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USGS2014

Petrographic maturity parameters of a Devonian shale maturation series, Appalachian Basin, USA. ICCP Thermal Indices Working Group interlaboratory exercise

This paper presents results of an interlaboratory exercise on organic matter optical maturity parameters using a natural maturation series comprised by three Devonian shale samples (Huron Member, Ohio Shale) from the Appalachian Basin, USA. This work was conducted by the Thermal Indices Working Group of the International Committee for Coal and Organic Petrology (ICCP) Commission II (Geological Applications of Organic Petrology). This study aimed to compare: 1. maturation predicted by different types of petrographic parameters (vitrinite reflectance and spectral fluorescence of telalginite), 2. reproducibility of the results for these maturation parameters obtained by different laboratories, and 3. improvements in the spectral fluorescence measurement obtained using modern detection systems in comparison with the results from historical round robin exercises. Mean random vitrinite reflectance measurements presented the highest level of reproducibility (group standard deviation 0.05) for low maturity and reproducibility diminished with increasing maturation (group standard deviation 0.12). Corrected fluorescence spectra, provided by 14 participants, showed a fair to good correspondence. Standard deviation of the mean values for spectral parameters was lowest for the low maturity sample but was also fairly low for higher maturity samples. A significant improvement in the reproducibility of corrected spectral fluorescence curves was obtained in the current exercise compared to a previous investigation of Toarcian organic matter spectra in a maturation series from the Paris Basin. This improvement is demonstrated by lower values of standard deviation and is interpreted to reflect better performance of newer photo-optical measuring systems. Fluorescence parameters measured here are in good agreement with vitrinite reflectance values for the least mature shale but indicate higher maturity than shown by vitrinite reflectance for the two more mature shales. This red shift in λ max beyond 0.65% vitrinite reflectance was also observed in studies of Devonian shale in other basins, suggesting that the accepted correlation for these two petrographic thermal maturity parameters needs to be re-evaluated. A good linear correlation between λ max and T max for this maturation series was observed and λ max 600 nm corresponds to T max of 440 °C. Nevertheless if a larger set of Devonian samples is included, the correlation is polynomial with a jump in λ max ranging from 540 to 570 nm. Up to 440 °C of T max , the λ max , mostly, reaches up to 500 nm; beyond a T max of 440 °C, λ max is in the range of 580–600 nm. This relationship places the “red shift” when the onset of the oil window is reached at T max of 440 °C. Moreover, the correlation between HI and λ max (r 2 = 0.70) shows a striking inflection and decrease in HI above a λ max of 600 nm, coincident with the approximate onset of hydrocarbon generation in these rocks.

International Journal of Coal Geology↗

USGS2022

Characterization of bituminite in Kimmeridge Clay by confocal laser scanning and atomic force microscopy

This work investigates bituminite (amorphous sedimentary organic matter) in Upper Jurassic Kimmeridge Clay source rock via confocal laser scanning microscopy (CLSM) and atomic force microscopy (AFM). These petrographic tools were used to provide better understanding of the nature of bituminite, which has been historically difficult to identify and differentiate from similar organic matter types in source rocks. As part of an International Committee for Coal and Organic Petrology (ICCP) working group, an immature (0.42% vitrinite reflectance), organic-rich (44.1 wt% total organic carbon content) sample of Kimmeridge Clay was distributed to multiple laboratories for CLSM characterization. The primary observations from CLSM imaging and spectroscopy include: 1) the interpreted presence of Botryococcus algae as a contributor to bituminite precursors; 2) color red-shift of sulfide reflectance and bituminite auto-fluorescence from below the sample surface; 3) positive alteration of bituminite from laser-induced photo-oxidation of the sample surface, including fluorescence blue-shift; 4) fluorescence blue-shift associated to higher fluorescence intensity regions in bituminite indicative of compositional (fluorophore) differences; 5) the need for fluorescence spectroscopy standardization as applied via CLSM; and 6) the suitability of CLSM fluorescence spectroscopy to predict solid bitumen reflectance from bituminite spectral emission via calibration to an extant dataset. Secondary CLSM observations include detection of reflected laser light from highly reflective inclusions in bituminite, including sulfides and fusinite, and radiolytic alteration of bituminite caused by substitution of U for Fe in sulfides. Findings from AFM include the observation that surface roughening or surface flattening of bituminite are induced by differential broad ion beam (BIB) milling and are dependent on the location and scale of AFM topology measurement. This result highlights our still limited understanding of the effects of BIB milling on sedimentary organic matter and indicates the need for further research before this technique can be advanced as a standard practice in petrographic sample preparation. Collectively, the results of this study illustrate the general applicability and versatility of AFM and CLSM as tools for organic petrology research, specifically for better understanding of the nature and properties of the bituminite maceral.

