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USGS2002

Rare earth element variations resulting from inversion of pigeonite and subsolidus reequilibration in lunar ferroan anorthosites

We present results of a secondary ion mass spectrometry study of the rare earth elements (REEs) in the minerals of two samples of lunar ferroan anorthosite, and the results are applicable to studies of REEs in all igneous rocks, no matter what their planet of origin. Our pyroxene analyses are used to determine solid-solid REE distribution coefficients (D = C REE in low-Ca pyroxene/C REE in augite) in orthopyroxene-augite pairs derived by inversion of pigeonite. Our data and predictions from crystal-chemical considerations indicate that as primary pigeonite inverts to orthopyroxene plus augite and subsolidus reequilibration proceeds, the solid-solid Ds for orthopyroxene-augite pairs progressively decrease for all REEs; the decrease is greatest for the LREEs. The REE pattern of solid-solid Ds for inversion-derived pyroxene pairs is close to a straight line for Sm-Lu and turns upward for REEs lighter than Sm; the shape of this pattern is predicted by the shapes of the REE patterns for the individual minerals. Equilibrium liquids calculated for one sample from the compositions of primary phases, using measured or experimentally determined solid-liquid Ds, have chondrite-normalized REE patterns that are very slightly enriched in LREEs. The plagioclase equilibrium liquid is overall less rich in REEs than pyroxene equilibrium liquids, and the discrepancy probably arises because the calculated plagioclase equilibrium liquid represents a liquid earlier in the fractionationsequence than the pyroxene equilibrium liquids. “Equilibrium” liquids calculated from the compositions of inversion-derived pyroxenes or orthopyroxene derived by reaction of olivine are LREE depleted (in some cases substantially) in comparison with equilibrium liquids calculated from the compositions of primary phases. These discrepancies arise because the inversion-derived and reaction-derived pyroxenes did not crystallize directly from liquid, and the use of solid-liquid Ds is inappropriate. The LREE depletion of the calculated liquids is a relic of formation of these phases from primary LREE-depleted minerals. Thus, if one attempts to calculate the compositions of equilibrium liquids from pyroxene compositions, it is important to establish that the pyroxenes are primary. In addition, our data suggest that experimental studies have underestimated solid-liquid Ds for REEs in pigeonite and that REE contents of liquids calculated using these Ds are overestimates. Our results have implications for Sm-Nd age studies. Our work shows that if pigeonite inversion and/or subsolidus reequilibration between augite and orthopyroxene occurred significantly after crystallization, and if pyroxene separates isolated for Sm-Nd studies do not have the bulk composition of the primary pyroxenes, then the Sm-Nd isochron age and ε Nd will be in error.

Geochimica et Cosmochimica Acta↗

USGS2003

Comparison of approaches for simulating reactive solute transport involving organic degradation reactions by multiple terminal electron acceptors

Reactive solute transport models are useful tools for analyzing complex geochemical behavior resulting from biodegradation of organic compounds by multiple terminal electron acceptors (TEAPs). The usual approach of simulating the reactions of multiple TEAPs by an irreversible Monod rate law was compared with simulations that assumed a partial local equilibrium or kinetically controlled reactions subject to the requirement that the Gibbs free energy of reaction (Δ G) was either less than zero or less than a threshold value. Simulations were performed using a single organic substrate and O 2 , FeOOH, SO 4 -2 and CO 2 as the terminal electron acceptors. It was assumed that the organic substrate was slowly and completely fermented to CO 2 and H 2 and the H 2 was oxidized by the TEAPs. Simulations using the Monod approach showed that this irreversible rate law forced the reduction of both FeOOH and CO 2 to proceed even when Δ G was positive. This resulted in an over prediction in amount of FeOOH reduced to Fe(II) in parts of the domain and it resulted in large errors in pH. Simulations using mass action kinetics agreed with equilibrium simulations for the case of large rate constants. The extent of reductive dissolution of FeOOH was strongly dependent on the thermodynamic stability of the FeOOH phase. Transport simulations performed assuming that the reactions of the TEAPs stopped when Δ G exceeded a threshold value showed that only simulated H 2 concentrations were affected if the threshold value was the same for each TEAP. Simulated H2 concentrations were controlled by the fastest reaction of the TEAP, but it was common for reactions to occur concomitantly rather than sequentially.

