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The U. S. Geological Survey, Digital Spectral Library: Version 1 (0.2 to 3.0um)

We have developed a digital reflectance spectral library, with management and spectral analysis software. The library includes 498 spectra of 444 samples (some samples include a series of grain sizes) measured from approximately 0.2 to 3.0 um . The spectral resolution (Full Width Half Maximum) of the reflectance data is <= 4 nm in the visible (0.2-0.8 um) and <= 10 nm in the NIR (0.8-2.35 um). All spectra were corrected to absolute reflectance using an NIST Halon standard. Library management software lets users search on parameters (e.g. chemical formulae, chemical analyses, purity of samples, mineral groups, etc.) as well as spectral features. Minerals from borate, carbonate, chloride, element, halide, hydroxide, nitrate, oxide, phosphate, sulfate, sulfide, sulfosalt, and the silicate (cyclosilicate, inosilicate, nesosilicate, phyllosilicate, sorosilicate, and tectosilicate) classes are represented. X-Ray and chemical analyses are tabulated for many of the entries, and all samples have been evaluated for spectral purity. The library also contains end and intermediate members for the olivine, garnet, scapolite, montmorillonite, muscovite, jarosite, and alunite solid-solution series. We have included representative spectra of H2O ice, kerogen, ammonium-bearing minerals, rare-earth oxides, desert varnish coatings, kaolinite crystallinity series, kaolinite-smectite series, zeolite series, and an extensive evaporite series. Because of the importance of vegetation to climate-change studies we have include 17 spectra of tree leaves, bushes, and grasses. The library and software are available as a series of U.S.G.S. Open File reports. PC user software is available to convert the binary data to ascii files (a separate U.S.G.S. open file report). Additionally, a binary data files are on line at the U.S.G.S. in Denver for anonymous ftp to users on the Internet. The library search software enables a user to search on documentation parameters as well as spectral features. The analysis system includes general spectral analysis routines, plotting packages, radiative transfer software for computing intimate mixtures, routines to derive optical constants from reflectance spectra, tools to analyze spectral features, and the capability to access imaging spectrometer data cubes for spectral analysis. Users may build customized libraries (at specific wavelengths and spectral resolution) for their own instruments using the library software. We are currently extending spectral coverage to 150 um. The libraries (original and convolved) will be made available in the future on a CD-ROM.

Open-File Report

1890 and 1990 Bathymetry of Florida Bay

This Open File Report contains bathymetric data collected in Florida Bay by the US Geological Survey, South Florida Place-Based Studies Program using SANDS (System for Accurate Nearshore Depth Surveying). SANDS is a USGS developed, high precision bathymetric system which integrates depth soundings, boat motion, and GPS positioning needed for nearshore bathymetric mapping. Data acquisition occurred between 1995 and 1999 on a 22' shallow draft boat. Processed data points are in X, Y, Z format and relative to the North American Datum of 1983 (GRS80/NAD83) and the North American Vertical Datum of 1988 (NAVD88). Vertical control was derived from GPS data processed with Jet Propulsion Laboratory GIPSY software. Horizontal and vertical accuracies are within +/- 4 centimeters and +/- 8 centimeters, respectively.

Florida

Digital atlas of Oklahoma

This compact disc contains 25 digital map data sets covering the State of Oklahoma that may be of interest to the general public, private industry, schools, and government agencies. Fourteen data sets are statewide. These data sets include: administrative boundaries; 104th U.S. Congressional district boundaries; county boundaries; latitudinal lines; longitudinal lines; geographic names; indexes of U.S. Geological Survey 1:100,000, and 1:250,000-scale topographic quadrangles; a shaded-relief image; Oklahoma State House of Representatives district boundaries; Oklahoma State Senate district boundaries; locations of U.S. Geological Survey stream gages; watershed boundaries and hydrologic cataloging unit numbers; and locations of weather stations. Eleven data sets are divided by county and are located in 77 county subdirectories. These data sets include: census block group boundaries with selected demographic data; city and major highways text; geographic names; land surface elevation contours; elevation points; an index of U.S. Geological Survey 1:24,000-scale topographic quadrangles; roads, streets and address ranges; highway text; school district boundaries; streams, river and lakes; and the public land survey system. All data sets are provided in a readily accessible format. Most data sets are provided in Digital Line Graph (DLG) format. The attributes for many of the DLG files are stored in related dBASE(R)-format files and may be joined to the data set polygon attribute or arc attribute tables using dBASE(R)-compatible software. (Any use of trade names in this publication is for descriptive purposes only and does not imply endorsement by the U.S. Government.) Point attribute tables are provided in dBASE(R) format only, and include the X and Y map coordinates of each point. Annotation (text plotted in map coordinates) are provided in AutoCAD Drawing Exchange format (DXF) files. The shaded-relief image is provided in TIFF format. All data sets except the shaded-relief image also are provided in ARC/INFO export-file format.

