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At least 397 records · Page 22Linked to original sources
USGS1989

Geochemical expression of early diagenesis in middle Eocene-lower Oligocene pelagic sediments in the southern Labrador Sea, Site 647, ODP Leg 105

Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below sea floor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this depositional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic inability in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was mediated by high sedimentation rates (36 m/m.Y.). High iron (Fe) and manganese (Mn) contents are associated with carbonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (CO2) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biagenic opal, much of which is now altered to smectite and/or opal CT. An increase in the sodium/potassium (Na/K) ratio in the upper Eocene corresponds to the beginning of coarser-grained feldspar flux to the site, possibly marking the onset of more vigorous deep currents. Although the Site 647 cores provide a nearly complete high-resolution, high-latitude Eocene-Oligocene record, the high sedimentation rate and somewhat unusual diagenetic conditions have led to variable alteration of benthic foraminifers and fine-fraction carbonate and have overprinted the original stable-isotope records. Planktonic foraminifers are less altered, but on the whole, there is little chance of sorting out the nature and timing of environmental change on the basis of our stable-isotope analyses.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS2015

Soil nitrogen accretion along a floodplain terrace chronosequence in northwest Alaska: Influence of the nitrogen-fixing shrub Shepherdia canadensis

Nitrogen enters terrestrial ecosystems through multiple pathways during primary succession. We measured accumulation of total soil nitrogen and changes in inorganic nitrogen (N) pools across a 300-y sequence of river terraces in northwest Alaska and assessed the contribution of the nitrogen-fixing shrub Shepherdia canadensis . Our work compared 5 stages of floodplain succession, progressing from a sparsely vegetated silt cap to dense shrubby vegetation, balsam poplar-dominated ( Populus balsamifera ) and white spruce-dominated ( Picea glauca ) mixed forests, and old-growth white spruce forest. Total soil N (0–30 cm depth) increased throughout the age sequence, initially by 2.4 g N·m −2 ·y −1 during the first 120 y of terrace development, then by 1.6 g N·m −2 ·y −1 during the subsequent 2 centuries. Labile soil N, measured by anaerobic incubation, increased most rapidly during the first 85 y of terrace formation, then remained relatively constant during further terrace development. On recently formed terraces, Shepherdia shrubs enriched soil N pools several-fold compared to soil beneath Salix spp. shrubs or intercanopy sites. Total and labile soil N accretion was proportional to Shepherdia cover during the first century of terrace development, and mineral soil δ 15 N content indicated that newly formed river terraces receive substantial N through N-fixation. About half the 600 g total N·m −2 accumulated across the river terrace chronosequence occurred during the 120 y when S. canadensis was dominant. Sediment deposited by periodic flooding continued to add N to terrace soils after the decline in Shepherdia abundance and may have contributed 25% of the total N found in the floodplain terrace soils.

Alaska↗
USGS2004

Pocomoke Sound Sedimentary and Ecosystem History

Summary of Results: Pocomoke Sound Sediment and Sediment Processes Transport of sediment from coastal marshes. Analyses of pollen and foraminifera from surface sediments in Pocomoke Sound suggest that neither the upstream forested wetlands nor coastal marshes bordering the sound have contributed appreciably to particulate matter in the 10- to 1000-micron size range that is currently being deposited in the sound. Sediment processes derived from short-lived isotope. Analyses of beryllium-7, cesium-137 and lead-210 and redox sensitive elements from Pocomoke sediments showed that there has been a significant increase in anthropogenic elements since the late 1940's when the Delmarva Peninsula became more accessible from the Baltimore-Washington region. Cesium-137 was found to be a useful tool to determine changes in sedimentation within the system. Three major stages of sedimentation occurred. Before 1950, the system was equilibrium with the agriculture activity in the watershed, whereas urbanization and agricultural activity changes during and immediately preceding World War II resulted in increased sediment flux. Around 1970, the sediment flux diminished and there was an apparent increase in bank erosion sediment to the deeper parts of the system. Rates of sediment deposition. Radiocarbon, lead-210, and pollen dating of sediment cores from Pocomoke Sound indicate relatively continuous deposition of fine-grained sediments in the main Pocomoke channel at > ~7 m water depths. Mean sediment accumulation rates during the past few centuries were relatively high (>1 cm yr -1 ). The ages of coarser-grained sediments (sands) blanketing the shallow (< ~ 7 m water depth) flanks of Pocomoke Sound are not well constrained but were probably deposited discontinuously. Impacts of land-use on benthic biota. The Pocomoke Sound paleoecological record shows that in the 1940-50s and again in the 1970-80s, the sound experienced unprecedented changes in the benthic assemblages of both ostracodes and foraminifera that can be attributed to degradation in water quality. These changes represent perturbations to the natural variability in faunal assemblages, which are normally driven by climatically influenced changes in salinity regimes. Changes in 20th century benthic communities were characterized by the rise to dominance of facultative anaerobic taxa tolerant of hypoxia and detrital-feeding species, reflecting increased influx of organic matter, and perhaps greater turbidity. Results support the hypothesis of Orth et al. (2002) and Orth and Moore (1983) that unprecedented changes to the bay ecosystem affected submerged aquatic vegetation in the Tangiers-Pocomoke region prior to large-scale monitoring began in the 1970s and 80s. Comparison of Pocomoke paleoecological record with those from the mainstem bay indicate that environmental degradation during the 20th century was nearly synchronous bay-wide within the limits of sediment core chronology (10-20 years). Stable isotopic evidence for decadal water quality changes. Stable isotopic records from benthic foraminifera in Pocomoke Sound sediment cores, especially oxygen isotopes, document regional decadal and centennial climate processes which influence salinity and water quality over the past few centuries. These results provide indirect evidence for discharge-driven changes in freshwater and presumably river-borne sediment from the watershed to the sound. They are consistent with studies in the mainstem indicating the important influence of climatic and hydrological processes on water quality. Pollen evidence for high sedimentation and vegetation change during colonial land clearance. Pollen assemblages from sediment cores in Pocomoke Sound document high sedimentation rates (0.7->4.0 cm yr -1 ) at most sites throughout the Sound in post-Colonial time. These results confirm those from other regions of the bay that land-clearance increased the flux of river-borne sediment to certain r

