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USGS2011

Suspended sediment and organic contaminants in the San Lorenzo River, California, water years 2009-2010

This report presents analyses of suspended sediment and organic contaminants measured during a two-year study of the San Lorenzo River, central California, which discharges into the Pacific Ocean within the Monterey Bay National Marine Sanctuary. Most suspended-sediment transport occurred during flooding caused by winter storms; 55 percent of the sediment load was transported by the river during a three-day flood in January 2010. Concentrations of polyaromatic hydrocarbons can exceed regulatory criteria during high-flow events in the San Lorenzo River. These results highlight the importance of episodic sediment and contaminant transport in steep, mountainous, coastal watersheds and emphasize the importance of understanding physical processes and quantifying chemical constituents in discharge from coastal watersheds on event-scale terms.

Open-File Report↗

USGS1995

Hydrochemical processes during snowmelt in a subalpine watershed, Colorado, USA

Snowmelt is the primary hydrologic event in the studied subalpine watershed, generating streamflow for 3 months from a 1-month snowmelt period which commenced in mid-April 1992 and mid-May 1993. The melting rate of the snowpack varied diurnally and was asymmetrical, increasing rapidly to a maximum at the onset of daily melt followed by an attenuated decrease. Streamflow varied diurnally, displaying a similar pattern to that of snowmelt, but variations were much less marked. Groundwater levels also varied diurnally, but were more attenuated than that of streamflow, and the time of daily maximum coincided with the streamflow maximum, whereas the snowmelt maximum preceded them. The major ions in meltwater were preferentially eluted from the snowpack, and meltwater was dominated by calcium, sulfate, and nitrate. The concentration decreases observed in snowmelt are partially reflected in stream water. Groundwater was dominated by calcium and generally bicarbonate. Concentrations of weathering products (silica, alkalinity, and base cations) increased down gradient, consistent with an increase in water residence time. A watershed mass balance for 1992 and 1993 indicates that (1) a major percentage of the primarily atmospherically derived N-species are retained by the watershed, (2) the watershed is the major source of base cations and silica, and (3) for the 2 year combined, atmospheric deposition balances stream water transport of sulfate and chloride.

Biogeochemistry of seasonally snow-covered catchme↗

USGS2008

Debris flows and floods in southeastern Arizona from extreme precipitation in July 2006 — Magnitude, frequency, and sediment delivery

