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At least 433 records · Page 24Linked to original sources

Quantifying long-term risks to sea otters from the 1989 'Exxon Valdez' oil spill: reply to Harwell & Gentile (2013)

Recovery of sea otter populations in Prince William Sound (PWS), Alaska, has been delayed for more than 2 decades following the 1989 ‘Exxon Valdez’ oil spill. Harwell & Gentile (2013; Mar Ecol Prog Ser 488:291–296) question our conclusions in Bodkin et al. (2012; Mar Ecol Prog Ser 447:273-287) regarding adverse effects that oil lingering in the environment may have on sea otters. They agree that exposure may continue, but disagree that it constitutes a significant risk to sea otters. In Bodkin et al. (2012), we suggested that subtle effects of chronic exposure were the most reasonable explanation for delayed recovery of the sea otter population in areas of western PWS, where shorelines were most heavily oiled. Here, we provide additional information on the ecology of sea otters that clarifies why the toxicological effects of oral ingestion of oil do not reflect all effects of chronic exposure. The full range of energetic, behavioral, and toxicological concerns must be considered to appraise how chronic exposure to residual oil may constrain recovery of sea otter populations.

Alaska↗

Diagenetic barite-pyrite-wurtzite formation and redox signatures in Triassic mudstone, Brooks Range, northern Alaska

Mineralogical and geochemical studies of interbedded black and gray mudstones in the Triassic part of the Triassic-Jurassic Otuk Formation (northern Alaska) document locally abundant barite and pyrite plus diverse redox signatures. These strata, deposited in an outer shelf setting at paleolatitudes of ~45 to 60°N, show widespread sedimentological evidence for bioturbation. Barite occurs preferentially in black mudstones (TOC = 0.93–6.46 wt%), forming displacive euhedral crystals with pyrite inclusions and rims, and late albite inclusions or intergrowths. Pyrite also occurs as small (3–20 μm) framboids, discontinuous laminae, euhedral and anhedral crystals, and replacements of barite and fossils (mainly radiolarians). Paragenetically early wurtzite is present as clusters of very small (1–3 μm) aggregates of radiating crystals 0.5 to 1.0 μm long with cores of organic matter that overgrow framboidal pyrite; later wurtzite forms 10- to 30-μm bladed crystals. Equant grains (3–30 μm) and small (20 μm) angular clusters of zinc sulfide that include <1-μm-long, comb-like structures are sphalerite or wurtzite, or both. Minor siderite forms euhedral crystals intergrown with albite that enclose wurtzite and barite. Illite shows intergrowths with sphalerite; rare K-feldspar is intergrown with barite. Formation of these minerals and assemblages is attributed to early diagenetic processes. Whole-rock geochemical data for 15 samples show large ranges in redox proxies including Post Archean Average Shale (PAAS)-normalized enrichment factors (EFs) for V, U, Mo, and Re, and Al-normalized ratios for V, U, and Mo. Results for most black mudstones, with or without abundant barite and/or pyrite, suggest deposition within an oxygen minimum zone. Cerium anomalies, PAAS-normalized and calculated on a detrital-free basis, range widely from 0.49 to 0.96 and may reflect diagenetic overprinting by Ce-depleted fluids. Considering data for both black and gray mudstones, the overall geochemical pattern together with evidence from pyrite framboid sizes suggest that redox conditions fluctuated greatly from euxinic to oxic, like the redox profiles reported for modern shelf sediments offshore Peru and Namibia. The euxinic redox signatures in some Otuk black mudstones may correlate with widespread Early to Middle Triassic ocean anoxic events proposed for other regions. Calculations of median EFs for trace elements in Otuk black mudstones reveal both enrichments and depletions. Normalizations to the median composition of the three least-mineralized black mudstones show that barite- and/or pyrite-rich samples display large (>50%) positive changes for Li (+80.4%), V (+75.6%), Sr (+75.9%), Ba (+790%), Cu (+92.1%), Ni (+169%), Ag (+156%), Au (+3091%), As (+109%), Sb (+476%), and Se (+205%); Zn shows a moderate positive change of +42.1%. Moderate negative changes are evident only for Ge (−47.2%) and W (−30.6%). The local enrichments may reflect one or more factors including redox variations in bottom waters and pore fluids, element mobility during diagenesis, and selective fractionation into minerals such as barite, pyrite, and wurtzite. Anomalously low U/Al and UEF values, compared to those for other modern and ancient organic-rich sediments and sedimentary rocks, are attributed to increased solubility and loss of U during bioturbation-related oxygenation in the subsurface. Physicochemical constraints on barite, pyrite, and wurtzite formation are informed by use of a pH-fO2 plot constructed at 10 °C. Based on paragenetic evidence for multistage deposition of these three minerals, together with the presence of illite intergrown with ZnS and K-feldspar with barite, proposed diagenetic trends involve an increase in pH and fO2 related to the ingress of sulfate-rich pore fluids during bioturbation, followed by a return to lower then higher pH and fO2 conditions linked to carbon, sulfur, barium, and iron cycling during diagenesis. Labile Ba of marine pelagic origin was mobilized from organic-rich sediment upward to the sulfate-methane transition zone where barite precipitated during the interaction of reduced Ba- and CH4-rich fluids with sulfate-bearing pore fluids. The formation of paragenetically early wurtzite (ZnS) crystals, as well as locally high EF values for Cu, Ni, Ag, and Au, is attributed to metal enrichment of pore fluids, with sources being derived in part from water-column deposition from hydrothermal plumes related to coeval Triassic seafloor vent systems including a volcanogenic massive sulfide deposit in British Columbia and the Wrangellia Large Igneous Province in Alaska.

