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USGS2017

Gallium

Gallium is a soft, silvery metallic element with an atomic number of 31 and the chemical symbol Ga. Gallium is used in a wide variety of products that have microelectronic components containing either gallium arsenide (GaAs) or gallium nitride (GaN). GaAs is able to change electricity directly into laser light and is used in the manufacture of optoelectronic devices (laser diodes, light-emitting diodes [LEDs], photo detectors, and solar cells), which are important for aerospace and telecommunications applications and industrial and medical equipment. GaAs is also used in the production of highly specialized integrated circuits, semiconductors, and transistors; these are necessary for defense applications and high-performance computers. For example, cell phones with advanced personal computer-like functionality (smartphones) use GaAs-rich semiconductor components. GaN is used principally in the manufacture of LEDs and laser diodes, power electronics, and radio-frequency electronics. Because GaN power transistors operate at higher voltages and with a higher power density than GaAs devices, the uses for advanced GaN-based products are expected to increase in the future. Gallium technologies also have large power-handling capabilities and are used for cable television transmission, commercial wireless infrastructure, power electronics, and satellites. Gallium is also used for such familiar applications as screen backlighting for computer notebooks, flat-screen televisions, and desktop computer monitors. Gallium is dispersed in small amounts in many minerals and rocks where it substitutes for elements of similar size and charge, such as aluminum and zinc. For example, gallium is found in small amounts (about 50 parts per million) in such aluminum-bearing minerals as diaspore-boehmite and gibbsite, which form bauxite deposits, and in the zinc-sulfide mineral sphalerite, which is found in many mineral deposits. At the present time, gallium metal is derived mainly as a byproduct of the processing of bauxite ore for aluminum; lesser amounts of gallium metal are produced from the processing of sphalerite ore from three types of deposits (sediment-hosted, Mississippi Valley-type, and volcanogenic massive sulfide) for zinc. The United States is expected to meet its current and expected future needs for gallium through imports of primary, recycled, and refined gallium, as well as through domestic production of recycled and refined gallium. The U.S. Geological Survey estimates that world resources of gallium in bauxite exceed 1 billion kilograms, and a considerable quantity of gallium could be present in world zinc reserves.

Professional Paper↗

USGS2000

Applications of imaging spectroscopy data: A case study at Summitville, Colorado

From 1985 through 1992, the Summitville open-pit mine produced gold from lowgrade ore using cyanide heap-leach techniques, a method to extract gold whereby the ore pile is sprayed with water containing cyanide, which dissolves the minute gold grains. Environmental problems due to mining activity at Summitville include significant increases in acidic and metal-rich drainage from the site, leakage of cyanide-bearing solutions from the heap-leach pad into an underdrain system, and several surface leaks of cyanide-bearing solutions into the Wightman Fork of the Alamosa River. In general, drainage from the Summitville mine moves downslope into the Wightman Fork, a small tributary of the Alamosa River, which in turn flows east into the Terrace Reservoir before entering the agricultural lands of the San Luis Valley. The increase in the trace-metal burden of the Alamosa River watershed due to the mining activities at Summitville is of concern to farmers and fisherman, as well as Federal and State of Colorado agencies having responsibility for land stewardship. The environment of the Summitville area is a result of 1) its geologic evolution, that culminated in the formation of precious-metal mineral deposits; and 2) previous metal mining activity. Mining accentuates, accelerates, and pertubates natural geochemical processes. The development of underground workings, open pits, mill tailings, and spoil heaps and the extractive processing of ore enhances the likelihood of releasing chemicals and elements to the surrounding areas and at increased rates relative to unmined areas. Both mined and unmined mineralized areas can produce acid drainage from the formation and movement of highly acidic water rich in heavy metals. This acidic water forms principally through the chemical reaction of oxygenated surface water and shallow subsurface water with rocks that contain sulfide minerals, producing sulphuric acid. Heavy metals can be leached by the acid solution that comes in contact with mineralized rocks, a process that may be enhanced by bacterial action. The resulting fluids may be highly toxic and, when mixed with groundwater, surface water, and soil, may have harmful effects on humans, animals, and plants. Thus, understanding the geologic and hydrologic history of this area is a critical piece of the environmental puzzle in the Summitville area. The Summitville mine operators had ceased active mining and begun environmental remediation, including treatment of the heap-leach pile and installation of a water-treatment facility, when it declared bankruptcy in December 1992 and abandoned the mine site. The U.S. Environmental Protection Agency (EPA) immediately took over the Summitville site under EPA Superfund Emergency Response authority. Summitville has focused public attention on the environmental effects of modern mineral-resource development. Soon after the mine was abandoned, Federal, State, and local agencies, along with Alamosa River water users and private companies, began extensive studies at the mine site and surrounding areas. These studies included analysis of water, soil, livestock and vegetation. The role of the U.S. Geological Survey (USGS) was to provide geologic, hydrologic and agricultural information about the mine and surrounding area and to describe and evaluate the environmental condition of the Summitville mine and the downstream effects of the mine on the San Luis Valley (King 1995).

