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At least 415 records · Page 23Linked to original sources

USGS2016

Inter-comparison of three-dimensional models of volcanic plumes

We performed an inter-comparison study of three-dimensional models of volcanic plumes. A set of common volcanological input parameters and meteorological conditions were provided for two kinds of eruptions, representing a weak and a strong eruption column. From the different models, we compared the maximum plume height, neutral buoyancy level (where plume density equals that of the atmosphere), and level of maximum radial spreading of the umbrella cloud. We also compared the vertical profiles of eruption column properties, integrated across cross-sections of the plume (integral variables). Although the models use different numerical procedures and treatments of subgrid turbulence and particle dynamics, the inter-comparison shows qualitatively consistent results. In the weak plume case (mass eruption rate 1.5 × 10 6 kg s − 1 ), the vertical profiles of plume properties (e.g., vertical velocity, temperature) are similar among models, especially in the buoyant plume region. Variability among the simulated maximum heights is ~ 20%, whereas neutral buoyancy level and level of maximum radial spreading vary by ~ 10%. Time-averaging of the three-dimensional (3D) flow fields indicates an effective entrainment coefficient around 0.1 in the buoyant plume region, with much lower values in the jet region, which is consistent with findings of small-scale laboratory experiments. On the other hand, the strong plume case (mass eruption rate 1.5 × 10 9 kg s − 1 ) shows greater variability in the vertical plume profiles predicted by the different models. Our analysis suggests that the unstable flow dynamics in the strong plume enhances differences in the formulation and numerical solution of the models. This is especially evident in the overshooting top of the plume, which extends a significant portion (~ 1/8) of the maximum plume height. Nonetheless, overall variability in the spreading level and neutral buoyancy level is ~ 20%, whereas that of maximum height is ~ 10%. This inter-comparison study has highlighted the different capabilities of 3D volcanic plume models, and identified key features of weak and strong plumes, including the roles of jet stability, entrainment efficiency, and particle non-equilibrium, which deserve future investigation in field, laboratory, and numerical studies.

Journal of Volcanology and Geothermal Research↗

USGS2003

Immobilization of cobalt by sulfate-reducing bacteria in subsurface sediments

We investigated the impact of sulfate-reduction on immobilization of metals in subsurface aquifers. Co 2+ was used as a model for heavy metals. Factors limiting sulfate-reduction dependent Co 2+ immobilization were tested on pure cultures of sulfate-reducing bacteria, and in sediment columns from a landfill leachate contaminated aquifer. In the presence of 1 mM Co 2+ , the growth of pure cultures of sulfate-reducing bacteria was not impacted. Cultures of Desulfovibrio desulfuricans, Desulfotomaculum gibsoniae , and Desulfomicrobium hypogeia removed greater than 99.99% of the soluble Co 2+ when CoCl 2 was used with no chelators. The above cultures and Desulfoarcula baarsi removed 98-99.94% of the soluble Co(II) when the metal was complexed with the model ligand nitrilotriacetate (Co-NTA). Factors controlling the rate of sulfate-reduction based Co 2+ precipitation were investigated in sediment-cobalt mixtures. Several electron donors were tested and all but toluene accelerated soluble Co 2+ loss. Ethanol and formate showed the greatest stimulation. All complex nitrogen sources tested slowed and decreased the extent of Co 2+ removal from solution relative to formate-amended sediment incubations. A range of pH values were tested (6.35-7.81), with the more alkaline incubations exhibiting the largest precipitation of Co 2+ . The immobilization of Co 2+ in sediments was also investigated with cores to monitor the flow of Co 2+ through undisturbed sediments. An increase in the amount of Co 2+ immobilized as CoS was observed as sulfate reduction activity was stimulated in flow through columns. Both pure culture and sediment incubation data indicate that stimulation of sulfate reduction is a viable strategy in the immobilization of contaminating metals in subsurface systems.

