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Choosing indicators of natural resource condition: A case study in Arches National Park, Utah, USA

Heavy visitor use in many areas of the world have necessitated development of ways to assess visitation impacts. Arches National Park recently completed a Visitor Experience and Resource Protection (VERP) plan. Integral to this plan was developing a method to identify biological indicators that would both measure visitor impacts and response to management actions. The process used in Arches for indicator selection is outlined here as a model applicable to many areas facing similar challenges. The steps were: (1) Vegetation types most used by visitors were identified. Impacted and unimpacted areas in these types were sampled, comparing vegetation and soil factors. (2) Variables found to differ significantly between compared sites were used as potential indicators. (3) Site-specific criteria for indicators were developed, and potential indicators evaluated using these criteria. (4) Chosen indicators were further researched for ecological relevancy. (5) Final indicators were chosen, field tested, and monitoring sites designated. In Arches, indicators were chosen for monitoring annually (soil crust index, soil compaction, number of used social trails and soil aggregate stability) and every five years (vegetation cover and frequency; ground cover; soil chemistry; and plant tissue chemistry).

Environmental Management↗

Analytical Results for Agricultural Soils Samples from a Monitoring Program Near Deer Trail, Colorado (USA)

Since late 1993, Metro Wastewater Reclamation District of Denver (Metro District, MWRD), a large wastewater treatment plant in Denver, Colorado, has applied Grade I, Class B biosolids to about 52,000 acres of nonirrigated farmland and rangeland near Deer Trail, Colorado, USA. In cooperation with the Metro District in 1993, the U.S. Geological Survey (USGS) began monitoring groundwater at part of this site. In 1999, the USGS began a more comprehensive monitoring study of the entire site to address stakeholder concerns about the potential chemical effects of biosolids applications to water, soil, and vegetation. This more comprehensive monitoring program has recently been extended through 2010. Monitoring components of the more comprehensive study include biosolids collected at the wastewater treatment plant, soil, crops, dust, alluvial and bedrock groundwater, and stream bed sediment. Soils for this study were defined as the plow zone of the dry land agricultural fields - the top twelve inches of the soil column. This report presents analytical results for the soil samples collected at the Metro District farm land near Deer Trail, Colorado, during three separate sampling events during 1999, 2000, and 2002. Soil samples taken in 1999 were to be a representation of the original baseline of the agricultural soils prior to any biosolids application. The soil samples taken in 2000 represent the soils after one application of biosolids to the middle field at each site and those taken in 2002 represent the soils after two applications. There have been no biosolids applied to any of the four control fields. The next soil sampling is scheduled for the spring of 2010. Priority parameters for biosolids identified by the stakeholders and also regulated by Colorado when used as an agricultural soil amendment include the total concentrations of nine trace elements (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc), plutonium isotopes, and gross alpha and beta activity (Colorado Department of Public Health and Environment, Hazardous Materials and Waste Management Division, 1997; Colorado Department of Public Health and Environment,1998; U.S. Environmental Protection Agency, 1993). Since these were the identified priority parameters for the biosolids, the soils have the same set of priority parameters. Although the composite soils' priority analytes have been reported earlier to Metro District, the remaining elemental datasets for both the composite soils samples and selected fields' individual subsamples' data are presented here for the first time. More information about the other monitoring components is presented elsewhere in the literature (http://co.water.usgs.gov/projects/CO406/CO406.html). In general, the objective of each component of the study was to determine whether concentrations of priority parameters (1) were higher than regulatory limits, (2) were increasing with time, and(or) (3) were significantly higher in biosolids-applied areas than in a similar farmed area where biosolids were not applied. The method chosen for sampling the soils proved to be an efficient and reliable representation of the average composition of each field. This was shown by analyzing individual subsamples, averaging the resulting values, and then comparing the values to the composited samples' values. The soil chemistry shows distinct differences between the two sites, most likely due to the different underlying parent material. Biosolids data were used to compile an inorganic-chemical biosolids signature that can be contrasted with the geochemical signature of the agricultural soils for this site. The biosolids signature and an understanding of the geology and hydrology of the site can be used to separate biosolids effects from natural geochemical effects. Elements of particular interest for a biosolids signature after application in the soils include bismuth, copper, silver, mercury, and phosphorus. This signat

Open-File Report↗

Occurrence of transformation products in the environment

Historically, most environmental occurrence research has focused on the parent compounds of organic contaminants. Research, however, has documented that the environmental transport of chemicals, such as pesticides and emerging contaminants, are substantially underestimated if transformation products are not considered. Although most examples described herein were drawn from research conducted by the U.S. Geological Survey, such results are generally reflective of those found in other parts of the world. Results from a study of 51 streams in the Midwestern United States found that transformation products were seven of the ten most frequently detected pesticide compounds in late spring runoff (after application of pre-emergent herbicides), and nine of the ten most frequently detected compounds in fall season runoff (during and after harvest). In fact, 70% of the total herbicide concentration in water from the Mississippi River Basin was from transformation products. Results from a study of 86 municipal wells in Iowa found the frequency of detection increased from 17%, when pesticide parent compounds were considered, to 53%, when both parents and transformation products were considered. Transformation products were 12 of the 15 most frequently detected compounds for this groundwater study. Although studies on transformation products of synthetic organic compounds other than pesticides are not as common, wastewater treatment plant discharges have repeatedly been shown to contribute such transformation products to streams. In addition, select detergent transformation products have been commonly found in solid waste in the 1000's mg/kg. These findings and many others document that transformation products must be considered to fully assess the potential environmental occurrence of chemical contaminants and their transport and fate in various compartments of the hydrologic system. ?? 2008 Springer-Verlag Berlin Heidelberg.