Colorado↗

USGS2016

Probing the volcanic-plutonic connection and the genesis of crystal-rich rhyolite in a deeply dissected supervolcano in the Nevada Great Basin: Source of the late Eocene Caetano Tuff

Late Cenozoic faulting and large-magnitude extension in the Great Basin of the western USA has created locally deep windows into the upper crust, permitting direct study of volcanic and plutonic rocks within individual calderas. The Caetano caldera in north–central Nevada, formed during the mid-Tertiary ignimbrite flare-up, offers one of the best exposed and most complete records of caldera magmatism. Integrating whole-rock geochemistry, mineral chemistry, isotope geochemistry and geochronology with field studies and geologic mapping, we define the petrologic evolution of the magmatic system that sourced the >1100 km 3 Caetano Tuff. The intra-caldera Caetano Tuff is up to ∼5 km thick, composed of crystal-rich (30–45 vol. %), high-silica rhyolite, overlain by a smaller volume of comparably crystal-rich, low-silica rhyolite. It defies classification as either a monotonous intermediate or crystal-poor zoned rhyolite, as commonly ascribed to ignimbrite eruptions. Crystallization modeling based on the observed mineralogy and major and trace element geochemistry demonstrates that the compositional zonation can be explained by liquid–cumulate evolution in the Caetano Tuff magma chamber, with the more evolved lower Caetano Tuff consisting of extracted liquids that continued to crystallize and mix in the upper part of the chamber following segregation from a cumulate-rich, and more heterogeneous, source mush. The latter is represented in the caldera stratigraphy by the less evolved upper Caetano Tuff. Whole-rock major, trace and rare earth element geochemistry, modal mineralogy and mineral chemistry, O, Sr, Nd and Pb isotope geochemistry, sanidine Ar–Ar geochronology, and zircon U–Pb geochronology and trace element geochemistry provide robust evidence that the voluminous caldera intrusions (Carico Lake pluton and Redrock Canyon porphyry) are genetically equivalent to the least evolved Caetano Tuff and formed from magma that remained in the lower chamber after ignimbrite eruption and caldera collapse. Thus, the Caetano Tuff contradicts models for the mutually exclusive origins of voluminous volcanic and plutonic magmas in the upper crust. Crystal-scale O isotope data indicate that the Caetano Tuff is one of the most 18 O-enriched rhyolites in the Great Basin (δ 18 O magma = 10·2 ± 0·2‰), supporting anatexis of local metasedimentary basement crust. Metapelite xenoliths in the Carico Lake pluton and ubiquitous xenocrystic zircons in the Caetano Tuff provide constraints for the anatexis process; these data point to shallow (<15 km) dehydration melting of a protolith similar to the Proterozoic McCoy Creek Group siliciclastic sediments in eastern Nevada, projected beneath Caetano in fault-stacked shelf sediments that were thickened during Mesozoic crustal shortening. Mean zircon U–Pb ages for different stratigraphic levels of the intra-caldera Caetano Tuff are 34·2–34·5 Ma, 0·2–0·5 Myr older than the caldera sanidine 40 Ar/ 39 Ar age of 34·00 ± 0·03 Ma, documenting protracted duration of assembly and homogenization of isotopically diverse upper crustal melts, followed by crystallization and zonation to generate the Caetano Tuff magma chamber. Sanidine rims in the least evolved Caetano Tuff and in the Carico Lake pluton and Redrock Canyon porphyry have sharply zoned Ba domains that point to crystal growth during magmatic recharge events. The recharge magma is inferred to have been compositionally similar to the Caetano Tuff magma, with increased Ba resulting from remelting of Ba-rich sanidine cumulates. Mush reactivation to generate the Caetano Tuff eruption was sufficiently rapid to preserve compositional gradients in the intracaldera ignimbrite, calling into question models that predict homogeneity as a prerequisite for remobilizing crystal-rich ignimbrite magmas.