Kimmeridge↗

USGS2025

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology↗

USGS2021

Multi-geophysical parameter classification of the Montserrat geothermal system

Multi-geophysical parameter classification can help to reduce the uncertainties of interpretations that often rely on one geophysical technique. Integrating these varying datasets requires a more robust classification approach rather than traditional qualitative methods. In this study, we applied the Fuzzy c-means (FCM) method to quantitatively classify similarities in a high resolution seismic tomography, a magnetotellurics and gravity datasets obtained in Montserrat. To group similar datapoints, this application uses a Euclidean distance measure and a membership function. Assigned membership values indicate the degree to which a datapoint belongs to a specific class. The spatial distribution of the derived classes, each classified with distinct geophysical parameters, helped to provide new structural and petrological information of the Montserrat geothermal system. In comparison to previous models, our new cluster model highlights two major improvements. These include the resolution and assessment of the spatial extension and 3D geometry of previously undetected features within the Montserrat geothermal system and the constrain and characterization of earlier identified anomalies. We additionally utilized geological and petrological data obtained from three geothermal wells in the Montserrat geothermal system to help validate our classifications. Based on a semi-quantitative approach we assessed the reliability of the FCM technique in relation to the likely uncertainties of the different geophysical models.

Geothermics↗

USGS2007

Two lithospheric profiles across southern California derived from gravity and seismic data

We present two detailed 2-D density transects for the crust and uppermost mantle across southern California using a linear gravity inversion technique. This technique parameterizes the crust and upper mantle as a set of blocks that are based on published geologic and seismic models. Each block can have a range of densities that are constrained where possible by borehole measurements, seismic velocities, and petrologic data. To further constrain the models, it is assumed that the lithosphere is close to isostatic equilibrium at both ends of the profiles, in the deep ocean and east of the Mojave Desert. We calculate the lithostatic pressure variations field for the whole cross section to rule out the geophysically insignificant solutions. In the linear equation, ρ = a + bV ( V , seismic P-wave velocity; ρ , density), which approximates the mantle density–velocity ( ρ – V ) relationship, different coefficients for b were evaluated. Lower coefficients ( b < 0.2) correspond to an almost purely thermally perturbed mantle, while higher coefficients ( b > 0.3) imply that other effects, such as composition and/or metamorphic changes, play an important role in the mantle. Density models were constructed with the coefficient b ranging from 0 to 0.6. The results indicate that a high b value in the mantle ρ – V relationship is associated with less dense crust in the Mojave block and more dense crust in the Catalina schist block. In the less dense Mojave block, the average density of the whole crust is ∼2.75 g/cm 3 , while that of the lower crust is ∼2.72 g/cm 3 . These densities imply a high silica content in the crust, and a minor fraction of basic rock in the lower crust, or perhaps the absence of a basaltic layer altogether. By comparison, the average density of a typical continental stable platform is ∼2.85 g/cm 3 . Models with higher b coefficients (0.5–0.6) are characterized by a large isostatic imbalance. On the other hand, lower b values (0–0.2) require a consolidated whole crust density in the Mojave Desert of ∼2.78 g/cm 3 , and a lower crust density of ∼2.89 g/cm 3 with mostly basaltic composition. This contradicts the observed, lower V p / V s -ratio in the Mojave Desert associated with mostly felsic and low-density crust. Models with lower b coefficients (0.1–0.2) are characterized by an absence of local Airy compensation beneath the San Gabriel Mountains at the LARSE-1 profile. These, and other non-gravity arguments, suggest optimal solutions to the mantle ρ – V relation of b ∼ 0.2–0.4. This, in turn, means that both thermal and petrological effects occur inside the downwelling of the uppermost mantle high velocity body located beneath the Transverse Ranges. During the development of this mantle downwelling, the basaltic layer of the Mojave block was likely eroded and pulled down into the high velocity body. Those basaltic fragments may have been transformed into eclogites, and this metamorphic change implies a higher b -coefficient density–velocity relationship than would be expected for a purely thermal process.

