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Klamath River Water Quality Data from Link River Dam to Keno Dam, Oregon, 2008

This report documents sampling and analytical methods and presents field data from a second year of an ongoing study on the Klamath River from Link River Dam to Keno Dam in south central Oregon; this dataset will form the basis of a hydrodynamic and water quality model. Water quality was sampled weekly at six mainstem and two tributary sites from early April through early November, 2008. Constituents reported herein include field-measured water-column parameters (water temperature, pH, dissolved oxygen concentration, specific conductance); total nitrogen and phosphorus; particulate carbon and nitrogen; total iron; filtered orthophosphate, nitrite, nitrite plus nitrate, ammonia, organic carbon, and iron; specific UV absorbance at 254 nanometers; chlorophyll a; phytoplankton and zooplankton enumeration and species identification; and bacterial abundance and morphological subgroups. Sampling program results indicated: *Most nutrient and carbon concentrations were lowest in spring, increased starting in mid-June, remained elevated in the summer, and decreased in fall. Dissolved nitrite plus nitrate had a different seasonal cycle and was below detection or at low concentration in summer. *Although total nitrogen and total phosphorus concentrations did not show large differences from upstream to downstream, filtered ammonia and orthophosphate concentrations increased in the downstream direction and particulate carbon and particulate nitrogen generally decreased in the downstream direction. *Large bacterial cells made up most of the bacteria biovolume, though cocci were the most numerous bacteria type. Cocci, with diameters of 0.1 to 0.2 micrometers, were smaller than the filter pore sizes used to separate dissolved from particulate matter. *Phytoplankton biovolumes were dominated by diatoms in spring and by the blue-green alga Aphanizomenon flos-aquae after mid-June. Another blue-green, Anabaena flos-aquae, was noted in samples from late May to late June. Phytoplankton biovolumes generally were highest at the upstream Link River and Railroad Bridge sites and decreased in the downstream direction. *Zooplankton densities were largest in late April. Populations were dominated by rotifers and copepods in early spring, and by rotifers and cladocerans in summer, with cladocerans most common at the most upstream site.

Open-File Report

High-Resolution Aeromagnetic Survey To Image Shallow Faults, Poncha Springs and Vicinity, Chaffee County, Colorado

High-resolution aeromagnetic data were acquired over the town of Poncha Springs and areas to the northwest to image faults, especially where they are concealed. Because this area has known hot springs, faults or fault intersections at depth can provide pathways for upward migration of geothermal fluids or concentrate fracturing that enhances permeability. Thus, mapping concealed faults provides a focus for follow-up geothermal studies. Fault interpretation was accomplished by synthesizing interpretative maps derived from several different analytical methods, along with preliminary depth estimates. Faults were interpreted along linear aeromagnetic anomalies and breaks in anomaly patterns. Many linear features correspond to topographic features, such as drainages. A few of these are inferred to be fault-related. The interpreted faults show an overall pattern of criss-crossing fault zones, some of which appear to step over where they cross. Faults mapped by geologists suggest similar crossing patterns in exposed rocks along the mountain front. In low-lying areas, interpreted faults show zones of west-northwest-, north-, and northwest-striking faults that cross ~3 km (~2 mi) west-northwest of the town of Poncha Springs. More easterly striking faults extend east from this juncture. The associated aeromagnetic anomalies are likely caused by magnetic contrasts associated with faulted sediments that are concealed less than 200 m (656 ft) below the valley floor. The faults may involve basement rocks at greater depth as well. A relatively shallow (<300 m or <984 ft), faulted basement block is indicated under basin-fill sediments just north of the hot springs and south of the town of Poncha Springs.

Open-File Report

Analyses of gas, steam and water samples collected in and around Lassen Volcanic National Park, California, 1975–2002

This report contains physical and chemical data from gas, steam, and water samples collected between July 1975 and September 2002 from locations in and around Lassen Volcanic National Park, California. Data are compiled as tables in Excel spreadsheets and are organized by locale. Most data are keyed to 1 of 107 site codes that are shown on local- and regional-scale maps. Brief descriptions of terminology, sampling, and analytical methods are provided.

