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USGS2006

State summaries: Kentucky

Kentucky mines coal, limestone, clay, sand and gravel. Coal mining operations are carried out mainly in the Western Kentucky Coal Field and the Eastern Kentucky Coal field. As to nonfuel minerals, Mississippian limestones are mined in the Mississippian Plateaus Region and along Pine Mountain in southeastern Kentucky. Ordovician and Silurian limestones are mined from the central part of the state. Clay minerals that are mined in the state include common clay, ceramic and ball clays, refractory clay and shale. Just like in 2004, mining activities in the state remain significant.

Mining Engineering↗

USGS1982

Chemical and mineralogical analysis of devonian black-shale samples from Martin County, Kentucky; Carroll and Washington counties, Ohio; Wise County, Virginia; and Overton County, Tennessee, U.S.A.

Core samples of Devonian shales from five localities in the Appalachian basin have been analyzed chemically and mineralogically. The amounts of major elements are similar; however, the minor constituents, organic C, S, phosphate and carbonate show ten-fold variations in amounts. Trace elements Mo, Ni, Cu, V, Co, U, Zn, Hg, As and Mn show variations in amounts that can be related to the minor constituents. All samples contain major amounts of quartz, illite, two types of mixed-layer clays, and chlorite in differing quantities. Pyrite, calcite, feldspar and kaolinite are also present in many samples in minor amounts. Dolomite, apatite, gypsum, barite, biotite and marcasite are present in a few samples in trace amounts. Trace elements listed above are strongly controlled by organic C with the exception of Mn which is associated with carbonate minerals. Amounts of organic C generally range from 3 to 6%, and S is in the range of 2-5%. Amounts of trace elements show the following general ranges in ppm (parts per million): Co, 20-40; Cu, 40-70; U, 10-40; As, 20-40; V, 150-300; Ni, 80-150; high values are as much as twice these values. The organic C was probably the concentrating agent, and the organic C and sulfide S together created an environment that immobilized and preserved these trace elements. Closely spaced samples showing an abrupt transition in color also show changes in organic C, S and trace-element contents. Several associations exist between mineral and chemical content. Pyrite and marcasite are the only minerals found to contain sulfide-S. In general, the illite-chlorite mixed-layer clay mineral shows covariation with organic C if calcite is not present. The enriched trace elements are not related to the clay types, although the clay and organic matter are intimately associated as the bulk fabric of the rock. ?? 1982.

Chemical Geology↗

USGS2014

Deposit model for heavy-mineral sands in coastal environments

This report provides a descriptive model of heavy-mineral sands, which are sedimentary deposits of dense minerals that accumulate with sand, silt, and clay in coastal environments, locally forming economic concentrations of the heavy minerals. This deposit type is the main source of titanium feedstock for the titanium dioxide (TiO 2 ) pigments industry, through recovery of the minerals ilmenite (Fe 2+ TiO 3 ), rutile (TiO 2 ), and leucoxene (an alteration product of ilmenite). Heavy-mineral sands are also the principal source of zircon (ZrSiO 4 ) and its zirconium oxide; zircon is often recovered as a coproduct. Other heavy minerals produced as coproducts from some deposits are sillimanite/kyanite, staurolite, monazite, and garnet. Monazite [(Ce,La,Nd,Th)PO 4 ] is a source of rare earth elements as well as thorium, which is used in thorium-based nuclear power under development in India and elsewhere. The processes that form coastal deposits of heavy-mineral sands begin inland. High-grade metamorphic and igneous rocks that contain heavy minerals weather and erode, contributing detritus composed of sand, silt, clay, and heavy minerals to fluvial systems. Streams and rivers carry the detritus to the coast, where they are deposited in a variety of coastal environments, such as deltas, the beach face (foreshore), the nearshore, barrier islands or dunes, and tidal lagoons, as well as the channels and floodplains of streams and rivers in the coastal plain. The sediments are reworked by waves, tides, longshore currents, and wind, which are effective mechanisms for sorting the mineral grains on the basis of differences in their size and density. The finest-grained, most dense heavy minerals are the most effectively sorted. The result is that heavy minerals accumulate together, forming laminated or lens-shaped, heavy-mineral-rich sedimentary packages that can be several meters and even as much as tens of meters thick. Most economic deposits of heavy-mineral sands are Paleogene, Neogene, and Quaternary in age; some are modern coastal deposits. Superimposed on these basic processes of ore formation are a multitude of contributing and modifying factors, such as the following: Strong, sustained wave action moves sand from offshore to the shore, where the sand and heavy minerals are sorted by size and density. Mineral sorting occurs mainly on the upper part of the hightide swash (wave) zone. Fine-grained sands and heavy minerals on the foreshore can be remobilized by winds, forming heavy mineral-rich sand dunes behind the beach. Longshore drift combined with the geomorphology of the coast exert strong influence on the location of the heavy-mineral sands deposits. Sea level changes are a function of climatic changes, such as ice ages. Rises in regional sea level (transgression) and lowering of sea level (regression) strongly influence the deposition and preservation of heavy-mineral sands. The majority of heavy-mineral sands accumulation appears related to seaward progradation of the shore during regression events. Local faulting may affect the geomorphology of the coast, which controls the distribution of heavy mineral deposition in a coastal basin. Heavy mineral grains appear to weather primarily after their deposition in the coastal plain; this weathering is caused by groundwaters, humic acids, and other intrabasinal fluids. This weathering can enhance the TiO 2 content of ilmenite. Iron is leached from ilmenite during weathering, which thereby upgrades the TiO 2 content of the ilmenite, forming leucoxene. The resulting deposits of heavy-mineral sands can be voluminous. Individual bodies of heavy mineral-rich sands are typically about 1 kilometer wide and more than 5 kilometers long. Many heavy-mineral sands districts extend for more than 10 kilometers and contain several individual deposits that are spread along an ancient or modern strandline. Reported thicknesses of economic deposits range from 3 to 45 meters. Individual ore deposits typically comprise at least 10 megatonnes of ore (the total size of the individual sand-silt body), whose overall heavy-mineral content is 2 to greater than 10 percent. Heavy-mineral sands deposits are relatively easy to mine because they are weakly to poorly consolidated, and they are relatively easy to process. From a geoenvironmental standpoint, mining of heavy mineral-sands generates little or no acid or solubilized metals. However, environmental and human health concerns related to such mining include potential effects on indigenous flora and fauna, effects on local hydrology, and issues related to processing and storing thorium-bearing monazite, owing to its radioactivity. Regional exploration for deposits of heavy-mineral sands can utilize the analyses of stream sediment samples for Ti, Hf, the rare earth elements, Th, and U, and geophysical surveys, particularly radiometric (gamma-ray spectrometry for K, U, and Th) and magnetic methods. Geophysical anomalies may be small, and surveys are generally more successful when conducted close to sources of interest.

