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USGS2002

Biomonitoring of Environmental Status and Trends (BEST) Program: Environmental contaminants and their effects on fish in the Mississippi River Basin

We collected, examined, and analyzed 1378 fish of 22 species from 47 sites in the Mississippi River basin (MRB) during 1995 and from a reference site in 1996. The sampling sites in the MRB represented National Contaminant Biomonitoring Program (NCBP) stations situated at key points on major rivers and National Water- Quality Assessment Program (NAWQA) stations located on lower-order rivers and streams in the Eastern Iowa Basins (EIB) and Mississippi Embayment (MSE) Study Units. The reference site was the water supply system of the USGS-Leetown Science Center in rural Jefferson County, WV. Common carp (Cyprinus carpio; carp) and black basses (Micropterus spp.; bass), the targeted species, together represented 82% of the fish collected. Each fish was examined in the field for externally and internally visible gross lesions, selected organs were weighed to compute various ponderal and organo-somatic indices, and selected tissues and fluids were obtained and preserved for analysis of biomarkers. Fish health indicators included splenic macrophage aggregates, lysozyme activity, and hispathological analysis of liver, kidney, and other tissues. Reproductive biomarkers included analysis of plasma concentrations of vitellogenin (vtg) and the sex steroid hormones 17-estradiol (E2) and 11-ketotestosterone (11- kt); and the histological determination of percent oocyte atresia (in female fish) and gonadal stage. Hepatic ethoxyresorufin O-deethylase (EROD) activity was also measured. Composite samples of whole fish from each station were grouped by species and gender and analyzed for persistent organochlorine and elemental contaminants and for dioxin-like activity (TCDD-EQ) using the H4IIE rat hepatoma cell bioassay. Organochlorine and inorganic contaminant concentrations in fish were generally low relative to historical levels at most sites, but remained present at concentrations representing threats to piscivorous wildlife in some locations. Toxaphene and DDT (mostly as p,p?-DDE) concentrations remained elevated in fish from the cottongrowing regions of the lower Mississippi valley, and were generally greater in the smaller streams draining agricultural areas (that is, in the MSE Study Unit) than at large river sites. Cyclodiene pesticide concentrations were also greatest in the EIB Study Unit and elsewhere in the corn-growing regions of the mid-MRB. Former point-sources of organochlorine pesticides also remained evident, especially in the Mississippi River near Memphis, TN. Consistent with previous findings, total PCB concentrations tended to be greatest (1-3 g/g) in the industrialized and urbanized Ohio River and Upper Mississippi sub-basins and at Memphis, TN, and were generally correlated with TCDD-EQ and EROD activity. Conversely, PCB concentrations were low (<0.1 g/g) in the more agricultural parts of the MRB. Concentrations of inorganic contaminants were also relatively low and stable or declining relative to past levels at most sites. Exceptions were Hg and Se; Hg concentrations were slightly elevated (>0.3 g/g) in bass from the Mississippi River at Memphis and several other sites and in carp from one MSE site. Concentrations of Se were also great enough to constitute a hazard to piscivorous wildlife (>0.6 g/g) at several MRB sites in the western parts of the MRB and were especially high (4-5 g/g) in fish from John Martin Reservoir, CO, where elevated concentrations were reported previously. Biomarker results indicated that fish from many stations had been exposed to contaminants, but at no sites did findings indicate exposure to high concentrations of toxic chemicals. Noteworthy among biomarker findings was that 73% of the male smallmouth bass (Micropterus dolomieui) from the Mississippi River at Lake City, MN (Lake Pepin) were intersex as indicated by the histological detection of ovotestes; and the combined EROD and H4IIE results indicated that fish from several rural sites in the

Mississippi River basin↗

USGS2020

Citizen scientists record novel leaf phenology of invasive shrubs in eastern U.S. forests