The Handbook of Environmental Chemistry series↗

Determination of silver, bismuth, cadmium, copper, lead, and zinc in geologic materials by atomic absorption spectrometry with tricaprylylmethylammonium chloride

Interferences commonly encountered in the determination of silver, bismuth, cadmium, copper, lead, and zinc at crustal abundance levels are effectively eliminated using a rapid, sensitive, organic extraction technique. A potassium chlorate-hydrochloric acid digestion solubilizes the metals not tightly bound in the silicate lattice of rocks, soils, and stream sediments. The six metals are selectively extracted into a 10% Aliquat 336-MIBK organic phase in the presence of ascorbic acid and potassium iodide. Metals in the organic extract are determined by flame atomic absorption spectrometry to the 0.02-ppm level for silver, cadmium, copper, and zinc and to the 0.2-ppm level for bismuth and lead with a maximum relative standard deviation of 18.8% for known reference samples. An additional hydrofluoric acid digestion may be used to determine metals substituted in the silicate lattice.

Analytical Chemistry↗

Effects of selected polybrominated diphenyl ether flame retardants on lake trout (Salvelinus namaycush) thymocyte viability, apoptosis, and necrosis

Polybrominated diphenyl ether (PBDE) flame-retardants have been identified as an emergent contaminants issue in many parts of the world. In vitro analyses were conducted to test the hypothesis that selected PBDEs congeners affect viability, apoptosis, and necrosis of thymocytes from laboratory-reared lake trout ( Salvelinus namaycush ). At current environmental levels (<1 mg/L), effects of the tested PBDEs on thymocytes were negligible. However, at 100 mg/L, major effects were seen for congener brominated diphenyl ether 47 (BDE-47) and minor effects were seen for congener BDE-99.

Environmental Toxicology and Chemistry↗

Assessment of stream quality using biological indices at selected sites in the Brandywine Creek basin, Chester County, Pennsylvania, 1981-97

In 1970, the Chester County Water Resources Authority (Pennsylvania) and the U.S. Geological Survey (USGS) established a longterm water-quality network with the goal of assessing the quality of streams in the county and understanding stream changes in response to urbanization using benthic-macroinvertebrate data. This database represents one of the longest continuous water-quality data sets in the country. Benthic macroinvertebrates are aquatic insects, such as mayflies, caddisflies, riffle beetles, and midges, and other invertebrates that live on the stream bottom. Benthic macroinvertebrates are useful in evaluating stream quality because their habitat preferences and low motility cause them to be affected directly by substances that enter the aquatic system. By evaluating the diversity and community structure of benthic-macroinvertebrate populations, a determination of stream quality can be made. Between 1981 and 1997, the water-quality network consisted of 43 sites in 5 major basins in Chester County—Delaware, Schuylkill, Brandywine, Big Elk and Octoraro, and Red and White Clay. Benthicmacroinvertebrate, water-chemistry, and habitat data were collected each year in October or November during base-flow conditions. Using these data, Reif evaluated the overall water-quality condition of Chester County streams. This Fact Sheet summarizes the key findings from Reif for streams in the Brandywine Creek Basin. These streams include West Branch Brandywine Creek (sites 37 and 38), Buck Run (site 46), Doe Run (site 45), East Branch Brandywine Creek (sites 48, 42, 36, and 39), Indian Run (site 47), West Valley Creek (site 44), and Main Stem Brandywine Creek (site 40). This summary includes an analysis of stream conditions based on benthic-macroinvertebrate samples and an analysis of trends in stream conditions for the 17-year study period.

Fact Sheet↗

Chemistry of ground water in the Silver Springs basin, Florida, with an emphasis on nitrate

