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Quaternary geologic map of the Hudson River 4° x 6° quadrangle, United States and Canada

The Quaternary Geologic Map of the Hudson River 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

Hudson River 4° x 6° quadrangle

Quaternary geologic map of the Lake Superior 4 degrees x 6 degrees quadrangle, United States and Canada

The Quaternary Geologic Map of the Lake Superior 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

IMAP

Quaternary geologic map of the Ottawa 4 degrees x 6 degrees quadrangle, United States and Canada

The Quaternary Geologic Map of the Ottawa 4 degree x 6 degree Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

IMAP

Quaternary geologic map of the Quebec 4 degrees x 6 degrees quadrangle, United States and Canada

The Quaternary Geologic Map of the Quebec 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the Earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

IMAP

Time-domain representation of frequency-dependent foundation impedance functions

Foundation impedance functions provide a simple means to account for soil-structure interaction (SSI) when studying seismic response of structures. Impedance functions represent the dynamic stiffness of the soil media surrounding the foundation. The fact that impedance functions are frequency dependent makes it difficult to incorporate SSI in standard time-history analysis software. This paper introduces a simple method to convert frequency-dependent impedance functions into time-domain filters. The method is based on the least-squares approximation of impedance functions by ratios of two complex polynomials. Such ratios are equivalent, in the time-domain, to discrete-time recursive filters, which are simple finite-difference equations giving the relationship between foundation forces and displacements. These filters can easily be incorporated into standard time-history analysis programs. Three examples are presented to show the applications of the method.

Soil Dynamics and Earthquake Engineering

Hyperspectral narrowband imaging spectroscopy: A new paradigm for Earth observation

This editorial introduces the Special Issue entitled “Hyperspectral Narrowband Imaging Spectroscopy: A New Paradigm for Earth Observation” in the August 2026 issue of Photogrammetric Engineering & Remote Sensing (PE&RS), the flagship journal of the American Society for Photogrammetry and Remote Sensing (ASPRS). This volume represents the fourth dedicated hyperspectral special issue published in PE&RS, following earlier contributions by Thenkabail et al. (2025, 2024a, 2024b), and continues ASPRS’s commitment to advancing cutting‑edge imaging spectroscopy research and its applications across Earth system science. Remote sensing is undergoing one of the most profound transformations in its history. The emergence of hyperspectral narrowband (HNB) imaging spectroscopy data, capable of acquiring hundreds of contiguous, narrow spectral bands, has shifted the discipline from observing Earth in a handful of broad spectral windows to capturing continuous spectral signatures of the Planet. This transition marks a decisive break from the multispectral paradigm that has dominated satellite remote sensing for nearly five decades, driven by the advent of new orbital imaging spectrometers such as EnMAP, PRISMA, and NASA’s EMIT, and by the forthcoming Surface Biology and Geology (SBG) mission ((Pires Silva et al., 2026; Bourriz et al., 2025; Thenkabail et al., 2025; Chabrillat et al., 2024; Aneece et al., 2024; Dave et al., 2024; Thenkabail et al., 2024a; Thenkabail et al., 2024b; Thenkabail, 2024a; Thenkabail, 2024b; Thompson et al., 2022; Kokaly et al., 2022; Aneece & Thenkabail, 2022; Cawse Nicholson et al., 2021; Guanter et al., 2021; Vangi et al., 2021; Thenkabail et al., 2021). These missions (e.g., Table 1) deliver unprecedented spectral fidelity, improved signal to noise ratios, and global coverage capabilities, enabling a new era of quantitative, spectroscopy based Earth observation. Where multispectral broadbands (MBBs) provide only a few discrete measurements along the electromagnetic spectrum, HNB systems deliver rich, diagnostic information that enables scientists to characterize Earth’s surface with unprecedented biochemical, biophysical, and structural detail (Figure 1a, 1b). The implications for environmental monitoring, agriculture, water resources, and mineral exploration are profound. Several overarching themes emerge: • Spectral fidelity matters. The ability to preserve subtle absorption features is essential for mineral mapping, vegetation trait retrieval, and biochemical modeling. • AI and deep learning are indispensable. From destriping to classification, modern analytics must be scalable, label‑efficient, and capable of exploiting the full spectral–spatial richness of HNB data. • Physics‑based and data‑driven approaches must converge. Radiative transfer models such as PROSAIL, enhanced with localized soil parameterizations, remain foundational for biophysical retrievals and model‑based inference. • Dimensionality reduction and feature extraction are critical. Techniques such as L1‑ISOMAP demonstrate that intelligent manifold learning can unlock the structure of fused, high‑dimensional datasets. • Next‑generation architectures must be interactive and multimodal. ICTNet exemplifies the future of hyperspectral classification: hybrid, synergistic, and capable of modeling both local textures and global spectral dependencies.

