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At least 37 records · Page 2Linked to original sources

Chesapeake Bay impact structure: Morphology, crater fill, and relevance for impact structures on Mars

The late Eocene Chesapeake Bay impact structure (CBIS) on the Atlantic margin of Virginia is one of the largest and best-preserved "wet-target" craters on Earth. It provides an accessible analog for studying impact processes in layered and wet targets on volatile-rich planets. The CBIS formed in a layered target of water, weak clastic sediments, and hard crystalline rock. The buried structure consists of a deep, filled central crater, 38 km in width, surrounded by a shallower brim known as the annular trough. The annular trough formed partly by collapse of weak sediments, which expanded the structure to ???85 km in diameter. Such extensive collapse, in addition to excavation processes, can explain the "inverted sombrero" morphology observed at some craters in layered targets. The distribution of crater-fill materials i n the CBIS is related to the morphology. Suevitic breccia, including pre-resurge fallback deposits, is found in the central crater. Impact-modified sediments, formed by fluidization and collapse of water-saturated sand and silt-clay, occur in the annular trough. Allogenic sediment-clast breccia, interpreted as ocean-resurge deposits, overlies the other impactites and covers the entire crater beneath a blanket of postimpact sediments. The formation of chaotic terrains on Mars is attributed to collapse due to the release of volatiles from thick layered deposits. Some flat-floored rimless depressions with chaotic infill in these terrains are impact craters that expanded by collapse farther than expected for similar-sized complex craters in solid targets. Studies of crater materials in the CBIS provide insights into processes of crater expansion on Mars and their links to volatiles. ?? The Meteoritical Society, 2006.

Meteoritics and Planetary Science

Chemical structure of humic acids - Part 1, a generalized structural model

A new model is proposed for the structure of humic acids. In this model humic acid is pictured as being made up of a hierarchy of structural elements. At the lowest level in this hierarchy are simple phenolic, quinoid, and benzene carboxylic acid groups. These groups are bonded covalently into small particles. Particles of similar chemical structure are linked together by weak bonds to form "homogeneous" aggregates. Two or more different types of aggregates may be linked together to form mixed aggregates. Complexes of humic acid and clay minerals are also formed.

Journal of Research of the U.S. Geological Survey

Dipolar-dephasing 13C NMR studies of decomposed wood and coalified xylem tissue: Evidence for chemical structural changes associated with defunctionalization of lignin structural units during coalification

A series of decomposed and coalified gymnosperm woods was examined by conventional solid-state 13C nuclear magnetic resonance (NMR) and by dipolar-dephasing NMR techniques. The results of these NMR studies for a histologically related series of samples provide clues as to the nature of codification reactions that lead to the defunctionalization of lignin-derived aromatic structures. These reactions sequentially involve the following: (1) loss of methoxyl carbons from guaiacyl structural units with replacement by hydroxyls and increased condensation; (2) loss of hydroxyls or aryl ethers with replacement by hydrogen as rank increases from lignin to high-volatile bituminous coal; (3) loss of alkyl groups with continued replacement by hydrogen. The dipolar-dephasing data show that the early stages of coalification in samples examined (lignin to lignite) involve a decreasing degree of protonation on aromatic rings and suggest that condensation is significant during coalification at this early stage. An increasing degree of protonation on aromatic rings is observed as the rank of the sample increases from lignite to anthracite.

Energy & Fuels

CO2 hydrate: Synthesis, composition, structure, dissociation behavior, and a comparison to structure I CH4 hydrate

