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Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N 2 from denitrification increases with age. Stable isotopes and excess N 2 imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 μmol N L −1 d −1 , comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.

Journal of Environmental Quality↗

Ground-Water Geology and Hydrology of the Kern River Alluvial-Fan Area, California

The Kern River alluvial fan is the southernmost major alluvial fan built by the streams which drain the west side of the Sierra Nevada. The climate is semiarid with rainfall near 5 inches per year. Agricultural development within the area uses over half the 700,000 acre-feet per year flow of the Kern River, plus a considerable amount drawn from the ground-water reservoir particularly during periods of low flow. The area overlies a deep structural trough between crystalline rocks of the Sierra Nevada and the marine rocks of Tertiary age of the Coast Ranges. The top horizon of the marine rocks that lap on the Sierra Nevada block underlies the report area at an average depth of 2,000 feet. The overlying continental deposits that form the groundwater reservoir consist of alluvial-fan and lacustrine deposits. The continental deposits are subdivided into three lithologic units on the basis of grain size and sorting. The gravel and clay unit consists of older alluvial-fan material, of both Sierra Nevada and Coast Range provenance, that shows extremely poor sorting with some diagenetic decomposition through chemical weathering. The fine sand to clay unit consists principally of fine sand, silt, and clay deposited in a lacustrine environment, although some of the unit is of alluvial-fan origin derived from poorly consolidated marine shale of the Coast Ranges. Within the fine sand to clay unit three distinct clays, which affect ground-water conditions, can be recognized. The gravel to medium sand unit consists of unweathered alluvial-fan material that shows much better sorting than the gravel and clay unit. In the eastern part of the area the basal part of this unit is a gravel lentil that can be traced in the subsurface more than 250 square miles. The overlying deposits consist principally of medium sand. In the western part of the area the unit is a heterogeneous gravel and sand unit. Permeability in Meinzer units of the gravel and clay unit ranges between 10 and 100 with specific yield about 5 percent. For the fine sand to clay unit the permeability ranges between 0.0001 and 100 with about 10 percent specific yield. The gravel to medium sand unit has permeabilities between 100 and 10,000, and specific yield is about 15 percent. For the period 1955-59 the annual gross surface-water supply was estimated at 421,000 acre-feet and pumpage was 664,000 acre-feet, giving a rounded total supply of 1,100,000 acre-feet. Annual consumptive use was estimated at 750,000 acre-feet and annual infiltration at 350,000 acre-feet. The approximate 300,000 acre-feet difference between 664,000 acre-feet pumped and 350,000 acre-feet infiltrated has caused an annual decline in water levels of up to 7 feet. Ground water occurs under both unconfined and confined conditions within the report area. In general, the gravel to medium sand unit contains unconfined water, and the other two units contain confined water. Pumping is less intense in the Kern River fan area than in the adjoining areas to the north or south. This fact, plus infiltration from the Kern River, results in ground-water movement being principally out of the area. There is a ground-water divide that approximately underlies the Kern River. South of the river the flow spreads out semicircularly from the river, and north of the river the flow is linear to the northwest. Based on chemical quality the ground water has been divided areally into (1) east side, (2) west side, and (3) axial water. With the exception of two areas of comparable size northwest of Bakersfield and a much smaller area southeast of that city where ground water is somewhat saline, east-side ground water is generally of the calcium bicarbonate and calcium sodium bicarbonate type of low to medium salinity. The chemical character of east-side ground water is necessarily related to that of Kern River water, the principal source of recharge, and water of intermittent streams which drain the dissected upland

Open-File Report↗

Chemical quality of ground water in Sacramento and Western Placer counties, California

Chemical quality of groundwater was investigated in Sacramento and western Placer Counties during the summer of 1982. Chemical analyses of water samples from 209 wells indicate that the groundwater is suitable for domestic and most agricultural uses. Water from wells near the Sacramento River and a few wells near Lincoln had high concentrations of dissolved solids and some trace elements. Although chemical water types varied, 53% of the wells had a combination of calcium magnesium bicarbonate water. More than 90% of the wells sampled had water with a low to medium sodium-salinity hazard when used for irrigation. (Author 's abstract)

