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USGS2004

Water-quality and biological conditions in the Lower Boise River, Ada and Canyon Counties, Idaho, 1994-2002

The water quality and biotic integrity of the lower Boise River between Lucky Peak Dam and the river's mouth near Parma, Idaho, have been affected by agricultural land and water use, wastewater treatment facility discharge, urbanization, reservoir operations, and river channel alteration. The U.S. Geological Survey (USGS) and cooperators have studied water-quality and biological aspects of the lower Boise River in the past to address water-quality concerns and issues brought forth by the Clean Water Act of 1977. Past and present issues include preservation of beneficial uses of the river for fisheries, recreation, and irrigation; and maintenance of high-quality water for domestic and agricultural uses. Evaluation of the data collected from 1994 to 2002 by the USGS revealed increases in constituent concentrations in the lower Boise in a downstream direction. Median suspended sediment concentrations from Diversion Dam (downstream from Lucky Peak Dam) to Parma increased more than 11 times, nitrogen concentrations increased more than 8 times, phosphorus concentrations increased more than 7 times, and fecal coliform concentrations increased more than 400 times. Chlorophyll-a concentrations, used as an indicator of nutrient input and the potential for nuisance algal growth, also increased in a downstream direction; median concentrations were highest at the Middleton and Parma sites. There were no discernible temporal trends in nutrients, sediment, or bacteria concentrations over the 8-year study. The State of Idaho?s temperature standards to protect coldwater biota and salmonid spawning were exceeded most frequently at Middleton and Parma. Suspended sediment concentrations exceeded criteria proposed by Idaho Department of Environmental Quality most frequently at Parma and at all but three tributaries. Total nitrogen concentrations at Glenwood, Middleton, and Parma exceeded national background levels; median flow-adjusted total nitrogen concentrations at Middleton and Parma were higher than those in undeveloped basins sampled nationwide by the USGS. Total phosphorus concentrations at Glenwood, Middleton, and Parma also exceeded those in undeveloped basins. Macroinvertebrate and fish communities were used to evaluate the long-term integration of water-quality contaminants and loss of habitat in the lower Boise. Biological integrity of the macroinvertebrate population was assessed with the attributes (metrics) of Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and metrics used in the Idaho River Macroinvertebrate Index (RMI): taxa richness; EPT richness; percent dominant taxon; percent Elmidae (riffle beetles); and percent predators. Average EPT was about 10, and RMI scores were frequently below 16, which indicated intermediate or poor water quality. The number of EPT taxa and RMI scores for the lower Boise were half those for least-impacted streams in Idaho. The fine sediment bioassessment index (FSBI) was used to evaluate macroinvertebrate sediment tolerance. The FSBI scores were lower than those for a site upstream in the Boise River Basin near Twin Springs, a site not impacted by urbanization and agriculture, which indicated that the lower Boise macroinvertebrate population may be impacted by fine sediment. Macroinvertebrate functional feeding groups and percent tolerant species, mainly at Middleton and Parma, were typical of those in areas of degraded water quality and habitat. The biological integrity of the fish population was evaluated using the Idaho River Fish Index (RFI), which consists of the 10 metrics: number of coldwater native species, percent sculpin, percent coldwater species, percent sensitive native individuals, percent tolerant individuals, number of nonindigenous species, number of coldwater fish captured per minute of electrofishing, percent of fish with deformities (eroded fins, lesions, or tumors), number of trout age classes, and percent carp. RFI scores for lower Boise sites indicated a d

