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At least 361 records · Page 20Linked to original sources

Hydrogeology and water quality of the Floridan aquifer system and effect of Lower Floridan aquifer withdrawals on the Upper Floridan aquifer at Barbour Pointe Community, Chatham County, Georgia, 2013

Two test wells were completed at the Barbour Pointe community in western Chatham County, near Savannah, Georgia, in 2013 to investigate the potential of using the Lower Floridan aquifer as a source of municipal water supply. One well was completed in the Lower Floridan aquifer at a depth of 1,080 feet (ft) below land surface; the other well was completed in the Upper Floridan aquifer at a depth of 440 ft below land surface. At the Barbour Pointe test site, the U.S. Geological Survey completed electromagnetic (EM) flowmeter surveys, collected and analyzed water samples from discrete depths, and completed a 72-hour aquifer test of the Floridan aquifer system withdrawing from the Lower Floridan aquifer. Based on drill cuttings, geophysical logs, and borehole EM flowmeter surveys collected at the Barbour Pointe test site, the Upper Floridan aquifer extends 369 to 567 ft below land surface, the middle semiconfining unit, separating the two aquifers, extends 567 to 714 ft below land surface, and the Lower Floridan aquifer extends 714 to 1,056 ft below land surface. A borehole EM flowmeter survey indicates that the Upper Floridan and Lower Floridan aquifers each contain four water-bearing zones. The EM flowmeter logs of the test hole open to the entire Floridan aquifer system indicated that the Upper Floridan aquifer contributed 91 percent of the total flow rate of 1,000 gallons per minute; the Lower Floridan aquifer contributed about 8 percent. Based on the transmissivity of the middle semiconfining unit and the Floridan aquifer system, the middle semiconfining unit probably contributed on the order of 1 percent of the total flow. Hydraulic properties of the Upper Floridan and Lower Floridan aquifers were estimated based on results of the EM flowmeter survey and a 72-hour aquifer test completed in Lower Floridan aquifer well 36Q398. The EM flowmeter data were analyzed using an AnalyzeHOLE-generated model to simulate upward borehole flow and determine the transmissivity of water-bearing zones. Aquifer-test data were analyzed with a two-dimensional, axisymmetric, radial, transient, groundwater-flow model using MODFLOW–2005. The flowmeter-survey and aquifer-test simulations provided an estimated transmissivity of about 60,000 square feet per day for the Upper Floridan aquifer and about 5,000 square feet per day for the Lower Floridan aquifer. Water in discrete-depth samples collected from the Upper Floridan aquifer, middle semiconfining unit, and Lower Floridan aquifer during the EM flowmeter survey in August 2013 was low in dissolved solids. Tested constituents were in concentrations within established U.S. Environmental Protection Agency drinking water-quality criteria. Concentrations of measured constituents in water samples from Lower Floridan aquifer well 36Q398 collected at the end of the 72-hour aquifer test in November 2013 were generally higher than in the discrete-depth samples collected during EM flowmeter testing in August 2013 but remained within established drinking water-quality criteria. Water-level data for the aquifer test were filtered for external influences such as barometric pressure, earth-tide effects, and long-term trends to enable detection of small (less than 1 ft) water-level responses to aquifer-test withdrawal. During the 72-hour aquifer test, the Lower Floridan aquifer was pumped at a rate of 750 gallons per minute resulting in a drawdown response of 35.5 ft in the pumped well; 1.6 ft in the Lower Floridan aquifer observation well located about 6,000 ft west of the pumped well; and responses of 0.7, 0.6, and 0.4 ft in the Upper Floridan aquifer observation wells located about 36 ft, 6,000 ft, and 6,800 ft from the pumped well, respectively

Georgia

Hydrogeologic framework and extent of saltwater intrusion in Kings, Queens, and Nassau Counties, Long Island, New York

In 2016, the U.S. Geological Survey began a multiyear cooperative study with the New York State Department of Environmental Conservation to evaluate the sustainability of Long Island’s sole-source aquifer system through hydrogeologic mapping, compilation of groundwater chloride concentrations, and groundwater flow modeling. In the initial phase of the islandwide study, the hydrogeologic framework and extent of saltwater intrusion in aquifers in Kings, Queens, and Nassau Counties on western Long Island, N.Y., were investigated. The aquifer system underlying western Long Island has been under stress from pumping of public, irrigation (golf course), and industrial supply wells. Saltwater intrusion has occurred from surrounding embayments (East River, Long Island Sound, Jamaica Bay, and the Atlantic Ocean) due to pumping. Eighteen boreholes were drilled and cores taken during 2019–21 to collect hydrogeologic, geochemical, and geophysical data to delineate the complex subsurface hydrogeology and extent of saltwater intrusion within the study area. Evaluation of the new cores, reexamination of legacy core descriptions, and analysis of borehole geophysical logs was used to refine the previously published hydrogeologic framework of Pleistocene and Cretaceous unconsolidated sediments in the area, including delineation of a previously undefined hydrogeologic unit between the Magothy aquifer and the Raritan confining unit, herein named the “upper Raritan aquifer.” The upper Raritan aquifer was first recognized in southeastern Nassau County from an analysis of about 50 closely spaced boreholes with high-resolution core descriptions and gamma-ray (gamma) logs. Further analysis of borehole logs across the study area indicated that the upper Raritan aquifer was also present in Kings and Queens Counties. Nuclear magnetic resonance (NMR) logging was used for the first time on Long Island to provide estimates of the hydraulic properties of the major aquifer and confining units. Unlike other geophysical logs that record responses to the rock matrix and fluid properties and are strongly dependent on mineralogy, NMR logs record responses to the presence of hydrogen protons in the formation fluid to determine water fraction and pore-size distribution. NMR log analysis provided estimates of the clay-bound, capillary-bound, and mobile water fractions and hydraulic conductivity of aquifers and confining units penetrated by five wells in Nassau County. Pumpage for public-supply and industrial wells on Long Island began in the 1870s with small, localized suppliers of populated areas in Kings and Queens Counties. By 1904–16, pumpage for public water supply in Kings County averaged 21 million gallons per day, and averaged 37 million gallons per day in Queens County, mostly from the upper glacial aquifer. Saltwater intrusion was reported as early as the beginning of the 20th century and included the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifer systems. By 1936, pumping in central Kings County created a major cone of depression in the water table extending to the south shore of much of Kings County and into southwestern Queens County. Saltwater intrusion has caused the shutdown of public-supply wells in Kings, Queens, and Nassau Counties. A large saltwater intrusion wedge in the Lloyd aquifer was indicated in southern Queens County in the early part of the 20th century, and the saltwater interface may have been onshore predevelopment. Most of Kings and Queens Counties are intruded with saltwater in both the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifers systems. Saltwater increased during the 20th century and continues to increase to the present (2023) in the Lloyd-North Shore aquifer system in Great Neck and Manhasset Neck in northern Nassau County. A major wedge of saltwater intrusion in the upper glacial-Jameco-Magothy aquifer in southwestern Nassau County appears to be increasing.

New York

American and Sacramento Rivers, California, erodibility measurements and model

Executive Summary A previous report by the authors described sediment sampling and drilling by the U.S. Geological Survey (USGS) beside the American and Sacramento Rivers near Sacramento, California, in support of a U.S. Army Corps of Engineers project focused on regional flood control. The drilling was performed to define lithology, extract samples for laboratory testing, and perform borehole erosion tests (BETs). The U.S. Department of Agriculture (USDA) performed jet erodibility tests (JETs) near each drilling site, and a team from Texas A&M University performed laboratory tests with an erosion function apparatus (EFA). Collectively, the effort was intended to reveal spatial variations in sediment erodibility and provide data for use in a model to simulate morphological response to a major flood. The data collected by the USGS are available in a public data release. This report, developed in cooperation with the U.S. Army Corps of Engineers, provides comparisons of the three types of measurements of the erodibility of riverbed sediments. The BET is performed in the field and reveals erodibility of sediments below the bed surface. The JET is likewise performed in the field but reveals only erodibility of exposed sediments. The EFA test is done in the laboratory and was performed on soils extracted from different depths beneath the bed surface, in many cases reconstituted for laboratory testing. Tests were performed at nominally similar locations but differed by meters to tens of meters in horizontal locations. The comparison was undertaken to investigate differences among results obtained by the individual measurement approaches and to elucidate pros and cons of each method. The critical shear stress to initiate erosion and the rate of change of erosion rate per unit increase of excess shear stress, sometimes referred to as the erosion coefficient, served as the primary basis for comparison. The three test methods in some cases resulted in order of magnitude differences in estimates of these parameters. Some differences could be attributed to variances in site location or result from testing surface sediment versus a deeper layer, but systematic differences are also evident in the results. The tests performed in the laboratory using the EFA resulted in much lower values of critical shear stress and much higher values of the erosion coefficient compared to the JET tests performed by the USDA team on surface sediments. Critical shear stress was poorly resolved in the BET results because of the limited number of results per site, but the erosion coefficients derived from BET results were systematically lower than those obtained using the EFA. A new, simplified approach is also proposed to estimate the increase in channel cross-sectional area during a large flood, given data describing the initial river cross section, riverbed erodibility parameters, and peak flood discharge and duration. The model runs until the cross section erodes to an equilibrium condition or the flood ends. Output describes the area of the cross section at the end of the simulation and the time required to reach equilibrium if it was reached within the simulated period. The model assumes unique, constant values for both the critical shear stress and the erosion coefficient and represents the fluid mechanics in a simplified way, making it of limited value for quantitative predictions. It does, however, provide an indication of which cross sections are most likely to undergo the greatest change in the design event and can be used to investigate sensitivity of erosion predictions to variability in sediment erodibility measurements.