Invasive shrubs are an emergent concern in deciduous forests of eastern North America. Their extended leaf phenology (ELP) – earlier leaf emergence and later leaf off compared to native shrubs and the overstory canopy – can simultaneously provide photosynthetic benefits to invasive shrubs while negatively affecting native flora and fauna through providing novel understory shade when the overstory canopy is leafless. However, phenology varies geographically, and the degree to which ELP from local-scale studies applies across the range of forests experiencing shrub invasion is unknown. In partnership with the USA National Phenology Network, we developed a citizen science campaign to record broad patterns of species-specific ELP – an otherwise prohibitively large effort. Using 1,500 observations of 14 species spanning 4 years, we found that the difference in leaf phenology between native and invasive shrubs can exceed 77 days within a growing season, a gap that decreases with increasing latitude by 2.9 [1.6, 4.2] days per degree latitude in the spring, and 2.2 [0.6,1.9] in the fall. Geographic trends in ELP provide a context for interpreting local scale phenology research while bridging inconsistent findings between existing studies and can streamline management by targeting detection and removal of invasive shrubs with leaves while natives are dormant. Furthermore, even small changes to seasonal phenology can impact forest communities, especially if there is a differential response to climate cues by nativity. After exploring broad-scale environmental variables associated with leaf phenology, we find a similar correlation with pre-growing season warmth for native and invasive shrubs, but a different relationship with dormant chill days – a variable less frequently considered for modeling spring phenology for forest productivity.

Biological Invasions↗

USGS2015

Declining Dioxin concentrations in the Rhone River, France, attest to the effectiveness of emissions controls

Emission-control policies have been implemented in Europe and North America since the 1990s for polychlorodibenzodioxins (PCDDs) and furans (PCDFs). To assess the effect of these policies on temporal trends and spatial patterns for these compounds in a large European river system, sediment cores were collected in seven depositional areas along the Rhone River in France, dated, and analyzed for PCDDs and PCDFs. Results show concentrations increase in the downstream direction and have decreased temporally at all sites during the last two decades, with an average decrease of 83% from 1992 to 2010. The time for a 50% decrease in concentrations (t1/2) averaged 6.9 ± 2.6 and 9.1 ± 2.9 years for the sum of measured PCDDs and PCDFs, respectively. Congener patterns are similar among cores and indicate dominance of regional atmospheric deposition and possibly weathered local sources. Local sources are clearly indicated at the most downstream site, where concentrations of the most toxic dioxin, TCDD, are about 2 orders of magnitude higher than at the other six sites. The relatively steep downward trends attest to the effects of the dioxin emissions reduction policy in Europe and suggest that risks posed to aquatic life in the Rhone River basin from dioxins and furans have been greatly reduced.

Environmental Science & Technology↗

USGS2016

Urban hydrology—Science capabilities of the U.S. Geological Survey

Urbanization affects streamflow characteristics, coastal flooding, and groundwater recharge. Increasing impervious areas, streamflow diversions, and groundwater pumpage are some of the ways that the natural water cycle is affected by urbanization. Assessment of the relations among these factors and changes in land use helps water-resource managers with issues such as stormwater management and vulnerability to flood and drought. Scientists with the U.S. Geological Survey (USGS) have the expertise to monitor and model urban hydrologic systems. Streamflow and groundwater data are available in national databases, and analyses of these data, including identification of long-term streamflow trends and the efficacy of management practices, are published in USGS reports.

Fact Sheet↗

USGS2025

A comprehensive freshwater mussel database for the Duck River Drainage, Tennessee

We have developed a comprehensive database for freshwater mussels for the Duck River drainage in Tennessee, including its largest tributary, the Buffalo River. This database is intended to serve as an expandable template that could be applied statewide. The Duck River is one of the most biologically diverse rivers in the world, with historically over 70 mussel species, and it has been selected as a priority watershed by multiple management and conservation entities. The database for this system compiles over 7,000 mussel records, spanning 200 years, from multiple Federal, State, academic, and private entities, representing 77 native species. The database is spatially explicit and includes temporal and methodological data for each record, and notes of negative survey data were made when possible. The database can facilitate the creation of distribution maps for each species and temporal maps of species richness to show watershed-wide trends. This project addresses the present lack of a centralized mussel database in Tennessee for a critical system. It will be available to facilitate species status assessments, inform conservation planning, and serve as a model for similar databases for other Tennessee watersheds.