From July 31 to August 1, 2006, an unusual set of atmospheric conditions aligned to produce record floods and an unprecedented number of slope failures and debris flows in southeastern Arizona. During the week leading up to the event, an upper-level low-pressure system centered over New Mexico generated widespread and locally heavy rainfall in southeastern Arizona, culminating in a series of strong, mesoscale convective systems that affected the region in the early morning hours of July 31 and August 1. Rainfall from July 27 through 30 provided sufficient antecedent moisture that the storms of July 31 through August 1 resulted in record streamflow flooding in northeastern Pima County and eastern Pinal County. The rainfall caused at least 623 slope failures in four mountain ranges, including more than 30 near Bowie Mountain in the northern Chiracahua Mountains, and 113 at the southern end of the Huachuca Mountains within and adjacent to Coronado National Memorial. In the Santa Catalina Mountains north of Tucson, 435 slope failures spawned debris flows on July 31 that, together with flood runoff, damaged structures and roads, affecting infrastructure within Tucson’s urban boundary. Heavy, localized rainfall in the Galiuro Mountains on August 1, 2006, resulted in at least 45 slope failures and an unknown number of debris flows in Aravaipa Canyon. In the southern Santa Catalina Mountains, the maximum 3-day precipitation measured at a climate station for July 29-31 was 12.04 in., which has a 1,200-year recurrence interval. Other rainfall totals from late July to August 1 in southeastern Arizona also exceeded 1,000-year recurrence intervals. The storms produced floods of record along six watercourses, and these floods had recurrence intervals of 100-500 years. Repeat photography suggests that the spate of slope failures was historically unprecedented, and geologic mapping and cosmogenic dating of ancient debris-flow deposits indicate that debris flows reaching alluvial fans in the Tucson basin are extremely rare events. Although recent watershed changes—particularly the impacts of recent wildland fires—may be important locally, the record number of slope failures and debris flows were related predominantly to extreme precipitation, not other factors such as fire history. The large number of slope failures and debris flows in an area with few such occurrences historically underscores the rarity of this type of meteorological event in southeastern Arizona. Most slope failures appeared to be shallow-seated slope failures of colluvium on steep slopes that caused deep scour of chutes and substantial aggradation of channels downstream. In the southern Santa Catalina Mountains, we estimate that 1.5 million tons of sediment were released from slope failures into the channels of ten drainage basins. Thirty-six percent of this sediment (527,000 tons) is gravel-sized or smaller and is likely to be transported by streamflow out of the mountain drainages and into the drainage network of metropolitan Tucson. This sediment poses a potential flood hazard by reducing conveyance in fixed-section flood control structures along Rillito Creek and its major tributaries, although our estimates suggest that deposition may be small if it is distributed widely along the channel, which is expected. Using the stochastic debris-flow model LAHARZ, we simulated debris-flow transport from slope failures to the apices of alluvial fans flanking the southern Santa Catalina Mountains. Despite considerable uncertainty in applying coefficients developed from worldwide observations to conditions in the southern Santa Catalina Mountains, we predicted the approximate area of depositional zones for several 2006 debris flows, particularly for Soldier Canyon. Better results could be achieved in some canyons if sediment budgets could be developed to account for alternating transport and deposition zones in channels with abrupt expansions and contractions, such as Rattlesnake Canyon.

Arizona↗

USGS2002

Traveltime characteristics of Gore Creek and Black Gore Creek, upper Colorado River basin, Colorado

In the Rocky Mountains of Colorado, major highways are often constructed in stream valleys. In the event of a vehicular accident involving hazardous materials, the close proximity of highways to the streams increases the risk of contamination entering the streams. Recent population growth has contributed to increased traffic volume along Colorado highways and has resulted in increased movement of hazardous materials, particularly along Interstate 70. Gore Creek and its major tributary, Black Gore Creek, are vulnerable to such contamination from vehicular accidents along Interstate 70. Gore Creek, major tributary of the Eagle River, drains approximately 102 square miles, some of which has recently undergone significant urban development. The headwaters of Gore Creek originate in the Gore Range in the eastern part of the Gore Creek watershed. Gore Creek flows west to the Eagle River. Beginning at the watershed boundary on Vail Pass, southeast of Vail Ski Resort, Interstate 70 parallels Black Gore Creek and then closely follows Gore Creek the entire length of the watershed. Interstate 70 crosses Gore Creek and tributaries 20 times in the watershed. In the event of a vehicular accident involving a contaminant spill into Gore Creek or Black Gore Creek, a stepwise procedure has been developed for water-resource managers to estimate traveltimes of the leading edge and peak concentration of a conservative contaminant. An example calculating estimated traveltimes for a hypothetical contaminant release in Black Gore Creek is provided. Traveltime measurements were made during May and September along Black Gore Creek and Gore Creek from just downstream from the Black Lakes to the confluence with the Eagle River to account for seasonal variability in stream discharge. Fluorometric dye injection of rhodamine WT and downstream dye detection by fluorometry were used to measure traveltime characteristics of Gore Creek and Black Gore Creek. During the May traveltime measurements, discharges ranged from 82 cubic feet per second (ft 3 /s) at Black Gore Creek near Minturn (U.S. Geological Survey station number 09066000) to 724 ft 3 /s at Gore Creek at mouth near Minturn (U.S. Geological Survey station number 09066510), whereas during the September traveltime measurements, discharges ranged from 3.6 ft 3 /s at Black Gore Creek near Minturn to 62 ft 3 /s at Gore Creek at mouth near Minturn. Cumulative traveltimes for the peak dye concentration during the May traveltime measurements ranged from 3.45 hours (site 1 to site 3) in Black Gore Creek to 2.50 hours (site 8 to site 12) in Gore Creek, whereas cumulative traveltimes for the peak dye concentration during the September traveltime measurements ranged from 15.33 hours (site 1 to site 3) in Black Gore Creek to 8.65 hours (site 8 to site 12) in Gore Creek. During the September dye injections, beaver dams on Black Gore Creek, between site 1 and the confluence with Gore Creek, substantially delayed movement of the rhodamine WT. Estimated traveltimes were developed using relations established from linear-regression methods of relating measured peak traveltime to discharge during those measurements, which were obtained at Black Gore Creek near Minturn and Gore Creek at mouth near Minturn. Resulting estimated peak traveltimes for Black Gore Creek (sites 1 to 5) ranged from 5.4 to 0.4 hour for 20 to 200 ft 3 /s and for Gore Creek (sites 5 to 12), 5.5 to 0.3 hour for 20 to 800 ft 3 /s. Longitudinal-dispersion coefficients that were calculated for selected stream reaches ranged from 17.2 square feet per second at 4 ft 3 /s between sites 2 and 3 to 650 square feet per second at 144 ft 3/ s between sites 7 and 8. Longitudinal-dispersion coefficients are necessary variables for future stream-contaminant modeling in the Gore Creek watershed.