California

Geologic framework, regional aquifer properties (1940s-2009), and spring, creek, and seep properties (2009-10) of the upper San Mateo Creek Basin near Mount Taylor, New Mexico

The U.S. Geological Survey, in cooperation with the U.S. Forest Service, examined the geologic framework, regional aquifer properties, and spring, creek, and seep properties of the upper San Mateo Creek Basin near Mount Taylor, which contains areas proposed for exploratory drilling and possible uranium mining on U.S. Forest Service land. The geologic structure of the region was formed from uplift of the Zuni Mountains during the Laramide Orogeny and the Neogene volcanism associated with the Mount Taylor Volcanic Field. Within this structural context, numerous aquifers are present in various Paleozoic and Mesozoic sedimentary formations and the Quaternary alluvium. The distribution of the aquifers is spatially variable because of the dip of the formations and erosion that produced the current landscape configuration where older formations have been exhumed closer to the Zuni Mountains. Many of the alluvial deposits and formations that contain groundwater likely are hydraulically connected because of the solid-matrix properties, such as substantive porosity, but shale layers such as those found in the Mancos Formation and Chinle Group likely restrict vertical flow. Existing water-level data indicate topologically downgradient flow in the Quaternary alluvium and indiscernible general flow patterns in the lower aquifers. According to previously published material and the geologic structure of the aquifers, the flow direction in the lower aquifers likely is in the opposite direction compared to the alluvium aquifer. Groundwater within the Chinle Group is known to be confined, which may allow upward migration of water into the Morrison Formation; however, confining layers within the Chinle Group likely retard upward leakage. Groundwater was sodium-bicarbonate/sulfate dominant or mixed cation-mixed anion with some calcium/bicarbonate water in the study area. The presence of the reduction/oxidation-sensitive elements iron and manganese in groundwater indicates reducing conditions at some time or in some location(s) in most aquifers. Frequent detections of zinc in the alluvium aquifer may represent anthropogenic influences such as mining. Along the mesas in the upper San Mateo Creek Basin, springs that form various creeks, including El Rito and San Mateo Creeks, discharge from the basalt-cap layer and the upper Cretaceous sedimentary layers. Streamflow in El Rito and San Mateo Creeks flows down steep gradients near the mesas sustained by groundwater discharges, and this streamflow transitions to shallow groundwater contained within the valley alluvium through infiltration where the subsequent groundwater is restricted from downward migration by the shaly Menefee Formation. This shallow groundwater reemerges at seeps where the land surface has been eroded below the groundwater level. Spring- and creek-water samples contained small amounts of dissolved solutes, and seep water contained substantially larger amounts of dissolved solutes. The pH of water within the creeks was neutral to alkaline, and all locations exhibited well-oxygenated conditions, although typically at substantially less than saturated levels. Changes in the stable-isotope ratios of water between spring and summer samples indicate differences in source-water inputs that likely pertain to seasonal recharge sources. Results of the water-isotope analysis and geochemical modeling indicate little evaporation and chemical weathering at the spring and creek sites but stronger evaporation and chemical weathering by the time the water reaches the seep locations in the center of the upper San Mateo Creek Basin.

New Mexico

Stratigraphy and tectonic history of the Tucson Basin, Pima County, Arizona, based on the Exxon state (32)-1 well

The Tucson Basin is a relatively large late Cenozoic extensional basin developed in the upper plate of the Catalina detachment fault in the southern Basin and Range Province, southeastern Arizona. In 1972, Exxon Company, U.S.A., drilled an exploration well (Exxon State (32)-1) near the center of the Tucson Basin that penetrated 3,658 m (12,001 ft) of sedimentary and volcanic rocks above granitoid basement. Detailed study of cuttings and geophysical logs of the Exxon State well has led to revision of the previously reported subsurface stratigraphy for the basin and provided new insight into its depositional and tectonic history. There is evidence that detachment faulting and uplift of the adjacent Catalina core complex on the north have affected the subsurface geometry of the basin. The gravity anomaly map of the Tucson Basin indicates that the locations of subbasins along the north-trending axis of the main basin coincide with the intersection of this axis with west-southwest projections of synforms in the adjacent core complex. In other words, the subbasins overlie synforms and the ridges between subbasins overlie antiforms. The Exxon State well was drilled near the center of one of the subbasins. The Exxon well was drilled to a total depth of 3,827 m (12,556 ft), and penetrated the following stratigraphic section: Pleistocene(?) to middle(?) Miocene upper basin-fill sedimentary rocks (0-908 m [0-2,980 ft]) lower basin-fill sedimentary rocks (908-1,880 m [2,980-6,170 ft]) lower Miocene and upper Oligocene Pantano Formation (1,880-2,516 m [6,170-8,256 ft]) upper Oligocene to Paleocene(?) volcanic and sedimentary rocks (2,516-3,056 m [8,256-10,026 ft]) Lower Cretaceous to Upper Jurassic Bisbee Group (3,056-3,658 m [10,026-12,001 ft]) pre-Late Jurassic granitoid plutonic rock (3,658-3,827 m [12,001- 12,556 ft]). Stratigraphy and Tectonic History of the Tucson Basin, Pima County, Arizona, Based on the Exxon State (32)-1 Well The 1,880 m (6,170 ft) of basin-fill sedimentary rocks consist of alluvial-fan, alluvial-plain, and playa facies. The uppermost unit, a 341-m-thick (1,120-ft) lower Pleistocene and upper Pliocene alluvial-fan deposit (named the Cienega Creek fan in this study), is an important aquifer in the Tucson basin. The facies change at the base of the alluvial fan may prove to be recognizable in well data throughout much of the basin. The well data show that a sharp boundary at 908 m (2,980 ft) separates relatively unconsolidated and undeformed upper basin fill from denser, significantly faulted lower basin fill, indicating that there were two stages of basin filling in the Tucson basin as in other basins of the region. The two stages apparently occurred during times of differing tectonic style in the region. In the Tucson area the Pantano Formation, which contains an andesite flow dated at about 25 Ma, fills a syntectonic basin in the hanging wall of the Catalina detachment fault, reflecting middle Tertiary extension on the fault. The formation in the well is 636 m thick (2,086 ft) and consists of alluvial-fan, playa, and lacustrine sedimentary facies, a lava flow, and rock- avalanche deposits. Analysis of the geophysical logs indicates that a K-Ar date of 23.4 Ma reported previously for the Pantano interval of the well was obtained on selected cuttings collected from a rock-avalanche deposit near the base of the unit and, thus, does not date the Pantano Formation. The middle Tertiary volcanic and sedimentary rocks have an aggregate thickness of 540 m (1,770 ft). We obtained a new 40Ar/ 39Ar age of 26.91+0.18 Ma on biotite sampled at a depth of 2,584-2,609 m (8,478-8,560 ft) from a 169-m-thick (554-ft) silicic tuff in this interval. The volcanic rocks probably correlate with other middle Tertiary volcanic rocks of the area, and the sedimentary rocks may correlate with the Cloudburst and Mineta Formations exposed on the flanks of the San Pedro Basin to the northeast. The Bisbee Group in the Exxon well is 602 m (1,975 f

Scientific Investigations Report

Geophysical Characterization of the Quaternary-Cretaceous Contact Using Surface Resistivity Methods in Franklin and Webster Counties, South-Central Nebraska

