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At least 397 records · Page 22Linked to original sources

USGS1999

Uranium biogeochemistry across the redox transition zone of a permanently stratified fjord: Framvaren, Norway

During August 1995, the vertical concentration profile of dissolved and particulate uranium exhibited strong non-conservative characteristics in the upper 30 m of Framvaren Fjord. There was a pronounced peak in both particulate (> 0.2 ??m; 1.09 nM) and dissolved (< 0.2 ??m; 17.06 nM) uranium in the finely stratified waters at the O2/H2S interface which is positioned well within the euphotic zone at about 20-21 m. Such concentration maxima at the redox boundary are also observed for dissolved organic carbon (DEC), Sr and Ba. Dissolved U levels seen in the water column from 18 m down to 30 m exceeded the high salinity (salinity = 35) U concentrations (13.63 ?? 0.84 nM; Chen, J.H., Edwards, R.L., Wasserburg, G.L., 1986. 238U, 234U and 232Th in seawater. Earth Planet Sci. Lett. 80, 241-251.) observed uniformly in the open ocean. A prolific population of S microbes (e.g., Chromatium, Chlorobium sp.) flourishes at the O2/H2S interface. The source of elevated U at the redox boundary must be due to microbial uptake and subsequent release processes rather than dilution from oceanic uranium. Uranium oxidation state determinations in waters from 1, 22 and 30 m depth reveal that reduced U(IV) is not present in significant abundance, and that the chemical and/or biological reduction of hexavalent uranium is largely inhibited. Our results suggest that U and other trace constituents such as DOC, Sr, Ba, Fe(II), Mn(II) are greatly modified by direct and indirect microbial transformation reactions which are most concentrated across the redox transition zone in Framvaren Fjord.

Marine Chemistry↗

USGS2015

Predicting redox conditions in groundwater at a regional scale

Defining the oxic-suboxic interface is often critical for determining pathways for nitrate transport in groundwater and to streams at the local scale. Defining this interface on a regional scale is complicated by the spatial variability of reaction rates. The probability of oxic groundwater in the Chesapeake Bay watershed was predicted by relating dissolved O 2 concentrations in groundwater samples to indicators of residence time and/or electron donor availability using logistic regression. Variables that describe surficial geology, position in the flow system, and soil drainage were important predictors of oxic water. The probability of encountering oxic groundwater at a 30 m depth and the depth to the bottom of the oxic layer were predicted for the Chesapeake Bay watershed. The influence of depth to the bottom of the oxic layer on stream nitrate concentrations and time lags (i.e., time period between land application of nitrogen and its effect on streams) are illustrated using model simulations for hypothetical basins. Regional maps of the probability of oxic groundwater should prove useful as indicators of groundwater susceptibility and stream susceptibility to contaminant sources derived from groundwater.

Maryland, New York, Pennsylvania, Virginia↗

USGS1999

The carbon cycle and biogeochemical dynamics in lake sediments

The concentrations of organic carbon (OC) and CaCO3 in lake sediments are often inversely related. This relation occurs in surface sediments from different locations in the same lake, surface sediments from different lakes, and with depth in Holocene sediments. Where data on accumulation rates are available, the relation holds for organic carbon and CaCO3 accumulation rates as well. An increase of several percent OC is accompanied by a decrease of several tens of percent CaCO3 indicating that the inverse relation is not due to simple dilution of one component by another. It appears from core data that once the OC concentration in the sediments becomes greater than about 12%, the CO2 produced by decomposition of that OC and production of organic acids lowers the pH of anoxic pore waters enough to dissolve any CaCO3 that reaches the sediment-water interface. In a lake with a seasonally anoxic hypolimnion, processes in the water column also can produce an inverse relation between OC and CaCO3 over time. If productivity of the lake increases, the rain rate of OC from the epilimnion increases. Biogenic removal of CO2 and accompanying increase in pH also may increase the production of CaCO3. However, the decomposition of organic matter in the hypolimnion will decrease the pH of the hypolimnion causing greater dissolution of CaCO3 and therefore a decrease in the rain rate of CaCO3 to the sediment-water interface.