Scientific Investigations Report↗
USGS1944

Ground-water resources of the Houston district, Texas

This report covers the current phase of an investigation of the supply of ground water available for the Houston district and adjacent region, Texas,- that has been in progress during the past 10 years. The field operations included routine inventories of pumpage, measurements of water levels in observation wells and collection of other hydrologic data, pumping tests on 21 city-owned wells to determine coefficients of permeability and storage, and the drilling of 13 deep test wells in unexplored parts of the district. Considerable attention has been given to studies of the location of areas or beds of sand that contain salt water. The ground water occurs in beds of sand, sandstone, and gravel of Miocene, Pliocene, and Pleistocene age. These formations crop out in belts that dip southeastward from their outcrop areas and are encountered by wells at progressively greater depths toward the southeast. The beds throughout the section are lithologically similar, and there is little agreement among geologists as to their correlation. -In this investigation, however, the sediments, penetrated by the wells are separated into six zones, chiefly on the basis of electrical logs. Most of the water occurs in zone 3, which ranges in thickness from 800 to 1,200 feet. Large quantities of ground water are pumped in three areas in the Houston district, as follows: The Houston tromping area, which includes Houston and the areas immediately adjacent; the Pasadena pumping area, which includes the industrial section extending along the ship channel from the Houston city limits eastward to Deer Park; and the Katy pumping area, an irregular-shaped area of several hundred square miles, which is roughly centered around the town of Katy, 30 miles west of Houston. In 1930 the total combined withdrawal of ground water in the Houston and Pasadena pumping areas averaged about 50 million gallons a day. It declined somewhat during 1932 and 1933 and then gradually increased, until in 1935 the total pumpage was about the same as it was in 1930. About March 1, 1937, the pumpage was increased by about 40 percent, when new wells near Pasadena were put into operation. During 1940 it is estimated that the total pumpage in the Houston and Pasadena areas averaged about 79 million gallons a day, an increase of about 65 percent over the pumpage in 1935. About 25 million gallons of this increase has occurred in the Pasadena area. In the Katy rice-growing area the pumpage in 1935 was about 14 million gallons a day; in 1937 it was about 30 million gallons a day; in 1939 about 40 million gallons a day; and in 1940 about 45 million gallons a day. In 1940 the estimated total pumpage from the Houston, Pasadena, and Katy pumping areas was about 124 million gallons a day, or twice as much as it was in 1935. The increase in pumping at Pasadena in the spring-of 1937 caused the water leveling wells in the Houston and Pasadena areas, which had not varied materially for about 7 years, to decline at a rapid rate. Further increases in the pumping both at Houston and Pasadena in 1939 and 1940 has caused further substantial decline. The water levels in wells in the Katy rice-growing area also declined materially. The evidence points to the probability that in all parts of the Houston district, except the Katy rice-growing area, the rainfall is recharging the aquifers at a rate greater than that at which the water is transmitted down the dip. In the Katy area the recharge is insufficient to balance the joint discharge by transmission down the dip and withdrawal from rice-irrigating wells. The average coefficient of transmissibility was. calculated as 160,000 gallons a day. On the basis of these estimates the inflow in February 1940 across the artesian contour 10 feet below sea level (see pl. 10) was computed as 72 million gallons a day. The amount of water taken out of artesian storage in the 300-square mile area within the -10 contour during the period February 1939 to February

Water Supply Paper↗
USGS2018

Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

Groundwater quality in the approximately 7,820-square-kilometer (km 2 ) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km 2 ), Pajaro Valley (360 km 2 ), Salinas Valley (2,000 km 2 ), and Highlands (5,250 km 2 ). This study had two primary components: the status assessment and the understanding assessment . The first primary component of this study—the status assessment —assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment —identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system. Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low. Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids. Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA ( N -nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit. Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions. Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems. Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater. The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater. The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater. Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater. The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however. Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture. Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

California↗
USGS2011

Geologic framework and hydrogeology of the middle Carson River Basin, Eagle, Dayton, and Churchill Valleys, West-Central Nevada

