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Uranium disequilibrium in groundwater: An isotope dilution approach in hydrologic investigations

The distribution and environmental disequilibrium patterns of naturally occurring uranium isotopes (U 234 and U 238 ) in waters of the Floridan aquifer suggest that variations in the ratios of isotopic activity and concentrations can be used quantitatively to evaluate mixing proportions of waters from differing sources. Uranium is probably unique in its potential for this approach, which seems to have general usefulness in hydrologic investigations.

Florida

Uranium deposits under conglomeratic sandstone of the Morrison Formation, Colorado and Utah

In southwestern Colorado and southeastern Utah, strata of conglomeratic sandstone are localized at the base of the Brushy Basin Member of the Morrison Formation of Jurassic age. These discrete lithologic units contain sedimentary structures oriented in a prevailing easterly direction. They are believed to cover about one-third of the underlying Salt Wash Member in southwestern Colorado and southeastern Utah, and they locally rest on ore-bearing sandstone in the Salt Wash Member. Eastward-trending planar cross-stratification and trough cross-stratification and a general westward coarsening of sediments in the conglomeratic sandstone strata suggest that they are the products of stream aggradation from westerly source areas. Uranium-vanadium deposits in the uppermost, almost continuous, layer of sandstone of the Salt Wash Member are classified according to their association with the conglomerate strata. Of the 363 deposits studied in the uppermost sandstone layer of the Salt Wash Member, 101 are known to be directly beneath conglomeratic sandstone strata, 211 are below the projected extension of conglomeratic sandstone strata, 33 are beyond the safe limits of such projection, and 18 are lateral to the margins of conglomeratic sandstone strata. At places, near clusters of deposits in the uppermost sandstone of the underlying Salt Wash Member, conglomeratic sandstone strata of the Brushy Basin Member are also mineralized. It is postulated that ground-water movement during deposition of the Morrison Formation in Late Jurassic time localized the uranium and vanadium. The direction of this ground-water movement is believed to have been related to streams that deposited the conglomeratic strata, so that in the ore-bearing sandstone metal ions contained in the ground water were localized in places of high transmissibility and in the vicinity of decaying organic debris. According to the age of the ores, precipitation of the metals was much later than their localization, probably during Late Cretaceous or early Tertiary time.

Colorado, Utah

Comparison of uranium-series, radiocarbon, and amino acid data from marine molluscs, Baffin Island, Arctic Canada

Uranium-series and 14 C dates and the extent of amino acid racemization are reported for 24 marine shell samples from three areas of Baffin Island, Arctic Canada. When the radiometric dates are plotted against the ratio of D-alloisoleucene:L-isoleucene in the shells, five broad age groups are recognized. The uranium-series data indicate that 231 Pa is incompletely retained in most fossil shells and that 230 Th is lost from some of the samples. Therefore, their apparent ages are minimum. However, a few dated samples in each group have yielded useful age results, and the minimum ages of the five groups of samples are estimated as 7,000 to 11,000, ≥ 70,000, ≥ 136,000, ≥ 190,000, and > 300,000 yr. Calculated integrated thermal histories based on the epimerization reaction in the mollusc Hiatella arctica Linné give paleotemperature estimates of around −5 °C, compared to the present mean annual air temperature of about −11 °C.

Baffin Island

Uranium-bearing sandstone deposits of the Colorado Plateau

The uranium-bearing sandstone deposits of the Colorado Plateau are commonly referred to as "carnotite deposits." They have been the principal domestic source of uranium, radium, and vanadium. The deposits are largely restricted to a few stratigraphic zones, along which they have a wide but spotty areal distribution. The ore minerals mainly impregnate sandstone, though in places fossil plants are richly mineralized. Most of the ore bodies are small, but have a wide range in size, and within individual deposits the ore has a considerable range in thickness and grade. The deposits are irregularly tabular or lenticular, with their long axes nearly parallel to the bedding, but the ore does not follow the beds in detail.The ore is thought to have been precipitated from ground-water solutions after the enclosing sands had accumulated and before regional deformation. Sedimentary structures that seem to have controlled the movement of these solutions and the features that probably localized the ore deposits are described, and their application as guides to ore finding is explained.

Colorado, Utah, Wyoming

Application of punched cards to geologic data concerning uranium deposits in sandstone

The punched card has been chosen for use in compiling the great mass of geologic data concerning uranium deposits in sandstone into permanent file. The most valuable uses of the punched-card file are as a multiple index to data and as a means of correlating different data. By using the punched card, uranium deposits in sandstone can also be compared to other metalliferous deposits in sandstone.Besides the geographic location of the deposit, about 120 different items can be punched on the sides of the card. In the center of the card more detailed data and a summary of the report are given. Although the card is designed for data on a single deposit or group of deposits, topical data on many studies such as chemistry, geobotanical prospecting, and geophysics can be summarized on the card.