Water-Resources Investigations Report↗

Sediment budgets, transport, and depositional trends in a large tidal delta

The Sacramento-San Joaquin Delta is the largest delta on the west coast of the United States. It is formed where the confluence of California’s two largest rivers (the Sacramento and San Joaquin) meet the ocean tides and has a significant physical gradient from fluvial to tidal. It is a semidiurnal system (two high and two low tides per day). Today, the Delta is one of the most manipulated in the United States. Once composed of many shallow, meandering and braided dendritic channels and dead-end sloughs and wetlands, it is now a network of leveed canals moving clear water around subsided islands. It historically has supported a biologically diverse tidal wetland complex, of which only 3% remains today (Whipple et al., 2012). It has also witnessed a collapse in the native fish populations. The Delta provides critical habitat for native species, however the hydrology and water quality are complicated by manipulations and diversions to satisfy multiple statewide objectives. Today water managers face co-equal goals of water supply to Californians and maintenance of ecosystem health and function. The Delta is a hub for both a multi-hundred-million dollar agricultural industry and a massive north-to-south water delivery system, supplying the primary source of freshwater to Central Valley farmers and drinking water for two-thirds of California’s population. Large pump facilities support the water demand and draw water from the Delta, further altering circulation patterns and redirecting the net flow toward the export facilities (Monsen et al., 2007). Fluvial sedimentation, along with organic accumulation, creates and sustains the Delta landscape. Hydraulic mining for gold in the watershed during the late 1800s delivered an especially large sediment pulse to the Delta. More recently, from 1955 to the present, a significant sediment decline has been observed that is thought to have been caused mostly by the construction of water storage reservoirs that trap the upstream sediment supply (Wright and Schoellhamer, 2004). Today, one concern is whether the volume of sediment supplied from the upper watershed is sufficient to support ecological function and sustain the Delta landscape and ecosystem in the face of climate change, sea level rise, and proposed restoration associated with the Bay Delta Conservation Plan (http://baydeltaconservationplan.com). Ecosystem health is a management focus and 150,000 acres of restoration is currently proposed, therefore it is of increasingly important to understand the quantity of sediment available for marsh and wetland restoration throughout the Bay Delta Estuary. It is also important to understand the pathways for sediment transport and the sediment budget into each of three Delta regions (figure 1) to guide restoration planning, modeling, and management.

California↗

Delta subsidence in California: The sinking heart of the state

The Sacramento-San Joaquin River Delta of California once was a great tidal freshwater marsh blanketed by peat and peaty alluvium. Beginning in the late 1800s, levees were built along the stream channels, and the land thus protected from flooding was drained, cleared, and planted. Although the Delta is now an exceptionally rich agricultural area (over a $500 million crop value in 1993), its unique value is as a source of freshwater for the rest of the State. It is the heart of a massive north-to-south waterdelivery system. Much of this water is pumped southward for use in the San Joaquin Valley and elsewhere in central and southern California. The leveed tracts and islands help to protect water-export facilities in the southern Delta from saltwater intrusion by displacing water and maintaining favorable freshwater gradients. However, ongoing subsidence behind the levees reduces levee stability and, thus, threatens to degrade water quality in the massive north-to-south water-transfer system.

California↗

A perspective on modern pesticides, pelagic fish declines, and unknown ecological resilience in highly managed ecosystems

Pesticides applied on land are commonly transported by runoff or spray drift to aquatic ecosystems, where they are potentially toxic to fishes and other nontarget organisms. Pesticides add to and interact with other stressors of ecosystem processes, including surface-water diversions, losses of spawning and rearing habitats, nonnative species, and harmful algal blooms. Assessing the cumulative effects of pesticides on species or ecological functions has been difficult for historical, legal, conceptual, and practical reasons. To explore these challenges, we examine current-use (modern) pesticides and their potential connections to the abundances of fishes in the San Francisco Estuary (California). Declines in delta smelt (Hypomesus transpacificus), Chinook salmon (Oncorhynchus tshawytscha), and other species have triggered mandatory and expensive management actions in the urbanizing estuary and agriculturally productive Central Valley. Our inferences are transferable to other situations in which toxics may drive changes in ecological status and trends.