Open-File Report

Assessment of the geoavailability of trace elements from minerals in mine wastes: analytical techniques and assessment of selected copper minerals

In this study, four randomly selected copper-bearing minerals were examined&mdash;azurite, malachite, bornite, and chalcopyrite. The objectives were to examine and enumerate the crystalline and chemical properties of each of the minerals, to determine which, if any, of the Cu-bearing minerals might adversely affect systems biota, and to provide a multi-procedure reference. Laboratory work included use of computational software for quantifying crystalline and amorphous material and optical and electron imaging instruments to model and project crystalline structures. Chemical weathering, human fluid, and enzyme simulation studies were also conducted. The analyses were conducted systematically: X-ray diffraction and microanalytical studies followed by a series of chemical, bio-leaching, and toxicity experiments.

Scientific Investigations Report

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

The distribution of selected elements and minerals in soil of the conterminous United States

In 2007, the U.S. Geological Survey initiated a low-density (1 site per 1600 km 2 , 4857 sites) geochemical and mineralogical survey of soil of the conterminous United States as part of the North American Soil Geochemical Landscapes Project. Three soil samples were collected, if possible, from each site; (1) a sample from a depth of 0 to 5 cm, (2) a composite of the soil A-horizon, and (3) a deeper sample from the soil C-horizon or, if the top of the C-horizon was at a depth greater than 100 cm, from a depth of approximately 80–100 cm. The < 2 mm fraction of each sample was analysed for a suite of 45 major and trace elements following near-total multi-acid digestion. The major mineralogical components in samples from the soil A- and C-horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling ended in 2010 and chemical and mineralogical analyses were completed in May 2013. Maps of the conterminous United States showing predicted element and mineral concentrations were interpolated from actual soil data for each soil sample type by an inverse distance weighted (IDW) technique using ArcGIS software. Regional- and national-scale map patterns for selected elements and minerals apparent in interpolated maps are described here in the context of soil-forming factors and possible human inputs. These patterns can be related to (1) soil parent materials, for example, in the distribution of quartz, (2) climate impacts, for example, in the distribution of feldspar and kaolinite, (3) soil age, for example, in the distribution of carbonate in young glacial deposits, and (4) possible anthropogenic loading of phosphorus (P) and lead (Pb) to surface soil. This new geochemical and mineralogical data set for the conterminous United States represents a major step forward from prior national-scale soil geochemistry data and provides a robust soil data framework for the United States now and into the future.

Journal of Geochemical Exploration

National energy research seismic library; Powder River basin, Montana-Wyoming; surface reflection and vertical seismic profile data used in seismic-stratigraphic investigations for ground-water aquifers and hydrocarbon traps

This Digital Data Series publication contains both raw and processed seismic data recorded during the period 1975 through 1978 by several geophysical service companies under contract to the USGS in the following study areas of the Powder River Basin, Montana and Wyoming: 1. Powder River and Custer Counties, MT (T. 1 S., T. 1-2 N., R. 53-54 E.) 2. Carter County, MT (T. 57-58 N., R. 65 W.) and Crook County, WY (T. 9 S., R.57-58 E.) 3. Powder River and Carter Counties, MT (T. 8 S., R. 53-55 E.) 4. Niobrara County, WY (T. 36-38 N., R. 61-62 W.) and Weston County, WY (T. 45 N., R. 61 W.) Four multichannel Vibroseis seismic lines, six Vertical Seismic Profiles (VSP's), and associated support material (observer's notes, X-Y coordinates, elevations of source and receivers, for example) are included. The raw (unprocessed) field data and a processed version of each surface profile and VSP are contained in standard SEG-Y format files; support material are in ASCII format text files. The processed surface data are versions which were reprocessed by the USGS in 1995 using state-of-the-art seismic data processing software.

Data Series

Processing and review interface for strong motion data (PRISM) software, version 1.0.0—Methodology and automated processing

A continually increasing number of high-quality digital strong-motion records from stations of the National Strong-Motion Project (NSMP) of the U.S. Geological Survey (USGS), as well as data from regional seismic networks within the United States, call for automated processing of strong-motion records with human review limited to selected significant or flagged records. The NSMP has developed the Processing and Review Interface for Strong Motion data (PRISM) software to meet this need. In combination with the Advanced National Seismic System Quake Monitoring System (AQMS), PRISM automates the processing of strong-motion records. When used without AQMS, PRISM provides batch-processing capabilities. The PRISM version 1.0.0 is platform independent (coded in Java), open source, and does not depend on any closed-source or proprietary software. The software consists of two major components: a record processing engine and a review tool that has a graphical user interface (GUI) to manually review, edit, and process records. To facilitate use by non-NSMP earthquake engineers and scientists, PRISM (both its processing engine and review tool) is easy to install and run as a stand-alone system on common operating systems such as Linux, OS X, and Windows. PRISM was designed to be flexible and extensible in order to accommodate new processing techniques. This report provides a thorough description and examples of the record processing features supported by PRISM. All the computing features of PRISM have been thoroughly tested.

Open-File Report

PRISM Software: Processing and Review Interface for Strong‐Motion Data

A continually increasing number of high‐quality digital strong‐motion records from stations of the National Strong Motion Project (NSMP) of the U.S. Geological Survey, as well as data from regional seismic networks within the United States, calls for automated processing of strong‐motion records with human review limited to selected significant or flagged records. The NSMP has developed the Processing and Review Interface for Strong Motion data (PRISM) software to meet this need. In combination with the Advanced National Seismic System Quake Monitoring System (AQMS), PRISM automates the processing of strong‐motion records. When used without AQMS, PRISM provides batch‐processing capabilities. The PRISM software is platform independent (coded in Java), open source, and does not depend on any closed‐source or proprietary software. The software consists of two major components: a record processing engine composed of modules for each processing step, and a review tool, which is a graphical user interface for manual review, edit, and processing. To facilitate use by non‐NSMP earthquake engineers and scientists, PRISM (both its processing engine and review tool) is easy to install and run as a stand‐alone system on common operating systems such as Linux, OS X, and Windows. PRISM was designed to be flexible and extensible to accommodate implementation of new processing techniques. All the computing features have been thoroughly tested.

Seismological Research Letters

Hydrographic surveys of four narrows within the Namakan reservoir system, Voyageurs National Park, Minnesota, 2011

The U.S. Geological Survey performed multibeam echosounder hydrographic surveys of four narrows in the Namakan reservoir system in August 2011, in cooperation with the International Joint Commission and Environment Canada. The data-collection effort was completed to provide updated and detailed hydrographic data to Environment Canada for inclusion in a Hydrologic Engineering Centers River Analysis System hydraulic model. The Namakan reservoir system is composed of Namakan, Kabetogama, Sand Point, Crane, and Little Vermilion Lakes. Water elevations in the Namakan reservoir system are regulated according to rule curves, or guidelines for water-level management based on the time of year, established by the International Joint Commission. Water levels are monitored by established gages on Crane Lake and the outlet of Namakan Lake at Kettle Falls, but water elevations throughout the system may deviate from these measured values by as much as 0.3 meters, according to lake managers and residents. Deviations from expected water elevations may be caused by between-lake constrictions (narrows). According to the 2000 Rule Curve Assessment Workgroup, hydrologic models of the reservoir system are needed to better understand the system and to evaluate the recent changes made to rule curves in 2000. Hydrographic surveys were performed using a RESON SeaBat™7125 multibeam echosounder system. Surveys were completed at Namakan Narrows, Harrison Narrows, King Williams Narrows, and Little Vermilion Narrows. Hydrographic survey data were processed using Caris HIPS TM and SIPS TM software that interpolated a combined uncertainty and bathymetric estimator (CUBE) surface. Quality of the survey results was evaluated in relation to standards set by the International Hydrographic Organization (IHO) for describing the uncertainty of hydrographic surveys. More than 90 percent of the surveyed areas at the four narrows have resulting bed elevations that meet the IHO “Special Order” quality. Survey datasets published in this report are formatted as text files of x-y-z coordinates and as CARIS Spatial Archive TM (CSAR TM ) files with corresponding metadata.

Minnesota

Computing ordinary least-squares parameter estimates for the National Descriptive Model of Mercury in Fish

A specialized technique is used to compute weighted ordinary least-squares (OLS) estimates of the parameters of the National Descriptive Model of Mercury in Fish (NDMMF) in less time using less computer memory than general methods. The characteristics of the NDMMF allow the two products X'X and X'y in the normal equations to be filled out in a second or two of computer time during a single pass through the N data observations. As a result, the matrix X does not have to be stored in computer memory and the computationally expensive matrix multiplications generally required to produce X'X and X'y do not have to be carried out. The normal equations may then be solved to determine the best-fit parameters in the OLS sense. The computational solution based on this specialized technique requires O(8 p 2 +16 p ) bytes of computer memory for p parameters on a machine with 8-byte double-precision numbers. This publication includes a reference implementation of this technique and a Gaussian-elimination solver in preliminary custom software.

Techniques and Methods

Application of automated image analysis to coal petrography

The coal petrologist seeks to determine the petrographic characteristics of organic and inorganic coal constituents and their lateral and vertical variations within a single coal bed or different coal beds of a particular coal field. Definitive descriptions of coal characteristics and coal facies provide the basis for interpretation of depositional environments, diagenetic changes, and burial history and determination of the degree of coalification or metamorphism. Numerous coal core or columnar samples must be studied in detail in order to adequately describe and define coal microlithotypes, lithotypes, and lithologic facies and their variations. The large amount of petrographic information required can be obtained rapidly and quantitatively by use of an automated image-analysis system (AIAS). An AIAS can be used to generate quantitative megascopic and microscopic modal analyses for the lithologic units of an entire columnar section of a coal bed. In our scheme for megascopic analysis, distinctive bands 2 mm or more thick are first demarcated by visual inspection. These bands consist of either nearly pure microlithotypes or lithotypes such as vitrite/vitrain or fusite/fusain, or assemblages of microlithotypes. Megascopic analysis with the aid of the AIAS is next performed to determine volume percentages of vitrite, inertite, minerals, and microlithotype mixtures in bands 0.5 to 2 mm thick. The microlithotype mixtures are analyzed microscopically by use of the AIAS to determine their modal composition in terms of maceral and optically observable mineral components. Megascopic and microscopic data are combined to describe the coal unit quantitatively in terms of (V) for vitrite, (E) for liptite, (I) for inertite or fusite, (M) for mineral components other than iron sulfide, (S) for iron sulfide, and (VEIM) for the composition of the mixed phases (X i ) i = 1,2, etc. in terms of the maceral groups vitrinite V, exinite E, inertinite I, and optically observable mineral content M. The volume percentage of each component present is indicated by a subscript. For example, a lithologic unit was determined megascopically to have the composition (V) 13 (I) 1 (S) 1 (X 1 ) 83 (X 2 ) 2 . After microscopic analysis of the mixed phases, this composition was expressed as (V) 13 (I) 1 (S) 1 (V 63 E 19 I 14 M 4 ) 83 (V 67 E 11 I 13 M 9 ) 2 . Finally, these data were combined in a description of the bulk composition as V 67 E 16 I 13 M 3 S 1 . An AIAS can also analyze textural characteristics and can be used for quick and reliable determination of rank (reflectance). Our AIAS is completely software based and incorporates a television (TV) camera that has optimum response characteristics in the range of reflectance less than 5%, making it particularly suitable for coal studies. Analysis of the digitized signal from the TV camera is controlled by a microprocessor having a resolution of 64 gray levels between full illumination and dark current. The processed image is reconverted for display on a TV monitor screen, on which selection of phases or features to be analyzed is readily controlled and edited by the operator through use of a lightpen. We expect that automated image analysis, because it can rapidly provide a large amount of pertinent information, will play a major role in the advancement of coal petrography.

International Journal of Coal Geology

Advanced Spaceborne Thermal Emission and Reflection Radiometer Level 1 Precision Terrain Corrected Registered At-Sensor Radiance (AST_L1T) Product, algorithm theoretical basis document

This document provides an overview of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) supplemental algorithms in conjunction with the reuse of Landsat geometric algorithms modified by the National Aeronautics and Space Administration (NASA Land Processes Distributed Active Archive Center (LP DAAC) to create an ASTER Level 1 Precision Terrain Corrected Registered At-Sensor Radiance (AST_L1T) product. Implementation of these algorithms occurs within the AST_L1T product generation executable (PGE) as part of the open source Simple, Scalable, Script-based Science Processor for Missions (S4PM) processing software subsystem. The AST_L1T algorithms include the following: Generation of the AST_L1A input product via supplemental algorithms Application of the radiometric and geometric corrections appended in the AST_L1A product Application of cross-talk correction coefficients Generation and application of affine transformation coefficients Modification and reuse of Landsat&rsquo;s geometric algorithms including: Systematic&mdash;generates the systematic grid Resampling&mdash;multi-use; only a single resample of input scene Gpyramid&mdash;scale input image to reference image (if necessary) Ground Control Point (GCP) Correlate&mdash;computes x,y offsets for GCPs to be used for precision grid generation Precision Refine&mdash;generates the precision grid GVERIFY&mdash;geometric verification

Open-File Report

The global lambda visualization facility: An international ultra-high-definition wide-area visualization collaboratory

The research outlined in this paper marks an initial global cooperative effort between visualization and collaboration researchers to build a persistent virtual visualization facility linked by ultra-high-speed optical networks. The goal is to enable the comprehensive and synergistic research and development of the necessary hardware, software and interaction techniques to realize the next generation of end-user tools for scientists to collaborate on the global Lambda Grid. This paper outlines some of the visualization research projects that were demonstrated at the iGrid 2005 workshop in San Diego, California.

Future Generation Computer Systems

Deposition, erosion, and bathymetric change in South San Francisco Bay: 1858-1983

Since the California Gold Rush of 1849, sediment deposition, erosion, and the bathymetry of South San Francisco Bay have been altered by both natural processes and human activities. Historical hydrographic surveys can be used to assess how this system has evolved over the past 150 years. The National Ocean Service (NOS) (formerly the United States Coast and Geodetic Survey (USCGS), collected five hydrographic surveys of South San Francisco Bay from 1858 to 1983. Analysis of these surveys enables us to reconstruct the surface of the bay floor for each time period and quantify spatial and temporal changes in deposition, erosion, and bathymetry. The creation of accurate bathymetric models involves many steps. Sounding data was obtained from the original USCGS and NOS hydrographic sheets and were supplemented with hand drawn depth contours. Shorelines and marsh areas were obtained from topographic sheets. The digitized soundings and shorelines were entered into a Geographic Information System (GIS), and georeferenced to a common horizontal datum. Using surface modeling software, bathymetric grids with a horizontal resolution of 50 m were developed for each of the five hydrographic surveys. Prior to conducting analyses of sediment deposition and erosion, we converted all of the grids to a common vertical datum and made adjustments to correct for land subsidence that occurred from 1934 to 1967. Deposition and erosion that occurred during consecutive periods was then computed by differencing the corrected grids. From these maps of deposition and erosion, we calculated volumes and rates of net sediment change in the bay. South San Francisco Bay has lost approximately 90 x 106 m3 of sediment from 1858 to 1983; however within this timeframe there have been periods of both deposition and erosion. During the most recent period, from 1956 to 1983, sediment loss approached 3 x 106 m3/yr. One of the most striking changes that occurred from 1858 to 1983 was the conversion of more than 80% of the tidal marsh to salt ponds, agricultural, and urban areas. In addition, there has been a decline of approximately 40% in intertidal mud flat area. Restoration of these features will require a detailed understanding of the morphology and sediment sources of this complex system.