California↗

USGS2008

Eruptive history and tectonic setting of Medicine Lake Volcano, a large rear-arc volcano in the southern Cascades

Medicine Lake Volcano (MLV), located in the southern Cascades ∼ 55 km east-northeast of contemporaneous Mount Shasta, has been found by exploratory geothermal drilling to have a surprisingly silicic core mantled by mafic lavas. This unexpected result is very different from the long-held view derived from previous mapping of exposed geology that MLV is a dominantly basaltic shield volcano. Detailed mapping shows that < 6% of the ∼ 2000 km 2 of mapped MLV lavas on this southern Cascade Range shield-shaped edifice are rhyolitic and dacitic, but drill holes on the edifice penetrated more than 30% silicic lava. Argon dating yields ages in the range ∼ 475 to 300 ka for early rhyolites. Dates on the stratigraphically lowest mafic lavas at MLV fall into this time frame as well, indicating that volcanism at MLV began about half a million years ago. Mafic compositions apparently did not dominate until ∼ 300 ka. Rhyolite eruptions were scarce post-300 ka until late Holocene time. However, a dacite episode at ∼ 200 to ∼ 180 ka included the volcano's only ash-flow tuff, which was erupted from within the summit caldera. At ∼ 100 ka, compositionally distinctive high-Na andesite and minor dacite built most of the present caldera rim. Eruption of these lavas was followed soon after by several large basalt flows, such that the combined area covered by eruptions between 100 ka and postglacial time amounts to nearly two-thirds of the volcano's area. Postglacial eruptive activity was strongly episodic and also covered a disproportionate amount of area. The volcano has erupted 9 times in the past 5200 years, one of the highest rates of late Holocene eruptive activity in the Cascades. Estimated volume of MLV is ∼ 600 km 3 , giving an overall effusion rate of ∼ 1.2 km 3 per thousand years, although the rate for the past 100 kyr may be only half that. During much of the volcano's history, both dry HAOT (high-alumina olivine tholeiite) and hydrous calcalkaline basalts erupted together in close temporal and spatial proximity. Petrologic studies indicate that the HAOT magmas were derived by dry melting of spinel peridotite mantle near the crust mantle boundary. Subduction-derived H 2 O-rich fluids played an important role in the generation of calcalkaline magmas. Petrology, geochemistry and proximity indicate that MLV is part of the Cascades magmatic arc and not a Basin and Range volcano, although Basin and Range extension impinges on the volcano and strongly influences its eruptive style. MLV may be analogous to Mount Adams in southern Washington, but not, as sometimes proposed, to the older distributed back-arc Simcoe Mountains volcanic field.

Journal of Volcanology and Geothermal Research↗

USGS2023

Imaging the magmatic plumbing of the Clear Lake Volcanic Field using 3-D gravity inversions

