Search USGSSearch

SEARCH · Search USGS

Results for “Analytical Methods”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 397 records · Page 22Linked to original sources

Interstitial water studies on small core samples, leg 14

The interstitial waters from the sediments cored on Leg 14 exhibit characteristic compositional trends with three important exceptions. At most of the sites, the changes in Na and Cl are very small while enrichment of Ca and Sr and depletion of Mg and SO 4 is typical of patterns observed in similar types of sediment recovered on previous legs. At Sites 139 and 140, off the African coast, and Site 144, off the coast of South America, systematic increases in concentration with depth are found for Na and Cl. At these sites, the concentration changes, in Ca, Mg, SO 4 and Sr generally follow diagenic patterns observed previously, but there is some indication of other factors affecting Mg concentrations. All analyses reported here, with the exception of bulk water content and pH, were carried out on water samples which were squeezed from the sediments on board ship and preserved by heat-sealing in lengths of polyethylene tubing. Analytical methods were identical to those outlined in earlier volumes of this series. We wish to thank Wen Chang, James O'Neill and Irene Uhlitzsch for their assistance in conducting the laboratory determinations and data reduction

Initial reports of the Deep Sea Drilling Project

Interstitial water studies on small core samples, Deep Sea Drilling Project, Leg 5

Leg 5 samples fall into two categories with respect to interstitial water composition: 1) rapidly deposited terrigenous or appreciably terrigenous deposits, such as in Hole 35 (western Escanaba trough, off Cape Mendocino, California); and, 2) slowly deposited pelagic clays and biogenic muds and oozes. Interstitial waters in the former show modest to slight variations in chloride and sodium, but drastic changes in non-conservative ions such as magnesium and sulfate. The pelagic deposits show only relatively minor changes in both conservative and non-conservative pore fluid constituents. As was pointed out in earlier Leg Reports, it is believed that much of the variation in chloride in pore fluids within individual holes is attributable to the manipulation of samples on board ship and in the laboratory. On the other hand, the scatter in sodium is due in part to analytical error (on the order of 2 to 3 per cent, in terms of a standard deviation), and it probably accounts for most of the discrepancies in total anion and cation balance. All constituents reported here, with the exception of bulk water content, were analyzed on water samples which were sealed in plastic tubes aboard ship and were subsequently opened and divided into weighed aliquots in the laboratory. Analytical methods follow the atomic absorption, wet chemical and emission spectrochemical techniques briefly summarized in previous reports, e.g. Manheim et al., 1969, and Chan and Manheim, 1970. The authors acknowledge assistance from W. Sunda, D. Kerr, C. Lawson and H. Richards, and thank D. Spencer, P. Brewer and E. Degens for allowing the use of equipment and laboratory facilities.

Initial reports of the Deep Sea Drilling Project

Interstitial water studies on small core samples, Deep Sea Drilling Project, Leg 6

Sediments from Leg 6 sites, west of the Hawaiian Islands, consisted primarily of various combinations of deep-sea biogenic oozes, volcanic ash, and its breakdown products. Pore fluids from most of the sites were similar in composition to present day ocean water, and in some sties almost identical. However, interstitial fluids from Site 53 (Philippine Sea) showed changes in ionic composition which were beyond those previously considered attributable to diagenetic influence. These samples show the beginnings of metamorphism by dramatic increases in calcium concentrations and corresponding decreases in alkali concentrations. Analytical methods were similar to those outlined in previous Leg Reports. However, obvious contamination of aliquots for sodium determination in the laboratory made it necessary to determine all sodium values by difference between anion and cation balances. These values are, if anything, more accurate than direct determinations which have been discussed in earlier legs. However, the authors will continue to analyze sodium directly, and in the future they may be able to improve the precision of the determinations to the point where small losses and gains of sodium in the pore fluids may be established accurately. Agreement between colorimetric and spectrometric determinations of silicon has improved, but there are still occasional marked differences for which the writers have no explanation. T. Takahashi has allowed the authors to compare total Carbon Dioxide (CO 2 ) measurements from his laboratory with their alkalinity determinations: both sets of data were obtained from fluids from the same squeezings of sediments and should give similar values at the indicated pH levels. Some disturbingly large discrepancies in the two sets of data are evident. The authors do not think that their back-titration alkalinity technique alone is responsible for the differences. However, they have not evaluated the possible influence of the heat-sealed polyethylene pipes on the alkalinity values; this should be considered a potential source of error. The pH data from water samples processed and measured on shipboard are reported here. In view of the major changes in pressure and temperature (laboratory temperatures were reported to be 26 to 28°C) and the sediments to new gaseous regimes prior to pH measurement, these values should be interpreted mainly as applying to the squeezed effluents, not to in situ values.