Open-File Report↗
USGS2007

Age Determination of the Remaining Peat in the Sacramento-San Joaquin Delta, California, USA

Introduction The Sacramento-San Joaquin Delta of California was once a 1,400 square kilometer (km2) tidal marsh, which contained a vast layer of peat ranging up to 15 meters (m) thick (Atwater and Belknap, 1980). Because of its favorable climate and highly fertile peat soils, the majority of the Delta was drained and reclaimed for agriculture during the late 1800s and early 1900s. Drainage of the peat soils changed the conditions in the surface layers of peat from anaerobic (having no free oxygen present) to aerobic (exposed to the atmosphere). This change in conditions greatly increased the decomposition rate of the peat, which consists largely of organic (plant) matter. Thus began the process of land-surface subsidence, which initially was a result of peat shrinkage and compaction, and later largely was a result of oxidation by which organic carbon in the peat essentially vaporized to carbon dioxide (Deverel and others, 1998; Ingebritsen and Ikehara, 1999). Because of subsidence, the land-surface elevation on farmed islands in the Delta has decreased from a few meters to as much as 8 m below local mean sea level (California Department of Water Resources, 1995; Steve Deverel, Hydrofocus, Inc., written commun., 2007). The USGS, in collaboration with the University of California at Davis, and Hydrofocus Inc. of Davis, California, has been studying the formation of the Delta and the impact of wetland reclamation on the peat column as part of a project called Rates and Evolution of Peat Accretion through Time (REPEAT). The purpose of this report is to provide results on the age of the remaining peat soils on four farmed islands in the Delta.

Open-File Report↗
USGS2009

Thatcher Bay, Washington, Nearshore Restoration Assessment

The San Juan Archipelago, located at the confluence of the Puget Sound, the Straits of Juan de Fuca in Washington State, and the Straits of Georgia, British Columbia, Canada, provides essential nearshore habitat for diverse salmonid, forage fish, and bird populations. With 408 miles of coastline, the San Juan Islands provide a significant portion of the available nearshore habitat for the greater Puget Sound and are an essential part of the regional efforts to restore Puget Sound (Puget Sound Shared Strategy 2005). The nearshore areas of the San Juan Islands provide a critical link between the terrestrial and marine environments. For this reason the focus on restoration and conservation of nearshore habitat in the San Juan Islands is of paramount importance. Wood-waste was a common by-product of historical lumber-milling operations. To date, relatively little attention has been given to the impact of historical lumber-milling operations in the San Juan Archipelago. Thatcher Bay, on Blakely Island, located near the east edge of the archipelago, is presented here as a case study on the restoration potential for a wood-waste contaminated nearshore area. Case study components include (1) a brief discussion of the history of milling operations. (2) an estimate of the location and amount of the current distribution of wood-waste at the site, (3) a preliminary examination of the impacts of wood-waste on benthic flora and fauna at the site, and (4) the presentation of several restoration alternatives for the site. The history of milling activity in Thatcher Bay began in 1879 with the construction of a mill in the southeastern part of the bay. Milling activity continued for more than 60 years, until the mill closed in 1942. Currently, the primary evidence of the historical milling operations is the presence of approximately 5,000 yd3 of wood-waste contaminated sediments. The distribution and thickness of residual wood-waste at the site was determined by using sediment coring and GIS-based interpolation techniques. Additionally, pilot studies were conducted to characterize in place sediment redox, organic composition, and sulfide impacts to nearshore flora and fauna. We found that the presence of wood-waste in Thatcher Bay may alter the quality of the benthic habitat by contributing to elevated levels of total organic composition (TOC) of the sediment. Increased TOC favors anaerobic respiration in marine sediments, and sulfide, a toxic by-product of this process, was found at levels as high as 17.5 mg L-1 in Thatcher Bay. The Thatcher Bay sulfide levels are several orders of magnitude higher than those known to impact benthic invertebrates. Eelgrass, Zostera marina, located on the western margin of Thatcher Bay, was surveyed by using underwater video surveys. This baseline distribution will in part be used to measure the impact of any future remediation efforts. Additionally, the distribution and survey data can provide an estimate of propagule source for future colonization of restored sediment. Three restoration alternatives were considered, and a ranking matrix was developed to score each alternative against site-specific and regional criteria. The process identified the removal of wood-waste from a water-based platform as the preferred alternative. Our multidisciplinary investigation identified the location, thickness, and potential impacts of wood-waste that has persisted in the nearshore environment of Thatcher Bay since at least 1942. We also provide a process to efficiently evaluate alternatives to remediate the impact of this historical disturbance and to potentially contribute to an increase of nearshore diversity and productivity at this site. Elements of this approach could inform restoration planning at similarly impacted sites throughout the region.

Open-File Report↗
USGS2016

Relation between Enterococcus concentrations and turbidity in fresh and saline recreational waters, coastal Horry County, South Carolina, 2003–04

Bacteria related to the intestinal tract of humans and other warm-blooded animals have been detected in fresh and saline surface waters used for recreational purposes in coastal areas of Horry County, South Carolina, since the early 2000s. Specifically, concentrations of the facultative anaerobic organism, Enterococcus , have been observed to exceed the single-sample regulatory limit of 104 colony forming units per 100 milliliters of water. Water bodies characterized by these concentrations are identified on the 303(d) list for impaired water in South Carolina; moreover, because current analytical methods used to monitor Enterococcus concentrations take up to 1 day for results to become available, water-quality advisories are not reflective of the actual health risk. To determine if Enterococcus concentrations in surface water could be assessed in a more rapid manner, an investigation was completed between 2003 and 2004 in the study area of coastal Horry County, South Carolina. The study was designed to assess the relation between Enterococcus concentrations and turbidity, which, unlike Enterococcus concentrations, can be measured continuously by using a multiparameter water-quality sensor and results reported in real time. In 2003, three water-quality data collection stations that included a multiparameter water-quality sensor that measured turbidity were located in three representative surface-water basins in coastal Horry County, South Carolina. All these locations had previous reports of high Enterococcus concentrations. At each station, the water-quality sensor was placed in the water column and continuously measured turbidity, pH, specific conductivity, dissolved oxygen, and temperature. Each water-quality data collection station also monitored instantaneous precipitation and wind speed and direction. Surface-water samples were collected at each station during events characterized by no precipitation and by some recorded precipitation using manual and automatic methods, and analyzed for Enterococcus concentrations. A comparison of Enterococcus concentrations in surface-water samples collected simultaneously using both methods indicated a positive relation, although the average percent relative difference between the methods was 46 percent. During a period of no precipitation in February 2004, no relation between turbidity and Enterococcus concentrations was observed for surface-water samples collected at the water-quality data collection station located in the channel that drains a freshwater swamp. In contrast, during periods of precipitation in March and August 2004 at this location, a positive relation was observed between turbidity and Enterococcus concentrations in surface-water samples; that is, water samples characterized by higher turbidity also contained higher Enterococcus concentrations. At the water-quality data collection station located in a channel that drains to the surf zone of the Atlantic Ocean, no relation was observed between turbidity and Enterococcus concentrations during periods of either no precipitation (July 2004) or precipitation (August 2004). At this location, the turbidity was inversely related to relative tide height, high turbidity was observed during low tide when freshwater flowed seaward, and low turbidity was observed during high tide when saline seawater flowed landward. The positive relation observed between turbidity and Enterococcus concentrations in surface water at the water-quality data collection station located in the channel that drains a freshwater swamp may be attributed to bacterial survival in the abundant channel bed sediments that characterized this more naturalized area. Surface-water bed sediments collected near each water-quality data collection station and the surf zone were incubated in static microcosms in the laboratory and analyzed for Enterococcus concentrations over time. Enterococcus concentrations continued to persist in bed sediments collected in the channel that drains the swamp even after almost 4 months of incubation. Conversely, enterococci were not observed to persist in bed sediments characterized by high specific conductance. Although it is currently (2016) unknown whether this persistence of enterococci demonstrates growth or viability, the data indicate that enterococci can exist in channel bed-sediment environments outside of a host for a long time. This observation confirms previous reports that challenge the use of Enterococcus concentrations as an indicator of the recent introduction of fecal-related material and the associated acute risk to other pathogens.

South Carolina↗
USGS1965

Hot brines and recent iron deposits in deeps of the Red Sea

Sedimentary iron and heavy-metal deposits of undetermined size have been found in the middle of the Red Sea some 2000 meters below the surface of the sea. This discovery has been made from the Research Vessel Atlantis II , which is still at sea engaged in a series of oceanographic investigations which ultimately will end in November 1965, after the ship has circumnavigated the globe. The discovery is significant because the environment and the processes controlling deposition of heavy metals are observable and appear to be still active. The environment of the deposits can be breiefly described as an isolated sub-marine pool of brine having a pH as low as 5.3, a temperature of 56° c. and a salt content of about 310 grams per liter (at 20° c). Shipboard oxygen determinations and the indicated presence of H 2 S, divalent iron and divalent manganese in the water suggest that the environment is anaerobic. This hot, dense brine is trapped in a local depression of the Red Sea median valley. (Atlantis II Deep). The iron deposits, consisting largely of hydrous iron oxides, are found in the same depression. Brines from the Discovery Deep (21° 17 1 N, 38° 02'E) (1), a few miles southwest of the Atlantis II Deep (21°21 1 N, 38 ° 04'E), have a pH of 6.2 and a temp­erature of 44.7° c, and are also associated with iron-bearing sedirnents. The Discovery and Atlantis II brine pools both extend about 150 meters above the bottom. A few miles south of the: Discovery Deep another depression of greater depth has been reported (2) containing essentially normal Red Sea water. Deeps several hundred miles to the north (Sta. 540) and south (Sta. 545) were investigated and contained no brine. One of these (Sta. 545) is known to contain normal sediments.

Open-File Report↗
USGS1972

Limnological studies of Big Bear Lake, California

Big Bear Lake exhibited seasonal changes in physical, chemical, and biological variables from June 1968 to June 1969. Dissolved-oxygen concentrations were depressed during the summer resulting in anaerobic conditions near the bottom of the lake. Water temperature decreased with depth in spring and summer, although classical thermal stratification was not observed. The nutrient standing crop was sufficient to maintain two distinct seasonal phytoplankton blooms. There were phytoplankton growth periods during the winter of 1968 and the summer of 1969, but the maximum populations that were observed were not excessive. During the study Big Bear Lake exhibited periods of biochemical stress symptomatic of organically enriched lakes; however, no attempt was made to determine the magnitude or rate of the eutrophicational processes occurring in the lake.

California↗
USGS1978

Effect of controlled land application of sludge on ground-water quality, Ocean County, New Jersey

Percolation of contaminants from the controlled land application of domestic anaerobic digested liquid sludge has affected the quality of ground water in the highly permeable unconfined Miocene Cohansey Sand aquifer at Colliers Mills and Webbs Mill areas of the Pine Barrens region in Ocean County, New Jersey. The sludge, containing five percent solids, was applied to three soil types, the Downer, Lakewood, and Woodmansie series, at rates of 10, 20, and 40 tons per acre (22.4, 44.8, and 89.6 metric tons per hectare) per year for the growing seasons 1973-75. Contaminant concentration reached a peak at the water table in a cyclic pattern in response to peak recharge from precipitation during the cool months from November to April. The nature and occurrence of the contaminated ground water, which is moving at estimated rates of 1.1 to 1.6 feet (0.33 to 0.48 m) per day at Colliers Mills and 0.62 to 0.69 feet (0.19 to 0.21 m) per day at Webbs Mill, has been identified by comparing changes in concentration and distribution, above background levels, of specific conductance, nitrate-nitrogen, and chloride. Contamination of ground water has occurred under all plots receiving sludge application and the degree of contamination is generally directly related to the application rates. At the 40 ton per acre per year (89.6 metric ton per hectare per year) application rate the nitrate-nitrogen concentration increased from a background level of 2.4 milligrams per liter to a peak of 93.3 milligrams per liter at the Downer soil site, from 2.0 milligrams per liter to a peak of 98 milligrams per liter at the Lakewood soil site, and from 5.0 milligrams per liter to a peak of 54 milligrams per liter at the Woodmansie soil site. At the minimum application rate of 10 ton per acre per year (22.4 metric ton per hectare per year) the nitrate-nitrogen concentration increased from a background level of 2.4 milligrams per liter to 11.6 milligrams per liter at the Downer soil site, from 2.0 milligrams per liter to 10 milligrams per liter at the Lakewood soil sites and from 5.0 milligrams per liter to 38 milligrams per liter at the Woodmansie soil site. Under continuous sludge application at these soil sites, the contaminant concentration in ground water is expected to increase in relative proportion to loading rates. Contamination will also continue after the cessation of sludge application as long as the residual layer contains excess quantities of soluble sludge constituents.

New Jersey↗
USGS1978

Dissolved-oxygen depletion and other effects of storing water in Flaming Gorge Reservoir, Wyoming and Utah

The circulation of water in Flaming Gorge Reservoir is caused chiefly by insolation, inflow-outflow relationships, and wind, which is significant due to the geographical location of the reservoir. During 1970-75, there was little annual variation in the thickness, dissolved oxygen, and specific conductance of the hypolimnion near Flaming Gorge Dam. Depletion of dissolved oxygen occurred simultaneously in the bottom waters of both tributary arms in the upstream part of the reservoir, and was due to reservoir stratification. Anaerobic conditions in the bottom water during summer stratification eventually results in a metalimnetic oxygen minimum in the reservoir.

Utah, Wyoming↗
USGS1979

Origin of marcasite and its implications regarding the genesis of roll-front uranium deposits

Study of five roll-type uranium deposits (three in Texas and two in Wyoming) has resulted in the recognition of ore-stage marcasite in each deposit. Ore-stage marcasite is identified by its close association with uranium- and vanadium-bearing phases in the ore zones; by its close association with ferroselite at and near the redox boundary in some deposits; by its abundance and distribution across deposits; and by its textural relationships with identifiable pre-ore iron disulfide minerals (primarily pyrite). In deposits that are essentially devoid of fossil vegetal debris, marcasite is the dominant ore-stage sulfide and occurs in a large volume of rock beyond the ore zones. In deposits that contain organic matter, ore-stage pyrite is at least as abundant as ore-stage marcasite. Many factors and processes may lead to the formation of either marcasite or pyrite as an ore-stage mineral in roll-type deposits. One of the dominant factors is the complex interrelationship of pH and sulfur species that are precursors of iron-disulfide minerals. Experimental work and study of geochemical environments analogous to those governing the formation of roll-type deposits indicate that relatively low pH (less than about six) and the presence of elemental sulfur favor marcasite, whereas higher pH and the presence of polysulfide ions favor pyrite. Conditions that favor marcasite as the dominant ore-stage iron disulfide are likely to arise during uranium deposition in host rock without fossil vegetal matter. In host rock containing carbonaceous debris, the presence of polysulfide ions and pH buffering any anaerobic bacterial metabolic processes apparently lead to the formation of ore-stage pyrite.

Open-File Report↗
USGS1983

Hydrology of the Price River basin, Utah, with emphasis on selected coal-field areas