Scientific Investigations Report↗

USGS2024

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine↗

USGS2023

Sequestration and reoxidation of chromium in experimental microcosms

Groundwater containing hexavalent chromium, Cr(VI), downgradient from the Pacific Gas and Electric Company (PG&E) Hinkley compressor station in the Mojave Desert, 80 miles northeast of Los Angeles, California, is undergoing bioremediation using added ethanol as a reductant in a volume of the aquifer defined as the in situ reactive zone (IRZ). This treatment reduces Cr(VI) to trivalent chromium, Cr(III), which is rapidly sequestered by sorption to aquifer particle surfaces and by co-precipitation within iron (Fe) or manganese (Mn) bearing minerals forming in place as reduction proceeds. Successful mitigation of the Cr(VI) plume is projected to require 10–95 years, at which time bioremediation with ethanol will likely cease. This projection assumes that Cr(VI) removal is permanent and that no Cr(III) will oxidize back to Cr(VI) in the event of changing hydrologic conditions that may cause oxygen-rich water to re-enter the IRZ. Laboratory microcosm experiments were done to explore the process of reductive sequestration of Cr(VI) to Cr(III) and the potential for reoxidation of Cr(III) to Cr(VI). In reductive sequestration experiments, batch microcosms were prepared with aquifer materials collected from sites upgradient of the Cr(VI) regulatory plume. Control microcosms were prepared using Fe- and Mn-coated quartz sand. Unfiltered Mojave River groundwater containing an added tracer of isotopically labeled chromium-50 were reacted with microcosm materials for up to 2 years; during this time, bio-reduction was stimulated by repeated additions of diluted ethanol to maintain reduced conditions within appropriate ranges, avoiding sulfate reducing or methanogenic conditions as much as possible while mimicking field conditions. Analysis of chromium-50, Fe, and Mn obtained by sequential extraction from microcosms harvested (incubation terminated and microcosm contents analyzed) at various times showed that some aqueous chromium (Cr) was sorbed to particle surfaces within hours; reduction to Cr(III) and incorporation into amorphous and crystalline solid phases occurred during the next few months. Amorphous Cr-containing fractions included Fe and Mn hydroxides and organic matter. Ultimately, most of the chromium-50 tracer was present in the less reactive crystalline phase. However, Fe and Mn were broadly distributed at later stages of reduction, and both were spatially co-located with Cr on a micrometer (μm) scale. Solid-phase data collected using scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) and X-ray absorption spectroscopy (XAS) indicated that some Cr(III) was associated with mixed valence Fe oxides like magnetite and Fe-Mn oxides like jacobsite. Additionally, Cr(III) was observed within several μm of Fe and Mn embedded in clays and in mineral coatings. To evaluate the potential for reoxidation of Cr(III) to Cr(VI), additional batch microcosms of aquifer materials and mixtures of Fe- and Mn-coated sand were first reduced for more than 1 year and subsequently oxidized for almost 2 years. Hexavalent chromium was formed and was available for release to the aqueous phase during oxidation of all materials; however, the timing and amount of Cr(VI) formed and released varied among substrates. Artificial substrates containing more Mn produced more Cr(VI). Site material characteristic of recent Mojave River deposits contained within the IRZ produced the least Cr(VI) during oxidation, while site materials composed of older Mojave River aquifer material (containing more Mn) produced more Cr(VI). Site material collected from within the IRZ contained more Cr but produced an intermediate amount of Cr(VI) following oxidation. The combined results of microcosm chemistry and solid-phase analyses showed that the nature and locus of Cr(III) sequestration influenced its vulnerability to reoxidation to Cr(VI). It was concluded that co-location of Cr with Mn at later stages of reduction influenced the susceptibility of Cr(III) to reoxidation in microcosms. Reoxidation of Cr(III) to Cr(VI) was observed in experiments with previously reduced material after just 14 days exposure to oxygen. As much as 10 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using recent Mojave River aquifer material, and as much as 20 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using older Mojave River aquifer material. Less Cr(VI) (less than 3 percent of Cr added before reduction) was released to the aqueous phase, and this release occurred following longer oxygen exposure. Site managers may need to plan for long-term monitoring and the possibility of active maintenance of anoxic conditions within the IRZ to ensure permanent sequestration of Cr after bioremediation with ethanol ceases.