Computers & Geosciences↗

USGS1997

Channel-fill coal beds along the western margin of the Eastern Kentucky Coal Field

Four channel-filling coal beds from the lower part of the Breathitt Formation (lower Middle Pennsylvanian, late Westphalian A) were examined palynologically, petrographically and geochemically to determine the paleoenvironmental conditions under which these peats accumulated. These results were then compared with detailed sedimentological analyses of the strata overlying the coal in the channels to see if any genetic relationship between coal composition and the origin of the overburden could be drawn. All four of the coal beds used in this study are located in the western-most part of the Eastern Kentucky Coal Field and occur at, or near, the Early Pennsylvanian unconformity (0–30 m). Lycospora and Densosporites (and related crassicingulate taxa, e.g. Cristatisporites , Cingulizonates and Radiizonates ) dominate the studied assemblages, with Granulatisporites (and related trilete, sphaerotriangular genera, e.g. Leiotriletes and Lophotriletes ), Laevigatosporites and Schulzospora being common accessory genera. Petrographically, all four coals contain high percentages of vitrinite macerals (avg. 78.6% mineral matter free), moderate amounts of liptinite (or exinite) macerals (avg. 14.9%, mmf) and low percentages of inertinite macerals (avg. 6.5%, mmf). Strata above the coals consist of dark, carbonaceous shales, and heterolithic strata that exhibit varying degrees of bioturbation. Commonly occurring trace fossils include Arenicolites , Monocraterion , Planolites and Skolithos . Although marine-influenced strata, as determined from detailed sedimentology and ichnology (the study of trace fossils), covers all four coal beds, they are not uniformly high in total total sulfur content as might be expected. Rather they are extremely variable, ranging from 1–9% (dry basis) total sulfur. Ash yields are also variable ranging from 6.2–54.3% (dry basis). It is probable that the origin of the very first sediments covering the peat, as well as the amount of brackish water influence during peat accumulation, were important factors in determining the total sulfur content of the resultant coal. Initial sedimentation of fresh water clays and silts may have acted as a barrier to downward percolation/diffusion of sulfate bearing waters, or may have served as a site for sulfide formation, thereby keeping the total sulfur content of the underlying coal low. If initial sedimentation was of brackish or marine origin, as indicated by bioturbated laminae directly above the coal, or if the peat was subject to frequent brackish or marine water influence during accumulation, then sulfide generation might proceed unchecked, resulting in high sulfur coal.