Colorado↗

USGS2018

Watershed ‘chemical cocktails’: forming novel elemental combinations in Anthropocene fresh waters

In the Anthropocene, watershed chemical transport is increasingly dominated by novel combinations of elements, which are hydrologically linked together as ‘chemical cocktails.’ Chemical cocktails are novel because human activities greatly enhance elemental concentrations and their probability for biogeochemical interactions and shared transport along hydrologic flowpaths. A new chemical cocktail approach advances our ability to: trace contaminant mixtures in watersheds, develop chemical proxies with high-resolution sensor data, and manage multiple water quality problems. We explore the following questions: (1) Can we classify elemental transport in watersheds as chemical cocktails using a new approach? (2) What is the role of climate and land use in enhancing the formation and transport of chemical cocktails in watersheds? To address these questions, we first analyze trends in concentrations of carbon, nutrients, metals, and salts in fresh waters over 100 years. Next, we explore how climate and land use enhance the probability of formation of chemical cocktails of carbon, nutrients, metals, and salts. Ultimately, we classify transport of chemical cocktails based on solubility, mobility, reactivity, and dominant phases: (1) sieved chemical cocktails (e.g., particulate forms of nutrients, metals and organic matter); (2) filtered chemical cocktails (e.g., dissolved organic matter and associated metal complexes); (3) chromatographic chemical cocktails (e.g., ions eluted from soil exchange sites); and (4) reactive chemical cocktails (e.g., limiting nutrients and redox sensitive elements). Typically, contaminants are regulated and managed one element at a time, even though combinations of elements interact to influence many water quality problems such as toxicity to life, eutrophication, infrastructure corrosion, and water treatment. A chemical cocktail approach significantly expands evaluations of water quality signatures and impacts beyond single elements to mixtures. High-frequency sensor data (pH, specific conductance, turbidity, etc.) can serve as proxies for chemical cocktails and improve real-time analyses of water quality violations, identify regulatory needs, and track water quality recovery following storms and extreme climate events. Ultimately, a watershed chemical cocktail approach is necessary for effectively co-managing groups of contaminants and provides a more holistic approach for studying, monitoring, and managing water quality in the Anthropocene.

Biogeochemistry↗

USGS2004

ArcCN-Runoff: An ArcGIS tool for generating curve number and runoff maps

The development and the application of ArcCN-Runoff tool, an extension of ESRI@ ArcGIS software, are reported. This tool can be applied to determine curve numbers and to calculate runoff or infiltration for a rainfall event in a watershed. Implementation of GIS techniques such as dissolving, intersecting, and a curve-number reference table improve efficiency. Technical processing time may be reduced from days, if not weeks, to hours for producing spatially varied curve number and runoff maps. An application example for a watershed in Lyon County and Osage County, Kansas, USA, is presented. ?? 2004 Elsevier Ltd. All rights reserved.