California↗

USGS2016

Rare earth element deposits in China

China is the world’s leading rare earth element (REE) producer and hosts a variety of deposit types. Carbonatite- related REE deposits, the most significant deposit type, include two giant deposits presently being mined in China, Bayan Obo and Maoniuping, the first and third largest deposits of this type in the world, respectively. The carbonatite-related deposits host the majority of China’s REE resource and are the primary supplier of the world’s light REE. The REE-bearing clay deposits, or ion adsorption-type deposits, are second in importance and are the main source in China for heavy REE resources. Other REE resources include those within monazite or xenotime placers, beach placers, alkaline granites, pegmatites, and hydrothermal veins, as well as some additional deposit types in which REE are recovered as by-products. Carbonatite-related REE deposits in China occur along craton margins, both in rifts (e.g., Bayan Obo) and in reactivated transpressional margins (e.g., Maoniuping). They comprise those along the northern, eastern, and southern margins of the North China block, and along the western margin of the Yangtze block. Major structural features along the craton margins provide first-order controls for REE-related Proterozoic to Cenozoic carbonatite alkaline complexes; these are emplaced in continental margin rifts or strike-slip faults. The ion adsorption-type REE deposits, mainly situated in the South China block, are genetically linked to the weathering of granite and, less commonly, volcanic rocks and lamprophyres. Indosinian (early Mesozoic) and Yanshanian (late Mesozoic) granites are the most important parent rocks for these REE deposits, although Caledonian (early Paleozoic) granites are also of local importance. The primary REE enrichment is hosted in various mineral phases in the igneous rocks and, during the weathering process, the REE are released and adsorbed by clay minerals in the weathering profile. Currently, these REE-rich clays are primarily mined from open-pit operations in southern China. The complex geologic evolution of China’s Precambrian blocks, particularly the long-term subduction of ocean crust below the North and South China blocks, enabled recycling of REE-rich pelagic sediments into mantle lithosphere. This resulted in the REE-enriched nature of the mantle below the Precambrian cratons, which were reactivated and thus essentially decratonized during various tectonic episodes throughout the Proterozoic and Phanerozoic. Deep fault zones within and along the edges of the blocks, including continental rifts and strike-slip faults, provided pathways for upwelling of mantle material.

Book chapter↗

USGS2013

Evaluation of Pleistocene groundwater flow through fractured tuffs using a U-series disequilibrium approach, Pahute Mesa, Nevada, USA