Tennessee↗

USGS2014

Long-term trends in alkalinity in large rivers of the conterminous US in relation to acidification, agriculture, and hydrologic modification

Alkalinity increases in large rivers of the conterminous US are well known, but less is understood about the processes leading to these trends as compared with headwater systems more intensively examined in conjunction with acid deposition studies. Nevertheless, large rivers are important conduits of inorganic carbon and other solutes to coastal areas and may have substantial influence on coastal calcium carbonate saturation dynamics. We examined long-term (mid-20th to early 21st century) trends in alkalinity and other weathering products in 23 rivers of the conterminous US. We used a rigorous flow-weighting technique which allowed greater focus on solute trends occurring independently of changes in flow. Increasing alkalinity concentrations and yield were widespread, occurring at 14 and 13 stations, respectively. Analysis of trends in other weathering products suggested that the causes of alkalinity trends were diverse, but at many stations alkalinity increases coincided with decreasing nitrate + sulfate and decreasing cation:alkalinity ratios, which is consistent with recovery from acidification. A positive correlation between the Sen–Thiel slopes of alkalinity increases and agricultural lime usage indicated that agricultural lime contributed to increasing solute concentration in some areas. However, several stations including the Altamaha, Upper Mississippi, and San Joaquin Rivers exhibited solute trends, such as increasing cation:alkalinity ratios and increasing nitrate + sulfate, more consistent with increasing acidity, emphasizing that multiple processes affect alkalinity trends in large rivers. This study was unique in its examination of alkalinity trends in large rivers covering a wide range of climate and land use types, but more detailed analyses will help to better elucidate temporal changes to river solutes and especially the effects they may have on coastal calcium carbonate saturation state.

Science of the Total Environment↗

USGS2014

Spatial and temporal patterns in concentrations of perfluorinated compounds in bald eagle nestlings in the Upper Midwestern United States

Perfluorinated chemicals (PFCs) are of concern due to their widespread use, persistence in the environment, tendency to accumulate in animal tissues, and growing evidence of toxicity. Between 2006 and 2011 we collected blood plasma from 261 bald eagle nestlings in six study areas from the upper Midwestern United States. Samples were assessed for levels of 16 different PFCs. We used regression analysis in a Bayesian framework to evaluate spatial and temporal trends for these analytes. We found levels as high as 7370 ng/mL for the sum of all 16 PFCs (∑PFCs). Perfluorooctanesulfonate (PFOS) and perfluorodecanesulfonate (PFDS) were the most abundant analytes, making up 67% and 23% of the PFC burden, respectively. Levels of ∑PFC, PFOS, and PFDS were highest in more urban and industrial areas, moderate on Lake Superior, and low on the remote upper St. Croix River watershed. We found evidence of declines in ∑PFCs and seven analytes, including PFOS, PFDS, and perfluorooctanoic acid (PFOA); no trend in two analytes; and increases in two analytes. We argue that PFDS, a long-chained PFC with potential for high bioaccumulation and toxicity, should be considered for future animal and human studies.

Minnesota, Wisconsin↗

USGS2008

Warming of the Indian Ocean threatens eastern and southern African food security but could be mitigated by agricultural development

Since 1980, the number of undernourished people in eastern and southern Africa has more than doubled. Rural development stalled and rural poverty expanded during the 1990s. Population growth remains very high, and declining per-capita agricultural capacity retards progress toward Millennium Development goals. Analyses of in situ station data and satellite observations of precipitation have identified another problematic trend: main growing-season rainfall receipts have diminished by ???15% in food-insecure countries clustered along the western rim of the Indian Ocean. Occurring during the main growing seasons in poor countries dependent on rain-fed agriculture, these declines are societally dangerous. Will they persist or intensify? Tracing moisture deficits upstream to an anthropogenically warming Indian Ocean leads us to conclude that further rainfall declines are likely. We present analyses suggesting that warming in the central Indian Ocean disrupts onshore moisture transports, reducing continental rainfall. Thus, late 20th-century anthropogenic Indian Ocean warming has probably already produced societally dangerous climate change by creating drought and social disruption in some of the world's most fragile food economies. We quantify the potential impacts of the observed precipitation and agricultural capacity trends by modeling 'millions of undernourished people' as a function of rainfall, population, cultivated area, seed, and fertilizer use. Persistence of current tendencies may result in a 50% increase in undernourished people by 2030. On the other hand, modest increases in per-capita agricultural productivity could more than offset the observed precipitation declines. Investing in agricultural development can help mitigate climate change while decreasing rural poverty and vulnerability. ?? 2008 by The National Academy of Sciences of the USA.