Environmental Modelling and Software↗

USGS2001

Effect of scale on the behavior of atrazine in surface waters

Field runoff is an important transport mechanism by which agricultural pesticides, including atrazine, move into the hydrologic environment. Atrazine is chosen because it is widely used, is transported in runoff relatively easily, is widely observed in surface waters, and has relatively little loss in the stream network. Data on runoff of atrazine from experimental plot and field studies is combined with annual estimates of load in numerous streams and rivers, resulting in a data set with 408 observations that span 14 orders of magnitude in area. The load as a percent of use (LAPU) on an annual basis is the parameter that is compared among the studies. There is no difference in the mean or range of LAPU values for areas from the size of experimental field plots (???0.000023 ha) and small watersheds (<100 000 ha). The relatively invariant LAPU value observed across a large range of watershed areas implies that the characteristics of atrazine itself (application method and chemical properties) are important in determining the extent of runoff. The variable influences on the extent of runoff from individual watershed characteristics and weather events are superimposed on the relatively invariant LAPU value observed across the range of watershed areas. The results from this study establish the direct relevance for agricultural field plot studies to watershed studies across the full range of scale.

Environmental Science & Technology↗

USGS2005

Transmission of atmospherically derived trace elements through an undeveloped, forested Maryland watershed

The transmission of atmospherically derived trace elements (Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn) was evaluated in a small, undeveloped, forested watershed located in north-central Maryland. Atmospheric input was determined for wet-only and vegetative throughfall components. Annual throughfall fluxes were significantly enriched over incident precipitation for most elements, although some elements exhibited evidence of canopy release (Mn) or preferential uptake (As, Cr, and Se). Stream export was gauged based on systematic sampling under varied flow regimes. Particle loading appears to contribute significantly to watershed export (> 10%) for only As, Pb, and Fe, and then only during large precipitation/runoff events. The degree of watershed transmission for each trace element was evaluated based on a comparison of total, net atmospheric input (throughfall) to stream export over an annual hydrologic cycle. This comparison indicates that the atmospheric input of some elements (Al, Cd, Ni, Zn) is effectively transmitted through the watershed, but other elements (Pb, As, Se, Fe, Cr, Cu) appear to be strongly sequestered, in the respective orders noted. Results suggest that precipitation and subsequent soil pH are the primary factors that determine the mobility of sequestered trace element phases. To further resolve primary atmospheric and secondary weathering components, the geochemical model NETPATH was applied. Results indicate that minerals dissolved include chlorite, plagioclase feldspar, epidote, and potassium feldspar; phases formed were kaolinite, pyrite, and silica. The model also indicates that weathering processes contribute negligible amounts of trace elements to stream export, indicative of the unreactive orthoquartzite bedrock lithology underlying the watershed. Thus, the stream export of trace elements primarily reflects atmospheric deposition to the local watershed.

Maryland↗

USGS2012

KINEROS2/AGWA: Model use, calibration and validation

KINEROS (KINematic runoff and EROSion) originated in the 1960s as a distributed event-based model that conceptualizes a watershed as a cascade of overland flow model elements that flow into trapezoidal channel model elements. KINEROS was one of the first widely available watershed models that interactively coupled a finite difference approximation of the kinematic overland flow equations to a physically based infiltration model. Development and improvement of KINEROS continued from the 1960s on a variety of projects for a range of purposes, which has resulted in a suite of KINEROS-based modeling tools. This article focuses on KINEROS2 (K2), a spatially distributed, event-based watershed rainfall-runoff and erosion model, and the companion ArcGIS-based Automated Geospatial Watershed Assessment (AGWA) tool. AGWA automates the time-consuming tasks of watershed delineation into distributed model elements and initial parameterization of these elements using commonly available, national GIS data layers. A variety of approaches have been used to calibrate and validate K2 successfully across a relatively broad range of applications (e.g., urbanization, pre- and post-fire, hillslope erosion, erosion from roads, runoff and recharge, and manure transport). The case studies presented in this article (1) compare lumped to stepwise calibration and validation of runoff and sediment at plot, hillslope, and small watershed scales; and (2) demonstrate an uncalibrated application to address relative change in watershed response to wildfire.