Groundwater flow through fractured felsic tuffs and lavas at the Nevada National Security Site represents the most likely mechanism for transport of radionuclides away from underground nuclear tests at Pahute Mesa. To help evaluate fracture flow and matrix–water exchange, we have determined U-series isotopic compositions on more than 40 drill core samples from 5 boreholes that represent discrete fracture surfaces, breccia zones, and interiors of unfractured core. The U-series approach relies on the disruption of radioactive secular equilibrium between isotopes in the uranium-series decay chain due to preferential mobilization of 234 U relative to 238 U, and U relative to Th. Samples from discrete fractures were obtained by milling fracture surfaces containing thin secondary mineral coatings of clays, silica, Fe–Mn oxyhydroxides, and zeolite. Intact core interiors and breccia fragments were sampled in bulk. In addition, profiles of rock matrix extending 15 to 44 mm away from several fractures that show evidence of recent flow were analyzed to investigate the extent of fracture/matrix water exchange. Samples of rock matrix have 234 U/ 238 U and 230 Th/ 238 U activity ratios (AR) closest to radioactive secular equilibrium indicating only small amounts of groundwater penetrated unfractured matrix. Greater U mobility was observed in welded-tuff matrix with elevated porosity and in zeolitized bedded tuff. Samples of brecciated core were also in secular equilibrium implying a lack of long-range hydraulic connectivity in these cases. Samples of discrete fracture surfaces typically, but not always, were in radioactive disequilibrium. Many fractures had isotopic compositions plotting near the 230 Th- 234 U 1:1 line indicating a steady-state balance between U input and removal along with radioactive decay. Numerical simulations of U-series isotope evolution indicate that 0.5 to 1 million years are required to reach steady-state compositions. Once attained, disequilibrium 234 U/ 238 U and 230 Th/ 238 U AR values can be maintained indefinitely as long as hydrological and geochemical processes remain stable. Therefore, many Pahute Mesa fractures represent stable hydrologic pathways over million-year timescales. A smaller number of samples have non-steady-state compositions indicating transient conditions in the last several hundred thousand years. In these cases, U mobility is dominated by overall gains rather than losses of U.

Nevada↗

USGS2011

Geochemistry of environmentally sensitive trace elements in Permian coals from the Huainan coalfield, Anhui, China

To study the geochemical characteristics of 11 environmentally sensitive trace elements in the coals of the Permian Period from the Huainan coalfield, Anhui province, China, borehole samples of 336 coals, two partings, and four roof and floor mudstones were collected from mineable coal seams. Major elements and selected trace elements were determined by inductively coupled plasma optical emission spectrometry (ICP-OES), inductively coupled plasma mass spectrometry (ICP-MS), and hydride generation atomic absorption spectrometry (HAAS). The depositional environment, abundances, distribution, and modes of occurrence of trace elements were investigated. Results show that clay and carbonate minerals are the principal inorganic constituents in the coals. A lower deltaic plain, where fluvial channel systems developed successively, was the likely depositional environment of the Permian coals in the Huainan coalfield. All major elements have wider variation ranges than those of Chinese coals except for Mg and Fe. The contents of Cr, Co, Ni, and Se are higher than their averages for Chinese coals and world coals. Vertical variations of trace elements in different formations are not significant except for B and Ba. Certain roof and partings are distinctly higher in trace elements than underlying coal bench samples. The modes of occurrence of trace elements vary in different coal seams as a result of different coal-forming environments. Vanadium, Cr, and Th are associated with aluminosilicate minerals, Ba with carbonate minerals, and Cu, Zn, As, Se, and Pb mainly with sulfide minerals.

Huainan coalfield↗

USGS2009

Provenance of Holocene sediment on the Chukchi-Alaskan margin based on combined diffuse spectral reflectance and quantitative X-Ray Diffraction analysis

Sediment clay and silt mineral assemblages provide an excellent means of assessing the provenance of fine-grained Arctic sediment especially when a unique mineral assemblage can be tied to specific source areas. The diffuse spectral reflectance (DSR) first derivative measurements and quantitative X-Ray Diffraction (qXRD) on a high-resolution sediment core from the continental slope north of Alaska constrain the sediment mineralogy. DSR results are augmented by measurements on several adjacent cores and compared to surface sediment samples from the northern Alaskan shelf and slope. Using Principal Component Analysis (PCA), we infer that the three leading DSR modes relate to mixtures of smectite + dolomite, illite + goethite, and chlorite + muscovite. This interpretation is consistent with the down core qXRD results. While the smectite + dolomite, and illite + goethite factors show increased variability down core, the chlorite + muscovite factor had highest positive loadings in the middle Holocene, between ca. 6.0 and 3.6??ka. Because the most likely source of the chlorite + muscovite suite in this vicinity lies in the North Pacific, we argue that the oscillations in chlorite + muscovite values likely reflect an increase in the inflow of Pacific water to the Arctic through the Bering Strait. The time interval of this event is associated in other parts of the globe with a non-linear response of the climate system to the decrease in insolation, which may be related to changes in water exchange between the Pacific and Arctic Ocean. ?? 2009 Elsevier B.V.