The Silver Springs group, in central Marion County, Florida, has a combined average discharge rate of 796 cubic feet per second and forms the headwaters of the Silver River. The springs support a diverse ecosystem and are an important cultural and economic resource. Concentrations of nitrite-plus-nitrate (nitrate-N) in water from the Main Spring increased from less than 0.5 milligrams per liter (mg/L) in the 1960s to about 1.0 mg/L in 2003. The Upper Floridan aquifer supplies the ground water to support spring discharge. This aquifer is at or near land surface in much of the ground-water basin; nutrients leached at land surface can easily percolate downward into the aquifer. Sources of nitrogen in ground water in the Silver Springs basin include atmospheric deposition, fertilizers used by agricultural and urban activities, and human and animal wastes. During 2000-2001, 56 wells in the area contributing recharge to Silver Springs were sampled for major ions, nutrients, and some trace constituents. Selected wells also were sampled for a suite of organic constituents commonly found in domestic and industrial wastewater and for the ratio of nitrogen isotopes (15N/14N) to better understand the sources of nitrate. Wells were selected to be representative of both confined and unconfined conditions of the Upper Floridan aquifer, as well as a variety of land-use types. Data from this study were compared to data collected from 25 wells in 1989-90. Concentrations of nitrate-N in ground water during this study ranged from less than the detection limit of 0.02 to 12 mg/L, with a median of 1.2 mg/L. For data from 1989-90, the range was from less than 0.02 to 3.6 mg/L, with a median of 1.04 mg/L. Water from wells in agricultural land-use areas had the highest median nitrate-N concentration (1.7 mg/L), although it is uncertain if the 12 mg/L maximum concentration was influenced by land-use activities or proximity to a septic tank. The median value for all urban land-use areas was 1.15 mg/L. Because fewer wells were in rangeland or forested areas, those categories were grouped together. The median concentration for that group was 0.09 mg/L. The ratio of 15N/14N in ground-water samples ranged from -0.5 to 11.5 per mil. The median value for ground-water samples from 35 wells, 4.9 per mil, is near the top of the range that indicates inorganic nitrogen sources. In agricultural areas, the median 15N/14N was 4.8 per mil, indicating mostly inorganic (fertilizer) sources. In urban areas, the median 15N/14N was 5.4 per mil, indicating more influence of organic nitrogen (N) sources. Thus, in both agricultural and urban areas, fertilizer is an important inorganic source of N in ground water (and, therefore, in spring water as well). The influence of organic N is more apparent in urban areas than in agricultural areas. Two distinct 15N/14N values were observed in water from the Main Spring, one indicating an inorganic nitrogen source and the other indicating a mixture of sources with a strong influence of organic nitrogen. Thirty-five wells and three springs of the Silver Springs group (the Main Spring, the Abyss, and the Blue Grotto) were sampled for a suite of 63 compounds common in wastewater. A total of 38 compounds was detected, nearly all in very low concentrations. The most frequently detected compound was the insecticide N,N-diethyl-meta-toluamide (DEET), which was detected in water from 27 wells and all three springs. The presence or absence of DEET in ground-water samples did not seem to be related to land use; however, hydrogeologic conditions at the well sites (confined or unconfined) generally did affect the presence or absence of DEET in the ground water. DEET also appears to be a useful tracer for the presence of reused water. Water samples were collected from the Main Spring and two other springs of the Silver Springs group and analyzed for concentrations of dissolved gasses and for chlorofluorocarbons (CFCs), sulfur hexaflu

Scientific Investigations Report↗

Investigating the influence of nitrate nitrogen on post-smolt Atlantic salmon Salmo salar reproductive physiology in water recirculation aquaculture systems

A major issue affecting land-based, closed containment Atlantic salmon Salmo salar growout production in water recirculation aquaculture systems (RAS) is precocious male maturation, which can negatively impact factors such as feed conversion, fillet yield, and product quality. Along with other water quality parameters, elevated nitrate nitrogen (NO 3 -N) has been shown to influence the reproductive development and endogenous sex steroid production in a number of aquatic animal species, including Atlantic salmon. We sought to determine whether elevated NO 3 -N in RAS can influence early maturation in post-smolt Atlantic salmon in an 8-month trial in replicated freshwater RAS. Post-smolt Atlantic salmon (102 ± 1 g) were stocked into six RAS, with three RAS randomly selected for dosing with high NO 3 -N (99 ± 1 mg/L) and three RAS set for low NO 3 -N (10 ± 0 mg/L). At 2-, 4-, 6-, and 8-months post-stocking, 5 fish were randomly sampled from each RAS, gonadosomatic index(GSI) data were collected, and plasma was sampled for 11-ketotestosterone (11-KT) quantification. At 4- and 8-months post-stocking, samples of culture tank and spring water (used as “makeup” or replacement water) were collected and tested for a suite of 42 hormonally active compounds using liquid chromatography/mass spectrometry , as well as for estrogenicity using the bioluminescent yeast estrogen screen (BLYES) reporter system. Finally, at 8-months post-stocking 8–9 salmon were sampled from each RAS for blood gas and chemistry analyses, and multiple organ tissues were sampled for histopathology evaluation. Overall, sexually mature males were highly prevalent in both NO 3 -N treatment groups by study’s end, and there did not appear to be an effect of NO 3 -N on male maturation prevalence based on grilse identification, GSI, and 11-KT results, indicating that other culture parameters likely instigated early maturation. No important differences were noted between treatment groups for whole blood gas and chemistry parameters, and no significant tissue changes were noted on histopathology. No hormones, hormone conjugates, or mycotoxins were detected in any water samples; phytoestrogens were generally detected at low levels but were unrelated to NO 3 -N treatment. Finally, low-level estrogenicity was detected in RAS water, but a NO 3 -N treatment effect could not be determined. The major findings of this study are i) the NO 3 -N treatments did not appear to be related to the observed male maturation, and ii) the majority of hormonally active compounds were not detectable in RAS water.