Geomicrobiology Journal↗

USGS2022

Synthetic evaluation of infrasonic multipole waveform inversion

Acoustic source inversions estimate the mass flow rate of volcanic explosions or yield of chemical explosions and provide insight into potential source directionality. However, the limitations of applying these methods to complex sources and their ability to resolve a stable solution have not been investigated in detail. We perform synthetic infrasound waveform inversions that use 3-D Green’s functions for a variety of idealized and realistic deployment scenarios using both a flat plane and Yasur volcano, Vanuatu as examples. We investigate the ability of various scenarios to retrieve the input source functions and relative amplitudes for monopole and multipole (monopole and dipole) inversions. Infrasound waveform inversions appear to be a robust method to quantify mass flow rates from simple sources (monopole) using deployments of infrasound sensors placed around a source, but care should be taken when analyzing and interpreting results from more complex acoustic sources (multipole) that have significant directional components. In the examples we consider the solution is stable for monopole inversions with a signal-to-noise ratio greater than five and the dipole component is small. For most scenarios investigated, the vertical dipole component of the multipole explosion source is poorly constrained and can impact the ability to recover the other source term components. Because multipole inversions are ill-posed for many deployments, a low residual does not necessarily mean the proper source vector has been recovered. Synthetic studies can help investigate the limitations and place bounds on information that may be missing using monopole and multipole inversions for potentially directional sources.

Journal of Geophysical Research-Solid Earth↗

USGS1981

Reservoir properties of submarine- fan facies: Great Valley sequence, California

Submarine-fan sandstones of the Great Valley sequence west of the Sacramento Valley, California, have low porosities and permeabilities (64 samples averaged 10.1% porosity and 0.87 millidarcies permeability). However, petrography and scanning electron microscope studies indicate that most sands in almost all submarine fan environments are originally porous and permeable. Thin turbidite sandstones deposited in areas dominated by shale in outer-fan, basin-plain, and overbank environments are cemented mainly by calcite; shale dewatering is inferred to contribute to rapid cementation early in the burial process. Sands deposited in inner- and middle-fan channels within interchannel and fan-fringe environments that contain only thin shale beds have small percentages of intergranular matrix or cement. The original porosity is substantially reduced mechanically at shallow depths and by pressure solution at deeper levels. Permeability decreases systematically with increasing age of the rocks, presumably as a result of increasing burial depths. Computer-run stepwise regression analyses show that the porosity is inversely related to the percentage of calcite cement. Such parameters as the contents of quartz, feldspar, and unstable rock fragments have no correlative effect on either porosity or permeability. The results reported here indicate original porosity and permeability can be high in deep-water submarine fans and that fan environments dominated by sand (with high sand/shale ratios) are more likely to retain higher porosity and permeability to greater depths than sand interbedded with thick shale sequences.

Journal of Sedimentary Petrology↗

USGS1999

Observations on preferential flow and horizontal transport of nitrogen fertilizer in the unsaturated zone

A study site underlain by a claypan soil was instrumented to examine the transport of fertilizer nitrogen (N) under corn ( Zea mays L.) cultivation. The study was designed to examine N transport within the unsaturated zone and in intedlow (the saturated flow of water on top of the claypan). A 15 N-labeled fertilizer (labeled N), bromide (Br), and chloride (Cl) were used as field tracers. Rapid or prolonged infiltration events allowed water and dissolved solutes to perch on the claypan for brief periods. However, a well-developed network of preferential flow paths quickly diverted water and solutes through the claypan and into the underlying glacial till aquifer. Excess fertilizer N in the unsaturated zone supplied a continuous, but declining input of N to ground water for a period of 15 mo after a single fertilizer application. Calculated solute velocities through the claypan matrix (6.4 × 10 −6 cm s −1 ) were similar to horizontal transport rates along the claypan (3.5 to 7.3 × 10 −6 cm s −1 ) but much slower than infiltration rates determined for preferential flow paths (1.67 × 10 −3 cm s −1 ). These flow paths accounted for 35% of the transport. A seasonally variable, dual mode of transport (matrix and preferential flow) prevented the daypan from being an effective barrier to vertical transport. Simulations of selected field observations, conducted using the variably saturated two-dimensional flow and transport model, VS2DT, confirmed the presence of a dual flow regime in the claypan.