Economic Geology

Correlation of uranium, thorium, and potassium with aeroradioaetivity in the Berea Area, Virginia

In the Berea area, a small quartz monzonite pluton intrudes chlorite-actinolite schist and is overlapped by Coastal Plain sand and gravel deposits. A detailed aeroradioactivity survey of the area shows unusually high radioactivity (1,150 counts per second) over the quartz monzonite. A total of 22 auger samples was taken across all formations to a depth of 2 to 3 feet, and radioelement concentrations were determined by gamma-ray spectrometry. There is a general direct correlation of high radioactivity with increase in radioelement concentrations. Abundances of uranium and particularly thorium in the quartz monzonite are two and three times the average for rocks of this type; a comparison is made with other granitic rocks high in uranium and thorium. © 1971 Society of Economic Geologists, Inc.

Virginia

Origin of a South Texas roll-type uranium deposit; I, Alteration of iron-titanium oxide minerals

The detrital Fe-Ti oxide minerals and their authigenic alteration products in samples from cores spanning 1.7 km across a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, south Texas, record important information on host-rock preparation and on development of the altered tongue of the deposit. In reduced rock, in front of and enveloping the altered tongue, iron disulfide minerals (pyrite and marcasite) have partially to completely replaced titanomagnetite and, to a lesser extent, titanohematite. Subsequent oxidation of these sulfidized Fe-Ti oxides, by processes that formed the altered tongue and uranium roll, produced ferric oxide and hydroxide phases (limonite) pseudomorphous after the sulfides. Fe-Ti oxides 1.0 km updip from the roll front were never sulfidized; titanomagnetite (partly replaced by hematite) and martite constitute nearly half of the heavy mineral fraction and limonite is absent. Oxidized rocks 210 m and closer to the nose of the roll front, however, are nearly devoid of titanomagnetite and contain abundant limonite. The redox interface that bounds the altered tongue, therefore, moved more than 210 m but less than 1.0 km. Detrital Fe-Ti oxide minerals are increasingly sulfidized in the downdip direction indicating that initial sulfidizaton was more intense in that direction. Organic carbon content is uniformly very low throughout the host sandstone, which implies that heterotrophic sulfate-reducing bacteria were not involved in the generation of sulfide. The H 2 S for the initial sulfidization may have been derived from oil and gas in formations that underlie the Catahoula Tuff. The H 2 S probably invaded the Catahoula along a fault that is 1.5 km downdip from the present roll front.

Texas

Biogenic and nonbiogenic ore-forming processes in the south Texas uranium district; evidence from the Panna Maria deposit

Geochemical and petrographic studies of core samples from the Panna Maria uranium deposit, a roll-type orebody in the Eocene Jackson Group in Karnes County, Texas, yield important information on the origin of the deposit. Organic carbon content averages about 0.42 weight percent in reduced rock and correlates postively with sulfur content. Pyrite is the dominant iron disulfide (FeS 2 ) mineral in most of the ore zone and throughout a surrounding zone of reduced barren ground, and it is commonly associated with organic debris. Marcasite is sparse except in ore adjacent to the altered tongue in one core and locally in mineralized lignite. Sulfur isotopic compositions (delta 34 S) of FeS 2 minerals range broadly from -1 to -34 per mil; the lightest delta 34 S values (less than -20 per mil) were measured in samples from mineralized lignite and from the nose of the ore roll. Petrographic and geochemical characteristics of the Panna Maria deposit contrast greatly with those of three other south Texas roll-type uranium deposits (the Benavides, Felder, and Lamprecht deposits), which are devoid of organic carbon and which contain more sulfide than does the Panna Maria. These three deposits are characterized by abundant isotopically light ore-stage marcasite and by isotopically heavy preore (in the Benavides) or postore (in the Felder and Lamprecht) pyrite. We have concluded previously that sulfide-bearing fault-leaked solutions from underlying hydrocarbon accumulations were important in the formation of the Benavides, Felder, and Lamprecht deposits. Although the Panna Maria deposit shows an apparent alignment along a fault zone, and although underlying formations in the Karnes County area contain sour gas (delta 34 S [asymp] + 14 per mil) and produce oil, the deposit lacks characteristics indicating that its formation or preservation involved extrinsically derived reductants such as fault-leaked aqueous sulfide. Mineralization of the Panna Maria, rather, appears to have been controlled by intrinsically derived reductants related either directly or indirectly to the presence of organic matter.