Aquacultural Engineering↗

Assessment of stream quality using biological indices at selected sites in the Schuylkill River basin, Chester County, Pennsylvania, 1981-97

Introduction In 1970, the Chester County Water Resources Authority (Pennsylvania) and the U.S. Geological Survey (USGS) established a long-term water-quality network with the goal of assessing the quality of streams in the county and understanding stream changes in response to urbanization using benthic-macroinvertebrate data. This database represents one of the longest continuous water-quality data sets in the country. Benthic macroinvertebrates are aquatic insects, such as mayflies, caddisflies, riffle beetles, and midges, and other invertebrates that live on the stream bottom. Benthic macroinvertebrates are useful in evaluating stream quality because their habitat preferences and low motility cause them to be affected directly by substances that enter the aquatic system. By evaluating the diversity and community structure of benthic-macroinvertebrate populations, a determination of stream quality can be made. Between 1981 and 1997, the network consisted of 43 sites in 5 major basins in Chester County—Delaware, Schuylkill, Brandywine, Big Elk and Octoraro, and Red and White Clay. Benthic-macroinvertebrate, water-chemistry, and habitat data were collected each year in October or November during base-flow conditions. Using these data, Reif evaluated the overall water-quality condition of Chester County streams. This Fact Sheet summarizes the key findings from Reif for streams in the Schuylkill River Basin. These streams include Pigeon Creek (site 10), Stony Run (site 6), French Creek (sites 12-16), Pickering Creek (sites 1-5), Little Valley Creek (site 49), and Valley Creek (site 50). This summary includes an analysis of stream conditions based on benthic-macroinvertebrate samples and an analysis of trends in stream conditions for the 17-year study period.

Fact Sheet↗

National water summary 1990-91: Hydrologic events and stream water quality

National Water Summary 1990-91 Hydrologic Events and Stream Water Quality was planned to complement existing Federal-State water-quality reporting to the U.S. Congress that is required by the Clean Water Act of 1972. This act, formally known as the Federal Water Pollution Control Act Amendments of 1972 (Public Law 92-500), and its amendments in 1977,1979,1980,1981,1983, and 1987, is the principal basis for Federal-State cooperation on maintaining and reporting on water quality in the United States. Under section 305(b) of the Clean Water Act, the States must designate uses for waterbodies, biennially assess whether the waterbodies meet designated uses, and report to the U.S. Environmental Protection Agency (EPA), which in turn summarizes the findings of the State assessments in a biennial National Water Quality Inventory report to the Congress. This volume of the National Water Summary uses a nationally consistent data base and methods of statistical analysis to document stream water quality in the United States, Puerto Rico, and the Western Pacific Islands. As a basis for preparation of this report, the U.S. Geological Survey (uses) created a data base of waterquality data from about 2,900 stream water-quality monitoring stations in the United States (Lanfear, 1993). These data, which were extracted primarily from the uses National Water Information System (NWIS) and supplemented with data from the EPA national data base known as STORET, consisted mostly of water-chemistry and physical-sediment data. About 1,400 of these stations met a criterion, used in this volume for trends analysis of data, of having a period of record that began before water year 1980. (A water year is the period from October 1 through September 30 and is identified by the calendar year at the end of the period.) Inasmuch as the determination of trends requires about 10 years of data, few biological data were suitable for trends analysis because biological indicators of water quality were not being collected extensively by water year 1980. Also, because of the lack of long-term data, an assessment of the water quality of lakes and reservoirs is not included in this National Water Summary . Constituent and waterproperty data were selected from this data base and analyzed with statistical techniques that have been used extensively by the uses to summarize conditions and trends in water quality. (Throughout the remainder of this article, the term "constituent" is used also to represent water properties, such as pH and alkalinity.) Selected results from this analysis are presented graphically, both by State and nationally, in this volume. The data base created for preparation of this volume and the resulting nationally consistent statistical analysis of these data provide a unique opportunity to compare and contrast stream water-quality conditions and trends nationally and State by State. Because of the complexity of water quality and the natural seasonal and diurnal variations in the concentrations of waterquality constituents, the determination of trends in water quality requires a relatively long period of record. Trends in constituent concentrations in the State summaries in this volume were calculated for one or more of four periods water years 1970-89,1975-89,1980- 89, and 1982-89. Unfortunately, few water-quality monitoring stations have periods of record of more than 10 or 15 years, and therefore most analyses in the State summaries were done for 8- or 10-year periods. Although interest in water quality has continued to heighten since passage of the Clean Water Act, funds for support of data-collection programs are limited and data records of many of the constituents now of current concern, especially organic constituents, do not exist or are less than 10-years long; consequently only a modest number of organic constituents are presented in this volume. Discussion of conditions and trends in water quality in this National Water Summary also draw upon information about land use, population, water use, application of agricultural chemicals in rural areas, the siting of industrial facilities, and other ancillary information. Because the results of analysis of a restricted number of constituents are presented in this volume, State 305(b) reports also are cited in the discussion of water quality in each State. The following discussion is an overview of the three parts of this 1990-91 National Water Summary - "Hydrologic Conditions and Water-Related Events, Water Years 1990-91," "Hydrologic Perspectives on Water Issues," and "State Summaries of Stream Water Quality."

