelihood for oxidation, thereby allowing a large fraction of the methane formed in the sediments to escape to the overlying water column.

Yucatan↗
USGS2026

Proposing sources for discrete groundwater discharges to patterned pools in three regional raised northern peat bogs

Raised northern peat bogs are generally assumed to be entirely precipitation-fed (ombrogenous), suggesting they are void of groundwater (minerogenous) inflow from underlying sediments. Patterned pools in raised bogs have often been attributed to surficial flow filling depressions along the peat surface that produces subtle differences in peat pore-water chemistry. However, we present evidence that certain patterned pools may be partially fed by localized upwelling of minerogenous groundwater from underlying glacial sediments in three northern peat bogs of Maine, USA. Underlying permeable glacial deposits, embedded in hydraulically confining glacio-marine clay deposits, were delineated using ground-penetrating radar and transient electromagnetic surveys. Paired point measurements of temperature and specific conductance (SpC) were surveyed around pools, and statistical relationships indicative of groundwater upwelling were established. Uncrewed aerial systems (UAS) thermal infrared (TIR) mapping was conducted, augmented by handheld TIR imaging, to examine characteristic groundwater temperatures in cold and warm seasons across pool surfaces. Surface water samples were acquired to assess the relationship between SpC / temperature signals and elevated iron and manganese concentrations that could be indicative of glacial aquifer sources. The combined datasets present evidence for localized upwelling in pools underlain by glacial structures, and the possibility of minerogenous groundwater contributions. Upwelling through the peat matrix is possibly partially facilitated by macropore, “peat pipe” features that serve as preferential flowpaths of varying lengths to the surface. Such upwelling could drive a positive feedback loop where elevated concentrations of ionic constituents repeatedly dilate the peat matrix and/or terminal electron acceptors enhance anaerobic respiration and microbial activity, accelerating the humification of peat around patterned pools and potentially magnifying carbon loss.

Maine↗
USGS1998

The inhibition of Clostridium botulinum type C by other bacteria in wetland sediments

Bacteria with inhibitory activity against Clostridium botulinum type C were isolated from 32% of sediment samples ( n = 1600) collected from 10 marshes in a northern California wetland over a 12 mo period. Aerobic and anaerobic bacteria with inhibitory activity were isolated from 12% and 23% of the samples, respectively. Bacteria with inhibitory activity were isolated from all 10 study sites and throughout the year. This study demonstrates that bacteria with inhibitory activity against C. botulinum type C occur naturally in wetland sediments.

California↗
USGS1986

Forested wetlands of the Southeast: Review of major characteristics and role in maintaining water quality

Forested wetlands occupying floodplains of major rivers in the Southeast are highly productive and diverse ecological systems. The wetlands are produced and maintained by fluvial processes and unique hydrologic regimes consisting of periodic flooding and subsequent drydown. Fluctuations in soil chemistry and biology resulting from this flooding and drydown provide a broad range of environmental conditions that are important in determining the role of forested wetlands in maintaining and improving water quality. The periodic shift between aerobic and anaerobic conditions in floodplain soils in response to flooding facilitates the assimilation of nutrients and organic matter, hastens the degradation of persistent pesticides, and decreases the bioavailability of heavy metals.

Resource Publication↗
USGS1989

Zinc movement in sewage-sludge-treated soils as influenced by soil properties, irrigation water quality, and soil moisture level