California

Stream-sediment samples reanalyzed for major, rare earth, and trace elements from ten 1:250,000-scale quadrangles, south-central Alaska, 2007-08

During the 1960s through the 1980s, the U.S. Geological Survey (USGS) conducted reconnaissance geochemical surveys of the drainage basins throughout most of the Anchorage, Bering Glacier, Big Delta, Gulkana, Healy, McCarthy, Mount Hayes, Nabesna, Talkeetna Mountains, and Valdez 1:250,000-scale quadrangles in Alaska as part of the Alaska Mineral Resource Assessment Program (AMRAP). These geochemical surveys provide data necessary to assess the potential for undiscovered mineral resources on public and other lands, and provide data that may be used to determine regional-scale element baselines. This report provides new data for 366 of the previously collected stream-sediment samples. These samples were selected for reanalysis because recently developed analytical methods can detect additional elements of interest and have lower detection limits than the methods used when these samples were originally analyzed. These samples were all analyzed for arsenic by hydride generation atomic absorption spectrometry (HGAAS), for gold, palladium, and platinum by inductively coupled plasma-mass spectrometry after lead button fire assay separation (FA/ICP-MS), and for a suite of 55 major, rare earth, and trace elements by inductively coupled plasma-atomic emission spectrometry and inductively coupled plasma-mass spectrometry (ICP-AES-MS) after sodium peroxide sinter at 450 degrees Celsius.

Open-File Report

Determination of the anionic surfactant di(ethylhexyl) sodium sulfosuccinate in water samples collected from Gulf of Mexico coastal waters before and after landfall of oil from the Deepwater Horizon oil spill, May to October, 2010

On April 22, 2010, the explosion on and subsequent sinking of the Deepwater Horizon oil drilling platform resulted in the release of crude oil into the Gulf of Mexico. At least 4.4 million barrels had been released into the Gulf of Mexico through July 15, 2010, 10 to 29 percent of which was chemically dispersed, primarily using two dispersant formulations. Initially, the dispersant Corexit 9527 was used, and when existing stocks of that formulation were exhausted, Corexit 9500 was used. Over 1.8 million gallons of the two dispersants were applied in the first 3 months after the spill. This report presents the development of an analytical method to analyze one of the primary surfactant components of both Corexit formulations, di(ethylhexyl) sodium sulfosuccinate (DOSS), the preliminary results, and the associated quality assurance/quality control (QA/QC) from samples collected from various points on the Gulf Coast between Texas and Florida. Seventy water samples and 8 field QC samples were collected before the predicted landfall of oil (pre-landfall) on the Gulf Coast, and 51 water samples and 10 field QC samples after the oil made landfall (post-landfall). Samples were collected in Teflon(Registered) bottles and stored at -20(degrees)C until analysis. Extraction of whole-water samples used sorption onto a polytetrafluoroethylene (PTFE) filter to isolate DOSS, with subsequent 50 percent methanol/water elution of the combined dissolved and particulate DOSS fractions. High-performance liquid chromatography/tandem mass spectrometry (LC/MS/MS) was used to identify and quantify DOSS by the isotope dilution method, using a custom-synthesized 13C4-DOSS labeled standard. Because of the ubiquitous presence of DOSS in laboratory reagent water, a chromatographic column was installed in the LC/MS/MS between the system pumps and the sample injector that separated this ambient background DOSS contamination from the sample DOSS, minimizing one source of blank contamination. Laboratory and field QA/QC for pre-landfall samples included laboratory reagent spike and blank samples, a total of 34 replicate analyses for the 78 environmental and field blank samples, and 11 randomly chosen laboratory matrix spike samples. Laboratory and field QA/QC for post-landfall samples included laboratory reagent spike and blank samples, a laboratory 'in-bottle' duplicate for each sample, and analysis of 24 randomly chosen laboratory matrix spike samples. Average DOSS recovery of 89(+/-)9.5 percent in all native (non-13C4-DOSS ) spikes was observed, with a mean relative percent difference between sample duplicates of 36 percent. The reporting limit for this analysis was 0.25 micrograms per liter due to blank limitations; DOSS was not detected in any samples collected in October (after oil landfall at certain study sites) above that concentration. It was detected prior to oil landfall above 0.25 micrograms per liter in 3 samples, but none exceeded the Environmental Protection Agency aquatic life criteria of 40 micrograms per liter.