The Quaternary Clear Lake Volcanic Field (CLVF) in the Northern California Coast Range is the youngest of a string of northward-younging volcanic centers in the state. The CLVF is located within the broad San Andreas Transform Fault System and has been active intermittently for ∼2 million years. Heat beneath the CLVF supports The Geysers, one of the largest producing geothermal fields in the world. Previous geophysical studies proposed the existence of a magma reservoir beneath Mount Hannah, which is northeast of The Geysers, near the geographic center of the CLVF. The lateral extent, depth, and presence of melt within this reservoir are poorly constrained, as is the relationship between this body and the broader magmatic plumbing of the CLVF. To gain a clearer and more comprehensive picture of the CLVF magma source region, a gravity dataset was compiled and the first 3-D gravity inversions of the CLVF were completed. Field and synthetic model inversions from the current study both indicate that the gravity low roughly centered on Mount Hannah is not accurately explained by a 5–7 km thick lens of Mesozoic Great Valley Sequence ( ρ = 2.58 g/cm 3 "> �=2.58g/cm3 ) as proposed by Stanley et al. (1998) . The observed gravity low is more accurately described by one or more silicic, partial melt bodies between The Geysers and Mount Hannah. Although our inversions cannot constrain the exact depth and geometry of these bodies, the recovered models indicate the existence of a partial melt zone between 6 and 13 km depth. The prolonged eruption history of the CLVF, coupled with the compositional variation of erupted rocks over time and space, is consistent with the existence of several, potentially ephemeral, melt-bearing bodies as opposed to one large melt body. Given the density and location of the recovered anomaly, rhyolite-MELTS thermodynamic modeling suggests the existence of 10–30% rhyodacitic melt within the proposed silicic magma reservoir at about 700 °C and 8 km depth (210 MPa). Independent petrologic, geochemical, and seismic evidence indicates that this silicic partial melt zone is underlain by basaltic melt in the lower to middle crust (13 to 21 km depth), which is fed by a mantle source. Eruptions in the past ∼8.5–13.5 thousand years; high regional heat flow; 3 He enrichment of hydrothermal fluids; and our modeling, which suggests the presence of a mid-crustal, silicic partial melt zone, point to a still-active CLVF. The relatively low estimates of partial melt (10–30%) predicted by thermodynamic modeling indicates that an injection of new magma into the imaged partial melt zone is needed to generate sufficient melt to incite future eruptions. Despite the low percent melt estimates within the proposed silicic partial melt zone the potential for future volcanic eruption remains. Due to the proximity of the CLVF to cities surrounding Clear Lake and the densely populated San Francisco Bay Area, continued research and monitoring of the volcanic field are warranted. The geophysical and petrologic modeling presented here improves our understanding of the CLVF magma plumbing system and allows us to better characterize its associated volcanic hazards.

California↗

USGS2003

Density of the continental roots: Compositional and thermal contributions

The origin and evolution of cratonic roots has been debated for many years. Precambrian cratons are underlain by cold lithospheric roots that are chemically depleted. Thermal and petrologic data indicate that Archean roots are colder and more chemically depleted than Proterozoic roots. This observation has led to the hypothesis that the degree of depletion in a lithospheric root depends mostly on its age. Here we test this hypothesis using gravity, thermal, petrologic, and seismic data to quantify differences in the density of cratonic roots globally. In the first step in our analysis we use a global crustal model to remove the crustal contribution to the observed gravity. The result is the mantle gravity anomaly field, which varies over cratonic areas from -100 to +100 mGal. Positive mantle gravity anomalies are observed for cratons in the northern hemisphere: the Baltic shield, East European Platform, and the Siberian Platform. Negative anomalies are observed over cratons in the southern hemisphere: Western Australia, South America, the Indian shield, and Southern Africa. This indicates that there are significant differences in the density of cratonic roots, even for those of similar age. Root density depends on temperature and chemical depletion. In order to separate these effects we apply a lithospheric temperature correction using thermal estimates from a combination of geothermal modeling and global seismic tomography models. Gravity anomalies induced by temperature variations in the uppermost mantle range from -200 to +300 mGal, with the strongest negative anomalies associated with mid-ocean ridges and the strongest positive anomalies associated with cratons. After correcting for thermal effects, we obtain a map of density variations due to lithospheric compositional variations. These maps indicate that the average density decrease due to the chemical depletion within cratonic roots varies from 1.1% to 1.5%, assuming the chemical boundary layer has the same thickness as the thermal boundary layer. The maximal values of the density drop are in the range 1.7-2.5%, and correspond to the Archean portion of each craton. Temperatures within cratonic roots vary strongly, and our analysis indicates that density variations in the roots due to temperature are larger than the variations due to chemical differences.