California↗

Evaluation of unsaturated-zone solute-transport models for studies of agricultural chemicals

Seven unsaturated-zone solute-transport models were tested with two data sets to select models for use by the Agricultural Chemical Team of the U.S. Geological Survey's National Water-Quality Assessment Program. The data sets were from a bromide tracer test near Merced, California, and an atrazine study in the White River Basin, Indiana. In this study the models are designated either as complex or simple based on the water flux algorithm. The complex models, HYDRUS2D, LEACHP, RZWQM, and VS2DT, use Richards' equation to simulate water flux and are well suited to process understanding. The simple models, CALF, GLEAMS, and PRZM, use a tipping-bucket algorithm and are more amenable to extrapolation because they require fewer input parameters. The purpose of this report is not to endorse a particular model, but to describe useful features, potential capabilities, and possible limitations that emerged from working with the model input data sets. More rigorous assessment of model applicability involves proper calibration, which was beyond the scope of this study. Uncalibrated ("cold") simulations were run using all seven models to predict the transport of bromide (Merced) and the transport and fate of atrazine and three of its transformation products (White River Basin). Among the complex models, HYDRUS2D successfully predicted both the surface retention and accumulation of bromide at depth at the Merced site, whereas RZWQM and VS2DT predicted only the latter. RZWQM predictions of atrazine were closest to observed values at the White River Basin site, where preferential flow has been observed. LEACHP predicted smaller solute concentrations than observed at both the Merced and White River Basin sites. Among the simple models, CALF predicted the highest values of atrazine and deethylatrazine at the measurement depth of 1.5 meters. CALF includes the Addiscott flow option for preferential flow, and also accepts user-specified dispersivity. PRZM underpredicted solute concentrations, probably because control of dispersion is a problem with this model. GLEAMS has a maximum simulation depth of 1.5 meters, which is limiting for mass-balance purposes because it creates a potential disconnect between unsaturated-zone transport and the water table. Of the models tested, RZWQM, HYDRUS2D, VS2DT, GLEAMS and PRZM had graphical user interfaces. Extensive documentation was available for RZWQM, HYDRUS2D, and VS2DT. RZWQM can explicitly simulate water and solute flux in macropores, and both HYDRUS2D and VS2DT can simulate water and solute flux in two dimensions. The version of RZWQM tested had a maximum simulation depth of 3 meters. The complex models simulate the formation, transport, and fate of degradates of up to three to five compounds including the parent, with the exception of VS2DT, which simulates the transport and fate of a single compound.

California, Indiana↗

Water quality and supply on Cortina Rancheria, Colusa County, California

Cortina Rancheria covers an area of 1 sq mi in Colusa County, California, near the western edge of the Sacramento Valley. Local sources of water for residents of the rancheria are of poor quality or limited availability. Domestic needs are presently met by water from a hand-dug well and from a drilled well with a potential yield of 15 gal/min. Water from both wells fails to meet California State drinking-water standards, primarily because of high concentrations of chloride and dissolved solids. High concentrations of sodium and boron pose additional problems for agricultural use of the water. The dissolved ions originate in Upper Cretaceous marine sediments of the Cortina Formation, which occurs at or near land surface throughout the rancheria. Small quantities of fresh groundwater may occur locally in the Tehama Formation which overlies the Cortina Formation in the eastern part of the rancheria. Canyon Creek, the largest stream on the rancheria, flows only during winter and spring. Water from one of the rancheria 's three springs meet drinking water standards, but it almost stops flowing in summer. The generally poor quality of ground and surface water on the rancheria is typical of areas along the west side of the Sacramento Valley. Additional hydrologic information could indicate more precisely the quantity and quality of surface and groundwater on Cortina Rancheria. Principal features of a possible data-collection program would include monitoring of discharge and water quality in three springs and in Canyon Creek, electromagntic terrain conductivity surveys, and monitoring of water levels and quality in two existing wells and several proposed test wells. (USGS)

Water-Resources Investigations Report↗

Geology, hydrology, and water quality in the Fresno area, California

The Fresno area comprises about 1.400 square miles lying west of the foothills of the Sierra Nevada and east of the trough of the San Joaquin Valley. The rainfall averages less than 10 inches per year causing agricultural development to depend mainly on surface-water deliveries and ground-water pumpage. Surface-water deliveries and ground-water pumpage, however, vary considerably from year to year. For example, in agricultural year 1958 (April 1, 1958-March 31, 1959) surface-water deliveries were about 1,340,000 acre-feet and agricultural ground-water pumpage was about 1,740,000 acre-feet, but in agricultural year 1960 deliveries were only about 560,000 acre-feet and pumpage was about 2,520,000 acre-feet. Alluvial fans are the dominant geomorphic features in the area. Small alluvial fans have been formed near the foothills by the deposits from the numerous intermittent streams that lie both north and south of the Kings River. Thicker and much more extensive alluvial fans have been formed under most of the area by deposits from the San Joaquin and Kings Rivers. Geologic units in the area consist of consolidated rocks and unconsolidated deposits. In turn, consolidated rocks consist of basement complex of pre-Tertiary age and marine and continental sedimentary rocks of Cretaceous and Tertiary age. Unconsolidated deposits are of both Tertiary and Quaternary age. Most of the geologic units dip gently southwestward approximately paralleling the back slope of the Sierra Nevada. Although some of these geologic units are faulted, especially in the deep subsurface, faulting has not affected the occurrence and movement of fresh ground water. The basement complex crops out along the eastern border of the area and yields only small amounts of water to wells; the marine and continental sedimentary rocks do not crop out in the area and do not yield any water to wells. The unconsolidated deposits are divided into an older series of Tertiary and Quaternary age, and a younger series of Quaternary age. The continental deposits of Tertiary and Quaternary age crop out beneath the extreme southeastern part of the area and yield small amounts of water to wells, and the deposits of Quaternary age crop out over most of the area and yield more than 90 percent of the water pumped from wells. The deposits of Quaternary age in turn are divided into older alluvium, lacustrine and marsh deposits, younger alluvium, flood-basin deposits. and sand dunes. The older alluvium is by far the most important aquifer in the Fresno area. It consists of intercalated lenses of clay, silt, silty and sandy clay, clayey and silty sand, sand, gravel, cobbles, and boulders, and in general it is fine grained near the trough of the valley and beneath the alluvial fans of intermittent streams. In the older alluvium, yields to wells range from less than 20 gpm (gallons per minute) to more than 3,000 gpm. The lacustrine and marsh deposits occur only in the subsurface in the western part of the area. Consisting mostly of silt and clay, they are virtually impermeable and thus restrict the vertical movement of water. These deposits from oldest to youngest are designated the E-clay, the C-clay, and the A-clay. The E-clay is the thickest and most extensive of all the lacustrine and marsh deposits. Because the clays tend to confine ground water in the Fresno area, five water bodies are recognized. These are the unconfined water body, the shallow water body, the confined water body below the A-clay, the confined water body below the C-clay, and the confined water body below the E-clay. The unconfined water body underlies most of the Fresno area. The shallow and confined water bodies underlie parts of the extreme western part of the area. There, heads in successively underlying water bodies are less than those in overlying water bodies, indicating that some ground water moves slowly downward through the clays. From agricultural years 1957 to 1962, outflow in the area exceeded inflow. As a result, for this period, the Fresno area had a net deficit of about 2,890,000 acre-feet. This deficit was made up for mostly by a decline in ground water stored. Water levels in all water bodies have been declining over the years, yet when streamflow and canal deliveries are large they show a general rise. The general movement of ground water in the Fresno area is toward the southwest, although pumping depressions near Fresno and near the western part of the area, cause ground water to move northward, southward, and westward toward them.

California↗

Documentation of the Santa Clara Valley regional ground-water/surface-water flow model, Santa Clara Valley, California