Alabama, Florida, Louisiana, Mississippi, Texas

Aqueous geochemical data from the analysis of stream-water samples collected in June and July 2006 — Taylor Mountains 1:250,000-scale quadrangle, Alaska

We report on the chemical analysis of water samples collected from the Taylor Mountains 1:250,000-scale quadrangle, Alaska. Parameters for which data are reported include pH, conductivity, water temperature, major cation and anion concentrations, trace-element concentrations, and dissolved organic-carbon concentrations. Samples were collected as part of a multiyear U.S. Geological Survey project entitled ?Geologic and Mineral Deposit Data for Alaskan Economic Development.? Data presented here are from samples collected in June and July 2006. The data are being released at this time with minimal interpretation. This is the third release of aqueous geochemical data from this project; aqueous geochemical data from samples collected in 2004 and 2005 were published previously. The data in this report augment but do not duplicate or supersede the previous data release. Site selection was based on a regional sampling strategy that focused on first- and second-order drainages. Water sample site selection was based on landscape parameters that included physiography, wetland extent, lithological changes, and a cursory field review of mineralogy from pan concentrates. Stream water in the Taylor Mountains quadrangle is dominated by bicarbonate (HCO3-), although in a few samples more than 50 percent of the anionic charge can be attributed to sulfate (SO42-). The major-cation chemistry ranges from Ca2+/Mg2+ dominated to a mix of Ca2+/Mg2+/Na++K+. Generally, good agreement was found between the major cations and anions in the duplicate samples. Many trace elements in these samples were at or near the analytical method detection limit, but good agreement was found between duplicate samples for elements with detectable concentrations. All field blank major-ion and trace-element concentrations were below detection.

Alaska

Whole-rock and sulfide-mineral geochemical data for samples from volcanogenic massive sulfide deposits of the Bonnifield district, east-central Alaska

This Open-File Report presents geochemical data for outcrop and drill-core samples from volcanogenic massive sulfide deposits and associated metaigneous and metasedimentary rocks in the Wood River area of the Bonnifield mining district, northern Alaska Range, east-central Alaska. The data consist of major- and trace-element whole-rock geochemical analyses, and major- and trace-element analyses of sulfide minerals determined by electron microprobe and laser ablation&mdash;inductively coupled plasma&mdash;mass spectrometry (LA-ICP-MS) techniques. The PDF consists of text, appendix explaining the analytical methods used for the analyses presented in the data tables, a sample location map, and seven data tables. The seven tables are also available as spreadsheets in several file formats. Descriptions and discussions of the Bonnifield deposits are given in Dusel-Bacon and others (2004, 2005, 2006, 2007, 2010).

Alaska

Shallow stratigraphy of the Skagit River Delta, Washington, derived from sediment cores

Sedimentologic analyses of 21 sediment cores, ranging from 0.4 to 9.6 m in length, reveal that the shallow geologic framework of the Skagit River Delta, western Washington, United States, has changed significantly since 1850. The cores collected from elevations of 3.94 to -2.41 m (relative to mean lower low water) along four cross-shore transects between the emergent marsh and delta front show relatively similar environmental changes across an area spanning ~75 km 2 . Offshore of the present North Fork Skagit River and South Fork Skagit River mouths where river discharge is focused by diked channels through the delta, the entire 5&ndash;7-km-wide tidal flats are covered with 1&ndash;2 m of cross-bedded medium-to-coarse sands. The bottoms of cores, collected in these areas are composed of mud. A sharp transition from mud to a cross-bedded sand unit indicates that the tidal flats changed abruptly from a calm environment to an energetic one. This is in stark contrast to the Martha's Bay tidal flats north of the Skagit Bay jetty that was completed in the 1940s to protect the newly constructed Swinomish Channel from flooding and sedimentation. North of the jetty, mud ranging from 1 to 2 m thick drapes a previously silt- and sand-rich tidal flat. The silty sand is a sediment facies that would be expected there where North Fork Skagit River sedimentation occurred prior to jetty emplacement. This report describes the compositional and textural properties of the sediment cores by using geophysical, photographic, x-radiography, and standard sediment grain-size and carbon-analytical methods. The findings help to characterize benthic habitat structure and sediment transport processes and the environmental changes that have occurred across the nearshore of the Skagit River Delta. The findings will be useful for quantifying changes to nearshore marine resources, including impacts resulting from diking, river-delta channelization, shoreline development, and natural variations in fluvial-sediment inputs. These results also provide important quantitative data on the amount of sediment delivered to the nearshore from the Skagit River for use in calculating sediment budgets for application to watershed planning and wetland and coastal-ecosystem restoration.

