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At least 397 records · Page 22Linked to original sources
USGS2017

The formation of gullies on Mars today

A decade of high-resolution monitoring has revealed extensive activity in fresh Martian gullies. Flows within the gullies are diverse: they can be relatively light, neutral or dark, colourful or bland, and range from superficial deposits to 10 m-scale topographic changes. We observed erosion and transport of material within gullies, new terraces, freshly eroded channel segments, migrating sinuous curves, channel abandonment, and lobate deposits. We also observed early stages of gully initiation, demonstrating that these processes are not merely modifying pre-existing landforms. The timing of activity closely correlates with the presence of seasonal CO 2 frost, so the current changes must be part of ongoing gully formation that is driven largely by its presence. We suggest that the cumulative effect of many flows erodes alcoves and channels, and builds lobate aprons, with no involvement of liquid water. Instead, flows may be fluidized by sublimation of entrained CO 2 ice or other mechanisms. The frequent activity is likely to have erased any features dating from high-obliquity periods, so fresh gully geomorphology at middle and high latitudes is not evidence for past liquid water. CO 2 ice-driven processes may have been important throughout Martian geological history and their deposits could exist in the rock record, perhaps resembling debris-flow sediments.

Geological Society, London, Special Publications↗
USGS2026

PDCD-DAT: A global database of pyroclastic density current deposit field data

Pyroclastic density currents represent one of the deadliest hazards posed by active volcanoes. Analysis of their deposits provides valuable insights into their internal dynamics and informs numerical simulations of pyroclastic density currents which underpin many volcanic hazard assessments. We present PDCD-DAT, a global database of pyroclastic density current deposit characteristics compiled from peer-reviewed literature. The database includes both quantitative datasets (e.g., grain size, density, bedform dimensions, thickness) and qualitative descriptors (e.g., sedimentary structures, lithofacies). PDCD-DAT includes data from 85 source publications, covering 97 eruptions or eruptive phases, and 214 individual depositional units from 55 globally distributed volcanoes. Eruptions recorded in the database range from VEI 1–8. We highlight examples of potential applications of the database, which include (i) comparison of single deposit case studies to global datasets, (ii) informing input parameters and conditions for numerical and analogue models of pyroclastic density currents, (iii) validation of numerical and analogue models against a wide variety of natural case study deposit architectures, and (iv) estimating hazard impact metrics of pyroclastic density currents from past eruptions. We show that the database represents a useful tool for improving our ability to model pyroclastic density currents, predict their associated hazards, and understand the relationships between the internal dynamics of pyroclastic density currents and the properties of their deposits. PDCD-DAT is integrated with the FlowDat Mass Flow Database, which provides a sustainable platform for the database. We aim for PDCD-DAT to be expanded in the future through addition of pyroclastic density current deposit datasets from new field studies conducted by the volcanology research community.

Journal of Applied Volcanology↗
USGS2002

Geological framework data from Long Island Sound, 1981-1990: A digital data release

Introduction Since 1980 the Coastal and Marine Geology Program of the U.S. Geological Survey and Connecticut Department of Environmental Protection have conducted a joint program of cooperative geologic research in Long Island Sound and its vicinity. As part of this program, a highly successful regional-scale study of the geologic framework was completed. Reconnaissance high-resolution seismic reflection data were collected and used to establish the basic stratigraphy within the Sound and to map the major geologic units; field verification of the geologic interpretations of the seismic profiles was primarily accomplished with vibratory cores. These interpretations were in turn used to produce basin-wide syntheses of the late Quaternary depositional history. Unfortunately, the original seismic records and core logs were generated only in analog form. These unique paper documents, which are still under demand for industrial applications and academic research, are fragile and have become ragged from frequent use. The purpose of this report is to preserve these data by converting the seismic profiles, core descriptions, and ancillary reports into digital form, and to organize these files into a product that can be more readily accessed and disseminated. Not all of the existing high-resolution seismic-reflection surveys, collected in Long Island Sound through cooperatives with the U.S. Geological Survey and the Connecticut Department of Environmental Protection, have been incorporated into this report. These surveys, whose records are still in need of preprocessing and annotation, generally cover smaller areas along the Connecticut coast and were originally intended to provide additional detail to the larger, more regional data sets presented herein. The digital release of the omitted data sets is planned as part of a future product.