The Santa Clara Valley is a long, narrow trough extending about 35 miles southeast from the southern end of San Francisco Bay where the regional alluvial-aquifer system has been a major source of water. Intensive agricultural and urban development throughout the 20th century and related ground-water development resulted in ground-water-level declines of more than 200 feet and land subsidence of as much as 12.7 feet between the early 1900s and the mid-1960s. Since the 1960s, Santa Clara Valley Water District has imported surface water to meet growing demands and reduce dependence on ground-water supplies. This importation of water has resulted in a sustained recovery of the ground-water flow system. To help support effective management of the ground-water resources, a regional ground-water/surface-water flow model was developed. This model simulates the flow of ground water and surface water, changes in ground-water storage, and related effects such as land subsidence. A numerical ground-water/surface-water flow model of the Santa Clara Valley subbasin of the Santa Clara Valley was developed as part of a cooperative investigation with the Santa Clara Valley Water District. The model better defines the geohydrologic framework of the regional flow system and better delineates the supply and demand components that affect the inflows to and outflows from the regional ground-water flow system. Development of the model includes revisions to the previous ground-water flow model that upgraded the temporal and spatial discretization, added source-specific inflows and outflows, simulated additional flow features such as land subsidence and multi-aquifer wellbore flow, and extended the period of simulation through September 1999. The transient-state model was calibrated to historical surface-water and ground-water data for the period 1970–99 and to historical subsidence for the period 1983–99. The regional ground-water flow system consists of multiple aquifers that are grouped into upper- and lower-aquifer systems. Ground-water inflow occurs as natural recharge in the form of streamflow infiltration and areal infiltration of precipitation along stream channels, artificial recharge from infiltration of imported water at recharge ponds and along selected stream channels, and leakage along selected transmission pipelines. Ground-water outflow occurs as evapotranspiration, stream base flow, discharge through pumpage from wells, and subsurface flow to the San Francisco Bay. The geohydrologic framework of the regional ground-water flow system was represented as six model layers. The hydraulic properties were redefined on the basis of cell-based lithologic properties that were delineated in terms of aggregate thicknesses of coarse-grained, fine-grained, and mixed textural categories. The regional aquifer systems also are dissected by several laterally extensive faults that may form at least partial barriers to the lateral flow of ground water. The spatial extent of the ground-water flow model was extended and refined to cover the entire Santa Clara Valley, including the Evergreen subregion. The temporal discretization was refined and the period of simulation was extended to 1970–99. The model was upgraded to MODFLOW-2000 (MF2K) and was calibrated to fit historical ground-water levels, streamflow, and land subsidence for the period 1970–99. The revised model slightly overestimates measured water levels with an root-mean-square error of -7.34 feet. The streamflow generally shows a good match on gaged creeks and rivers for flows greater than 1.2 cubic feet per second. The revised model also fits the measured deformation at the borehole extensometer site located near San Jose within 16 to 27 percent and the extensometer site near Sunnyvale within 3 percent of the maximum measured seasonal deformation for the deepest extensometers. The total ground-water inflow and outflow of about 225,500 acre-feet per year (acre-ft/yr) for the period 1970–89 and of about 205,300 acre-feet per year for the period for the period 1970–99 is comparable with that of the previous model, 207,200 acre-ft/yr for the period 1970–89. Overall the simulated net change in storage increased by about 189,500 acre-ft/yr for the entire period of simulation, which represents about one and a half years of the 1970–99 average pumping. The changes in ground-water flow and storage generally reflect the major climate cycles and the additional importation of water by Santa Clara Valley Water District, with the basin in recovery since the drought of the late 1980s and early 1990s. The average total recharge rate, from natural and artificial recharge and from streamflow infiltration for the revised model for the entire simulation period 1970–99, was about 157,100 acre-ft/yr, which represents about 59 percent of the inflow to the ground-water flow system. The average rate of artificial recharge of about 77,600 acre-ft/yr represents about 30 percent of the inflow to the ground-water flow system. The average pumpage for the entire 29.75-year simulation period is about 133,400 acre-ft/yr and represents about 69 percent of the outflow from the ground-water flow system. Most of the simulated recharge infiltrates and flows through the uppermost layers (i.e. model layers 1 and 3) of the aquifer system. Most of the water that flows to the deeper model layers is occurring through wellbores, with wellbore flow representing 19 percent of the total ground-water inflow between model layers.