Journal of Petrology↗

USGS2011

Exploration case study using indicator minerals in till at the giant Pebble porphyry Cu-Au-Mo deposit, southwest Alaska, USA

The Pebble deposit in southwest Alaska (Fig. 1) contains one of the largest resources of copper and gold in the world. It includes a measured and indicated resource of 5,942 million tonnes (Mt) at 0.42% Cu, 0.35 g/t Au, and 250 ppm Mo (0.30% copper equivalent, CuEQ, cut off) and contains significant concentrations of Ag, Pd, and Re (Northern Dynasty Minerals 2011). The deposit remains open at depth. The Pebble West zone was discovered in 1989 by Cominco American. In 2005, Northern Dynasty Minerals Ltd. (NDM) discovered Pebble East, and in July 2007, NDM partnered with Anglo American to form the Pebble Limited Partnership (PLP). The U.S. Geological Survey began collaborative investigations with PLP in 2007 to identify techniques that will improve mineral exploration in covered terranes. The Pebble deposit is an ideal location for such a study because the deposit is undisturbed (except for drilling), is almost entirely concealed by post-mineral volcanic rocks and glacial deposits, and because its distribution is well constrained in the subsurface by PLP’s drill-hole geology and geochemistry. An exploration method developed by Averill (2007) that utilizes porphyry copper indicator minerals (PCIMR) in glacial till samples was applied at Pebble; samples were collected up- and down-ice (of former glaciers) from the deposit. The distribution of several PCIMs identifies the deposit, which suggests that PCIMs may be useful in exploration for other concealed porphyry deposits in the region. In this study, we compare the efficacy of PCIMs relative to that of pond and stream sediments also collected in the deposit area. The Pebble deposit is located 380 km southwest of Anchorage, in the Bristol Bay region of southwest Alaska. There is no road network and access to the study area is by helicopter. The deposit is situated in a broad glacially sculpted topographic low at the head of three drainages, Talarik Creek, North Fork Koktuli River, and the South Fork Koktuli River (Fig. 1). The study area is in a zone of discontinuous permafrost and is masked by lichen-rich tundra vegetation.

Alaska↗

USGS1980

Potassium-argon geochronology of the eastern Transverse Ranges and southern Mojave Desert, southern California

More than 200 potassium-argon apparent ages on minerals from crystalline rocks, chiefly from the San Bernardino and eastern San Gabriel Mountains and the southern Mojave Desert, define an area greater than 10,000 km 2 in which the potassium-argon isotopic systematics have been highly disturbed. The disturbance or disturbances appear to have culminated at different times in different parts of the region, ranging from 57 m.y. ago in the eastern San Gabriel Mountains to about 70 m.y. ago in the southern Mojave Desert. The region can be subdivided into three parts on the basis of potassium-argon dating: (1) An inner area of anomalous ages in which the rocks yield apparent potassium-argon ages that indicate complete or nearly complete resetting of the isotopic system. (2) An outer area in which the rocks yield apparent ages that are, or approach, emplacement ages. (3) A zone separating these two areas from which rocks yield discordant apparent ages on coexisting mineral pairs. This discordant zone varies in width from about 6 to 12 km and grades inward to rocks reset to the degree that they yield concordant potassium-argon apparent ages on coexisting mineral pairs and outward toward rocks that yield near-concordant apparent ages. Rocks from the center and the inner parts of the discordant zone yield the most discordant apparent ages. Contouring of the apparent ages defines the extent of the reset region that occurs on both sides of the San Andreas fault. The apparent ages can be contoured across the fault, although the position of the fault is well defined by abrupt deflection of the contours parallel to the fault. The reverse fault bounding the north side of the San Bernardino Mountains mayor may not be reflected by offset contours; correlation of possible offset features across the fault is uncertain. Several northwest-trending faults on the Mojave Desert strongly disrupt the contours but do not show the right-lateral displacements that have been attributed to them on the basis of apparent offsets of geologic features. These faults may have a component of vertical movement, and it is not known what effect this might have on the contours; even a small amount could be profound. The cause of the isotopic disturbance is not well understood, as the area of most complete resetting does not appear to be coincident with any single batholithic mass. The apparent-age contours cross the boundaries of individual plutons, and the configuration of the contours shows no apparent relation to the shapes of plutons or groups of plutons. Even though there does appear to be a lack of correlation between individual plutons or batholith-size collections of plutons, this lack of correlation may be more apparent than real. It is possible that some of the plutons within the area of anomalous ages are part of an extensive batholithic mass of which only the uppermost part is exposed. An alternative interpretation of the anomalous ages is that a continuing post-emplacement heat source generated by continued under thrusting of the Pacific plate beneath North America caused the region to remain at elevated temperatures such that argon retention by minerals datable by potassium-argon methods was not possible for some time after pluton emplacement. As suggested by Coney and Reynolds (1977), possibly the angle of underthrusting was shallower than when the Transverse Range plutons were emplaced. Locally, the youngest ages show a spatial relation to the Vincent thrust fault and its correlatives. If this fault is the cause of the region-wide resetting, it has to have extended under most of the western part of southern California. The configuration of the anomalous-age zone is roughly coincident with the position of the Transverse Ranges, the recently discovered southern California uplift, a relatively shallow high-velocity zone in southern California, and the projection of the Murray fracture zone. The eastward extent coincides roughly with the eastern limit of high seismicity in southern California.