Initial reports of the Deep Sea Drilling Project

Acute toxicity of resmethrin, malathion and methoprene to larval and juvenile American lobsters ( Homarus amemcanus ) and analysis of pesticide levels in surface waters after Scourge™, Anvil™ and Altsoid™ application

Acute toxicity and immune response, combined with temperature stress effects, were evaluated in larval and juvenile American lobsters ( Homarus americanus ) exposed to malathion, resmethrin and methoprene. These pesticides were used to control West Nile virus in New York in 1999, the same year the American lobster population collapsed in western Long Island Sound (LIS). Whereas the suite of pesticides used for mosquito control changed in subsequent years, a field study was also conducted to determine pesticide concentrations in surface waters on Long Island and in LIS after operational applications. The commercial formulations used in 2002 and 2003—Scourge, Anvil and Altosid—contain the active ingredients resmethrin, sumithrin and methoprene, respectively. Concentrations of the synergist piperonyl butoxide (PBO) were also measured as a proxy for pesticide exposure. Acute mortality in Stage I-II larval lobsters demonstrated that they are extremely sensitive to continuous resmethrin exposure. Resmethrin LC50s for larval lobsters determined under flow-through conditions varied from 0.26–0.95 μg L −1 in 48- and 96-h experiments at 16°C, respectively. Increased temperature (24°C) did not significantly alter resmethrin toxicity. Malathion and methoprene were less toxic than resmethrin. The 48-h LC50 for malathion was 3.7 μg L −1 and methoprene showed no toxicity at the highest (10 μg L −1 ) concentration tested. Phenoloxidase activity was used as a measure of immune response for juvenile lobsters exposed to sublethal pesticide concentrations. In continuous exposures to sublethal doses of resmethrin (0.03 μg L −1 ) or malathion (1 μg L −1 ) for 7 d at 16 or 22°C, temperature had a significant effect on phenoloxidase activity ( P ≤ 0.006) whereas pesticide exposure did not ( P = 0.880). The analytical methods developed using high performance liquid chromatography coupled to time-of-flight mass spectroscopy (LC-TOF-MS) provided high sensitivity with mass detection limits of 0.1–0.3 ng L −1 . Pesticide levels were often detected in the ng L −1 range in Long Island surface waters and western LIS (except in open waters), but rarely at concentrations found to be toxic in flow-through laboratory exposures, even immediately after spray events.

Journal of Shellfish Research

Physical and chemical data on sediments deposited in the Missouri and the Mississippi River flood plains during the July through August 1993 flood

In July and August 1993, Missouri and Mississippi River floodwaters overtopped or breached levees and inundated agricultural and urban areas in the flood plains. To assess the regional variability of quality of silt and clay sediments transported and deposited during inundation, sediment samples were collected in September 1993 at 25 sites in the Missouri and the Mississippi River flood plains. The samples were analyzed for physical properties and chemical constituents that included particle-size distribution, water content, volatile solids, nutrients, carbon, selected trace elements, pesticides, and semi volatile organic compounds for post flood sediment samples, and particle-size distribution for preflood soil samples. Pesticides were detected in samples from many of the sites, with alachlor detected in one sample at a concentration of 54 micrograms per kilogram. Many semi volatile organic compounds were detected in samples at several sites, with the concentration of fluoranthene in one sample at 270 milligrams per kilogram. Procedures for selecting sites, techniques developed for sampling, laboratory analytical methods, and quality-assurance sampling methods also are described.

Illinois, Iowa, Missouri

Groundwater-quality data associated with abandoned underground coal mine aquifers in West Virginia, 1973-2016: Compilation of existing data from multiple sources

This report describes a compilation of existing water-quality data associated with groundwater resources originating from abandoned underground coal mines in West Virginia. Data were compiled from multiple sources for the purpose of understanding the suitability of groundwater from abandoned underground coal mines for public supply, industrial, agricultural, and other uses. This compilation includes data collected for multiple individual studies conducted from July 13, 1973 through September 7, 2016. Analytical methods varied by the time period of data collection and requirements of the independent studies.This project identified 770 water-quality samples from 294 sites that could be attributed to abandoned underground coal mine aquifers originating from multiple coal seams in West Virginia.

West Virginia

Data on dissolved pesticides and volatile organic compounds in surface and ground waters in the San Joaquin-Tulare basins, California, water years 1992-1995

This report contains pesticide, volatile organic compound, major ion, nutrient, tritium, stable isotope, organic carbon, and trace-metal data collected from 149 ground-water wells, and pesticide data collected from 39 surface-water stream sites in the San Joaquin Valley of California. Included with the ground-water data are field measurements of pH, specific conductance, alkalinity, temperature, and dissolved oxygen. This report describes data collection procedures, analytical methods, quality assurance, and quality controls used by the National Water-Quality Assessment Program to ensure data reliability. Data contained in this report were collected during a four year period by the San Joaquin?Tulare Basins Study Unit of the United States Geological Survey's National Water-Quality Assessment Program. Surface-water-quality data collection began in April 1992, with sampling done three times a week at three sites as part of a pilot study conducted to provide background information for the surface-water-study design. Monthly samples were collected at 10 sites for major ions and nutrients from January 1993 to March 1995. Additional samples were collected at four of these sites, from January to December 1993, to study spatial and temporal variability in dissolved pesticide concentrations. Samples for several synoptic studies were collected from 1993 to 1995. Ground-water-quality data collection was restricted to the eastern alluvial fans subarea of the San Joaquin Valley. Data collection began in 1993 with the sampling of 21 wells in vineyard land-use settings. In 1994, 29 wells were sampled in almond land-use settings and 9 in vineyard land-use settings; an additional 11 wells were sampled along a flow path in the eastern Fresno County vineyard land-use area. Among the 79 wells sampled in 1995, 30 wells were in the corn, alfalfa, and vegetable land-use setting, and 1 well was in the vineyard land-use setting; an additional 20 were flow-path wells. Also sampled in 1995 were 28 wells used for a regional assessment of ground-water quality in the eastern San Joaquin Valley.

Data Series

Occurrence of selected pharmaceutical and non-pharmaceutical compounds, and stable hydrogen and oxygen isotope ratios, in a riverbank filtration study, Platte River, Nebraska, 2001 to 2003, Volume 1

Although studied extensively in recent years in Europe, the occurrence of endocrine disrupters and other organic wastewater compounds in the environment in the United States is not well documented. To better understand the efficiency of riverbank filtration with respect to endocrine disrupting compounds and to evaluate the use of riverbank filtration as an effective means of drinking-water treatment, a study was conducted during 2001-2003 by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Lincoln, at an established riverbank-filtration well field with horizontal collector wells and vertical wells. This study provides information that will be useful for (1) increased understanding of the processes and factors important in controlling the transport of endocrine disrupters, such as pesticides and pharmaceuticals during riverbank filtration, (2) better understanding of the physical and chemical processes that affect riverbank-filtration efficiency, and (3) managing the water resources of the eastern Platte River Basin. This report presents analytical methods and data collected during the study. Data are presented as generalized statistics and in figures showing temporal variations. Sites from which water-quality samples were collected for this study included wastewater sites (a cattle feedlot lagoon, a hog confinement lagoon, and wastewater-treatment plant effluent), surface-water sites (Platte River, Salt Creek, and Loup Power Canal), ground-water sites (one collector well and three vertical wells), and drinking-water sites (raw and finished). Field water-quality properties were measured in samples from these sites. Pharmaceutical compounds were detected often in the wastewater-treatment plant effluent. Surface and ground water showed low-level concentrations of pharmaceuticals. Finished drinking-water samples did not contain detectable concentrations of pharmaceuticals except for low levels of cotinine and caffeine. Antibiotics were found in some of the wastewater samples and twice in Salt Creek. Antibiotics were not detected in any samples from the Platte River or the well field. Surface-water samples were analyzed for total organic carbon and ground-water samples were analyzed for dissolved organic carbon. Samples from all sites were analyzed for major ions. Herbicides commonly detected in surface, ground, and drinking water included acetachlor, alachlor, atrazine, and metolachlor as well as degradates of these compounds. Most of the samples from wastewater sites were found to contain predominantly acetamide degradates. High concentrations of several organic wastewater indicator compounds were detected at the wastewater sites and in Salt Creek. Several organic wastewater indicator compounds were detected multiple times in samples from the Platte River. Bromoform, a by-product of disinfection in the treatment plant, was found in samples from the finished drinking water. Stable hydrogen isotope ratios show a range in seasonal variation of -73.6 per mill to -38.1 per mill relative to Vienna Standard Mean Ocean Water (VSMOW) reference water and -69.2 per mill to -46.5 per mill for surface water and ground water, respectively. Oxygen isotope ratios for surface-water samples varied between -9.86 per mill and -5.05 per mill. Stable oxygen isotope ratios of ground waters varied between -9.62 per mill and -5.81 per mill.

Nebraska

National geochronological and natural radioelement data bases

This CD-ROM contains both the National Geochronological Data Base [NGDB] and the Natural Radioelement Data Base [NRDB]. Supporting location, geologic, and reference information is provided for both data bases. The NGDB is a compilation of more than 30,000 individual published Pb-alpha, fission-track, K-Ar, Rb-Sr, U-Th-Pb, and Sm-Nd rock and mineral ages reported on approximately 18,000 dated samples from the United States. A program is provided to search the data files by latitude and longitude, state, analytical method, and age range. The NGDB is provided as quote-comma delimited files that can be entered into most commercial spreadsheet programs. The NRDB gives gamma-ray spectrometric analyses of the natural radioelements (U, Th, and K) for more than 8500 whole-rock samples obtained under the USGS Natural Radioelement Distribution Project. A program is provided to search the data files by state, keyword, U content, Th content, and K content.

Data Series

Occurrence of selected pharmaceutical and non-pharmaceutical compounds, and stable hydrogen and oxygen isotope ratios in a riverbank filtration study, Platte River, Nebraska, 2002 to 2005, Volume 2

This document is the second volume of a data series report that describes the data collected during a study conducted during 2001 through 2005 by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Lincoln, at an established riverbank-filtration well field with horizontal collector wells and vertical wells. The data were collected as part of a study designed to help researchers better understand the efficiency of riverbank filtration with respect to endocrine disrupting compounds and to evaluate the use of riverbank filtration as an effective means of drinking-water treatment. This study provides information that will be useful for (1) increased understanding of the processes and factors controlling the transport of endocrine disrupters, such as pesticides and pharmaceuticals during riverbank filtration, (2) better understanding of the physical and chemical processes that affect riverbank-filtration efficiency, and (3) managing the water resources of the eastern Platte River Basin. This report presents analytical methods and additional data for pharmaceuticals, dissolved organic carbon (DOC), ultraviolet absorbance at 254 nanometer (nm) wavelength (UV254), specific ultraviolet absorbance (SUVA), nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), nonylphenol ethoxycarboxylates (NPECs), and stable hydrogen and oxygen isotope ratios that were not available at the time of publication of Volume 1 in the data series. Data are presented as generalized statistics and in figures showing temporal variations. Sites from which water-quality samples were collected for this study included wastewater sites (a cattle feedlot lagoon, a hog confinement lagoon, and wastewater-treatment plant effluent), surface-water sites (Platte River, Salt Creek, and Loup Power Canal), ground-water sites (one collector well and five vertical wells), and drinking-water sites (raw and finished). Field water-quality properties also were measured in samples from these sites. Pharmaceuticals detected at least once in samples collected from the Platte River included 1,7-dimethylxanthine, acetaminophen, caffeine, carbamazapine, and cotinine. Among the ground-water samples, pharmaceutical compounds detected at low concentrations in at least one sample included 1,7-dimethylxanthine, acetaminophen, carbamazapine, and trimethoprim. When analyzing for non-pharmaceutical compounds in samples from the wastewater sites, the wastewater-treatment plant effluent samples had the highest concentrations of each of NTA, EDTA, and NPECs compounds. Surface-water samples from Salt Creek had higher concentrations of EDTA and NPECs than samples from the Platte River. NTA was not detected in any samples from the ground-water sites. EDTA was detected in all samples from all wells. Detectable concentrations of EDTA were also observed in all samples from the raw water and finished water.