Washington

Alaska Geochemical Database - Mineral Exploration Tool for the 21st Century - PDF of presentation

The U.S. Geological Survey has created a geochemical database of geologic material samples collected in Alaska. This database is readily accessible to anyone with access to the Internet. Designed as a tool for mineral or environmental assessment, land management, or mineral exploration, the initial version of the Alaska Geochemical Database - U.S. Geological Survey Data Series 637 - contains geochemical, geologic, and geospatial data for 264,158 samples collected from 1962-2009: 108,909 rock samples; 92,701 sediment samples; 48,209 heavy-mineral-concentrate samples; 6,869 soil samples; and 7,470 mineral samples. In addition, the Alaska Geochemical Database contains mineralogic data for 18,138 nonmagnetic-fraction heavy mineral concentrates, making it the first U.S. Geological Survey database of this scope that contains both geochemical and mineralogic data. Examples from the Alaska Range will illustrate potential uses of the Alaska Geochemical Database in mineral exploration. Data from the Alaska Geochemical Database have been extensively checked for accuracy of sample media description, sample site location, and analytical method using U.S. Geological Survey sample-submittal archives and U.S. Geological Survey publications (plus field notebooks and sample site compilation base maps from the Alaska Technical Data Unit in Anchorage, Alaska). The database is also the repository for nearly all previously released U.S. Geological Survey Alaska geochemical datasets. Although the Alaska Geochemical Database is a fully relational database in Microsoft&reg; Access 2003 and 2010 formats, these same data are also provided as a series of spreadsheet files in Microsoft&reg; Excel 2003 and 2010 formats, and as ASCII text files. A DVD version of the Alaska Geochemical Database was released in October 2011, as U.S. Geological Survey Data Series 637, and data downloads are available at http://pubs.usgs.gov/ds/637/ . Also, all Alaska Geochemical Database data have been incorporated into the interactive U.S. Geological Survey Mineral Resource Data web portal, available at http://mrdata.usgs.gov/ .

Alaska

A Markov chain analysis of the movements of juvenile salmonids, including sockeye salmon, in the forebay of McNary Dam, Washington and Oregon, 2006-09

