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At least 397 records · Page 22Linked to original sources

USGS2014

Earth is (mostly) flat: Apportionment of the flux of continental sediment over millennial time scales: COMMENT

Recent synthesis of 10 Be-derived denudation rates by Willenbring et al. (2013) suggests that the “flat” areas of the world, those with average slopes of <∼100 m/km and representing ∼90% of Earth’s land surface, have adequately high rates of denudation to produce most of the sediment transported to the world’s oceans. This finding is based on the product of interpolated denudation rates (L/T) over the world’s drainage areas (L 2 ) using landscape slope as the controlling variable. We suggest that these findings are incorrect on several grounds.

Geology↗

USGS2017

Fluidized-sediment pipes in Gale crater, Mars, and possible Earth analogs

Since landing in Gale crater, the Mars Science Laboratory rover Curiosity has traversed fluvial, lacustrine, and eolian sedimentary rocks that were deposited within the crater ∼3.6 to 3.2 b.y. ago. Here we describe structures interpreted to be pipes formed by vertical movement of fluidized sediment. Like many pipes on Earth, those in Gale crater are more resistant to erosion than the host rock; they form near other pipes, dikes, or deformed sediment; and some contain internal concentric or eccentric layering. These structures provide new evidence of the importance of subsurface aqueous processes in shaping the near-surface geology of Mars.

Geology↗

USGS2026

Zircon petrochronology fingerprints mantle sources of magmatic rare earth element deposits

The mantle sources of carbonatite and alkaline magmatic systems that host rare earth element (REE) deposits are difficult to constrain because whole-rock compositions are commonly altered. Alteration-resistant zircon trace-element compositions are used to fingerprint mantle sources at Mountain Pass, California, the largest REE deposit in the United States, and extend this approach to a global carbonatite−alkaline rock dataset. Autocrystic zircon samples from the Mountain Pass intrusive suite record subduction-like U-Sc-Nb-Yb compositions, oxidized fO2 (0.8−2.4 relative to fayalite-magnetite-quartz buffer [ΔFMQ]), and Ti-in-zircon temperatures up to ∼970 °C, indicating a lithospheric mantle source enriched and oxidized by Paleoproterozoic subduction and subsequently tapped during Mesoproterozoic postcollisional lithospheric thinning. This contrasts with the ocean island basalt−like enriched mantle recorded by Mesoproterozoic zircon from the Bayan Obo carbonatite complex, China, demonstrating that world-class REE deposits of comparable age can reflect fundamentally different mantle sources. New classifiers separate subduction-metasomatized from non-subduction-enriched mantle domains with ∼90% accuracy, providing a zircon-based tool for fingerprinting the mantle source regions of magmatic REE deposits.

Geology↗

USGS2022

Flood lavas on Earth, Io and Mars

Flood lavas are major geological features on all the major rocky planetary bodies. They provide important insight into the dynamics and chemistry of the interior of these bodies. On the Earth, they appear to be associated with major and mass extinction events. It is therefore not surprising that there has been significant research on flood lavas in recent years. Initial models suggested eruption durations of days and volumetric fluxes of order 10 7 m 3 s −1 with flows moving as turbulent floods. However, our understanding of how lava flows can be emplaced under an insulating crust was revolutionized by the observations of actively inflating pahoehoe flows in Hawaii. These new ideas led to the hypothesis that flood lavas were emplaced over many years with eruption rates of the order of 10 4 m 3 s −1 . The field evidence indicates that flood lava flows in the Columbia River Basalts, Deccan Traps, Etendeka lavas, and the Kerguelen Plateau were emplaced as inflated pahoehoe sheet flows. This was reinforced by the observation of active lava flows of ≥100 km length on Io being formed as tube-fed flows fed by moderate eruption rates (10 2 –10 3 m 3 s −1 ). More recently it has been found that some flood lavas are also emplaced in a more rapid manner. New high-resolution images from Mars revealed ‘platy–ridged’ flood lava flows, named after the large rafted plates and ridges formed by compression of the flow top. A search for appropriate terrestrial analogues found an excellent example in Iceland: the 1783–1784 Laki Flow Field. The brecciated Laki flow top consists of pieces of pahoehoe, not aa clinker, leading us to call this ‘rubbly pahoehoe’. Similar flows have been found in the Columbia River Basalts and the Kerguelen Plateau. We hypothesize that these flows form with a thick, insulating, but mobile crust, which is disrupted when surges in the erupted flux are too large to maintain the normal pahoehoe mode of emplacement. Flood lavas emplaced in this manner could have (intermittently) reached effusion rates of the order of 10 6 m 3 s −1 .