California↗

USGS1989

Dikes, joints, and faults in the upper mantle

Three different types of macroscopic fractures are recognized in upper-mantle and lower-crustal xenoliths in volcanic rocks from around the world: 1. (1) joints that are tensile fractures not occupied by crystallized magma products 2. (2) dikes that are tensile fractures occupied by mafic magmas crystallized to pyroxenites, gabbros or hydrous-mineral-rich rocks, 3. (3) faults that are unfilled shear fractures with surface markings indicative of shear displacement. In addition to intra-xenolith fractures, xenoliths commonly have polygonal or faceted shapes that represent fractures exploited during incorporation of the xenoliths into the host magma that brought them to the surface. The various types of fractures are considered to have formed in response to the pressures associated with magmatic fluids and to the ambient tectonic stress field. The presence of fracture sets and crosscutting relations indicate that both magma-filled and unfilled fractures can be contemporaneous and that the local stress field can change with time, leading to repeated episodes of fracture. These observations give insight into the nature of deep fracture processes and the importance of fluid-peridotite interactions in the mantle. We suggest that unfilled fractures were opened by volatile fluids exsolved from ascending magmas to the tops of growing dikes. These volatile fluids are important because they are of low viscosity and can rapidly transmit fluid pressure to dike and fault tips and because they lower the energy and tectonic stresses required to extend macroscopic cracks and to allow sliding on pre-existing fractures. Mantle seismicity at depths of 20-65 km beneath active volcanic centers in Hawaii corresponds to the depth interval where CO2-rich fluids are expected to be liberated from ascending basaltic magmas, suggesting that such fluids play an important role in facilitating earthquake instabilities in the presence of tectonic stresses. Other phenomena related to the fractures include permeation of peridotite by fluid inclusions derived by degassing of magmas, partial melting of peridotite and dike rocks, and metasomatic alteration of peridotite host rock by magmas emplaced in fractures. These effects of magmatism generally reduce the bulk density of peridotite and might also reduce seismic velocities. The velocity contrasts between fractured and unfractured peridotite might be detected by seismic-velocity profiling techniques.

Tectonophysics↗

USGS1970

Lithium metaborate flux in silicate analysis

Lithium metaborate is an effective flux for silicates and other rock-forming minerals. The glass resulting from fusion is mechanically strong, reasonably nonhygroscopic, and is readily soluble in dilute acids. These characteristics lead to its use in X-ray spectrography and in methods which require whole-rock solutions, such as atomic absorption and emission spectrometry. Difficulties have been encountered in the use of such techniques : a high-quality reagent has been difficult to obtain ; fusion conditions must be rather closely controlled; graphite crucibles used in the fusions need special treatment. Methods for overcoming these difficulties are outlined. Selected procedures for various instrumental methods of analysis are described.

Analytica Chimica Acta↗

USGS2001

Some simple guides to finding useful information in exploration geochemical data

Most regional geochemistry data reflect processes that can produce superfluous bits of noise and, perhaps, information about the mineralization process of interest. There are two end-member approaches to finding patterns in geochemical data—unsupervised learning and supervised learning. In unsupervised learning, data are processed and the geochemist is given the task of interpreting and identifying possible sources of any patterns. In supervised learning, data from known subgroups such as rock type, mineralized and nonmineralized, and types of mineralization are used to train the system which then is given unknown samples to classify into these subgroups. To locate patterns of interest, it is helpful to transform the data and to remove unwanted masking patterns. With trace elements use of a logarithmic transformation is recommended. In many situations, missing censored data can be estimated using multiple regression of other uncensored variables on the variable with censored values. In unsupervised learning, transformed values can be standardized, or normalized, to a Z-score by subtracting the subset's mean and dividing by its standard deviation. Subsets include any source of differences that might be related to processes unrelated to the target sought such as different laboratories, regional alteration, analytical procedures, or rock types. Normalization removes effects of different means and measurement scales as well as facilitates comparison of spatial patterns of elements. These adjustments remove effects of different subgroups and hopefully leave on the map the simple and uncluttered pattern(s) related to the mineralization only. Supervised learning methods, such as discriminant analysis and neural networks, offer the promise of consistent and, in certain situations, unbiased estimates of where mineralization might exist. These methods critically rely on being trained with data that encompasses all populations fairly and that can possibly fall into only the identified populations.