Global and Planetary Change↗

USGS2018

Geochemistry and mineralogy of late Quaternary loess in the upper Mississippi River valley, USA: Provenance and correlation with Laurentide Ice Sheet history

The midcontinent of North America contains some of the thickest and most extensive last-glacial loess deposits in the world, known as Peoria Loess. Peoria Loess of the upper Mississippi River valley region is thought to have had temporally varying glaciogenic sources resulting from inputs of sediment to the Mississippi River from different lobes of the Laurentide Ice Sheet. Here, we explore a new method of determining loess provenance using K/Rb and K/Ba values (in K-feldspars and micas) in loess from a number of different regions in North America. Results indicate that K/Rb and K/Ba values can distinguish loess originating from diverse geologic terrains in North America. Further, different loess bodies that are known to have had the same source sediments (using other criteria) have similar K/Rb and K/Ba values. We also studied three thick loess sections in the upper Mississippi River valley region. At each site, the primary composition of the loess changed over the course of the last glacial period, and K/Rb and K/Ba values parallel changes in carbonate mineral content and clay mineralogy. We thus confirm conclusions of earlier investigators that loess composition changed as a result of the shifting dominance of different lobes of the Laurentide Ice Sheet and the changing course of the Mississippi River. We conclude that K/Rb and K/Ba values are effective, robust, and rapid indicators of loess provenance that can be applied to many regions of the world.

Quaternary Science Reviews↗

USGS2013

Characterizing regional soil mineral composition using spectroscopyand geostatistics

This work aims at improving the mapping of major mineral variability at regional scale using scale-dependent spatial variability observed in remote sensing data. Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and statistical methods were combined with laboratory-based mineral characterization of field samples to create maps of the distributions of clay, mica and carbonate minerals and their abundances. The Material Identification and Characterization Algorithm (MICA) was used to identify the spectrally-dominant minerals in field samples; these results were combined with ASTER data using multinomial logistic regression to map mineral distributions. X-ray diffraction (XRD)was used to quantify mineral composition in field samples. XRD results were combined with ASTER data using multiple linear regression to map mineral abundances. We testedwhether smoothing of the ASTER data to match the scale of variability of the target sample would improve model correlations. Smoothing was donewith Fixed Rank Kriging (FRK) to represent the mediumand long-range spatial variability in the ASTER data. Stronger correlations resulted using the smoothed data compared to results obtained with the original data. Highest model accuracies came from using both medium and long-range scaled ASTER data as input to the statistical models. High correlation coefficients were obtained for the abundances of calcite and mica (R2 = 0.71 and 0.70, respectively). Moderately-high correlation coefficients were found for smectite and kaolinite (R2 = 0.57 and 0.45, respectively). Maps of mineral distributions, obtained by relating ASTER data to MICA analysis of field samples, were found to characterize major soil mineral variability (overall accuracies for mica, smectite and kaolinite were 76%, 89% and 86% respectively). The results of this study suggest that the distributions of minerals and their abundances derived using FRK-smoothed ASTER data more closely match the spatial variability of soil and environmental properties at regional scale.

Remote Sensing of Environment↗

USGS2017

A loess–paleosol record of climate and glacial history over the past two glacial–interglacial cycles (~ 150 ka), southern Jackson Hole, Wyoming

Loess accumulated on a Bull Lake outwash terrace of Marine Oxygen Isotope Stage 6 (MIS 6) age in southern Jackson Hole, Wyoming. The 9 m section displays eight intervals of loess deposition (Loess 1 to Loess 8, oldest), each followed by soil development. Our age-depth model is constrained by thermoluminescence, meteoric 10 Be accumulation in soils, and cosmogenic 10 Be surface exposure ages. We use particle size, geochemical, mineral-magnetic, and clay mineralogical data to interpret loess sources and pedogenesis. Deposition of MIS 6 loess was followed by a tripartite soil/thin loess complex (Soils 8, 7, and 6) apparently reflecting the large climatic oscillations of MIS 5. Soil 8 (MIS 5e) shows the strongest development. Loess 5 accumulated during a glacial interval (~ 76–69 ka; MIS 4) followed by soil development under conditions wetter and probably colder than present. Deposition of thick Loess 3 (~ 43–51 ka, MIS 3) was followed by soil development comparable with that observed in Soil 1. Loess 1 (MIS 2) accumulated during the Pinedale glaciation and was followed by development of Soil 1 under a semiarid climate. This record of alternating loess deposition and soil development is compatible with the history of Yellowstone vegetation and the glacial flour record from the Sierra Nevada.