Journal of the Geological Society↗

USGS2014

An enhanced model of land water and energy for global hydrologic and earth-system studies

LM3 is a new model of terrestrial water, energy, and carbon, intended for use in global hydrologic analyses and as a component of earth-system and physical-climate models. It is designed to improve upon the performance and to extend the scope of the predecessor Land Dynamics (LaD) and LM3V models by better quantifying the physical controls of climate and biogeochemistry and by relating more directly to components of the global water system that touch human concerns. LM3 includes multilayer representations of temperature, liquid water content, and ice content of both snowpack and macroporous soil–bedrock; topography-based description of saturated area and groundwater discharge; and transport of runoff to the ocean via a global river and lake network. Sensible heat transport by water mass is accounted throughout for a complete energy balance. Carbon and vegetation dynamics and biophysics are represented as in LM3V. In numerical experiments, LM3 avoids some of the limitations of the LaD model and provides qualitatively (though not always quantitatively) reasonable estimates, from a global perspective, of observed spatial and/or temporal variations of vegetation density, albedo, streamflow, water-table depth, permafrost, and lake levels. Amplitude and phase of annual cycle of total water storage are simulated well. Realism of modeled lake levels varies widely. The water table tends to be consistently too shallow in humid regions. Biophysical properties have an artificial stepwise spatial structure, and equilibrium vegetation is sensitive to initial conditions. Explicit resolution of thick (>100 m) unsaturated zones and permafrost is possible, but only at the cost of long (≫300 yr) model spinup times.

Journal of Hydrometeorology↗

USGS1982

The use of vertical seismic profiles in seismic investigations of the earth

During the past 8 years, the U.S. Geological Survey has conducted an extensive investigation on the use of vertical seismic profiles (VSP) in a variety of seismic exploration applications. Seismic sources used were surface air guns, vibrators, explosives, marine air guns, and downhole air guns. Source offsets have ranged from 100 to 7800 ft. Well depths have been from 1200 to over 10,000 ft. We have found three specific ways in which VSPs can be applied to seismic exploration. First, seismic events observed at the surface of the ground can be traced, level by level, to their point of origin within the earth. Thus, one can tie a surface profile to a well log with an extraordinarily high degree of confidence. Second, one can establish the detectability of a target horizon, such as a porous zone. One can determine (either before or after surface profiling) whether or not a given horizon or layered sequence returns a detectable reflection to the surface. The amplitude and character of the reflection can also be observed. Third, acoustic properties of a stratigraphic sequence can be measured and sometimes correlated to important exploration parameters. For example, sometimes a relationship between apparent attenuation and sand percentage can be established. The technique shows additional promise of aiding surface exploration indirectly through studies of the evolution of the seismic pulse, studies of ghosts and multiples, and studies of seismic trace inversion techniques. Nearly all current seismic data‐processing techniques are adaptable to the processing of VSP data, such as normal moveout (NMO) corrections, stacking, single‐and multiple‐channel filtering, deconvolution, and wavelet shaping.