Data obtained during a hydrologic study of the Price River basin, Utah, are used to describe seasonal variations of flow of springs, relation between ground water and surface water, hydraulic properties of the ground-water reservoir, ground-water recharge and discharge, flood characteristics of streams, mineralogic composition and depositional rates of sediments, nutrient and inorganic loading in streams and Scofield Reservoir, and water budgets for selected basins. Additional study and monitoring are needed to detect possible hydrologic changes caused by coal mining. Much of the ground-water discharge from the Star Point Sandstone in the Mesaverde Group in the Wasatch Plateau occurs along faults. In the Book Cliffs, where faulting is less extensive, most of the ground-water discharge is from the Flagstaff Limestone. The Flagstaff Limestone is greatly diffusive, has a small storage coefficient, and contains water which is perched. Springs issuing from the Star Point Sandstone in the Mud Creek drainage (Wasatch Plateau) had recession indexes greater than 365 days per log cycle. Springs issuing at higher altitudes from the Colton Formation and the Flagstaff Limestone in the Soldier Creek area (Book Cliffs) have great seasonal variability, with recession indexes ranging from 24 to 115 days per log cycle. Estimated transmissivities in the Soldier Creek area ranged from 0.003 foot squared per day in the lower part of the Castlegate Sandstone to 0.07 foot squared per day in the Price River Formation. Seepage from the Star Point Sandstone is the major contributor to base flow of the stream in Eccles Canyon (Wasatch Plateau). Gains of as much as 230 gallons per minute occurred near a fault zone which crosses Eccles Canyon at the junction with South Fork Canyon. The potentiometric surface of water in the Blackhawk Formation in the Wasatch Plateau (Mud Creek drainage) and the Book Cliffs (Soldier Creek area) generally is above the coal zones, and dewatering will be necessary in most places during mining. The total reported mine discharge during 1980 was about 2,800 acre-feet. During the 1980 water year, ground-water discharge from the Flagstaff Limestone contributed about 4,400 acre-feet, or 41 percent of the combined streamflow of Coal, Soldier, and Dugout Creeks. Discharge from the Blackhawk and other formations contributed about 2,200 acre-feet, or 21 percent of the streamflow. The recharge to a 4,020-acre outcrop of the Flagstaff Limestone in the Soldier Creek area was determined from measurements of the discharge of springs and seepage gains in streams. The estimated recharge was 2 inches per year, or 12 percent of the April 1 snowpack, or 9 percent of the precipitation during 1980. Benthic-diversity indexes at streams in the Book Cliffs and Wasatch Plateau are related to the size of the bed material. The Shannon-Weiner diversity index for five sites in the Mud Creek drainage ranged from 1.57 to 4.20 during four sampling periods in 1979-80. In the Soldier Creek drainage, the diversity index for four sampling sites ranged from 0.8 to 2.3 during three sampling periods in 1979-80. Sediment deposition in Scofield Reservoir during 1943-79 was estimated to be 3,000 acre-feet but most of the coal deposition in the reservoir occurred prior to about 1950. An anaerobic zone develops in the reservoir during the summer, but the water in the reservoir completely mixes during late summer or early fall.

Utah↗
USGS1985

Chemical and biological quality of selected lakes in Ohio, 1978 and 1979

Twenty-eight Ohio lakes were sampled by the U.S. Geological Survey and the Ohio Environmental Protection Agency for water-quality characteristics during the spring and summer of 1978 and 1979. This report is the third in a series covering a lake-sampling program that began in 1975. Data include water-column profiles of temperature, dissolved oxygen, pH, and specific conductance. Chemical, physical, and biological properties were measured at specific points in the water column, and selected physical and chemical properties also were measured in the principal inflows. The lakes were predominatly hard (120 180 milligrams per liter) to very hard water, although several soft-water lakes were found in southeastern Ohio. Calcium, bicarbonate, and sulfate were the principal dissolved constituents. Specific conductance ranged from 103 micromhos per centimeter (at 25 degrees Celsius) at Tycoon Lake, 1978, to 2,550 micromhos per centimeter at West Fork Mill Creek Lake, 1978. Thirteen lakes had trace-element concentrations that were above the limits for exceptional warm-water habitat recammended by the Ohio Environmental Protection Agency. Seasonal thermal gradients developed in most lakes deeper than 17 feet. Oxygen concentrations were zero or near zero during the summer sampling of the bottom water of all lakes having definite thermal gradients. Most anaerobic zones contained hydrogen sulfide and high concentrations of ammonia. All lakes were evaluated and classified by Carlson's trophic state index. Most of the lakes were classified as eutrophic. Blue-green algae (CyanophytaJ) dominated the summer algal communities. Fecal colifrom counts were within Ohio standards, although high (more than 1,000 colonies per 100 milliliters) fecal colifrom and fecal streptococcus counts were observed in West Fork Mill Creek Lake after significant runoff.

Open-File Report↗
USGS1984

Movement and fate of creosote waste in ground water, Pensacola, Florida; U.S. Geological Survey toxic waste--ground-water contamination program

In 1983, the U.S. Geological Survey, Office of Hazardous Waste Hydrology, selected the former American Creosote Works site near Pensacola, Florida as a national research demonstration area. Seventy-nine years (1902-81) of seepage from unlined discharge impoundments had released creosote, diesel fuel, and pentachlorophenol (since 1950) wastes into the ground-water system. A cluster of from 2 to 5 wells constructed at different depths at 9 sites yielded water which revealed contamination 600 feet downgradient and to a depth of 100 feet below land surface near the site. The best cross-sectional representation of the contaminant plume was obtained from samples collected and analyzed for oxidation-reduction sensitive inorganic chemical constituents. Energy dispersive x-ray fluorescence detected recently formed iron carbonate in soil samples from highly reducing ground-water zones. Approximately eighty specific organic contaminants were isolated from ground-water samples by gas-chromotography/mass spectrometry. Column studies indicate the dimethyl phenols are not sorbed or degraded by the sand-and-gravel aquifer materials. Five of nineteen individual phenolic and related compounds are biodegradable based on anaerobic digestor experiments with ACW site bacterial populations. The potential impacts in the nearby Pensacola Bay biotic community are being evaluated. (USGS)