Water Supply Paper↗

Assessment of stream quality using biological indices at selected sites in the Red Clay and White Clay Creek basins, Chester County, Pennsylvania, 1981-97

In 1970, the Chester County Water Resources Authority (Pennsylvania) and the U.S. Geological Survey (USGS) established a long-term water-quality network with the goal of assessing the quality of streams in the county and understanding stream changes in response to urbanization using benthic-macroinvertebrate data. This database represents one of the longest continuous water-quality data sets in the country. Benthic macroinvertebrates are aquatic insects, such as mayflies, caddisflies, riffle beetles, and midges, and other invertebrates that live on the stream bottom. Benthic macroinvertebrates are useful in evaluating stream quality because their habitat preference and low motility cause them to be affected directly by substances that enter the aquatic system. By evaluating the diversity and community structure of benthic-macroinvertebrate populations, a determination of stream quality can be made. Between 1981 and 1997, the water-quality network consisted of 43 sites in 5 major basins in Chester County—Delaware, Schuylkill, Brandywine, Big Elk and Octoraro, and Red and White Clay. Benthicmacroinvertebrate, water-chemistry, and habitat data were collected each year in October or November during base-flow conditions. Using these data, Reif evaluates the overall water-quality condition of Chester County streams. This Fact Sheet summarizes the key findings from Reif for streams in the Red Clay and White Clay Creek Basins. These streams include East Branch Red Clay Creek (site 26), West Branch Red Clay Creek (site 27), East Branch White Clay Creek (site 28), the Middle Branch White Clay Creek (site 29), and West Branch White Clay Creek (site 30). This summary includes an analysis of stream conditions on the basis of benthic-macroinvertebrate samples and an analysis of trends in stream conditions for the 17-year study period.

Pennsylvania↗

Semimicrodetermination of tantalum with selenous acid

Tantalum is separated and determined gravimetrically by precipitation with selenous acid from a highly acidic solution containing oxalic and tartaric acids. The method is selective for the determination of up to 30 mg. of tantalum pentoxide, and tolerates relatively large amounts of scandium, yttrium, cerium, titanium, zirconium, thorium, vanadium, niobium, molybdenum, tungsten, uranium, iron, aluminum, gallium, tin, lead, antimony, and bismuth. The separation of tantalum from niobium and titanium is not strictly quantitative, and correction is made colorimetrically for the small amounts of niobium and titanium co-precipitating with the tantalum. The method was applied to the determination of tantalum in tantaloniobate ores.

Analytical Chemistry↗

Assessment of stream quality using biological indices at selected sites in the Delaware River basin, Chester County, Pennsylvania, 1981-97

Introduction In 1970, the Chester County Water Resources Authority (Penn-sylvania) and the U.S. Geological Survey (USGS) established a long-term water-quality network with the goal of assessing the quality of streams in the county and understanding stream changes in response to urbanization using benthic-macroinvertebrate data. This database represents one of the longest continuous water-quality data sets in the country. Benthic macroinvertebrates are aquatic insects, such as mayflies, caddisflies, riffle beetles, and midges, and other invertebrates that live on the stream bottom. Benthic macroinvertebrates are useful in evaluating stream quality because their habitat preferences and low motility cause them to be affected directly by substances that enter the aquatic system. By evaluating the diversity and community structure of benthic-macroinvertebrate populations, a determination of stream quality can be made. Between 1981 and 1997, the water-quality network consisted of 43 sites in 5 major basins in Chester County—Delaware, Schuylkill, Brandywine, Big Elk and Octoraro, and Red and White Clay. Benthic-macroinvertebrate, water-chemistry, and habitat data were collected each year in October or November during base-flow condition. Using these data, Reif evaluates the overall water-quality condition of Chester County streams. This Fact Sheet summarizes the key findings from Reif for streams in the Delaware River Basin. These streams include Darby Creek (site 17), Crum Creek (site 19), Ridley Creek (sites 20 and 21), East Branch Chester Creek (sites 22-24, and 51), and Goose Creek (site 25). This summary includes an analysis of stream conditions on the basis of benthic-macroinvertebrate samples and an analysis of trends in stream conditions for the 17-year study period.