Alaska↗

Deep magmatic degassing versus scrubbing: Elevated CO2 emissions and C/S in the lead-up to the 2009 eruption of Redoubt Volcano, Alaska

We report CO 2, SO 2 , and H 2 S emission rates and C/S ratios during the five months leading up to the 2009 eruption of Redoubt Volcano, Alaska. CO 2 emission rates up to 9018 t/d and C/S ratios ≥30 measured in the months prior to the eruption were critical for fully informed forecasting efforts. Observations of ice-melt rates, meltwater discharge, and water chemistry suggest that surface waters represented drainage from surficial, perched reservoirs of condensed magmatic steam and glacial meltwater. These fluids scrubbed only a few hundred tonnes/day of SO 2 , not the >2100 t/d SO 2 expected from degassing of magma in the mid- to upper crust (3–6.5 km), where petrologic analysis shows the final magmatic equilibration occurred. All data are consistent with upflow of a CO 2 -rich magmatic gas for at least 5 months prior to eruption, and minimal scrubbing of SO 2 by near-surface groundwater. The high C/S ratios observed could reflect bulk degassing of mid-crustal magma followed by nearly complete loss of SO 2 in a deep magmatic-hydrothermal system. Alternatively, high C/S ratios could be attributed to decompressional degassing of low silica andesitic magma that intruded into the mid-crust in the 5 months prior to eruption, thereby mobilizing the pre-existing high silica andesite magma or mush in this region. The latter scenario is supported by several lines of evidence, including deep long-period earthquakes (−28 to −32 km) prior to and during the eruption, and far-field deformation following the onset of eruptive activity.

Alaska↗

Carbonate margin, slope, and basin facies of the Lisburne Group (Carboniferous-Permian) in northern Alaska

The Lisburne Group (Carboniferous-Permian) consists of a carbonate platform that extends for >1000 km across northern Alaska, and diverse margin, slope, and basin facies that contain world-class deposits of Zn and Ba, notable phosphorites, and petroleum source rocks. Lithologic, paleontologic, isotopic, geochemical, and seismic data gathered from outcrop and subsurface studies during the past 20 years allow us to delineate the distribution, composition, and age of the off-platform facies, and to better understand the physical and chemical conditions under which they formed. The southern edge of the Lisburne platform changed from a gently sloping, homoclinal ramp in the east to a tectonically complex, distally steepened margin in the west that was partly bisected by the extensional Kuna Basin (~200 by 600 km). Carbonate turbidites, black mudrocks, and radiolarian chert accumulated in this basin; turbidites were generated mainly during times of eustatic rise in the late Early and middle Late Mississippian. Interbedded black mudrocks (up to 20 wt% total organic carbon), granular and nodular phosphorite (up to 37 wt% P 2 O 5 ), and fine-grained limestone rich in radiolarians and sponge spicules formed along basin margins during the middle Late Mississippian in response to a nutrient-rich, upwelling regime. Detrital zircons from a turbidite sample in the western Kuna Basin have mainly Neoproterozoic through early Paleozoic U-Pb ages (~900-400 Ma), with subordinate populations of Mesoproterozoic and late Paleoproterozoic grains. This age distribution is similar to that found in slightly older rocks along the northern and western margins of the basin. It also resembles age distributions reported from Carboniferous and older strata elsewhere in northwestern Alaska and on Wrangel Island. Geochemical and isotopic data indicate that suboxic, denitrifying conditions prevailed in the Kuna Basin and along its margins. High V/Mo, Cr/Mo, and Re/Mo ratios (all marine fractions [MF]) and low MnO contents (<0.01 wt%) characterize Lisburne black mudrocks. Low Qmf/Vmf ratios (mostly 0.8-4.0) suggest moderately to strongly denitrifying conditions in suboxic bottom waters during siliciclastic and phosphorite sedimentation. Elevated to high Mo contents (31-135 ppm) in some samples are consistent with seasonal to intermittent sulfidic conditions in bottom waters, developed mainly along the basin margin. High d 15 N values (6-120) imply that the waters supplying nutrients to primary producers in the photic zone had a history of denitrification either in the water column or in underlying sediments. Demise of the Lisburne platform was diachronous and reflects tectonic, eustatic, and environmental drivers. Southwestern, south-central, and northwestern parts of the platform drowned during the Late Mississippian, coincident with Zn and Ba metallogenesis within the Kuna Basin and phosphogenesis along basin margins. This drowning was temporary (except in the southwest) and likely due to eutrophication associated with upwelling and sea-level rise enhanced by regional extension, which allowed suboxic, denitrifying waters to form on platform margins. Final drowning in the southcentral area occurred in the Early Pennsylvanian and also may have been linked to regional extension. In the northwest, platform sedimentation persisted into the Permian; its demise there appears to have been due to increased siliciclastic input. Climatic cooling may have produced additional stress on parts of the Lisburne platform biota during Pennsylvanian and Permian times.