Earth and Planetary Science Letters↗

USGS2000

Recent tectonics of the Blanco Ridge, eastern blanco transform fault zone

Bathymetric, hydro-acoustic, seismic, submersible, and gravity data are used to investigate the active tectonics of the eastern Blanco Transform Fault Zone (BTFZ). The eastern BTFZ is dominated by the ∼150 km long transform-parallel Blanco Ridge (BR) which is a right-lateral strike-slip fault bordered to the east and west by the Gorda and Cascadia Depressions. Acoustic locations, fault-parameter information, and slip vector estimates of 43 earthquakes ( M w ≥3.8) that occurred along the eastern BTFZ over the last 5 years reveal that the Blanco Ridge is a high-angle right-lateral strike-slip fault, with a small component of dip-slip motion, where the Juan de Fuca plate is the hanging wall relative to the Pacific plate. Furthermore, the Cascadia and Gorda basins are undergoing normal faulting with extension predominantly oblique to the transform trend. Seafloor submersible observations agree with previous hypotheses that the active transform fault trace is the elongate basin that runs the length of the BR summit. Brecciated and undeformed basalt, diabase, and gabbro samples were collected at the four submersible survey sites along the Blanco Ridge. These petrologic samples indicate the Blanco Ridge is composed of an ocean crustal sequence that has been uplifted and highly fractured. The petrologic samples also appear to show an increase in elevation of the crustal section from east to west along the Blanco Ridge, with gabbros exposed at a shallower depth farther west along the southern (Pacific plate side) BR ridge flank. Further supporting evidence for BR uplift exists in the seismic reflection profiles across the BR showing uplift of turbidite sequences along the north and south ridge base, and gravity and magnetics profiles that indicate possible basement uplift and a low-density zone centered on the ridge's Pacific plate side. The BR formation mechanism preferred here is first, uplift achieved partially through strike-slip motion (with a small dip-slip component). Second, seawater penetration along the fault into the lower crust upper mantle, which then enhanced formation and intrusion of a mantle-derived serpentinized-peridotite diapir into the shallow ocean crust, causing further uplift along the fault.

Marine Geophysical Research↗

USGS2022

Multidisciplinary constraints on the thermal-chemical boundary between Earth's core and mantle

Heat flux from the core to the mantle provides driving energy for mantle convection thus powering plate tectonics, and contributes a significant fraction of the geothermal heat budget. Indirect estimates of core-mantle boundary heat flow are typically based on petrological evidence of mantle temperature, interpretations of temperatures indicated by seismic travel times, experimental measurements of mineral melting points, physical mantle convection models, or physical core convection models. However, previous estimates have not consistently integrated these lines of evidence. In this work, an interdisciplinary analysis is applied to co-constrain core-mantle boundary heat flow and test the thermal boundary layer (TBL) theory. The concurrence of TBL models, energy balance to support geomagnetism, seismology, and review of petrologic evidence for historic mantle temperatures supports Q CMB ∼15 TW, with all except geomagnetism supporting as high as ∼20 TW. These values provide a tighter constraint on core heat flux relative to previous work. Our work describes the seismic properties consistent with a TBL, and supports a long-lived basal mantle molten layer through much of Earth's history.

Geochemistry, Geophysics, Geosystems↗

USGS2026

Erupted volume during the 2014–2023 Semisopochnoi unrest and eruption constrained by multi-platform InSAR and volcanic gas observations

Volcano deformation data provide important constraints on magma dynamics during volcanic unrest and eruptions. From these observations, we can estimate subsurface pressure changes and relate them to volume change in the reservoir. However, because magma and rock are compressible, this volume change cannot be directly equated with eruptive volume. When we combine geodetic analyses with gas observations, petrologic constraints, volatile solubility modeling, and magma compressibility equations, however, we can estimate realistic lower and upper bounds of eruptive volume. Leveraging multi‐platform InSAR time series and satellite SO 2 data, we apply these methods to the 2014–2023 unrest and eruption of Semisopochnoi, Alaska. We find that this phreatomagmatic eruption sequence was fed by a spherical magma source at 6.5–7.5 km depth bsl, centered beneath the caldera, ∼5 km offset to the east from the vent. Volatile solubility modeling indicates that ∼50% of the initial dissolved CO 2 has exsolved at depths consistent with the geodetic source depth, increasing the magma compressibility. Combining geodetic model constraints with SO 2 observations, petrologic constraints, solubility models, and magma compressibility findings yields 12–32 Mm 3 as the most‐likely juvenile, dense‐rock equivalent eruptive volume, with a best estimate of 20 Mm 3 . Stress change modeling suggests that the local stress field encouraged conduit formation west of the pre‐eruptive inflation center, and that the 2014 M7.9 Rat Island earthquake, ∼65 km to the west of Semisopochnoi, reduced the compressive stress underneath the volcano, supporting prolonged eruptive activity.