Journal of Environmental Quality↗

USGS2025

Evaluating the applicability of the generalized power-law rating curve model: With applications to paired discharge-stage data from Iceland, Sweden, and the United States

Hydrologic research and operations make extensive use of streamflow time series. In most applications, these time series are estimated from rating curves, which relate flow to some easy-to-measure surrogate, typically stage. The conventional stage-discharge rating takes the form of a segmented power law, with one segment for each hydrologic control at the stream gauge. However, these ratings are notoriously difficult to estimate with numerical methods, so that most are still developed manually. A few automated algorithms have emerged, but their use is sporadic, and their relative merits have not been rigorously assessed. One recently developed approach, the generalized power-law, avoids the segmenting problem by representing the power-law exponent as a Gaussian process. On the one hand, this representation is more flexible and easier to fit, but its flexibility might allow unrealistic solutions, so it needs to be tested under a range of conditions to assess its operational viability. This study evaluates the generalized power-law rating curve model by applying it to observations from 180 streams in Iceland, Sweden, and the United States. Overall, the model proved flexible and computationally robust, generating convincing rating curves across a range of geographic settings and was comparable to curves generated by a segmented rating model. Lastly, we propose a model-selection algorithm based on information theory to help identify the best rating curve model for a particular stream gauge.

Journal of Hydrology↗

USGS2021

Review: “Jacob’s Zoo”— How using Jacob’s method for aquifer testing leads to more intuitive understanding of aquifer characteristics

The interpretation of aquifer responses to pumping tests is an important tool for assessing aquifer geometry and properties, which are critical in the assessment of water resources or in environmental remediation. However, the responses of aquifers, measured by time-drawdown relationships in monitoring wells, are nonunique solutions that are affected by many factors. Jacob’s Zoo is a collection of graphical interpretations that allows students and practitioners to develop an intuitive feel for how natural hydrogeological systems work, and develop a set of skills that provide a better understanding of aquifer properties far beyond interpretation of pumping tests. Jacob’s Zoo, based on the work of Jacob (1950), fosters a deeper understanding, although few practitioners realize the full utility of the method. Jacob CE (1950) Flow of groundwater, In: Rouse H (ed) Engineering Hydraulics, Wiley, New York. P 321–386.

Hydrogeology Journal↗

USGS2025

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal↗

USGS2006

A review of methods to estimate cause-specific mortality in presence of competing risks

Estimating cause-specific mortality is often of central importance for understanding the dynamics of wildlife populations. Despite such importance, methodology for estimating and analyzing cause-specific mortality has received little attention in wildlife ecology during the past 20 years. The issue of analyzing cause-specific, mutually exclusive events in time is not unique to wildlife. In fact, this general problem has received substantial attention in human biomedical applications within the context of biostatistical survival analysis. Here, we consider cause-specific mortality from a modern biostatistical perspective. This requires carefully defining what we mean by cause-specific mortality and then providing an appropriate hazard-based representation as a competing risks problem. This leads to the general solution of cause-specific mortality as the cumulative incidence function (CIF). We describe the appropriate generalization of the fully nonparametric staggered-entry Kaplan–Meier survival estimator to cause-specific mortality via the nonparametric CIF estimator (NPCIFE), which in many situations offers an attractive alternative to the Heisey–Fuller estimator. An advantage of the NPCIFE is that it lends itself readily to risk factors analysis with standard software for Cox proportional hazards model. The competing risks–based approach also clarifies issues regarding another intuitive but erroneous “cause-specific mortality” estimator based on the Kaplan–Meier survival estimator and commonly seen in the life sciences literature.