Alaska↗

Accuracy assessment of the U.S. Geological Survey National Elevation Dataset, and comparison with other large-area elevation datasets: SRTM and ASTER

The National Elevation Dataset (NED) is the primary elevation data product produced and distributed by the U.S. Geological Survey. The NED provides seamless raster elevation data of the conterminous United States, Alaska, Hawaii, U.S. island territories, Mexico, and Canada. The NED is derived from diverse source datasets that are processed to a specification with consistent resolutions, coordinate system, elevation units, and horizontal and vertical datums. The NED serves as the elevation layer of The National Map, and it provides basic elevation information for earth science studies and mapping applications in the United States and most of North America. An important part of supporting scientific and operational use of the NED is provision of thorough dataset documentation including data quality and accuracy metrics. The focus of this report is on the vertical accuracy of the NED and on comparison of the NED with other similar large-area elevation datasets, namely data from the Shuttle Radar Topography Mission (SRTM) and the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER).

Open-File Report↗

Bouguer gravity map of Alaska

The Bouguer gravity map of Alaska has been compiled from about 30,000 Alaska land gravity measurements plus approximately 40,000 km of surface-ship gravimeter traverses over the bordering continental shelves. The compilation thus represents nearly three times as much land data and ten times as much marine data as were available for one previous Alaskan gravity map (Barnes, 1969b) and fiftyfold increase since the original compilation of Alaskan land gravity data (Wollard and others, 1960). However, data from many parts of the state are still too scattered (inset 1) for accurate contouring; such deficiencies are most serious in the southwestern part of the state and in the Bering Sea. The map shows the variation of the simple Bouguer anomaly field and is thus comparable to the existing Bouguer gravity map of the conterminous 48 states (Wollard and Joesting, 1964). On land the Bouguer anomaly contours reflect the regional variations of gravity better than free-air anomaly contours, which are not adequately corrected for topography. However, in oceanic areas the free-air anomaly is less sensitive to bottom topography than the Bouguer anomaly. Accordingly, the map coverage includes available data from the continental shelves where the bottom relief is small, but it has not been extended to cover the continental slope, the deep ocean, or the islands of the Aleutian arc, where the free-air anomaly would be a better indicator of the regional variation of gravity, and where Bouguer gravity are only available for a few small areas (Miller and Bath, 1969; Healy and Kibler, 1976a and 1976b).

Alaska↗

Priority-pollutant trace elements in streambed sediments of the Cook Inlet basin, Alaska, 1998-2000

Trace element concentrations in 48 streambed sediment samples collected at 47 sites in the Cook Inlet Basin, Alaska, were compared to concentrations from studies in the conterminous United States using identical methods and to Probable Effect Concentrations. Concentrations of arsenic, chromium, mercury, and nickel in the 0.063-mm size fraction of streambed sediments from the Cook Inlet Basin were elevated relative to reference sites in the conterminous United States. Concentrations of cadmium, lead, and zinc were highest at the most urbanized site in Anchorage and at two sites downstream from an ore body in Lake Clark National Park and Preserve. At least 35 percent of the 48 samples collected in the Cook Inlet Basin exceeded the Probable Effect Concentration for arsenic, chromium, or nickel. More than 50 percent of the samples were considered to have low potential toxicity for cadmium, lead, mercury, nickel, selenium, and zinc. A Probable Effect Concentration quotient that reflects the combined toxicity of arsenic, cadmium, chromium, copper, lead, mercury, nickel, and zinc was exceeded in 44 percent of the samples from the Cook Inlet Basin. The potential toxicity was high in the Denali and Lake Clark National Parks and Preserves where organic carbon concentrations in streambed sediments were low. However, potential toxicity results should be considered in context with the very small amounts of fine-grained sediment present in the streambed sediments of the Cook Inlet Basin.