International Journal of Coal Geology↗

USGS2001

Trends in long-period seismicity related to magmatic fluid compositions

Sound speeds and densities are calculated for three different types of fluids: gas-gas mixture; ash-gas mixture; and bubbly liquid. These fluid properties are used to calculate the impedance contrast (Z) and crack stiffness (C) in the fluid-driven crack model (Chouet: J. Geophys. Res., 91 (1986) 13,967; 101 (1988) 4375; A seismic model for the source of long-period events and harmonic tremor. In: Gasparini, P., Scarpa, R., Aki, K. (Eds.), Volcanic Seismology, IAVCEI Proceedings in Volcanology, Springer, Berlin, 3133). The fluid-driven crack model describes the far-field spectra of long-period (LP) events as modes of resonance of the crack. Results from our calculations demonstrate that ash-laden gas mixtures have fluid to solid density ratios comparable to, and fluid to solid velocity ratios lower than bubbly liquids (gas-volume fractions <10%). This difference results in synthetic far-field spectra with higher impedance contrasts and narrower spectral bandwidths for ash-laden gas mixture than spectra for bubbly liquids. Spectral characteristics are described in terms of the quality factor Q-1. Q-1 is measured by the ratio of the frequency of the dominant spectral peak to the bandwidth of the peak measured at one half of its amplitude. This factor expresses the losses of energy due to elastic radiation Q-1r and other dissipative mechanisms Q-1i at the source, Q-1 = Q-1r + Q-1i. Spectra for LP events recorded at active volcanoes such as Galeras in Colombia and Kilauea in Hawaii, have Q-1 factors in the range of 0.1-0.002. The Q-1r factors due to radiation loss calculated for a sphere filled with a H2O-CO2 or H2O-SO2 gas mixture, vary between 0.0015 and 0.0040 with a change in wt% H2O at 800-1600 K and 10-50 MPa. For gas-rich mixtures, Q-1r has a strong dependence on resonator geometry (spherical versus rectangular). The spectra from a resonating sphere filled with gas-rich mixture yields values of Q-1r an order of magnitude smaller than those from a rectangular crack. For a resonating crack filled with an ash-gas mixture (or pseudogas), Q-1r varies parabolically from ???0.006 for an ash-rich mixture, to 0.0015 or 0.0023 for a H2O-rich or CO2-rich mixture at 800 K and 25 MPa. For low (<20%) gas-volume fraction fluids (foams, bubbly fluids and ash-rich pseudogases), the magnitudes for Q-1r are independent of crack geometry. Spectra associated with a foam (gas-volume fractions 10-90%) or bubbly basalt (gas-volume fractions <10%) may have a dominant spectral peak with values of Q-1r on the order of 0.01 and 0.1, respectively. The spectra from a resonating sphere filled with a foam containing >20% gas-volume fraction yields values of Q-1r similar to those for a rectangular crack. As with gas-gas and ash-gas mixtures, an increase in mass fraction narrows the bandwidth of the dominant mode and shifts the spectra to lower frequencies. Including energy losses due to dissipative processes in a bubbly liquid increases attenuation. Attenuation may also be higher in ash-gas mixtures and foams if the effects of momentum and mass transfer between the phases were considered in the calculations. ?? 2001 Elsevier Science B. V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2012

Monitoring that matters

Monitoring is a critically important activity for assessing the status of a system, such as the health of an individual, the balance in one's checking account, profits and losses of a business, the economic activity of a nation, or the size of an animal population. Monitoring is especially vital for evaluating changes in the system associated with specific known impacts occurring to the system. It is also valuable for detecting unanticipated changes in the system and identifying plausible causes of such changes, all in time to take corrective action. Before proceeding, we should define "monitoring." One definition of "monitor" (Microsoft Corporation 2009) is "to check something at regular intervals in order to find out how it is progressing or developing." The key point here is "at regular intervals," suggesting a continuing process. Some definitions do not indicate the repetitive nature of monitoring and are basically synonymous with "observing." Most monitoring, in the strict sense of the word, is intended to persist for long periods of time, perhaps indefinitely or permanently. Similarly, Thompson et al. (1998: 3) referred to the "repeated assessment of status" of something, but noted that the term "monitor" is sometimes used for analogous activities such as collecting baseline information or evaluating projects for either implementation or effectiveness. For their purposes, they restricted the term to involve repeated measurements collected at a specified frequency of time units. Let us adopt that definition, recognizing that repeated measurements imply collecting comparable information on each occasion.

Book chapter↗

USGS2006

The use of photographic rates to estimate densities of tigers and other cryptic mammals: a comment on misleading conclusions

The search for easy-to-use indices that substitute for direct estimation of animal density is a common theme in wildlife and conservation science, but one fraught with well-known perils (Nichols & Conroy, 1996; Yoccoz, Nichols & Boulinier, 2001; Pollock et al., 2002). To establish the utility of an index as a substitute for an estimate of density, one must: (1) demonstrate a functional relationship between the index and density that is invariant over the desired scope of inference; (2) calibrate the functional relationship by obtaining independent measures of the index and the animal density; (3) evaluate the precision of the calibration (Diefenbach et al., 1994). Carbone et al. (2001) argue that the number of camera-days per photograph is a useful index of density for large, cryptic, forest-dwelling animals, and proceed to calibrate this index for tigers (Panthera tigris). We agree that a properly calibrated index may be useful for rapid assessments in conservation planning. However, Carbone et al. (2001), who desire to use their index as a substitute for density, do not adequately address the three elements noted above. Thus, we are concerned that others may view their methods as justification for not attempting directly to estimate animal densities, without due regard for the shortcomings of their approach.