Journal of Paleolimnology↗

USGS2001

Seismic mapping of shallow fault zones in the San Gabriel Mountains from the Los Angeles Region Seismic Experiment, southern California

During the Los Angeles Region Seismic Experiment (LARSE), a reflection/refraction survey was conducted along a profile (line 1) extending from Seal Beach, California, northeastward to the Mojave Desert and crossing the Los Angeles and San Gabriel Valley basins and San Gabriel Mountains. In most shot gathers from the southern and central San Gabriel Mountains, clear secondary arrivals are seen that merge, or appear to merge, with first arrivals at three locations, including the location of the Vincent thrust fault, an exposed late Mesozoic/early Cenozoic megathrust. These secondary arrivals are interpretable as reflections in the shallow crust (<5 km depth) from a concave-upward interface that projects to the surface in the north near the Vincent thrust fault, is offset in its central part at the San Gabriel fault (an old branch of the San Andreas fault), and terminates in the south at 1 to 2 km depth at the southern mountain front. The velocity structure above and below this interface strongly suggests it is the Vincent thrust fault: intermediate velocities (6.2 km/s), consistent with mylonites overlying the Vincent thrust fault, are observed above it; lower velocities (5.8 km/s), consistent with the Pelona Schist underlying the Vincent thrust fault, are observed below it. Problems arise, however, in attempting to match this reflector to the exposed Vincent thrust fault, which is seen in outcrops east of line 1. The Vincent thrust fault is shallower than the reflector in most places. An unmapped structure (steep fault, monocline, or thrust fault) is required between line 1 and the outcrops that either drops the Vincent thrust fault down to the depths of the reflector or repeats the Vincent thrust fault beneath line 1 in the footwall of another thrust fault. An alternative interpretation of the reflector is a deep greenstone horizon within the Pelona Schist, although this alternative is not favored by the velocity structure. Copyright 2001 by the American Geophysical Union.

California↗

USGS2002

Strong interseismic coupling, fault afterslip, and viscoelastic flow before and after the Oct. 9, 1995 Colima-Jalisco earthquake: continuous GPS measurements from Colima, Mexico

Continuous GPS measurements from Colima, Mexico during 4/93-6/01, bracketing the Oct. 9, 1995 M = 8.0 Colima-Jalisco earthquake, provide new constraints on Rivera plate subduction mechanics. Modeling of margin-normal strain accumulation before the earthquake suggests the Rivera-North America subduction interface was fully locked. Transient postseismic motion from 10/ 95-6/97 is well fit by a model that includes logarithmically-decaying fault afterslip, elastic strain from shallow fault relocking, and possibly a minor viscoelastic response, but is fit poorly by models that assume a dominant Maxwell viscoelastic response of the lower crust and upper mantle, independent of the assumed viscosities. Landward, margin-normal motion since mid-1997 is parallel to but ??? 75% slower than the pre-seismic velocity. Afterslip alone fails to account for this slowdown. The viscoelastic response predicted by a FEM correctly resolves the remaining velocity difference within the uncertainties. Both processes thus offset elastic strain accumulating from the relocked subduction interface.

Colima↗

USGS2005

Magnitude and location of historical earthquakes in Japan and implications for the 1855 Ansei Edo earthquake

Japan Meteorological Agency (JMA) intensity assignments IJMA are used to derive intensity attenuation models suitable for estimating the location and an intensity magnitude Mjma for historical earthquakes in Japan. The intensity for shallow crustal earthquakes on Honshu is equal to -1.89 + 1.42MJMA - 0.00887?? h - 1.66log??h, where MJMA is the JMA magnitude, ??h = (??2 + h2)1/2, and ?? and h are epicentral distance and focal depth (km), respectively. Four earthquakes located near the Japan Trench were used to develop a subducting plate intensity attenuation model where intensity is equal to -8.33 + 2.19MJMA -0.00550??h - 1.14 log ?? h. The IJMA assignments for the MJMA7.9 great 1923 Kanto earthquake on the Philippine Sea-Eurasian plate interface are consistent with the subducting plate model; Using the subducting plate model and 226 IJMA IV-VI assignments, the location of the intensity center is 25 km north of the epicenter, Mjma is 7.7, and MJMA is 7.3-8.0 at the 1?? confidence level. Intensity assignments and reported aftershock activity for the enigmatic 11 November 1855 Ansei Edo earthquake are consistent with an MJMA 7.2 Philippine Sea-Eurasian interplate source or Philippine Sea intraslab source at about 30 km depth. If the 1855 earthquake was a Philippine Sea-Eurasian interplate event, the intensity center was adjacent to and downdip of the rupture area of the great 1923 Kanto earthquake, suggesting that the 1855 and 1923 events ruptured adjoining sections of the Philippine Sea-Eurasian plate interface.