Alaska↗

Stable isotope analysis and satellite tracking reveal interspecific resource partitioning of nonbreeding albatrosses off Alaska

Albatrosses (Diomedeidae) are the most threatened family of birds globally. The three North Pacific species (Phoebastria Reichenbach, 1853) are listed as either endangered or vulnerable, with the population of Short-tailed Albatross (Phoebastria albatrus (Pallas, 1769)) less than 1% of its historical size. All North Pacific albatross species do not currently breed sympatrically, yet they do co-occur at-sea during the nonbreeding season. We incorporated stable isotope analysis with the first simultaneous satellite-tracking study of all three North Pacific albatross species while sympatric on summer (nonbreeding season) foraging grounds off Alaska. Carbon isotope ratios and tracking data identify differences in primary foraging domains of continental shelf and slope waters for Short-tailed Albatrosses and Black-footed Albatrosses (Phoebastria nigripes (Audubon, 1839)) versus oceanic waters for Laysan Albatrosses (Phoebastria immutabilis (Roths-child, 1893)). Short-tailed and Black-footed albatrosses also fed at higher trophic levels than Laysan Albatrosses. The relative trophic position of Black-footed and Laysan albatrosses, however, appears to differ between nonbreeding and breeding seasons. Spatial segregation also occurred at a broader geographic scale, with Short-tailed Albatrosses ranging more north into the Bering Sea than Black-footed Albatrosses, which ranged more to the southeast, and Laysan Albatrosses more to the southwest. Differences in carbon isotope ratios among North Pacific albatross species during the nonbreeding season likely reflect the relative proportion of neritic (more carbon enriched) versus oceanic (carbon depleted) derived nutrients, and possible differential use of fishery discards, rather than latitudinal differences in distribution.

Canadian Journal of Zoology↗

Revisiting the 1899 earthquake series using integrative geophysical analysis in Yakutat Bay, Alaska

A series of large earthquakes in 1899 affected southeastern Alaska near Yakutat and Disenchantment Bays. The largest of the series, a M W 8.2 event on 10 September 1899, generated an ~12-m-high tsunami and as much as 14.4 m of coseismic uplift in Yakutat Bay, the largest coseismic uplift ever measured. Several complex fault systems in the area are associated with the Yakutat terrane collision with North America and the termination of the Fairweather strike-slip system, but because faults local to Yakutat Bay have been incompletely or poorly mapped, it is unclear which fault system(s) ruptured during the 10 September 1899 event. Using marine geophysical data collected in August 2012, we provide an improved tectonic framework for the Yakutat area, which advances our understanding of earthquake hazards. We combined 153 line km of 2012 high-resolution multichannel seismic (MCS) reflection data with compressed high-intensity radar pulse (Chirp) profiles, basin-scale MCS data, 2018 seafloor bathymetry, published geodetic models and thermochronology data, and previous measurements of coseismic uplift to better constrain fault geometry and subsurface structure in the Yakutat Bay area. We did not observe any active or concealed faults crossing Yakutat Bay in our high-resolution data, requiring faults to be located entirely onshore or nearshore. We interpreted onshore faults east of Yakutat Bay to be associated with the transpressional termination of the Fairweather fault system, forming a series of splay faults that exhibit a horsetail geometry. Thrust and reverse faults on the west side of the bay are related to Yakutat terrane underthrusting and collision with North America. Our results include an updated fault map, structural model of Yakutat Bay, and quantitative assessment of uncertainties for legacy geologic coseismic uplift measurements. Additionally, our results indicate the 10 September 1899 rupture was possibly related to stress loading from the earlier Yakutat terrane underthrusting event of 4 September 1899, with the majority of 10 September coseismic slip occurring on the Esker Creek system on the northwest side of Yakutat Bay. Limited (~2 m) coseismic or postseismic slip associated with the 1899 events occurred on faults located east of Yakutat Bay.