Alaska↗

USGS1998

The Soufriere Hills eruption, Montserrat, British West Indies: Introduction to special section, part 1

The special section on the eruption of Soufriere Hills volcano is a collection of 24 papers that summarises the early scientific work of the Montserrat Volcano Observatory. Part 1 of the special section, published in a previous issue of GRL , provided a sampling of the multidisciplinary investigations undertaken at Montserrat. The papers published in Part 1 included an overview of the eruption, investigations on seismicity, ground deformation studies, and petrology. The papers of this issue comprise Part 2 of the special section. These papers also cover a broad spectrum of topics, including various topics in seismology, petrology, pyroclastic flow models, gas chemistry, hydrothermal systems, and tsunami models. In general, papers in Part 1 may be said to be more observational- or data-orientated, and those of Part 2 more model-orientated, but indeed there is much overlap of descriptive material, data, and modelling within the individual contributions. Considered in total the collection presents a representative summary of the scientific effort carried out in Montserrat through much of 1997.

Geophysical Research Letters↗

USGS1980

Volcanic rocks cored on hess rise, Western Pacific Ocean

Large aseismic rises and plateaus in the western Pacific include the Ontong-Java Plateau, Magellan Rise, Shatsky Rise, Mid-Pacific Mountains, and Hess Rise. These are relatively old features that rise above surrounding sea floors as bathymetric highs. Thick sequences of carbonate sediments overlie, what are believed to be, Upper Jurassic and Lower Cretaceous volcanic pedestals. We discuss here petrological and tectonic implications of data from volcanic rocks cored on Hess Rise. The data suggest that Hess Rise originated at a spreading centre in the late early Cretaceous (Aptian-Albian stages). Subsequent off-ridge volcanism in the late Albian-early Cenomanian stages built a large archipelago of oceanic islands and seamounts composed, at least in part, of alkalic rocks. The volcanic platform subsided during its northward passage through the mid-Cretaceousequatorial zone. Faulting and uplift, and possibly volcanism, occurred in the latest Cretaceous (Campanian-Maastrichtian stages). Since then, Hess Rise continued its northward movement and subsidence. Volcanic rocks from holes drilled on Hess Rise during IPOD Leg 62 (Fig. 1) are briefly described here and we relate the petrological data to the origin and evolution of that rise. These are the first volcanic rocks reported from Hess Rise. ?? 1980 Nature Publishing Group.

Nature↗

USGS2022

Evolving magma temperature and volatile contents over the 2008–2018 summit eruption of Kīlauea Volcano

Magma rheology and volatile contents exert primary and highly nonlinear controls on volcanic activity. Subtle changes in these magma properties can modulate eruption style and hazards, making in situ inference of their temporal evolution vital for volcano monitoring. Here, we study thousands of impulsive magma oscillations within the shallow conduit and lava lake of Kīlauea Volcano, Hawai‘i, USA, over the 2008–2018 summit eruptive sequence, encoded by “very-long-period” seismic events and ground deformation. Inversion of these data with a petrologically informed model of magma dynamics reveals significant variation in temperature and highly disequilibrium volatile contents over days to years, within a transport network that evolved over the eruption. Our results suggest a framework for inferring subsurface magma dynamics associated with prolonged eruptions in near real time that synthesizes petrologic and geophysical volcano monitoring approaches.