Connecticut, New York↗
USGS2004

Immunoassay screening of sediment cores for polychlorinated biphenyls, Devil's Swamp Lake near Baton Rouge, Louisiana, 2004

Devil’s Swamp Lake near Baton Rouge, Louisiana, constructed by dredging in 1973 in Devil’s Swamp along the Mississippi River, is contaminated with polychlorinated biphenyls (PCBs). This study investigated the possible historical contribution of PCBs from a hazardous-chemical disposal facility by way of a wastewater drainage ditch that operated from 1971 to 1993. Six sediment cores from the lake and three bottom-material samples from the drainage ditch were collected on October 5, 2004, and analyzed for PCBs using an immunoassay screening method. The results were used to evaluate qualitatively the historical input record of PCBs to the lake. Deposition dates in three of the cores were estimated by assuming that penetration of the push corer was stopped by firmer, pre-lake materials that mark the 1973 subsurface level of dredging. Sixty-one samples from five of the six cores and three bottom-material samples from the drainage ditch were analyzed. PCBs were at higher concentrations in ditch bottom material (about 1.1 to 2.2 milligrams per kilogram) than in cores from sites near where the ditch enters the lake (about 0.1 to 1.0 milligrams per kilogram). The highest concentrations of PCBs (maximum about 15 milligrams per kilogram) were detected in lake-bottom sediment about 350 meters west of where the drainage ditch enters the lake. Detection rates and median PCB concentrations were higher in all of the dated core sediments deposited before about 1990 than after 1990.

Louisiana↗
USGS1999

An ARC/Info point coverage of Mineral Resource Data System (MRDS) locations in eleven western states

This ARC/Info coverage, derived from the USGS Mineral Resource Data System (MRDS), contains 60,490 records that fall within the states of Arizona, California, Colorado, Idaho, Montana, New Mexico, Nevada, Oregon, Utah, Washington, Wyoming. The dataset has 13 fields containing information on record identification, location, commodity, geology, and deposit type. The data for this report was retrieved from the master database as a tab text file and imported into a Microsoft Access database. The data was then imported into ESRI’s ArcView where shape files were created. These shape files were then converted into an ARC/INFO coverage.

Arizona, California, Colorado, Idaho, Montana, New↗
USGS2008

Late-Holocene fossil rodent middens from the Arica region of northernmost Chile

Identification of >40 taxa of plant macrofossils in 14 rodent (Abrocoma) middens collected from 2800 to 3590 m elevation at the latitude of Arica, Chile (18°S) provide snapshots of vegetation in the northernmost Atacama Desert over the past 3000 years. Midden floras show considerable stability throughout the late Holocene, which may be due in part to the broad elevational ranges of many perennial species and midden insensitivity to changes in plant community structure. The greatest variability is found in annuals in the Prepuna, a climatically sensitive zone. This variability, however might also arise from the brevity of midden depositional episodes. As the first midden record from the Arica-Parinacota Region (Chile's northernmost administrative region), this study demonstrates the potential for future midden research in this area.

Arica-Parinacota Region↗
USGS1999

Diagenesis of lower Cretaceous pelagic carbonates, North Atlantic: Paleoceanographic signals obscured

The stable isotope and minor element geochemistry of Neocomian (Lower Cretaceous) pelagic carbonates of the North Atlantic Basin (Deep Sea Drilling Project Sites 105, 367, 387, 391, and 603) was examined to develop a diagenetic model for pelagic limestones. In particular, we hoped to test the fidelity of whole-rock geochemical records as paleoceanographic indicators for pelagic deposits of pre-Aptian age, in which individual microfossils are not available for analysis. Data indicate that in addition to depth of burial, rhythmic variations in primary carbonate content have strongly controlled diagenetic patterns and associated geochemical signatures in these Neocomian sequences. Samples become increasingly depleted in Sr and 18O with increasing CaCO3 content. Within individual sedimentary sections, substantial decreases in Sr/Ca ratios and ??18O values are evident over a range of 4 to 98% CaCO3. However, even over a relatively narrow range of 50 to 98% CaCO3 a 2.5%c variation in ??18O values and a change of a factor of 1.7 in Sr/Ca ratios are observed. Carbon isotope compositions do not vary as extensively with CaCO3 content, but carbonate-rich intervals tend to be relatively depleted in 13C. Petrographic analysis reveals that these geochemical patterns are related to the transfer of CaCO3 from carbonate-poor intervals (calcareous shales and marlstones) to adjacent carbonate-rich intervals (limestones) during burial compaction and pressure solution. This process results in the addition of diagenetic cement to carbonate-rich intervals to produce a bulk composition that is relatively depleted in Sr and 18O and, at the same time, enables the retention of more-or-less primary carbonate that is relatively enriched in Sr and 18O in adjacent carbonate-poor intervals. Thus, although cyclic variations in CaCO3 content are primary in the Neocomian sequences examined, measured variations in Sr/Ca ratios and ??18O values are not and, as such, do not provide reliable proxies for past variations in climate, oceanographic conditions, or global ice volume.