Alaska↗

Environmental geochemistry of shale-hosted Ag-Pb-Zn massive sulfide deposits in northwest Alaska: Natural background concentrations of metals in water from mineralized areas

Red Dog, Lik and Drenchwater are shale-hosted stratiform Ag-Pb-Zn massive sulfide deposits in the northwestern Brooks Range. Natural background concentrations of metals in waters from the undisturbed (unmined) Drenchwater prospect and Lik deposit were compared to pre-mining baseline studies conducted at Red Dog. The primary factors affecting water chemistry are the extent of exposure of the deposits, the grade of mineralization, the presence of carbonate reeks in the section, and the proportion of Fe-sulfide in the ore. Surface water samples from the Drenchwater prospect, which has pyrite-dominant mineralization exposed in outcrop, have pH values as low as 2.8 and high dissolved concentrations of metals including as much as 95 mg 1-1 Al, 270 mg 1-1 Fe, 8 ??1-1 Cd, 10 ??1-1 Pb, and 2600 ??1-1 Zn, with As up to 26 ??g1-1. Surface waters from the Red Dog deposit prior to mining were also acidic and metal-rich, however, dissolved metal concentrations in Red Dog waters were many times greater. The higher metal concentrations in Red Dog waters reflect the high Zn grades and the abundant sphalerite, pyrite, and galena that were present in outcrop prior to mining. In contrast, despite significant mineralization at the Lik deposit, carbonate rocks in the section buffer the system, resulting in less acidic, mostly near-neutral pH values with low concentrations of most metals except Zn.

Applied Geochemistry↗

Postglacial vegetation history of Mitkof Island, Alexander Archipelago, southeastern Alaska

An AMS radiocarbon-dated pollen record from a peat deposit on Mitkof Island, southeastern Alaska provides a vegetation history spanning ∼12,900 cal yr BP to the present. Late Wisconsin glaciers covered the entire island; deglaciation occurred > 15,400 cal yr BP. The earliest known vegetation to develop on the island (∼12,900 cal yr BP) was pine woodland ( Pinus contorta ) with alder ( Alnus ), sedges (Cyperaceae) and ferns (Polypodiaceae type). By ∼12,240 cal yr BP, Sitka spruce ( Picea sitchensis ) began to colonize the island while pine woodland declined. By ∼11,200 cal yr BP, mountain hemlock ( Tsuga mertensiana ) began to spread across the island. Sitka spruce-mountain hemlock forests dominated the lowland landscapes of the island until ∼10,180 cal yr BP, when western hemlock ( Tsuga heterophylla ) began to colonize, and soon became the dominant tree species. Rising percentages of pine, sedge, and sphagnum after ∼7100 cal yr BP may reflect an expansion of peat bog habitats as regional climate began to shift to cooler, wetter conditions. A decline in alders at that time suggests that coastal forests had spread into the island's uplands, replacing large areas of alder thickets. Cedars ( Chamaecyparis nootkatensis , Thuja plicata ) appeared on Mitkof Island during the late Holocene.

Quaternary Research↗

Katmai volcanic cluster and the great eruption of 1912

In June 1912, the world's largest twentieth century eruption broke out through flat-lying sedimentary rocks of Jurassic age near the base of Trident volcano on the Alaska Peninsula. The 60 h ash-flow and Plinian eruptive sequence excavated and subsequently backfilled with ejecta a flaring funnel-shaped vent since called Novarupta. The vent is adjacent to a cluster of late Quaternary stratocones and domes that have released about 140 km 3 of magma in the past 150 k.y. Although the 1912 vent is closest to the Trident group and is also close to Mageik and Griggs volcanoes, it was the summit of Mount Katmai, 10 km east of Novarupta, that collapsed during the eruption to form a 5.5 km 3 caldera. Many earthquakes, including 14 in the range M 6−7, took place during and after the eruption, releasing 250 times more seismic energy than the 1991 caldera-forming eruption of the Philippine volcano, Pinatubo. The contrast in seismic behavior may reflect the absence of older caldera faults at Mount Katmai, lack of upward (subsidence opposing) magma flow owing to lateral magma withdrawal in 1912, and the horizontally stratified structure of the thick shale-rich Mesozoic basement. The Katmai caldera compensates for only 40% of the 13 km 3 of 1912 magma erupted, which included 7–8 km 3 of slightly zoned high-silica rhyolite and 4.5 km 3 of crystal-rich dacite that grades continuously into 1 km 3 of crystal-rich andesite. We have now mapped, sampled, and studied the products of all 20 components of the Katmai volcanic cluster. Pyroxene dacite and silicic andesite predominate at all of them, and olivine andesite is also common at Griggs, Katmai, and Trident volcanoes, but basalt and rhyodacite have erupted only at Mount Katmai. Rhyolite erupted only in 1912 and is otherwise absent among Quaternary products of the cluster. Pleistocene products of Mageik and Trident and all products of Griggs are compositionally distinguishable from those of 1912 at Novarupta. Holocene products of Mount Martin and Trident are closer in composition to the andesite-dacite array of 1912, but they reveal consistent differences. The affinity of the 1912 suite is closest with the array of products erupted by the Southwest Katmai cone, the edifice that had produced the only pre-1912 rhyodacite as well as the largest prehistoric Plinian eruption in the cluster. It is doubtful that any 1912 magma had been stored beneath Novarupta or Trident, and there is no evidence that more than one magma chamber erupted in 1912. Despite a compositional gap separating the aphyric rhyolite from the very crystal-rich andesite-dacite continuum, isotopic and chemical affinities linking all the 1912 ejecta and the continuity of all those ejecta in magmatic temperature and oxygen fugacity suggest that the rhyolite originated principally by incremental upward expulsion of interstitial melt from subjacent andesite-dacite mush. A large reservoir of such hot crystal mush is required both as the residue of rhyolitic melt separation and as a proximate heat source to thermally sustain the nearly aphyric condition of the overlying rhyolite. A model is presented for a unitary zoned chamber beneath Mount Katmai.