Passage and survival data were collected at McNary Dam between 2006 and 2009. These data have provided critical information for resource managers to implement structural and operational changes designed to improve the survival of juvenile salmonids as they migrate past the dam. Much of the valuable information collected at McNary Dam was in the form of three-dimensional (hereafter referred to as 3-D) tracks of fish movements in the forebay. These data depicted the behavior of multiple species (in three dimensions) during different diel periods, spill conditions, powerhouse operations, and testing of the surface bypass structures (temporary spillway weirs; TSWs). One of the challenges in reporting 3-D results is presenting the information in a manner that allows interested parties to summarize the behavior of many fish over many different conditions across multiple years. To accomplish this, we used a Markov chain analysis to characterize fish movement patterns in the forebay of McNary Dam. The Markov chain analysis allowed us to numerically summarize the behavior of fish in the forebay. This report is the second report published in 2012 that uses this analytical method. The first report included only fish released as part of the annual studies conducted at McNary Dam. This second report includes sockeye salmon that were released as part of studies conducted by the Chelan and Grant County Public Utility Districts at mid-Columbia River dams. The studies conducted in the mid-Columbia used the same transmitters as were used for McNary Dam studies, but transmitter pulse width was different between studies. Additionally, no passive integrated transponder tags were implanted in sockeye salmon. Differences in transmitter pulse width resulted in lower detection probabilities for sockeye salmon at McNary Dam. The absence of passive integrated transponder tags prevented us from determining if fish passed the powerhouse through the juvenile bypass system (JBS) or turbines. To facilitate comparison among species in this report, we combined JBS and turbine passage for yearling Chinook salmon, steelhead, and subyearling Chinook salmon even though we were able to differentiate between passage through the JBS or turbines for these three species. Information on passage proportions through the JBS and turbines can be found in the first report. Numerically summarizing the behavior of juvenile salmonids in the forebay of McNary Dam using the Markov chain analysis allowed us to confirm what had been previously summarized using visualization software. For example, within the powerhouse region, passage proportions among the three powerhouse areas were often greater in the southern and middle areas of the powerhouse compared to the northern area of the powerhouse for yearling and subyearling Chinook salmon. The opposite generally was observed for steelhead. The results of this analysis also allowed us to confirm and quantify the extent of milling behavior that was observed for steelhead. For fish that were first detected in the powerhouse region, less than 0.10 of the steelhead, on average, passed within each of the powerhouse areas. Instead, steelhead transitioned to adjoining areas in the spillway before passing the dam. In comparison, greater than 0.20 of the Chinook salmon passed within each of the powerhouse areas. Less milling behavior was observed for all species for fish that first approached the spillway. Compared to the powerhouse areas, a higher proportion of fish, regardless of species, passed the spillway areas and fewer transitioned to adjoining areas in the powerhouse. In addition to quantifying what had been previously speculated about the behavior of fish in the forebay of McNary Dam, the Markov chain analysis refined our understanding of how fish behavior and passage can be influenced by changes to the operations and structure of McNary Dam. For example, the addition of TSWs to the spillway area clearly influenced the passage of fish. Previous results have been reported showing that TSWs increased passage through non-turbine routes and the fish-track videos indicated, in general, how fish behaved before passing the TSWs. However, the analysis presented in this report allowed us to better understand how fish transitioned across the face of the dam before passing the TSWs and resulted in a quantitative way to measure the effect of moving the location of the TSWs from year to year. Installation of the TSWs in bays 22 and 20 clearly increased passage proportions through the southern one-third of the spillway area for all species, most significantly for steelhead. When the TSWs were moved to bays 19 and 20 in 2008, overall passage through the southern one-third of the spillway remained higher than 2006, but decreased from what was observed in 2007. Shifting the TSWs to the north decreased the proportion of fish passing through the TSWs and increased the number of fish that transitioned to adjoining areas before passing the dam. Perhaps the most interesting new information to come out of the two-step Markov chain analysis relates to how the performance of the TSWs was influenced by their proximity to the powerhouse. During 2007, the highest proportion of fish passing through TSW 22 was for fish that transitioned from the powerhouse area. In contrast, a relatively low proportion of fish passed through TSW 20 after coming from the powerhouse area. Instead, the proportion of fish that passed TSW 20 after coming from the northern part of the spillway was twice as high as the proportion of fish that passed through TSW 20 after coming from the powerhouse. During 2008, the TSW in bay 22 was moved to bay 19, leaving the TSW in bay 20 as the one closest to the powerhouse. As was the case when a TSW was located in bay 22, the proportion of fish passing through TSW 20 after coming from the powerhouse was higher than the proportion of fish passing TSW 20 after coming from the northern part of the spillway. Passage proportions for fish passing through TSW 19, the farthest north of the two TSWs during 2008, was higher for fish that came from the northern part of the spillway compared to the proportion of fish that passed through TSW 19 after coming from the powerhouse. The Markov chain analysis provided a mathematical way to characterize fish behavior in the forebay of McNary Dam and helped refine our understanding of how fish movements were influenced by operational and structural changes at the dam. The numerical information used to quantify the behavior of fish also can be used to construct simulations to examine how proposed fish passage structures might influence passage of juvenile salmonids. To demonstrate this, we used the results of the Markov chain analysis to examine how a virtual fish collector located in the center of the powerhouse might influence passage of juvenile salmonids at McNary Dam.