Nebraska

Water- and air-quality monitoring of the Sweetwater Reservoir Watershed, San Diego County, California-Phase One results, continued, 1999-2001

In 1998, the U.S. Geological Survey, in cooperation with the Sweetwater Authority, began a study to assess the overall health of the Sweetwater watershed with respect to chemical contamination. The study included regular sampling of air and water at Sweetwater Reservoir for chemical contaminants, including volatile organic compounds, polycyclic aromatic hydrocarbons, pesticides, and major and trace elements. Background water samples were collected at Loveland Reservoir for volatile organic compounds and pesticides. The purpose of this study was to monitor changes in contaminant composition and concentration in the air and water resulting from the construction and operation of State Route 125 near Sweetwater Reservoir. To accomplish this, the study was divided into two phases. Phase One sampling was designed to establish baseline conditions for target compounds in terms of detection frequency and concentration in air and water. Phase Two sampling is planned to continue at the established monitoring sites during and after construction of State Route 125 to assess the chemical impact this roadway alignment project may have on the water quality in the reservoir. In addition to the ongoing data collection, several special studies were initiated to assess the occurrence of specific chemicals of concern, such as low-use pesticides, trace metals, and wastewater compounds. This report describes the study design, and the sampling and analytical methods, and presents the results for the second and third years of the study (October 1999 to September 2001). Data collected during the first year of sampling (October 1998 to September 1999) were published in 2002.

California

Concentrations of selected pharmaceuticals and antibiotics in south-central Pennsylvania waters, March through September 2006

This report presents environmental and quality-control data from analyses of 15 pharmaceutical and 31 antibiotic compounds in water samples from streams and wells in south-central Pennsylvania. The analyses are part of a study by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP) to define concentrations of selected emerging contaminants in streams and well water in Pennsylvania. Sampling was conducted at 11 stream sites and at 6 wells in 9 counties of south-central Pennsylvania. Five of the streams received municipal wastewater and 6 of the streams received runoff from agricultural areas dominated by animal-feeding operations. For all 11 streams, samples were collected at locations upstream and downstream of the municipal effluents or animal-feeding operations. All six wells were in agricultural settings. A total of 120 environmental samples and 21 quality-control samples were analyzed for the study. Samples were collected at each site in March/April, May, July, and September 2006 to obtain information on changes in concentration that could be related to seasonal use of compounds. For streams, 13 pharmaceuticals and 11 antibiotics were detected at least 1 time. Detections included analytical results that were estimated or above the minimum reporting limits. Seventy-eight percent of all detections were analyzed in samples collected downstream from municipal-wastewater effluents. For streams receiving wastewater effluents, the pharmaceuticals caffeine and para-xanthine (a degradation product of caffeine) had the greatest concentrations, 4.75 μg/L (micrograms per liter) and 0.853 μg/L, respectively. Other pharmaceuticals and their respective maximum concentrations were carbamazepine (0.516 μg/L) and ibuprofen (0.277 μg/L). For streams receiving wastewater effluents, the antibiotic azithromycin had the greatest concentration (1.65 μg/L), followed by sulfamethoxazole (1.34 μg/L), ofloxacin (0.329 μg/L), and trimethoprim (0.256 μg/L). For streams receiving runoff from animal-feeding operations, the only pharmaceuticals detected were acetaminophen, caffeine, cotinine, diphenhydramine, and carbamazepine. The maximum concentration for pharmaceuticals was 0.053 μg/L. Three streams receiving runoff from animal-feeding operations had detections of one or more antibiotic compound--oxytetracycline, sulfadimethoxine, sulfamethoxazole, and tylosin. The maximum concentration for antibiotics was 0.157 μg/L. The average number of compounds (pharmaceuticals and antibiotics) detected in sites downstream from animal-feeding operations was three. The average number of compounds detected downstream from municipal-wastewater effluents was 13. For wells used to supply livestock, four compounds were detected--two pharmaceuticals (cotinine and diphenhydramine) and two antibiotics (tylosin and sulfamethoxazole). There were five detections in all the well samples. The maximum concentration detected in well water was for cotinine, estimated to be 0.024 μg/L. Seasonal occurrence of pharmaceutical and antibiotic compounds in stream water varied by compound and site type. At four stream sites, the same compounds were detected in all four seasonal samples. At other sites, pharmaceutical or antibiotic compounds were detected only one time in seasonal samples. Winter samples collected in streams receiving municipalwastewater effluent had the greatest number of compounds detected (21). Research analytical methods were used to determine concentrations for pharmaceuticals and antibiotics. To assist in evaluating the quality of the analyses, detailed information is presented on laboratory methodology and results from qualitycontrol samples. Quality-control data include results for nine blanks, nine duplicate environmental sample pairs, and three laboratory-spiked environmental samples as well as the recoveries of compounds in laboratory surrogates and laboratory reagent spikes.