Changes in land use and water use and increasing development of water resources in the middle Carson River basin may affect flow of the river and, in turn, affect downstream water users dependent on sustained river flows to Lahontan Reservoir. The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, began a study in 2008 of the middle Carson River basin, extending from Eagle Valley to Churchill Valley. Various types of geologic and hydrologic data were compiled from previous studies, collected for this study, and compiled and analyzed to provide a framework for development of a numerical model of the groundwater and surface-water flow systems of the basin. Geologic units that are assumed to have similar hydrologic characteristics were grouped into hydrogeologic units comprised of consolidated rocks of pre-Cenozoic age that underlie a unit of consolidated volcanic rock and semi-consolidated sediments of Tertiary age. The principal aquifer in the study area is comprised of unconsolidated sediments of Quaternary age. The Quaternary sediments include alluvial fan, fluvial, and lake sediments, and were grouped into a basin-fill hydrogeologic unit that overlies the pre-Cenozoic and Tertiary hydrologic units. The thickness of the combined section of Tertiary volcanic and sedimentary rocks and Quaternary basin-fill deposits previously was estimated to range from zero where pre-Cenozoic rocks are exposed to greater than 10,000 feet in the Bull Canyon subbasin, and greater than 6,000 feet on the western side of Churchill Butte and beneath the Desert Mountains. The thickness of Quaternary basin-fill sediments was estimated using gravity data and lithologic descriptions from driller’s logs. The most permeable parts of basin-fill sediments are greater than 1,000 feet thick in the Carson Plains subbasin, greater than 800 feet and 600 feet thick in the western and northeastern parts of the Stagecoach subbasin, and greater than 1,000 feet and 800 feet thick in the northern and southern parts of Churchill Valley, respectively. The distribution of aquifer properties was estimated for basin-fill sediments using slug-test and aquifer test data, and the lithologic descriptions of previously mapped geologic units. Slug-test data show hydraulic conductivity is greater than 10 to greater than 100 feet per day for fluvial sediments near the flood plain, less than 10 feet per day for basin-fill sediments outside the flood plain, and less than 1 foot per day for consolidated rocks. Estimates of transmissivity exceed 20,000 feet squared per day near the Carson River in Dayton, Churchill, and western Lahontan Valleys and in the northern part of the Stagecoach subbasin, and exceed 10,000 feet squared per day in the western part of Churchill Valley. A transmissivity of 90,000 feet squared per day was estimated from results of an aquifer test in the Carson Plains subbasin, indicating that permeable gravel and cobble zones at depths greater than 400 feet supplied water to the pumping well. Estimates of specific yield ranged from less than 1 to 2 percent for most consolidated rocks, from 1 to 15 percent for semi-consolidated Tertiary sediments, and from 10 to 40 percent for unconsolidated basin-fill sediments. Water-level altitude maps based on measurements at about 300 wells in 2009 show water levels have declined as much as 70 feet since 1964 on the northwestern side of Eagle Valley, about 10 feet since 1995 near Dayton in the Carson Plains subbasin, and from 5 to 10 feet since 1982 in the western and northeastern parts of the Stagecoach subbasin and the northwestern part of Churchill Valley. The declines are likely the result of municipal and agricultural pumping. The maps show a groundwater divide between the Carson Plains and Stagecoach subbasins, and a continuous hydraulic gradient between the Stagecoach subbasin and Churchill Valley. Groundwater flow directions are uncertain beneath parts of the boundary of Churchill Valley. The altitude of the top of pre-Cenozoic rocks shows thick sections of saturated Tertiary rocks and sediments south of the Dead Camel Mountains and beneath the eastern part of the Desert Mountains through which groundwater flow between Churchill Valley, Mason Valley, and Lahontan Valley may take place. North of Lahontan reservoir, beneath the Dead Camel Mountains, and beneath the southern part of Adrian Valley, the altitude of pre-Cenozoic rocks indicates groundwater flow between the three valleys is minimal. Streamflow measurements, supported by data on the deuterium content and specific conductance of surface-water samples, indicate a loss of Carson River streamflow in the Riverview subbasin, streamflow gains in the Moundhouse subbasin and the eastern part of the Carson Plains subbasin, and streamflow losses in the Bull Canyon subbasin. Comparisons of fluctuations in groundwater levels to those in stream stage in the Carson Plains subbasin indicate that streamflow lost to infiltration from the Carson River, from irrigation ditches, and from irrigated fields is an important source of groundwater recharge. Fluctuations in groundwater levels compared with the stage of Lahontan Reservoir in Churchill Valley indicate losses to infiltration from the reservoir during high stage and groundwater seepage to the reservoir during low stage.