Photogrammetric Engineering and Remote Sensing (PE

The Loma Prieta, California, Earthquake of October 17, 1989: Performance of the built environment

Professional Paper 1552 focuses on the response of buildings, lifelines, highway systems, and earth structures to the earthquake. Losses to these systems totaled approximated $5.9 billion. The earthquake displaced many residents from their homes and severely disrupted transportation systems. Some significant findings were: * Approximately 16,000 housing units were uninhabitable after the earthquake including 13,000 in the San Francisco Bay region. Another 30,000-35,000 units were moderately damaged in the earthquake. Renters and low-income residents were particularly hard hit. * Failure of highway systems was the single largest cause of loss of life during the earthquake. Forty-two of the 63 earthquake fatalities died when the Cypress Viaduct in Oakland collapsed. The cost to repair and replace highways damaged by the earthquake was $2 billion, about half of which was to replace the Cypress Viaduct. * Major bridge failures were the result of antiquated designs and inadequate anticipation of seismic loading. * Twenty one kilometers (13 mi) of gas-distribution lines had to be replaced in several communities and more than 1,200 leaks and breaks in water mains and service connections had to be excavated and repaired. At least 5 electrical substations were badly damaged, overwhelming the designed redundancy of the electrical system. * Instruments in 28 buildings recorded their response to earthquake shaking that provided opportunities to understand how different types of buildings responded, the importance of site amplification, and how buildings interact with their foundation when shaken (soil structure interaction).

Professional Paper

U.S. Geological Survey programs and investigations related to soil and water conservation

The U.S. Geological Survey has a rich tradition of collecting hydrologic data, especially for fluxes of water and suspended sediment, that provide a foundation for studies of soil and water conservation. Applied and basic research has included investigations of the effects of land use on rangelands, croplands, and forests; hazards mapping; derivation of flood and drought frequency, and other statistics related to streamflow and reservoir storage; development and application of models of rainfall-runoff relations, chemical quality, and sediment movement; and studies of the interactive processes of overland and channel flow with vegetation. Networks of streamgaging stations and (or) sampling sites within numerous drainage basins are yielding information that extends databases and enhances the ability to use those data for interpretive studies.

International Journal of Sediment Research

Geohydrology of the shallow aquifers in the Denver metropolitan area, Colorado

The Denver metropolitan area is underlain by shallow layers of water-bearing sediments (aquifers) consisting of unconsolidated gravel, sand, silt, and clay. The depth to water in these aquifers is less than 20 feet in much of the area, and the aquifers provide a ready source of water to numerous shallow, small-capacity wells. The shallow depth to water also makes the aquifers susceptible to contamination from the land surface. Water percolating downward from residential, commercial, and industrial property, spills of hazardous materials, and leaks from underground storage tanks and pipelines can cause contaminants to enter the shallow aquifers. Wet basements, unstable foundation materials, and waterlogged soils also are common in areas of very shallow ground water. Knowledge of the extent, thickness, and water-table altitude of the shallow aquifers is incomplete. This, coupled with the complexity of development in this large metropolitan area, makes effective use, management, and protection of these aquifers extremely difficult. Mapping of the geologic and hydrologic characteristics of these aquifers would provide the general public and technical users with information needed to better use, manage, and protect this water resource. A study to map the geohydrology of shallow aquifers in the Denver metropolitan area was begun in 1994. The work was undertaken by the U.S. Geological Survey in cooperation with the U.S. Army-Rocky Mountain Arsenal, U.S. Department of Energy-Rocky Flats Field Office, Colorado Department of Public Health and Environment, Colorado Department of Natural Resources-State Engineers Office, Denver Water Department, Littleton-Englewood Wastewater Treatment Plant, East Cherry Creek Valley Water and Sanitation District, Metro Wastewater Reclamation District, Willows Water District, and the cities of Aurora, Lakewood, and Thornton. This report presents the results of a systematic mapping of the extent, thickness, and water-table altitude of the shallow aquifers in a 700-square-mile part of the greater Denver metropolitan area (fig. 1). The five sheets in this report (figs. 2-7) show (1) the thickness and extent of the unconsolidated sediments that overlie bedrock formations in the area, (2) the altitude and configuration of the buried bedrock surface, (3) the altitude of the water table and direction of ground-water movement, (4) the saturated thickness of the shallow aquifers, and (5) the depth to the water table in the shallow aquifers. The maps primarily are intended to indicate the general trends in altitude and thickness of the aquifers and are not intended to define conditions at specific sites.