Geophysics↗

USGS2021

Integrated geophysical imaging of rare-earth-element-bearing iron oxide-apatite deposits in the eastern Adirondack Highlands, New York

The eastern Adirondack Highlands of northern New York host dozens of iron oxide-apatite (IOA) deposits containing magnetite and rare earth element (REE)-bearing apatite. We use new aeromagnetic, aeroradiometric, ground gravity, and sample petrophysical and geochemical data to image and understand these deposits and their geologic framework. Aeromagnetic total field data reflect highly magnetic leucogranite host rock and major structures that likely served as fluid conduits for the hydrothermal system. Bandpass filtering of the aeromagnetic data reveals individual deposits that were verified in the field or from historical records. A three-dimensional inversion for magnetic susceptibility images these deposits at depth, allowing inference of plunge directions and relative size. Radiometric data highlight variations in the surface geology and several large tailings piles that contain REE-bearing apatite. Within the host rock, eTh (equivalent Th), K and the eTh/K ratio are variable with high eTh/K near several of the IOA deposits. Areas with elevated K or low eTh/K representing potassic alteration appear to be rare; instead elevated eTh/K ratios likely reflect widespread sodic alteration overprinting potassic alteration. Bouguer gravity anomalies show limited correspondence to the surface geology, radiometric data, or magnetic data, but do exhibit ~10-km wide highs in areas where deposits are observed. Two-dimensional forward models of the gravity and magnetic data show that deeper dense material beneath the leucogranite is quantitatively feasible. If these dense rocks represent intrusions that were emplaced or still cooling at the time of mineralization, they may have served as a heat source that helped to drive the hydrothermal system. Combining datasets, we find that deposits occur towards the distal ends of major structures within the host leucogranite and mostly above gravity highs. The geophysical modeling thus suggests that IOA deposits formed in structural, thermal, and chemical traps near the distal ends of the hydrothermal system.

New York↗

USGS2014

Geophysical expression of a buried niobium and rare earth element deposit: the Elk Creek carbonatite, Nebraska, USA

The lower Paleozoic Elk Creek carbonatite is a 6–8-km-diameter intrusive complex buried under 200 m of sedimentary rocks in southeastern Nebraska. It hosts the largest known niobium deposit in the U.S. and a rare earth element (REE) deposit. The carbonatite is composed of several lithologies, the relations of which are poorly understood. Niobium mineralization is most enriched within a magnetite beforsite (MB) unit, and REE oxides are most concentrated in a barite beforsite unit. The carbonatite intrudes Proterozoic country rocks. Efforts to explore the carbonatite have used geophysical data and drilling. A high-resolution airborne gravity gradient and magnetic survey was flown over the carbonatite in 2012. The carbonatite is associated with a roughly annular vertical gravity gradient high and a subdued central low and a central magnetic high surrounded by magnetic field values lower than those over the country rocks. Geophysical, borehole, and physical property data are combined for an interpretation of these signatures. The carbonatite is denser than the country rocks, explaining the gravity gradient high. Most carbonatite lithologies have weaker magnetic susceptibilities than those of the country rocks, explaining why the carbonatite does not produce a magnetic high at its margin. The primary source of the central magnetic high is interpreted to be mafic rocks that are strongly magnetized and are present in large volumes. MB is very dense (mean density 3200 kg/m 3 ) and strongly magnetized (median 0.073 magnetic susceptibility), producing a gravity gradient high and contributing to the aeromagnetic high. Barite beforsite has physical properties similar to most of the carbonatite volume, making it a poor geophysical target. Geophysical anomalies indicate the presence of dense and strongly magnetized rocks at depths below existing boreholes, either a large volume of MB or another unknown lithology.

Nebraska↗

USGS2014

Geophysical interpretation of U, Th, and rare earth element mineralization of the Bokan Mountain peralkaline granite complex, Prince of Wales Island, southeast Alaska

A prospectivity map for rare earth element (REE) mineralization at the Bokan Mountain peralkaline granite complex, Prince of Wales Island, southeastern Alaska, was calculated from high-resolution airborne gamma-ray data. The map displays areas with similar radioelement concentrations as those over the Dotson REE-vein-dike system, which is characterized by moderately high %K, eU, and eTh (%K, percent potassium; eU, equivalent parts per million uranium; and eTh, equivalent parts per million thorium). Gamma-ray concentrations of rocks that share a similar range as those over the Dotson zone are inferred to locate high concentrations of REE-bearing minerals. An approximately 1300-m-long prospective tract corresponds to shallowly exposed locations of the Dotson zone. Prospective areas of REE mineralization also occur in continuous swaths along the outer edge of the pluton, over known but undeveloped REE occurrences, and within discrete regions in the older Paleozoic country rocks. Detailed mineralogical examinations of samples from the Dotson zone provide a means to understand the possible causes of the airborne Th and U anomalies and their relation to REE minerals. Thorium is sited primarily in thorite. Uranium also occurs in thorite and in a complex suite of ± Ti ± Nb ± Y oxide minerals, which include fergusonite, polycrase, and aeschynite. These oxides, along with Y-silicates, are the chief heavy REE (HREE)-bearing minerals. Hence, the eU anomalies, in particular, may indicate other occurrences of similar HREE-enrichment. Uranium and Th chemistry along the Dotson zone showed elevated U and total REEs east of the Camp Creek fault, which suggested the potential for increased HREEs based on their association with U-oxide minerals. A uranium prospectivity map, based on signatures present over the Ross-Adams mine area, was characterized by extremely high radioelement values. Known uranium deposits were identified in the U-prospectivity map, but the largest tract occurs over a radioelement-rich granite phase within the pluton that is likely not related to mineralization. Neither mineralization type displays a well-defined airborne magnetic signature.

Alaska↗

USGS2016

Predicting the occurrence of cave-inhabiting fauna based on features of the earth surface environment

One of the most challenging fauna to study in situ is the obligate cave fauna because of the difficulty of sampling. Cave-limited species display patchy and restricted distributions, but it is often unclear whether the observed distribution is a sampling artifact or a true restriction in range. Further, the drivers of the distribution could be local environmental conditions, such as cave humidity, or they could be associated with surface features that are surrogates for cave conditions. If surface features can be used to predict the distribution of important cave taxa, then conservation management is more easily obtained. We examined the hypothesis that the presence of major faunal groups of cave obligate species could be predicted based on features of the earth surface. Georeferenced records of cave obligate amphipods, crayfish, fish, isopods, beetles, millipedes, pseudoscorpions, spiders, and springtails within the area of Appalachian Landscape Conservation Cooperative in the eastern United States (Illinois to Virginia and New York to Alabama) were assigned to 20 x 20 km grid cells. Habitat suitability for these faunal groups was modeled using logistic regression with twenty predictor variables within each grid cell, such as percent karst, soil features, temperature, precipitation, and elevation. Models successfully predicted the presence of a group greater than 65% of the time (mean = 88%) for the presence of single grid cell endemics, and for all faunal groups except pseudoscorpions. The most common predictor variables were latitude, percent karst, and the standard deviation of the Topographic Position Index (TPI), a measure of landscape rugosity within each grid cell. The overall success of these models points to a number of important connections between the surface and cave environments, and some of these, especially soil features and topographic variability, suggest new research directions. These models should prove to be useful tools in predicting the presence of species in understudied areas.

Appalachian Landscape Conservation Cooperative↗

USGS2019

Measuring sustainability of seed-funded Earth science informatics projects

Short term funding is a common funding model for informatics projects. Funders are interested in maximizing the sustainability and accessibility of the outputs, but there are no commonly accepted practices to do so in the Earth sciences informatics field. We constructed and applied a framework for sustainability drawing from other disciplines that have more published work in sustainability of projects. This framework had seven sustainability influences (outputs modified, code repository used, champion present, workforce stability, support from other organizations, collaboration/partnership, and integration with policy), and three ways of defining sustainability (at the individual-, organization-, and community-level). Using this framework, we evaluated outputs of projects funded by the U.S. Geological Survey’s Community for Data Integration (CDI). We found that the various outputs are widely accessible, but not necessarily sustained or maintained. Projects with most of the sustainability influences often became institutionalized, and met a required need of the community. Even if proposed outputs were not delivered or sustained, knowledge of lessons learned could be spread to build community capacity in a topic, which is another type of sustainability. We conclude by summarizing lessons for individuals applying for short-term funding, and for organizations running programs that provide such funding, in terms of maximizing sustainability of their projects.

PLoS ONE↗

USGS1981

Earth flows along Henry Creek, northern Alaska

Many earth flows occurred during the summer of 1979 in the hilly terrain near Umiat, Alaska, particularly along Henry Creek. Most were shallow, involving only the tundra mat and no more than 1.5 m of the underlying mud. The summer of 1979 was the warmest and wettest for the period of record at Umiat, and precipitation was characterized by brief but intense localized rainstorms. Failure probably was triggered by the heavy rains and facilitated by an absorbent tundra mat over a clayey substrate, and perhaps in some cases by a thicker than normal active layer. Flows of this kind have occurred repeatedly in the Umiat area, most likely during summers in which climatic conditions were similar to those of 1979.

Alaska↗

USGS2017

Improvements in absolute seismometer sensitivity calibration using local earth gravity measurements

The ability to determine both absolute and relative seismic amplitudes is fundamentally limited by the accuracy and precision with which scientists are able to calibrate seismometer sensitivities and characterize their response. Currently, across the Global Seismic Network (GSN), errors in midband sensitivity exceed 3% at the 95% confidence interval and are the least‐constrained response parameter in seismic recording systems. We explore a new methodology utilizing precise absolute Earth gravity measurements to determine the midband sensitivity of seismic instruments. We first determine the absolute sensitivity of Kinemetrics EpiSensor accelerometers to 0.06% at the 99% confidence interval by inverting them in a known gravity field at the Albuquerque Seismological Laboratory (ASL). After the accelerometer is calibrated, we install it in its normal configuration next to broadband seismometers and subject the sensors to identical ground motions to perform relative calibrations of the broadband sensors. Using this technique, we are able to determine the absolute midband sensitivity of the vertical components of Nanometrics Trillium Compact seismometers to within 0.11% and Streckeisen STS‐2 seismometers to within 0.14% at the 99% confidence interval. The technique enables absolute calibrations from first principles that are traceable to National Institute of Standards and Technology (NIST) measurements while providing nearly an order of magnitude more precision than step‐table calibrations.

Bulletin of the Seismological Society of America↗

USGS2022

Earth’s upper crust seismically excited by infrasound from the 2022 Hunga Tonga–Hunga Ha’apai eruption, Tonga

Records of pressure variations on seismographs were historically considered unwanted noise; however, increased deployments of collocated seismic and acoustic instrumentation have driven recent efforts to use this effect induced by both wind and anthropogenic explosions to invert for near‐surface Earth structure. These studies have been limited to shallow structure because the pressure signals have relatively short wavelengths (<∼300 m). However, the 2022 eruption of Hunga Tonga–Hunga Ha’apai (also called “Hunga”) volcano in Tonga generated rare, globally observed, high‐amplitude infrasound signals with acoustic wavelengths of tens of kilometers. In this study, we examine the acoustic‐to‐seismic coupling generated by the Hunga eruption across 82 Global Seismographic Network (GSN) stations and show that ground motion amplitudes are related to upper (0 to ∼5 km) crust material properties. We find high (>0.8) correlations between pressure and vertical component ground motion at 83% of the stations, but only 30% of stations show this on the radial component, likely due to complex tilt effects. We use average elastic properties in the upper 5.2 km from the CRUST1.0 model to estimate vertical seismic/acoustic coupling coefficients ( ⁠ S V / A ">

Seismological Research Letters↗

USGS2015

Book review: Rare earth elements—A new approach to the nexus of supply, demand and use: exemplified along the use of neodymium in permanent magnets

This book is part of the “Springer Theses” published by Springer, a book series designed to highlight and share outstanding Ph.D. research. As explained by Springer (on the second page), this series “brings together a selection of the very best Ph.D. theses from around the world and across the physical sciences.” I admire Springer for this endeavor because a large number of exceptional theses are never published, and thus are difficult to obtain, while most of those that are published are presented only in highly condensed form as journal articles. Review info: Rare Earth Elements—A New Approach to the Nexus of Supply, Demand and Use: Exemplified Along the Use of Neodymium in Permanent Magnets . By Volker Zerf. 2013. ISBN 978-3-642-35457-1. 157 pp.

Economic Geology↗

USGS2016

Regional geologic and petrologic framework for iron oxide ± apatite ± rare earth element and iron oxide copper-gold deposits of the Mesoproterozoic St. Francois Mountains terrane, southeast Missouri, USA

This paper provides an overview on the genesis of Mesoproterozoic igneous rocks and associated iron oxide ± apatite (IOA) ± rare earth element, iron oxide-copper-gold (IOCG), and iron-rich sedimentary deposits in the St. Francois Mountains terrane of southeast Missouri, USA. The St. Francois Mountains terrane lies along the southeastern margin of Laurentia as part of the eastern granite-rhyolite province. The province formed during two major pulses of igneous activity: (1) an older early Mesoproterozoic (ca. 1.50–1.44 Ga) episode of volcanism and granite plutonism, and (2) a younger middle Mesoproterozoic (ca. 1.33–1.30 Ga) episode of bimodal gabbro and granite plutonism. The volcanic rocks are predominantly high-silica rhyolite pyroclastic flows, volcanogenic breccias, and associated volcanogenic sediments with lesser amounts of basaltic to andesitic volcanic and associated subvolcanic intrusive rocks. The iron oxide deposits are all hosted in the early Mesoproterozoic volcanic and volcaniclastic sequences. Previous studies have characterized the St. Francois Mountains terrane as a classic, A-type within-plate granitic terrane. However, our new whole-rock geochemical data indicate that the felsic volcanic rocks are effusive derivatives from multicomponent source types, having compositional similarities to A-type within-plate granites as well as to S- and I-type granites generated in an arc setting. In addition, the volcanic-hosted IOA and IOCG deposits occur within bimodal volcanic sequences, some of which have volcanic arc geochemical affinities, suggesting an extensional tectonic setting during volcanism prior to emplacement of the ore-forming systems.

Missouri↗

USGS2016

Geochemistry, Nd-Pb Isotopes, and Pb-Pb Ages of the Mesoproterozoic Pea Ridge Iron Oxide-Apatite–Rare Earth Element Deposit, Southeast Missouri