Fact Sheet↗

Geochemical and isotopic variations in shallow groundwater in areas of the Fayetteville Shale development, north-central Arkansas

Exploration of unconventional natural gas reservoirs such as impermeable shale basins through the use of horizontal drilling and hydraulic fracturing has changed the energy landscape in the USA providing a vast new energy source. The accelerated production of natural gas has triggered a debate concerning the safety and possible environmental impacts of these operations. This study investigates one of the critical aspects of the environmental effects; the possible degradation of water quality in shallow aquifers overlying producing shale formations. The geochemistry of domestic groundwater wells was investigated in aquifers overlying the Fayetteville Shale in north-central Arkansas, where approximately 4000 wells have been drilled since 2004 to extract unconventional natural gas. Monitoring was performed on 127 drinking water wells and the geochemistry of major ions, trace metals, CH 4 gas content and its C isotopes (&delta; 13 C CH4 ), and select isotope tracers (&delta; 11 B, 87 Sr/ 86 Sr, &delta; 2 H, &delta; 18 O, &delta; 13 C DIC ) compared to the composition of flowback-water samples directly from Fayetteville Shale gas wells. Dissolved CH 4 was detected in 63% of the drinking-water wells (32 of 51 samples), but only six wells exceeded concentrations of 0.5 mg CH 4 /L. The &delta; 13 C CH4 of dissolved CH 4 ranged from &minus;42.3&permil; to &minus;74.7&permil;, with the most negative values characteristic of a biogenic source also associated with the highest observed CH 4 concentrations, with a possible minor contribution of trace amounts of thermogenic CH 4 . The majority of these values are distinct from the reported thermogenic composition of the Fayetteville Shale gas (&delta; 13 C CH4 = &minus;35.4&permil; to &minus;41.9&permil;). Based on major element chemistry, four shallow groundwater types were identified: (1) low (<100 mg/L) total dissolved solids (TDS), (2) TDS > 100 mg/L and Ca&ndash;HCO 3 dominated, (3) TDS > 100 mg/L and Na&ndash;HCO 3 dominated, and (4) slightly saline groundwater with TDS > 100 mg/L and Cl > 20 mg/L with elevated Br/Cl ratios (>0.001). The Sr ( 87 Sr/ 86 Sr = 0.7097&ndash;0.7166), C (&delta; 13 C DIC = &minus;21.3&permil; to &minus;4.7&permil;), and B (&delta; 11 B = 3.9&ndash;32.9&permil;) isotopes clearly reflect water&ndash;rock interactions within the aquifer rocks, while the stable O and H isotopic composition mimics the local meteoric water composition. Overall, there was a geochemical gradient from low-mineralized recharge water to more evolved Ca&ndash;HCO 3 , and higher-mineralized Na&ndash;HCO 3 composition generated by a combination of carbonate dissolution, silicate weathering, and reverse base-exchange reactions. The chemical and isotopic compositions of the bulk shallow groundwater samples were distinct from the Na&ndash;Cl type Fayetteville flowback/produced waters (TDS &sim;10,000&ndash;20,000 mg/L). Yet, the high Br/Cl variations in a small subset of saline shallow groundwater suggest that they were derived from dilution of saline water similar to the brine in the Fayetteville Shale. Nonetheless, no spatial relationship was found between CH 4 and salinity occurrences in shallow drinking water wells with proximity to shale-gas drilling sites. The integration of multiple geochemical and isotopic proxies shows no direct evidence of contamination in shallow drinking-water aquifers associated with natural gas extraction from the Fayetteville Shale.

Applied Geochemistry↗

Low rate of population establishment of a freshwater invertebrate (Gammarus lacustris) in experimental conservation translocations

Conservation translocations may be a useful tool for the restoration of declining freshwater invertebrates, but they are poorly represented in the literature. We conducted a before-after/control-impact (BACI) experiment to test the efficacy of conservation translocation for re-establishing abundant populations of the amphipod Gammarus lacustris , a declining species and wildlife food resource in depressional wetlands in the upper Midwest of the United States of America. Each study site ( n = 19) contained at least one treatment wetland receiving translocated G. lacustris from a local donor and one control wetland. We selected study wetlands based on a suite of wetland characteristics and randomly assigned recipient versus control treatment. Gammarus lacustris was detected post-translocation at only 2 of 22 recipient wetlands (1 of 19 sites). Overall, there was a statistical increase in G. lacustris density in recipient wetlands compared to controls; however, the results were of minimal biological significance due to being driven by a single site with low G. lacustris densities. Accordingly, our results suggest that future conservation translocations of amphipods might be successful if limited to recently restored wetlands or informed by a more complex habitat suitability model to differentiate dispersal limitations from habitat limitations. To develop such a model would involve identifying the fewest, most influential physical and biological factors (e.g. wetland size/structure, fish, aquatic vegetation, and water chemistry) from the numerous inter-related factors that correlate with the abundance of naturally occurring G. lacustris ; candidate wetlands to receive amphipods would be those for which the model predicts abundant G. lacustris but in which they do not presently occur.