Wyoming↗

USGS1957

Magmatic, connate, and metamorphic waters

Some major types of water of “deep” origin are believed to be recognizable from their chemical and isotopic compositions. Oil-field brines dominated by sodium and calcium chlorides differ markedly from average ocean water. In general, the brines are believed to be connate in origin (“fossil” sea water) with a negligible to high proportion of meteoric water. Many brines, particularly in pre-Tertiary rocks, are much higher in salinity than sea water and are greatly enriched in calcium as well as sodium chloride. Brines near the salinity of sea water are generally higher, relative to sea water, in bicarbonate, iodine, boron, lithium, silica, ammonium, and water-soluble organic compounds, and lower in sulfate, potassium, and magnesium. Many changes take place after sea water is entrapped in newly deposited marine sediments: (1) Iodine, silicon, boron, nitrogen, and other elements have been selectively concentrated in organisms that decompose during and after burial in sediments. Many of the elements may redissolve in the interstitial water. (2) Bacteria are active in the sediments and reduce sulfate to sulfide and produce methane, ammonia, carbon dioxide, and other products. (3) Some elements have been selectively removed from sea water by inorganic processes, such as adsorption on clays and colloidal matter. When this matter is reconstituted by diagenetic and other changes, some components are redissolved. The abundance of lithium and possibly boron and other elements may be controlled to a considerable extent by these inorganic processes. (4) The interstitial water may react chemically with enclosing sediments and produce dolomite, reconstituted clays, and other minerals. The high loss of magnesium relative to calcium in most connate waters is probably caused by such reactions. Volcanic hot-spring waters of different compositions have been discussed in an accompanying paper (White, 1957). The most significant type is believed to be dominated by sodium chloride, and is best explained as originating from dense gases driven at high temperature and pressure from magma and containing much matter of low volatility that is in solution because of the solvent properties of high-density steam. This dense vapor is condensed in and greatly diluted by deeply circulating meteoric water. Most other types of volcanic water are believed to be derived from the sodium-chloride type. Volcanic sodium-chloride waters are similar in many respects to connate waters but are believed to be distinguishable by relatively high lithium, fluorine, silica, boron, sulfur, CO 2 , arsenic, and antimony; by relatively low calcium and magnesium; and by lack of hydrocarbons, water-soluble organic compounds, and perhaps ammonia and nitrate. Relatively high boron and combined CO 2 are alone not reliable indicators of a volcanic origin. During compaction, rocks lose most of their interstitial high-chloride water; much additional water may then be lost during progressive metamorphism, and the content changes from about 5 per cent in shale to perhaps 1 per cent in gneiss. This expelled water is here called metamorphic. Because of pressure and permeability gradients, it must normally escape upward and mix with connate and meteoric water. Even though large quantities must exist, no example of metamorphic water has been positively identified. Some thermal springs in California are high in salinity and relatively low in temperature and apparent associated heat flow. Some are clearly connate in origin. Other springs are characterized by very high combined carbon dioxide and boron, relative to chloride. Their compositions are considerably different from known connate and volcanic waters and are believed to be best explained by a metamorphic origin. Although some major types of deep water seem to be recognizable, there is much danger of oversimplifying the problems. Many waters are no doubt mixtures of different types, and some of high salinity result from dissolution of salts by meteoric water.

GSA Bulletin↗

USGS1967

Stratigraphy and paleoenvironment of the phosphatic miocene strata of North Carolina

Foraminifera and Mollusca collected from the phosphatic Pungo River Formation and the overlying Yorktown Formation in eastern North Carolina were analyzed and interpreted for stratigraphic and environmental significance in order to determine optimum depositional sites for primary phosphorite. The Mollusca and benthonic foraminifera of the Pungo River Formation correlate with those of the Calvert Formation of Maryland, and the planktonic foraminifera in both of these formations correlate with the Globigerinatella insueta zone of Trinidad, postulated as late Aquitanian age. The paleoenvironment of the phosphorite deposition, interpreted primarily from the benthonic foraminifera, was of cool-temperate waters, ranging in depth from 100 to 200 m in the phosphatic beds to less than 70 m in the upper calcareous beds where phosphate is scarce. Phosphorite deposition occurred in an oceanic embayment located south of the Fort Monroe high in southern Virginia and north of a positive feature whose axis lies in the vicinity of New Bern, North Carolina . Cool-temperate waters in this area during Pungo River time indicate that circulation patterns of ocean currents and the resultant faunal provinces were not the same as those at present and later in the Miocene . In the Pungo River and its time equivalents of the Atlantic Coastal Plain, the presence of thick diatomaceous clay units, volcanic ash beds, shards, attapulgite clays, and other minerals probably derived from volcanic rocks, suggests a volcanic source somewhere off the coast during the Miocene . The Yorktown unconformably overlies the Pungo River Formation. The unconformity is marked by channels into the Pungo River, filled with phosphatic pebbles, vertebrate bones, and lower York-town molluscs and microfauna. The coarse-grained phosphatic material is derived from the underlying fine-grained primary phosphorite in the Pungo River and is abundant only in the lower part of the Yorktown Formation. Deposition of the lower part of the Yorktown occurred in waters about 100 m deep. The waters gradually became more shallow as deposition of the formation continued until depths of less than 15 m, and probable brackish conditions, were reached as the uppermost part of the formation was deposited. Temperature of the waters, cool-temperate during lower Yorktown deposition, became warm-temperate to subtropical in later Yorktown time. The faunal patterns suggest that circulation patterns reached their present state during late Yorktown time.