California↗

Generalized water-level contours, September-October 2000 and March-April 2001, and long-term water-level changes, at the U.S. Air Force Plant 42 and vicinity, Palmdale, California

Historically, the U.S. Air Force Plant 42 has relied on ground water as the primary source of water owing, in large part, to the scarcity of surface water in the region. Groundwater withdrawal for municipal, industrial, and agricultural use has affected ground-water levels at U.S. Air Force Plant 42, and vicinity. A study to document changes in groundwater gradients and to present historical water-level data was completed by the U.S. Geological Survey in cooperation with the U.S. Air Force. This report presents historical water-level data, hydrographs, and generalized seasonal water-level and water-level contours for September?October 2000 and March?April 2001. The collection and interpretation of ground-water data helps local water districts, military bases, and private citizens gain a better understanding of the ground-water flow systems, and consequently water availability. During September?October 2000 and March?April 2001 the U.S. Geological Survey and other agencies made a total of 102 water-level measurements, 46 during September?October 2000 and 56 during March?April 2001. These data document recent conditions and, when compared with historical data, document changes in ground-water levels. Two water-level contour maps were drawn: the first depicts water-level conditions for September?October 2000 map and the second depicts water-level conditions for March?April 2001 map. In general, the water-level contour maps show water-level depressions formed as result of ground-water withdrawal. One hundred sixteen long-term hydrographs, using water-level data from 1915 through 2000, were constructed to show water-level trends in the area. The hydrographs indicate that water-level decline occurred throughout the study area, with the greatest declines south of U.S. Air Force Plant 42.

Scientific Investigations Report↗

Simulations of ground-water flow and particle pathline analysis in the zone of contribution of a public-supply well in Modesto, eastern San Joaquin Valley, California

Shallow ground water in the eastern San Joaquin Valley is affected by high nitrate and uranium concentrations and frequent detections of pesticides and volatile organic compounds (VOC), as a result of ground-water development and intensive agricultural and urban land use. A single public-supply well was selected for intensive study to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Modesto area. A network of 23 monitoring wells was installed, and water and sediment samples were collected within the approximate zone of contribution of the public-supply well, to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state local ground-water-flow and transport model was developed to evaluate the age of ground water reaching the well and to evaluate the vulnerability of the well to nonpoint source input of nitrate and uranium. Particle tracking was used to compute pathlines and advective travel times in the ground-water flow model. The simulated ages of particles reaching the public-supply well ranged from 9 to 30,000 years, with a median of 54 years. The age of the ground water contributed to the public-supply well increased with depth below the water table. Measured nitrate concentrations, derived primarily from agricultural fertilizer, were highest (17 milligrams per liter) in shallow ground water and decreased with depth to background concentrations of less than 2 milligrams per liter in the deepest wells. Because the movement of water is predominantly downward as a result of ground-water development, and because geochemical conditions are generally oxic, high nitrate concentrations in shallow ground water are expected to continue moving downward without significant attenuation. Simulated long-term nitrate concentrations indicate that concentrations have peaked and will decrease in the public-supply well during the next 100 years because of the low nitrate concentrations in recharge beneath the urban area and the increasing proportion of urban-derived ground water reaching the well. The apparent lag time between peak input concentrations and peak concentrations in the well is about 20 to 30 years. Measured uranium concentrations were also highest (45 micrograms per liter) in shallow ground water, and decreased with depth to background concentrations of about 0.5 microgram per liter. Naturally-occurring uranium adsorbed to aquifer sediments is mobilized by oxygen-rich, high-alkalinity water. Alkalinity increased in shallow ground water in response to agricultural development. As ground-water pumping increased in the 1940s and 1950s, this alkaline water moved downward through the ground-water flow system, mobilizing the uranium adsorbed to aquifer sediments. Ground water with high alkalinity and high uranium concentrations is expected to continue to move deeper in the system, resulting in increased uranium concentrations with depth in ground water. Because alkalinity (and correspondingly uranium) concentrations were high in shallow ground water beneath both the urban and the agricultural land, long-term uranium concentrations in the public-supply well are expected to increase as the proportion of uranium-affected water contributed to the well increases. Assuming that the alkalinity near the water table remains the same, the simulation of long-term alkalinity in the public-supply well indicates that uranium concentrations in the public-supply well will likely approach the maximum contaminant level; however, the time to reach this level is more than 100 years because of the significant proportion of old, unaffected water at depth that is contributed to the public-supply well.