Journal of Foraminiferal Research↗
USGS2019

Recent sandy deposits at five northern California coastal wetlands — Stratigraphy, diatoms, and implications for storm and tsunami hazards

A recent geological record of inundation by tsunamis or storm surges is evidenced by deposits found within the first few meters of the modern surface at five wetlands on the northern California coast. The study sites include three locations in the Crescent City area (Marhoffer Creek marsh, Elk Creek wetland, and Sand Mine marsh), O’rekw marsh in the lower Redwood Creek alluvial valley, and Pillar Point marsh at the northern end of Half Moon Bay.

California↗
USGS2020

Climatically driven displacement on the Eglington fault, Las Vegas, Nevada

The Eglington fault is one of several intrabasinal faults in the Las Vegas Valley, Nevada and is the only one recognized as a source for significant earthquakes. Its broad warp displaces late Pleistocene paleo-spring deposits of the Las Vegas Formation, which record hydrologic fluctuations that occurred in response to millennial and submillennial-scale climate oscillations throughout the late Quaternary. The sediments allow us to constrain the timing of displacement on the Eglington fault and identify hydrologic changes that are temporally coincident with that event. The fault warps deposits that represent widespread marshes that filled the valley between 31.7 and 27.6 ka. These marshes desiccated abruptly in response to warming and groundwater lowering during Dansgaard-Oeschger (D-O) events 4 and 3, resulting in the formation of a pervasive, hard carbonate cap by 27.0 ka. Vertical offset by as much as 4.2 meters occurred after the cap hardened, and most likely after younger marshes desiccated irreversibly due to a sudden depression of the water table during D-O 2, beginning at 23.3 ka. The timing of displacement is further constrained to before 19.5 ka as evidenced by undeformed spring deposits that are inset into the incised topography of the warp. Coulomb stress calculations validate the hypothesis that the significant groundwater decline during D-O 2 triggered fault displacement through unloading of vertical stress of the water column. The synchroneity of this abrupt hydrologic change and warping on the Eglington fault suggests that climatically modulated tectonics operated in the Las Vegas Valley during the late Quaternary.

Nevada↗
USGS1996

Charcoal deposition and redeposition in Elk Lake, Minnesota, USA

Sedimentary charcoal, diatom and phytolith records of the past 1500 years at Elk Lake, Minnesota, in combination with sediment trap studies and a transect of surface sediment samples, document the mechanisms by which previously deposited charcoal is redeposited and finally buried in this lake. The frequent correspon dence of high diatom concentrations and peaks of phytolith and charcoal fragments suggests that currents and turbulence related to lake circulation are responsible for winnowing charcoal and phytoliths from shallow water depositional sites to deeper areas of the lake. High diatom concentrations in the record relate to increased nutrient fluxes also supplied by circulation. Despite the fact that the watershed and area around Elk Lake has not been burned since AD 1922, charcoal continues to reach the profundal zone from littoral source areas in Elk Lake. The variable redeposition of within-lake charcoal requires evaluation before fire-history records can be related to global, regional or even local fire events.