Journal of Wildlife Management↗

USGS1983

Mechanical and chemical compaction in fine-grained shallow-water limestones

Artificial compaction of in-situ cores of sediments resulted in: 1) reduction of sediment thickness by 50 percent and more; 2) reduction of initial porosities of 65 to 75 percent to 35 to 45 percent; 3) creation of megascopic textures almost identical to many ancient lime mud- and wackestone; 4) creation of organic, wispy "stylolite-like" layers; 5) chemical compaction, evidenced by thin sections showing quartz grains piercing mollusc shells without causing fractures and SEM evidence of solutional interfitting of 1 to 4-mu m-size aragonitic carbonate grains; 6) obliteration of pellets and birdseye or fenestral voids in those sediments where early cementation was lacking; obliteration of identifiable marine grasses and vertical "root" tube voids; 8) mashing of sediment-filled circular burrows to produce ellipsoidal structures. Significant mechanical compaction resulted from pressures simulating less than 1,000 ft of burial. Increasing loads to more than 10,000 ft did not significantly increase compaction. Chemical compaction was detected only in cores compacted to pressures greater than 10,000 ft of burial. These experiments suggest that chemical compaction would begin at much shallower depths given geologic time. Experiments that caused chemical compaction lend support to the hypothesis that cement required to produce a low-porosity/low-permeability fine-grained limestone is derived internally. Dissolution, ion diffusion, and reprecipitation are the most likely processes for creating significant thicknesses of dense limestones. Continuation of chemical compaction after significant porosity reduction necessitates expulsion of connate fluids, possibly including hydrocarbons.--Modified journal abstract.

Journal of Sedimentary Petrology↗

USGS2019

Timescales of water-quality change in a karst aquifer, south-central Texas

Understanding the drivers and timescales over which groundwater quality changes informs groundwater management, use, and protection. To better understand timescales of water-quality change over short (daily to monthly) and long (seasonal to decadal) timescales, the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Enhanced Trends Network (ETN) program instrumented and sampled three wells in the Edwards aquifer in south-central Texas. The wells were instrumented to provide high-frequency continuous (subhourly) water-quality data (temperature, pH, specific conductance, and dissolved oxygen), which were augmented by the collection of discrete samples (about 6 per year) for a range of geochemical constituents (including selected isotopes and age tracers). ETN data (2013–2017) are considered with data from additional sites for the same time period, and also historical records (over more than 80 years) of climatic and hydrologic conditions. During the four-year study, hydrologic conditions transitioned from very dry to very wet. Sites in the updip/unconfined part of the aquifer showed notable changes in water level and geochemistry (1) in response to rainfall/recharge events, and (2) over the multiyear dry/wet cycle. Sites in the downdip/confined part of the aquifer showed changes in water level/spring discharge over similar timescales, although the response is more muted. Geochemistry at the downdip/confined sites, however, varied slowly and minimally, indicating that the geochemical response of the deeper aquifer is decoupled from recent hydrologic responses. Changes at the updip/unconfined sites reflect mixing with recent recharge, whereas the downdip/confined sites were dominated by mineral-solution reactions resulting from longer (decadal) residence times. Mean groundwater ages interpreted from measured age tracers and lumped parameter models range from 7 to >700 years (where mixed with premodern downdip water) but were mostly modern. The aquifer is characterized by updip-to-downdip trends in geochemistry with respect to water-rock interaction and groundwater age. Fourier spectral analysis of historical records indicate hydrologic variability has occurred at dominant periods of 30 and 15 years; in conjunction with age tracers, these results provide insight into timescales at which the aquifer’s public supply is vulnerable to changes in the water quality of recharge.