To help manage and understand the Platte River system in Nebraska, the Platte River Cooperative Hydrology Study (COHYST), a group of state and local governmental agencies, developed a regional ground-water model. The southern boundary of this model lies along the Republican River, where an area with insufficient geologic data immediately north of the Republican River led to problems in the conceptualization of the simulated flow system and to potential problems with calibration of the simulation. Geologic descriptions from a group of test holes drilled in south-central Nebraska during 2001 and 2002 indicated a possible hydrologic disconnection between the Quaternary-age alluvial deposits in the uplands and those in the Republican River lowland. This disconnection was observed near a topographic high in the Cretaceous-age Niobrara Formation, which is the local bedrock. In 2003, the U.S. Geological Survey, in cooperation with the COHYST, collected surface geophysical data near these test holes to better define this discontinuity. Two-dimensional imaging methods for direct-current resistivity and capacitively coupled resistivity were used to define the subsurface distribution of resistivity along several county roads near Riverton and Inavale, Nebraska. The relation between the subsurface distribution of resistivity and geology was defined by comparing existing geologic descriptions of test holes to surface-geophysical resistivity data along two profiles and using the information gained from these comparisons to interpret the remaining four profiles. In all of the resistivity profile sections, there was generally a three-layer subsurface interpretation, with a resistor located between two conductors. Further comparison of geologic data with the geophysical data and with surficial features was used to identify a topographic high in the Niobrara Formation near the Franklin Canal which was coincident with a resistivity high. Electrical properties of the Niobrara Formation made accurate interpretation of the resistivity profile sections difficult and less confident because of similar resistivity of this formation and that of the coarser-grained sediment of the Quaternary-age deposits. However, distinct conductive features were identified within the resistivity profile sections that aided in delineating the contact between the resistive Quaternary-age deposits and the resistive Niobrara Formation. Using this information, an interpretive boundary was drawn on the resistivity profile sections to represent the contact between the Quaternary-age alluvial deposits and the Cretaceous-age Niobrara Formation. A digital elevation model (DEM) of the top of the Niobrara Formation was constructed using the altitudes from the interpreted contact lines. This DEM showed that the general trend of top of the Niobrara Formation dips to the southeast. At the north edge of the study site, the Niobrara Formation topographic high trends east-west with an altitude range of 559 meters in the west to 543 meters in the east. Based on the land-surface elevation and the Niobrara Formation DEM, the estimated thickness of the Quaternary-age alluvial deposits throughout the study area was mapped and showed a thinning of the Quaternary-age alluvial deposits to the north, approximately where the topographic high of the Niobrara Formation is located. This topographic high in the Niobrara Formation has the potential to act as a barrier to ground-water flow from the uplands alluvial aquifer to the Republican River alluvial aquifer as shown in the resistivity profile sections. The Quaternary-age alluvial deposits in the uplands and those in the Republican River Valley are not fully represented as disconnected because it is possible that there are ground-water flow paths that were not mapped during this study.

Scientific Investigations Report

Hydrogeology and water quality of the Floridan aquifer system and effects of Lower Floridan aquifer pumping on the Upper Floridan aquifer at Fort Stewart, Georgia

Test drilling, field investigations, and digital modeling were completed at Fort Stewart, GA, during 2009?2010, to assess the geologic, hydraulic, and water-quality characteristics of the Floridan aquifer system and evaluate the effect of Lower Floridan aquifer (LFA) pumping on the Upper Floridan aquifer (UFA). This work was performed pursuant to the Georgia Environmental Protection Division interim permitting strategy for new wells completed in the LFA that requires simulation to (1) quantify pumping-induced aquifer leakage from the UFA to LFA, and (2) identify the equivalent rate of UFA pumping that would produce the same maximum drawdown in the UFA that anticipated pumping from LFA well would induce. Field investigation activities included (1) constructing a 1,300-foot (ft) test boring and well completed in the LFA (well 33P028), (2) constructing an observation well in the UFA (well 33P029), (3) collecting drill cuttings and borehole geophysical logs, (4) collecting core samples for analysis of vertical hydraulic conductivity and porosity, (5) conducting flowmeter and packer tests in the open borehole within the UFA and LFA, (6) collecting depth-integrated water samples to assess basic ionic chemistry of various water-bearing zones, and (7) conducting aquifer tests in new LFA and UFA wells to determine hydraulic properties and assess interaquifer leakage. Using data collected at the site and in nearby areas, model simulation was used to assess the effects of LFA pumping on the UFA. Borehole-geophysical and flowmeter data indicate the LFA at Fort Stewart consists of limestone and dolomitic limestone between depths of 912 and 1,250 ft. Flowmeter data indicate the presence of three permeable zones at depth intervals of 912-947, 1,090-1,139, and 1,211?1,250 ft. LFA well 33P028 received 50 percent of the pumped volume from the uppermost permeable zone, and about 18 and 32 percent of the pumped volume from the middle and lowest permeable zones, respectively. Chemical constituent concentrations increased with depth, and water from all permeable zones contained sulfate at concentrations that exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter. A 72-hour aquifer test pumped LFA well 33P028 at 740 gallons per minute (gal/min), producing about 39 ft of drawdown in the pumped well and about 0.4 foot in nearby UFA well 33P029. Simulation using the U.S. Geological Survey finite-difference code MODFLOW was used to determine long-term, steady-state flow in the Floridan aquifer system, assuming the LFA well was pumped continuously at a rate of 740 gal/min. Simulated steady-state drawdown in the LFA was identical to that observed in pumped LFA well 33P028 at the end of the 72-hour test, with values larger than 1 ft extending 4.4 square miles symmetrically around the pumped well. Simulated steady-state drawdown in the UFA resulting from pumping in LFA well 33P028 exceeded 1 ft within a 1.4-square-mile circular area, and maximum drawdown in the UFA was 1.1 ft. Leakage from the UFA through the Lower Floridan confining unit contributed about 98 percent of the water to the well; lateral flow from specified-head model boundaries contributed about 2 percent. About 80 percent of the water supplied to LFA well 33P028 originated from within 1 mile of the well, and 49 percent was derived from within 0.5 mile of the well. Vertical hydraulic gradients and vertical leakage are progressively higher near the LFA pumped well which results in a correspondingly higher contribution of water from the UFA to the pumped well at distances closer to the pumped well. Simulated pumping-induced interaquifer leakage from the UFA to the LFA totaled 725 gal/min (1.04 million gallons per day), whereas simulated pumping at 205 gal/min (0.3 million gallons per day) from UFA well 33P029 produced the equivalent maximum drawdown as pumping LFA well 33P028 at 740 gal/min during the aquifer test. This equivalent pumpin

Georgia

Field-based description of rhyolite lava flows of the Calico Hills Formation, Nevada National Security Site, Nevada

Contaminants introduced into the subsurface of Pahute Mesa, Nevada National Security Site, by underground nuclear testing are of concern to the U.S. Department of Energy and regulators responsible for protecting human health and safety. The potential for contaminant movement away from the underground test areas at Pahute Mesa and into the accessible environment is greatest by groundwater transport through fractured volcanic rocks. The 12.9 Ma (mega-annums, million years) Calico Hills Formation, which consists of a mixture of rhyolite lava flows and intercalated nonwelded and bedded tuff and pyroclastic flow deposits, occurs in two areas of the Nevada National Security Site. One area is north of the Rainier Mesa caldera, buried beneath Pahute Mesa, and serves as a heterogeneous volcanic-rock aquifer but is only available to study through drilling and is not described in this report. A second accumulation of the formation is south of the Rainier Mesa caldera and is exposed in outcrop along the western boundary of the Nevada National Security Site at the Calico Hills near Yucca Mountain. These outcrops expose in three dimensions an interlayered sequence of tuff and lava flows similar to those intercepted in the subsurface beneath Pahute Mesa. Field description and geologic mapping of these exposures described lithostratigraphic variations within lava flows and assisted in, or at least corroborated, conceptualization of the rhyolite lava-bearing parts of the formation. In the area south of the Rainier Mesa caldera, surface exposures and nearby subsurface equivalents were studied through compilation of geologic maps, new field mapping, subsurface information from boreholes, and data extracted from three-dimensional geologic framework models. Rhyolite lava flows within the Calico Hills Formation are described in terms of lithostratigraphic variations established for rhyolite lava flows in other volcanic fields. In general, the flows consist of a core of crystallized, flow-banded rhyolite lava, surrounded by a carapace of obsidian, commonly mantled by blocky, pumiceous rhyolite lava and flow breccia. Rhyolite lava flows were correlated and mapped on the basis of distinctive appearance in outcrop, stratigraphic sequence, and the presence of stratigraphic markers. Pyroclastic deposits that are spatially, temporally, and genetically related to the rhyolite lava flows consist of a series of intercalated pyroclastic flows, bedded ash-fall, and reworked tuff that have varying amounts of pumice and volcanic rock clasts. In the area south of the Rainier Mesa caldera, surface and subsurface geologic data are combined to interpret the overall thickness of the Calico Hills Formation and the proportion of lava flow lithology across the study area. The formation is at least 500 meters (m) thick and contains the greatest proportion of rhyolite lava flow to the northeast of Yucca Mountain in the lower part of Fortymile Canyon. The formation thins to the south and southwest where it is between 50 and 200 m thick beneath Yucca Mountain and contains no rhyolite lavas. Geologic mapping and field-based correlation of individual lava flows allow for the interpretation of the thickness and extent of specific flows and the location of their source areas. The most extensive flows have widths from 2 to 3 kilometers (km) and lengths of at least 5–6 km. Lava flow thickness varies from 150 to 250 m above interpreted source vents to between 30 and 80 m in more distal locations. Rhyolite lavas have length-to-height ratios of 10:1 or greater and, in one instance, a length-to-width ratio of 2:1 or greater, implying a tongue-shaped geometry instead of circular domes or tabular bodies. Although geologic mapping did not identify any physical feature that could be positively identified as a vent, lava flow thickness and the size of clasts in subjacent pyroclastic deposits suggest that primary vent areas for at least some of the flows in the study area are on the east side of Fortymile Canyon, to the northeast of Yucca Mountain.