California↗

Selenium contamination of the Grasslands, a major California waterfowl area

In a recent study at Kesterson Reservoir in California, selenium was shown to cause mortality and deformities in embryos of aquatic birds. The present study was conducted to determine if selenium or other contaminants in agricultural drainwater used for marsh management were likely to cause similar adverse effects in the nearby Grasslands area. Selenium concentrations were elevated (greater than 15 ppm, dry-weight) in livers of some birds of all species collected from the Grasslands. Mean selenium concentrations in all species sampled in the South Grasslands were significantly higher (P less than 0.05) than those from the 'control site', the Volta Wildlife Area. Mean selenium levels in black-necked stilts (Himantopus mexicanus) from the South Grasslands (35.6 ppm) were similar (P greater than 0.05) to levels in stilts from Kesterson (46.4 ppm), but means for American avocets (Recurvirostra americana) from the South Grasslands (67.3 ppm) were higher (P less than 0.05) than those from Kesterson (28.4 ppm). Bird eggs and fish from the Grasslands also contained elevated levels of selenium. Concentrations of eight heavy metals in fish generally reflected those patterns previously found in water entering the study areas. Of the organochlorines detected in fish, only DDE occurred at concentrations potentially harmful to birds (6.1 and 3.0 ppm, wet weight, at two South Grassland sites). The effect on avian health or reproduction of the other contaminants, singly or in combination, could not be determined. However, selenium levels were apparently sufficiently elevated in 1984 to have caused adverse effects on avian reproduction in the South Grasslands.

California↗

Effects of rice idling on occupancy dynamics and survival of giant gartersnakes ( Thamnophis gigas ) in the Sacramento Valley, California, 2016–24

The giant gartersnake ( Thamnophis gigas ) is a semi-aquatic species of snake endemic to marshes and sloughs in the Central Valley of California. Because the Central Valley has lost a substantial amount of wetland habitat, giant gartersnake populations are typically found in aquatic habitats associated with rice ( Oryza sativa ) agriculture. Therefore, changes to the amount and location of rice agriculture on the landscape could affect giant gartersnake populations. We present analyses of 9 years of data examining how the occurrence of giant gartersnakes is affected by rice idling. We sampled agricultural canals associated with active rice fields and fallowed fields at 119 sites from 2016 through 2024. We captured giant gartersnakes at 95 of 119 sites sampled during our study, totaling 5,269 captures of 2,687 individuals. We used these capture data, as well as data on the trapping effort, habitat, vegetation, prey availability, and amount of active rice growing at each site, to estimate occupancy and detection probabilities of giant gartersnakes. Mean daily detection probability at a site was 0.38 (95-percent credible interval 0.22–0.56). Given the mean daily detection probability, the probability of detecting giant gartersnakes at an occupied site at least once during a 21-day sampling period within a given year was greater than (>) 0.99 (>0.99 to much greater than [>>] 0.99). The spatial extent of active rice growing within a 2-kilometer buffer of a site was positively correlated with initial site occupancy and the probability of site colonization. Giant gartersnake population density (hereinafter, density) estimated using spatially explicit capture-recapture models, varied among traplines and years, with densities consistently highest in the Butte basin. The annual population growth rate also varied among site-clusters and years, with no temporal trend of growth or decline among sites. Annual apparent survival of giant gartersnakes varied slightly between years and among site clusters, with overall mean annual apparent survival of 0.51 (95-percent credible interval 0.34–0.71) for female snakes and 0.45 (0.30–0.63) for male snakes. The amount of rice in the surrounding landscape was positively correlated to giant gartersnake survival. Rice contributes positively to giant gartersnake occurrence, colonization, and survival, and maximizing the amount of rice agriculture within 4 kilometers of canals with giant gartersnake populations would likely minimize the effects of rice idling on these populations.

California↗

Intrinsic prey preference and selection of the giant gartersnake: A threatened predator in a nonnative prey-dominated community

The introduction of exotic species into an environment can introduce great change in the trophic dynamics of native species. This is of even greater concern if the native species is of conservation concern. The giant gartersnake, Thamnophis gigas , an endemic predator of the Central Valley of California and a species of conservation concern at the state and federal levels, has declined as a result of conversion of its once vast wetland habitat to agriculture. Another anthropogenic factor contributing to this snake's changing ecology is the introduction of nonnative prey into the species' habitats. These introductions have resulted in a prey community that is almost completely composed of exotic species and have potential for considerable effects. In order to assess prey preference and selection we performed three sets of behavioral trials on naïve neonates. We examined 1) neonate prey preference in response to olfactory cues of prepared prey extracts, 2) neonate consumption of different live prey items presented simultaneously; and 3) terrestrial feeding behavior and/or latency to successful attack. Results from the olfactory study suggest that native Sierran treefrogs, Pseudacris sierra, are preferred by neonates. Results from consumption trials suggest that neonates are more likely to select frog species than fish species. This is the first study that we are aware of that examines prey selection of this threatened species and serves to inform its conservation and management.