Iron oxide-apatite and iron oxide-copper-gold deposits occur within ~1.48 to 1.47 Ga volcanic rocks of the St. Francois Mountains terrane near a regional boundary separating crustal blocks having contrasting depleted-mantle Sm-Nd model ages (T DM ). Major and trace element analyses and Nd and Pb isotope data were obtained to characterize the Pea Ridge deposit, improve identification of exploration targets, and better understand the regional distribution of mineralization with respect to crustal blocks. The Pea Ridge deposit is spatially associated with felsic volcanic rocks and plutons. Mafic to intermediate-composition rocks are volumetrically minor. Data for major element variations are commonly scattered and strongly suggest element mobility. Ratios of relatively immobile elements indicate that the felsic rocks are evolved subalkaline dacite and rhyolite; the mafic rocks are basalt to basaltic andesite. Granites and rhyolites display geochemical features typical of rocks produced by subduction. Rare earth element (REE) variations for the rhyolites are diagnostic of rocks affected by hydrothermal alteration and associated REE mineralization. The magnetite-rich rocks and REE-rich breccias show similar REE and mantle-normalized trace element patterns. Nd isotope compositions (age corrected) show that: (1) host rhyolites have ɛ Nd from 3.44 to 4.25 and T DM from 1.51 to 1.59 Ga; (2) magnetite ore and specular hematite rocks display ɛ Nd from 3.04 to 4.21 and T DM from 1.6 to 1.51 Ga, and ɛ Nd from 2.23 to 2.81, respectively; (3) REE-rich breccias have ɛ Nd from 3.04 to 4.11 and T DM from 1.6 to 1.51 Ga; and (4) mafic to intermediate-composition rocks range in ɛ Nd from 2.35 to 3.66 and in T DM from 1.66 to 1.56. The ɛ Nd values of the magnetite and specular hematite samples show that the REE mineralization is magmatic; no evidence exists for major overprinting by younger, crustal meteoric fluids, or by externally derived Nd. Host rocks, breccias, and magnetite ore shared a common origin from a similar source. Lead isotope ratios are diverse: (1) host rhyolite has 206 Pb/ 204 Pb from 24.261 to 50.091; (2) Pea Ridge and regional galenas have 206 Pb/ 204 Pb from 16.030 to 33.548; (3) REE-rich breccia, magnetite ore, and specular hematite rock are more radiogenic than galena; (4) REE-rich breccias have high 206 Pb/ 204 Pb (38.122–1277.61) compared to host rhyolites; and (5) REE-rich breccias are more radiogenic than magnetite ore and specular-hematite rock, having 206 Pb/ 204 Pb up to 230.65. Radiogenic 207 Pb/ 206 Pb age estimates suggest the following: (1) rhyolitic host rocks have ages of ~1.50 Ga, (2) magnetite ore is ~1.44 Ga, and (3) REE-rich breccias are ~1.48 Ga. These estimates are broadly consistent and genetically link the host rhyolite, REE-rich breccia, and magnetite ore as being contemporaneous. Alteration style and mineralogical or textural distinctions among the magnetite-rich rocks and REE-rich breccias do not correlate with different isotopic sources. In our model, magmatic fluids leached metals from the coeval felsic rocks (rhyolites), which provided the metal source reflected in the compositions of the REE-rich breccias and mineralized rocks. This model allows for the likelihood of contributions from other genetically related felsic and intermediate to more mafic rocks stored deeper in the crust. The deposit thus records an origin as a magmatic-hydrothermal system that was not affected by Nd and Pb remobilization processes, particularly if these processes also triggered mixing with externally sourced metal-bearing fluids. The Pea Ridge deposit was part of a single, widespread, homogeneous mixing system that produced a uniform isotopic composition, thus representing an excellent example of an igneous-dominated system that generated coeval magmatism and REE mineralization. Geochemical features suggest that components in the Pea Ridge deposit originated from sources in an orogenic margin. Basaltic magmatism produced by mantle decompression melting provided heat for extracting melts from the middle or lower crust. Continual addition of mafic magmas to the base of the subcontinental lithosphere, in a back-arc setting, remelted calc-alkaline rocks enriched in metals that were stored in the crust. The St. Francois Mountains terrane is adjacent to the regional T DM line (defined at a value of 1.55 Ga) that separates ~1600 Ma basement to the west, from younger basements to the east. Data for Pea Ridge straddle the T DM values proposed for the line. The Sm-Nd isotope system has been closed since formation of the deposit and the original igneous signatures have not been affected by cycles of alteration or superimposed mineralizing events. No evidence exists for externally derived Nd or Sm. The source region for metals within the Pea Ridge deposit had a moderate compositional variation and the REE-rich breccias and mineralized rocks are generally isotopically homogeneous. The Pea Ridge deposit thus constitutes a distinctive isotopic target for use as a model in identifying other mineralized systems that may share the same metal source in the St. Francois Mountains terrane and elsewhere in the eastern Granite-Rhyolite province.