Open-File Report↗
USGS1984

Assessment of ground-water contamination by coal-tar derivatives, St. Louis Park area, Minnesota

Operation of a coal-tar distillation and wood-preserving facility in St. Louis Park, Minnesota, during 1918-72 contaminated ground water with coal-tar derivatives and inorganic chemicals. Coal-tar derivatives entered the groundwater system through three major paths: (1) Spills and drippings that percolated to the water table, (2) surface runoff and plant process water that was discharged to wetlands south of the former plant site, and (3) movement of coal tar directly into bedrock aquifers through a multiaquifer well on the site. In the drift, Platteville, and St. Peter aquifers, ground water flows laterally from west to east and vertically downward. Near the former plant site, creosote-like organic fluids have migrated vertically downward through the drift and are being partially dissolved by ground water. Ground water has preferentially mobilized low-molecular-weight compounds such as phenolic compounds, alkyl-benzenes, and naphthalene, although polynuclear aromatic hydrocarbons as heavy as benzo(a)pyrene have been mobilized at low concentrations. Sorption of high-molecular-weight compounds has retarded their migration down the hydraulic gradient compared to low-molecular-weight compounds in the plume. Some simple phenolic compounds are being degraded to methane and carbon dioxide by bacteria under anaerobic conditions in the drift-PlattevilleSt. Peter aquifer system. Other low-molecular-weight aromatic compounds are apparently being degraded by aerobic bacteria at the periphery of the plume where oxygen is available. Intermediate degradation products such as volatile fatty acids are likely present, but complete conversion of the organic contaminants to innocuous inorganic substances has not been demonstrated. Near and south of 36th and Wooddale Avenues, contaminants enter the St. Peter aquifer where the Glenwood confining unit has been eroded in a buried bedrock valley. Contaminants previously entered the Prairie du Chien-Jordan aquifer through at least one multiaquif er well (W38). Other sources of contaminants and the low concentrations of contaminants hamper delineation of the maximum areal extent of contaminants that are resistant to biologic degradation. These biorefractory compounds will probably continue to migrate down the hydraulic gradients in the drift and Platteville and St. Peter aquifers. Of particular concern with respect to the health risk to humans are the polynuclear aromatic hydrocarbons, which are a major constituent of coal tar and are found in municipal wells near the site that are completed in the Prairie du Chien-Jordan aquifer. The Prairie du Chien-Jordan aquifer lies 250 to 500 feet below land surface and is relatively well protected from nearsurface sources of contamination by overlying rocks. However, the aquifer has been contaminated since at least 1932 because coal-tar derivatives have entered the aquifer through multiaquifer wells. The most significant single source of contamination in the aquifer is a well drilled on the site in 1917 (well W23) that has contained liquid coal-tar since at least 1958. The introduction, dissolution, and movement of this coal-tar in ground water has contaminated nearby municipal wells. The composition of the tar in well W23, and the ratio of concentrations of individual compounds in water from well W23 to those in municipal well SLP15, are consistent with known hydrologic, chemical, and biologic processes, and the conclusion that contaminants in well SLP15 are due primarily to contaminants introduced at well W23. Most of the major polynuclear aromatic hydrocarbons in the tar, although slightly soluble in water and strongly sorbed by aquifer materials, have moved greater distances at higher concentrations than have the lower-molecular-weight, more soluble compounds such as phenolic compounds and naphthalene. The latter are apparently being degraded by bacteria. The direction and rate of contaminant movement within the Prairie du Chien-Jordan aquifer changes with time because the ground-water-flow system continually adjusts to hydraulic stresses caused by ground-water withdrawals and flow through multiaquifer wells. Contaminants can move rapidly through the Prairie du Chien-Jordan because the upper part of the aquifer is a carbonate rock having fracture and solution-channel permeability, low effective porosity, and relatively small surface area for sorption. Consequently, the concentration and composition of contaminants in water pumped from individual industrial and municipal wells completed in the aquifer fluctuate with time. Although contaminants have been in the aquifer for at least 50 years and their spatial distribution is complex, concentrations remain highest near their points of introduction through multiaquifer wells near and on the site of the former plant. Contaminants reached the Ironton-Galesville aquifer through at least two deep multiaquifer wells (W23 and W38), but the extent of contamination in this aquifer, and in the underlying Mount Simon-Hinckley aquifer, is not known.