Texas↗

USGS2019

Reanalysis of the U.S. Geological Survey Benchmark Glaciers: Long-term insight into climate forcing of glacier mass balance

Mountain glaciers integrate climate processes to provide an unmatched signal of regional climate forcing. However, extracting the climate signal via intercomparison of regional glacier mass balance records can be problematic when methods for extrapolating and calibrating direct glaciological measurements are mixed or inconsistent. To address this problem, we reanalyzed and compared long-term mass balance records from the U.S. Geological Survey Benchmark Glaciers. These five glaciers span maritime and continental climate regimes of the western United States and Alaska. Each glacier exhibits cumulative mass loss since the mid-20th century, with average rates ranging from –0.58 to –0.30 m water equivalent (w.e.) a-1. We produced a set of solutions using different extrapolation and calibration methods to inform uncertainty estimates, which range from 0.22–0.44 m w.e. a-1. Mass losses are primarily driven by increasing summer warming. Continentality exerts a stronger control on mass loss than latitude. Similar to elevation, topographic shading, snow redistribution, and glacier surface features often exert first-order control on mass balance. The reanalysis underscores the value of geodetic calibration to resolve mass balance magnitude, as well as the irreplaceable value of direct measurements in contributing to process-based understanding of glacier mass balance.

Journal of Glaciology↗

USGS2011

Characteristics, distribution, origin, and significance of opaline silica observed by the Spirit rover in Gusev crater, Mars

The presence of outcrops and soil (regolith) rich in opaline silica (∼65–92 wt % SiO 2 ) in association with volcanic materials adjacent to the “Home Plate” feature in Gusev crater is evidence for hydrothermal conditions. The Spirit rover has supplied a diverse set of observations that are used here to better understand the formation of silica and the activity, abundance, and fate of water in the first hydrothermal system to be explored in situ on Mars. We apply spectral, chemical, morphological, textural, and stratigraphic observations to assess whether the silica was produced by acid sulfate leaching of precursor rocks, by precipitation from silica‐rich solutions, or by some combination. The apparent lack of S enrichment and the relatively low oxidation state of the Home Plate silica‐rich materials appear inconsistent with the originally proposed Hawaiian analog for fumarolic acid sulfate leaching. The stratiform distribution of the silica‐rich outcrops and their porous and brecciated microtextures are consistent with sinter produced by silica precipitation. There is no evidence for crystalline quartz phases among the silica occurrences, an indication of the lack of diagenetic maturation following the production of the amorphous opaline phase.

Journal of Geophysical Research E: Planets↗

USGS2012

Chemical bonding in the outer core: high-pressure electronic structures of oxygen and sulfur in metallic iron

From its density the outer core is believed to be an alloy of iron and a light element such as sulfur or oxygen. The nature of the light element in the core is an important constraint for theories of the Earth's formation. In this paper the electronic structures of oxygen and sulfur impurities in metallic iron are investigated to determine if pressure, temperature, and composition-induced changes in bonding might affect phase equilibria along the Fe-FeS and Fe-FeO binaries. The electronic structure of sulfur in metallic iron is consistent with the miscibility between Fe and FeS liquids. Volume compression strengthens the Fe-S bond, and it is expected that at sufficiently high pressure, sulfur can substitute for Fe and give solid solution behavior between Fe and FeS. In contrast, the electronic structure of oxygen in metallic iron shows that oxygen cannot act as a substitutional impurity (replacing Fe). This explains the observed miscibility gap on the Fe-FeO binary at 1 atm pressure. Volume compression does not greatly change the electronic structure if oxygen substitutes for iron in bcc and fcc iron. Iron-oxygen bonding does occur, however, if oxygen occupies interstitial sites. Insofar as the molar volume of FeO incorporated as interstitial oxygen in metallic iron is smaller than that of pure FeO, the incorporation of oxygen into metallic iron may be favored under the pressures of the Earth's core.