Proceedings of the National Academy of Sciences of↗

USGS1961

Dating desert ground water

Tritium in Arabian rainfall has followed the trend observed in North America with peaks in 1958 and the spring of 1959. These measurements will be useful for future hydrologie studies. Water from wadi gravels averages 10 yr old. Carbon-14 measurements of deep waters indicate ages of several thousand years.

Science↗

USGS1963

Radiogenic strontium-87 as an index of geologic processes

The abundance of radiogenic Sr 87 relative to Sr 86 at the time of crystallization has been determined for 45 rocks. The total range in the ratio Sr 87 /Sr 86 is less than 2 percent. Ratios for recent lavas range from 0.702 to 0.711. Oceanic basalts are closely grouped at 0.703, whereas ratios for continental volcanic rocks spread from 0.702 to 0.711. Among the volcanic rocks, ranging from basalt to rhyolite, no correlation was found between original ratio and rock type. Older mafic and felsic rocks that include both plutonic and extrusive types also cover this same range in original Sr 87 /Sr 86 ratios; however, there is a definite trend with geologic time. Precambrian rocks give values as low as 0.700. The data indicate that Sr 87 /Sr 86 of the weathering crust has changed 1.1 percent in 3000 million years, while the ratio in the mantle has changed no more than 0.5 percent.

Science↗

USGS1984

Chromite from the Blue Ridge province of North Carolina

Accessory chromite in dunite shows a variety of textures that indicate alteration. One group, type A, consists of four types of chromite: clean chromite; lattice chromite, in which the invading chlorite occurs along three directions in the (100) plane; optically zoned chromite; and poikiloblastic chromite. Most of type A chromites are surrounded by chromian clinochlore. The other group, type B, consists of euhedral to subhedral chromite grains which are included in olivine or pyroxene. The accessory chromites define a trend exhibited by chromite from other areas that have undergone metamorphism. Olivine-spinel geothermometry indicates equilibration temperatures near 700 degrees C, roughly consistent with mineral assemblages in the host gneisses. Thus, the Blue Ridge dunites are metamorphic rocks and not primary mantle peridotites.

North Carolina↗

USGS2010

Modeling Climate Change and Sturgeon Populations in the Missouri River

The U.S. Geological Survey (USGS) Columbia Environmental Research Center (CERC), in collaboration with researchers from the University of Missouri and Iowa State University, is conducting research to address effects of climate change on sturgeon populations (Scaphirhynchus spp.) in the Missouri River. The CERC is conducting laboratory, field, and modeling research to identify causative factors for the responses of fish populations to natural and human-induced environmental changes and using this information to understand sensitivity of sturgeon populations to potential climate change in the Missouri River drainage basin. Sturgeon response information is being used to parameterize models predicting future population trends. These models will provide a set of tools for natural resource managers to assess management strategies in the context of global climate change. This research complements and builds on the ongoing Comprehensive Sturgeon Research Program (CSRP) at the CERC. The CSRP is designed to provide information critical to restoration of the Missouri River ecosystem and the endangered pallid sturgeon (S. albus). Current research is being funded by USGS through the National Climate Change Wildlife Science Center (NCCWSC) and the Science Support Partnership (SSP) Program that is held by the USGS and the U.S. Fish and Wildlife Service. The national mission of the NCCWSC is to improve the capacity of fish and wildlife agencies to respond to climate change and to address high-priority climate change effects on fish and wildlife. Within the national context, the NCCWSC research on the Missouri River focuses on temporal and spatial downscaling and associated uncertainty in modeling climate change effects on sturgeon species in the Missouri River. The SSP research focuses on improving survival and population estimates for pallid sturgeon population models.