Oregon;Washington

Compilation of gallium resource data for bauxite deposits

Gallium (Ga) concentrations for bauxite deposits worldwide have been compiled from the literature to provide a basis for research regarding the occurrence and distribution of Ga worldwide, as well as between types of bauxite deposits. In addition, this report is an attempt to bring together reported Ga concentration data into one database to supplement ongoing U.S. Geological Survey studies of critical mineral resources. The compilation of Ga data consists of location, deposit size, bauxite type and host rock, development status, major oxide data, trace element (Ga) data and analytical method(s) used to derive the data, and tonnage values for deposits within bauxite provinces and districts worldwide. The range in Ga concentrations for bauxite deposits worldwide is <10 to 812 parts per million (ppm), with an average of 57 ppm. Gallium concentrations in lateritic bauxites range from below detection (< 8 ppm) to 146 ppm; the average concentration is 57 ppm Ga. The average Ga concentration for karst bauxite deposits is 58 ppm with a range between <10 to 180 ppm Ga. As a result, there are no substantial differences in gallium concentrations between karst- and laterite-type bauxites. We calculate the range in geologically available Ga in bauxite deposits worldwide between 30 and 82,720 metric tons (t), with an average of 14,909 t.

Open-File Report

Relation between Enterococcus concentrations and turbidity in fresh and saline recreational waters, coastal Horry County, South Carolina, 2003–04

Bacteria related to the intestinal tract of humans and other warm-blooded animals have been detected in fresh and saline surface waters used for recreational purposes in coastal areas of Horry County, South Carolina, since the early 2000s. Specifically, concentrations of the facultative anaerobic organism, Enterococcus , have been observed to exceed the single-sample regulatory limit of 104 colony forming units per 100 milliliters of water. Water bodies characterized by these concentrations are identified on the 303(d) list for impaired water in South Carolina; moreover, because current analytical methods used to monitor Enterococcus concentrations take up to 1 day for results to become available, water-quality advisories are not reflective of the actual health risk. To determine if Enterococcus concentrations in surface water could be assessed in a more rapid manner, an investigation was completed between 2003 and 2004 in the study area of coastal Horry County, South Carolina. The study was designed to assess the relation between Enterococcus concentrations and turbidity, which, unlike Enterococcus concentrations, can be measured continuously by using a multiparameter water-quality sensor and results reported in real time. In 2003, three water-quality data collection stations that included a multiparameter water-quality sensor that measured turbidity were located in three representative surface-water basins in coastal Horry County, South Carolina. All these locations had previous reports of high Enterococcus concentrations. At each station, the water-quality sensor was placed in the water column and continuously measured turbidity, pH, specific conductivity, dissolved oxygen, and temperature. Each water-quality data collection station also monitored instantaneous precipitation and wind speed and direction. Surface-water samples were collected at each station during events characterized by no precipitation and by some recorded precipitation using manual and automatic methods, and analyzed for Enterococcus concentrations. A comparison of Enterococcus concentrations in surface-water samples collected simultaneously using both methods indicated a positive relation, although the average percent relative difference between the methods was 46 percent. During a period of no precipitation in February 2004, no relation between turbidity and Enterococcus concentrations was observed for surface-water samples collected at the water-quality data collection station located in the channel that drains a freshwater swamp. In contrast, during periods of precipitation in March and August 2004 at this location, a positive relation was observed between turbidity and Enterococcus concentrations in surface-water samples; that is, water samples characterized by higher turbidity also contained higher Enterococcus concentrations. At the water-quality data collection station located in a channel that drains to the surf zone of the Atlantic Ocean, no relation was observed between turbidity and Enterococcus concentrations during periods of either no precipitation (July 2004) or precipitation (August 2004). At this location, the turbidity was inversely related to relative tide height, high turbidity was observed during low tide when freshwater flowed seaward, and low turbidity was observed during high tide when saline seawater flowed landward. The positive relation observed between turbidity and Enterococcus concentrations in surface water at the water-quality data collection station located in the channel that drains a freshwater swamp may be attributed to bacterial survival in the abundant channel bed sediments that characterized this more naturalized area. Surface-water bed sediments collected near each water-quality data collection station and the surf zone were incubated in static microcosms in the laboratory and analyzed for Enterococcus concentrations over time. Enterococcus concentrations continued to persist in bed sediments collected in the channel that drains the swamp even after almost 4 months of incubation. Conversely, enterococci were not observed to persist in bed sediments characterized by high specific conductance. Although it is currently (2016) unknown whether this persistence of enterococci demonstrates growth or viability, the data indicate that enterococci can exist in channel bed-sediment environments outside of a host for a long time. This observation confirms previous reports that challenge the use of Enterococcus concentrations as an indicator of the recent introduction of fecal-related material and the associated acute risk to other pathogens.