Alaska↗

Evolution of the submarine–subaerial edifice of Bogoslof volcano, Alaska, during its 2016–2017 eruption based on analysis of satellite imagery

The 2016–2017 eruption of Bogoslof volcano involved at least 70 detected eruptive events between mid-December 2016 and August 30, 2017. Acquisition of high-resolution satellite imagery throughout the duration of the eruptive period allowed us to document and map the various morphologic changes that occurred on the subaerial part of Bogoslof Island. The emplacement of pyroclastic-flow and surge deposits caused the island to increase in area by about 1.5 km 2 . The dominant volcanic landforms of the eruption were a series of tuff rings emplaced around various submarine vents. Many of the tuff rings were mantled with surface dunes and impressive amounts of ballistic ejecta, likely derived from erupting magma bodies or previously emplaced submarine lava domes. Debris-flow deposits and surface channels extending over tuff ring surfaces apparent in multiple satellite images are evidence for explosive ejection of seawater. In most cases, erupting vents were initially submarine or began at subaerial lava domes and were largely flooded by seawater suggesting that water-magma ratios were likely high. Under such conditions where water is abundant, eruptive products typically reflect a high degree of water involvement and are dominated by the formation of wet tephra jets and flows and associated deposits typically consist of fine ash and lapilli, contain accretionary lapilli and ash aggregates, and usually form tuff cones and mounds. We observed none of these features in our analysis of satellite data or during our examination of eruptive deposits on Bogoslof Island in 2018. On the contrary, the dominant landform associated with the Bogoslof eruption was tuff rings. The development of tuff rings and surface dunes are commonly associated with the formation of pyroclastic base surges that are by comparison emplaced relatively dry. Dry base surge deposits can be generated from phreatomagmatic explosions involving superheated steam. It is possible that shallow submarine, magma–wet sediment interactions were a characteristic and possibly a dominant eruptive process of the 2016–2017 Bogoslof eruption.

Alaska↗

Upper Triassic igneous rocks of the southern Kenai Peninsula, Alaska – Prelude to Early Jurassic subduction along the western Wrangellia composite terrane margin

New U–Pb zircon geochronology identifies a latest Triassic (ca 214–201 Ma) igneous suite of tuff, hypabyssal dikes, and a pluton on the southern Kenai Peninsula, Alaska. The igneous suite was emplaced within Upper Triassic sedimentary rocks along the southern margin of Western Wrangellia, the western-most fragment of the Wrangellia composite terrane. The igneous rocks range from mafic (50.6% SiO 2 ) to felsic (78.3% SiO 2 ), characteristically have less than 1.55% K 2 O, and generally have low trace element abundances. The tonalitic and trondhjemitic magmas were largely sourced in mafic-rich lower crust and incompletely assimilated quartz and other mineral xenocrysts are common. Fractionation involving plagioclase and amphibole is indicated for some magmas and composite intrusions and igneous xenoliths indicate magma mixing was possible. Paleozoic and Precambrian inherited zircons and initial 87 Sr/ 86 Sr (0.704103–0.705609) and 143 Nd/ 144 Nd (0.512396–0.512777) ratios indicate that the Western Wrangellia crustal sources are heterogeneous and contain sialic components. The latest Triassic magmatism reflects processes that preceded Early Jurassic subduction along the Wrangellia composite terrane and Pacific Ocean plate boundary. These processes involved heating and melting of mantle lithosphere and lower crust as mantle instabilities accompanied the breaking of the plate boundary linkages. The Late Triassic transition to subduction along the Wrangellia composite terrane margin coincided with the transition to subduction cessation in the Late Triassic arcs of the western Intermontane terranes of Canada. The shift to subduction along the outboard Wrangellia composite terrane margin marks the beginning of the Pacific Ocean–Cordillera plate interactions that came to dominate the tectonic evolution of the northern Cordillera from the Early Jurassic to today.