Journal of Fish and Wildlife Management↗

Water quality

Sustainable water policy in California will require maintaining or improving water quality. The Delta is an important source of drinking water for Californians, but sustaining a quality sufficient for human and agricultural consumption presents a number of problems and challenges to water managers. Similarly, poor environmental water quality is recognized as one of the influential stressors contributing to the ecological problems of the Delta (Bennett 2005; Kimmerer 2004).

California↗

New generation hyperspectral data From DESIS compared to high spatial resolution PlanetScope data for crop type classification

Thoroughly investigating the characteristics of new generation hyperspectral and high spatial resolution spaceborne sensors will advance the study of agricultural crops. Therefore, we compared the performances of hyperspectral Deutsches Zentrum fur Luftund Raumfahrt- (DLR) Earth Sensing Imaging Spectrometer (DESIS) and high spatial resolution PlanetScope in classifying eight crop types in California's Central Valley during the 2020 growing season. The DESIS sensor onboard the International Space Station collects data at 235 hyperspectral narrowbands (HNB) each with 2.55 nm bandwidth from 400–1000 nm and 30 m spatial resolution. In contrast, PlanetScope Dove-R data have four multispectral broadbands (MBB) with 3–4 m spatial resolution. We obtained best classification accuracies using 14 DESIS HNB from the August 2020 image, with an overall accuracy of 85% and producer's and user's accuracies of 72–100% and 75–100%, respectively, for the eight crops. The best classification accuracies using PlanetScope data were obtained using an image mosaic pair from June and August 2020; this resulted in an overall accuracy of 79% and producer's and user's accuracies of 56–100% and 61–100%, respectively. Combining the best 14 DESIS HNB from August 2020 with the 4 PlanetScope MBB from August 2020 yielded an overall accuracy of 82% and producer's and user's accuracies of 65–100% and 60–94%, respectively. On one-to-one single date comparisons of DESIS versus PlanetScope data, the hyperspectral data always outperformed high spatial resolution data in crop type classification. Nevertheless, high spatial resolution data will remain invaluable in assessing within-field variability and crop biophysical/biochemical modeling in precision agriculture.

IEEE Journal of Selected Topics in Applied Earth O↗

Major- and trace-element concentrations in soils from northern California: Results from the Geochemical Landscapes Project pilot study

In 2004, the U.S. Geological Survey (USGS), the Geological Survey of Canada (GSC), and the Mexican Geological Survey (Servicio Geologico Mexicano, or SGM) initiated pilot studies in preparation for a soil geochemical survey of North America called the Geochemical Landscapes Project. The purpose of this project is to provide a better understanding of the variability in chemical composition of soils in North America. The data produced by this survey will be used to construct baseline geochemical maps for regions within the continent. Two initial pilot studies were conducted: (1) a continental-scale study involving a north-south and east-west transect across North America and (2) a regional-scale study. The pilot studies were intended to test and refine sample design, sampling protocols, and field logistics for the full continental soils geochemical survey. Smith and others (2005) reported the results from the continental-scale pilot study. The regional-scale California study was designed to represent more detailed, higher resolution geochemical investigations in a region of particular interest that was identified from the low-sample-density continental-scale survey. A 20,000-km2 area of northern California (fig. 1), representing a wide variety of topography, climate, and ecoregions, was chosen for the regional-scale pilot study. This study area also contains diverse geology and soil types and supports a wide range of land uses including agriculture in the Sacramento Valley, forested areas in portions of the Sierra Nevada, and urban/suburban centers such as Sacramento, Davis, and Stockton. Also of interest are potential effects on soil geochemistry from historical hard rock and placer gold mining in the foothills of the Sierra Nevada, historical mercury mining in the Coast Range, and mining of base-metal sulfide deposits in the Klamath Mountains to the north. This report presents the major- and trace-element concentrations from the regional-scale soil geochemical survey in northern California.

California↗