South Carolina

GIS-based identification of areas that have resource potential for lode gold in Alaska

Several comprehensive, data-driven geographic information system (GIS) analyses were conducted to assess prospectivity for lode gold in Alaska. These analyses use available geospatial datasets of lithologic, geochemical, mineral occurrence, and geophysical data to build models for recognizing different types of gold deposits within physiographic units defined by stream drainage basins that are approximately 100 square kilometers in area. The analytical methods successfully delineated areas in the State that contain known lode gold deposits and occurrences, providing some measure of confidence in their ability to predict gold prospectivity in areas of unknown lode gold potential. The results of our analyses indicate high prospectivity in a few areas scattered around the State that are not known to contain lode gold deposits. In addition to assessing the potential for lode gold deposits in Alaska, we designed analyses to distinguish different lode gold deposit types, including orogenic, reduced-intrusion-related, epithermal, and gold-bearing porphyry. These can primarily be differentiated using their unique trace element geochemical fingerprints and elemental enrichments, which reflect the characteristics of the geologic environment and chemistry of the ore-forming fluids. We identified multiple parameters that would discriminate the different types of gold deposits, but owing to the limits of available data, the compositional similarity of ore-forming fluids among some types of lode gold deposits, and overlapping geologic environments, distinguishing deposit types at the state scale in Alaska remains problematic. These limitations resulted in overlapping areas of prospectivity for different deposit types, highlighting the challenges for targeted gold exploration in Alaska. Adjustment of some scoring parameters and recharacterization at smaller scales to highlight individual mineral systems for application of prospectivity analyses may be helpful at a district scale. At a regional scale, the aerial overlap of individual deposit type analyses reinforces confidence in prospectivity for a lode gold resource in a drainage basin. Our analysis for undivided lode gold deposits will be the most practical analysis for landuse decisions in which delineation of areas that have confident potential for gold deposits in general is the primary goal. Data-driven GIS analysis for lode gold potential in Alaska, although limited by the size and uneven coverage of available datasets, objectively indicates prospectivity in areas where exposure is good as well as in areas under cover. The results of our analyses show medium to high prospectivity in areas that surround known deposits, indicating an overall expansion of areas that have the potential to contain gold deposits. Exploration in these areas may help improve the balance between the volume of gold produced in placer districts statewide and the relatively low volume of identified lode resources that contribute to these placer deposits. The results of our analyses can help focus future investigations in areas that show prospectivity but are not known to contain gold deposits, as well as in areas where data are lacking and the geology is poorly understood, and acquisition of additional data may help better define and constrain gold prospectivity.

Alaska

Chemical analysis of archived stream-sediment samples, Alaska

Geochemical data are presented for more than 1,500 archived stream-sediment samples and accompanying quality control samples. The archived sediments were reanalyzed to improve the stream geochemical dataset for Alaska and to support ongoing U.S. Geological Survey (USGS) studies. Sediment samples were primarily from the USGS Mineral Resources Program’s sample archive in Denver, Colorado, but a few were from the Alaska Geological & Geophysical Surveys’ Geologic Materials Center in Anchorage, Alaska. All samples were submitted to the USGS contract laboratory, AGAT Laboratories, for analysis. All samples were analyzed using a 60-element analytical method involving fusion of the sample by sodium peroxide, dissolution of the fusion cake by nitric acid, and elemental analysis by inductively coupled plasma-optical emission spectroscopy and inductively coupled plasma-mass spectroscopy. Additionally, 106 samples from the Nixon Fork area were analyzed by a second multi-element method involving decomposition by a mixture of hydrochloric, nitric, perchloric, and hydrofluoric acids and the elemental analysis of the resulting solution by inductively coupled plasma-optical emission spectroscopy and inductively coupled plasma-mass spectroscopy. The latter method was used because the detection limit is lower for several elements including As, Cd, Pb, and Sb. Mercury concentrations in 296 samples from southeast Alaska were determined using a cold-vapor atomic absorption spectrometry method. The concentration data from the archived samples are presented along with concentration data from the standard reference material that was submitted with the samples.

