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At least 433 records · Page 24Linked to original sources

Lead and barium sources in Cambrian siliciclastics and sediment provenance of a sector of the Taconic Orogen, Quebec: a mixing scenario based on Pb-isotopic evidence

To test the hypothesis that siliciclastic rocks constituted the major source of Pb and Ba in barite-galena deposits of the Taconic Orogen, we determined Pb-isotope ratios in galena, barren rocks and contained minerals, as well as concentrations of Pb, U, Th and Ba in the latter (detrital feldspars, sandstones, mudstones, rock clasts and carbonate cements and clasts). Ranges in 206 Pb/ 204 Pb, 207 Pb/ 204 Pb and 208 Pb/ 204 Pb of 28 galena samples are 17.96–18.05, 15.56–15.59 and 37.75–37.93, respectively; ranges for 41 barren rocks and minerals are 16.17–23.31, 15.26–15.86 and 35.98–42.51, respectively. The lowest ratios are in feldspar, and the highest in carbonate and mudstone. Values of the mudstones samples overlap those of galena when corrected for in situ decay of U and Th since galena precipitation (∼450Ma). We thus propose that mudstones constituted a source of lead. Corrected ratios for anomalously Pb-rich mudstones are virtually identical to galena-Pb ratios and may be due to contamination by lead-bearing brines. Assuming that burial diagenesis did not disturb the Pb-isotope values of sandstones, these rocks contributed only a minor fraction of lead to the galena, estimated at∼20% for one deposit. The source of barite-Ba was probably perthite. Low Ba and Pb concentrations of sandstone adjacent to this deposit, compared to high concentrations remote from it, support leaching of barium (and minor lead) from feldspar penecontemporaneous with feldspar dissolution. Geological data indicate that the provenance of the siliciclastic rocks was mainly from Grenville terrane. A comparison of our Pb-isotopic data for Taconic perthite with those of Grenville K-feldspar, as well as ratios of trace elements, support this provenance for both sandstones and mudstones. The presence of carbonate platforms peripheral to the orogen, and the Middle Ordovician-Middle Devonian depositional range of the studied and Mississippi Valley type deposits north (Newfoundland) and south (U.S.A. Appalachians) of our study area suggest targets for exploration in these platforms.

Applied Geochemistry↗

Behavior of trace elements during magmatic processes - A summary of theoretical models and their applications

Progress in understanding the behavior of trace elements during the processes that produce igneous rocks has been made possible by the parallel development of theoretical models to describe that behavior and analytical techniques that permit precise measurement of trace-element concentrations in igneous rocks and minerals. The result of this progress is that trace-element studies may now be used to place strong limits on both the degree of partial melting or fractional crystallization involved in the production of a given magma and the identity and quantity of the residual phases. A summary of quantitative trace-element theory and partition coefficient data for igneous rocks is presented.

Journal of Research of the U.S. Geological Survey↗

Samarium-neodymium data on two late Proterozoic ophiolites of Saudi Arabia and implications for crustal and mantle evolution

Whole-rock and mineral samples from the Jabal al Wask and Jabal Ess ophiolites, northwestern Saudi Arabia, yield Sm-Nd isochron ages of 743+24 Ma and 782??38 Ma, respectively. These formation ages, which provide maximum limits for possible obduction ages, are in broad but not precise agreement with the previously known geologic history of the Arabian Shield. They indicate that the ophiolitic rocks are roughly coeval with nearby volcanic and plutonic rocks, supporting a back-arc origin for the two ophiolites. We suggest that the Jabal al Wask and Jabal Ess ophiolites were parts of the same northeast-southwest trending ophiolite belt, now offset along the Najd fault system. Initial e{open}Nd values range from +6.6 to+ 7.6, indicating derivation from a mantle source that has been LIL-depleted for at least 2 Ga. Reported e{open}Nd values from the Arabian Shield that are lower than this suggest the presence of older, reworked continental crust. ?? 1984 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

PERMEABILITY CHANGES IN CRYSTALLINE ROCKS DUE TO TEMPERATURE: EFFECTS OF MINERAL ASSEMBLAGE.