Holocene↗
USGS1991

Modern sedimentary environments in Boston Harbor, Massachusetts

Analyses of sidescan-sonar records supplemented by available bathymetric, sedimentary, subbottom, and bottom-current data reveal the distributions of the following three categories of sedimentary environments within the glaciated, topographically complex Boston Harbor estuary in Massachusetts. 1) Environments of erosion appear on the sonographs either as patterns with isolated strong reflections or as uniform patterns of strong reflectivity. These patterns define outcrops of bedrock or till and coarse lag deposits that are being scoured and winnowed by tidal- and wave-induced currents. Erosional areas are located primarily along mainland and insular shores, within large channels that have strong tidal currents, atop submerged ridges and knolls, and across much of the harbor entrance. 2) Environments of deposition are depicted on the sidescan-sonar records as smooth, featureless surfaces that have low to moderate reflectivity. Depositional environments are found predominantly over shallow subtidal flats and in broad bathymetric lows where tidal currents are weak. Sediments within depositional areas are organic-rich sandy and clayey silts that are accumulating at rates ranging from 0.01 to 0.11 g/cm 2 /yr or 4000 to 46,100 metric tons/yr. The cumulative mass of modern mud in harbor depocenters is 24.3 million metric tons. 3) Environments of sediment reworking constitute areas affected by a combination of erosional and depositional processes. They are characterized on the sonographs by mosaics of light and dark patches produced by relatively subtle and gradational changes in reflectivity. Reworked sediments have diverse grain sizes that overlap and are transitional between those of the other two sedimentary environments, and they are indicative of highly variable bottom currents.

Massachusetts↗
USGS1991

Pliocene-Pleistocene coastal events and history along the western margin of Australia

Coastal deposits along the western coastal margin of Australia, a region of relative tectonic stability, record Plio-Pleistocene events and processes affecting the inner shelf and adjacent hinterland. Tectonic deformation of these deposits is more apparent in the Carnarvon Basin, and rather less so in the Perth Basin. The most complete record comes from the Perth Basin, where units of Pliocene and Pleistocene ages are well represented. In the Perth Basin, the predominantly siliciclastic Yoganup Formation, Ascot Formation and Bassendean Sand represent a complex of shoreline, inner shelf and regressive-dune facies equivalents, the deposition of which began at an undetermined stage of the Pliocene, through to the Early Pleistocene. The deposition of this sequence closed with a major regression and significant faunal extinction. Bioclastic carbonates characterize the Middle and Late Pleistocene of the Perth and Carnarvon basins. Fossil assemblages include a distinct subtropical element, unknown from the Ascot Formation and suggesting a strengthening of the Leeuwin Current. The estuarine arcoid bivalve Anadara trapezia characterizes assemblages of Oxygen Isotope Stages 5 and 7 in the Perth and Carnarvon basins, where it is now extinct. Deposits of Substage 5e (Perth Basin) also record a southerly expansion of warm-water corals and other fauna consistent with shelf temperatures warmer than present. New uranium-series ages on corals from marine sequences of the Tantabiddi Member, of the Bundera Calcarenite of the western Cape Range are consistent with the ‘double peak’ hypothesis for levels of Substage 5e but the evidence remains less than conclusive. Initial uranium-series dates from the Bibra and Dampier formations of Shark Bay indicate that both derive from the Late Pleistocene. These numerical ages contradict previous interpretations of relative ages obtained from field studies. The age relationship of the units requires further investigation.

Quaternary Science Reviews↗
USGS2016

Trends in mercury wet deposition and mercury air concentrations across the U.S. and Canada

This study examined the spatial and temporal trends of mercury (Hg) in wet deposition and air concentrations in the United States (U.S.) and Canada between 1997 and 2013. Data were obtained from the National Atmospheric Deposition Program (NADP) and Environment Canada monitoring networks, and other sources. Of the 19 sites with data records from 1997–2013, 53% had significant negative trends in Hg concentration in wet deposition, while no sites had significant positive trends, which is in general agreement with earlier studies that considered NADP data up until about 2010. However, for the time period 2007–2013 (71 sites), 17% and 13% of the sites had significant positive and negative trends, respectively, and for the time period 2008–2013 (81 sites) 30% and 6% of the sites had significant positive and negative trends, respectively. Non-significant positive tendencies were also widespread. Regional trend analyses revealed significant positive trends in Hg concentration in the Rocky Mountains, Plains, and Upper Midwest regions for the recent time periods in addition to significant positive trends in Hg deposition for the continent as a whole. Sulfate concentration trends in wet deposition were negative in all regions, suggesting a lower importance of local Hg sources. The trend in gaseous elemental Hg from short-term datasets merged as one continuous record was broadly consistent with trends in Hg concentration in wet deposition, with the early time period (1998–2007) producing a significantly negative trend (− 1.5 ± 0.2% year − 1 ) and the recent time period (2008–2013) displaying a flat slope (− 0.3 ± 0.1% year − 1 , not significant). The observed shift to more positive or less negative trends in Hg wet deposition primarily seen in the Central-Western regions is consistent with the effects of rising Hg emissions from regions outside the U.S. and Canada and the influence of long-range transport in the free troposphere.