Nevada

Paleomagnetic correlation of surface and subsurface basaltic lava flows and flow groups in the southern part of the Idaho National Laboratory, Idaho, with paleomagnetic data tables for drill cores

Paleomagnetic inclination and polarity studies have been conducted on thousands of subcore samples from 51 coreholes located at and near the Idaho National Laboratory. These studies are used to paleomagnetically characterize and correlate successive stratigraphic intervals in each corehole to similar depth intervals in adjacent coreholes. Paleomagnetic results from 83 surface paleomagnetic sites, within and near the INL, are used to correlate these buried lava flow groups to basaltic shield volcanoes still exposed on the surface of the eastern Snake River Plain. Sample handling and demagnetization protocols are described as well as the paleomagnetic data averaging process. Paleomagnetic inclination comparisons between coreholes located only kilometers apart show comparable stratigraphic successions of mean inclination values over tens of meters of depth. At greater distance between coreholes, comparable correlation of mean inclination values is less consistent because flow groups may be missing or additional flow groups may be present and found at different depth intervals. Two shallow intersecting cross-sections, A-A- and B-B- (oriented southwest-northeast and northwest-southeast, respectively), drawn through southwest Idaho National Laboratory coreholes show the corehole to corehole or surface to corehole correlations derived from the paleomagnetic inclination data. From stratigraphic top to bottom, key results included the (1) Quaking Aspen Butte flow group, which erupted from Quaking Aspen Butte southwest of the Idaho National Laboratory, flowed northeast, and has been found in the subsurface in corehole USGS 132; (2) Vent 5206 flow group, which erupted near the southwestern border of the Idaho National Laboratory, flowed north and east, and has been found in the subsurface in coreholes USGS 132, USGS 129, USGS 131, USGS 127, USGS 130, USGS 128, and STF-AQ-01; and (3) Mid Butte flow group, which erupted north of U.S. Highway 20, flowed northwest, and has been found in the subsurface at coreholes ARA-COR-005 and STF-AQ-01. The high K20 flow group erupted from a vent that may now be buried south of U.S. Highway 20 near Middle Butte, flowed north, and is found in the subsurface in coreholes USGS 131, USGS 127, USGS 130, USGS 128, USGS 123, STF-AQ-01, and ARA-COR-005 ending near the Idaho Nuclear Technology and Engineering Center. The vent 5252 flow group erupted just south of U.S. Highway 20 near Middle and East Buttes, flowed northwest, and is found in the subsurface in coreholes ARA-COR-005, STF-AQ-01, USGS 130, USGS 128, ICPP 214, USGS 123, ICPP 023, USGS 121, USGS 127, and USGS 131. The Big Lost flow group erupted from a now-buried vent near the Radioactive Waste Management Complex, flowed southwest to corehole USGS 135, and northeast to coreholes USGS 132, USGS 129, USGS 131, USGS 127, USGS 130, STF-AQ-01, and ARA-COR-005. The AEC Butte flow group erupted from AEC Butte near the Advanced Test Reactor Complex and flowed south to corehole Middle 1823, northwest to corehole USGS 134, northeast to coreholes USGS 133 and NRF 7P, and south to coreholes USGS 121, ICPP 023, USGS 123, and USGS 128. Evidence of progressive subsidence of the axial zone of the ESRP is shown in these cross-sections, distorting the original attitudes of the lava flow groups and interbedded sediments. A deeper cross-section, C-C- (oriented west to east), spanning the entire southern Idaho National Laboratory shows correlations of the lava flow groups in the saturated part of the ESRP aquifer. Areally extensive flow groups in the deep subsurface (from about 100-800 meters below land surface) can be traced over long distances. In cross-section C-C-, the flow group labeled "Matuyama" can be correlated from corehole USGS 135 to corehole NPR Test/W-02, a distance of about 28 kilometers (17 miles). The flow group labeled "Matuyama 1.21 Ma" can be correlated from corehole Middle 1823 to corehole ANL-OBS-A-001, a distance of 26 kilometers (16 miles). Other flo