Natural Resources Research↗

USGS2012

Mineral parageneses, regional architecture, and tectonic evolution of Franciscan metagraywackes, Cape Mendocino-Garberville-Covelo 30' x 60' quadrangles, northwest California

The Franciscan Complex is a classic subduction-zone assemblage. In northwest California, it comprises a stack of west vergent thrust sheets: westernmost Eastern Belt outliers; Central Belt mélange; Coastal Belt Yager terrane; Coastal Belt Coastal terrane; Coastal Belt King Range/False Cape terranes. We collected samples and determined P-T conditions of recrystallization for 88 medium-fine-grained metasandstones to assess their subduction-exhumation histories and assembly of the host allochthons. Feebly recrystallized Yager, Coastal, and King Range strata retain clear detrital features. Scattered neoblastic prehnite occurs in several Coastal terrane metasandstones; traces of possible pumpellyite are present in three Yager metaclastic rocks. Pumpellyite ± lawsonite ± aragonite-bearing Central Belt metasandstones are moderately deformed and reconstituted. Intensely contorted, thoroughly recrystallized Eastern Belt affinity quartzose metagraywackes contain lawsonite + jadeitic pyroxene ± aragonite ± glaucophane. We microprobed neoblastic phases in 23 rocks, documenting mineral parageneses that constrain the tectonic accretion and metamorphic P-T evolution of these sheets. Quasi-stable mineral assemblages typify Eastern Belt metasandstones, but mm-sized domains in the Central and Coastal belt rocks failed to achieve chemical equilibrium. Eastern Belt slabs rose from subduction depths approaching 25–30 km, whereas structurally lower Central Belt mélanges returned from &sim;15–18 km. Coastal Belt assemblages suggest burial depths less than 5–8 km. Eastern and Central belt allochthons sequentially decoupled from the downgoing oceanic lithosphere and ascended into the accretionary margin; K-feldspar-rich Coastal Belt rocks were stranded along the continental edge without undergoing appreciable subduction, probably during Paleogene unroofing of the older, deeply subducted units of the Franciscan Complex in east-vergent crustal wedges.

California↗

USGS1991

An aem-tem study of weathering and diagenesis, Abert Lake, Oregon: I. Weathering reactions in the volcanics

Abert Lake in south-central Oregon provides a site suitable for the study of sequential weathering and diagenetic events. In this first of two papers, transmission electron microscopy was used to characterize the igneous mineralogy, subsolidus alteration assemblage, and the structural and chemical aspects of silicate weathering reactions that occur in the volcanic rocks (basalts, basaltic andesites, and dacitic/ rhyolitic extrusive and pyroclastics) that outcrop around the lake. Olivine and pyroxene replacement occurred topotactically, whereas feldspar and glass alteration produced randomly oriented smectite in channels and cavities. The tetrahedral, octahedral, and interlayer compositions of the weathering products, largely dioctahedral smectites, varied with primary mineral composition, rock type, and as the result of addition of elements released from adjacent reaction sites. Weathering of the highly evolved, Fe-rich Jug Mountain complex at the north end of the lake produced a homogeneous smectite assemblage that contrasts with the heterogeneous smectite assemblage replacing the volcanics along the eastern margin of the lake. The variability within and between the smectite assemblages highlights the microenvironmental diversity, fluctuating redox conditions, and variable solution chemistry associated with mineral weathering reactions in the surficial environment. Late-stage exhalative and aqueous alteration of the volcanics redistributed many components and formed a variety of alkali and alkali-earth carbonate, chloride, sulfate, and fluoride minerals in vugs and cracks. Overall, substantial Mg, Si, Na, Ca, and K are released by weathering reactions that include the almost complete destruction of the Mg-smectite that initially replaced olivine. The leaching of these elements from the volcanics provides an important source of these constituents in the lake water. The nature of subsequent diagenetic reactions resulting from the interaction between the materials transported to the lake and the solution will be described in part II ( Banfield et al., 1991).

Geochimica et Cosmochimica Acta↗

USGS1941

Igneous rocks of the Highwood Mountains, Montana: Part VI. Mineralogy

The minerals of the igneous rocks of the Highwood Mountains are described. The primary hornblende of the quartz latites is basaltic and it has been partly replaced by a common green hornblende. Hornblende is rare in the alkalic rocks. Augite is an abundant mineral of the alkalic rocks; in the syenites it contains some acmite, especially on the borders of the crystals. Aegirite is a common metamorphic mineral. The olivine of the shonkinites contains from 12 to 22 mol per cent of fayalite, that of the syenite from Square Butte 50 per cent. Monticellite twinned into trillings on (031) is an abundant mineral in one small intrusive body. In the alkalic rocks barium sanidine is abundant and plagioclase rare; leucite, primary analcime, and pseudoleucite are common and sodalite rare. Natrolite, thomsonite, and other zeolites are widespread and very abundant.