Science of the Total Environment↗
USGS2005

Stratabound copper-silver deposits of the Mesoproterozoic Revett Formation, Montana and Idaho, with a section on databases and spatial-data files for the geology and mineral deposits of the Revett Formation

The western Montana copper belt in western Montana and northern Idaho contains several large stratabound copper-silver deposits in fine- to medium-grained quartzite beds of the Revett Formation of the Mesoproterozoic (1,470-1,401 Ma) Belt Supergroup. Production from the deposits at the Troy Mine and lesser production from the Snowstorm Mine has yielded 222,237 tons Cu and 1,657.4 tons Ag. Estimates of undeveloped resources, mostly from the world-class Rock Creek-Montanore deposits, as well as lesser amounts at the Troy Mine, total more than 2.9 million tons Cu and 2,600 tons Ag in 406 million tons of ore.The Rock Creek-Montanore and Troy deposits, which are currently the most significant undeveloped resources identified in the copper belt, are also among the largest stratabound copper-silver deposits in North America and contain about 15 percent of the copper in such deposits in North America. Worldwide, stratabound copper-silver deposits contain 23 percent of all copper resources and are the second-most important global source of the metal after porphyry copper deposits.The Revett Formation, which consists of subequal amounts of argillite, siltite, and quartzite, is informally divided into lower, middle, and upper members on the basis of the proportions of the dominant rock types. The unit thickness increases from north to south, from 1,700 ft near the Troy Mine, 55 mi north of Wallace, Idaho, to more than 5,300 ft at Wallace, Idaho, in the Coeur d'Alene Trough south of the Osburn Fault, a major right-lateral strike-slip fault.Mineral deposits in the Revett Formation occur mostly in the A-D beds of the lower member and in the middle quartzite of the upper member. The deposits are concentrated along a preore pyrite/hematite interface in relatively coarse grained, thick quartzite beds that acted as paleoaquifers for ore fluids. The deposits are characterized by mineral zones (alteration-mineral assemblages) that are a useful guide to the locations of mineral deposits. In particular, the gradational zone between the chalcopyrite-ankerite and pyrite-calcite zones is the site of most mineral deposits. Detailed information on the geology and mineral deposits of the Revett Formation is presented in the accompanying files that include (1) a tab-delimited text file providing details of the geologic and mineral-resource data for 57 Revett-subtype stratabound copper-silver deposits, occurrences, and prospects; (2) the stratigraphic records of 40 diamond-drill cores and 86 measured sections, totaling 150,752 ft of true thickness, which are provided in Excel spreadsheet and Adobe Portable Document Format files; and (3) spatial geologic data consisting of geologic maps of the Revett Formation, the subsurface locations of resources in Revett-subtype stratabound copper-silver deposits based on diamond-drill-core data, and the locations of diamond-drill holes and measured sections. The spatial data are contained in Arc/Info interchange files. Spatial information derived from these data includes the locations of mineral zones, a digital database showing untested exploration areas, and a digital database of permissive tracts for undiscovered mineral deposits.

Idaho, Montana↗
USGS2025

Calcareous nannofossil biostratigraphy and floral response to environmental changes recorded in the Pliocene Yorktown Formation, southeastern Virginia, USA