Hawaii↗

USGS1983

Tin granites of Seward Peninsula, Alaska

Seven granite plutons, spatially and genetically related to tin metalization, are exposed in a 170-km-long belt across northwestern Seward Peninsula, Alaska. These plutons are cupolas and epizonal composite stocks that consist of several textural varieties of biotite granite, including medium- to coarse-grained seriate biotite granite, porphyritic biotite granite with an aplitic groundmass, and fine- to medium-grained equigranular biotite granite. The common accessory minerals are fluorite, allanite, apatite, and zircon. Other accessory minerals that are locally present include tourmaline, sphene, opaque oxide minerals, and late-forming (deuteric) muscovite and chlorite. The granites range in major-element contents as follows: SiO 2 , 72.5% to 76.6%; A1 2 O 3 , 12.7% to 14.3%; Na 2 O, 2.9% to 4.0%; K 2 O, 3.9% to 5.6%; and CaO, 0.6% to 1.2%. The sum of FeO + Fe 2 O 3 + MgO ranges from 0.3% to 2.4%; and the K 2 O to Na 2 O ratio from 1.1 to 1.8. The 0.1% to 0.9% F and 0.01% to 0.2% Cl reflect the over-all volatile-rich nature of the granites. The granites contain average or below-average concentrations of Co, Sc, Cr, and Zn, and generally above-average to distinctly high concentrations of Th, U, Hf, and Ta. The large cations emphasize the evolved nature of the granites; the Rb/Sr ratio is as high as 90 in some samples. Initial 87 Sr/ 86 Sr ratios range from 0.708 to as high as 0.720. The three Rb-Sr isochrons defined by the data agree with K-Ar age determinations and show that the stocks were emplaced during the Late Cretaceous, between about 70 and 80 m.y. ago. The field, petrologic, and geochemical data indicate that the plutons had a multistage origin that involved large-scale melting of sialic crust, emplacement of magmas derived from batholithic fractionation at depth, and subsequent evolution of these magmas to generate small volumes of more highly evolved residual magmas. Although evolution of the granite complexes was largely governed by crystal-melt fractionation, some minor-element variations in the highly evolved granites cannot be explained by this process. For example, the distribution of rubidium and the light rare-earths appears to have been influenced by volatile depletion at the final stages of crystallization. The field data, petrologic data, and variation trends, such as distinct shifts toward higher albite contents in the residual granites, suggest that the coexistence of a volatile phase was important in their evolution. These results require that models seeking to explain compositional gradients in high-level granite (rhyolite) systems fully consider the role of a coexisting volatile phase.

Alaska↗

USGS1983

Distribution of differentiated tholeiitic basalts on the lower east rift zone of Kilauea Volcano, Hawaii: A possible guide to geothermal exploration

Geologic mapping of the lower east rift zone of Kilauea Volcano, Hawaii, indicates that more than 100 eruptions have extruded an estimated 10 km 3 of basalt during the past 2,000 yr. Six eruptions in the past 200 yr have extruded about 1 km 3 . The eruptive recurrence interval has ranged from 1 to 115 yr since the middle 18th century and has averaged 20 yr or less over the past 2,000 yr. One hundred new chemical analyses indicate that the erupted tholeiites commonly are differentiated beyond olivine control or are hybrid mixtures of differentiates with more mafic (olivine-controlled) summit magmas. The distribution of vents for differentiated lavas indicates that several large magma chambers underlie the lower east rift zone. Several workers have recognized that a chamber underlies the area near a producing well, HGP-A; petrologic and 14 C data indicate that it has existed for at least 1,300 yr. Stratigraphy, petrology, and surface deformation patterns suggest that two other areas, Heiheiahulu and Kaliu, also overlie large magma chambers and appear to be favorable geothermal prospects.

Geology↗

USGS2014

U-Pb zircon geochronology of plutonism in the northern Peninsular Ranges batholith, southern California: Implications for the Late Cretaceous tectonic evolution of southern California