The change in permeability with time of granite, quartzite, anorthosite and gabbro was measured while these rocks were subjected to a temperature gradient. Permeability reductions of up to two orders of magnitude were observed, with the greatest reactions occurring in the quartzite. These changes are thought to be caused by dissolution of minerals at high temperatures, and redeposition of the dissolved material at lower temperatures. Quartz appears to be an important mineral in this self-sealing process. If very low permeability is desired around a nuclear waste repository in crystalline rocks, then a quartz-rich rock may be the most appropriate host.

Conference Paper↗

Geologic and aeromagnetic maps of the Fossil Ridge area and vicinity, Gunnison County, Colorado

This data set includes a GIS geologic map database of an Early Proterozoic metavolcanic and metasedimentary terrane extensively intruded by Early and Middle Proterozoic granitic plutons. Laramide to Tertiary deformation and intrusion of felsic plutons have created numerous small mineral deposits that are described in the tables and are shown on the figures in the accompanying text pamphlet. Also included in the pamphlet are numerous chemical analyses of igneous and meta-igneous bodies of all ages in tables and in summary geochemical diagrams. The text pamphlet also contains a detailed description of map units and discussions of the aeromagnetic survey, igneous and metmorphic rocks, and mineral deposits. The printed map sheet and browse graphic pdf file include the aeromagnetic map of the study area, as well as figures and photographs. Purpose: This GIS geologic map database is provided to facilitate the presentation and analysis of earth-science data for this region of Colorado. This digital map database may be displayed at any scale or projection. However, the geologic data in this coverage are not intended for use at a scale other than 1:30,000. Supplemental useful data accompanying the database are extensive geochemical and mineral deposits data, as well as an aeromagnetic map.

IMAP↗

Geologic setting and genesis of the Mule Canyon low-sulfidation epithermal gold-silver deposit, north-central Nevada