Alaska↗

Heavy-mineral trends in the Beaufort Sea

Sediments of the Beaufort Sea, off the North Slope of Alaska contain a great variety of heavy minerals. These include garnet, chrome spinel, augite, pigeonite, diopside, hornblende, enstatite, hypersthene, epidote, clinozoisite, zoisite, apatite, tourmaline, chloritoid, sphene, zircon, and opaque minerals. Much rarer constituents are glaucophane, lamprobolite, rutile, kyanite, staurolite, and riebeckite. The heavy-mineral fractions that were not treated with hydrochloric acid contain "iron-stained aggregates", grains of unidentifiable material encrusted with limonite. Samples containing relatively high percentages of iron-stained aggregates and altered opaque minerals occur in depths less than 10 m and within 16 km from shore. Garnet increases in abundance from east to west, which corresponds to a similar increase in garnet abundance in coastal outcrops of the Gubik Formation sands. Only garnet and iron-stained aggregates appear to have source-related distribution patterns. The other heavy minerals lack distinct distributive provinces, reflecting an environment dominated by intense mixing by ice-gouging and bioturbation and a homogenous source area. Waves and currents are not strong enough to sort sediments at depths greater than 10 m except during summer storms. The source of the Beaufort Sea heavy minerals is dominated by contributions from the Alaskan North Slope deposits of Tertiary and younger age. The Colville River, largest in the region, is probably the most influential in transporting sediments, but because of wave and current—mixing of sediments on the shelf, exact contributions from each river drainage cannot be ascertained. Coastal erosion of the Gubik Formation is probably at least as important as the Colville River in supplying heavy minerals to the Beaufort Sea.

Alaska↗

Event classification, seismicity, and eruption forecasting at Great Sitkin Volcano, Alaska: 1999–2023

The frequency content of volcanogenic seismicity is often used to classify events and their spatial and temporal progression is then used to map subsurface volcanic processes. The progression of volcano-seismic events and associated source processes also plays a critical role in eruption forecasting. Here we develop and evaluate a computerized methodology for characterizing volcano-seismic event types using Frequency Index and Average Peak Frequency. We apply and test this technique at Great Sitkin Volcano, Alaska, classifying over 9000 hypocenters between 1999 and 2023. This 24-year time span covers periods of seismic quiescence, earthquake activity on nearby tectonic (bookshelf) faults, precursory unrest from 2016 to 2021, and the explosive onset in May 2021 of the ongoing effusive eruption. We use the spatial and temporal evolution of classified event types to map the active volcanic and tectonic processes, develop a conceptual model of the subsurface magmatic system, and perform a retrospective analysis of eruption forecasts at Great Sitkin Volcano between 2016 and the present. The classification and progression of hypocenters suggests the subsurface Great Sitkin Volcano magmatic system consists of a mid- to lower- crustal source zone between 10 and 40 km depth and an upper crustal magma storage area between −1 and 10 km depth (hypocenter depth is referenced to sea level and negative depths reflect height above sea level). The earliest precursors occurred in July 2016 and consisted of deep long-period and volcano-tectonic earthquakes at mid-crustal depths suggesting the subsequent unrest and eruption were triggered by a deeper intrusion of magma. This mid-crustal seismic activity was immediately followed by the onset upper-crustal long-period events and volcano-tectonic earthquakes VTs suggesting a strong linkage between the shallow and deeper portions of the magmatic system. The upper crustal area was likely capped by the 1974 lava dome until the magmatic explosion on May 26, 2021.

Alaska↗

Paleozoic sedimentary rocks in the Red Dog Zn-Pb-Ag district and vicinity, western Brooks Range, Alaska: provenance, deposition, and metallogenic significance