Minnesota↗
USGS1987

Movement and fate of crude-oil in contaminants in the subsurface environment at Bemidji, Minnesota: Chapter C in U.S. Geological Survey program on toxic waste--ground-water contamination: Proceedings of the Third technical meeting, Pensacola, Florida, March 23-27, 1987

On August 20, 1979, a pipeline break in a remote area near Bemidji, Minn. (fig. C-l), resulted in the release of 1.5x10 5 L (liters) of crude oil. Although about 1.1x10 5 L were removed from the site as part of the cleanup, some crude oil infiltrated the ground and percolated to the water table. The spill occurred in the recharge area of a local flow system that discharges to a small lake 300 m (meters) downgradient (Hult, 1984). The aquifer is a pitted and dissected outwash plain underlain at a depth of about 20 m by low-permeability till. Crude oil is floating on the water table about 8 m below land surface and has migrated about 20 m as a separate fluid phase. Soluble petroleum derivatives have dissolved in and are moving with ground water. Volatile constituents are migrating through the unsaturated zone by diffusion. The abstracts presented in this chapter provide an overview of ongoing efforts to combine the results of interdependent, interdisciplinary research into the comprehensive understanding of the physical, chemical, and biological processes that will be needed to develop predictive models of contaminant mobilization, transport, and fate. Franzi investigates the relationship between depositional and post-depositional processes and the heterogeneity and anisotropy of the aquifer. Post-depositional subsidence and collapse caused by melting of stagnant ice has created significant geomorphic and hydrogeologic structures. Miller describes a preliminary ground-water flow and chemical-transport model used to assess the effect of these hydrologic discontinuities, estimate aquifer properties, and to guide continuing field work. Abstracts by Siegel, Bennett, and Berndt describe studies of dissolved inorganic constituents and parameters done to characterize the geochemical environments in and around the site. An anoxic zone, probably plume shaped, extends downgradient of the oil pool and into an oxic zone that surrounds the contamination. Carbonate minerals are actively dissolving in the oxic spray zone upgradient of the oil pool where oil is being mineralized, whereas quartz is dissolving underneath the oil by organic-acid complexation. Selective leaching experiments show that fractionation of metals is also occurring where the aquifer matrix is contaminated. Morphological analysis of quartz sand grains clearly show unusual rock-water interactions are occurring in the anaerobic contaminant zone. Preliminary analysis indicates the possibility of an organic/quartz interaction that is significantly increasing the mobility of silica through the system. Predictions of the evolution and ultimate geometry of contaminant plumes resulting from spills require quantitative descriptions of the rate of mass transfer from the organic fluid to ground water. Pfannkuch presents laboratory and field work that describe how the the rate of oil dissolution, and therefore the strength of the contaminant source, is controlled by fluctuations in ground-water velocity and water-table fluctuations.

Minnesota↗
USGS1991

Selected hydrologic data for farmland treated with sewage sludge near Platteville, Colorado, 1985-91

The U.S. Geological Survey, in cooperation with the Metro Wastewater Reclamation District, studied the ground-water-quality effects of the application of anaerobic digested municipal sewage sludge at agronomic rates to farmland near Platteville. Beginning in the fall of 1985, the sludge was injected annually into the sandy farmland in a 1-square-mile area. Generally, water-quality samples were collected from observation wells two or three times during each irrigation season from 1985 through 1990 and once each winter or late spring from 1987 through early 1991. Water levels were measured, and water-quality, soil and soil-moisture samples, and precipitation data were collected at selected sites throughout the study area. This report presents the data collected during 1985-91 from observation wells, irrigation wells, domestic wells, and other selected sites in the study area.

Colorado↗
USGS2004

Fractionation and characterization of organic matter in wastewater from a swine waste-retention basin

Organic matter in wastewater sampled from a swine waste-retention basin in Iowa was fractionated into 14 fractions on the basis of size (particulate, colloid, and dissolved); volatility; polarity (hydrophobic, transphilic, hydrophilic); acid, base, neutral characteristics; and precipitate or flocculates (floc) formation upon acidification. The compound-class composition of each of these fractions was determined by infrared and 13C-NMR spectral analyses. Volatile acids were the largest fraction with acetic acid being the major component of this fraction. The second most abundant fraction was fine particulate organic matter that consisted of bacterial cells that were subfractionated into extractable lipids consisting of straight chain fatty acids, peptidoglycans components of bacterial cell walls, and protein globulin components of cellular plasma. The large lipid content of the particulate fraction indicates that non-polar contaminants, such as certain pharmaceuticals added to swine feed, likely associate with the particulate fraction through partitioning interactions. Hydrocinnamic acid is a major component of the hydrophobic acid fraction, and its presence is an indication of anaerobic degradation of lignin originally present in swine feed. This is the first study to combine particulate organic matter with dissolved organic matter fractionation into a total organic matter fractionation and characterization.

Scientific Investigations Report↗