Journal of Geophysical Research B: Solid Earth↗

USGS2018

Direct observations of hydrologic exchange occurring with less‐mobile porosity and the development of anoxic microzones in sandy lakebed sediments

Quantifying coupled mobile/less‐mobile porosity dynamics is critical to the prediction of biogeochemical storage, release, and transformation processes in the zone where groundwater and surface water exchange. The recent development of fine‐scale geoelectrical monitoring paired with pore‐water sampling in groundwater systems enables direct characterization of hydrologic exchange between more‐ and less‐mobile porosity during tracer tests. We adapt this technique to sandy interface sediments at a groundwater flow‐through kettle lake. Tracer experiments were conducted within controlled‐head permeameters over a range of specified downward flow conditions over several days. Although the bed was predominantly composed of highly permeable sands and gravels, cobble inclusions created less‐mobile flow zones at the centimeter scale. Less‐mobile porosity fractions, residence times, and rates of exchange were inferred from paired bulk and fluid electrical conductivity data, without the need for inverse model calibration. The conservative solute experiments were paired with 15 NO 3 − and other reactive amendments, revealing anaerobic processes occurring at shallow sediment depths where pore‐water sampling indicated bulk‐oxic conditions. The average less‐mobile porosity residence times as evaluated with the geoelectrical method were on 1‐hr timescales, which appear to be biogeochemically important in the context of creating anoxic microzones within less‐mobile porosity of sandy interface sediments.

Water Resources Research↗

USGS2021

Constraints on the geometry of the subducted Gorda Plate with converted phases generated by local earthquakes

The largest slip in great megathrust earthquakes often occurs in the 10–30 km depth range, yet seismic imaging of the material properties in this region has proven difficult. We utilize a dense onshore-offshore passive seismic dataset from the southernmost Cascadia subduction zone where seismicity in the mantle of the subducted Gorda Plate produces S -to- P and P -to- S conversions generated within a few km of the plate interface. These conversions typically occur in the 10–20 km depth range at either the top or bottom of a ∼5 km thick layer with a high Vp/Vs that we infer to be primarily the subducted crust. We use their arrival times and amplitudes to infer the location of the top and bottom of the subducted crust as well as the velocity contrasts across these discontinuities. Comparing with both the Slab1.0 and the updated Slab2 interface models, the Slab2 model is generally consistent with the converted phases, while the Slab1.0 model is 1–2 km deeper in the 2–20 km depth range and ∼6–8 km too deep in the 10–20 km depth range between 40.25°N and 40.4°N. Comparing the amplitudes of the converted phases to synthetics for simplified velocity structures, the amplitude of the converted phases requires models containing a ∼5 km thick zone with at least a ∼10%–20% reduction in S wave velocity. Thus, the plate boundary is likely contained within or at the top of this low velocity zone, which potentially indicates a significant porosity and fluid content within the seismogenic zone.

California↗

USGS2012

Strain accumulation in western Washington

The Juan de Fuca plate is subducted beneath the North American plate off the coast of Washington at a rate of about 40 mm/yr N68°E. The average principal strain rates (extension reckoned positive) measured in northwestern Washington are as follows: Olympic peninsula 25 km south of Port Angeles from 1982 through 1990, and and near Seattle from 1972 through 1985, and . Both strain measurements are consistent with uniaxial contraction in the direction of plate convergence. Uplift rates inferred from tide gage recordings are about 4 mm/yr on the Pacific coast and near 0 mm/yr farther inland near Seattle. These deformation rates are consistent with a model of the Cascadia subduction zone in which the plate interface beneath the continental slope and outer continental shelf is locked but free to slip farther landward. The limited downdip extent of the locked segment of the plate interface is consistent with a shallow depth (∼20 km) of the isotherm (∼450°C) that defines the brittle‐ductile transition. Small thrust events diagnostic of seismic subduction should then occur only offshore and at shallow depths. The principal strain rates measured from 1972 through 1983 in the back arc region near Richland, Washington, are and .