Hydrologic Atlas

Remote sensing observations of landslides and ground deformation from the 2004 Niigata Ken Chuetsu earthquake

In recent years, major developments in remote sensing have made it possible to use these technologies to document the effects of earthquakes. Specifically, high-resolution satellite imagery and three-dimensional laser scanning (LIDAR) can provide important observations of earthquake damage that supplement traditional observations from field reconnaissance. The 2004 Niigata Ken Chuetsu earthquake provided an opportunity to use remote sensing to document the distribution of landslides in the epicentral region through the use of high-resolution satellite imagery and to document the detailed three-dimensional geometries of several failures using LIDAR. The satellite imagery was acquired the day after the earthquake, but at very large acquisition angles that resulted in image distortion. Nonetheless, the satellite imagery accurately identified the landslide distribution in the epicentral region, although the total area of landslides was underestimated by about 25% as compared with traditional aerial reconnaissance because of the large acquisition angle for the satellite imagery. Terrestrial LIDAR was used to collect three-dimensional data at several failure sites, including two large rock slides and a railroad tunnel portal affected by ground deformation. The LIDAR data allowed for precise measurement of failure deformations and geometries, and provided digital terrain models that could be archived and used in future analyses. In the future, satellite imagery and LIDAR, as well as other remote sensing technologies, will play an increasing role in documenting and understanding the effects of earthquakes.

Niigata Prefecture

Propagation of seismic waves in tall buildings

A discrete-time wave propagation formulation of the seismic response of tall buildings is introduced. The building is modeled as a layered medium, similar to a layered soil medium, and is subjected to vertically propagating seismic shear waves. Soil layers and the bedrock under the foundation are incorporated in the formulation as additional layers. Seismic response is expressed in terms of the wave travel times between the layers, and the wave reflection and transmission coefficients at the layer interfaces. The equations account for the frequency-dependent filtering effects of the foundation and floor masses. The calculation of seismic response is reduced to a pair of simple finite-difference equations for each layer, which can be solved recursively starting from the bedrock. Compared to the commonly used vibration formulation, the wave propagation formulation provides several advantages, including simplified calculations, better representation of damping, ability to account for the effects of the soil layers under the foundation, and better tools for identification and damage detection from seismic records. Examples presented show the versatility of the method. ?? 1998 John Wiley & Sons, Ltd.

Structural Design of Tall Buildings

Geology and occurrence of radon

The accumulation of radon indoors is commonly due to movement of radon from adjacent soil and rock into a building foundation through joints, utility openings, cracks, or porous block walls. When air pressure inside the building is lower than that in the soil, pressure-driven flow of radonbearing soil gas can occur (see Chapter 2). Whether or not an indoor radon problem results depends on: (1) the radium concentration in the soil and underlying rock, (2) the ability of radon to escape from the solid material holding the parent radium, and (3) the ability of radon to move through the rock and soil fractures and pores.

Book chapter

A combined microbial and ecosystem metric of carbon retention efficiency explains land cover-dependent soil microbial biodiversity–ecosystem function relationships

While soil organic carbon (C) is the foundation of productive and healthy ecosystems, the impact of the ecology of microorganisms on C-cycling remains unknown. We manipulated the diversity, applied here as species richness, of the microbial community present in similar soils on two contrasting land-covers—an adjacent pasture and forest—and observed the transformations of plant detritus and soil organic matter (SOM) using stable isotope ( 13 C) tracing coupled with a novel nuclear magnetic resonance (NMR) experiment. The amount of detritus-C degraded was not affected by the microbial diversity (p > 0.05), however the fate of detritus- and SOM-C across the diversity gradient was complex and land cover-dependent. For example, in the pasture soil, higher diversity led to lower CO 2 production (p = 0.001), a trend driven solely by SOM-C mineralization. There was no relationship between diversity and detritus-C mineralization or production of new mineral-associations after one year (p > 0.05). In contrast, in the forest soil higher diversity resulted in increased detritus-C (p = 0.01) and SOM-C (p = 0.0008) mineralization and decreased mineral-associated organic matter formation (p = 0.02). In both land cover types, retention efficiency—a measure that integrates both microbial physiology and the ability of the ecosystem to retain C—explained C loss and transformation trends. Overall, this demonstrates that the trajectory of C gained and lost is altered by land management-induced changes to microbial communities, soil structure, and chemical characteristics underlying SOM persistence.