Minnesota↗

Distribution of mineral phases in the Eocene Green River Formation, Piceance Basin, Colorado – Implications for the evolution of Lake Uinta

The mineralogy of the Eocene Green River Formation in the Piceance Basin, Colorado, has been the subject of numerous studies since the 1920s. Most previous work has focused on the resource potential of these lacustrine mudrocks, which in addition to substantial oil shale potential (in-place resources of 353 billion barrels of synthetic crude oil for rocks yielding at least 25 gallons per ton, GPT), includes nahcolite, a currently utilized soda ash resource, and dawsonite, a potential alternative source of aluminum. Another reason to study the mineralogy in this system is that the geographic and stratigraphic distribution of various authigenic minerals may provide insights into the geochemistry and depositional environment of the long-lived Eocene Lake Uinta. In this study, legacy non-quantitative (presence/absence) X-ray diffraction (XRD) data recently published by the U.S. Geological Survey (USGS) for more than nine-thousand samples collected from thirty coreholes in the Green River Formation, Piceance Basin were examined. These data were used to better define the stratigraphic and paleogeographic extent of a set of indicator minerals (illite, analcime, albite, dawsonite, and nahcolite) within the Piceance Basin lacustrine strata. This set of minerals was selected based on observations from previous work and variability in their occurrence and co-occurrence within the Piceance Basin. The USGS database has been used to (1) construct maps showing geographic variations in mineral occurrences for 14 stratigraphically defined rich and lean oil shale zones; (2) assess co-occurrences of indicator minerals; and (3) compare occurrence results with quantitative XRD datasets collected on Piceance Basin oil shales. Occurrences of many authigenic minerals (analcime, dawsonite, and nahcolite) varied in the lacustrine strata near and around the depocenter, but others, like quartz, dolomite, and feldspar (potassium + undifferentiated), were widely and consistently present (>90% of samples) across the basin. Shifts in the distribution of indicator mineral occurrences generally coincide with changes identified in previous lake history descriptions and indicate that the water chemistry of Lake Uinta varied significantly going from near-shore to the depocenter and through time.

Colorado↗

Assessment of stream quality using biological indices at selected sites in the Big Elk and Octoraro Creek basins, Chester County, Pennsylvania, 1981-97

Introduction In 1970, the Chester County Water Resources Authority (Pennsylvania) and the U.S. Geological Survey (USGS) established a long-term water-quality network with the goal of assessing the quality of streams in the county and understanding stream changes in response to urbanization using benthic-macroinvertebrate data. This database represents one of the longest continuous water-quality data sets in the country. Benthic macroinvertebrates are aquatic insects, such as mayflies, caddisflies, riffle beetles, and midges, and other invertebrates that live on the stream bottom. Benthic macroin-vertebrates are useful in evaluating stream quality because their habitat preference and low motility cause them to be affected directly by substances that enter the aquatic system. By evaluating the diversity and community structure of benthic-macroinvertebrate populations, a determination of stream quality can be made. Between 1981 and 1997, the water-quality network consisted of 43 sites in 5 major basins in Chester County—Delaware, Schuylkill, Brandywine, Big Elk and Octoraro, and Red and White Clay. Benthic-macroinvertebrate, water-chemistry, and habitat data were collected each year in October or November during base-flow conditions. Using these data, Reif evaluates the overall water-quality condition of Chester County streams. This Fact Sheet summarizes the key findings from Reif for streams in the Big Elk and Octoraro Creek Basins. These streams include East Branch Big Elk Creek (site 31), West Branch Big Elk Creek (site 32), East Branch Octoraro Creek (site 33) and Valley Creek (site 34). This summary includes an analysis of stream conditions based on benthic-macroinvertebrate samples and an analysis of trends in stream conditions for the 17-year study period.

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Effects of selected low-impact-development (LID) techniques on water quality and quantity in the Ipswich River Basin, Massachusetts: Field and modeling studies