The Mule Canyon mine exploited shallow, low - sulfidation , epithermal Au-Ag deposits that lie near the west side of the Northern Nevada rift in northern Lander County, Nevada . Mule Canyon consists of six small deposits that contained premining reserves of about 8.2 Mt at an average grade of 3.81 g Au/tonne. It is an uncommon mafic end member of low - sulfidation Au-Ag deposits associated with tholeiitic bimodal basalt-rhyolite magmatism. The ore is hosted by a basalt-andesite eruptive center that formed between about 16.4 to 15.8 Ma during early mafic eruptions related to regionally extensive bimodal magmatism. Hydrothermal alteration and Au-Ag ores formed at about 15.6 Ma and were tightly controlled by north -northwest- to north -striking high-angle fault and breccia zones developed during rifting, emplacement of mafic dikes, and eruption of mafic lava flows. Hydrothermal alteration assemblages are zoned outward from fluid conduits in the sequence silica-adularia, adularia-smectite, smectite (intermediate argillic), and smectite-carbonate (propylitic). All alteration types contain abundant pyrite and/or marcasite ± arsenopyrite. Field relations indicate that silica-adularia alteration is superimposed on argillic and propylitic alteration. Little or no steam-heated acid-sulfate alteration is present, probably the result of a near-surface water table during hydrothermal alteration and ore deposition. Two distinct ore types are present at Mule Canyon : early replacement and later open-space filling. Replacement ores consist of disseminated and vesicle-filling pyrite, marcasite, and arsenopyrite in argillically altered or weakly silicified rocks. Ore minerals consist of Au-bearing arsenopyrite and arsenian pyrite overgrowths on earlier-formed pyrite and marcasite. Open-space filling ores include narrow stockwork quartz-adularia veins, banded and crustiform opaline and chalcedonic silica-adularia veins, silica-adularia cemented breccias, and sparse carbonate-pyrite and/or marcasite veins. Ore minerals consist mostly of electrum and Ag sulfide and selenide minerals, with minor to major amounts of pyrite, marcasite, and arsenopyrite, and local stibnite. Both types of ores have similar geochemical signatures, characterized by high Au, Ag, As, Sb, and Se contents, locally high Hg, Mo, Tl, and W contents, and low Cu, Pb, and Zn contents. Stable isotope data indicate that ore fluids consisted dominantly of meteoric water that evolved by deep circulation through Paleozoic sedimentary rocks at low water/rock ratios (about 1) and high temperatures (>200°C). Calculated isotopic compositions of ore fluids are δ 18 O H2O = -3 to -7 per mil, δD H2O = -107 to -124 per mil, δ 13 C CO2 = 0 to -6 per mil, and δ 34 S H2S = -3 to +8 per mil. The ore fluids obtained much of their H 2 S and CO 2 and probably scavenged ore metals and trace elements from the Paleozoic sedimentary rocks. Some H 2 S and CO 2 may have been derived from degassing Miocene magmas. Mule Canyon formed at shallow depths, probably about 100 m below the paleosurface. Ore fluids were dilute, nearly neutral in pH, reduced, H 2 S-rich, and CO 2 -bearing. Peak temperatures in ore zones reached 230° to 265°C at nearly lithostatic pressures when some crystalline quartz ± adularia precipitated, but most ore formed at temperatures <200°C at near hydrostatic pressures and was accompanied by precipitation of opaline and chalcedonic silica ± adularia ± calcite and dolomite. Deposition of gold in As-rich overgrowths on pyrite and/or marcasite in disseminated ores occurred owing to decreasing H 2 S in the ore fluids resulting from sulfidation reactions. Later electrum and Ag selenide precipitation in open spaces occurred owing to boiling, loss of H 2 S to the vapor phase, and cooling. Mule Canyon is similar to most other low - sulfidation Au-Ag deposits associated with Miocene tholeiitic bimodal basalt-rhyolite magmatism in the Great Basin, such as Sleeper, Midas, and Buckhorn. Major differences at Mule Canyon are the high Fe sulfide contents of some ores and altered wall rocks, the paucity of silicification, and the presence of only narrow and discontinuous gold -bearing siliceous veins. These differences primarily are due to the mafic composition of the host rocks. Mule Canyon differs from low - sulfidation deposits associated with subduction-related calc-alkaline porphyry intrusions, such as the Comstock lode, in that a much smaller proportion of water, salts, and metals was derived from crystallizing magmas.

Nevada↗

National geochronological and natural radioelement data bases

This CD-ROM contains both the National Geochronological Data Base [NGDB] and the Natural Radioelement Data Base [NRDB]. Supporting location, geologic, and reference information is provided for both data bases. The NGDB is a compilation of more than 30,000 individual published Pb-alpha, fission-track, K-Ar, Rb-Sr, U-Th-Pb, and Sm-Nd rock and mineral ages reported on approximately 18,000 dated samples from the United States. A program is provided to search the data files by latitude and longitude, state, analytical method, and age range. The NGDB is provided as quote-comma delimited files that can be entered into most commercial spreadsheet programs. The NRDB gives gamma-ray spectrometric analyses of the natural radioelements (U, Th, and K) for more than 8500 whole-rock samples obtained under the USGS Natural Radioelement Distribution Project. A program is provided to search the data files by state, keyword, U content, Th content, and K content.

Data Series↗

Rare earth element concentrations in geological and synthetic samples using synchrotron X-ray fluorescence analysis

The concentrations of rare earth elements (REEs) in specific mineral grains from the Bayan Obo ore deposit and synthetic high-silica glass samples have been measured by synchrotron X-ray fluorescence (SXRF) analysis using excitation of the REE K lines between 33 and 63 keV. Because SXRF, a nondestructive analytical technique, has much lower minimum detection limits (MDLs) for REEs, it is an important device that extends the in situ analytical capability of electron probe microanalysis (EPMA). The distribution of trace amounts of REEs in common rock-forming minerals, as well as in REE minerals and minerals having minor quantities of REEs, can be analyzed with SXRF. Synchrotron radiation from a bending magnet and a wiggler source at the National Synchrotron Light Source, Brookhaven National Laboratory, was used to excite the REEs. MDLs of 6 ppm (La) to 26 ppm (Lu) for 3600 s in 60-??m-thick standard samples were obtained with a 25-??m diameter wiggler beam. The MDLs for the light REEs were a factor of 10-20 lower than the MDLs obtained with a bending magnet beam. The SXRF REE concentrations in mineral grains greater than 25 ??m compared favorably with measurements using EPMA. Because EPMA offered REE MDLs as low as several hundred ppm, the comparison was limited to the abundant light REEs (La, Ce, Pr, Nd). For trace values of medium and heavy REEs, the SXRF concentrations were in good agreement with measurements using instrumental neutron activation analysis (INAA), a bulk analysis technique. ?? 1993.

Nuclear Instruments and Methods in Physics Researc↗

Non-pegmatitic resources of beryllium in United States

During the period from 1948 to 1950 the U.S. Geological Survey conducted a program of field and laboratory research w determine the mode of occurrence of beryllium in non-pegmatitic rocks and mineral deposits as part of the Beryllium Program of the Division of Raw Materials of the U.S. Atomic Energy Commission. Approximately 23 man months were spent in the field collecting samples from 146 localities in 15 states; a total of 680 samples were collected and analyzed for beryllium. Additional samples collected by the Geological Survey. U.S. Bureau of Mines, various state Geological Surveys and other institutions. and private companies were analyzed for beryllium. In total, the beryllium content of 1,238 samples from about 600 localities in the United States is compiled in the final report which is being prepared for publication by the U.S. Geological Survey. The main topics discussed are: uses and properties of beryllium; methods of analysis and mineralogy of beryllium; occurrence of beryllium in igneous, sedimentary and metamorphic rocks, pyrometasomatic and related deposits, vein deposits, and hot spring deposits; the genesis of beryllium deposits; and a description of the deposits examined. This abstract and table 1 summarize the more pertinent economic data. Beryllium is more abundant than arsenic, gold, silver, and molybdenum in the lithosphere, but its chemical and physical properties prohibit its concentration in minerals which are common w large commercial vein and replacement deposits. There are 29 minerals in which beryllium is an essential constituent but of these only beryl, mined from granite pegmatites, is an ore of beryllium., Beryl also occurs disseminated in granites and high-temperature veins. The other 28 minerals occur as rare constituents in syenite and granite pegmatites, granites, and pyrometasomatic deposits. Beryllium, as a trace constituent, has been detected in 49 minerals but recovery of the beryllium requires metallurgical methods as yet unknown.

Trace Elements Investigations↗

Determination of niobium in rocks by an isotope dilution spectrophotometric method

Rocks and minerals are fused with sodium peroxide in the presence of carrierfree 95 Nb. The fusion cake is leached with water and the precipitate dissolved in hydrofluoric-sulfuric acid mixture. Niobium is extracted into methyl isobutyl ketone and further purified by ion exchange. The amount of niobium is determined spectrophotometrically with 4-(2-pyridylazo)-resorcinol, and the chemical yield of the separations determined by counting 95 Nb. This procedure is faster and less sensitive to interferences than previously proposed methods for determining niobium in rocks. The high purity of the separated niobium makes the method applicable to nearly all matrices.

Analytica Chimica Acta↗

Development of industrial minerals in Colorado

Technology and engineering have helped make mining safer and cleaner for both humans and the environment. Inevitably, mineral development entails costs as well as benefits. Developing a mine is an environmental, engineering, and planning challenge that must conform to many Federal, State, and local regulations. Community collaboration, creative design, and best management practices of sustainability and biodiversity can be positive indicators for the mining industry. A better understanding of aesthetics, culture, economics, geology, climate, vegetation and wildlife, topography, historical significance, and regional land planning is important in resolving land-use issues and managing mineral resources wisely. Ultimately, the consuming public makes choices about product use (including water, food, highways, housing, and thousands of other items) that influence operations of the mineral industry. Land planners, resource managers, earth scientists, designers, and public groups have a responsibility to consider sound scientific information, society's needs, and community appeals in making smart decisions concerning resource use and how complex landscapes should change. An effort to provide comprehensive geosciences data for land management agencies in central Colorado was undertaken in 2003 by scientists of the U.S. Geological Survey and the Colorado Geological Survey. This effort, the Central Colorado Assessment Project, addressed a variety of land-use issues: an understanding of the availability of industrial and metallic rocks and minerals, the geochemical and environmental effects of historic mining activity on surface water and groundwater, and the geologic controls on the availability and quality of groundwater. The USDA Forest Service and other land management agencies have the opportunity to contribute to the sustainable management of natural aggregate and other mineral resources through the identification and selective development of mineral resources and the reclamation of mines on lands that they administer. The information in this Circular will help them carry out that task.

Colorado↗

Deep geothermal brine near Salton Sea, California

A well drilled for geothermal power near Salton Sea in Imperial Valley, Calif., is 5,232 feet deep; it is the deepest well in the world (1962) in a high-temperature hot spring area. In the lower half of the hole temperatures are too high to measure with available equipment, but are at loast 270°C, and may be as much as 370°C. For comparison, maximum temperature heretofore reported at depth (1962) for hot spring areas is 295°C. The well taps a very saline brine of Na-Ca-K-Cl type (about 185,000 ppm Cl) with exceptionally high potassium, and with the highest content of minor alkali elements known for natural waters; Fe, Mn, Zn, Pb, Cu, Ag, and some other metals are also exceptionally high. This brine may be connate, but present evidence favors a source in the magma chamber at depth that supplied late Quaternary rhyolite domes of the area. If the latter is correct, the brine is an undiluted magmatic water that is residual from the separation of a more volatile phase high in CO 2 , H 2 S, and with some alkali halides. Elsewhere, the hypothesized volatile phase may account for near-surface hot spring activity of most thermal areas of volcanic association. The residual brine of high salinity may ordinarily remain relatively deep in the volcanic systems because of high specific gravity and low content of volatiles, seldom appearing at the surface except in a greatly diluted form. The hot springs of Arima, Japan, may be a rare example of this type of magmatic water discharging at the surface in moderate concentration (Cl as much as 42,000 ppm). Independent evidence from fluid inclusions in minerals of high-temperature base-metal deposits also favors the existence of magmatic water high in Na, Ca, and Cl, and low in CO 2 and other volatile components. During a three-month production test several tons of material precipitated in the horizontal discharge pipe from the well. Amorphous silica with iron and manganese, and bornite are the dominant recognized components. This material contains the astonishingly high contents of about 20 percent copper, 2 percent silver, and notable sulfur, arsenic, bismuth, lead, antimony, and some other minor elements. Total quantities of all elements in the original whole brine are not yet known, but calculated amounts corresponding to 1 to 3 ppm of copper and 0.1 to 0.3 ppm of silver were precipitated from the brine to form the pipe deposits. The brine, therefore, may be man’s first sample of an « active » ore solution. Equally fascinating to many geologists is the possibility that in the lower part of the hole temperatures are so high and pressures are sufficient for young sedimentary rocks to be undergoing transformation into rocks with mineral assemblages of the greenschist facies of metamorphism. Drill cores from 4,400 to 5,000 feet in depth contain chlorite, albite, K-feldspar, epidote, mica, and quartz, with some indication of increase in metamorphic grade downward. Regional geological and geophysical studies favor a depth of about 20,000 feet to pre-Tertiary basement rocks in the general area. A shallow basement or local upfaulting of old metamorphic rocks are not likely possibilities for the thermal area.