A soil column study was conducted to assess the movement of Zn in sewage-sludge-amended soils. Varables investigated were soil properties, irrigation water quality, and soil moisture level. Bulk samples of the surface layer of six soil series were packed into columns, 10.2 cm in diameter and 110 cm in length. An anaerobically digested municipal sewage sludge was incorporated into the top 20 cm of each column at a rate of 300 mg ha-1. The columns were maintained at moisture levels of saturation and unsaturation and were leached with two waters of different quality. At the termination of leaching, the columns were cut open and the soil was sectioned and analyzed. Zinc movement was evaluated by mass balance accounting and correlation and regression analysis. Zinc movement in the unsaturated columns ranged from 3 to 30 cm, with a mean of 10 cm. The difference in irrigation water quality did not have an effect on Zn movement. Most of the Zn applied to the unsaturated columns remained in the sludge-amended soil layer (96.1 to 99.6%, with a mean of 98.1%). The major portion of Zn leached from the sludge-amended soil layer accumulated in the 0- to 3-cm depth (35.7 to 100%, with a mean of 73.6%). The mean final soil pH values decreased in the order: saturated columns = sludge-amended soil layer > untreated soils > unsaturated columns. Total Zn leached from the sludge-amended soil layer was correlated negatively at P = 0.001 with final pH (r = -0.85). Depth of Zn movement was correlated negatively at P = 0.001 with final pH (r = -0.91). Multiple linear regression analysis showed that the final pH accounted for 72% of the variation in the total amounts of Zn leached from the sludge-amended soil layer of the unsaturated columns and accounted for 82% of the variation in the depth of Zn movement among the unsaturated columns. A significant correlation was not found between Zn and organic carbon in soil solutions, but a negative correlation significant at P = 0.001 was found between pH and Zn (r = -0.61).

Soil Science↗
USGS1991

Assessing the effects of microbial metabolism and metabolities on reservoir pore structure

The effect of microbial treatment on pore structure of sandstone and carbonatereservoirs was determined. Understanding how different bacterial strains and their metabolic bioproducts affect reservoir pore structure will permit the prudent application of microorganisms for enhanced oil recovery. The microbial strains tested included Clostridium acetobutylicum, a polymer-producing Bacillus strain, and an unidentified halophilic anaerobe that mainly produced acids and gases. Electrical conductivity, absolute permeability, porosity and centrifuge capillary pressure were used to examine rock pore structures. Modifications of the pore structure observed in the laboratory cores included pore enlargement due to acid dissolution of carbonates and poare throat reduction due to biomass plugging. This paper shows that careful selection of microbes based on proper understanding of the reservoir petrophysical characteristics is necessary for applications of microbially enhanced oil recovery. These methods and results can be useful to field operators and laboratory researchers involved in design and screening of reservoirs for MEOR. The methods are also applicable in evaluation of formation damage caused by drilling, injection or completion fluids or stimulation caused by acids.

Conference Paper↗
USGS1999

Natural attenuation of chloroacetinilide herbicides in aquatic systems

Chloroacetanilide herbicides (e.g. alachlor and metolachlor) and their breakdown products are frequently found in agriculturally impacted and other natural waters. Although these compounds are usually present at low concentrations in aquatic systems, defining their fate and attenuation rate is important because they can be toxic at comparatively low exposure levels. This paper summarizes results from a four-year research program assessing factors that affect herbicide attenuation rates and breakdown product formation patterns in aquatic systems. Over 70 different field microcosms (11.3 m 3 cylindrical fiberglass tanks) were selectively manipulated (in replicate) to create nine unique aquatic ecosystems for this study. Alachlor and/or metolachlor were added to these units and transformations were observed over time. Alachlor half-lives ranged from 6.0 days to more than 100 days depending upon the temperature, oxygen conditions, and the nutrient conditions in the microcosm waters. The highest rates of alachlor decay were observed in warm, nutrient-rich, anaerobic water columns, whereas the lowest alachlor decay rates were observed under cooler, aerobic, oligotrophic water conditions. Similar relationships were observed for metolachlor, although metolachlor decay rates were about 40% slower. Our data suggest that herbicides will decay rapidly in waters that are high in nutrients possibly resulting from human activities. Alternately, low nutrient or pristine waters will have the lowest rates of herbicide decay. On a policy level, all efforts should be made to prevent exposure of comparatively pristine waters to herbicide inputs.

Conference Paper↗
USGS2002

Enhanced CAH dechlorination in a low permeability, variably-saturated medium

An innovative pilot-scale field test was performed to enhance the anaerobic reductive dechlorination (ARD) of chlorinated aliphatic hydrocarbons (CAHs) in a low permeability, variably-saturated formation. The selected technology combines the use of a hydraulic fracturing (fracking) technique with enhanced bioremediation through the creation of highly-permeable sand- and electron donor-filled fractures in the low permeability matrix. Chitin was selected as the electron donor because of its unique properties as a polymeric organic material and based on the results of lab studies that indicated its ability to support ARD. The distribution and impact of chitin- and sand-filled fractures to the system was evaluated using hydrologic, geophysical, and geochemical parameters. The results indicate that, where distributed, chitin favorably impacted redox conditions and supported enhanced ARD of CAHs. These results indicate that this technology may be a viable and cost-effective approach for remediation of low-permeability, variably saturated systems.

Conference Paper↗
USGS2001

Methanogenic biodegradation of charcoal production wastes in groundwater at Kingsford, Michigan, USA

A house exploded in the City of Kingsford, Michigan USA. The explosion was caused by CH4 that leaked into the basement from the surrounding soil. Evidence suggests that biodegradation of products from the distillation and spillage at or near a former wood carbonization plant site was the major source of CH4 and CO2 in the groundwater system. The plant area is directly upgradient from deep groundwater, samples of which are green-yellow in colour, have a very strong odour of burnt wood, contain high concentrations of mononuclear aromatic and phenolic compounds, and extremely high concentrations of volatile fatty acids. The majority of the dissolved compounds in these groundwater samples have been shown, using laboratory microcosms, to be anaerobically biodegradable to CH4 and CO2. The biodegradable compounds, and the amounts of CH4 and CO2 produced in the microcosms, are consistent with observations from field samples.

Michigan↗
USGS2002

Considerations for sampling inorganic constituents in ground water using diffusion samplers

Data indicate that nylon-screen and dialysis diffusion samplers are capable of obtaining concentrations of inorganic solutes in ground water from wells that closely correspond to concentrations obtained by low-flow sampling. Conservative solutes, such as chloride, can be sampled by filling the diffusion samplers with oxygenated water. The samplers should be filled with anaerobic water for sampling redoxsensitive solutes. Oxidation of iron within the samplers, either by using aerobic fill water or by in-well oxygenation events, can lead to erroneous iron concentrations. Lithologic and chemical heterogeneity and sampler placement depth can lead to differences between concentrations from diffusion samples and low-flow samples because of mixing during pumping. A disadvantage of regenerated cellulose dialysis samplers is that they can begin to biodegrade within the two weeks of deployment. Nylon-screen samplers buried beneath streambed sediment along the unnamed tributary in a discharge zone of arseniccontaminated ground water were useful in locating the specific discharge zone.

Conference Paper↗
USGS2002

Alkylcyclohexanes in environmental geochemistry

Two case studies of oil spills that demonstrate the changing distribution patterns resulting from long-term anaerobic microbial degradation were presented. These spills were the 1979 crude-oil spill in Bemidji, MN, and a chronic diesel-fuel spillage from 1953-1991 at Mandan, ND. The alkylcyclohexanes in both spilled oil products were affected by similar biodegradative processes in which the compounds underwent a consistent pattern of loss from the high molecular weight end of the homolog distribution. Degradation resulted in a measurable increase in the concentrations of the homologs in the lower molecular weight range, a gradual lowering in carbon number of the homolog maximum, and a gradual decrease of the total homolog range from the high molecular weight end. The Mandan diesel fuel spill showed that the progressive enhancement of the low-molecular-mass n-alkane and n-alkylcyclohexane homologs reflected an absolute increase in their concentrations as the high-molecular-mass homologs were diminishing. These degradation patterns were different from those observed in aerobic or physically weathered systems, where loss of n-alkenes and other aliphatic homologs occurred from the low molecular weight end of the distributions. Spilled diesel and other mid-cut refinery fuels were defined by the range and distribution of the n-alkylcyclohexanes. If the biodegradation has progressed well into or beyond n-alkane loss and to the stage of low-molecular-mass n-alkylcyclohexane enhancement and high-molecular-mass loss, the hydrocarbon pattern could be erroneously attributed to other lower-range middle distillate fuels or admixtures of fuels. This is an abstract presented at the 25th Arctic and Marine OilSpill Program Technical Seminar (Calgary, Alberta, 6/11-13/2002).

Conference Paper↗