Montana↗

USGS1987

Hydrogeologic and water-quality characteristics of glacial-drift aquifers in Minnesota

Water in Minnesota 's glacial drift aquifers generally is of acceptable quality for most uses, including household supply, industrial use, and irrigation. The aquifers generally contain calcium magnesium bicarbonate-type waters, but other types are present also. Calcium magnesium sulfate-type waters are common in the confined drift aquifers in the southwestern and northwestern parts of the State. The elevated concentrations of sulfate, which exceed limits recommended for drinking water by the EPA, results mainly from solution of sulfate bearing minerals in rocks of Cretaceous age that have been reworked in deep glacial drift. Sodium and chloride-type waters are common in drift aquifers in northwestern Minnesota owing to the inflow of saline water from bedrock aquifers of Paleozoic age North Dakota. Cation exchange with clay minerals in the drift also is a source of sodium to these waters, particularly in the confined drift aquifers. Some of the water from these aquifers are unsuitable for irrigation because of elevated concentrations of sodium, and some are unsuitable for drinking because of elevated concentrations of chloride. Concentrations of nitrite plus nitrate (as N) locally exceed the EPA recommended limits for drinking water in central and northwestern Minnesota. Shallow, unconfined drift aquifers are particularly susceptible to nitrate contamination from land surface. Confined drift aquifers are much less susceptible because overlying till deposits retard downward movement of contaminants to the deeper aquifers. Nitrate contamination, which may cause methemoglobinemia in infants, is one of the more serious water quality concerns in Minnesota. Iron and manganese concentrations commonly exceed EPA 's recommendations for drinking water throughout the State, but these constituents affect aesthetic properties of water rather than health.

Minnesota↗

USGS2016

Book Review: Potassic igneous rocks and associated gold-copper mineralization, Fourth edition (D. Muller and D.I. Groves)

The fourth edition of this comprehensive textbook, which succeeds those published in 1995, 1997, and 2000, very nicely summarizes the geochemical and petrological characteristics of potassic igneous rock complexes and the different tectonic settings in which they occur. The authors provide an overview and a classification of these rocks and they outline the geochemical differences between barren and mineralized potassic igneous complexes. Owing to the common association of potassic igneous rocks with many gold- and copper-rich ore deposits, this book will be of interest not only to research scientists but also to those exploring for major deposits in young and ancient terranes. In fact, there was a clear attempt by the authors to provide a good mix of theoretical discussions based on experimental work, with case studies that illustrate field and applied research. Review info: Potassic Igneous Rocks and Associated Gold-Copper Mineralization , Fourth Edition. By Daniel Müller, David I. Groves. 2016. ISBN 978-3-319-23051-1. 311 p.

Economic Geology↗

USGS1952

Stratigraphic sections of the Phosphoria formation in Idaho, 1947-48, Part I

The Permian Phosphoria formation of the western states contains one of the world's largest reserves of phosphate. Although previous investigations (see especially Mansfield, 1927), including reconnaissance geologic mapping and sampling, established the location of most of the important deposits and their quality of scattered localities, they were not sufficiently detailed to permit a comparison of the merits of individual deposits or an appraisal of the reserves of phosphate rock that might be available under present economic conditions. Because the growing importance of the western phosphate deposits requires a better, more detailed understanding of their distribution and quality, the Geological Survey began in 1947 a comprehensive investigation, including (1) reconnaissance geologic mapping, mostly in Montana, of areas in which the Phosphoria formation could occur but where it had not previously been looked for or found; (2) geologic mapping, mostly in Montana, at a scale no smaller than 1:62,500, of several areas known to contain the Phosphoria formation but not previously mapped except in reconnaissance fashion; (3) geologic and topographic mapping, at a scale of 1:12,000, of some of the richest, thickest, and most accessible deposits; (4) measuring, describing, and sampling all beds of the phosphatic and shaly parts, and in some places the full thickness, of the Phosphoria formation and its stratigraphic equivalents at one or two localities per township over the entire field; (5) chemical and spectrographic analysis of the samples for phosphate, fluorine, minor metals, oil, and rock-forming constituents; and (6) petrologic and geochemical studies of the rocks and minerals of the formation. These studies are designed to define the regional and local geologic structures in which the phosphate bed lie, to provide a basis for the estimation of reserves of the inferred class over the entire region, and to determine the origin of the rocks and the elements contained in them. The data collected are not of the detail required to plan actual mining operations, but it is hoped they will guide industry in the selection of individual deposits worthy of further exploration. Most of the field work contemplated as a part of this investigation is now completed. Although the data will not be compiled or published in final form for some years to come, segments of the data, accompanied by little or no interpretation, will be published as preliminary maps or reports as they are assembled. The present report is the first of a series presenting in abbreviated form the description and analyses of the beds measured and sampled at various localities in southeastern Idaho (pl. 1). Companion reports presenting segments of the data from Montana, Wyoming, and Utah (Swanson and others, 1952, and McKelvey and others, 1952a and 1952b) are being released at the same time as this report, and others are in preparation.

Idaho↗

USGS2009

Identification of hydrated silicate minerals on Mars using MRO-CRISM: Geologic context near Nili Fossae and implications for aqueous alteration

[1] The Noachian terrain west of the Isidis basin hosts a diverse collection of alteration minerals in rocks comprising varied geomorphic units within a 100,000 km 2 region in and near the Nili Fossae. Prior investigations in this region by the Observatoire pour l'Minéralogie, l'Eau, les Glaces, et l'Activité (OMEGA) instrument on Mars Express revealed large exposures of both mafic minerals and iron magnesium phyllosilicates in stratigraphic context. Expanding on the discoveries of OMEGA, the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) aboard the Mars Reconnaissance Orbiter (MRO) has found more spatially widespread and mineralogically diverse alteration minerals than previously realized, which represent multiple aqueous environments. Using CRISM near-infrared spectral data, we detail the basis for identification of iron and magnesium smectites (including both nontronite and more Mg-rich varieties), chlorite, prehnite, serpentine, kaolinite, potassium mica (illite or muscovite), hydrated (opaline) silica, the sodium zeolite analcime, and magnesium carbonate. The detection of serpentine and analcime on Mars is reported here for the first time. We detail the geomorphic context of these minerals using data from high-resolution imagers onboard MRO in conjunction with CRISM. We find that the distribution of alteration minerals is not homogeneous; rather, they occur in provinces with distinctive assemblages of alteration minerals. Key findings are (1) a distinctive stratigraphy, in and around the Nili Fossae, of kaolinite and magnesium carbonate in bedrock units always overlying Fe/Mg smectites and (2) evidence for mineral phases and assemblages indicative of low-grade metamorphic or hydrothermal aqueous alteration in cratered terrains. The alteration minerals around the Nili Fossae are more typical of those resulting from neutral to alkaline conditions rather than acidic conditions, which appear to have dominated much of Mars. Moreover, the mineralogic diversity and geologic context of alteration minerals found in the region around the Nili Fossae indicates several episodes of aqueous activity in multiple distinct environments.

Journal of Geophysical Research E: Planets↗

USGS2007

Integration of seafloor point data in usSEABED

Sediments of the beach, nearshore, and continental shelves record a complex interplay of processes including wave energy and direction , currents, beach erosion or accretion, bluff or cliff retreat, fluvial input, sediment longshore and cross-shelf transport processes, contaminant content and transport, sediment sources and sinks, and others. In turn, sediments and rocks modify wave patterns, affect recreation and tourism, and provide habitat for fish, epifauna, and infauna. Character of the surficial seafloor also influences navigation, commercial and recreational fishing and gathering of other food sources, communication, piplines, national defense, and provides geologic resources including sand and gravel aggregates, minerals, and real or potential energy sources. The beaches, nearshore, and continental margins fall under overlapping levels of managerial responsibility between Federal, State, regional, and local government agencies and consortia. In addition, universities and other academic institutions investigate these places for pure or applied scientific reasons. Mapping is usually the first step in understanding any issue and is often comprised of remotely gathered geophysical data such as bathymetry and backscatter imagery, and groundtruthing; that is, the collection of physical and virtual samples to tie the remotely gathered data to reality. The physical samples are described and (or) carefully analyzed for grain-size information -- which records both the site's physical conditions and geologic past -- and commonly, for constituent components such as mineral and rock types (to determine onland sources and in situ chemical processes), carbonate and organic content and microfossils (for biological and oceanographic influences), and structure such as layering and bioturbation (for physical influences). The samples may also be subjected to physical tests such as comp[action analyses, liquefaction or plasticity limits, ans other parameters important when considering construction of offshore structures. In recent years, virtual sampling of the seafloor has become popular, through the use of towed video or photographic equipment and the addition of camera to oceanographic equipment such as corers and tripods. Before about ten years ago, most maps were made by hand. Recently, with the advent of desktop GIS packages, map making and resource analysis can be done nearly "on-the-fly" if geographically located data exist. While the problems of projection, scale, and resolution of digitized paper maps are commonly known amongst GIS-users, access to the original underlying point data allows for maps to be regenerated for digital use using statistically proven methods, provides increasing data density by including multiple studies, as well as allows the point data to be used in other ways than just mapping. These point data may be available in raw or refined or in worded descriptions. Raw data such as granulometric analyses can be manipulated through the use of known equations or empirical relationships to provide information about other parameters of the sediment, such as mean grainsize, sorting, erodability, or rugosity. If refined data are presented such as gravel, sand, and mud percentages, the parameter noted earlier may be estimated. In the case of worded descriptions, values for geologic terms can be assigned, for example, "fine sand" equate to 0.2 mm sized particles, to provide numeric terms for GIS or modeling purposes.