Animal Conservation↗

USGS2013

Microbiological reduction of Sb(V) in anoxic freshwater sediments

Microbiological reduction of millimolar concentrations of Sb(V) to Sb(III) was observed in anoxic sediments from two freshwater settings: (1) a Sb- and As-contaminated mine site (Stibnite Mine) in central Idaho and 2) an uncontaminated suburban lake (Searsville Lake) in the San Francisco Bay Area. Rates of Sb(V) reduction in anoxic sediment microcosms and enrichment cultures were enhanced by amendment with lactate or acetate as electron donors but not by H2, and no reduction occurred in sterilized controls. Addition of 2- 14 C-acetate to Stibnite Mine microcosms resulted in the production of 14 CO 2 coupled to Sb(V) reduction, suggesting that this process proceeds by a dissimilatory respiratory pathway in those sediments. Antimony(V) reduction in Searsville Lake sediments was not coupled to acetate mineralization and may be associated with Sb-resistance. The microcosms and enrichment cultures also reduced sulfate, and the precipitation of insoluble Sb(III)-sulfide complexes was a major sink for reduced Sb. The reduction of Sb(V) by Stibnite Mine sediments was inhibited by As(V), suggesting that As(V) is a preferred electron acceptor for the indigenous community. These findings indicate a novel pathway for anaerobic microbiological respiration and suggest that communities capable of reducing high concentrations of Sb(V) commonly occur naturally in the environment.

Environmental Science & Technology↗

USGS2004

Relative effect of temperature and pH on diel cycling of dissolved trace elements in Prickly Pear Creek, Montana

Diel (24 hr) cycles in dissolved metal and As concentrations have been documented in many northern Rocky Mountain streams in the U.S.A. The cause(s) of the cycles are unknown, although temperature- and pH-dependent sorption reactions have been cited as likely causes. A light/dark experiment was conducted to isolate temperature and pH as variables affecting diel metal cycles in Prickly Pear Creek, Montana. Light and dark chambers containing sediment and a strand of macrophyte were placed in the stream to simulate instream temperature oscillations. Photosynthesis-induced pH changes were allowed to proceed in the light chambers while photosynthesis was prevented in the dark chambers. Water samples were collected periodically for 22 hr in late July 2001 from all chambers and the stream. In the stream, dissolved Zn concentrations increased by 300% from late afternoon to early morning, while dissolved As concentrations exhibited the opposite pattern, increasing 33% between early morning and late afternoon. Zn and As concentrations in the light chambers showed similar, though less pronounced, diel variations. Conversely, Zn and As concentrations in the dark chambers had no obvious diel variation, indicating that light, or light-induced reactions, caused the variation. Temperature oscillations were nearly identical between light and dark chambers, strongly suggesting that temperature was not controlling the diel variations. As expected, pH was negatively correlated ( P < 0.01) with dissolved Zn concentrations and positively correlated with dissolved As concentrations in both the light and dark chambers. From these experiments, photosynthesis-induced pH changes were determined to be the major cause of the diel dissolved Zn and As cycles in Prickly Pear Creek. Further research is necessary in other streams to verify that this finding is consistent among streams having large differences in trace-element concentrations and mineralogy of channel substrate.

Montana↗

USGS2000

Dating of major normal fault systems using thermochronology: An example from the Raft River detachment, Basin and Range, western United States

Application of thermochronological techniques to major normal fault systems can resolve the timing of initiation and duration of extension, rates of motion on detachment faults, timing of ductile mylonite formation and passage of rocks through the crystal-plastic to brittle transition, and multiple events of extensional unroofing. Here we determine the above for the top-to-the-east Raft River detachment fault and shear zone by study of spatial gradients in 40 Ar/ 39 Ar and fission track cooling ages of footwall rocks and cooling histories and by comparison of cooling histories with deformation temperatures. Mica 40 Ar/ 39 Ar cooling ages indicate that extension-related cooling began at ∼25–20 Ma, and apatite fission track ages show that motion on the Raft River detachment proceeded until ∼7.4 Ma. Collective cooling curves show acceleration of cooling rates during extension, from 5–10°C/m.y. to rates in excess of 70–100°C/m.y. The apparent slip rate along the Raft River detachment, recorded in spatial gradients of apatite fission track ages, is 7 mm/yr between 13.5 and 7.4 Ma and is interpreted to record the rate of migration of a rolling hinge. Microstructural study of footwall mylonite indicates that deformation conditions were no higher than middle greenschist facies and that deformation occurred during cooling to cataclastic conditions. These data show that the shear zone and detachment fault represent a continuum produced by progressive exhumation and shearing during Miocene extension and preclude the possibility of a Mesozoic age for the ductile shear zone. Moderately rapid cooling in middle Eocene time likely records exhumation resulting from an older, oppositely rooted, extensional shear zone along the west side of the Grouse Creek, Raft River, and Albion Mountains.