Biogeochemistry Letters

The automated reference toolset: A soil-geomorphic ecological potential matching algorithm

Ecological inventory and monitoring data need referential context for interpretation. Identification of appropriate reference areas of similar ecological potential for site comparison is demonstrated using a newly developed automated reference toolset (ART). Foundational to identification of reference areas was a soil map of particle size in the control section (PSCS), a theme in US Soil Taxonomy. A 30-m resolution PSCS map of the Colorado Plateau (366,000 km 2 ) was created by interpolating ∼5000 field soil observations using a random forest model and a suite of raster environmental spatial layers representing topography, climate, general ecological community, and satellite imagery ratios. The PSCS map had overall out of bag accuracy of 61.8% (Kappa of 0.54, p < 0.0001), and an independent validation accuracy of 93.2% at a set of 356 field plots along the southern edge of Canyonlands National Park, Utah. The ART process was also tested at these plots, and matched plots with the same ecological sites (ESs) 67% of the time where sites fell within 2-km buffers of each other. These results show that the PSCS and ART have strong application for ecological monitoring and sampling design, as well as assessing impacts of disturbance and land management action using an ecological potential framework. Results also demonstrate that PSCS could be a key mapping layer for the USDA-NRCS provisional ES development initiative.

Soil Science Society of America Journal

Plant richness and composition in hardwood forest understories vary along an acidic deposition and soil-chemical gradient in the northeastern United States

Aims A century of atmospheric deposition of sulfur and nitrogen has acidified soils and undermined the health and recruitment of foundational tree species in the northeastern US. However, effects of acidic deposition on the forest understory plant communities of this region are poorly documented. We investigated how forest understory plant species composition and richness varied across gradients of acidic deposition and soil acidity in the Adirondack Mountains of New York State. Methods We surveyed understory vegetation and soils in hardwood forests on 20 small watersheds and built models of community composition and richness as functions of soil chemistry, nitrogen and sulfur deposition, and other environmental variables. Results Community composition varied significantly with gradients of acidic deposition, soil acidity, and base cation availability (63% variance explained). Several species increased with soil acidity while others decreased. Understory plant richness decreased significantly with increasing soil acidity ( r = 0.60). The best multivariate regression model to predict richness ( p < 0.001, adjusted -R 2 = 0.60) reflected positive effects of pH and carbon-to-nitrogen ratio (C:N). Conclusions The relationship we found between understory plant communities and a soil-chemical gradient, suggests that soil acidification can reduce diversity and alter the composition of these communities in northern hardwood forests exposed to acidic deposition.

New York

Preliminary geohydrologic assessment of Buenos Aires National Wildlife Refuge, Altar Valley, southeastern Arizona