Pennsylvania

Data on mercury in water, bed sediment, and fish from streams across the United States, 1998-2005

The U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) and Toxic Substances Hydrology Programs conducted the National Mercury Pilot Study in 1998 to examine relations of mercury (Hg) in water, bed sediment and fish in streams across the United States, including Alaska and Hawaii. Water and bed-sediment samples were analyzed for total Hg (THg), methylmercury (MeHg), and other constituents; fish were analyzed for THg. Similar sampling was conducted at additional streams across the country in 2002 and 2004-05. This report summarizes sample collection and processing protocols, analytical methods, environmental data, and quality-assurance data for stream water, bed sediment, and fish for these national studies. To extend the geographic coverage of the data, this report also includes four regional USGS Hg studies conducted during 1998-2001 and 2004. The environmental data for these national and regional Hg studies are provided in an electronic format.

Data Series

Total Mercury, Methylmercury, and Ancillary Water-Quality and Streamflow Data for Selected Streams in Oregon, Wisconsin, and Florida, 2002-06

Field and analytical methods, mercury and ancillary water-quality data, and associated quality-control data are reported for eight streams in Oregon, Wisconsin, and Florida from 2002 to 2006. The streams were sampled as part of a U.S. Geological Survey National Water-Quality Assessment Program study of mercury cycling, transport, and bioaccumulation in urban and nonurban stream ecosystems that receive mercury predominantly by way of atmospheric deposition.

Data Series

Total mercury, methylmercury, methylmercury production potential, and ancillary streambed-sediment and pore-water data for selected streams in Oregon, Wisconsin, and Florida, 2003-04

Mercury contamination of aquatic ecosystems is an issue of national concern, affecting both wildlife and human health. Detailed information on mercury cycling and food-web bioaccumulation in stream settings and the factors that control these processes is currently limited. In response, the U.S. Geological Survey (USGS) National Water-Quality Assessment Program (NAWQA) conducted detailed studies from 2002 to 2006 on various media to enhance process-level understanding of mercury contamination, biogeochemical cycling, and trophic transfer. Eight streams were sampled for this study: two streams in Oregon, and three streams each in Wisconsin and Florida. Streambed-sediment and pore-water samples were collected between February 2003 and September 2004. This report summarizes the suite of geochemical and microbial constituents measured, the analytical methods used, and provides the raw data in electronic form for both bed-sediment and pore-water media associated with this study.

Oregon, Wisconsin, Florida

Discrete and continuous water-quality data and hydrologic parameters from seven agricultural watersheds in the United States, 2002-09

Field and analytical methods; discrete organic and non-organic water-quality data and associated quality-control data; and continuous hydrologic and water-quality parameters are reported for sites in California, Indiana, Iowa, Maryland, Mississippi, Nebraska, and Washington. The sites were sampled as part of the U.S. Geological Survey National Water-Quality Assessment Program?s Agricultural Chemicals Team study to better understand how environmental processes and agricultural practices interact to determine the transport and fate of agricultural chemicals in the environment.

Data Series

Acetamide herbicides and their degradation products in ground water and surface water of the United States, 1993-2003

During 1993 through 2003, the U.S. Geological Survey conducted a number of studies to investigate and document the occurrence, fate, and transport of acetamide herbicides and their degradation products in ground and surface water. As part of these studies, approximately 5,100 water samples were collected and analyzed for the acetamide parent herbicides acetochlor, alachlor, dimethenamid, flufenacet, and metolachlor and their degradation products ethanesulfonic acid, oxanilic acid, and sulfinyl acetic acid. During this period, various analytical methods were developed to detect and measure concentrations of acetamide herbicides and their degradation products in ground water and surface water. Results showed that the degradation products of acetamide herbicides in ground water were detected more frequently and occurred at higher concentrations than their parent compounds. Further study showed that the acetamide herbicides and their degradation products were detected more frequently in surface water than in ground water. In general, the parent compounds were detected at similar or greater frequencies than the degradation products in surface water. The developed methods and data were valuable for acquiring information about the occurrence, fate, and transport of the herbicides and their degradation products and the importance of analyzing for both parent compounds and their degradate products in water-quality studies.

Data Series

Geochronology of Cenozoic rocks in the Bodie Hills, California and Nevada

The purpose of this report is to present geochronologic data for unaltered volcanic rocks, hydrothermally altered volcanic rocks, and mineral deposits of the Miocene Bodie Hills and Pliocene to Pleistocene Aurora volcanic fields of east-central California and west-central Nevada. Most of the data presented here were derived from samples collected between 2000–13, but some of the geochronologic data, compiled from a variety of sources, pertain to samples collected during prior investigations. New data presented here (tables 1 and 2; Appendixes 1–3) were acquired in three U.S. Geological Survey (USGS) 40 Ar/ 39 Ar labs by three different geochronologists: Robert J. Fleck (Menlo Park, CA), Lawrence W. Snee (Denver, CO), and Michael A. Cosca (Denver, CO). Analytical methods and data derived from each of these labs are presented separately. The middle to late Miocene Bodie Hills volcanic field (BHVF) is a large (>700 km 2 ), long-lived (~9 million years [m.y.]), episodic eruptive complex (John and others, 2012) in the southern segment of the ancestral Cascades arc (du Bray and others, written commun., 2015) north of Mono Lake and east of Bridgeport, California (fig. 1). The field is near the west edge of the Walker Lane and the northwest edge of the Mina deflection where structures related to these shear zones may have localized magmatism. The Walker Lane (fig. 1) is a broad, northwest-striking zone of right-lateral shear that accommodates right-lateral motion between the Pacific and North America plates; the Mina deflection constitutes a 60-km-long right step in the Walker Lane (Faulds and Henry, 2008; Oldow, 1992, 2003; Stewart, 1988). The Bodie Hills volcanic field includes at least 31 volcanic rock units erupted from 21 significant volcanic eruptive centers. Four trachyandesite stratovolcanoes developed along the margins of the volcanic field and numerous silicic trachyandesite to rhyolite flow dome complexes erupted more centrally. Volcanism in the Bodie Hills volcanic field peaked at two periods, ~15.0 to 12.6 million years before present (Ma) and ~9.9 to 8.0 Ma, which were dominated by emplacement of large stratovolcanoes and large silicic trachyandesite-dacite lava domes, respectively. A final period of small-volume silicic dome emplacement began in the western part of the volcanic field at ~6 Ma and culminated at ~5.5 Ma (John and others, 2012).

California, Nevada