Texas

Results and assessment of uranium series dating of vertebrate fossils from Quaternary alluvium in Colorado

An average uranium-series age of 102,000 ± 14,000 yr for bones from Louviers Alluvium, near Denver, Colorado, is compatible with the inferred geologic age of from 120,000 to 150,000 yr. A uranium-series date of about 190,000 yr for a bone from Slocum Alluvium, near Canon City, Colorado, is consistent with the inferred geologic age of from 150,000 to 260,000 yr. Age determinations for the Broadway Alluvium are inconsistent but its geologic age is considered to be 15,000 to 30,000 yr BP.

Colorado

Arsenic, iron, lead, manganese, and uranium concentrations in private bedrock wells in southeastern New Hampshire, 2012-2013

Trace metals, such as arsenic, iron, lead, manganese, and uranium, in groundwater used for drinking have long been a concern because of the potential adverse effects on human health and the aesthetic or nuisance problems that some present. Moderate to high concentrations of the trace metal arsenic have been identified in drinking water from groundwater sources in southeastern New Hampshire, a rapidly growing region of the State (Montgomery and others, 2003). During the past decade (2000–10), southeastern New Hampshire, which is composed of Hillsborough, Rockingham, and Strafford Counties, has grown in population by nearly 48,700 (or 6.4 percent) to 819,100. These three counties contain 62 percent of the State’s population but encompass only about 22 percent of the land area (New Hampshire Office of Energy and Planning, 2011). According to a 2005 water-use study (Hayes and Horn, 2009), about 39 percent of the population in these three counties in southeastern New Hampshire uses private wells as sources of drinking water, and these wells are not required by the State to be routinely tested for trace metals or other contaminants. Some trace metals have associated human-health benchmarks or nonhealth guidelines that have been established by the U.S. Environmental Protection Agency (EPA) to regulate public water supplies. The EPA has established a maximum contaminant level (MCL) of 10 micrograms per liter (μg/L) for arsenic (As) and a MCL of 30 μg/L for uranium (U) because of associated health risks (U.S. Environmental Protection Agency, 2012). Iron (Fe) and manganese (Mn) are essential for human health, but Mn at high doses may have adverse cognitive effects in children (Bouchard and others, 2011; Agency for Toxic Substances and Disease Registry, 2012); therefore, the EPA has issued a lifetime health advisory (LHA) of 300 μg/L for Mn. Recommended secondary maximum contaminant levels (SMCLs) for Fe (300 μg/L) and Mn (50 μg/L) were established primarily as nonhealth guidelines—based on aesthetic considerations, such as taste or the staining of laundry and plumbing fixtures—because these contaminants, at the SMCLs, are not considered to present risks to human health. Because lead (Pb) contamination of drinking water typically results from corrosion of plumbing materials belonging to water-system customers but still poses a risk to human health, the EPA established an action level (AL) of 15 μg/L for Pb instead of an MCL or SMCL (U.S. Environmental Protection Agency, 2012). The 15-μg/L AL for Pb has been adopted by the New Hampshire Department of Environmental Services for public water systems, and if exceeded, the public water system must inform their customers and undertake additional actions to control corrosion in the pipes of the distribution system (New Hampshire Department of Environmental Services, 2013). Unlike the quality of drinking water provided by public water suppliers, the quality of drinking water obtained from private wells in New Hampshire is not regulated; consequently, private wells are sampled only when individual well owners voluntarily choose to sample them. The U.S. Geological Survey (USGS), in cooperation with the EPA New England, conducted an assessment in 2012–13 to provide private well owners and State and Federal health officials with information on the distribution of trace-metal (As, Fe, Pb, Mn, and U) concentrations in groundwater from bedrock aquifers in the three counties of southeastern New Hampshire. This fact sheet analyzes data from water samples collected by a randomly selected group of private well owners from the three-county study area and describes the major findings for trace-metal concentrations.

New Hampshire

Balancing natural resource use and extraction of uranium and other elements in the Grand Canyon region

The Grand Canyon region is an important natural, cultural, and archeological resource known worldwide. The region contains uranium resources that could be used to generate electricity. The U.S. Geological Survey (USGS), in cooperation with the National Park Service, Bureau of Land Management, and U.S. Department of Agriculture Forest Service, is conducting studies to answer questions about the environmental effects of mining uranium and other associated elements in the region.

Arizona

Mineral resource assessment of rare-earth elements, thorium, titanium, and uranium in the Greenville 1° x 2° quadrangle, South Carolina, Georgia, and North Carolina

Mineral resources of the Greenville 1° x 2° quadrangle, South Carolina, Georgia, and North Carolina, were assessed between 1984 and 1990 under the Conterminuous United States Mineral Assessment Program (CUSMAP) of the U.S. Geological Survey (USGS). The mineral resource assessments were made on the basis of geologic, geochemical, and geophysical investigations and the presence of mines, prospects, and mineral occurrences from the literature. This report is an assessment of the rare-earth elements (REE), thorium, titanium, and uranium resources in the Greenville quadrangle and is based on heavy mineral concentrates collected in 1951-54 by the USGS (Overstreet and others, 1968; Caldwell and White, 1973; Cuppels and White, 1973); on the results of the U.S. Department of Energy, National Uranium Resource Evaluation (NURE) sampling program (Ferguson, 1978, 1979); on analyses of stream-sediment and heavy-mineral-concentrate samples (Jackson and Moore, 1992, G.C Cullin, USGS, unpub. data, 1992) on maps showing aerial gamma radiation in the Greenville quadrangle (D.L. Daniels, USGS, unpub. data, 1992); and on the geology as mapped by Nelson and others (1987, 1989).

Georgia, North Carolina, South Carolina

Aeromagnetic and Aeroradiometric Data for the Conterminous United States and Alaska from the National Uranium Resource Evaluation (NURE) Program of the U.S. Department of Energy

The National Uranium Resource Evaluation (NURE) program was initiated in 1973 with a primary goal of identifying uranium resources in the United States. The airborne program's main purpose was to collect radiometric data of the conterminous United States and Alaska. Magnetic data were also collected. After the program ended, most of the data were given to the U.S. Geological Survey (USGS). All areas were flown at about 400 feet above ground, the optimum height for collecting radiometric data, and the line spacing varied from 3 to 6 mile intervals. A few selected quadrangles or parts of quadrangles were flown at 1- or 2-mile line spacing. About forty smaller areas were targeted and flown at 0.25-mile to 1 mile line spacing.

Open-File Report

Groundwater restoration at uranium in-situ recovery mines, south Texas coastal plain

This talk was presented by U.S. Geological Survey (USGS) geologist Susan Hall on May 11, 2009, at the Uranium 2009 conference in Keystone, Colorado, and on May 12, 2009, as part of an underground injection control track presentation at the Texas Commission on Environmental Quality (TCEQ) Environmental Trade Fair and Conference in Austin, Texas. Texas has been the location of the greatest number of uranium in-situ recovery (ISR) mines in the United States and was the incubator for the development of alkaline leach technology in this country. For that reason, the author chose to focus on the effectiveness of restoration at ISR mines by examining legacy mines developed in Texas. The best source for accurate information about restoration at Texas ISR mines is housed at the TCEQ offices in Austin. The bulk of this research is an analysis of those records.

Open-File Report

Reconnaissance soil geochemistry at the Riverton Uranium Mill Tailings Remedial Action Site, Fremont County, Wyoming

Soil samples were collected and chemically analyzed from the Riverton Uranium Mill Tailings Remedial Action Site, which lies within the Wind River Indian Reservation in Fremont County, Wyoming. Nineteen soil samples from a depth of 0 to 5 centimeters were collected in August 2011 from the site. The samples were sieved to less than 2 millimeters and analyzed for 44 major and trace elements following a near-total multi-acid extraction. Soil pH was also determined. The geochemical data were compared to a background dataset consisting of 160 soil samples previously collected from the same depth throughout the State of Wyoming as part of another ongoing study by the U.S. Geological Survey. Risk from potentially toxic elements in soil from the site to biologic receptors and humans was estimated by comparing the concentration of these elements with soil screening values established by the U.S. Environmental Protection Agency. All 19 samples exceeded the carcinogenic human health screening level for arsenic in residential soils of 0.39 milligrams per kilogram (mg/kg), which represents a one-in-one-million cancer risk (median arsenic concentration in the study area is 2.7 mg/kg). All 19 samples also exceeded the lead and vanadium screening levels for birds. Eighteen of the 19 samples exceeded the manganese screening level for plants, 13 of the 19 samples exceeded the antimony screening level for mammals, and 10 of 19 samples exceeded the zinc screening level for birds. However, these exceedances are also found in soils at most locations in the Wyoming Statewide soil database, and elevated concentrations alone are not necessarily cause for alarm. Uranium and thorium, two other elements of environmental concern, are elevated in soils at the site as compared to the Wyoming dataset, but no human or ecological soil screening levels have been established for these elements.

Wyoming

Solid-phase data from cores at the proposed Dewey Burdock uranium in-situ recovery mine, near Edgemont, South Dakota

This report releases solid-phase data from cores at the proposed Dewey Burdock uranium in-situ recovery site near Edgemont, South Dakota. These cores were collected by Powertech Uranium Corporation, and material not used for their analyses were given to the U.S. Geological Survey for additional sampling and analyses. These additional analyses included total carbon and sulfur, whole rock acid digestion for major and trace elements, 234 U/ 238 U activity ratios, X-ray diffraction, thin sections, scanning electron microscopy analyses, and cathodoluminescence. This report provides the methods and data results from these analyses along with a short summary of observations.

South Dakota