The Buenos Aires National Wildlife Refuge is located in the southern part of Altar Valley, southwest of Tucson in southeastern Arizona. The primary water-supply well at the Buenos Aires National Wildlife Refuge has experienced a two-decade decrease in groundwater levels in the well, as have other wells in the southern part of Altar Valley. In part to understand this trend, a study was undertaken by the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, to summarize what is known about the geohydrologic system on the refuge and analyze groundwater-level trends and precipitation-groundwater correlations. In addition, available data were compiled where possible on the climate, land cover, soils, geology, and hydrology to provide a foundation for future modeling of the system. Altar Valley is a sedimentary basin bounded by a mixture of Paleozoic to Tertiary sedimentary, volcanic, granitic, and metamorphic rocks. The valley fill is undifferentiated Tertiary to Quaternary sediments underlain by middle Miocene to Pliocene rocks that consist of moderately to strongly consolidated conglomerate and sandstone. Surface water, when present in the predominantly ephemeral streams of the valley, flows from south to north. Arivaca Creek has a cienega (or wetland) where groundwater surfaces before it flows as a short perennial reach out of Arivaca Basin. Groundwater maps compiled between 1934 and 2016 showed groundwater flowing from south to north. Before the 1980s, temporal patterns of groundwater levels in wells in Altar Valley varied substantially from one well to another. In the mid-1980s, comparatively high levels of precipitation occurred: the 1980s median value was 15.3 inches, whereas the median for the period of record was 13.2 inches. In addition, apparently corresponding groundwater level increases were seen in nearly all wells studied. After this initial increase, two different groundwater-level trends began to be observed in two spatially distinct sets of wells: in the northern part, groundwater levels were relatively steady, whereas in the southern part, groundwater levels declined from 10 to 20 feet between 1990 and 2019. Annual groundwater pumpage declined substantially in the northern part of the valley beginning in the early 1980s, but it began to increase again in the 1990s. Pumpage in the southern part has remained low and relatively steady compared to the northern part. Although the precise reasons for the declining groundwater levels in the southern part remain unclear, groundwater levels may be affected by factors such as climate cycles, long-term drought, and temperature-induced declines in recharge, resulting in increased evapotranspiration. Preliminary analyses of two wells, one selected from each part of the valley, using linear regression and lag correlation to investigate correlation between annual precipitation and groundwater levels, showed a maximum correlation at a lag of about 17 years in the southern part of the valley and about 25 years in the northern part, indicating that, although variable sources and traveltimes of recharged water may be needed to propagate to each location, the strongest correlation at each well is with precipitation that was recharged 17 and 25 years prior to the groundwater response in that well. Assuming a constant flow of groundwater from the southern to the northern part of the valley, a decrease in recharge is expected to lead to a decrease in aquifer storage. As to the comparatively stable groundwater levels in the northern part, pumpage is still only about one-half what it was in the early 1980s, even though pumpage has increased there since the 1990s. Water levels in most wells in the northern part were drawn down prior to the decrease in pumping in the early 1980s, possibly owing to a combination of pumping and the nearly 20-year midcentury drought that occurred between 1940 and 1960. Water levels were in the process of recovering when the increase in pumping occurred in the 1990s. Because the water levels were recovering (increasing) instead of remaining static, the increased pumping may have only limited the recovery rather than causing a decrease in water levels, as a new quasi-equilibrium state may have been reached. Additional possible causes for the stable groundwater levels include (1) upgradient aquifer transmissivity that was high enough to offset pumping, (2) a low-permeability barrier, such as bedrock or clay, at the north end of the valley that caused groundwater pooling, (3) higher lateral inflow of groundwater in the northern part of the valley, (4) a delay in the effect of storage declines propagating from the south, or (5) some combination thereof.

Arizona

Predicting foundation bunchgrass species abundances: Model-assisted decision-making in protected-area sagebrush steppe

Foundation species are structurally dominant members of ecological communities that can stabilize ecological processes and influence resilience to disturbance and resistance to invasion. Being common, they are often overlooked for conservation but are increasingly threatened from land use change, biological invasions, and over-exploitation. The pattern of foundation species abundances over space and time may be used to guide decision-making, particularly in protected areas for which they are iconic. We used ordinal logistic regression to identify the important environmental influences on the abundance patterns of bluebunch wheatgrass ( Pseudoroegneria spicata ), Thurber's needlegrass ( Achnatherum thurberianum ), and Sandberg bluegrass ( Poa secunda ) in protected-area sagebrush steppe. We then predicted bunchgrass abundances along gradients of topography, disturbance, and invasive annual grass abundance. We used model predictions to prioritize the landscape for implementation of a management and restoration decision-support tool. Models were fit to categorical estimates of grass cover obtained from an extensive ground-based monitoring dataset. We found that remnant stands of abundant wheatgrass and bluegrass were associated with steep north-facing slopes in higher and more remote portions of the landscape outside of recently burned areas where invasive annual grasses were less abundant. These areas represented only 25% of the landscape and were prioritized for protection efforts. Needlegrass was associated with south-facing slopes, but in low abundance and in association with invasive cheatgrass ( Bromus tectorum ). Abundances of all three species were strongly negatively correlated with occurrence of another invasive annual grass, medusahead ( Taeniatherum caput-medusae ). The rarity of priority bunchgrass stands underscored the extent of degradation and the need for prioritization. We found no evidence that insularity reduced invasibility; annual grass invasion represents a serious threat to protected-area bunchgrass communities. Our study area was entirely within the Wyoming big sagebrush ecological zone, understood to have inherently low resilience to disturbance and resistance to weed invasion. However, our study revealed important variation in abundance of the foundation species associated with resilience and resistance along the topographic-soil moisture gradient within this zone, providing an important foothold for conservation decision-making in these steppe ecosystems. We found the foundation species focus a parsimonious strategy linking monitoring to decision-making via biogeographic modeling.

Ecosphere

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado