Search USGS⌕ Search

SEARCH · Search USGS

Results for “Natural Selections”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 433 records · Page 24Linked to original sources

Selected techniques for monitoring water movement through unsaturated alluvium during managed aquifer recharge

Managed aquifer recharge is used to augment natural recharge to aquifers. It can be used to replenish aquifers depleted by pumping or to store water during wetter years for withdrawal during drier years. Infiltration from ponds is a commonly used, inexpensive approach for managed aquifer recharge. At some managed aquifer-recharge sites, the time when infiltrated water arrives at the water table is not always clearly shown by water-level data. As part of site characterization and operation, it can be desirable to track downward movement of infiltrated water through the unsaturated zone to identify when it arrives at the water table.

California↗

The influence of local- and landscape-level factors on wetland breeding birds in the Prairie Pothole Region of North and South Dakota

We examined the relationship between local- (wetland) and landscape-level factors and breeding bird abundances on 1,190 depressional wetlands in the Prairie Pothole Region of North and South Dakota during the breeding seasons in 1995–97. The surveyed wetlands were selected from five wetland classes (alkali, permanent, semipermanent, seasonal, or temporary), two wetland types (natural or restored), and two landowner groups (private or Federal). We recorded 133 species of birds in the surveyed wetlands during the 3 years. We analyzed the nine most common (or focal) species (that is, species that were present in 25 percent or more of the 1,190 wetlands): the Red-winged Blackbird ( Agelaius phoeniceus ), Blue-winged Teal ( Anas discors ), Mallard (Anas platyrhynchos ), American Coot ( Fulica americana ), Gadwall ( Anas strepera ), Common Yellowthroat ( Geothlypis trichas ), Yellow-headed Blackbird ( Xanthocephalus xanthocephalus ), Northern Shoveler ( Anas clypeata ), and Savannah Sparrow ( Passerculus sandwichensis ). Our results emphasize the ecological value of all wetland classes, natural and restored wetlands, and publicly and privately owned wetlands in this region, including wetlands that are generally smaller and shallower (that is, temporary and seasonal wetlands) and thus most vulnerable to drainage. Blue-winged Teal, Northern Shoveler, Gadwall, Common Yellowthroat, and Red-winged Blackbird had higher abundances on Federal than on private wetlands. Abundances differed among wetland classes for seven of the nine focal species: Blue-winged Teal, Northern Shoveler, Mallard, American Coot, Common Yellowthroat, Yellow-headed Blackbird, Red-winged Blackbird. American Coot had higher abundances on restored wetlands than on natural wetlands overall, and Gadwall and Common Yellowthroat had higher abundances on private restored wetlands than on private natural wetlands. The Common Yellowthroat was the only species that had higher abundances on restored private wetlands than on restored Federal wetlands. After adjusting for wetland size and the date and location of the surveys, our results demonstrated that incorporating wetland- and landscape-level factors in models can improve our ability to predict abundances of wetland birds in this region. The top model for eight of the nine focal species included wetland- and landscape-level factors, whereas the best model for Blue-winged Teal included only wetland-level attributes. Although local factors (for example, percent open water or emergent vegetation) in individual wetlands are important factors for some wetland breeding birds, it is important that natural resource managers consider landscape-level factors beyond the local factors in their conservation plans for wetland birds.

North Dakota, South Dakota↗

Surface water of Muddy Boggy River basin in south-central Oklahoma

This report summarizes basic hydrologic data of the surface water resources of Muddy Boggy River basin, and by analysis and interpretation, presents certain streamflow characteristics at specified points in the basin. Muddy Boggy River has a drainage area of 2,429 square miles. The climate is moist subhumid and the annual precipitation averages about 39 inches. Gross annual lake evaporation averages 54 inches. The average annual discharge at the gaging stations for the period 1938-62 was 24,000 acre-feet for Chickasaw Creek near Stringtown; 72,000 acre-feet for McGee Creek near Stringtown; 671,800 acre-feet for Muddy Boggy Creek near Farris; and 358,200 acre-feet for Clear Boggy Creek near Caney. Flow-duration curves of daily discharge have been developed to show the percentage of time various rates of discharge have been equaled or exceeded. Procedures for determining the frequency of annual floods at any point in the basin are given. Low-flow frequency curves that define the recurrence intervals of 7, 14, 30, 60, and 120 day mean flows have been prepared for two gaging stations. Curves showing the relation of measured discharge at the low-flow partial-record stations to the daily mean discharge at a base gaging station are presented. Discharge measurements made in February 1963 at selected sites show the areal distribution of low flow. The storage requirements to supplement natural flows have been prepared for two gaging-stations sites. The chemical quality of surface water of Muddy Boggy River basin varies from place-to-place during base flow periods. Limestone and dolomite outcrops and oilfield brines affect water quality in some areas. Water of North Boggy Creek, McGee Creek, and their tributaries contains less than 100 ppm (parts per million) dissolved solids. Water of other streams in Muddy Boggy River basin has a higher dissolved-solids content, but the content does not exceed 500 ppm. Water of Muddy Boggy River basin is usable for domestic, irrigation, and most industrial purposes. Softening of water from some streams may be desirable, however.

Open-File Report↗

Chemical correlation of some late Cenozoic tuffs of Northern and Central California by neutron activation analysis of glass and comparison with X-ray fluorescence analysis

Glasses separated from several dacitic and rhyolitic late Cenozoic tuffs of northern and central California were analyzed by neutron activation for more than 43 elemental abundances. Eighteen elements--scandiurn, manganese, iron, zinc, rubidium, cesium, barium, lanthanum, cerium, samarium, europium, terbiurn, dysprosiurn, ytterbiurn, hafniurn, tantalurn, thorium and uranium--were selected as most suitable for purposes of chemical correlation on the basis of their natural variability in silicic tuffs and the precision obtainable in analysis. Stratigraphic relations between tuffs and replicate chemical analyses on individual tuffs make it possib1e to calibrate a quantitative parameter, the similarity coefficient, which indicates the degree of correlation for the tuffs studied. The highest similarity coefficient (0.99) was obtained for analyses of two tuffs (potassium-argon dated at about' 6.0 m.y.) exposed in the Merced(?) and Petaluma Formations of Sonoma County, which represent different paleoenvironments, shallow-water marine and fresh water or brackish marine, respectively. Corre1ation of these formations on the basis of criteria other than tephrochronoloqy would be difficult. Results of neutron activation analysis in general confirm earlier correlations made on the basis of analysis by X-ray fluorescence but also make it possible to resolve small compositional differences between chemically simi1ar tuffs in stratigraphic proximity. The Lawlor Tuff (potassium-argon dated at about 4.0 m.y.) is identified at two new localities: in a core sample obtained from a bore hole east of Suisun Bay, and from the Kettleman Hills of western San Joaquin Valley. This identification permits correlation of the uppermost part of the marine Etchegoin Formation in the San Joaquin Valley with the continental Livermore Gravels of Clark, the Tassajara Formation, and the upper part of the Sonoma Volcanics in the cel1tral Coast Ranges of California. A younger tuff near the top of the marine San Joaquin Formation in the Kettleman Hills has been identified at both new 1oca1ities .

Professional Paper↗

Hydrogeology and water quality of sand and gravel aquifers in McHenry County, Illinois, 2009–14, and comparison to conditions in 1979

Baseline conditions for the sand and gravel aquifers (groundwater) in McHenry County, Illinois, were assessed using data from a countywide network of 44 monitoring wells collecting continuous water-level data from 2009–14. In 2010, water-quality data were collected from 41 of the monitoring wells, along with five additional monitoring wells available from the U.S. Geological Survey National Water Quality Assessment Program. Periodic water-quality data were collected from 2010–14 from selected monitoring wells. The continuous water-level data were used to identify the natural and anthropogenic factors that influenced the water levels at each well. The water-level responses to natural influences such as precipitation, seasonal and annual variations, barometric pressure, and geology, and to anthropogenic influences such as pumping were used to determine (1) likely hydrogeologic setting (degree of aquifer confinement and interconnections) that, in part, are related to lithostratigraphy; and (2) areas of recharge and discharge related to vertical flow directions. Water-level trends generally were determined from the 6 years of data collection (2009–14) to infer effects of weather variability (drought) on recharge. Precipitation adds an estimated 2.4 inches per year of recharge to the aquifer. Some of this recharge is subsequently discharged to streams and some is discharged to supply wells. A few areas in the eastern half of the county had higher average recharge rates, indicating a need for adequate protection of these recharge areas. Downward vertical flow gradients in upland areas indicate that recharge to the confined aquifer units occurs near upland areas. Upward vertical flow gradients in lowland areas indicate discharge at locations of surface water and groundwater interaction (wetlands, ponds, and streams). Monitoring wells were sampled for major and minor ions, metals, and nutrients and a subset of wells was sampled for trace elements, dissolved gases, pesticides, and volatile organic compounds. The results were compared to health ‑ based and aesthetically based standards, which include the U.S. Environmental Protection Agency Maximum Contaminant Level (EPA MCL), and EPA Secondary Maximum Contaminant Levels (SMCL), as well as EPA Health-based Standards Drinking Water Advisories. Health‑based standards were exceeded for arsenic in 22 percent, sodium in 20 percent, and nitrates in 2 percent of the monitoring wells sampled. Aesthetically based standards were exceeded for total dissolved solids in 33 percent, chloride in 11 percent, iron in 85 percent, and manganese in 30 percent of the wells sampled. Many of these same constituents, such as arsenic, iron, and manganese, are naturally occurring but become elevated in areas that have anoxic, mixed, and suboxic conditions. Some areas of potential vulnerability to anthropogenic-sourced constituents in the sand and gravel aquifers were evidenced by trace amounts of volatile organic compounds and pesticides detected in water-quality samples from shallow wells (total depth less of than 46 feet below land surface) near urban settings, and by the detection of elevated major ions (chloride, sodium, magnesium, and calcium) associated, in part, with road-salt applications. Source analysis for chloride indicates mixtures of road salt, water softeners, and sewage. Continuously measured specific conductance values were used as a surrogate for continuously measured chloride concentrations in the groundwater. The estimated chloride concentrations generally were highest in spring and lowest in summer, and occasionally peak during spring melt. Overall, the range of concentrations varied depending on the local thickness and hydraulic conductivity of the aquifer. Water levels and water quality from the countywide groundwater monitoring network were compared to water levels and water-quality results in 1979 from a previous U.S. Geological Survey study. Potentiometric surface maps show areas with inferred decreases of water levels near the southern and southeastern areas of McHenry County. Significant increases were noted for total dissolved solids and specific conductance. Chloride concentrations increased as much as 521 percent in three of six wells resampled in 2015 from the previous study.

Illinois↗

Water resources data of the Seward area, Alaska

Favorable geohydrologic conditions in the Seward area provide several choices for developing additional water supplies. Abundant stream runoff and the prospects for expanded well-field development in the Jap Creek alluvial fan, as well as other similar fans, allow a selection of future water sources based on factors other than the availability of the natural resource. Although water in both streams and deep aquifers is of good potable quality, ground water has the inherent advantages of being free of suspended sediment, of being warmer during winter months, and of being less vulnerable to pollution. Shallow infiltration galleries constructed along the alluvial-fan reaches of some streams should provide large volumes of water for public supply. A potential exists at Seward for serious flooding of the alluvial fans by the major streams, for coastal flooding by bay waters resulting from storm-driven waves or tsunamis, and for pollution of shallow ground water by onsite sewage disposal.

Alaska↗

Testing for genetic differences in survival and growth between hatchery and wild Chinook salmon from Warm Springs River, Oregon (Study sites: Warm Springs Hatchery and Little White Salmon River; Stocks: Warm Springs hatchery and Warm Springs River wild; Year classes: 1992 and 1996)

The program at Warm Springs National Fish Hatchery in north - central Oregon was initiated with spring Chinook salmon Oncorhynchus tshawytscha from the Warm Springs River. Managers included wild fish in the broodstock most years and avoided artificial selection to minimize genetic divergence from the wild founder population. We tested for genetic differences in survival and growth between the hatchery and wild populations to ascertain whether this goal has been achieved. Progeny of hatchery x hatchery (HH), hatchery female x wild male (HW), and wild x wild (WW) crosses were genetically marked at the sSOD - 1* allozyme locus and released together as unfed fry in hatchery ponds in 1992 and 1996 and in the Little White Salmon River, in south - central Washington, in 1996. Fish were evaluated to returning adult at the hatchery and over their freshwater residence of 16 months in the stream. The three crosses differed on several measures including survival to outmigration in the stream (WW>HH>HW) and juvenile growth in the hatchery (1992 year - class; WW>HW>HH); however, results may have been confounded. The genetic marks were found to differentially effect survival in a companion study (HH mark favored over WW mark; HW mark intermediate). Furthermore, HW survival in the current study was neither intermediate, as would be expect ed from additive genetic effects, nor similar to that of HH fish as would be expected from maternal effects since HW and HH fish were maternal half - siblings. Finally, the unexpected performance of HW fish precludes ruling out maternal differences between hatchery and wild mothers as the cause of differences between HH and WW fish. The key finding that survival of HH fish in a stream was 0.91 that for WW fish, indicating a small loss of fitness for natural rearing in the hatchery population, is valid only if three conditions hold: (1) any selection on the genetic marks was in the same direction as in the companion study, (2) lower survival in the stream for HW than for HH fish resulted because some HW families were genetically atypical, not from problems w ith either pure type, and (3) lower survival for HH than for WW fish was not due to maternal effects. Although all three conditions had support, none of it was conclusive. This study provides only suggestions, not definitive answers for the primary quest ion of whether the hatchery population has diverged genetically from its wild founder population in fitness - related traits.

Oregon↗

USFWS selected geographic analyses

The geographic information system (GIS) used by the National Wetlands Research Center (NWRC) of the U.S. Fish and Wildlife Service has been valuable in assisting natural resource managers in planning and managing coastal fish and wildlife resources. In the past 5 years, NWRC has conducted about 60 studies employing this technology. Applications have ranged from simple natural resource inventories to documentation of trends in wetland changes and complex predictive modeling of impacts of harbor expansion on biological resources. Maps, tables, and data bases from these studies have been presented before local, State, and Congressional committees as well as numerous scientific and public organizations. This paper describes and summarizes selected GIS projects related to resource inventories, analyses of wetland change, and cartographic modeling of coastal areas of the United States.

Conference Paper↗

Ecosystem history: Terrestrial and fresh-water ecosystems of southern Florida

Introduction Plant and animal communities of the historic Everglades have undergone striking changes over the last few decades, including declines in wading bird populations, invasion by exotic (non-native) plant and animal species, and areal expansion of cattails into sawgrass marshes. Many of these changes have been attributed to human activities in the region, and efforts are underway to restore the Everglades to a more pristine state. Restoration plans include alteration of the present levee and canal system that controls water flow throughout southern Florida and changes in agricultural and land development activities. However, can we be sure that the observed changes are related to human practices rather than representing an extreme in the natural variability of the system? This question should be answered before changing current land-use practices to alleviate environmental concerns. To address this question, it is necessary to look at patterns of floral and faunal change over the last century as well as over the last few millennia. This project aims to reconstruct floral and faunal composition at selected time intervals throughout southern Florida to determine: 1) detailed biotic changes over the last 150 years; 2) the natural range of biotic variability over the last few thousand years; and 3) determine whether any cause-and-effect relationships exist between biotic and environmental changes. Such questions are being addressed by scientists in the South Florida Initiative of the Ecosystem Program at the U.S. Geological Survey.

Florida↗

Water-quality characteristics for selected streams in Lawrence County, South Dakota, 1988-92

During the 1980’s, significant economic development and population growth began to occur in Lawrence County in the northern part of the Black Hills of western South Dakota. Rising gold prices and heap-leach extraction methods allowed the economic recovery of marginal gold ore deposits, resulting in development of several large-scale, open-pit gold mines in Lawrence County. There was increasing local concern regarding potential impacts on the hydrologic system, especially relating to the quantity and quality of water in the numerous streams and springs of Lawrence County. In order to characterize the water quality of selected streams within Lawrence County, samples were collected from 1988 through 1992 at different times of the year and under variable hydrologic conditions. During the time of this study, the Black Hills area was experiencing a drought; thus, most samples were collected during low-flow conditions. Streamflow and water-quality characteristics in Lawrence County are affected by both geologic conditions and precipitation patterns. Most streams that cross outcrops of the Madison Limestone and Minnelusa Formation lose all or large part of their streamflow to aquifer recharge. Streams that are predominantly spring fed have relatively stable streamflow, varying slightly with dry and wet precipitation cycles. Most streams in Lawrence County generally have calcium magnesium bicarbonate type waters. The sites from the mineralized area of central Lawrence County vary slightly from other streams in Lawrence County by having higher concentrations of sodium, less bicarbonate, and more sulfate. False Bottom Creek near Central City has more sulfate than bicarbonate. Nitrogen, phosphorous, and cyanide concentrations were at or near the laboratory reporting limits for most sites and did not exceed any of the water-quality standards. Nitrite plus nitrate concentrations at Annie Creek near Lead, Whitetail Creek at Lead, Squaw Creek near Spearfish, and Spearfish Creek below Robison Gulch were somewhat higher than at other sites. Mining activity, agricultural activity, and domestic development are possible sources of nitrogen to the streams. Increased mining activities were identified as the probable cause of increased nitrogen concentrations in Annie Creek. In the mineralized area of the northern Black Hills, detectable concentrations of trace elements are common in stream water, occasionally exceeding beneficial-use and aquatic-life criteria. In addition, many basins have been disturbed by both historical and recent mining operations and cleanup activities. The maximum dissolved arsenic concentration at Annie Creek near Lead (48 micrograms per liter) approached the current arsenic drinking-water standard. Concentrations at or greater than 5 micrograms per liter were found in samples from Annie Creek near Lead, Spearfish Creek above Spearfish, Whitetail Creek at Lead, and False Bottom Creek near Spearfish. Bear Butte Creek near Deadwood had one sample with a dissolved copper concentration that exceeded acute and chronic aquatic-life criteria. Bear Butte Creek near Deadwood had several manganese concentrations that exceeded the secondary maximum contaminant level of 50 micrograms per liter. Bed-sediment and water-quality data from selected sites in small drainage basins were used to determine if factors such as pH, arsenic concentrations in bed sediments, and calcite saturation control dissolved arsenic concentrations. Arsenic solubility is controlled by adsorption, mainly on ferrihydrite. In addition, adsorption/desorption of arsenic is controlled by the pH of the stream, with high arsenic concentrations appearing only at higher pH conditions (above 8). There are significant arsenic sources available to almost all the small streams of the northern Black Hills mining area, but arsenic is less mobile in streams that are not influenced to the higher pH values by calcite. Streams where arsenic is more mobile have lower iron concentrations in their bed sediments, and they have relatively high concentrations of calcite Additional water-quality data have been collected as part of other studies or monitoring programs by the South Dakota Department of Environment and Natural Resources, U.S. Environmental Protection Agency, U.S. Forest Service, and the U.S. Geological Survey. Summaries of selected data from these other sources are included as additional information.

South Dakota↗

Rapid Data Delivery System (RDDS)

Since the start of the active 2000 summer fire season, the U. S. Geological Survey (USGS) Rocky Mountain Geographic Science Center (RMGSC) has been actively engaged in providing crucial and timely support to Federal, State, and local natural hazards monitoring, analysis, response, and recovery activities. As part of this support, RMGSC has developed the Rapid Data Delivery System (RDDS) to provide emergency and incident response teams with timely access to geospatial data. The RDDS meets these needs by combining a simple web-enabled data viewer for the selection and preview of vector and raster geospatial data with an easy to use data ordering form. The RDDS viewer also incorporates geospatial locations for current natural hazard incidents, including wildfires, earthquakes, hurricanes, and volcanoes, allowing incident responders to quickly focus on their area of interest for data selection.

Fact Sheet↗

Natural-channel-design restorations that changed geomorphology have little effect on macroinvertebrate communities in headwater streams

Stream restorations that increase geomorphic stability can improve habitat quality, which should benefit selected species and local aquatic ecosystems. This assumption is often used to define primary restoration goals; yet, biological responses to restoration are rarely monitored or evaluated methodically. Macroinvertebrate communities were inventoried at 6 study reaches within 5 Catskill Mountain streams between 2002 and 2006 to characterize their responses to natural-channel-design (NCD) restoration. Although bank stability increased significantly at most restored reaches, analyses of variation showed that NCD restorations had no significant effect on 15 of 16 macroinvertebrate community metrics. Multidimensional scaling ordination indicated that communities from all reach types within a stream were much more similar to each other within any given year than they were in the same reaches across years or within any type of reach across streams. These findings indicate that source populations and watershed-scale factors were more important to macroinvertebrate community characteristics than were changes in channel geomorphology associated with NCD restoration. Furthermore, the response of macroinvertebrates to restoration cannot always be used to infer the response of other stream biota to restoration. Thus, a broad perspective is needed to characterize and evaluate the full range of effects that restoration can have on stream ecosystems.

Catskill Mountains↗

Trace element, semivolatile organic, and chlorinated organic compound concentrations in bed sediments of selected streams at Fort Gordon, Georgia, February-April 2010

A spatial survey of streams was conducted from February to April 2010 to assess the concentrations of major ions, selected trace elements, semivolatile organic compounds, organochlorine pesticides, and polychlorinated biphenyls associated with the bed sediments of surface waters at Fort Gordon military installation near Augusta, Georgia. This investigation expanded a previous study conducted in May 1998 by the U.S. Geological Survey, in cooperation with the U.S. Department of the Army Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, that evaluated the streambed sediment quality of selected surface waters at Fort Gordon. The data presented in this report are intended to help evaluate bed sediment quality in relation to guidelines for the protection of aquatic life, and identify temporal trends in trace elements and semivolatile organic compound concentrations at streambed sites previously sampled. Concentrations of 34 major ions and trace elements and 102 semivolatile organic, organochlorine pesticide, and polychlorinated biphenyl compounds were determined in the fine-grained fraction of bed sediment samples collected from 13 of the original 29 sites in the previous study, and 22 additional sites at Fort Gordon. Three of the sites were considered reference sites as they were presumed to be located away from potential sources of contaminants and were selected to represent surface waters flowing onto the fort, and the remaining 32 nonreference sites were presumed to be located within the contamination area at the fort. Temporal trends in trace elements and semivolatile organic compound concentrations also were evaluated at 13 of the 32 nonreference sites to provide an assessment of the variability in the number of detections and concentrations of constituents in bed sediment associated with potential sources, accumulation, and attenuation processes. Major ion and trace element concentrations in fine-grained bed sediment samples from most nonreference sites exceeded concentrations in samples from reference sites at Fort Gordon. Bed sediments from one of the nonreference sites sampled contained the highest concentrations of copper and lead with elevated levels of zinc and chromium relative to reference sites. The percentage change of major ions, trace elements, and total organic carbon that had been detected at sites previously sampled in May 1998 and current bed sediment sites ranged from -4 to 8 percent with an average percentage change of less than 1 percent. Concentrations of major ions and trace elements in bed sediments exceeded probable effect levels for aquatic life (based on the amphipod Hyalella azteca) established by the U.S. Environmental Protection Agency at 46 and 69 percent of the current and previously sampled locations, respectively. The greatest frequency of exceedances for major ions and trace elements in bed sediments was observed for lead. Concentrations of semivolatile organic compounds, organochlorine pesticides, and polychlorinated biphenyls were detected in bed sediment samples at 94 percent of the sites currently sampled. Detections of these organic compounds were reported with greater frequency in bed sediments at upstream sampling locations, when compared to downstream locations. The greatest number of detections of these compounds was reported for bed sediment samples collected from two creeks above a lake. The percentage change of semivolatile organic compounds detected at previously sampled and current bed sediment sites ranged from -68 to 100 percent with the greatest percentage increase reported for one of the creeks above the lake. Concentrations of semivolatile organic compounds and polychlorinated biphenyls in bed sediments exceeded aquatic life criteria established by the U.S. Environmental Protection Agency at three sites. Contaminant compounds exceeding aquatic life criteria included fluoranthene, phenanthrene, anthracene, benzo(a)anthracene

Georgia↗

Arsenic concentration and selected geochemical characteristics for ground water and aquifer materials in southeastern Michigan

Fifty-six private wells, 20 public wells and 38 monitoring wells in ten counties in southeastern Michigan were sampled to determine the concentration of naturally-occurring arsenic and specific geochemical parameters. The majority of ground water samples were analyzed for pH, dissolved oxygen, oxidation/reduction potential, specific conductance, major ions, dissolved and suspended organic carbon, and arsenic. Selected samples were analyzed for minor elements, nutrients, the isotope ratio of carbon and the concentration of tritium. The Mississippian Marshall Sandstone comprises a major aquifer in southeastern Michigan. To compare the lithology of the Marshall Aquifer to water chemistry, two new wells were drilled through the Marshall Sandstone to the underlying Coldwater Shale. Depth-specific bedrock and water samples were collected from these wells. For public and private drinking-water wells, the lowest concentration detected by USGS analysis was <1 microgram per liter and the highest was 220 micrograms per liter. Arsenic concentrations near or exceeding the current USEPA standard of 50 micrograms per liter occurred in ground water from each of the major aquifers in the study area. In the two newly-drilled wells, the lowest concentration detected by the USGS was <1 microgram per liter at about 350 ft below land surface and the highest concentration of 140 micrograms per liter was detected at around 50 ft below land surface. The data from this study may be used to indicate well characteristics and water chemistry factors that are related to arsenic in ground water in southeastern Michigan.

Michigan↗

Plan for assessment of the occurrence, status, and distribution of volatile organic compounds in aquifers of the United States

The occurrence of volatile organic compounds (VOCs) in water is of national concern because of their relatively high aqueous solubility, mobility, and persistence, because many are known or suspected carcinogens, because of their widespread use, and because they have been found in drinking-water supplies. Because of this national concern, VOCs were selected for National investigation (hereafter termed "National Synthesis") by the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program in 1994. The broad goals of this National Synthesis are to: (1) describe current water- quality conditions with respect to VOCs; (2) define trends, or lack of trends, in VOCs in surface and ground water; and (3) identify, describe, and explain causal relations among the occurrence and distribution of VOCs in surface water and ground water, and natural and human factors. The National Synthesis of VOCs in ground water has three objectives: (1) to describe their occurrence, status, and distribution; (2) to determine relations among VOCs in shallow ground water and natural and human factors; and (3) to determine, compare, and contrast the occurrence, transformation, transport, and fate of selected VOCs in the hydrologic cycle for several regionally or nationally important aquifer systems. The description of VOC occurrence, status, and distribution in ground water focuses on major aquifers of the United States. Occurrence describes the presence or absence of VOCs, their frequency of occurrence, and their ranges of concentrations. Status compares the concentrations of VOCs detected in relation to water-quality regulations or advisories, such as Maximum Contaminant Levels, Proposed Maximum Contaminant Levels, Maximum Contaminant Level Goals, and Health Advisories. Distribution describes the variability of VOCs in ground water, areally and by depth. This report describes the study design for conducting such an assessment. The assessment focuses on aquifers, or parts of aquifers, that are currently used or have the potential to be used as sources of water supplies, using data collected as part of local, State, and Federal ground-water monitoring programs since 1985. Assessment by aquifer and comparison of results among aquifers will be completed for those aquifers for which adequate spatial or depth-related data are available. Assessment of VOCs in aquifers also will be completed at regional and national scales. A set of criteria for well-network design, well construction, sample-collection methods, and methods of laboratory analysis must be met before VOC data are used for assessment. An appropriate well-network design will provide a generally unbiased, random, equal-area distribution of sampling sites throughout the aquifer, or part of the aquifer, of interest. Well-construction information must be sufficient to ensure that the hydrogeologic unit (or units) represented by the water level measured and the hydrologic unit (or units) contributing water to the well are known. In addition, the well construction and pumping equipment in the well need to be of a type that are not likely to affect concentrations of VOCs in the water sample. VOC data will be considered suitable for use in the occurrence assessment if nationally accepted methods for collection and analysis were used and if the quantitation level for VOC analytes was less than about 5 micrograms per liter; laboratory analysis was done by a laboratory certified by the U.S. Environ- mental Protection Agency; and the sample was collected from untreated (raw) water at or near the well head before being held in a pressure tank or holding tank.

Open-File Report↗

Selected trace-elements in alluvium and rocks, western Mojave Desert, southern California

Concentrations of twenty-seven elements, including naturally-occurring water-quality contaminants arsenic, chromium, and uranium, were measured in 217 samples of alluvium and rock from the western Mojave Desert, southern California, using portable (pXRF) and laboratory (LXRF) X-ray fluorescence. Comparison of measurements with NIST-traceable standards was good, although pXRF overestimated iron compared to LXRF. Results suggest pXRF survey data are sufficiently accurate to assess regional geochemical differences in geologic-source terrains. Principal component analysis showed rubidium and potassium were associated with alluvium eroded from felsic terrain, while iron, copper, chromium, and to a lesser extent titanium, manganese, and nickel were associated with alluvium eroded from mafic terrain. Zinc, vanadium, and arsenic were associated with alluvium eroded from hydrothermal terrain. Elemental assemblages associated with different source terrains were traced spatially to identify the source and composition of alluvium composing aquifers pumped for water supply. Changes in geologic source terrain to the Mojave River, associated with movement along the San Andreas Fault over the past one to five million years, reduced the mafic fraction and increased the felsic fraction of alluvium deposited to the regionally important floodplain aquifer along the Mojave River—lowering chromium concentrations in alluvium through geologic time. Comparison of pXRF and sequential extraction data from 40 samples showed arsenic and uranium were more abundant on the surfaces of mineral grains, while chromium and vanadium remained mostly within unweathered mineral grains—suggesting arsenic and uranium may be more readily mobilized into groundwater with changes in pH, redox, or ionic strength than chromium or vanadium.

California↗

Biological control of ticks

Ticks have numerous natural enemies, but only a few species have been evaluated as tick biocontrol agents (BCAs). Some laboratory results suggest that several bacteria are pathogenic to ticks, but their mode of action and their potential value as biocontrol agents remain to be determined. The most promising entomopathogenic fungi appear to be Metarhizium anisopliae and Beauveria bassiana, strains of which are already commercially available for the control of some pests. Development of effective formulations is critical for tick management. Entomopathogenic nematodes that are pathogenic to ticks can potentially control ticks, but improved formulations and selection of novel nematode strains are needed. Parasitoid wasps of the genus Ixodiphagus do not typically control ticks under natural conditions, but inundative releases show potential value. Most predators of ticks are generalists, with a limited potential for tick management (one possible exception is oxpeckers in Africa). Biological control is likely to play a substantial role in future IPM programmes for ticks because of the diversity of taxa that show high potential as tick BCAs. Considerable research is required to select appropriate strains, develop them as BCAs, establish their effectiveness, and devise production strategies to bring them to practical use.

Book chapter↗

Occurrence of selected pharmaceuticals, personal-care products, organic wastewater compounds, and pesticides in the lower Tallapoosa River watershed near Montgomery, Alabama, 2005

Synthetic and natural organic compounds derived from agricultural operations, residential development, and treated and untreated sanitary and industrial wastewater discharges can contribute contaminants to surface and ground waters. To determine the occurrence of these compounds in the lower Tallapoosa River watershed, Alabama, new laboratory methods were used that can detect human and veterinary antibiotics; pharmaceuticals; and compounds found in personal-care products, food additives, detergents and their metabolites, plasticizers, and other industrial and household products in the environment. Well-established methods for detecting 47 pesticides and 19 pesticide degradates also were used. In all, 186 different compounds were analyzed by using four analytical methods. The lower Tallapoosa River serves as the water-supply source for more than 100,000 customers of the Montgomery Water Works and Sanitary Sewer Board. Source-water protection is a high priority for the Board, which is responsible for providing safe drinking water. The U.S. Geological Survey, in cooperation with the Montgomery Water Works and Sanitary Sewer Board, conducted this study to provide baseline data that could be used to assess the effects of agriculture and residential development on the occurrence of selected organic compounds in the lower Tallapoosa River watershed. Twenty samples were collected at 10 sites on the Tallapoosa River and its tributaries. Ten samples were collected in April 2005 during high base streamflow, and 10 samples were collected in October 2005 when base streamflow was low. Thirty-two of 186 compounds were detected in the lower Tallapoosa River watershed. Thirteen compounds, including atrazine, 2-chloro-4-isopropylamino-6-amino-s-triazine (CIAT), hexazinone, metalaxyl, metolachlor, prometryn, prometon, simazine, azithromycin, oxytetracycline, sulfamethoxazole, trimethoprim, and tylosin, had measurable concentrations above their laboratory reporting levels. Concentrations were estimated for an additional 19 compounds that were detected below their laboratory reporting levels. The two most frequently detected compounds were the pesticides atrazine (19 of 20 samples) and simazine (13 of 20 samples). Tylosin, a veterinary antibiotic, was detected in 8 of 20 samples. Other compounds frequently detected at very low concentrations included CIAT and hexazinone (a degradate of atrazine and a pesticide, respectively); camphor (derived from personal-care products or flavorants), para-cresol (various uses including solvent, wood preservative, and in household cleaning products), and N,N-diethyl-m-toluamide (DEET, an insect repellent).

Alabama↗