Idaho, Utah↗

USGS2004

Crustal structure across the San Andreas Fault at the SAFOD site from potential field and geologic studies

We present newly compiled magnetic, gravity, and geologic datasets from the Parkfield region around the San Andreas Fault Observatory at Depth (SAFOD) pilot hole in order to help define the structure and geophysical setting of the San Andreas Fault (SAF). A 2‐D cross section of the SAF zone at SAFOD, based on new, tightly spaced magnetic and gravity observations and surface geology, shows that as drilling proceeds NE toward the SAF, it is likely that at least 2 fault bounded magnetic slivers, possibly consisting of magnetic granitic rock, serpentinite, or unusually magnetic sandstone, will be encountered. The upper 2 km of the model is constrained by an order of magnitude increase in magnetic susceptibility at 1400 m depth observed in pilot hole measurements. NE of the SAF, a flat lying, tabular body of serpentinite at 2 km depth separates two masses of Franciscan rock and truncates against the SAF.

California↗

USGS2011

Water year 2004: Western water managers feel the heat

This spring, a rare combination of exceptionally warm temperatures and near-record lack of precipitation in the western United States caused a rapid change in hydrologic conditions and an unexpectedly early onset of spring conditions. With much of the western U.S. already in its fifth year of drought, an above-average western snowpack on 1 March 2004 provided hope for much-needed abundant runoff. Unfortunately snowmelt began far earlier than anticipated, resulting in dramatic declines in seasonal spring-summer streamflow forecasts as the month proceeded, declines more rapid by some measures than ever before in the past 75 years. With reservoirs near historic lows, many water users have been hard pressed to deal with the continuing drought.

Eos, Earth and Space Science News↗

USGS2005

The calcite → aragonite transformation in low-Mg marble: Equilibrium relations, transformations mechanisms, and rates

Experimental transformation of a rather pure natural calcite marble to aragonite marble did not proceed via the expected straightforward polymorphic replacement. Instead, the small amount of Mg in the starting material (0.36 wt %) was excluded from the growing aragonite and diffused preferentially into the remaining calcite grains, producing Mg-rich calcite rods that persisted as relicts. Nucleation of aragonite occurred exclusively on grain boundaries, with aragonite [001] oriented subparallel to calcite [0001]. The aragonite crystals preferentially consumed the calcite crystal on which they nucleated, and the reaction fronts developed preferentially along the {010} and {110} planes of aragonite. Each aragonite neoblast that grew was nearly free of Mg (typically <0.1 wt %). The excess Mg was taken up by the calcite grains in between, stabilizing them and causing a few volume percent rodlike relicts of Mg-enriched calcite (up to 10 wt % MgO) to be left behind by the advancing reaction front. The aragonite growth rates are approximately linear and range from &sim;3 × 10 −11 m s −1 at 600°C to &sim;9 × 10 −9 m s −1 at 850°C, with an apparent activation enthalpy of 166 ± 91 kJ mol −1 . This reaction mechanism and the resultant texture are akin to cellular precipitation reactions in metals. Similar transformation textures have been reported from high-Mg marbles in Japan and China that disproportionated to low-Mg calcite and dolomite.