North Carolina↗

USGS1997

Mapping hydrothermally altered rocks on Mount Rainier, Washington, with Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data

Mount Rainier has produced numerous Holocene debris flows, the largest of which contain clays and other minerals derived from hydrothermally altered rocks on the volcano's edifice. Imagery from an advanced airborne sensor was used to map altered rocks at Mount Rainier and demonstrates their distinctly nonuniform distribution. The mapping of altered rocks helps to identify edifice failure surfaces and to recognize the source areas for the largest debris flow events. Remote sensing methods like those used at Mount Rainier can enhance ground-based mapping efforts and should prove useful for rapidly identifying hazardous sectors at other volcanoes.

Geology↗

USGS2001

Leg 188 synthesis: Transitions in the glacial history of the Prydz Bay region, East Antarctica, from ODP drilling

Drilling during Leg 119 (1988) and Leg 188 (2000; Sites 1165–1167) of the Ocean Drilling Program (ODP) provides direct evidence for long- and short-term changes in Cenozoic paleoenvironments in the Prydz Bay region. Cores from across the continental margin reveal that in preglacial times the present shelf was an alluvial plain system with austral conifer woodland in the Late Cretaceous that changed to cooler Nothofagus rainforest scrub by the middle to late Eocene (Site 1166). Earliest recovered evidence of nearby mountain glaciation is seen in late Eocene–age grain textures in fluvial sands. In the late Eocene to early Oligocene, Prydz Bay permanently shifted from being a fluvio-deltaic complex to an exclusively marine continental shelf environment. This transition is marked by a marine flooding surface later covered by overcompacted glacial sediments that denote the first advance of the ice sheet onto the shelf. Cores do not exist for the early Oligocene to early Miocene, and seismic data are used to infer the transition from a shallow to normal depth prograding continental shelf with submarine canyons on the slope and channel/levees on the rise. Cores from the continental rise at Site 1165 show long-term (millions of years) early Miocene and younger decreases in sedimentation rates as well as short-term (Milankovitch periods) cyclicity between principally biogenic and terrigenous sediment supply—resulting from the cyclic presence of onshore glaciers and changes in ocean circulation. Middle Miocene transitions include rapid decreases in sedimentation rates, increased ice-rafted debris, shifts in clays and other minerals, and regional erosion of the slope and rise. These transitions may reflect enhanced glacial erosion and reduced glacial meltwater from progressively colder ice. At this time, seismic data show that depocenters began to shift from the outer continental rise to the base of the continental slope coincident with the initial stages of the glacial erosion and overdeepening of the continental shelf. During the late Miocene to early Pliocene there was a transition to greater subglacial activity on the shelf and more pronounced cyclic facies variations on the continental rise. At this time, severe glacial morphologies initiated on the shelf with the erosion of Prydz Channel and other troughs by fast-moving ice and the deposition of overcompacted glacial diamictons by slow-moving ice on adjacent banks. The Prydz trough-mouth fan also began to form with alternating deposition of debris flows (ice at shelf edge) and muddy units (reduced ice) (Site 1167). The fan also records a transition during the late Pleistocene for times younger than 780 k.y. when short-term glacial variations continued but ice reached the shelf edge only a few times. Both short-term and long-term transitions characterize the Cenozoic evolution of the Prydz Bay region from the Cretaceous nonglacial to late Neogene full-glacial paleoenvironments. These transitions are known only from ODP cores, and further insights will require additional drilling.

Prydz Bay region↗

USGS2003

Preliminary Mineralogic and Stable Isotope Studies of Altered Summit and Flank Rocks and Osceola Mudflow Deposits on Mount Rainier, Washington

About 5600 years ago part of Mount Rainier?s edifice collapsed with the resultant Osceola Mudflow traveling more than 120 km and covering an area of at least 505 km2. Mineralogic and stable isotope studies were conducted on altered rocks from outcrops near the summit and east flank of the volcano and samples of clasts and matrix from the Osceola Mudflow. Results of these analyses are used to constrain processes responsible for pre-collapse alteration and provide insight into the role of alteration in edifice instability prior to the Osceola collapse event. Jarosite, pyrite, alunite, and kaolinite occur in hydrothermally altered rock exposed in summit scarps formed by edifice collapse events and in altered rock within the east-west structural zone (EWSZ) of the volcano?s east flank. Deposits of the Osceola Mudflow contain clasts of variably altered and unaltered andesite within a clay-rich matrix. Minerals detected in samples from the edifice are also present in many of the clasts. The matrix includes abundant smectite, kaolinite and variably abundant jarosite. Hydrothermal fluid compositions calculated from hydrogen and oxygen isotope data of alunite, and smectite on Mount Rainier reflect mixing of magmatic and meteoric waters. The range in the dD values of modern meteoric water on the volcano (-85 to 155?) reflect the influence of elevation on the dD of precipitation. The d34S and d18OSO4 values of alunite, gypsum and jarosite are distinct but together range from 1.7 to 17.6? and -12.3 to 15.0?, respectively; both parameters increase from jarosite to gypsum to alunite. The variations in sulfur isotope composition are attributed to the varying contributions of disproportionation of magmatic SO2, the supergene oxidation of hydrothermal pyrite and possible oxidation of H2S to the parent aqueous sulfate. The 18OSO4 values of jarosite are the lowest recorded for the mineral, consistent with a supergene origin. The mineralogy and isotope composition of alteration minerals define two and possibly three environments of alteration. At deeper levels magmatic vapor, H2S, SO2 and other gases from venting magmas migrated upward and condensed into the meteoric water. Disproportionation of SO2 into aqueous sulfate and H2S resulted in acid-sulfate (alunite + kaolinite + pyrite) and related argillic and propylitic alteration envelopes in a magmatic hydrothermal environment. At shallow levels H2S reacted with andesite to form pyrite that is associated with smectite along fractures on both the flanks and upper edifice. It is not clear to what extent H2S was oxidized by atmospheric O2 to form aqueous sulfate in a steam-heated environment. Near the ground surface, pyrite is oxidized by atmospheric oxygen resulting in soluble iron-and aluminum-hydroxysulfates. These supergene hydroxysulfates, which may also form around fumaroles from the oxidation of H2S, are subject to continuous solution and redeposition.