Fact Sheet↗

USGS2012

Recent population trends of mountain goats in the Olympic Mountains, Washington

Mountain goats ( Oreamnos americanus ) were introduced in Washington's Olympic Mountains during the 1920s. The population subsequently increased in numbers and expanded in range, leading to concerns by the 1970s over the potential effects of non-native mountain goats on high-elevation plant communities in Olympic National Park. The National Park Service (NPS) transplanted mountain goats from the Olympic Mountains to other ranges between 1981 and 1989 as a means to manage overabundant populations, and began monitoring population trends of mountain goats in 1983. We estimated population abundance of mountain goats during 18–25 July 2011, the sixth survey of the time series, to assess current population status and responses of the population to past management. We surveyed 39 sample units, comprising 39% of the 59,615-ha survey area. We estimated a population of 344 ± 72 (90% confidence interval [CI]) mountain goats in the survey area. Retrospective analysis of the 2004 survey, accounting for differences in survey area boundaries and methods of estimating aerial detection biases, indicated that the population increased at an average annual rate of 4.9% since the last survey. That is the first population growth observed since the cessation of population control measures in 1990. We postulate that differences in population trends observed in western, eastern, and southern sections of the survey zone reflected, in part, a variable influence of climate change across the precipitation gradient in the Olympic Mountains.

Washington↗

USGS2012

Earthquake studies reveal the magmatic plumbing system of the Katmai volcanoes

The 1912 eruption of Novarupta was the largest of the 1900s (Fierstein and Hildreth 2001, Hildreth et al. 2003). A century later, fundamental questions remain regarding the source of the magma for that eruption. A previous seismic study of the Katmai area (Jolly et al. 2007) identified a single large area of anomalous structure in the subsurface centered beneath Katmai Pass (Figure 2), but the magma source for the 1912 eruption is thought to have been beneath Mt. Katmai (Hildreth et al. 2003). This mystery was a prime motivation for the research project described here. In summer 2008, scientists and staff from the Alaska Volcano Observatory (AVO) and the University of Wisconsin- Madison installed 11 temporary seismic recording instruments around the Katmai Pass area, complementing the existing AVO seismic network stations (Figure 3). The primary goal of the deployment was to record data from local earthquakes in order to yield an improved model of the three-dimensional structure of the upper crust beneath and surrounding Katmai Pass, using an analysis method known as double-difference seismic tomography (Zhang and Thurber 2003). The method yields a threedimensional image of the velocity of seismic waves in the subsurface, and also produces improved estimates of the locations of the earthquakes beneath the seismic stations. Our main finding is that there is not a single large anomalous zone centered beneath Katmai Pass; rather there are several separate anomalous zones, one each beneath Katmai, Trident-Novarupta, and Martin-Mageik. Furthermore, the earthquakes are tightly clustered beneath the various volcanic centers, and are found to be systematically deeper than previously thought. Linear trends of earthquakes are also revealed, similar to features observed at other volcanoes, possibly outlining previously unidentified fault structures or indicating the path of migrating magma or magmatic fluids and gases.

Alaska↗

USGS2005

Structure and regional significance of the Late Permian(?) Sierra Nevada - Death Valley thrust system, east-central California

An imbricate system of north-trending, east-directed thrust faults of late Early Permian to middle Early Triassic (most likely Late Permian) age forms a belt in east-central California extending from the Mount Morrison roof pendant in the eastern Sierra Nevada to Death Valley. Six major thrust faults typically with a spacing of 15-20 km, original dips probably of 25-35??, and stratigraphic throws of 2-5 km compose this structural belt, which we call the Sierra Nevada-Death Valley thrust system. These thrusts presumably merge into a de??collement at depth, perhaps at the contact with crystalline basement, the position of which is unknown. We interpret the deformation that produced these thrusts to have been related to the initiation of convergent plate motion along a southeast-trending continental margin segment probably formed by Pennsylvanian transform truncation. This deformation apparently represents a period of tectonic transition to full-scale convergence and arc magmatism along the continental margin beginning in the Late Triassic in central California. ?? 2005 Elsevier B.V. All rights reserved.