Journal of Geophysical Research B: Solid Earth↗

USGS2011

Estimating groundwater recharge

Groundwater recharge is the entry of fresh water into the saturated portion of the subsurface part of the hydrologic cycle, the modifier “saturated” indicating that the pressure of the pore water is greater than atmospheric. Briefly stated, recharge is downward flux across the water table. The term “groundwater recharge” can refer either to the multiple interacting processes generating and controlling the flux or to the flux R itself. When referring to flux, R can represent either (1) a value integrated over large areas and long periods of time or (2) a point value, or instantaneous flux density, that varies erratically as well as continuously in time and space. Knowing how R is distributed through space and time is required for understanding the dynamics of groundwater flow and transport in any watershed, aquifer, or selected domain of interest and for understanding heads, flow paths, and discharges to streams, wetlands, and other surface water bodies. Clearly among the most important of hydrologic fluxes, R is also one of the most difficult to measure. Advancements in hydrologic science have proceeded surprisingly in lockstep with advances in determining R .

Eos, Transactions, American Geophysical Union↗

USGS2019

Streamflow reconstruction in the Upper Missouri River Basin using a novel Bayesian network model

A Bayesian model that uses the spatial dependence induced by the river network topology, and the leading principal components of regional tree-ring chronologies for paleo-streamflow reconstruction is presented. In any river basin, a convergent, dendritic network of tributaries comes together to form the main stem of a river. Consequently, it is natural to think of a spatial Markov process that recognizes this topological structure to develop a spatially consistent basin-scale streamflow reconstruction model that uses the information in streamflow and tree-ring chronology data to inform the reconstructed flows, while maintaining the space-time correlation structure of flows that is critical for water resource assessments and management. Given historical data from multiple streamflow gauges along a river, their tributaries in a watershed, and regional tree-ring chronologies, the model is fit and used to simultaneously reconstruct the full network of paleo-streamflow at all gauges in the basin progressing upstream to downstream along the river. The spatial network structure allows a substantial reduction in the uncertainty associated with paleo-streamflow as one proceeds downstream in the network and the spatial dependence structure increases the information content. Our application to eighteen streamflow gauges in the Upper Missouri River Basin shows that the mean adjusted-R2 for the basin is approximately 0.5 with good overall cross-validated skill as measured by five different skill metrics. A comparison with the traditional principal components regression shows that the spatial Bayesian model offers improvements, as downstream gauges are informed by the reconstruction of the upstream gauges, as well as the tree-ring chronologies.

Idaho, Montana, Wyoming↗

USGS2025

Rupture process of the Mw7.0 December 5, 2024 Offshore Cape Mendocino earthquake

The Mw7.0 December 5, 2024 Offshore Cape Mendocino earthquake ruptured a km long portion of the east-west trending Mendocino fault zone (MFZ). In order to clarify the rupture process, we assemble three-component seismograms from regional seismic stations, horizontal coseismic displacement vectors derived from Global Navigation Satellite System (GNSS) time series, and a Sentinel-1 ascending interferogram. These data are interpreted with a model of slip distributed on two vertical fault planes representative of the eastern MFZ and spanning the ~70 km length of the aftershock zone. Assuming right-lateral strike slip, we find that the rupture initiates in the oceanic mantle at 20-30 km depth and proceeds unilaterally updip and toward the east. Early aftershocks locate adjacent to the peak slip areas, tracking the coseismic rupture propagation from oceanic mantle to shallower depth and implying a significant role of static stress transfer in driving aftershocks in an ocean plate environment.