The Pliocene Yorktown Formation, deposited on the U.S. Mid-Atlantic Coastal Plain, has played an important role in advancing our knowledge of Pliocene paleoclimate. To refine the age and paleoenvironment of the Yorktown Formation, we analyzed the calcareous nannofossil assemblage and compared it with variations in lithology and calculated sea surface temperature (SST) from previous studies. The Yorktown Formation in the studied sections consists of, in ascending order, the Sunken Meadow, Rushmere, Morgarts Beach, and Moore House members. Sediment samples were collected from these units and analyzed for calcareous nannoplankton assemblages. The last occurrences of both Reticulofenestra pseudoumbilicus (3.82 Ma) and Sphenolithus spp. (3.61 Ma) were recognized within the Sunken Meadow Member. Discoaster tamalis and Discoaster surculus sporadically occurred within the Rushmere Member, but no specimens of the genus Sphenolithus were recorded, suggesting that this unit was deposited sometime between 3.61–2.76Ma. Rare occurrences of the genus Discoaster made it difficult to constrain the age of the Morgarts Beach and Moore House members, but they are most likely deposited before re-entrance of small Gephyrocapsa (ca. 2.5 Ma), supporting previous age estimates based on planktic foraminiferal biostratigraphy and variation in alkenone-based sea-surface temperature estimates. The abrupt decline of both cold-water species ( Coccolithus pelagicus ) and coastal species ( Helicosphaera spp.) is associated with a rise in SST within the Rushmere Member just below the Morgarts Beach Member, and it may reflect a rapid transgression following the global sea-level low stand associated with Marine Isotope Stage (MIS)M2.

Virginia↗
USGS1996

Seafloor environments in Cape Cod Bay, a large coastal embayment

Cape Cod Bay is a glacial, semi-enclosed embayment that has a patchy distribution of modern seafloor sedimentary environments of erosion or nondeposition, deposition, and sediment reworking. Sidescan-sonar records and supplemental bathymetric, sedimentary, subbottom, and physical-oceanographic data indicate that the characteristics and distribution of these three categories of bottom environments are controlled by a combination of geologic and oceanographic processes that range from episodic to long-term and from regional to local. (1) Environments of erosion or nondeposition comprise exposures of bedrock, glacial drift, and coarse lag deposits that contain sediments (where present) ranging from boulder fields to gravelly coarse-to-medium sands. These environments are dominant on the shallow margins of the bay (water depths < 30 m) where they reflect sediment resuspension, winnowing, and transport during modern northerly storms. (2) Environments of deposition are blanketed by fine-grained sediments ranging from muds to muddy fine sands. These environments are dominant across the floor of the central basin (water depths = 30–60 m) where fine-grained sediments (derived from regional and local sources and emplaced primarily during episodic wind- and density-driven flow) settle through the water column and accumulate under weak bottom currents during nonstorm conditions. (3) Environments of sediment reworking contain patches with diverse textures ranging from gravelly sands to muds. These environments occupy much of the transitional slopes between the margins and the basin floor and reflect a combination of erosion and deposition. The patchy distribution of sedimentary environments within the bay reflects not only regional changes in processes between the margins and the basin but local changes within each part of the bay as well. Small-scale patchiness is caused by local changes in the strengths of wave- and wind-driven currents and (on the margins) by local variations in the supply of fine-grained sediments. This study indicates areas within Cape Cod Bay where fine-grained sediments and associated contaminants are likely to be either moved or deposited. It also provides a guide to the locations and variability of benthic habitats.

Cape Cod Bay↗
USGS1978

Origin of a South Texas roll-type uranium deposit; I, Alteration of iron-titanium oxide minerals

The detrital Fe-Ti oxide minerals and their authigenic alteration products in samples from cores spanning 1.7 km across a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, south Texas, record important information on host-rock preparation and on development of the altered tongue of the deposit. In reduced rock, in front of and enveloping the altered tongue, iron disulfide minerals (pyrite and marcasite) have partially to completely replaced titanomagnetite and, to a lesser extent, titanohematite. Subsequent oxidation of these sulfidized Fe-Ti oxides, by processes that formed the altered tongue and uranium roll, produced ferric oxide and hydroxide phases (limonite) pseudomorphous after the sulfides. Fe-Ti oxides 1.0 km updip from the roll front were never sulfidized; titanomagnetite (partly replaced by hematite) and martite constitute nearly half of the heavy mineral fraction and limonite is absent. Oxidized rocks 210 m and closer to the nose of the roll front, however, are nearly devoid of titanomagnetite and contain abundant limonite. The redox interface that bounds the altered tongue, therefore, moved more than 210 m but less than 1.0 km. Detrital Fe-Ti oxide minerals are increasingly sulfidized in the downdip direction indicating that initial sulfidizaton was more intense in that direction. Organic carbon content is uniformly very low throughout the host sandstone, which implies that heterotrophic sulfate-reducing bacteria were not involved in the generation of sulfide. The H 2 S for the initial sulfidization may have been derived from oil and gas in formations that underlie the Catahoula Tuff. The H 2 S probably invaded the Catahoula along a fault that is 1.5 km downdip from the present roll front.