Idaho

Summary appraisals of the nation's ground-water resources – California region

Most people in the California Region live in a semiarid or arid climate, with precipitation less than the potential evapotranspiration- environments of perennial water deficiency. The deficiency becomes most onerous during the characteristically rainless summers and during recurrent droughts that may continue for 10--20 years. However, water from winter rain and snow can be stored for use during the dry summer months, and water stored during a wet climatic period can be used in a succeeding dry period; moreover, perennial deficiency can be overcome by bringing water from areas of perennial surplus. Ground-water reservoirs have especial significance in arid and semiarid regions as repositories where water is stored or can be stored with minimum loss by evaporation. Nearly all the ground-water reservoirs of the California Region are in alluvial sediments of valleys and plains that flank the mountain ranges. The largest, underlying the vast Central Valley, occupies 10 percent of the area of the region, has an estimated usable capacity exceeding 100 million acre-feet (125 cubic kilometres), and has an annual pumpage from wells of about 13 million acre-feet (16 cubic kilometres). Another 10 percent of the region is occupied by 55 developed ground-water reservoirs that are widely distributed; aggregate annual pumpage from them is about 3 1/2 million acre-feet (4 cubic kilometres). In the southeastern desert about 60 ground-water reservoirs occupy still another 10 percent of the region; these have been explored only enough to show that most have some usable water, but current use is negligible. In northeastern California and adjacent Oregon and Nevada, ground-water reservoirs are identified only in valleys and lowlands where wells are feasible, but basaltic rocks of the Cascade Range and Modoc Plateau are excellent aquifers distributed over an area constituting about 15 percent of the region. In sum, slightly less than half the California Region is underlain by ground-water reservoirs, either in valley fill or in volcanic rocks, which can yield significant quantities of water to wells. The rest of the California Region includes the mountains, canyons, slopes, and foothills of the Sierra Nevada, Coast Ranges, and Basin Ranges, whose consolidated rocks and products of their weathering may be permeable locally but are not generally so. Here, the prevailing method of ground-water development is still mostly trial and error, and while in many places a well can yield enough water for a family, some families might have to do without amenities such as flush toilets and automatic washers. For more than half a century the California Region has led all others in North America in pumping of ground water as well as in the area, variety, yield, and export of crops irrigated by water from wells. It has led in the development and use of deep-well turbine pumps for large yield and in the drilling of water wells to great depths. At the same time, such developments have resulted in the elimination of artesian pressures that produced thousands of flowing wells in the 19th century and led to the wide distribution of "falling water tables." Also, California was first to induce encroachment of seawater into wells (in 1906); first to recognize subsidence of land caused by pumping from wells (in 1933), generating news about land sinking in San Jose, Long Beach, and along the Delta-Mendota and Friant-Kern Canals; and first to experience pollution of ground-water reservoirs by brines, chemicals, industrial wastes, and petroleum byproducts including gasoline. The region has led in research in several fields leading to solution of many of these problems. Ground-water problems developed rapidly after World War II with booming population, agriculture, industry, and water demand during several years of regionwide drought. Water levels in wells trended downward almost everywhere as a natural effect of the drought and at accelerated rates in areas of pumping for new enterprises or to supplement subnormal surface-water supplies. The declines in many pumping areas exceeded 100 feet (30 metres), and in some confined aquifers the potentiometric surface was drawn down more than 330 feet (100 metres). The depletion of ground-water storage has had "permanent" side effects, including subsidence of the land exceeding 10 feet (3 metres) in extensive areas, and seawater intrusion that ended the useful lives of many wells along the coast and as much as 6 miles (10 kilometres) inland. Some problems have been solved, but these solutions have at times created other problems. Many ground-water reservoirs have gone through one or more stages - exploration for productive aquifers, exploitation and development for use of the water, restriction to the perennial supply or "safe" yield, importation of surface water, artificial recharge of ground water, conjunctive use of surface and ground water, protection of water quality, and integrated management of use and disposal of water. This evolutionary sequence is unique for each reservoir, and so generalizations become difficult in a regional appraisal; also, the changes with time are significant and varied, and knowledge of prior events is a prerequisite in an appraisal of the resource in a specific year. As of 1970, water levels in many wells had risen significantly from the minimum levels of record reached during the 1960's or earlier; only in areas of new development and in desert areas of long-continued "mining" of nonreplenished water was ground-water storage still being depleted. Land subsidence has continued at diminishing rates and practically has come to a halt in some areas; invading seawater has been stopped or nudged back in most places where problems were significant. The current, favorable situation has been helped by climatic variations, from drought in 1945-52 and exceedingly dry years in 1959 and 1961 to above-normal precipitation in 1969 and 1970; but most of the serious problems have been solved by human efforts, including especially the implementation of the California Water Plan, transporting water from areas of perennial surplus to areas where it is used in lieu of ground water or for ground-water replenishment. All major urban areas now import water to supplement or replace the water pumped from wells. Extensive agricultural areas that formerly were irrigated solely by ground water now obtain some of their water from surface reservoirs and canals, especially in the Central Valley. With surface water available as an alternative supply, well owners can view their ground water with complacency. But complacency can lead to neglect and carelessness and consequent deterioration of the ground-water resource by pollution. Claiming heritage from the English Common Law, the existing California law grants to the landowner (riparian) and private enterprise (appropriator) rights to the water stored in ground-water reservoirs or discharged from them, including the base flow of streams. Ground-water development has been by private and local enterprise, and the California legislature has protected and encouraged local responsibility, control, and management of ground water. As to surface water, a constitutional amendment in 1928 limited riparian rights to the quantities of water that were "reasonably required for the beneficial use to be served." The surpluses have become public waters which are collected, stored, transported, and delivered under various contracts by Federal, State, and other agencies. The agencies have not stored water underground because of uncertainty as to their rights, but some local agencies have been encouraged with favorable pricing schedules to undertake the artificial recharge and management of ground-water reservoirs. Thus, conjunctive use of surface and ground water has become a matter of interagency negotiation. Of all the constraints on effective use of ground-water reservoirs, the most formidable may be the attitudes of people. Assurance of water supply is vital in areas of water deficiency, and Government has assumed increasing responsibility for the welfare of people in these areas. Unfortunately, when Government provides this assurance, most beneficiaries demand continued subsidy to the exclusion of perhaps cheaper private development. Indeed, as the water resources are presently segregated-with private rights predominant in ground water and public interest dominant in surface water-ground-water development has suffered for lack of public concern. The region has the scientific and technologic capability for effective use of groundwater reservoirs, as shown by the achievements and programs of several districts, but many districts are not organized or staffed for such comprehensive management and will need assistance and scientific expertise available from State and Federal agencies. Those agencies, in turn, may not have the scientific data that are essential to prevent haphazard activities and to enable programs to be organized for the most effective and attractive utilization of the water resources. In these days of increasing concern over pollution, existing data are generally inadequate to assess the natural deterioration of ground waters as a basis for defining pollution.

California

Shallow groundwater quality and geochemistry in the Fayetteville Shale gas-production area, north-central Arkansas, 2011

The Mississippian Fayetteville Shale serves as an unconventional gas reservoir across north-central Arkansas, ranging in thickness from approximately 50 to 550 feet and varying in depth from approximately 1,500 to 6,500 feet below the ground surface. Primary permeability in the Fayetteville Shale is severely limited, and successful extraction of the gas reservoir is the result of advances in horizontal drilling techniques and hydraulic fracturing to enhance and develop secondary fracture porosity and permeability. Drilling and production of gas wells began in 2004, with a steady increase in production thereafter. As of April 2012, approximately 4,000 producing wells had been completed in the Fayetteville Shale. In Van Buren and Faulkner Counties, 127 domestic water wells were sampled and analyzed for major ions and trace metals, with a subset of the samples analyzed for methane and carbon isotopes to describe general water quality and geochemistry and to investigate the potential effects of gas-production activities on shallow groundwater in the study area. Water-quality analyses from this study were compared to historical (pregas development) shallow groundwater quality collected in the gas-production area. An additional comparison was made using analyses from this study of groundwater quality in similar geologic and topographic areas for well sites less than and greater than 2 miles from active gas-production wells. Chloride concentrations for the 127 groundwater samples collected for this study ranged from approximately 1.0 milligram per liter (mg/L) to 70 mg/L, with a median concentration of 3.7 mg/L, as compared to maximum and median concentrations for the historical data of 378 mg/L and 20 mg/L, respectively. Statistical analysis of the data sets revealed statistically larger chloride concentrations (p-value <0.001) in the historical data compared to data collected for this study. Chloride serves as an important indicator parameter based on its conservative transport characteristics and relatively elevated concentrations in production waters associated with gas extraction activities. Major ions and trace metals additionally had lower concentrations in data gathered for this study than in the historical analyses. Additionally, no statistical difference existed between chloride concentrations from water-quality data collected for this study from 94 wells located less than 2 miles from a gas-production well and 33 wells located 2 miles or more from a gas-production well; a Wilcoxon rank-sum test showed a p-value of 0.71. Major ion chemistry was investigated to understand the effects of geochemical and reduction-oxidation (redox) processes on the shallow groundwater in the study area along a continuum of increased rock-water interaction represented by increases in dissolved solids concentration. Groundwater in sandstone formations is represented by a low dissolved solids concentration (less than 30 mg/L) and slightly acidic water type. Shallow shale aquifers were represented by dissolved solids concentrations ranging upward to 686 mg/L, and water types evolving from a dominantly mixed-bicarbonate and calcium-bicarbonate to a strongly sodium-bicarbonate water type. Methane concentration and carbon isotopic composition were analyzed in 51 of the 127 samples collected for this study. Methane occurred above a detection limit of 0.0002 mg/L in 32 of the 51 samples, with concentrations ranging upward to 28.5 mg/L. Seven samples had methane concentrations greater than or equal to 0.5 mg/L. The carbon isotopic composition of these higher concentration samples, including the highest concentration of 28.5 mg/L, shows the methane was likely biogenic in origin with carbon isotope ratio values ranging from -57.6 to -74.7 per mil. Methane concentrations increased with increases in dissolved solids concentrations, indicating more strongly reducing conditions with increasing rock-water interaction in the aquifer. As such, groundwater-quality data collected for this study indicate that groundwater chemistry in the shallow aquifer system in the study area is a result of natural processes, beginning with recharge of dilute atmospheric precipitation and evolution of observed groundwater chemistry through rock-water interaction and redox processes.