Structure I (sI) carbon dioxide (CO 2 ) hydrate exhibits markedly different dissociation behavior from sI methane (CH 4 ) hydrate in experiments in which equilibrated samples at 0.1 MPa are heated isobarically at 13 K/h from 210 K through the H 2 O melting point (273.15 K). The CO 2 hydrate samples release only about 3% of their gas content up to temperatures of 240 K, which is 22 K above the hydrate phase boundary. Up to 20% is released by 270 K, and the remaining CO 2 is released at 271.0 plusmn; 0.5 K, where the sample temperature is buffered until hydrate dissociation ceases. This reproducible buffering temperature for the dissociation reaction CO 2 ·nH 2 O = CO 2 (g) + nH 2 O(1 to s) is measurably distinct from the pure H 2 O melting point at 273.15 K, which is reached as gas evolution ceases. In contrast, when si CH 4 hydrate is heated at the same rate at 0.1 MPa, >95% of the gas is released within 25 K of the equilibrium temperature (193 K at 0.1 MPa). In conjunction with the dissociation study, a method for efficient and reproducible synthesis of pure polycrystalline CO 2 hydrate with suitable characteristics for material properties testing was developed, and the material was characterized. CO 2 hydrate was synthesized from CO 2 liquid and H 2 O solid and liquid reactants at pressures between 5 and 25 MPa and temperatures between 250 and 281 K. Scanning electron microscopy (SEM) examination indicates that the samples consist of dense crystalline hydrate and 50-300 μm diameter pores that are lined with euhedral cubic hydrate crystals. Deuterated hydrate samples made by this same procedure were analyzed by neutron diffraction at temperatures between 4 and 215 K; results confirm that complete conversion of water to hydrate has occurred and that the measured unit cell parameter and thermal expansion are consistent with previously reported values. On the basis of measured weight gain after synthesis and gas yields from the dissociation experiments, approximately all cages in the hydrate structure are filled such that n ≈ 5.75.

Journal of Physical Chemistry B

Crustal structure and quaternary acceleration of deformation rates in central Washington revealed by stream profile inversion, potential field geophysics, and structural geology of the Yakima folds

Post‐Miocene tectonic uplift along fault‐cored anticlines within central Washington produced the Yakima Fold Province, a region of active NNE‐SSW shortening in the Cascadian backarc. The relative timing and rate of deformation along individual structures is coarsely defined yet imperative for seismic hazard assessment. In this work, we use geomorphic and geophysical mapping, stream profile inversion, and balanced cross‐section methods to constrain fault geometries and slip rates in the Yakima Canyon region. We extract stream profiles from LiDAR data and analytically solve for the rate of relative rock uplift along several active fault‐cored anticlines. To constrain the fault geometries at depth and the long‐term magnitude of deformation, we constructed two line‐balanced cross sections across the folds with forward‐modeled magnetic and gravity anomaly data. Our stream profile results indicate an increase of incision rates in the Pleistocene, and we infer the increase is tectonically controlled. We estimate modern slip rates between 0.4 and 0.6 mm/year accommodated on reverse faults that core the Manastash Ridge, Umtanum Ridge, and Selah Butte anticlines and establish that these faults reactivate and invert older normal faults in basement rocks. Finally, we calculate the time required to accumulate sufficient strain energy for a large magnitude earthquake (M ≥ 7) along individual structures in the Yakima Fold Province. Results show that the Yakima folds likely accommodate large magnitude earthquakes and that it takes several hundred to several thousand years to accumulate sufficient strain energy for an M ≥ 7 earthquake.

Washington

Crustal structure of east central Oregon: Relation between Newberry Volcano and regional crustal structure

A 180-km-long seismic refraction transect from the eastern High Cascades, across Newberry Volcano, to the eastern High Lava Plains is used to investigate the subvolcanic crustal and upper mantle velocity structure there. Near-surface volcanic flows and sedimentary debris (1.6-4.7 km/s), ranging from 3 to 5 km in thickness, overlie subvolcanic Basin and Range structures. East and west of Newberry Volcano, the subvolcanic basement (5.6 km/s) has been downwarped, producing 5-km-deep basins. The midcrust (8- to 28-km depth) is characterized by velocities ranging from 6.1 to 6.5 km/s and varies laterally in thicknesses. The lower crust is characterized by an unusually high velocity (about 7.4 km/s), and its geometry mirrors the subvolcanic basement geometry. The Moho is located at a depth of 37 km and represents a transition to an upper mantle velocity of 8.1 km/s. The shallow subsurface (1.2 km) beneath Newberry Volcano is characterized by high-velocity 5.6 km/s, versus 4.1 km/s for the surrounding area) intrusions and appears to be located on a basement high. Beneath the seismic refraction array at Newberry Volcano, an absence of low-velocity anomalies suggests that large silicic magma chambers do not exist in the upper crust, but apparent high attenuation of the seismic wave field may be consistent with either partial melts in small volumes, elevated crustal temperatures, and/or poor geophone-recording site coupling.