California↗

USGS2010

Geophysical studies of the West Antarctic rift system

The West Antarctic rift system extends over a 3000 × 750 km, largely ice covered area from the Ross Sea to the base of the Antarctic Peninsula, comparable in area to the Basin and Range and the East African rift system. A spectacular rift shoulder scarp along which peaks reach 4–5 km maximum elevation marks one flank and extends from northern Victoria Land-Queen Maud Mountains to the Ellsworth-Whitmore-Horlick Mountains. The rift shoulder has maximum present physiographic relief of 5 km in the Ross Embayment and 7 km in the Ellsworth Mountains-Byrd Subglacial Basin area. The Transantarctic Mountains part of the rift shoulder (and probably the entire shoulder) has been interpreted as rising since about 60 Ma, at episodic rates of ∼1 km/m.y., most recently since mid-Pliocene time, rather than continuously at the mean rate of 100 m/m.y. The rift system is characterized by bimodal alkaline volcanic rocks ranging from at least Oligocene to the present. These are exposed asymmetrically along the rift flanks and at the south end of the Antarctic Peninsula. The trend of the Jurassic tholeiites (Ferrar dolerites, Kirkpatric basalts) marking the Jurassic Transantarctic rift is coincident with exposures of the late Cenozoic volcanic rocks along the section of the Transantarctic Mountains from northern Victoria Land to the Horlick Mountains. The Cenozoic rift shoulder diverges here from the Jurassic tholeiite trend, and the tholeiites are exposed continuously (including the Dufek intrusion) along the lower- elevation (1–2 km) section of Transantarctic Mountains to the Weddell Sea. Widely spaced aeromagnetic profiles in West Antarctica indicate the absence of Cenozoic volcanic rocks in the ice covered part of the Whitmore-Ellsworth-Mountain block and suggest their widespread occurrence beneath the western part of the ice sheet overlying the Byrd Subglacial Basin. A German Federal Institute for Geosciences and Natural Resources (BGR)-U.S. Geological Survey (USGS) aeromagnetic survey over the Ross Sea continental shelf indicates rift fabric and suggests numerous submarine volcanoes along discrete NNW trending zones. A Bouguer anomaly range of approximately 200 (+50 to −150) mGal having 4–7 mGal/km gradients where measured in places marks the rift shoulder from northern Victoria Land possibly to the Ellsworth Mountains (where data are too sparse to determine maximum amplitude and gradient). The steepest gravity gradients across the rift shoulder require high density (mafic or ultramafic?) rock within the crust as well as at least 12 km of thinner crust beneath the West Antarctic rift system in contrast to East Antarctica. Sparse land seismic data reported along the rift shoulder, where velocities are greater than 7 km/s, and marine data indicating velocities above 7 km/s beneath the Ross Sea continental shelf support this interpretation. The maximum Bouguer gravity range in the Pensacola Mountains area of the Transantarctic Mountains is only about 130 mGal with a maximum 2 mGal/km gradient, which can be explained solely by 8 km of crustal thickening. Large offset seismic profiles over the Ross Sea shelf collected by the German Antarctic North Victoria Land Expedition V (GANOVEX V) combined with earlier USGS and other results indicate 17–21 km thickness for the crust beneath the Ross Sea shelf which we interpret as evidence of extended rifted continental crust. A regional positive Bouguer anomaly (0 to +50 mGal), the width of the rift, extends from the Ross Sea continental shelf throughout the Ross Embayment and Byrd Subglacial Basin area of the West Antarctic rift system and indicates that the Moho is approximately 20 km deep tied to the seismic results (probably coincident with the top of the asthenosphere) rather than the 30 km reported in earlier interpretations. The interpretation of horst and graben structures in the Ross Sea, made from marine seismic reflection data, probably can be extended throughout the rift (i.e., the Ross Ice shelf and the Byrd Subglacial Basin areas). The near absence of earthquakes in the West Antarctic rift system probably results from a combination of primarily sparse seismograph coverage and, secondarily, suppression of earthquakes by the ice sheet (e.g., Johnston, 1987) and very high seismicity shortly after deglaciation in the Ross Embayment followed by abnormally low seismicity at present (e.g., Muir Wood, 1989). The evidence of high temperatures at shallow depth beneath the Ross Sea continental shelf and adjacent Transantarctic Mountains is supportive of thermal uplift of the mountains associated with lateral heat conduction from the rift and can possibly also explain the volcanism, rifting, and high elevation of the entire rift shoulder to the Ellsworth-Horlick-Whitmore Mountains. We infer that the Gondwana breakup and the West Antarctic rift are part of a continuously propagating rift that started in the Jurassic when Africa separated from East Antarctica (including the failed Jurassic Transantarctic rift). Rifting proceeded clockwise around East Antarctica to the separation of New Zealand and the Campbell Plateau about 85–95 Ma and has continued (with a spreading center jump) to its present location in the Ross Embayment and West Antarctica. The Cenozoic activity of the West Antarctic rift system appears to be continuous in time with rifting in the same area that began only in the late Mesozoic. Although the mechanism for rifting is not completely explained, we suggest a combination of the flexural rigidity model (Stem and ten Brink, 1989) proposed for the Ross Embayment and the thermal plume or hot spot concepts. The propagating rift may have been “captured” by the thermal plume.

Tectonics↗

USGS2012

Geochemistry of water

The quadrennium 1967–1970 has been a productive period in the field of water geochemistry. Field studies, laboratory investigations, and theoretical considerations have led to significant advances in our knowledge of the chemical behavior of natural waters and of the solid earth materials that contain them. A symposium on trace inorganics in water, sponsored by the American Chemical Society, was held in Miami, Florida, in 1967. The proceedings of this conference were published in 1968 in the Advances in Chemistry Series 73. This volume deals with the occurrence, behavior, and analysis of inorganic constituents in natural waters.

Eos, Transactions, American Geophysical Union↗

USGS2012

Modification of wave-cut and faulting-controlled landforms

From a casual observation that the form of degraded fault scarps resembles the error function, this investigation proceeds through an elementary diffusion equation representation of landform evolution to the application of the resulting equations to the modern topography of scarplike landforms. The morphologic observations can be analyzed either in the form of one or more cross-strike elevation profiles or in the form of the slope-offset plot, a point plot of maximum scarp slope versus scarp offset. Working with either or both of these data representations for nine geologic structures, which range in age from 3 to 400 ka B.P. and in offset from 1 to 50 m, we apply analytical solutions for the vertical initial value scarp, the vertical continuous offset scarp, and the finite slope, initial value scarp. The model calculations are intrinsically ambiguous, yielding as the final answer only the product κ t (in the case of the initial value problem) or the product κ A −1 (in the case of the repeated faulting problem); here t is the age of a single scarp-forming event, 2 A is the vertical slip rate, and κ is the “mass diffusivity.” A single profile across three sea cliffs along the Santa Cruz, California, coast is analyzed as three separate initial value problems. A reasonably constrained age for the sea cliff standing above the Highway 1 platform returns κ = 11 GKG (1 GKG = 1 m 2 /ka). With this κ, we can date the two older sea cliffs. In fact, we do the converse: age estimates for these two older sea cliffs based on a uniform rate of uplift both yield the same κ as for the lower sea cliff. We treat a single profile of the Raymond fault in Pasadena/San Marino in terms of the repeated faulting problem; for it the uplift rate of R. Crook and others yields κ = 16 GKG. The very substantial preexisting offset across the Raymond fault must have been buried/leveled some 230 ka B.P., when the modern topography began to form. Our analysis of the Lake Bonneville shoreline scarps reveals a dependence of κ t on 2a, suggestive of nonlinear modification processes. This appearance is treated with the finite slope initial value scarp model to determine κ=1.1 GKG for the Lake Bonneville shoreline scarps. The suggestion of M. N. Machette that approximately 100,000-year-old, meter-high scarps are “unobservable” in weakly consolidated alluvial terranes of the Basin and Range and Rio Grande Rift Valley provinces can be formulated as κ ≳ 1 GKG. The coincidence between this inequality and the Lake Bonneville shoreline κ is striking, and it suggests that the value of κ = 1 GKG may be generally applicable, as a good first approximation, to the modification of alluvial terranes within the semiarid regions of the western United States. The Lake Bonneville shoreline κ is the basis for dating four sets of fault scarps in west-central Utah. The Drum Mountains fault scarps can be modeled in several different circumstances, but the most likely interpretation is that these fault scarps formed as the result of a single episode of normal faulting 3.6 to 5.7 ka B.P. The younger age is associated with quite low initial slope angles (25°). The other three sets of fault scarps show no evidence for finite initial value slopes. Fault scarps along the eastern base of the Fish Springs Range are very young, 3 ka B.P. We estimate the age of fault scarps along the western flank of the Oquirrh Mountains to be 32 ka B.P., which meets the weak geologic constraint that they be older than the Lake Bonneville shoreline. Fault scarps along the northeastern margin of the Sheeprock Mountains are even older, 53 ka B.P. An intriguing consequence of our single-event analysis of these scarps is that an 11.5-m offset occurred in a single earthquake.

Journal of Geophysical Research Solid Earth↗