Texas↗
USGS1993

Stable carbon and oxygen isotope studies of the sediments of Elk Lake, Minnesota

Variations in the ratios of 18 O: 16 O and 13 C: 12 C in calcite throughout the Holocene in Elk Lake, Minnesota, are recorded in three varve-calibrated carbonate cores. Marl in a varved deep-basin (29.6 m) core consists mainly of calcite precipitated from surface waters during the summer and probably provides the least complicated isotope record. Marl in a sublittoral (10 m) core consists of calcite contributed from several inorganic and organic sources and probably is the most complicated of the three isotope records. Calcite from shells of the ostracod Candona ohioensis in the sublittoral core provides a record of shallow-water conditions in Elk Lake for the period between 10,500 and 5500 varve yr. Variations in the 13 C: 12 C ratio of organic carbon deposited in Elk Lake during the Holocene are recorded in organic matter in the deep-basin core. All three oxygen isotope records show that, in general, the 18 O: 16 O ratio in carbonate was enriched in 18 O by several parts per mil during the mid-Holocene relative to the past few thousand years. This pattern of oxygen isotope variation is similar to that observed for carbonate materials from other lakes in the northeastern and north-central United States. Oxygen isotope records from these other lakes also show that the 18 O: 16 O ratio during the early Holocene was lower than during the mid-Holocene, and this pattern has been interpreted as representing a response to a generally warmer and drier climate during the mid-Holocene beginning about 8000 varve yr (the so-called hypsithermal). Ostracod and diatom assemblages from Elk Lake cores show, however, that the lake was colder and more saline than at present until at least 6700 varve yr, with conditions similar to those that exist today in cold prairie lakes of Canada. It may be more appropriate, therefore, to refer to the mid-Holocene in northwestern Minnesota as the “prairie period” rather than the hypsithermal, indicating that the climate was drier, but with no connotation regarding temperature. The oxygen isotope data from the three Elk Lake records for this period are somewhat equivocal. Values of δ 18 O in the marl from the sublittoral core and shells of Candona increase from 10,000 to about 6800 varve yr. However, values of δ 18 O in the marl that accumulated in the deepest part of the lake over the same interval (10,000–6800 varve yr) are more or less constant and enriched in 18 O; this probably reflects the cold, saline prairie-lake conditions predicted from the ostracod and diatom assemblage data. All three oxygen isotope records show decreases in 18 O: 16 O ratios after about 6800 varve yr in response to an increase in temperature and decrease in salinity of the lake. The 13 C: 12 C ratios in carbonates from all three Elk Lake records show a distinct pattern; the ratio increased gradually from 10,000 to 8000 varve yr going into the mid-Holocene prairie period and then decreased gradually coming out of the prairie period between about 5500 and 2500 varve yr. These changes in the 13 C: 12 C ratio could have been related to temperature through its effect on solubility of carbon dioxide; however, this interpretation is not supported by the oxygen isotope data. Another possibility is that changes in the 13 C: 12 C ratio are related to organic productivity that removes 13 C-depleted organic carbon and results in 13 C-enriched surface waters. This interpretation implies that organic productivity was higher in Elk Lake during the mid-Holocene prairie period. Support for the high-productivity, 13 C-enriched surface-water model for the mid-Holocene prairie period in Elk Lake is provided by changes in the 13 C: 12 C ratio of organic carbon in the deep-basin core. These changes parallel almost exactly those in the 13 C: 12 C ratio of carbonate carbon, but are about 2% larger (about 6% as opposed to about 4% for carbonate carbon). The difference of about 2% may represent 13 C depletion due to CO 2 limitation. The percentage of organic carbon in the sediment did not increase during the prairie period because it was diluted by an increased flux of detrital clastic material. The ultimate burial rate of organic carbon increased considerably, however, indicating that organic productivity was higher and/or the degree of preservation increased. Diatom assemblages and plant-pigment concentrations indicate that productivity was higher during the prairie period. Pyrolysis hydrogen and oxygen indices show that the 13 C-enriched organic matter that accumulated during the prairie period was hydrogen rich and oxygen poor relative to organic matter that accumulated before and after. These two indices demonstrate that the organic matter that accumulated during the prairie period was much better preserved.

Minnestoa↗