Journal of Geophysical Research↗

USGS2007

United States‐Mexican border watershed assessment: Modeling nonpoint source pollution in Ambos Nogales

Ecological considerations need to be interwoven with economic policy and planning along the United States‐Mexican border. Non‐point source pollution can have significant implications for the availability of potable water and the continued health of borderland ecosystems in arid lands. However, environmental assessments in this region present a host of unique issues and problems. A common obstacle to the solution of these problems is the integration of data with different resolutions, naming conventions, and quality to create a consistent database across the binational study area. This report presents a simple modeling approach to predict nonpoint source pollution that can be used for border watersheds. The modeling approach links a hillslopescale erosion‐prediction model and a spatially derived sediment‐delivery model within a geographic information system to estimate erosion, sediment yield, and sediment deposition across the Ambos Nogales watershed in Sonora, Mexico, and Arizona. This paper discusses the procedures used for creating a watershed database to apply the models and presents an example of the modeling approach applied to a conservation‐planning problem.

Arizona, Sonoma↗

USGS2018

Changes in long-term water quality of Baltimore streams are associated with both gray and green infrastructure

The steadily rising global urban population has placed substantial strain on urban water quality, and this strain is projected to increase for the foreseeable future. Considerable attention has been given to the hydrological and physico-chemical effects of urbanization on stream ecosystems. However, due to the relative infancy of the field of urban ecology, long-term water quality analyses in urban streams are sparse. Using a 15-year stream chemistry monitoring record from Baltimore, MD, USA, we quantified long-term trends in nitrate, phosphate, total nitrogen, total phosphorus, chloride, and sulfate export at several sites along a rural-urban gradient. We found no significant change in solute export at most sites, although we did find specific patterns of interest for certain solutes. For example, nitrogen export declined at the most headwater urban site, while phosphorus export declined at the most downstream urban site. Coupling long-term monitoring with data on gray and green infrastructure management throughout the landscape, we established relationships between solute export at the most downstream urban monitoring site and sanitary sewer overflows (SSOs), best management practice (BMP) implementation, and road salt application rates. Phosphorus export was correlated with BMP implementation in the watershed, whereas nitrogen export was related to SSOs. Despite highly urbanized watersheds, water quality does not appear to be declining at most of these sites, suggesting that current management may have limited further impairment. Results of our study suggest that both gray and green infrastructure are key for maintaining and improving water quality in this highly urbanized watershed.

Maryland↗

USGS1994

The travel-time ellipse: An approximate zone of transport

A zone of transport for a well is defined as the area in the horizontal plane bounded by a contour of equal ground-water travel time to the well. For short distances and ground-water travel times near a well, the potentiometric surface may be simulated analytically as that for a fully penetrating well in a uniform flow field. The zone of transport for this configuration is nearly elliptical. A simple method is derived to calculate a travel-time ellipse that approximates the zone of transport for a well in a uniform flow field. The travel-time ellipse was nearly congruent with the exact solution for the theoretical zone of transport for ground-water travel times of at least 10 years and for aquifer property values appropriate for southeastern Minnesota. For distances and travel times approaching infinity, however, the ellipse becomes slightly wider at its midpoint and narrower near its upgradient boundary than the theoretical zone of transport. The travel-time ellipse also may be used to simulate the plume area surrounding an injection well. However, the travel-time ellipse is an approximation that does not account for the effect of dispersion in enlarging the true area of an injection plume or zone of transport; hence, caution is advised in the use and interpretation of this simple construction.

Journal of Hydrology↗

USGS1992

The aqueous photolysis of α-pinene in solution with humic acid

Terpenes are produced abundantly by environmental processes but are found in very low concentrations in natural waters. Aqueous photolysis of solutions containing α-pinene, a representative terpene, in the presence of humic acid resulted in degradation of the pinene. Comparison of this reaction to photolysis of α-pinene in the presence of methylene blue leads to the conclusion that the reactive pathway for the abiotic degradation of α-pinene is due to reaction with singlet oxygen produced by irradiation of the humic material. The initial product of single oxygen and α-pinene is a hydroperoxide. Since humic materials are prevalent in most natural waters, this mechanism of photodecomposition for α-pinene probably also applies to other terpenes in surface waters and may be reasonably considered to contribute to their low environmental concentration.

Journal of Contaminant Hydrology↗