Oregon

Crustal structure of Yunnan province, People's Republic of China, from seismic refraction profiles

Seismic refraction, profiles in Yunnan Province, southwestern China, define the crustal structure in an area of active tectonics on the southern end of the Himalaya-Burma arc. The crustal thickness ranges from 38 to 46 kilometers, and the relatively low mean crustal velocity indicates a crustal composition compatible with normal continental crust and consisting mainly of meta-sedimentary and silicic intrusive rocks, with little mafic or ultramafic component. This composition suggests a crustal evolution involving sedimentary processes on the flank of the Yangtze platform rather than the accretion of oceanic island arcs, as has been proposed. An anomalously low upper-mantle velocity observed on one profile but not on another at right-angles to it may indicate active tectonic processes in the mantle or seismic anisotropy.

Yunnan Province

Structure contours of base of upper Arapahoe aquifer in "Structure, outcrop, and subcrop of the bedrock aquifers along the western margin of the Denver Basin, Colorado." Hydrologic Atlas 742

This digital geospatial data set consists of structure contours on the base of the upper member of the Arapahoe aquifer. The U.S. Geological Survey developed this data set as part of a project described in the report,"Structure, Outcrop, and Subcrop of the Bedrock Aquifers Along the Western Margin of the Denver Basin, Colorado" (Robson and others, 1998)

Colorado

The regional structural setting of the 2008 Wells earthquake and Town Creek Flat Basin: implications for the Wells earthquake fault and adjacent structures

The 2008 Wells earthquake occurred on a northeast-striking, southeast-dipping fault that is clearly delineated by the aftershock swarm to a depth of 10-12 km below sea level. However, Cenozoic rocks and structures around Wells primarily record east-west extension along north- to north-northeast-striking, west-dipping normal faults that formed during the middle Miocene. These faults are responsible for the strong eastward tilt of most basins and ranges in the area, including the Town Creek Flat basin (the location of the earthquake) and the adjacent Snake Mountains and western Windermere Hills. These older west-dipping faults are locally overprinted by a younger generation of east-dipping, high-angle normal faults that formed as early as the late Miocene and have remained active into the Quaternary. The most prominent of these east-dipping faults is the set of en-échelon, north-striking faults that bounds the east sides of the Ruby Mountains, East Humboldt Range, and Clover Hill (about 5 km southwest of Wells). The northeastern-most of these faults, the Clover Hill fault, projects northward along strike toward the Snake Mountains and the approximately located surface projection of the Wells earthquake fault as defined by aftershock locations. The Clover Hill fault also projects toward a previously unrecognized, east-facing Quaternary fault scarp and line of springs that appear to mark a significant east-dipping normal fault along the western edge of Town Creek Flat. Both western and eastern projections may be northern continuations of the Clover Hill fault. The Wells earthquake occurred along this east-dipping fault system. Two possible alternatives to rupture of a northern continuation of the Clover Hill fault are that the earthquake fault (1) is antithetic to an active west-dipping fault or (2) reactivated a Mesozoic thrust fault that dips east as a result of tilting by the west-dipping faults along the west side of the Snake Mountains. Both alternatives are precluded by the depths of the earthquake and aftershocks, about 8 km and as deep as 12 km, respectively. These depths are below where an antithetic fault would intersect any main fault, and a tilted, formerly shallow and sub-horizontal thrust fault would not extend to depths of more than about 5–6 km. The east-dipping, high-angle, earthquake fault cuts older west-dipping faults rather than reactivating them, highlighting a change in the structural style of Basin and Range extension in this region from closely-spaced, west-dipping faults that rotated significantly during slip and accommodated large-magnitude extension, to widely-spaced, high-angle faults that accommodate much less total strain over a long time span.