Nevada↗
USGS2021

Geologic and hydrogeologic characteristics of the White River Formation, Lance Formation, and Fox Hills Sandstone, northern greater Denver Basin, southeastern Laramie County, Wyoming

In cooperation with the Wyoming State Engineer’s Office, the U.S. Geological Survey studied the geologic and hydrogeologic characteristics of Cenozoic and Upper Cretaceous strata at a location in southeastern Laramie County within the Wyoming part of the Cheyenne Basin, the northern subbasin of the greater Denver Basin. The study aimed to improve understanding of the aquifers/aquifer systems in these strata, motivated in part by declining groundwater levels and interest in exploring future groundwater supplies. Based on detailed geologic characterization using information obtained by drilling and coring a 960-foot-(ft) deep exploratory borehole, and comparisons with previously published descriptions, identified Cenozoic lithostratigraphic units included 40 ft of Quaternary older alluvial fan deposits consisting of an unconsolidated mixture of sand and gravel with lesser quantities of silt and clay in varying proportions and the underlying 407.3-ft-thick White River Formation of late Eocene-Oligocene age consisting largely of mudrocks with sparse thin beds of sandstone, muddy gravel, and conglomeratic mudrocks. Identified Upper Cretaceous lithostratigraphic units included the 351.6-ft-thick Lance Formation, consisting of terrestrial sedimentary rocks including mudrocks (muddy shale and silty and sandy shale, siltstone, claystone, and mudstone) interbedded with much smaller quantities of very fine- to medium-grained muddy and silty sandstone and coal; the 79.6-ft-thick Fox Hills Sandstone, consisting of a transitional marine sequence of muddy or silty sandstone present in five individual beds; and 86.7 ft of the upper transition member of the Pierre Shale, consisting largely of marine sedimentary rocks such as muddy shale. Beds of the upper and lower Fox Hills Sandstone were separated by tongues of the Lance Formation and upper transition member of the Pierre Shale, respectively. The White River hydrogeologic unit, consisting of the entire White River Formation or Group at the study site, did not contain any substantial secondary permeability features in the mudrocks that composed almost all the unit. A monitoring well (BR–1) was completed in the White River aquifer with the well screen open to the only coarse-grained unit (muddy sandstone) that had sufficient thickness and permeability to be considered as an aquifer. Sampling of the well for a broad suite of constituents indicated groundwater generally was of excellent quality except dissolved arsenic was detected at a concentration greater than the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level, and dissolved sodium was measured at a concentration greater than several EPA Drinking Water Advisory Levels (DWAs) for the constituent. Well development, well purging for groundwater sampling, and calculated aquifer properties indicated the sandstone aquifer screened by monitoring well BR–1 was not very productive. Analysis of the well water-level responses in BR–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response with wellbore-storage effects. Hydraulic properties estimated based on these responses yielded values of hydraulic conductivity ( K , 0.057 foot per day [ft/d]), specific storage ( Ss , 1.6×10 −6 per foot [ft −1 ]) and porosity ( n , 0.43). Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated an upward trend (+1.13 foot per year [ft/yr]) during the period analyzed, September 5, 2014, to September 30, 2017. Lithologic characteristics of the Lance hydrogeologic unit, consisting of the entire Lance Formation at the study site, indicated a potential aquifer in a “sandy” interval in the upper part of the unit. Most of the Lance hydrogeologic unit below the “sandy” interval consisted of various low-permeability lithologies unlikely to yield substantial quantities of water. This lower part of the hydrogeologic unit likely functions as a confining unit separating the underlying Lance-Fox Hills aquifer. A geologic cross section constructed for this study indicated fine-grained sediments composed most of the Lance Formation/hydrogeologic unit not only at the study location, but also throughout southern Laramie County along the line of section and throughout the Wyoming and Colorado parts of the Cheyenne Basin. A monitoring well (LN–1) completed in a sandstone bed in the “sandy” interval of the Lance hydrogeologic unit produced a mean of about 23 gallons per minute (gal/min) during well development, indicating sandstone beds can form moderately productive confined subaquifers in this part of the hydrogeologic unit. Analysis of the well water-level responses in well LN–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties estimated based on these responses yielded values for a lower bounding K of 0.60 ft/d, Ss of 1.6×10 −6 ft −1 , and n of 0.38. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−0.86 ft/yr) during the period analyzed (November 8, 2014, to September 30, 2017). Analyses for a broad suite of constituents in samples from well LN–1 indicated groundwater quality generally was excellent, although dissolved sodium was measured at a concentration greater than two EPA DWA levels for the constituent. Because of the absence of any overlying or intertonguing sandstone beds belonging to the lower/basal part of the Lance Formation, the Lance-Fox Hills aquifer at the study site consisted only of the five sandstone beds of the Fox Hills Sandstone. The cross section constructed for this study illustrated how the Fox Hills Sandstone, and thus, most of the Lance-Fox Hills aquifer, consists of a series of sandstone bodies that overlap (shingle) upward to the east across southern Laramie County. These bodies collectively form a fairly continuous body of sandstone, thus potentially forming an areally extensive aquifer across southern Laramie County, and by extension, throughout most of the formation’s extent in the Wyoming part of the Cheyenne Basin, as is the case in the Colorado part of the basin. A monitoring well (FH–1) completed in part of the thickest sandstone bed of the Lance-Fox Hills aquifer was moderately to highly productive and easily produced 25 to 30 gal/min after development. Substantially larger water production rates likely could be obtained by penetrating the full thickness of this bed and by completing a well open to the other overlying and underlying sandstone beds of the aquifer. Analysis of the water-level responses in well FH–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties computed based on these responses yielded values for a lower bounding estimate for K of 0.26 ft/d, for Ss of 1.0×10 −6 ft −1 , and for n of 0.41. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−1.74 ft/yr) during the period analyzed, December 19, 2014, to September 30, 2017. Sampling of monitoring well FH–1 and two production wells completed in the Fox Hills Sandstone in other parts of Laramie County indicated groundwater quality generally is excellent, although pH exceeded a recommended EPA aesthetic drinking-water standard (Secondary Maximum Contaminant Level) in two of three sampled wells, total dissolved solids concentrations exceeded the Secondary Maximum Contaminant Level in one of the two sampled production wells, and dissolved sodium was measured in all three sampled wells at a concentration greater than two EPA DWA levels for the constituent. The Wyoming Class II agricultural (irrigation) sodium adsorption ratio standard of 8 was exceeded in all three sampled wells, indicating these waters are not suitable for irrigation use. Computed vertical hydraulic gradients indicated a strong potential for downward flow throughout the groundwater system at the study site, including from the low-yielding aquifer in the upper White River Formation/hydrogeologic unit (monitoring well BR–1) to the sandstone subaquifer in the Lance Formation/hydrogeologic unit (monitoring well LN–1), and from the Lance subaquifer (monitoring well LN–1) to the sandstone bed/aquifer that composes much of the Lance-Fox Hills aquifer thickness at the study site (monitoring well FH–1). However, large hydraulic-head differences between wells indicated high resistance to vertical flow attributable to the low vertical hydraulic conductivity of intervening strata, which consisted almost entirely of low-permeability mudrocks. The confined nature of the sandstone aquifers monitored by the various wells coupled with dissimilarities between groundwater-level fluctuations and trends in groundwater levels indicated downward flow through the intervening strata (primarily mudrocks in the various lithostratigraphic/hydrogeologic units) between the examined sets of wells likely was small.