During the months of August and September, flows in the Ipswich River, Massachusetts, dramatically decrease largely due to groundwater withdrawals needed to meet increased residential and commercial water demands. In the summer, rates of groundwater recharge are lower than during the rest of the year, and water demands are higher. From 2005 to 2008, the U.S. Geological Survey, in a cooperative funding agreement with the Massachusetts Department of Conservation and Recreation, monitored small-scale installations of low-impact-development (LID) enhancements designed to diminish the effects of storm runoff on the quantity and quality of surface water and groundwater. Funding for the studies also was contributed by the U.S. Environmental Protection Agency’s Targeted Watersheds Grant Program through a financial assistance agreement with Massachusetts Department of Conservation and Recreation. The monitoring studies examined the effects of (1) replacing an impervious parking lot surface with a porous surface on groundwater quality, (2) installing rain gardens and porous pavement in a neighborhood of 3 acres on the quantity and quality of stormwater runoff, and (3) installing a 3,000-square foot (ft2) green roof on the quantity and quality of stormwater runoff. In addition, the effects of broad-scale implementation of LID techniques, reduced water withdrawals, and water-conservation measures on streamflow in large areas of the basin were simulated using the U.S. Geological Survey’s Ipswich River Basin model. From June 2005 to 2007, groundwater quality was monitored at the Silver Lake town beach parking lot in Wilmington, MA, prior to and following the replacement of the conventional, impervious-asphalt surface with a porous surface consisting primarily of porous asphalt and porous pavers. Changes in the concentrations of the water-quality constituents, phosphorus, nitrogen, cadmium, chromium, copper, lead, nickel, zinc, and total petroleum hydrocarbons, were monitored. Increased infiltration of precipitation did not result in discernible increases in concentrations of these potential groundwater contaminants. Concentrations of dissolved oxygen increased slightly in groundwater profiles following the removal of the impervious asphalt parking lot surface. In Wilmington, MA, in a 3-acre neighborhood, stormwater runoff volume and quality were monitored to determine the ability of selected LID enhancements (rain gardens and porous paving stones) to reduce flows and loads of the above constituents to Silver Lake. Flow-proportional water-quality samples were analyzed for nutrients, metals, total petroleum hydrocarbons, and total-coliform and Escherichia coli bacteria. In general, when all storms were considered, no substantial decreases were observed in runoff volume as a result of installing LID enhancements. However, the relation between rainfall and runoff did provide some insight into how the LID enhancements affected the effective impervious area for the neighborhood. A decrease in runoff was observed for storms of 0.2 inches (in.) or less of precipitation, which indicated a reduction in effective impervious area from approximately 10 percent to about 4.5 percent for the 3-acre area. Water-quality-monitoring results were inconclusive; there were no statistically significant differences in concentrations or loads when the pre- and post-installation-period samples were compared. Three factors were probably most important in minimizing differences: (1) the small decrease in effective impervious area, (2) the differences in the size of storms sampled for water-quality constituents before and after installation of the infiltration enhancing measures, and (3) small sample sizes. In a third field study, the characteristics of runoff from a vegetated “green” roof and a conventional, rubber-membrane roof were compared. The amount of precipitation and the length of the antecedent dry period were the two primary factors affecting the green roof’s water-storage capacity. The green roof retained more than 50 percent of the precipitation from storms with 0.04 to 1.0 in. of rain. Approximately 95 percent of the precipitation from one storm of nearly 2 in. was retained by the green roof. On the rubber-membrane roof, only a small, shallow puddle of insubstantial volume ever remained after a storm. Bulk precipitation from 10 storms was monitored for the same constituents (nutrients, metals, and total petroleum hydrocarbons) as the roof runoff, and the results were compared with those for roof-runoff samples. The use of fertilizers to help establish the vegetation during the study probably distorted any effect the plants and growing medium may have had on the retention of target analytes. As a result of the fertilizer and growing medium chemistry, median concentrations of total nitrogen, total phosphorus, cadmium, copper, and nickel in runoff from the green roof were greater than in the runoff from the conventional roof or in bulk precipitation. Concentrations of lead and zinc were greater in runoff from the conventional roof, probably a result of passage through the old, metal drainpipes. Simulations of the effects of LID on streamflow in the Ipswich River Basin were conducted with a previously calibrated Hydrological Simulation Program-FORTRAN (HSPF) precipitation-runoff model. Simulations were conducted at multiple spatial scales to evaluate the effects of (1) updated water withdrawals for the towns of Reading and Wilmington; (2) potential land-use changes at buildout (potential future development); (3) effective impervious area reductions upstream from the South Middleton streamgage to represent the effects of widespread implementation of LID retrofit techniques; (4) basin-scale water withdrawal reductions scaled up (expanded to the town level) from water-conservation pilot programs conducted by the Massachusetts Department of Conservation and Recreation; and (5) land-use change and LID techniques at a local scale, which is smaller than the HSPF subbasin. Effects on streamflow generally were evaluated by comparing results of two or more related simulations for selected reaches in the basin; thus, relative rather than absolute changes in simulated flow were the focus of the assessment. Simulations indicated that reduced withdrawals for the towns of Reading and Wilmington led to substantially higher medium and low flows in most of the reaches upstream from the South Middleton streamgage. Simulations of water-conservation measures resulted in negligible effects on streamflow. Overall, simulations indicated that spatial scale is an important factor in determining the effects of land-use change and LID practices on streamflow. Potential land-use changes at buildout had modest (percent differences of less than 20 percent) effects on streamflow in most subbasins because relatively little land in the basin was available for development (about 17 percent); moreover, most of the available open land is zoned for low-density residential development, and this land-use category was simulated to contain relatively little effective impervious area and to be similar hydrologically to the forested land in place prior to development. Results of the simulations conducted to evaluate widespread effective impervious area reductions upstream from the South Middleton streamgage indicated that the percentage of urban land use and associated effective impervious area was too small for a 50-percent reduction of effective impervious area to appreciably affect streamflow (percent differences of less than 20 percent) in most subbasins. In contrast, the results of the hypothetical local-scale simulations indicated that for smaller streams, where the percentage of urban land use and associated effective impervious area in the drainage area may be substantially higher, land-use change, development patterns, and LID practices potentially have much greater effects on streamflow. Modeling results also indicated that LID was potentially most beneficial for minimizing streamflow alteration when applied to dense urban development, largely because larger tracts of effective impervious area were available for reduction than were available for other land-use categories. For example, commercial-industrial-transportation land use is composed of 37 percent pervious area and 63 percent effective impervious area in the HSPF model, whereas low-density residential area is composed of 97.5 percent pervious area and only 2.5 percent effective impervious area. Field and modeling studies concurred in the assessment that LID enhancements would likely have the greatest effect on decreasing stormwater runoff when broadly applied to highly impervious urban areas. A measurable effect for small rainfall events (less than 0.25 inch) was determined in the small, highly pervious area that was monitored in this study, but the volume difference was not great.

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