Nevada

Tectonostratigraphy and major structures of the Georgian Greater Caucasus: Implications for structural architecture, along-strike continuity, and orogen evolution

Although the Greater Caucasus Mountains have played a central role in absorbing late Cenozoic convergence between the Arabian and Eurasian plates, the orogenic architecture and the ways in which it accommodates modern shortening remain debated. Here, we addressed this problem using geologic mapping along two transects across the southern half of the western Greater Caucasus to reveal a suite of regionally coherent stratigraphic packages that are juxtaposed across a series of thrust faults, which we call the North Georgia fault system. From south to north within this system, stratigraphically repeated ~5–10-km-thick thrust sheets show systematically increasing bedding dip angles (<30° in the south to subvertical in the core of the range). Likewise, exhumation depth increases toward the core of the range, based on low-temperature thermochronologic data and metamorphic grade of exposed rocks. In contrast, active shortening in the modern system is accommodated, at least in part, by thrust faults along the southern margin of the orogen. Facilitated by the North Georgia fault system, the western Greater Caucasus Mountains broadly behave as an in-sequence, southward-propagating imbricate thrust fan, with older faults within the range progressively abandoned and new structures forming to accommodate shortening as the thrust propagates southward. We suggest that the single-fault-centric “Main Caucasus thrust” paradigm is no longer appropriate, as it is a system of faults, the North Georgia fault system, that dominates the architecture of the western Greater Caucasus Mountains.

Geosphere

Changes in vegetation structure and gopher tortoise population structure after 17 years of restoration management

We examined a study plot sampled in the Conecuh National Forest of southern Alabama in 1999 and again in 2016 after stand thinning and persistent prescribed fire were used to improve habitat quality. These management activities were designed, in part, to enhance habitat quality for the gopher tortoise ( Gopherus polyphemus ), a species considered for protection under the Endangered Species Act because of range-wide population declines. Comparisons of vegetation structure were made at burrows that were active in 1999 and remained active in 2016, and at burrows that were active in 1999 but were classified as abandoned in 2016. Burrows that remained active across this span of time were distinctive in retaining a greater reduction of canopy cover and lacking hardwoods while having a high percentage of longleaf pine in neighboring canopy trees. Active burrows that were abandoned in 2016 were distinctive in possessing hardwoods among neighboring canopy trees, lacking pine seedlings in the midstory, and having increased frequency of legumes and decreased bare ground in the understory. All burrows experienced a decrease in canopy cover and an increase in distance to, and dbh of, neighboring canopy trees; all burrows also had a decrease in litter and non-legume forbs as well as an increase in shrub stems in the understory and midstory. These results indicate that management activities were successful in opening canopy cover but were largely unsuccessful at reducing shrub stems and increasing understory grasses and forbs. Nevertheless, burrows of gopher tortoises increased in abundance during this time period. The size distribution of these burrows changed from a unimodal distribution dominated by adults to a bimodal distribution indicative of increased juvenile recruitment. Thus, the gopher tortoise population increased in association with vegetation changes that suggest tortoises are more sensitive to shading caused by canopy closure than they are to available forage.

Alabama

Salinity, water level, and forest structure contribute to baldcypress (Taxodium distichum) rhizosphere and endosphere community structure

As rising sea levels alter coastal ecosystems, there is a pressing need to examine the effects of saltwater intrusion on coastal communities. Using 16S Illumina profiling, we characterized the communities of baldcypress tree ( Taxodium distichum ) root endosphere and rhizosphere soil bacteria. Our study utilized established sites along salinity and flooding gradients in the United States of Georgia, Louisiana, and South Carolina. We hypothesized that environmental variables, namely salinity and water level, as well as distance between sites would be correlated with baldcypress-associated rhizosphere and root endosphere bacterial communities. We found that geographic distance correlated with rhizosphere but not root endosphere bacterial communities, suggesting that the trees may have stabilized their endosphere communities via recruitment of a more specific suite of taxa from the surrounding soil. Mean water level, mean salinity, and the volume of woody debris were associated with both endosphere and rhizosphere bacterial communities in baldcypress trees. The density of host trees was also associated with endosphere community composition. Our study is the first to use 16S Illumina sequencing to characterize bacterial communities in baldcypress trees— a key restoration species in coastal swamp ecosystems under threat from rising sea levels.

Louisiana, Georgia, South Carolina