Wyoming↗
USGS2017

Geophysics- and geochemistry-based assessment of the geochemical characteristics and groundwater-flow system of the U.S. part of the Mesilla Basin/Conejos-Médanos aquifer system in Doña Ana County, New Mexico, and El Paso County, Texas, 2010–12

One of the largest rechargeable groundwater systems by total available volume in the Rio Grande/Río Bravo Basin (hereinafter referred to as the “Rio Grande”) region of the United States and Mexico, the Mesilla Basin/Conejos-Médanos aquifer system, supplies water for irrigation as well as for cities of El Paso, Texas; Las Cruces, New Mexico; and Ciudad Juárez, Chihuahua, Mexico. The U.S. Geological Survey in cooperation with the Bureau of Reclamation assessed the groundwater resources in the Mesilla Basin and surrounding areas in Doña Ana County, N. Mex., and El Paso County, Tex., by using a combination of geophysical and geochemical methods. The study area consists of approximately 1,400 square miles in Doña Ana County, N. Mex., and 100 square miles in El Paso County, Tex. The Mesilla Basin composes most of the study area and can be divided into three parts: the Mesilla Valley, the West Mesa, and the East Bench. The Mesilla Valley is the part of the Mesilla Basin that was incised by the Rio Grande between Selden Canyon to the north and by a narrow valley (about 4 miles wide) to the southeast near El Paso, Tex., named the Paso del Norte, which is sometimes referred to in the literature as the “El Paso Narrows.” Previously published geophysical data for the study area were compiled and these data were augmented by collecting additional geophysical and geochemical data. Geophysical resistivity measurements from previously published helicopter frequency domain electromagnetic data, previously published direct-current resistivity soundings, and newly collected (2012) time-domain electromagnetic soundings were used in the study to detect spatial changes in the electrical properties of the subsurface, which reflect changes that occur within the hydrogeology. The geochemistry of the groundwater system was evaluated by analyzing groundwater samples collected in November 2010 for physicochemical properties, major ions, trace elements, nutrients, pesticides (reported but not used in the assessment), and environmental tracers. The data obtained from these samples (with the exception of the pesticide data) were used to gain insights into processes controlling the groundwater movement through the groundwater system in the study area. Results from the geophysical and geochemical assessments facilitated the interpretation of the geochemical characteristics of the groundwater sources and geochemical groups within the groundwater system. The groundwater-flow system in the study area consists primarily of the Mesilla Basin aquifer system, which can be divided into four hydrogeologic units by using an informal classification scheme based on basin-fill stratigraphy and sedimentology with an emphasis on aquifer characteristics. The four hydrogeologic units are (1) the Rio Grande alluvium, which is the shallow aquifer of the Mesilla Basin within the confines of the Mesilla Valley, and the three hydrogeologic units that compose the Santa Fe Group: (2) the lower part of the Santa Fe Group, which is the least productive zone, (3) the middle part of the Santa Fe Group, which is the primary water-bearing hydrogeologic unit in the basin and is generally saturated, and (4) the upper part of the Santa Fe Group, which is the most productive water-bearing unit within the Santa Fe Group but is only partially saturated in the north and largely unsaturated in the south and western parts of the Mesilla Basin. The helicopter frequency domain electromagnetic survey results indicated that approximately half of the resistivity values were less than 10 ohm-meters at depths of 50 and 100 feet with a transition where the resistivity values changed from relatively high values (greater than 20 ohm-meters) to relatively low resistivity values (less than 10 ohm-meters) near Vado, New Mexico. Slightly more than 25 percent of the gridded resistivity values from the three-dimensional grid of the combined inverse modeling results of the direct-current resistivity and time-domain electromagnetic soundings were equal to or less than 10 ohm-meters with large regions of low resistivity becoming apparent in the southernmost part of the study area near the Paso Del Norte where these low resistivity features are spatially the widest at or below the top of the bedrock. These low resistivity values might represent clayey deposits, sediments composed largely of sand and gravel saturated with saline water, or both. Historical dissolved-solids-concentration data within the surface geophysical subset area of the study area were compiled and compared to the inverse modeling results of the combined direct-current resistivity and time-domain soundings; this comparison was done to strengthen the interpretation made from the combined inverse modeling results that the low resistivity features were representative of sand and gravel deposits saturated with saline water and not clayey deposits. Water-level altitudes within the Rio Grande alluvium generally decreased from north to south, with a west to east decrease in water-level altitudes near Las Cruces, New Mexico, as a result of groundwater pumping. Groundwater flow within the Santa Fe Group is more complex than the groundwater flow within the Rio Grande alluvium because of the larger lateral and vertical extent of the Santa Fe Group compared to the Rio Grande alluvium. Groundwater from the Organ Mountains flows directly south towards the Paso del Norte. Groundwater from the Robledo Mountains, the Rough and Ready Hills, and the Sleeping Lady Hills generally flows to the southeast. Groundwater flowing near the north end of the midbasin uplift generally continues east towards the Rio Grande and then flows south on the east side of the midbasin uplift. Groundwater flowing near the west side of the midbasin uplift generally continues south parallel to the faults that make up the midbasin uplift and then flows east towards the Paso del Norte when it reaches the south end of the midbasin uplift. Groundwater from the Aden Hills and the East and West Potrillo Mountains flows to the south end of the midbasin uplift and then continues east towards the Paso del Norte. Throughout most of the Mesilla Valley, the vertical hydraulic gradient was downward because the water-level altitude in the Rio Grande alluvium was higher than it was in the Santa Fe Group, but in some areas (typically in the middle and southern parts of the Mesilla Valley), the vertical hydraulic gradient was substantially reduced or even reversed to an upward hydraulic gradient. The geochemistry data indicate that there was a complex system of multiple geochemical endmembers and mixing between these endmembers with recharge to the Rio Grande alluvium and Santa Fe Group composed mostly of seepage from the Rio Grande, inflows from deeper or neighboring water systems, and mountain-front recharge. Five distinct geochemical groups were identified in the Mesilla Basin study area: (1) ancestral Rio Grande (pre-Pleistocene) geochemical group, (2) modern Rio Grande (Pleistocene to present) geochemical group, (3) mountain-front geochemical group, (4) deep groundwater upwelling geochemical group, and (5) unknown freshwater geochemical group. The ancestral Rio Grande groundwater was water that recharged into the system as seepage losses from the ancestral Rio Grande; this groundwater generally flows from north to south-southeast towards the Paso del Norte. Groundwater on the west side of the midbasin uplift generally flows south until it reaches the southern part of the study area; from the southern part of the study area, the groundwater flows east towards the Paso del Norte. Groundwater on the east side of the midbasin uplift flows south-southeast towards the Paso del Norte where it mixes with groundwater from the modern Rio Grande, uplifted areas in the west, and the deep saline source. The water type of the modern Rio Grande geochemical group ranged from calcium-sulfate water type in the northern part of the study area to sodium-chloride-sulfate water type in the southern part of the study area; from north to south there was a substantial increase in specific conductance, strontium-87/strontium-86 ratio, potassium, and the trace metals of iron and lithium, changing the water chemistry such that it became similar to the water chemistry of the deep groundwater upwelling geochemical group. From age-dating results, water in the modern Rio Grande geochemical group was recharged to the Rio Grande alluvium within the past 10 years. The mountain-front geochemical group was generally old water (apparent age was greater than 10,000 carbon-14 years before present) that was somewhat mineralized and has relatively high concentrations of fluoride and silica, which might indicate longer exposure to volcanic and siliciclastic rocks or aluminosilicate minerals. There were five different locations of recharge determined from the groundwater geochemistry within the mountain-front geochemical group, all having a slightly different geochemical signature: (1) the Rough and Ready Hills, Robledo Mountains, and the Sleeping Lady Hills, (2) the Doña Ana Mountains, (3) the Aden Hills and West Potrillo Mountains, (4) the East Potrillo Mountains, and (5) the Sierra Juárez in Mexico. The groundwater from the Rough and Ready Hills, Robledo Mountains, the Sleeping Lady Hills, and the Doña Ana Mountains generally flows toward the Rio Grande and eventually mixes together and with the modern Rio Grande groundwater. The groundwater originating from the Aden Hills and East and West Potrillo Mountains generally flows east to southeast at a slow rate and eventually mixes and continues east, where it mixes with groundwater from the ancestral Rio Grande geochemical group and with the groundwater from the Sierra Juárez. The groundwater from the Sierra Juárez flows north and then east towards the Paso del Norte where it mixes with groundwater from the uplifted areas in the west, ancestral and modern Rio Grande groundwater, and the upwelling groundwater from a deep saline source. The deep groundwater upwelling geochemical group had the highest concentrations of bicarbonate, potassium, silica, aluminum, iron, and lithium within the study area, indicating that it had been in contact with carbonate and siliciclastic rocks for a much longer period of time and at higher temperatures compared to the other geochemical groups, and was most likely ancient marine groundwater originating from the Paleozoic and Cretaceous carbonate rocks which was upwelling into the Mesilla Basin aquifer system in the southeastern part of the study area through the extensive fault systems. Direct-current resistivity and time-domain electromagnetic soundings support the interpretation of ancient marine groundwater upwelling into the Mesilla Basin aquifer system, as do the analytical results from wells, and the helicopter frequency domain electromagnetic data collected along the Rio Grande. The hydrogen-2/hydrogen-1 ratio and oxygen-18/oxygen-16 ratio isotopic results for samples in the unknown freshwater geochemical group did not plot on the Rio Grande evaporation line, indicating this group did not have a Rio Grande signature (that is, there was no isotopic evidence of a component of Rio Grande water) and it also had the lowest mineralized content of any geochemical group in the study area.

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