Transactions of the ASABE↗

USGS2004

Hydrologic and geochemical controls on pesticide and nutrient transport to two streams on the Delmarva Peninsula

Pesticides and nutrients move from application areas through ground water and surface runoff to streams on the Delmarva Peninsula. The relative importance of different transport media to the movement of these compounds in different watersheds is related to locally variable hydrologic and geochemical conditions among areas of regionally similar land use, geology, and soils. Consideration of such local variability is important to land-management efforts or future environmental investigations on the Peninsula. Chemical analyses of samples collected over a multiyear period from two streams on the Delmarva Peninsula were analyzed along with similar available analyses of ground water to document the occurrence of pesticides and nutrients, and illustrate important processes controlling their movement through watersheds to streams. The upper Pocomoke River and Chesterville Branch drain predominantly agricultural watersheds typical of the Delmarva Peninsula. Chesterville Branch drains a watershed of moderate relief, good drainage, and a permeable surficial aquifer that ranges in thickness from about 15 to 25 meters. The upper Pocomoke River Watershed, however, is extremely flat with poorly drained soils and abundant artificial drainage. Influences on the chemistry of water in each stream were determined from seasonal patterns in the concentrations of selected constituents from 1996 through 2001, and relations with streamflow. Nutrients and pesticides are detectable throughout the year in the upper Pocomoke River and Chesterville Branch. Water in both streams is typically dilute, slightly acidic, and well oxygenated, and nitrate and phosphorus concentrations generally exceed estimated natural levels. Pesticide concentrations are generally low, although concentrations of selected metabolites commonly exceed 1 microgram per liter, particularly in Chesterville Branch. Nitrate and metabolites of pesticide compounds are apparently transported to Chesterville Branch preferentially through ground water in the surficial aquifer, although selected pesticide parent compounds and less soluble nutrients move primarily in surface runoff. Conversely, the relative proportion of discharge from surficial and partially confined aquifers is the most important factor controlling the chemistry of water in the upper Pocomoke River. Surface runoff in the larger and predominantly flat upper Pocomoke River Watershed is apparently limited to particularly significant precipitation events. Transport of pesticides in surface runoff becomes important in both watersheds during such events. Instantaneous loads of pesticides in streams typically stabilize or continue to increase with increasing flow even after runoff begins, although in-stream concentrations may decrease due to dilution.

Scientific Investigations Report↗

USGS2011

Estimation of volumetric runoff coefficients for Texas watersheds using land-use and rainfall-runoff data

The rational method for peak discharge ( Q p "> Q p ) estimation was introduced in the 1880s. Although the rational method is considered simplistic, it remains an effective method for estimating peak discharge for small watersheds. The runoff coefficient ( C "> C ) is a key parameter for the rational method and can be estimated in various ways. Literature-based C "> C values ( C lit "> C lit ) are listed for different land-use/land cover (two words, no hyphen) (LULC) conditions in various design manuals and textbooks; however, these C lit "> C lit values were developed with little basis on observed rainfall and runoff data. In this paper, C lit "> C lit values were derived for 90 watersheds in Texas by using LULC data for 1992 and 2001; the C lit "> C lit values derived from the two data sets were essentially the same. Also for this study, volumetric runoff coefficients ( C v "> C v ) were estimated by using observed rainfall and runoff depths from more than 1,600 events observed in the watersheds. Watershed-median and watershed-average C v "> C v values were computed, and both are consistent with data from the National Urban Runoff Program. In addition, C v "> C v values were estimated by using rank-ordered pairs of rainfall and runoff depths (i.e., frequency matching). As anticipated, C "> C values derived by all three methods (literature based, event totals, and frequency matching) consistently had larger values for developed watersheds than for undeveloped watersheds. Two regression equations of C v "> C v versus percent impervious area were developed and combined into a single equation that can be used to rapidly estimate C v "> C v values for similar Texas watersheds.