Missouri↗

USGS2016

Mineral thermometry and fluid inclusion studies of the Pea Ridge iron oxide-apatite–rare earth element deposit, Mesoproterozoic St. Francois Mountains Terrane, southeast Missouri, USA

Mineral thermometry and fluid inclusion studies were conducted on variably altered and mineralized samples from the Mesoproterozoic Pea Ridge iron oxide-apatite (IOA)-rare earth element (REE) deposit in order to constrain P-T conditions, fluid chemistry, and the source of salt and volatiles during early magnetite and later REE mineralization. Scanning electron microscopy (SEM)-cathodoluminescence and SEM-backscatter electron images show that quartz and rutile precipitated before, during, and after magnetite and REE mineral growth. Ti-in-quartz and Zr-in-rutile equilibration temperatures range from ≤350° to 750°C in the amphibole, magnetite, hematite, and silicified zones where T increased during magnetite and quartz growth and dropped precipitously after fracturing and brecciation. Late drusy quartz cements within a REE-rich breccia pipe record the lowest T (≤315°–400°C). Liquid-, vapor-rich, and hypersaline (±hematite, calcite) fluid inclusions are common and liquid CO 2 is present locally. Salinities define three populations: saline (10–27 wt % NaCl equiv), hypersaline (34–>60 wt % NaCl equiv), and dilute (0–10 wt % NaCl equiv ). The wide range of eutectic melting temperatures (−67° to −19°C) suggests that saline inclusions trapped variable proportions of a CaCl-MgCl-FeCl-bearing fluid end member and an NaCl-KCl fluid end member. Homogenization temperatures and pressures of these saline inclusions suggest they were trapped when fluids unmixed into brine and vapor at T <350°C, P <15 MPa, and a depth of ~1.5 km. Hypersaline inclusions were trapped at low T and P (~200°C and ~1 MPa) along the V + L + H curve when the system vented to the paleosurface. Data for dilute inclusions in late drusy quartz from the REE-rich breccia pipe are indicative of a boiling epithermal environment. The Na/Cl, Na/K, and Cl/Br ratios of fluid inclusion extracts provide evidence for mixtures of magmatic hydrothermal fluids and evaporated seawater. Extracts from magnetite, hematite, and pyrite plot in the magmatic-hydrothermal field, indicating that Fe was derived from a magmatic source. Their enrichments in Mg and Ca are consistent with a mafic magmatic source. The positive correlation between Na/Mg and Na/Ca ratios may be due to halite saturation or albitization of igneous rocks. Extracts from barite in the REE-rich breccia pipes are enriched in Na and Br and plot near the seawater evaporation trend. He is highly enriched relative to Ne and Ar in fluid inclusion extracts, which precludes air as a source of He. Although the He is mostly of crustal origin, pyrite with a 3 He/ 4 He (R/R A ) of 0.1 contains up to 12% mantle He. Many extracts have low 20 Ne/ 22 Ne ratios due to nucleogenic production of 22 Ne in high F/O minerals such as fluorapatite or F biotite. The arrays of data for 3 He/ 4 He (R/R A ) and 22 Ne/ 20 Ne suggest that volatiles were derived from two sources, a moderate F mafic magma containing mantle He and a high F silicic magma with crustal He. Together with other evidence cited in this report, these data (1) support a magmatic hydrothermal origin for the Mesoproterozoic magnetite-apatite deposit with ore fluids derived from a concealed mafic to intermediate-composition intrusion, (2) suggest that the REE minerals in breccia pipes were either derived from apatite or precipitated in response to decompression and cooling during breccia pipe formation, (3) provide evidence for the influx of basinal brine, magmatic fluids from granitic intrusions, and meteoric water after breccia pipe formation, and (4) show that Pea Ridge was relatively unaffected by the late Paleozoic Mississippi Valley-type (MVT) Pb-Zn system in overlying Cambrian sedimentary rocks.

Missouri↗