Arkansas

Transient effects on groundwater chemical compositions from pumping of supply wells at the Nevada National Security Site, 1951-2008

Nuclear testing and support activities at the Nevada National Security Site have required large amounts of water for construction, public consumption, drilling, fire protection, hydraulic and nuclear testing, and dust control. To supply this demand, approximately 20,000 million gallons of water have been pumped from 23 wells completed in 19 boreholes located across the Nevada National Security Site starting as early as the 1950s. As a consequence of more or less continuous pumping from many of these wells for periods as long as 58 years, transient groundwater flow conditions have been created in the aquifers that supplied the water. To evaluate whether long-term pumping caused changes in water compositions over time, available chemical analyses of water samples from these 19 boreholes were compiled, screened, and evaluated for variability including statistically significant temporal trends that can be compared to records of groundwater pumping. Data used in this report have been extracted from a large database (Geochem08, revision 3.0, released in September 2008) containing geochemical and isotopic information created and maintained by primary contractors to the U.S. Department of Energy, National Nuclear Security Administration, Nevada Site Office. Data extracted from this source were compiled for the entire period of record, converted to uniform reporting units, and screened to eliminate analyses of poor or unknown quality, as well as clearly spurious values. The resulting data are included in accompanying spreadsheets that give values for (1) pH and specific conductance, (2) major ion concentrations, (3) trace element concentrations and environmental isotope ratios, and (4) mean, median, and variance estimates for major ion concentrations. The resulting data vary widely in quality and time-series density. An effort has been made to establish reasonable ranges of analytical uncertainty expected for each analyte and eliminate analyses that are obvious outliers. Analysis of chemical trends in this report primarily rely on specific conductance measurements and major ion concentrations, data considered to be the most accurate and reliable over the entire time span of investigation. The analysis uses parametric and non-parametric evaluations to provide a statistical basis for trend identification. Trace element and isotope data are examined for consistency, but typically are too inaccurate or infrequent to provide a reliable long term basis for trend evaluation. Groundwater withdrawal records compiled in a companion report are included graphically in this report to allow qualitative comparisons between water quality and pumping history. Data for each supply well include (1) a borehole description and summary of pumping history, (2) a description of water-quality parameters, (3) an evaluation of temporal variations of specific conductance and major ion concentrations, and (4) an examination of supporting information from trace element and isotope data. A range of responses are observed for individual supply wells that likely include the effects of both aquifer dynamics and changing borehole conditions. Data from most wells show little or no evidence for temporal variation in water-quality parameters indicating that aquifers at the Nevada National Security Site are capable of producing large volumes of compositionally uniform water over many years of pumping. A smaller number of wells show evidence of transient changes. Wells that have ceased pumping commonly show compositions that shift toward lower concentrations in subsequent bailed samples, which indicates that more dilute water entered the well over time due to either leakage of meteoric water into the well casing or more wide-spread recharge into the shallow phreatic zone. Wells that show systematic changes in water compositions during episodes of pumping commonly have multiple open intervals whose contributions to water in the well may change over time due to hydraulic conditions or well dynamics.

Nevada

Hydrogeologic framework of the uppermost principal aquifer systems in the Williston and Powder River structural basins, United States and Canada

The glacial, lower Tertiary, and Upper Cretaceous aquifer systems in the Williston and Powder River structural basins within the United States and Canada are the uppermost principal aquifer systems and most accessible sources of groundwater for these energy-producing basins. The glacial aquifer system covers the northeastern part of the Williston structural basin. The lower Tertiary and Upper Cretaceous aquifer systems are present in about 91,300 square miles (mi 2 ) of the Williston structural basin and about 25,500 mi 2 of the Powder River structural basin. Directly under these aquifer systems are 800 to more than 3,000 feet (ft) of relatively impermeable marine shale that serves as a basal confining unit. The aquifer systems in the Williston structural basin have a shallow (less than 2,900 ft deep), wide, and generally symmetrical bowl shape. The aquifer systems in the Powder River structural basin have a very deep (as much as 8,500 ft deep), narrow, and asymmetrical shape. The Williston structural basin has been an important oil and natural gas producing region since the 1950s, and production has increased substantially since the mid-2000s due to improved drilling and hydraulic fracturing methods from deep formations, such as the Bakken and Three Forks Formations. These improved methods require considerable volumes of freshwater mostly from shallow aquifers or surface water. Coal, lignite, and coal-bed natural gas are additional sources of energy in both basins that can affect the quality and quantity of shallow aquifers through strip mining and groundwater depletion. In 2011, the U.S. Geological Survey initiated a regional study of the glacial, lower Tertiary, and Upper Cretaceous aquifer systems in the Williston and Powder River structural basins with the goal to quantify groundwater availability. This report, together with a companion report of the conceptual flow model, provides an improved understanding of the groundwater flow systems and a basis for a numerical, regional groundwater-flow model. This study combines the lithostratigraphic units of the glacial, lower Tertiary, and Upper Cretaceous aquifer systems in the United States and Canada into 7 regional hydrogeologic units&mdash;glacial deposits, 4 bedrock aquifers, and 2 bedrock confining units&mdash;using general hydraulic properties. The glacial deposits are composed of till and glacial outwash sands and gravels with areas of cobbles and boulders. The four bedrock aquifers are the upper Fort Union, lower Fort Union, lower Hell Creek, and Fox Hills aquifers and are contained primarily in sandstone layers. The two confining units are the middle Fort Union hydrogeologic unit (shale) and upper Hell Creek hydrogeologic unit (contains less sandstone than the underlying lower Hell Creek aquifer). Water from hydrogeologic units in these three aquifer systems is relatively fresh and potable, whereas withdrawals seldom occur from units below the basal confining unit because of great depths (greater than 800 ft) and poor water quality. Analysis of about 300 electric (resistivity) and lithologic logs in the Williston structural basin and numerous existing publications for the Powder River structural basin were used to develop a three-dimensional hydrogeologic framework for both basins. Interpolated thicknesses of the glacial deposits, the lower Tertiary aquifer system, and the Upper Cretaceous aquifer system in the Williston structural basin are less than about 750; 2,250; and 1,050 ft, respectively. Interpolated thicknesses of the lower Tertiary aquifer system and the Upper Cretaceous aquifer system in the Powder River structural basin are less than about 7,180 and 5,070 ft, respectively. Interpolated horizontal hydraulic conductivity values for the Williston structural basin were as much as 25 feet per day (ft/d) in the glacial deposits and had smaller ranges in the lower Tertiary aquifer system (0.01&ndash;9.8 ft/d) and in the Upper Cretaceous aquifer system (0.06&ndash;5.5 ft/d). In the Powder River structural basin, the lower Tertiary aquifer system had a greater range of interpolated horizontal hydraulic conductivity values (0.10&ndash;11 ft/d) than the Upper Cretaceous aquifer system (0.02&ndash;5.7 ft/d). Transmissivity is greatest in the gravel zones of the glacial deposits (2,120 feet squared per day) and generally decreases with depth into the bedrock units. Regionally, water in the lower Tertiary and Upper Cretaceous aquifer systems flows in a northerly or northeasterly direction from the Powder River structural basin to the Williston structural basin. Groundwater flow in the Williston structural basin generally is easterly or northeasterly. Flow in the uppermost hydrogeologic units generally is more local and controlled by topography where unglaciated in the Williston structural basin than is flow in the glaciated part and in underlying aquifers. Groundwater flow in the Powder River structural basin generally is northerly with local variations greatest in the uppermost aquifers. Groundwater is confined, and flow is regional in the underlying aquifers.

Powder River Basin;Williston Basin

Hydrogeology and water quality of the Floridan aquifer system and effect of Lower Floridan aquifer pumping on the Upper Floridan aquifer at Hunter Army Airfield, Chatham County, Georgia

Test drilling and field investigations, conducted at Hunter Army Airfield (HAAF), Chatham County, Georgia, during 2009, were used to determine the geologic, hydraulic, and water-quality characteristics of the Floridan aquifer system and to evaluate the effect of Lower Floridan aquifer (LFA) pumping on the Upper Floridan aquifer (UFA). Field investigation activities included (1) constructing a 1,168-foot (ft) test boring and well completed in the LFA, (2) collecting drill cuttings and borehole geophysical logs, (3) collecting core samples for analysis of vertical hydraulic conductivity and porosity, (4) conducting flowmeter and packer tests in the open borehole within the UFA and LFA, (5) collecting depth-integrated water samples to assess basic ionic chemistry of various water-bearing zones, and (6) conducting aquifer tests in the new LFA well and in an existing UFA well to determine hydraulic properties and assess interaquifer leakage. Using data collected at the site and in nearby areas, model simulation was used to quantify the effects of interaquifer leakage on the UFA and to determine the amount of pumping reduction required in the UFA to offset drawdown resulting from the leakage. Borehole-geophysical and flowmeter data indicate the LFA at HAAF consists of limestone and dolomitic limestone between depths of 703 and 1,080 ft, producing water from six major permeable zones: 723-731; 768-785; 818-837; 917-923; 1,027-1,052; and 1,060-1,080 ft. Data from a flowmeter survey, conducted at a pumping rate of 748 gallons per minute (gal/min), suggest that the two uppermost zones contributed 469 gal/min or 62.6 percent of the total flow during the test. The remaining four zones contributed from 1.7 to 18 percent of the total flow. Grab water samples indicate that with the exception of fluoride, constituent concentrations in the LFA increased with depth; water from the deepest interval (1,075 ft) contained chloride and sulfate concentrations of 480 and 240 milligrams per liter (mg/L), respectively. These relatively high concentrations were interpreted to have little effect on the overall quality of the well because flowmeter results indicated that water from 1,060 to 1,080 ft contributed less than 2 percent of the total flow to the completed well. Results of a 72-hour aquifer test indicate that pumping a LFA well at a rate of 748 gal/min produced a drawdown response of 0.76 ft in a well completed in the UFA located 176 ft from the pumped well. A revised regional groundwater-flow model was used to simulate long-term (steady-state) leakage response of the UFA to pumping from the LFA and to estimate the equivalent amount of pumping from the UFA that would produce similar drawdown. Pumping the well at a rate of 748 gal/min (about 1 million gallons per day [Mgal/d]) resulted in a maximum simulated steady-state drawdown of 36.2 ft in the LFA and was greater than 1 ft over a 146 square-mile area. Simulated steady-state drawdown in the overlying UFA that resulted from interaquifer leakage was greater than 1 ft over a 141 square-mile area and was 2.03 ft at the pumped well. Flow to the pumped well was derived from increased lateral flow across the specified-head boundary (0.02 Mgal/d) and increased leakage from the UFA (0.52 Mgal/d), and by reductions in discharge to the Lower Floridan confining unit (0.53 Mgal/d) and to the lateral specified-head boundary (0.53 Mgal/d). Sixty-five percent of the leakage from the UFA occurred within 1 mile of the pumped well. This larger contribution results from a larger head gradient between the pumped well and the overlying aquifer in areas close to the pumped well. The Georgia Environmental Protection Division interim permitting strategy for the LFA requires simulation of (1) aquifer leakage from the UFA to LFA resulting from pumping the new LFA well, and (2) the equivalent rate of UFA pumping that induces the identical maximum drawdown in the UFA that would be expected as a result of pumping th