California↗

Zinc, copper, and lead in mid-ocean ridge basalts and the source rock control on Zn/Pb in ocean-ridge hydrothermal deposits

The contents of Zn, Cu, and Pb in mid-ocean ridge basalts (MORB) and the MORB source-rock control on Zn/Pb in ocean-ridge hydrothermal deposits are examined. The values of Zn, Cu, and Pb for submarine mid-ocean ridge basalts (MORB) are, respectively (in ppm): average MORB—75, 75, and 0.7; West Valley, Juan de Fuca Ridge (JFR)—87, 64, and 0.5; southern JFR—120 and 0.5; and 21°N, East Pacific Rise (EPR)—73, 78, and 0.5. Values of Zn/Pb range from about 100–240 and Cu/ Pb from 100–156. In this study, Zn is found to correlate positively with TiO 2 + FeO (mean square of weighted deviates, MSWD, of 1.6 for JFR basalt), and inversely with Mg number (MSWD of 3.5). Therefore, contrary to statements in the literature that Zn should be compatible in MORB, Zn is a mildly incompatible element and must be enriched in the glass phase relative to olivine as Zn does not fit into the other major phenocryst phase, plagioclase. In the source of MORB, Zn likely is most enriched in oxides: spinel, magnetite, and titanomagnetite. Copper generally does not correlate well with other elements in most MORB data examined. When differentiation is dominated by olivine, Cu has a tendency to behave incompatibly (e.g., at Mg numbers > 70), but, overall, Cu shows some tendency towards being a compatible element, particularly along the Mid-Atlantic Ridge, a behavior presumably due to separation of sulfides in which Cu (but not Zn) is markedly enriched. Copper thus may be in dispersed sulfides in the source of MORB. Ocean ridges provide important data on source-rock controls for sulfide deposits because, in sediment-starved ridges, much is known about the possible source rocks and mineralization is presently occurring. In contrast to Zn/Pb ~5 in continental hot Cl-rich brines, Zn/Pb in the hottest sediment-starved ridge black smoker hydrothermal fluids at 21 °N, EPR is about 110, similar to local MORB (145), but Cu/Pb is closer to 30, possibly due to subsurface deposition of Cu. At the JFR, the best value of Zn/Pb in the hydrothermal fluids is about 175, again similar to local MORB (240), but Cu is very low in the fluids that are at temperatures less than 300°C. The large MORB-like Zn/Pb in the hottest black-smoker fluids suggests a source-rock control for the metals that prohibits significant galena in the black-smoker deposits of sediment-starved ridges. In contrast, exhalative deposits on sediment-swamped ridges have significant galena; its presence is suggestive of Pb derivation from sediments, an origin supported by Pb isotope studies of LeHuray and colleagues in 1988.

Geochimica et Cosmochimica Acta↗

The United States Polar Rock Repository: A geological resource for the Earth science community

The United States Polar Rock Repository (USPRR) is a U. S. national facility designed for the permanent curatorial preservation of rock samples, along with associated materials such as field notes, annotated air photos and maps, raw analytic data, paleomagnetic cores, ground rock and mineral residues, thin sections, and microfossil mounts, microslides and residues from Polar areas. This facility was established by the Office of Polar Programs at the U. S. National Science Foundation (NSF) to minimize redundant sample collecting, and also because the extreme cold and hazardous field conditions make fieldwork costly and difficult. The repository provides, along with an on-line database of sample information, an essential resource for proposal preparation, pilot studies and other sample based research that should make fieldwork more efficient and effective. This latter aspect should reduce the environmental impact of conducting research in sensitive Polar Regions. The USPRR also provides samples for educational outreach. Rock samples may be borrowed for research or educational purposes as well as for museum exhibits.