California

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper

Spectral reflectance properties (0.4-2.5 um) of secondary Fe-oxide, Fe-hydroxide, and Fe-sulfate-hydrate minerals associated with sulfide-bearing mine waste

Fifteen Fe-oxide, Fe-hydroxide, and Fe-sulphate-hydrate mineral species commonly associated with sulphide bearing mine wastes were characterized by using X-ray powder diffraction and scanning electron microscope methods. Diffuse reflectance spectra of the samples show diagnostic absorption features related to electronic processes involving ferric and/or ferrous iron, and to vibrational processes involving water and hydroxyl ions. Such spectral features enable field and remote sensing based studies of the mineral distributions. Because secondary minerals are sensitive indicators of pH, Eh, relative humidity, and other environmental conditions, spectral mapping of these minerals promises to have important applications to mine waste remediation studies. This report releases digital (ascii) spectra (spectral_data_files.zip) of the fifteen mineral samples to facilitate usage of the data with spectral libraries and spectral analysis software. The spectral data are provided in a two-column format listing wavelength (in micrometers) and reflectance, respectively.

Open-File Report

USGS Digital Spectral Library splib06a

Introduction We have assembled a digital reflectance spectral library that covers the wavelength range from the ultraviolet to far infrared along with sample documentation. The library includes samples of minerals, rocks, soils, physically constructed as well as mathematically computed mixtures, plants, vegetation communities, microorganisms, and man-made materials. The samples and spectra collected were assembled for the purpose of using spectral features for the remote detection of these and similar materials. Analysis of spectroscopic data from laboratory, aircraft, and spacecraft instrumentation requires a knowledge base. The spectral library discussed here forms a knowledge base for the spectroscopy of minerals and related materials of importance to a variety of research programs being conducted at the U.S. Geological Survey. Much of this library grew out of the need for spectra to support imaging spectroscopy studies of the Earth and planets. Imaging spectrometers, such as the National Aeronautics and Space Administration (NASA) Airborne Visible/Infra Red Imaging Spectrometer (AVIRIS) or the NASA Cassini Visual and Infrared Mapping Spectrometer (VIMS) which is currently orbiting Saturn, have narrow bandwidths in many contiguous spectral channels that permit accurate definition of absorption features in spectra from a variety of materials. Identification of materials from such data requires a comprehensive spectral library of minerals, vegetation, man-made materials, and other subjects in the scene. Our research involves the use of the spectral library to identify the components in a spectrum of an unknown. Therefore, the quality of the library must be very good. However, the quality required in a spectral library to successfully perform an investigation depends on the scientific questions to be answered and the type of algorithms to be used. For example, to map a mineral using imaging spectroscopy and the mapping algorithm of Clark and others (1990a, 2003b), one simply needs a diagnostic absorption band. The mapping system uses continuum-removed reference spectral features fitted to features in observed spectra. Spectral features for such algorithms can be obtained from a spectrum of a sample containing large amounts of contaminants, including those that add other spectral features, as long as the shape of the diagnostic feature of interest is not modified. If, however, the data are needed for radiative transfer models to derive mineral abundances from reflectance spectra, then completely uncontaminated spectra are required. This library contains spectra that span a range of quality, with purity indicators to flag spectra for (or against) particular uses. Acquiring spectral measurements and performing sample characterizations for this library has taken about 15 person-years of effort. Software to manage the library and provide scientific analysis capability is provided (Clark, 1980, 1993). A personal computer (PC) reader for the library is also available (Livo and others, 1993). The program reads specpr binary files (Clark, 1980, 1993) and plots spectra. Another program that reads the specpr format is written in IDL (Kokaly, 2005). In our view, an ideal spectral library consists of samples covering a very wide range of materials, has large wavelength range with very high precision, and has enough sample analyses and documentation to establish the quality of the spectra. Time and available resources limit what can be achieved. Ideally, for each mineral, the sample analysis would include X-ray diffraction (XRD), electron microprobe (EM) or X-ray fluorescence (XRF), and petrographic microscopic analyses. For some minerals, such as iron oxides, additional analyses such as Mossbauer would be helpful. We have found that to make the basic spectral measurements, provide XRD, EM or XRF analyses, and microscopic analyses, document the results, and complete an entry of one spectral library sample, all takes about

Data Series