Texas↗

USGS2010

Suspended-sediment sources in an urban watershed, Northeast Branch Anacostia River, Maryland

Fine sediment sources were characterized by chemical composition in an urban watershed , the Northeast Branch Anacostia River , which drains to the Chesapeake Bay. Concentrations of 63 elements and two radionuclides were measured in possible land-based sediment sources and suspended sediment collected from the water column at the watershed outlet during storm events. These tracer concentrations were used to determine the relative quantity of suspended sediment contributed by each source . Although this is an urbanized watershed , there was not a distinct urban signature that can be evaluated except for the contributions from road surfaces. We identified the sources of fine sediment by both physiographic province (Piedmont and Coastal Plain) and source locale (streambanks, upland and street residue) by using different sets of elemental tracers. The Piedmont contributed the majority of the fine sediment for seven of the eight measured storms. The streambanks contributed the greatest quantity of fine sediment when evaluated by source locale. Street residue contributed 13% of the total suspended sediment on average and was the source most concentrated in anthropogenically enriched elements. Combining results from the source locale and physiographic province analyses, most fine sediment in the Northeast Branch watershed is derived from streambanks that contain sediment eroded from the Piedmont physiographic province of the watershed . Sediment fingerprinting analyses are most useful when longer term evaluations of sediment erosion and storage are also available from streambankerosion measurements, sediment budget and other methods.

Maryland↗

USGS2021

Event scale relationships of DOC and TDN fluxes in throughfall and stemflow diverge from stream exports in a forested catchment

Aquatic fluxes of carbon and nutrients link terrestrial and aquatic ecosystems. Within forests, storm events drive both the delivery of carbon and nitrogen to the forest floor and the export of these solutes from the land via streams. To increase understanding of the relationships between hydrologic event character and the relative fluxes of carbon and nitrogen in throughfall, stemflow and streams, we measured dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) concentrations in each flow path for 23 events in a forested watershed in Vermont, USA. DOC and TDN concentrations increased with streamflow, indicating their export was limited by water transport of catchment stores. DOC and TDN concentrations in throughfall and stemflow decreased exponentially with increasing precipitation, suggesting that precipitation removed a portion of available sources from tree surfaces during the events. DOC and TDN fluxes were estimated for 76 events across a 2-year period. For most events, throughfall and stemflow fluxes greatly exceeded stream fluxes, but the imbalance narrowed for larger storms (>30 mm). The largest 10 stream events exported 40% of all stream event DOC whereas those same 10 events contributed 14% of all throughfall export. Approximately 2–5 times more DOC and TDN was exported from trees during rain events than left the catchment via streams annually. The diverging influence of event size on tree versus stream fluxes has important implications for forested ecosystems as hydrological events increase in intensity and frequency due to climate change.

Vermont↗

USGS2019

Shining light on the storm: In-stream optics reveal hysteresis of dissolved organic matter character