Open-File Report↗

Geologic map of the Ahankashan-Rakhna basin, Badghis, Ghor, and Herat Provinces, Afghanistan, modified from the 1974 original map compilation of Y.I. Shcherbina and others

This geologic map of the Ahankashan-Rakhna basin, Afghanistan, is a redrafted and modified version of the Geological map of the area of Ahankashan-Rakhna basin, scale 1:50,000 and Geological map of the Ahankashan area with data on mineral resources, scale 1:12,000 from Shcherbina and others (1974) (Soviet report no. 0822). That unpublished Soviet report contains the original maps and cross sections, which were prepared in cooperation with the Ministry of Mines and Industries of the Republic of Afghanistan in Kabul during 1974 under contract no. 50728 (Technoexport, USSR). The redrafted maps and cross sections in this USGS publication illustrate the geology of the Ahankashan and Rakhna basins, located within Badghis, Ghor, and Herat Provinces. The Ahankashan and Rakhna prospect area is one of several gold and copper deposits within west-central Afghanistan. Here, various felsic to intermediate igneous porphyries intrude Lower Triassic to lower Paleogene sedimentary rocks, producing mineral and ore-bearing zones related to hydrothermal alteration, skarns, silicification, and crushing (brecciation). Mineralized skarns contain assemblages such as magnetite, magnetite-hematite, epidote-hematite, and epidote-garnet, as well as disseminations of chalcopyrite, covellite, chalcocite, cuprite, malachite, and azurite. Gold mineralization is mainly associated with zones of crushing along faults, and with small silicified igneous veins within granite and quartz porphyry.

Badghis, Ghor, Herat↗

Book review: Economic geology: Principles and practice: Metals, minerals, coal and hydrocarbons—Introduction to formation and sustainable exploitation of mineral deposits

This volume, available in both hardcover and paperback, is an English translation of the fifth edition of the German language text Mineralische und Energie-Rohstoffe. The book provides an extensive overview of natural resources and societal issues associated with extracting raw materials. The comprehensive list of raw materials discussed includes metals, industrial minerals, coal, and hydrocarbons. The book is divided into four parts: (1) “Metalliferous ore deposits,” (2) “Nonmetallic minerals and rocks,” (3) “Practice of economic geology,” and (4) “Fossil energy raw materials—coal, oil, and gas.” These sections are bound by a brief introduction and an extensive list of up-to-date references as well as an index. Each chapter begins with a concise synopsis and concludes with a summary that contains useful suggestions for additional reading. All figures are grayscale images and line drawings; however, several have been grouped together and reproduced as color plates. Also included is a companion website ( www.wiley.com/go/pohl/geology ) that contains additional resources, such as digital copies of figures, tables, and an expanded index, all available for download in easy-to-use formats. Economic Geology: Principles and Practice: Metals, Minerals, Coal and Hydrocarbons—Introduction to Formation and Sustainable Exploitation of Mineral Deposits. Walter l. Pohl. 2011. Wiley-Blackwell. Pp. 663. ISBN 978-1-4443-3663-4 (paperback).

Economic Geology↗

ASTER spectral analysis and lithologic mapping of the Khanneshin carbonatite volcano, Afghanistan