Georgia

Lithostratigraphic and Hydrogeologic Characteristics of the Ordovician Sinnipee Group in the Vicinity of Waupun, Fond du Lac County, Wisconsin, 1995-96

Three boreholes were drilled at a farm site near Waupun, Wis., to improve the understanding of regional hydrogeology of the Ordovician Sinnipee Group. At the site the Sinnipee Group is the uppermost bedrock unit and is found to be about 183 ft thick. On the basis of core descriptions by the Illinois State Geological Survey, the Sinnipee Group at the site comprises (stratigraphically lowest to highest) the Platteville Formation (about 51 ft thick), the Decorah Formation (about 14 ft thick), and the Galena Dolomite (about 119 ft thick). The Illinois State Geological Survey noted that hardgrounds were common in the rock core, some having stratigraphic significance. Four very well developed hardgrounds were identified, three of which were used as formation or member contacts. The hardground at about 797 ft NGVD 29 represents the top of the Platteville Formation, the hardground at about 754 ft represents the top of the Pecatonica Member of the Platteville Formation, and the hardground at about 746 ft represents the top of the Glenwood Formation. On the basis of samples collected from one borehole, the ground water at the site is of the calcium-magnesium bicarbonate type. Trichloroethene was detected in one sample at a concentration of 1 ?g/L, and the concentration of antimony in one sample exceeded the U.S. Environmental Protection Agency (USEPA) Primary Drinking Water Standard. Other water samples contained aluminum and sodium in concentrations that exceeded the USEPA Secondary Drinking Water Standard and the USEPA Drinking Water Equivalent Level, respectively. Samples from various depths contained concentrations of iron, manganese, or dissolved manganese that were near or exceeded the USEPA Secondary Drinking Water Standard. The cross-borehole radar tomography data show differences in velocity and attenuation among the three major units in the Sinnipee Group. Matrix porosity measured in rock-core samples correlates well with these velocity and attenuation tomograms. The Galena Dolomite has the lowest mean porosity at 2.4 percent (7 samples) and is represented in the tomograms as generally having the lowest attenuation and greatest velocity. Below the Galena Dolomite is a transition to a zone with the greatest attenuation and lowest velocity on the tomograms. The rock core shows this interval to be the shaley dolomite of the Decorah Formation which has a mean porosity of 8.3 percent (2 samples). Below the Decorah Formation, the Platteville Formation has a mean porosity of 3.6 percent (6 samples) and is represented in the tomograms as having velocity and attenuation generally intermediate between the Galena Dolomite and the Decorah Formation. The evaluation of the single-hole directional ground-penetrating radar reflection survey in FL-800 identified 15 reflectors (secondary permeability features). Some of the reflectors do correlate with fractures and partings noted on geophysical logs and rock core; however, many additional fractures and partings identified by the televiewer log and/or core description were not measured by the borehole radar survey. Horizontal or sub-horizontal reflectors (bedding-plane partings) which do correlate with indications of bedding-plane partings on the acoustic televiewer intersect the borehole at about 917 ft, 907 ft, 870 ft, 805 ft, and 797 ft. The flowmeter profiles indicate that water entering and exiting the boreholes at seven bedding-plane partings accounts for most of the total borehole transmissivity. The flowmeter profiles in all three boreholes show that more than 90 percent of the total borehole transmissivity is provided by bedding-plane partings found at 870 ft and higher stratigraphically within the Galena Dolomite. Static water levels were measured in selected intervals of the three boreholes, and vertical hydraulic gradients were estimated by comparing levels in adjacent intervals. Gradients were found to be almost uniformly downward, ranging from -0.040 to -1.251 ft/ft. On th

Scientific Investigations Report

Organic contaminants, trace and major elements, and nutrients in water and sediment sampled in response to the Deepwater Horizon oil spill

Beach water and sediment samples were collected along the Gulf of Mexico coast to assess differences in contaminant concentrations before and after landfall of Macondo-1 well oil released into the Gulf of Mexico from the sinking of the British Petroleum Corporation's Deepwater Horizon drilling platform. Samples were collected at 70 coastal sites between May 7 and July 7, 2010, to document baseline, or "pre-landfall" conditions. A subset of 48 sites was resampled during October 4 to 14, 2010, after oil had made landfall on the Gulf of Mexico coast, called the "post-landfall" sampling period, to determine if actionable concentrations of oil were present along shorelines. Few organic contaminants were detected in water; their detection frequencies generally were low and similar in pre-landfall and post-landfall samples. Only one organic contaminant--toluene--had significantly higher concentrations in post-landfall than pre-landfall water samples. No water samples exceeded any human-health benchmarks, and only one post-landfall water sample exceeded an aquatic-life benchmark--the toxic-unit benchmark for polycyclic aromatic hydrocarbons (PAH) mixtures. In sediment, concentrations of 3 parent PAHs and 17 alkylated PAH groups were significantly higher in post-landfall samples than pre-landfall samples. One pre-landfall sample from Texas exceeded the sediment toxic-unit benchmark for PAH mixtures; this site was not sampled during the post-landfall period. Empirical upper screening-value benchmarks for PAHs in sediment were exceeded at 37 percent of post-landfall samples and 22 percent of pre-landfall samples, but there was no significant difference in the proportion of samples exceeding benchmarks between paired pre-landfall and post-landfall samples. Seven sites had the largest concentration differences between post-landfall and pre-landfall samples for 15 alkylated PAHs. Five of these seven sites, located in Louisiana, Mississippi, and Alabama, had diagnostic geochemical evidence of Macondo-1 oil in post-landfall sediments and tarballs. For trace and major elements in water, analytical reporting levels for several elements were high and variable. No human-health benchmarks were exceeded, although these were available for only two elements. Aquatic-life benchmarks for trace elements were exceeded in 47 percent of water samples overall. The elements responsible for the most exceedances in post-landfall samples were boron, copper, and manganese. Benchmark exceedances in water could be substantially underestimated because some samples had reporting levels higher than the applicable benchmarks (such as cobalt, copper, lead and zinc) and some elements (such as boron and vanadium) were analyzed in samples from only one sampling period. For trace elements in whole sediment, empirical upper screening-value benchmarks were exceeded in 57 percent of post-landfall samples and 40 percent of pre-landfall samples, but there was no significant difference in the proportion of samples exceeding benchmarks between paired pre-landfall and post-landfall samples. Benchmark exceedance frequencies could be conservatively high because they are based on measurements of total trace-element concentrations in sediment. In the less than 63-micrometer sediment fraction, one or more trace or major elements were anthropogenically enriched relative to national baseline values for U.S. streams for all sediment samples except one. Sixteen percent of sediment samples exceeded upper screening-value benchmarks for, and were enriched in, one or more of the following elements: barium, vanadium, aluminum, manganese, arsenic, chromium, and cobalt. These samples were evenly divided between the sampling periods. Aquatic-life benchmarks were frequently exceeded along the Gulf of Mexico coast by trace elements in both water and sediment and by PAHs in sediment. For the most part, however, significant differences between pre-landfall and post-landfall samples were limited to concentrations of PAHs in sediment. At five sites along the coast, the higher post-landfall concentrations of PAHs were associated with diagnostic geochemical evidence of Deepwater Horizon Macondo-1 oil.