Utilizing both sensitive high-resolution ion microprobe (SHRIMP) and conventional isotope dilution–thermal ionization mass spectrometry (ID-TIMS) methods, crystallization and/or emplacement ages have been obtained for a suite of Cretaceous intermediate-composition plutonic samples collected along a roughly E-W–trending traverse through the northern Peninsular Ranges batholith. Previously noted petrologic, mineralogic, and textural differences delineated four major zonations from west to east and raised the need for detailed geochemical and isotopic work. U-Pb zircon geochronology establishes that these zonations are essentially temporally separate. Mean 206 Pb/ 238 U ages date the three older zones from west to east at 126–107 Ma, 107–98 Ma, and 98–91 Ma. Despite petrologic differences, a relatively smooth progression of magmatism is seen from west to east. A fourth zone is defined by magmatism at ca. 85 Ma, which represents emplacement of deeper-level plutons east of the Eastern Peninsular Ranges mylonite zone in an allochthonous thrust sheet in the northeastern Peninsular Ranges batholith. The age data presented here differ slightly from those presented in earlier work for similar rocks exposed across the middle and southern portions of the Peninsular Ranges batholith in that our data define a relatively smooth progression of magmatism from west to east, and that the transition from western-type to eastern-type plutonism is interpreted to have occurred at ca. 98 Ma and not at ca. 105 Ma. The progressive involvement of older crustal components in the enrichment of eastern Peninsular Ranges batholith–type magma sources is documented by the occurrence of Proterozoic zircon inheritance within samples of the eastern part of the batholith.

Book chapter↗

USGS2007

Time, space, and composition relations among northern Nevada intrusive rocks and their metallogenic implications

Northern Nevada contains &sim;360 igneous intrusions subequally distributed among three age groups: middle Tertiary, Cretaceous, and Jurassic. These intrusions are dominantly granodiorite and monzogranite, although some are more mafic. Major-oxide and trace-element compositions of intrusion age groups are remarkably similar, forming compositional arrays that are continuous, overlapping, and essentially indistinguishable. Within each age group, compositional diversity is controlled by a combination of fractional crystallization and two-component mixing. Mafic intrusions represent mixing of mantle-derived magma and assimilated continental crust, whereas intermediate to felsic intrusions evolved by fractional crystallization. Several petrologic parameters suggest that the northern Nevada intrusion age groups formed in a variety of subduction-related, magmatic arc settings: Jurassic intrusions were likely formed during backarc, slab-window magmatism related to breakoff of the Mezcalera plate; Cretaceous magmatism was related to rapid, shallow subduction of the Farallon plate and consequent inboard migration of arc magmatism; and Tertiary magmatism initially swept southward into northern Nevada in response to foundering of the Farallon plate and was followed by voluminous Miocene bimodal magmatism associated with backarc continental rifting. Nearly 3000 hydrothermal mineral deposits (many only small uneconomic occurrences), of diverse size and type, are spatially and (or) genetically associated with northern Nevada intrusions; significantly, the largest and most important deposits are aligned along prominent mineral-deposit trends. Because northern Nevada is a globally significant metallogenic province, determining whether age, modal composition, and geochemical features of associated intrusive rocks discriminate productive intrusions is important. Mineral-deposit types, including W vein and skarn, polymetallic vein, distal disseminated Au-Ag, porphyry Cu-Mo-W-Au, and epithermal Ag-Au deposits, all spatially and genetically associated with intrusions and known to involve magmatic inputs, are emphasized in this analysis. In addition, although evidence for a direct magmatic input, other than heat, is scarce for Carlin-type gold deposit formation, this deposit type was included because of its economic significance. Consequently, intrusions along mineral-deposit trends, in particular those associated with the largest and economically most significant mineral deposits, were a focus of the investigation. Importantly, modal composition, age, and geochemical characteristics of intrusions associated with large mineral deposits along the trends, are indistinguishable from non-mineralized intrusions in northern Nevada and thus do not identify intrusions associated with significant deposits. Moreover, intrusion age and composition show little correlation with mineral-deposit type, abundance, and size. Given the lack of diagnostic characteristics for intrusions associated with deposits, it is uncertain whether age, modal composition, and geochemical data can identify intrusions associated with mineral deposits. These findings suggest that associations between northern Nevada intrusions and mineral deposits reflect superimposition of many geologic factors, none of which was solely responsible for mineral-deposit formation. These factors might include intrusion size, efficiency of fluid and metal extraction from magma, prevailing redox and sulfidation conditions, or derivation of metals and ligands from host rocks and groundwater. The abundance and diversity of mineral deposits in northern Nevada may partly reflect geochemical inheritance, for example, along the mineral trends rather than the influence of petrologically unique magma or associated fluids.

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