Advanced Spaceborne Thermal and Reflection Radiometer (ASTER) data of the early Quaternary Khanneshin carbonatite volcano located in southern Afghanistan were used to identify carbonate rocks within the volcano and to distinguish them from Neogene ferruginous polymict sandstone and argillite. The carbonatitic rocks are characterized by diagnostic CO 3 absorption near 11.2 μm and 2.31–2.33 μm, whereas the sandstone, argillite, and adjacent alluvial deposits exhibit intense Si-O absorption near 8.7 μm caused mainly by quartz and Al-OH absorption near 2.20 μm due to muscovite and illite. Calcitic carbonatite was distinguished from ankeritic carbonatite in the short wave infrared (SWIR) region of the ASTER data due to a slight shift of the CO 3 absorption feature toward 2.26 μm (ASTER band 7) in the ankeritic carbonatite spectra. Spectral assessment using ASTER SWIR data suggests that the area is covered by extensive carbonatite flows that contain calcite, ankerite, and muscovite, though some areas mapped as ankeritic carbonatite on a preexisting geologic map were not identified in the ASTER data. A contact aureole shown on the geologic map was defined using an ASTER false color composite image (R = 6, G = 3, B = 1) and a logical operator byte image. The contact aureole rocks exhibit Fe 2+ , Al-OH, and Fe, Mg-OH spectral absorption features at 1.65, 2.2, and 2.33 μm, respectively, which suggest that the contact aureole rocks contain muscovite, epidote, and chlorite. The contact aureole rocks were mapped using an Interactive Data Language (IDL) logical operator. A visible through short wave infrared (VNIR-SWIR) mineral and rock-type map based on matched filter, band ratio, and logical operator analysis illustrates: (1) laterally extensive calcitic carbonatite that covers most of the crater and areas northeast of the crater; (2) ankeritic carbonatite located southeast and north of the crater and some small deposits located within the crater; (3) agglomerate that primarily covers the inside rim of the crater and a small area west of the crater; (4) a crater rim that consists mostly of epidote-chlorite-muscovite–rich metamorphosed argillite and sandstone; and (5) iron (Fe 3+ ) and muscovite-illite–rich rocks and iron-rich eolian sands surrounding the western part of the volcano. The thermal infrared (TIR) rock-type map illustrates laterally extensive carbonatitic and mafic rocks surrounded by quartz-rich eolian and fluvial reworked sediments. In addition, the combination of VNIR, SWIR, and TIR data complement one another in that the TIR data illustrate more laterally extensive rock types and the VNIR-SWIR data distinguish more specific varieties of rocks and mineral mixtures.

Geosphere↗

Actualistic models of mantle metasomatism documented in a composite xenolith from Dish Hill, California

Major and trace-element whole rock and mineral variations in composite hornblendite-peridotite xenolith Ba-2-1, from Dish Hill, CA, are due to a single event of metasomatism in the mantle. The hornblendite is the crystallized selvage of a dike conduit charged with incompatible-element-enriched hydrous mafic magma. The magma infiltrated the refractory peridotite wallrock, reacted with its constituent minerals, and simultaneously deposited amphibole. The systematic data from this study show considerable variation in isotopic values and trace elements. These data provide insight into a mantle process that was defined previously from samples without context, lacking evidence about the number or source of metasomatic events. In the contact zone of Ba-2-1, peridotite is enriched in Fe, Ti, CO 2 ) and H 2 O; clinopyroxene and amphibole also are enriched in Fe and Ti, but clinopyroxene appears slightly depleted in CaO. Compared to chondrites, peridotite, clinopyroxene, and probably amphibole are enriched in light rare earth (LREE cn ) and other incompatible trace elements. Values of 87 Sr 86 Sr "> 87 Sr 86 Sr and 143 Nd 144 Nd "> 143 Nd 144 Nd in the contact zone are close to isotopic equilibrium with the dike. Whole rock and constituent clinopyroxene compositions change to those of refractory peridotite with distance from the contact. These compositional variations were modelled using Gresens' equation for whole-rock major and minor elements, and calculations for isotopic ratios and REEs, which emulate the effects of Chromatographic fractionation. The choice of endmembers was restricted to compositions actually present in mantle samples from Dish Hill. Model results indicate that: 1. the variations can be explained as the result of a single metasomatic event, probably a single pulse of previously fractionated liquid; 2. the ratio of total interacting liquid to peridotite was at least 1:3 by weight in the contact zone; and 3. the composition of the metasomatic liquid changed progressively as it infiltrated beyond that zone. The small distance over which variations occur is due to the small amount of liquid that infiltrated. Only in the contact zone was peridotite wallrock saturated by a liquid composition similar to the dike. Comparison of the Ba-2-1 data with those of another xenolith from Dish Hill suggests that the compositional variations of mantle metasomatism result from both the compositional contrast between the metasomatizing liquid and wallrock and the relative abundances of each. Compositional and volumetric variations of mantle partial melts and their fractionates, and repeated events of melting and reaction in contiguous mantle, can create broad ranges of metasomatic “signatures” from the same process.

California↗