Earth-Science Reviews↗

USGS2013

Differential mercury transfer in the aquatic food web of a double basined lake associated with selenium and habitat

Food web trophodynamics of total mercury (THg) and selenium (Se) were assessed for the double-basined ultraoligotrophic system of Lake Moreno, Patagonia. Each basin has differing proportions of littoral and pelagic habitats, thereby providing an opportunity to assess the importance of habitat (e.g. food web structure or benthic MeHg production) in the transfer of Hg and Se to top trophic fish species. Pelagic plankton, analyzed in three size classes (10–53, 53–200, and > 200 μm), had very high [THg], exceeding 200 μg g − 1 dry weight (DW) in the smallest, and a low ratio of MeHg to THg (0.1 to 3%). In contrast, [THg] in littoral macroinvertebrates showed lower values (0.3 to 1.8 μg g − 1 DW). Juvenile and small fish species feeding upon plankton had higher [THg] (0.2 to 8 μg g − 1 muscle DW) compared to large piscivore fish species (0.1 to 1.6 μg g − 1 muscle DW). Selenium concentrations exhibited a much narrower variation range than THg in the food web, varying from 0.5 to 2.7 μg g − 1 DW. Molar Se:Hg ratios exceeded 1 for the majority of organisms in both basins, with most ratios exceeding 10. Using stable nitrogen isotopes as indicator of trophic level, no significant correlations were found with [THg], [Se] or Se:Hg. The apparent lack of biomagnification trends was attributed to elevated [THg] in plankton in the inorganic form mostly, as well as the possibility of consistent Se supply reducing the biomagnification in the food web of the organic portion of THg.

Patagonia;Lake Moreno↗

USGS2019

Stratification of reactivity determines nitrate removal in groundwater

Biogeochemical reactions occur unevenly in space and time, but this heterogeneity is often simplified as a linear average due to sparse data, especially in subsurface environments where access is limited. For example, little is known about the spatial variability of groundwater denitrification, an important process in removing nitrate originating from agriculture and land use conversion. Information about the rate, arrangement, and extent of denitrification is needed to determine sustainable limits of human activity and to predict recovery time frames. Here, we developed and validated a method for inferring the spatial organization of sequential biogeochemical reactions in an aquifer in France. We applied it to five other aquifers in different geological settings located in the United States and compared results among 44 locations across the six aquifers to assess the generality of reactivity trends. Of the sampling locations, 79% showed pronounced increases of reactivity with depth. This suggests that previous estimates of denitrification have underestimated the capacity of deep aquifers to remove nitrate, while overestimating nitrate removal in shallow flow paths. Oxygen and nitrate reduction likely increases with depth because there is relatively little organic carbon in agricultural soils and because excess nitrate input has depleted solid phase electron donors near the surface. Our findings explain the long-standing conundrum of why apparent reaction rates of oxygen in aquifers are typically smaller than those of nitrate, which is energetically less favorable. This stratified reactivity framework is promising for mapping vertical reactivity trends in aquifers, generating new understanding of subsurface ecosystems and their capacity to remove contaminants.

Proceedings of the National Academy of Sciences↗

USGS2022

High-resolution remote sensing and multistate occupancy estimation identify drivers of spawning site selection in fall chum salmon (Oncorhynchus keta) across a sub-Arctic riverscape

Groundwater upwellings provide warmer, stable overwinter temperatures for developing salmon embryos, which may be particularly important in cold, braided, gravel-bed sub-Arctic rivers. We used a three-year time series of aerial counts and remote sensing to estimate the distribution of low and high aggregations of spawning fall chum salmon ( Oncorhynchus keta ), classify approximately 0.5 km long river segments by geomorphic channel type, and map thermal variability along a 25.4 km stretch of the Teedriinjik River, Alaska. We used a dynamic multistate occupancy model to estimate detectability, occupancy, and the dynamics of spawning aggregations among river segments. Detectability was higher for large (>150) relative to smaller aggregations. Unoccupied segments were likely to remain so from year to year; low abundance spawning segments were dynamic and rarely remained in that state for multiple years, while ∼20%–35% of high abundance segments remained stable, indicating the presence of high-quality spawning habitat. Spawning habitat use was associated with warmer water temperatures likely caused by groundwater upwellings. We identified spawning habitat characteristics and trends in usage by fall chum salmon, which will inform land management decisions and assist in evaluating impacts of shifting climate conditions and resource management on Arctic salmon populations.

Alaska↗