Washington↗

USGS2010

The role of groundwater transport in aquatic mercury cycling

Mercury, which is transported globally by atmospheric pathways to remote aquatic environments, is a ubiquitous contaminant at very low (nanograms Hg per liter) aqueous concentrations. Until recently, however, analytical and sampling techniques were not available for freshwater systems to quantify the actual levels of mercury concentrations without introducing significant contamination artifacts. Four different sampling strategies were used to evaluate ground water flow as a mercury source and transport mechanism within aquatic systems. The sampling strategies employ ultraclean techniques to determine mercury concentrations in groundwater and pore water near Pallette Lake, Wisconsin. Ambient groundwater concentrations are about 2–4 ng Hg L −1 , whereas pore waters near the sediment/water interface average about 12 ng Hg L −1 , emphasizing the importance of biogeochemical processes near the interface. Overall, the groundwater system removes about twice as much mercury (1.5 g yr −1 ) as it contributes (0.7 g yr −1 ) to Pallette Lake. About three fourths of the groundwater mercury load is recycled, thought to be derived from the water column.

Wisconsin↗

USGS2012

The seismic velocity structure of the Newfoundland Appalachian orogen

The deep structure of the Newfoundland Appalachian orogen is investigated by analyses of three intersecting seismic refraction/wide-angle reflection profiles which traverse the Gander and Dunnage zones or central mobile belt of Newfoundland. A simultaneous travel time inversion for velocity and interface was applied to the in-line seismic refraction/wide-angle reflection data and constrained by synthetic amplitude models. The results of the modeling procedure show a subhorizontally layered crust with upper crustal velocities ranging from 5.4 to 6.2 km/s, a midcrustal velocity of 6.25–6.35 km/s, and a lower crustal velocity of 6.7±0.2 km/s. The top of the lower crust is marked by a series of prominent reflections between 18 and 23 km depth which suggest a complex layered velocity interface. Strong laterally coherent Moho reflections indicate a sharp crust-mantle transition at 35 ± 3 km. The uppermost mantle has a velocity of 8.0±0.2 km/s, and a reflecting horizon at 55 km depth suggests an increase to velocities approaching 8.5 km/s. Normal moveout corrections applied to fan profiles provide constraining evidence for the reflecting horizon at the top of the lower crust and laterally continuous Moho reflections at 11–12 s two-way travel time. Comparisons with a coincident deep seismic reflection profile show that the refraction and reflection Mohos match to better than 2–3 km. Bulk Poisson's ratios of 0.23–0.24 for the whole crust calculated from P m P / S m S travel times suggest a crust dominated by quartzofeldspathic lithologies and a notable absence of voluminous mafic additions to the lower crust. The absence of a deep crustal root, coupled with the bulk intermediate composition inferred for the lower crust from the seismic refraction/wide-angle data, implies that the crust beneath central Newfoundland has undergone multiple periods of reactivation and equilibration following successive orogenic episodes.

Newfoundland and Labrador↗

USGS2012

Applications of mineral surface chemistry to environmental problems

Environmental surface chemistry involves processes that occur at the interface between the regolith, hydrosphere and atmosphere. The more limited scope of the present review addresses natural and anthropogenically-induced inorganic geochemical reactions between solutes in surface and ground waters and soil and aquifer substrates. Important surficial reactions include sorption, ion exchange, dissolution, precipitation and heterogeneous oxidation/reduction processes occurring at the solid/aqueous interface. Recent research advances in this field have addressed, both directly and indirectly, societal issues related to water quality, pollution, biogeochemical cycling, nutrient budgets and chemical weathering related to long term global climate change. This review will include recent advances in the fundamental and theoretical understanding of these surficial processes, breakthroughs in experimental and instrumental surface characterization, and development of methodologies for field applications.