Conference Paper↗

USGS2013

Inferring fault rheology from low-frequency earthquakes on the San Andreas

Families of recurring low-frequency earthquakes (LFEs) within nonvolcanic tremor (NVT) on the San Andreas fault in central California show strong sensitivity to shear stress induced by the daily tidal cycle. LFEs occur at all levels of the tidal shear stress and are in phase with the very small, ~400 Pa, stress amplitude. To quantitatively explain the correlation, we use a model from the existing literature that assumes the LFE sources are small, persistent regions that repeatedly fail during shear of a much larger scale, otherwise aseismically creeping fault zone. The LFE source patches see tectonic loading, creep of the surrounding fault which may be modulated by the tidal stress, and direct tidal loading. If the patches are small relative to the surrounding creeping fault then the stressing is dominated by fault creep, and if patch failure occurs at a threshold stress, then the resulting seismicity rate is proportional to the fault creep rate or fault zone strain rate. Using the seismicity rate as a proxy for strain rate and the tidal shear stress, we fit the data with possible fault rheologies that produce creep in laboratory experiments at temperatures of 400 to 600°C appropriate for the LFE source depth. The rheological properties of rock-forming minerals for dislocation creep and dislocation glide are not consistent with the observed fault creep because strong correlation between small stress perturbations and strain rate requires perturbation on the order of the ambient stress. The observed tidal modulation restricts ambient stress to be at most a few kilopascal, much lower than rock strength. A purely rate dependent friction is consistent with the observations only if the product of the friction rate dependence and effective normal stress is ~ 0.5 kPa. Extrapolating the friction rate strengthening dependence of phyllosilicates (talc) to depth would require the effective normal stress to be ~50 kPa, implying pore pressure is lithostatic. If the LFE source is on the order of tens of meters, as required by the model, rate-weakening friction rate dependence (e.g., olivine) at 400 to 600°C requires that the minimum effective pressure at the LFE source is ~ 2.5 MPa.

California↗

USGS1953

Niobium (columbium) and titanium at Magnet Cove and Potash Sulphur Springs, Arkansas

This work was done because niobium (columbium) has been found in several of the minerals and rocks of the Magnet Cove and Potash Sulphur Springs areas. Niobium is in demand for use in high-temperature and non-creep steels. The Magnet Cove and Potash Sulphur Springs areas are in central Arkansas between Malvern and Hot Springs. They are underlain by similar alkaline igneous complexes consisting of nepheline syenite, more basic alkaline rocks, and calcite rock or carbonatite. The igneous rocks intrude Paleozoic sedimentary rocks and are truncated by a Late Cretaceous erosion surface. At Magnet Cove deposits of rutile (TiO 2) occur within the igneous complex; two deposits of brookite (TiO 2 ) occur in quartzite of the Arkansas novaculite formation of probable Devonian and Mississippian age, near the margin of the complex. Perovskite (calcium titanate) occurs in several places in the igneous complex. Niobium is present in rutile, brookite, and perovskite, and also probably in other minerals not yet analyzed. In order to determine the distribution and average content of niobium in the larger titanium deposits, drill core and channel samples were analyzed for niobium, titanium, and other elements; and average figures were calculated. Concentrates and single crystals were also analyzed. Material from drill cores of perovskite-bearing magnetite-pyroxene rock on the Mo-Ti Corporation property was studied and analyzed. The Kimsey calcite quarry area was mapped, and channel samples and single crystals were analyzed. Channel samples from trenches on the Wilson prospect at Potash Sulphur Springs were analyzed. The areas studied contain large resources of titanium and niobium, of low grade. The major results of the analytical work are summarized in the following table.

Arkansas↗