The quantity and character of dissolved organic matter (DOM) can change rapidly during storm events, affecting key biogeochemical processes, carbon bioavailability, metal pollutant transport, and disinfection byproduct formation during drinking water treatment. We used in situ ultraviolet–visible spectrophotometers to concurrently measure dissolved organic carbon (DOC) concentration and spectral slope ratio, a proxy for DOM molecular weight. Measurements were made at 15-minute intervals over three years in three streams draining primarily agricultural, urban, and forested watersheds. We describe storm event dynamics by calculating hysteresis indices for DOC concentration and spectral slope ratio for 220 storms and present a novel analytical framework that can be used to interpret these metrics together. DOC concentration and spectral slope ratio differed significantly among sites, and individual storm DOM dynamics were remarkably variable at each site and among the three sites. Distinct patterns emerged for storm DOM dynamics depending on land use/land cover (LULC) of each watershed. In agricultural and forested streams, DOC concentration increased after the time of peak discharge, and spectral slope ratio dynamics indicate that this delayed flux was of relatively higher molecular weight material compared to the beginning of each storm. In contrast, DOM character during storms at the urban stream generally shifted to lower molecular weight while DOC concentration increased on the falling limb, indicating either the introduction of lower molecular weight DOM, the exhaustion of a higher molecular weight DOM sources, or a combination of these factors. We show that the combination of high-frequency DOM character and quantity metrics have the potential to provide new insight into short-timescale DOM dynamics and can reveal previously unknown effects of LULC on the chemical nature, source, and timing of DOM export during storms.

Vermont↗

USGS2015

Legacy effects of wildfire on stream thermal regimes and rainbow trout ecology: an integrated analysis of observation and individual-based models

Management of aquatic resources in fire-prone areas requires understanding of fish species’ responses to wildfire and of the intermediate- and long-term consequences of these disturbances. We examined Rainbow Trout populations in 9 headwater streams 10 y after a major wildfire: 3 with no history of severe wildfire in the watershed (unburned), 3 in severely burned watersheds (burned), and 3 in severely burned watersheds subjected to immediate events that scoured the stream channel and eliminated streamside vegetation (burned and reorganized). Results of a previous study of this system suggested the primary lasting effects of this wildfire history on headwater stream habitat were differences in canopy cover and solar radiation, which led to higher summer stream temperatures. Nevertheless, trout were present throughout streams in burned watersheds. Older age classes were least abundant in streams draining watersheds with a burned and reorganized history, and individuals >1 y old were most abundant in streams draining watersheds with an unburned history. Burned history corresponded with fast growth, low lipid content, and early maturity of Rainbow Trout. We used an individual-based model of Rainbow Trout growth and demographic patterns to determine if temperature interactions with bioenergetics and competition among individuals could lead to observed phenotypic and ecological differences among populations in the absence of other plausible mechanisms. Modeling suggested that moderate warming associated with wildfire and channel disturbance history leads to faster individual growth, which exacerbates competition for limited food, leading to decreases in population densities. The inferred mechanisms from this modeling exercise suggest the transferability of ecological patterns to a variety of temperature-warming scenarios.

Idaho↗

USGS2009

High-frequency in situ optical measurements during a storm event: Assessing relationships between dissolved organic matter, sediment concentrations, and hydrologic processes

Dissolved organic matter (DOM) dynamics during storm events has received considerable attention in forested watersheds, but the extent to which storms impart rapid changes in DOM concentration and composition in highly disturbed agricultural watersheds remains poorly understood. In this study, we used identical in situ optical sensors for DOM fluorescence (FDOM) with and without filtration to continuously evaluate surface water DOM dynamics in a 415 km 2 agricultural watershed over a 4 week period containing a short-duration rainfall event. Peak turbidity preceded peak discharge by 4 h and increased by over 2 orders of magnitude, while the peak filtered FDOM lagged behind peak turbidity by 15 h. FDOM values reported using the filtered in situ fluorometer increased nearly fourfold and were highly correlated with dissolved organic carbon (DOC) concentrations (r 2 = 0.97), providing a highly resolved proxy for DOC throughout the study period. Discrete optical properties including specific UV absorbance (SUVA 254 ), spectral slope (S 290–350 ), and fluorescence index (FI) were also strongly correlated with in situ FDOM and indicate a shift toward aromatic, high molecular weight DOM from terrestrially derived sources during the storm. The lag of the peak in FDOM behind peak discharge presumably reflects the draining of watershed soils from natural and agricultural landscapes. Field and experimental evidence showed that unfiltered FDOM measurements underestimated filtered FDOM concentrations by up to ∼60% at particle concentrations typical of many riverine systems during hydrologic events. Together, laboratory and in situ data provide insights into the timing and magnitude of changes in DOM quantity and quality during storm events in an agricultural watershed, and indicate the need for sample filtration in systems with moderate to high suspended sediment loads.