Reviews of Geophysics↗

USGS1998

Displacement field for an edge dislocation in a layered half-space

The displacement field for an edge dislocation in an Earth model consisting of a layer welded to a half-space of different material is found in the form of a Fourier integral following the method given by Weeks et al. [1968]. There are four elementary solutions to be considered: the dislocation is either in the half-space or the layer and the Burgers vector is either parallel or perpendicular to the layer. A general two-dimensional solution for a dip-slip faulting or dike injection (arbitrary dip) can be constructed from a superposition of these elementary solutions. Surface deformations have been calculated for an edge dislocation located at the interface with Burgers vector inclined 0°, 30°, 60°, and 90° to the interface for the case where the rigidity of the layer is half of that of the half-space and the Poisson ratios are the same. Those displacement fields have been compared to the displacement fields generated by similarly situated edge dislocations in a uniform half-space. The surface displacement field produced by the edge dislocation in the layered half-space is very similar to that produced by an edge dislocation at a different depth in a uniform half-space. In general, a low-modulus (high-modulus) layer causes the half-space equivalent dislocation to appear shallower (deeper) than the actual dislocation in the layered half-space.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

A dislocation model of strain accumulation and release at a subduction zone

Strain accumulation and release at a subduction zone are attributed to stick slip on the main thrust zone and steady aseismic slip on the remainder of the plate interface. This process can be described as a superposition of steady state subduction and a repetitive cycle of slip on the main thrust zone, consisting of steady normal slip at the plate convergence rate plus occasional thrust events that recover the accumulated normal slip. Because steady state subduction does not contribute to the deformation at the free surface, deformation observed there is completely equivalent to that produced by the slip cycle alone. The response to that slip is simply the response of a particular earth model to embedded dislocations. For a purely elastic earth model, the deformation cycle consists of a coseismic offset followed by a linear‐in‐time recovery to the initial value during the interval between earthquakes. For an elastic‐viscoelastic earth model (elastic lithosphere over a viscoelastic asthenosphere), the postearthquake recovery is not linear in time. Records of local uplift as a function of time indicate that the long‐term postseismic recovery is approximately linear, suggesting that elastic earth models are adequate to describe the deformation cycle. However, the deformation predicted for a simple elastic half‐space earth model does not reproduce the deformation observed along the subduction zones in Japan at all well if stick slip is restricted to the main thrust zone. As recognized earlier by Shimazaki, Seno, and Kato, the uplift profiles could be explained if stick slip were postulated to extend along the plate interface beyond the main thrust zone to a depth of perhaps 100 km, but independent evidence suggests that stick slip at such depths is unlikely.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

Petrology and comparative thermal and mechanical histories of clasts in breccia 62236

Lunar breccia 62236 contains large lithic fragments of troctolite, norite, and anorthosite. The mafic phases, olivine, inverted pigeonite, and augite, fill interstitial areas between larger plagioclases and appear to be cumulate phases with extensive adcumulus growth. Pyroxene compositional homogeneity indicates that cation exchange during cooling was limited to an area of about 1 mm. Primary augite and pigeonite both contain 30 μm-wide lamellae of the other along ‘001’. Pigeonite inverted to orthopyroxene without retaining any crystallographic orientation and subsequently exsolved fine lamellae of augite on (100). Profiles across orthopyroxene-augite interfaces obtained in the analytical transmission electron microscope show an increase of ∼5% wollastonite in augite within 0.5 μm of the interface, suggesting that short-range cation exchange continued to temperatures below 500°C. The entire sample has undergone heterogeneous shock deformation. Shock melting of the troctolitic clast suggests pressures of 200–300 kb and well-developed basal twinning in augite from the norite clasts suggests pressures of 50–300 kbars. The present evidence indicates that 62236 contains parts of a slowly cooled microlayered adcumulate that has been heterogeneously shocked several times and combined into the present breccia.

Journal of Geophysical Research Solid Earth↗

USGS2020

Subduction megathrust heterogeneity characterized from 3D seismic data

Megathrust roughness and structural complexity are thought to be controls on earthquake slip at subduction zones because they result in heterogeneity in shear strength and resolved stress. However, because active megathrust faults are difficult to observe, the causes and scales of complexity are largely unknown. Here we measured the in situ properties of the megathrust of the Middle America subduction zone in a three-dimensional seismic reflection volume to determine how fault properties vary. We quantify spatial variability in the megathrust roughness, overburden and rock physical properties. Heterogeneity in the megathrust roughness exists at length scales of a few kilometres because the megathrust is dissected by active lower-plate normal faults, which offset the megathrust and renewed fault roughness. Spatial variations in the rock physical properties at the plate interface are characterized by correlation length scales of hundreds of metres. Frontal prism taper, historical seismicity and the variation in earthquake stress drop values local to the megathrust are all affected by the heterogeneity at these length scales. Both geometric and rheological complexities may therefore control the mechanical behaviour of the subduction plate interface, which includes earthquake rupture characteristics.

Central America megathrust, Pacific Ocean↗

USGS2021

Correlation of porosity variations and rheological transitions on the southern Cascadia megathrust

The unknown onshore extent of megathrust earthquake rupture in the Cascadia subduction zone represents a key uncertainty in earthquake hazard for the Pacific Northwest that is governed by the physical state and mechanical properties of the plate interface. The Cascadia plate interface is segmented into an interseismically locked zone located primarily offshore that is expected to rupture in large earthquakes, a region of aseismic slow slip at greater depth, and an intervening transition zone of uncertain rupture potential. Here we image the evolution of the ratio of seismic compressional to shear wave velocities from the locked zone to the transition zone, which is related to changes in fluid content of the plate boundary zone, using a dense onshore–offshore seismic dataset from southernmost Cascadia. The locked zone shows evidence of high fluid content implying a high porosity, yet the downdip transition zone shows an order of magnitude lower porosity. This strong variation is consistent with models that contain a ductile region between the earthquake rupture and slow slip zones that would inhibit onshore propagation of future large earthquake ruptures and hence reduce seismic hazard.

California↗

USGS2023

Georectified polygon database of ground-mounted large-scale solar photovoltaic sites in the United States

Over 4,400 large-scale solar photovoltaic (LSPV) facilities operate in the United States as of December 2021, representing more than 60 gigawatts of electric energy capacity. Of these, over 3,900 are ground-mounted LSPV facilities with capacities of 1 MWdc or more. Ground mounted LSPV installations continue increasing, with more than 400 projects appearing online in 2021 alone; however, a comprehensive, publicly available georectified dataset including spatial footprints of these facilities is lacking. Analysts from U.S. Over 4,400 large-scale solar photovoltaic (LSPV) facilities operate in the United States as of December 2021, representing more than 60 gigawatts of electric energy capacity. Of these, over 3,900 are ground-mounted LSPV facilities with capacities of 1 megawatt direct current (MW dc ) or more. Ground-mounted LSPV installations continue increasing, with more than 400 projects appearing online in 2021 alone; however, a comprehensive, publicly available georectified dataset including spatial footprints of these facilities is lacking. The United States Large-Scale Solar Photovoltaic Database (USPVDB) was developed to fill this gap. Using US Energy Information Administration (EIA) data, locations of 3,699 LSPV facilities were verified using high-resolution aerial imagery, polygons were digitized around panel arrays, and attributes were appended. Quality assurance and control were achieved via team peer review and comparison to other US PV datasets. Data are publicly available via an interactive web application and multiple downloadable formats, including: comma-separated value (CSV), application programming interface (API), and GIS shapefile and GeoJSON. Survey and Lawrence Berkeley National Laboratory collaborated to develop the United States Large-Scale Solar Photovoltaic Database (USPVDB). Using Energy Information Administration (EIA) data, locations of LSPV facilities were verified using high-resolution aerial imagery, polygons were digitized around panel arrays, and attributes were appended. Quality assurance and control were achieved via team peer review and comparison to other US PV datasets. Data are publicly available in an interactive web application, and a number of downloadable formats, including: comma-separated value spreadsheet (CSV), application programming interface (API), and GIS shapefile.

Scientific Data↗