Open-File Report↗

USGS1985

Geology and regional setting of the Al Masane ancient mine area, southeastern Arabian Shield, Kingdom of Saudi Arabia

Stratiform zinc-copper massive-sulfide deposits at Al Masane occur in thin dolomitic interbeds within Proterozoic felsic crystal tuff and mafic flows and volcaniclastics. These strata dip steeply westward and are underlain by shale and shaly graywacke to the east and overlain by lapilli crystal tuff to the west. This section is part of the Habawnah fold or mineral belt that extends from the Wadi Wassat area southward into Yemen. Western parts of the Habawnah fold belt, including the Al Masane area, are characterized by a bimodal assemblage of of phenocryst-poor basalts and sodic rhyolite crystal tuff, and by zinc-copper mineral deposits. Strata in the eastern part of the belt, mostly east of the Ashara fault zone, contain abundant phenocryst-rich mafic volcanic rocks, little felsic crystal tuff, and barren or locally nickeliferous massive pyrite deposits. Stratified rocks and gabbro sills of the Al Masane area were isoclinally folded and metamorphosed to the greenschist facies. Structural analysis indicates that foliation, lineation, joints, major and minor folds, and one of three sets of faults formed during a single east-west compressional deformational episode. Axial-plane foliation dips steeply westward and is usually coincident with bedding. Lineation plunges steeply to the northwest throughout the map area and is parallel to the intersection of joints of two major sets and to the intersection of these joints with foliation. Major folds have north-trending, gently plunging axes to which the axis of a minor fold set is essentially parallel. A second minor fold-set has a steeply plunging axis parallel to lineation. The Saadah massive-sulfide body is elongated by a fold of this system. Unmetamorphosed Proterozoic felsic sills, quartz monzonite and gabbro plutons, porphyritic diorite dikes, mafic dikes, and basalt dikes, in that apparent order, have intruded the stratified section. Basalt dikes are offset by southwestward-dipping reverse faults and by faults parallel to bedding. Malachite and metal-oxide-bearing gossans in the Al Masane area were mined in ancient times. Radiocarbon dating of charcoal in slag indicates that the ores were smelted about 1,200 years ago. Gossans are depleted in copper, silver, and zinc, relative to underlying sulfide, by factors of about 0.33, 0.2, and 0.08, respectively. Evaluation of numerous analyses of gossans, carbonates, and silicate rocks indicates that exploration for zinc-copper massive-sulfide deposits in the region should center on detailed geochemical studies of dolomitic beds. Dolomitization of host siliceous shales and tuffs and the formation of the massive-sulfide bodies at Al Masane probably caused by submarine fumarolic hydrothermal activity during periods of relative volcanic quiescence. Further work in the Al Masane region should include a study of the dolomitized areas and a search for other potential alteration "pipe" products (e.g. chlorite) as a guide to location of proximal deposits. Zinc-copper deposits at Al Masane and in the Dhahar-Al Hajrah and Kutam-Farah Garan areas have characteristics in common and are associated with felsic volcanic centers in the western bimodal part of the Habawnah mineral belt. They probably have parallel origins related to sea-floor volcanism. Deposits at Al Masane and Dhahar-Al Hajrah are possibly in the same general stratigraphic interval. Characteristics and distribution of altered rocks at Kutam suggest that the observed structural control of mineralization may represent remobilization. Chemical characteristics of volcanic rocks at Al Masane and elsewhere, along with features such as zinc-copper-iron sulfide mineralization, rhyolite-basalt bimodality, and the quartz phenocryst-rich nature of the felsic rocks, are compatible with an unusually primitive tholeiitic island-arc origin for the strata and mineral deposits of the Habawnah mineral belt.

Open-File Report↗