Alaska

Guide to per- and polyfluoroalkyl substances (PFAS) sampling within Natural Resource Damage Assessment and Restoration

Per- and polyfluoroalkyl substances (PFAS) are synthetic chemicals with a nondegradable fluorinated carbon backbone that have been incorporated in countless industrial and commercial applications. Because PFAS are nondegradable, they have been detected in all environmental media, indicating extensive global contamination. The unique physiochemical properties of PFAS and their complex interactions with environmental matrices create a great challenge for researchers when selecting site-specific sample matrices, sampling logistics, various analytical methods, and data interpretation. The widespread contamination and the potential toxicity of PFAS to human and environmental health have resulted in the proposed designation of two commonly used PFAS as hazardous substances, which may prompt new requirements for reporting, regulatory action, and site cleanup. For researchers involved in natural resource damage assessment efforts, understanding the multifaceted dynamics of the environmental fate and transport of PFAS will be essential for appropriate sample collections, analyses, and data interpretation. This guide aims to provide fundamental concepts and considerations involved with environmental sampling for PFAS during site assessments.

Open-File Report

Select elements of concern in surface water of three hydrologic basins (Delaware River, Illinois River, and Upper Colorado River)—Data screening for the development of spatial and temporal models

The report focuses on the screening of previously published concentration data associated with 12 elements of concern (aluminum, arsenic, cadmium, chromium, copper, iron, mercury, manganese, lead, selenium, uranium, and zinc) measured in stream surface waters of three hydrologic basins (Delaware River Basin, Illinois River Basin, and the Upper Colorado River Basin). The purpose of this analysis is to determine what subsets of the original dataset (containing more than 1,500,000 observations) may be most suitable for each of two types of modeling efforts. The first type of modeling envisions a machine learning approach to determine which geospatial attributes are most significant in describing the spatial distribution of elemental concentrations within a basin. The second type of modeling envisions a stepwise regression approach to develop multivariable models that can be used to determine high resolution time-series estimates of elemental concentrations or loads at discrete U.S. Geological Survey real-time stream surface water sites. These site-specific temporal models are based on continuous measurements of available discharge and (or) in situ sensor data (temperature, pH, turbidity, dissolved oxygen, specific conductance, and (or) fluorescent dissolved organic matter) as the explanatory variables. The data screening for both model types considered historical trends in analytical methods and detection quantitation limits, the extent of censored data, data density, and environmental relevance with respect to three U.S. Environmental Protection Agency water quality thresholds (drinking water guidelines, human health criteria, and aquatic life criteria). The result of this analysis was the production of a final list of potential models deemed suitable for further development based upon the data exclusion (or inclusion) scheme developed herein for each model type. In both cases, the final models included mostly the three crustal elements (iron, manganese, and aluminum) that are found at comparatively high concentrations in surface water, whereas most of the more pernicious elements were excluded from the final model lists owing to various data limitations. The one exception to this was arsenic, for which the existing data were sufficient at three U.S. Geological Survey real-time sites for potential further development of time-series models.

Colorado, Delaware, Illinois, Indiana, Maryland, N

Radiochemical analyses of surface water from U.S. Geological Survey hydrologic bench-mark stations

The U.S. Geological Survey's program for collecting and analyzing surface-water samples for radiochemical constituents at hydrologic bench-mark stations is described. Analytical methods used during the study are described briefly and data obtained from 55 of the network stations in the United States during the period from 1967 to 1971 are given in tabular form. Concentration values are reported for dissolved uranium, radium, gross alpha and gross beta radioactivity. Values are also given for suspended gross alpha radioactivity in terms of natural uranium. Suspended gross beta radioactivity is expressed both as the equilibrium mixture of strontium-90/yttrium-90 and as cesium-137. Other physical parameters reported which describe the samples include the concentrations of dissolved and suspended solids, the water temperature and stream discharge at the time of the sample collection.

Open-File Report