Journal of Geological Research↗

USGS2018

Characterization and evaluation of controls on post-fire streamflow response across western U.S. watersheds

This research investigates the impact of wildfires on watershed flow regimes, specifically focusing on evaluation of fire events within specified hydroclimatic regions in the western United States, and evaluating the impact of climate and geophysical variables on response. Eighty-two watersheds were identified with at least 10 years of continuous pre-fire daily streamflow records and 5 years of continuous post-fire daily flow records. Percent change in annual runoff ratio, low flows, high flows, peak flows, number of zero flow days, baseflow index, and Richards–Baker flashiness index were calculated for each watershed using pre- and post-fire periods. Independent variables were identified for each watershed and fire event, including topographic, vegetation, climate, burn severity, percent area burned, and soils data. Results show that low flows, high flows, and peak flows increase in the first 2 years following a wildfire and decrease over time. Relative response was used to scale response variables with the respective percent area of watershed burned in order to compare regional differences in watershed response. To account for variability in precipitation events, runoff ratio was used to compare runoff directly to PRISM precipitation estimates. To account for regional differences in climate patterns, watersheds were divided into nine regions, or clusters, through k-means clustering using climate data, and regression models were produced for watersheds grouped by total area burned. Watersheds in Cluster 9 (eastern California, western Nevada, Oregon) demonstrate a small negative response to observed flow regimes after fire. Cluster 8 watersheds (coastal California) display the greatest flow responses, typically within the first year following wildfire. Most other watersheds show a positive mean relative response. In addition, simple regression models show low correlation between percent watershed burned and streamflow response, implying that other watershed factors strongly influence response. Spearman correlation identified NDVI, aridity index, percent of a watershed's precipitation that falls as rain, and slope as being positively correlated with post-fire streamflow response. This metric also suggested a negative correlation between response and the soil erodibility factor, watershed area, and percent low burn severity. Regression models identified only moderate burn severity and watershed area as being consistently positively/negatively correlated, respectively, with response. The random forest model identified only slope and percent area burned as significant watershed parameters controlling response. Results will help inform post-fire runoff management decisions by helping to identify expected changes to flow regimes, as well as facilitate parameterization for model application in burned watersheds.

Hydrology and Earth System Sciences↗

USGS2018

Direct channel precipitation and storm type influence short-term fallout radionuclide assessment of sediment source

Fallout radionuclides (FRNs) and their ratios, such as Beryllium‐7 ( 7 Be) and excess Lead‐210 ( 210 Pb xs ), have been used to determine suspended sediment source and age in catchments. These models are based on numerous assumptions, for example, that channel deposition of FRNs from precipitation is negligible in comparison to their delivery to the channel from land surface erosion during individual storm events. We test this assumption using a mass balance approach during eight storms from summer 2011 to fall 2012 in a mid‐Atlantic United States piedmont region watershed with mixed land use. Event peak discharge and storm type corresponded to the importance of direct channel FRN deposition from precipitation. During relatively low discharge summer thunderstorms, with minimal overland flow, less than 1% of 7 Be and 210 Pb xs flux deposited on the watershed exits the watershed associated with suspended sediment. The majority but not all deposited on the stream channel exits the watershed associated with suspended sediment (60% of 7 Be and 80% of 210 Pb xs ). Here precipitation and throughfall onto the wetted channel area can be responsible for any FRN newly associated with suspended sediment, as opposed to landscape surface erosion. Furthermore, FRNs can be stored with sediments in the channel between events. Events with higher discharges, including hurricanes, show the opposite pattern—FRN flux associated with suspended sediment exported from the reach is greater than channel FRN wet deposition, suggesting net erosion from the watershed landscape and/or stored material during these types of storms.

Water Resources Research↗