Alabama, Arkansas, Florida, Georgia, Louisiana, Te

Simulation of groundwater flow in the Long Island, New York regional aquifer system for pumping and recharge conditions from 1900 to 2019

The U.S. Geological Survey has developed a transient, groundwater-flow model that simulates hydrologic conditions in the Long Island aquifer system as part of an ongoing (since 2016) multiyear, cooperative investigation with the New York State Department of Environmental Conservation. The goals of this investigation are to assist stakeholders and resource managers to evaluate the response of the hydrologic system to changes in future hydraulic stresses. Responses in the hydrologic system include changes in water levels in the hydrogeologic units; discharge to streams, coastal waters, and subsurface infrastructure; and the extent of saline groundwater in the aquifers. Hydraulic stresses include future water-supply management and changes in land use and infrastructure. The numerical model synthesizes a diverse set of physiographic, geologic, climatic, land-use, and historical population, water use, and infrastructure data to physically represent the Long Island aquifer system from land surface to bedrock and to simulate annual hydrologic conditions between 1900 and 2019. A three-dimensional hydrogeologic framework was developed from existing and recently collected borehole geologic and geophysical data collected as part of a companion drilling program. Water-transmitting properties of the principal aquifer sediments were defined in three dimensions from new and existing lithologic logs. The distribution of recharge from precipitation was estimated from landscape characteristics and climate data. Anthropogenic recharge from wastewater, leaky infrastructure, and storm runoff were estimated from population, infrastructure, and pumping data. Water-use data, including well locations, depths, and pumping rates, were obtained from historical sources and records and used to estimate pumping stresses continuously in time and space, at an annual average time scale. The data were incorporated into a three-dimensional numerical model using the U.S. Geological Survey finite difference modeling code MODFLOW 6; the model encompassed all of Long Island and surrounding surface waters and simulated historical hydrologic conditions from 1900 to 2019. The calibration process involved trial and error adjustments using prior knowledge to improve general fit to observations followed by an inverse calibration to update and optimize input parameters, using an iterative ensemble smoother algorithm implemented in PEST++ version 5.0. This resulted in a model that generally was in good agreement with observed, dynamically varying hydrologic conditions from 1900 to 2019. The calibrated model was used to develop two base-case models for scenario testing of future, hypothetical conditions where one represented average-annual conditions, and one represented average-seasonal conditions from 2010 to 2019. The model representing average-annual conditions was modified further to represent an alternate sea-level position of 6 feet above the North American Vertical Datum of 1988, and the model representing average-seasonal conditions was modified to represent the average seasonal effects of a 5-year drought imposed upon current hydrologic conditions. Recharge is the sole source of water to the aquifer system; groundwater discharges to coastal water and streams and is withdrawn by pumped wells. Model-estimated annual recharge ranged from about 11 inches in 1965 to 41 inches in 1983. On average, from 2010 to 2019, about 23 percent of water was pumped from wells, and about 47 and 27 percent discharged to coastal waters and streams, respectively; the remaining 4 percent was water that moved into storage in the aquifer matrix. Water levels on Long Island vary naturally during time in response to changes in recharge; the amount of variation is largest in the interior of the island, in areas with highest water table altitudes near groundwater divides and lowest near streams and the coastal waters. The total range of water table altitudes on Long Island between 1900 and 2019 ranged from near 0 to more than 70 feet in western parts of Long Island. The largest range in altitudes is in New York City and is associated with areas of large historical withdrawals between the 1920s and the late 1980s. Water table altitudes generally varied by less than 10 feet in eastern Suffolk County, where the aquifer is under more natural conditions. Saltwater intrusion is of great concern on Long Island, particularly in western Long Island where both the unconfined and confined parts of the aquifer system have been intruded in response to large-scale groundwater withdrawals; however, the volume of freshwater in the islandwide aquifer system only has changed by about 5 percent between 1900 and 2019. The decadal change in the freshwater volume was largest during the early and mid-20th century, corresponding to the largest historical pumping, but that volume change did not exceed 1 percent. The negligible change in freshwater volume suggests that saltwater intrusion as of 2019 was limited at an islandwide scale but continues to occur in local areas of Queens and Nassau Counties, adversely affecting current water supplies and limiting future water supplies for affected communities. The regional groundwater model developed for this investigation is a tool that can be used to help determine the viability of current and future water supplies at a regional scale and can be used to support development of additional models at finer scale to support more focused assessments of groundwater sustainability.

New York

Groundwater hydrology in the area of Savannah and Gunstocker Creeks in northeastern Hamilton, southern Meigs, and northwestern Bradley Counties, Tennessee, 2007–09

The U.S. Geological Survey, in cooperation with the Savannah Valley Utility District, evaluated the groundwater hydrology of the Valley and Ridge carbonate rock aquifer in northeastern Hamilton, southern Meigs, and northwestern Bradley Counties, Tennessee, from 2007 through 2009. The evaluation included, and built on, the results of test drilling conducted in the area in 1974 to determine the potential for groundwater as a source of public supply for the utility and the results of an investigation conducted to define recharge areas for wells used by groundwater-source public-supply water systems throughout Hamilton County in the early 1990s. Groundwater-level data collected from wells open to the aquifer in the study area were used to prepare potentiometric-surface maps for fall 1992, spring and fall 1993, summer 2008, and spring 2009 conditions. Two primary groundwater basins were delineated from the maps—the larger of which coincides with the watershed of Savannah Creek in the southern part of the study area and the smaller of which coincides with the watershed of Gunstocker Creek in the northern part of the study area. Both basins are characterized by potentiometric surfaces that contain a central area of low-altitude groundwater levels and low gradients relative to the basin margins that reflect the orientation of enhanced permeability along dissolution-enlarged features that have developed parallel to strike in the aquifer. The recharge area of the Savannah Creek groundwater basin is estimated to be about 31 square miles, and the recharge area of the Gunstocker Creek groundwater basin is estimated to be about 17 square miles. Recharge to the aquifer in the Savannah Creek and Gunstocker Creek groundwater basins primarily occurs in the uplands area along White Oak Mountain in the eastern part of the study area and along the western boundaries of the basins. Groundwater flows toward the potentiometric lows in each basin, discharging as base flow to the streams and to springs locally. Groundwater withdrawals for public supply by the utility influence the potentiometric low in the north-central part of the Savannah Creek groundwater basin and disrupt flow in the creek and nearby Anderson Spring, particularly during the summer and fall seasons. No large groundwater withdrawals currently occur in the Gunstocker Creek basin, but there is potential for groundwater supply development in the basin. A conceptual model of the groundwater hydrology of the area developed from the evaluation indicates that Chickamauga Lake is the base-level control on groundwater discharge from the Savannah Creek and Gunstocker Creek basins and that lake stage affects the potentiometric surfaces and groundwater discharge in the most downgradient parts of the basins as a result of inferred hydraulic connection between the aquifer and the lake. The model also infers that captured surface water from sections of Savannah Creek and the Hiwassee River that are embayed by the lake could recharge the aquifer and serve as a source of water withdrawn by wells in each basin if the potentiometric surfaces were lowered to altitudes less than the stage of the lake, particularly under potential future groundwater-development scenarios in the Gunstocker Creek basin. Geochemical analysis of samples collected from six wells for the study indicate that groundwater in the Valley and Ridge aquifer in the area generally is a calcium-magnesium-bicarbonate type, and although the water generally is hard, it is suitable for most uses. Trace-element concentrations were less than primary drinking-water criteria in all the samples. Results of the investigation indicate that options are available for additional groundwater withdrawal in the study area. Water-level data collected since 1975 at the Savannah Valley Utility District Smith Road well site indicate that some additional amount of groundwater is available for withdrawal from the aquifer in the Savannah Creek groundwater basin. The potentiometric low within the Gunstocker Creek groundwater basin indicates that an area with enhanced permeability is present as a northeastern counterpart to the potentiometric low within the Savannah Creek basin. Because the Gunstocker Creek basin is about one-half the total area of the Savannah Creek basin, a commensurate decrease in available groundwater storage is likely. Furthermore, groundwater withdrawal locations in the Gunstocker Creek basin would be closer to—and possibly connected hydraulically to—the Hiwassee River, thus increasing the potential for induced surface-water recharge in the basin if sustained drawdown from pumping lowered groundwater levels to altitudes less than the stage of the river.

Tennessee