Geochemical analyses of Paleozoic sedimentary rocks in the western Brooks Range reveal a complex evolutionary history for strata surrounding the large Zn-Pb-Ag deposits of the Red Dog district. Data for major elements, trace elements, and rare earth elements (REE) were obtained on 220 samples of unaltered and unmineralized siliciclastic rocks from the Upper Devonian-Lower Mississippian Endicott Group (Hunt Fork Shale, Noatak Sandstone, Kanayut Conglomerate, Kayak Shale), the overlying Carboniferous Lisburne Group (Kuna Formation, unnamed drowned shelf facies), and the Pennsylvanian-Permian Siksikpuk Formation. Major base metal sulfide deposits of the region are present only in the Kuna Formation, which in the Red Dog district comprises siliceous black shale and black chert, minor limestone (calcareous radiolarite), and sparse lithic turbidite and bedded siliceous rock. Gray and rare black shales of the Kayak Shale and common black shales of the Kuna Formation are anomalously low in iron (avg Fe/Ti = 6.25 and 6.34, respectively) relative to other Paleozoic shales in the region (9.58-10.6) and to average shales worldwide (10.1-10.5). In contrast, the bedded siliceous rocks contain appreciable hematite (avg Fe/Ti = 35.0) and high U/Ti and REE/Ti ratios that are interpreted to reflect low amounts of detrital material and a major Fe-rich eolian component. Geochemical data (e.g., MnO <0.01 wt %; avg Cr = 317 ppm), sizes of framboidal pyrite grains, and limited bioturbation suggest anoxic and denitrifying depositional conditions for most black shales of the Kuna Formation; low Mo/Ti ratios argue against euxinic (sulfate-reducing) conditions. Organic-rich black shales of the Kuna Formation with up to 8.4 wt percent C organic and gray to black shales of the Kayak Shale with up to 4.1 wt percent C organic typically have only sparse pyrite (<1 wt % S) and very low iron-limited S/C ratios (mostly <0.2). Immobile element plots (e.g., Th-Zr/10-Sc) suggest that source terranes for all of the formations were dominated by one or more felsic-rich continental arcs; a small proportion of recycled sediments is present locally. A minor mafic igneous component also occurs in several shales of the Kuna and Siksikpuk Formations. High average values for the chemical index of alteration [Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O)] &infin; 100 for shales of the Endicott Group (76.4-81.5) imply moderate to intense chemical weathering in source areas of these sediments. A lower average for black shales of the Kuna Formation (73.7) does not require such weathering. Textural and geochemical data record the effects of diagenetic and/or hydrothermal fluid flow in some of the Paleozoic rocks. Mobility of P, F, U, and light REE is documented in black shales of the Kuna Formation by phosphate replacements of carbonate clasts and of matrix material surrounding the clasts. A relatively low average Ce/Ce* value of 0.73 for P-poor black shales of the Kuna Formation ( < 0.05 wt % P 2 O 5 ) and a similar Ce/Ce* value of 0.78 for a siderite concretion in Kayak Shale suggest that these diagenetic fluids were oxidizing. Many shales of the Kuna Formation have high (K 2 O &infin; 100)/(K 2 O + Al 2 O 3 ) ratios of 21.0 to 23.0, which contrast with low ratios of generally <18.0 for shales of the underlying Endicott Group. The high ratios in shales of the Kuna Formation reflect preferential reaction of smectite to illite during the Jurassic-Cretaceous Brookian orogeny, owing to high silica activities in pore fluids that were generated by the dissolution of abundant biogenic silica. The distribution and composition of Paleozoic strata in the western Brooks Range may have played a fundamental role in Zn-Pb mineralization of the Red Dog district. In our model, deposition and early lithification of biogenic chert and bedded siliceous rocks in the upper part of the Kuna Formation served as a regional hydrologic seal, acting as a cap rock to heat and hydrothermal fluids during Late Mississippian base-metal mineralization. Equally important was the iron-poor composition of black shales of the Kuna Formation (i.e., low Fe/Ti ratios), which limited synsedimentary pyrite formation in precursor sediments, resulting in significant H 2 S production in pore waters through the interaction of aqueous sulfate with abundant organic matter. This H 2 S may have been critical to the subsurface deposition of the huge quantities of Zn and Pb in the district. On the basis of this model, we propose that low Fe/Ti and S/C ratios in black shale sequences are potential basin-scale exploration guides for giant sediment-hosted, stratiform Zn-Pb-Ag deposits.

Alaska↗

Source and progression of a submarine landslide and tsunami: The 1964 Great Alaska earthquake at Valdez

Like many subduction zone earthquakes, the deadliest aspects of the 1964 M = 9.2 Alaska earthquake were the tsunamis it caused. The worst of these were generated by local submarine landslides induced by the earthquake. These caused high runups, engulfing several coastal towns in Prince William Sound. In this paper, we study one of these cases in detail, the Port Valdez submarine landslide and tsunami. We combine eyewitness reports, preserved film, and careful posttsunami surveys with new geophysical data to inform numerical models for landslide tsunami generation. We review the series of events as recorded at Valdez old town and then determine the corresponding subsurface events that led to the tsunami. We build digital elevation models of part of the pretsunami and posttsunami fjord‐head delta. Comparing them reveals a ~1500 m long region that receded 150 m to the east, which we interpret as the primary delta landslide source. Multibeam imagery and high‐resolution seismic reflection data identify a ~400 m wide chute with hummocky deposits at its terminus, which may define the primary slide path. Using these elements we run hydrodynamic models of the landslide‐driven tsunamis that match observations of current direction, maximum inundation, and wave height at Valdez old town. We speculate that failure conditions at the delta front may have been influenced by manmade changes in drainage patterns as well as the fast retreat of Valdez and other glaciers during the past century.

Alaska↗