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Ring distributions in alkali- and alkaline-earth aluminosilicate framework glasses- A raman spectroscopic study

Raman spectra of crystalline polymorphs of a number of tectosilicate minerals having various sizes of smallest rings of TO 4 tetrahedra (T = Si, Al) have been investigated to identify the bands that are sensitive indicators of the smallest rings in the network. The information obtained from the Raman spectra of tectosilicate minerals (e.g., SiO 2 polymorphs, NaAlSi 3 O 8 (Ab), NaAlSiO 4 (Ne), KAlSi 3 O 8 (Or), and KAlSi 2 O 6 (Lc)) is used to interpret the Raman spectra of the isochemical glasses. It is shown that the frequency of the dominant ν s (TOT) band in the spectra of both crystals and glasses is related to the dominant size of TO 4 rings in the structure. In agreement with previous X-ray RDF work, it is found that in the glasses of Ab and Jd (NaAlSi 2 O 6 ) compositions, six-membered rings of TO 4 tetrahedra predominate. The Raman spectrum of Or glass, however, indicates that clusters of intermixed four- and six-membered rings of TO 4 tetrahedra, similar to those existing in crystalline leucite, are also present in the glass. Raman evidence indicates that four-membered rings of TO 4 tetrahedra predominate in the glass of An composition. Similarly, the higher frequency of the ν s (TOT) band in the spectrum of Ne glass as compared with the frequency the ν s (TOT) band in the spectra of crystalline cargenieite and nephelite indicates either an admixture of the four- and six-membered rings or the puckering of six-membered rings in the glass structure.

Journal of Non-Crystalline Solids↗

The compositions of the lunar crust and upper mantle: Spectral analysis of the inner rings of lunar impact basins

The innermost ring in impact basins exposes material originating from various depths, and can be used to study the composition of the lunar crust with depth. In this study, we conduct quantitative mineralogical analyses of the innermost ring in 13 lunar impact basins using reflectance data from the Kaguya Multiband Imager and radiative transfer modeling. We use results from recent hydrocode modeling to calculate the depth of origin of the material exposed by the innermost rings. We find that the most abundant rock type on the innermost ring of most basins is anorthosite. The mafic assemblages are dominated by olivine in some cases, but most often by pyroxene. The impact modeling suggests that the innermost ring material was excavated from a wide range of depths. Here we focus on two mean depths: a crustal component and a mantle component. The crustal component largely dominates the innermost ring material, and the mantle component is present on the innermost ring of 9 of the basins we studied. On these 9 rings, the abundance of low-calcium pyroxene decreases with the proportion of crustal component, suggesting a dominantly mantle origin. However, as we do not detect exposures of ultramafic material, such mantle material is possibly present at the sub-pixel scale (<62 m). This quantitative study reassesses the composition of the lunar crust and upper mantle, which is of great importance for understanding the formation of the Moon.

Planetary and Space Science↗

Larch tree rings as a tool for reconstructing 20th century central European atmospheric mercury trends

We propose the tree rings of European Larch ( Larix decidua ) as a widely available and reliable geochemical archive of local and regional changes in atmospheric mercury (Hg). Mean Hg concentrations in larch tree rings from 8 background sites across the Czech Republic ranged from 2.2 to 4.8 μg kg –1 ; the maximum concentrations occurred in the period 1951–1970. At 3 sites impacted by Hg-emission sources [gold amalgamation processing, caustic soda production, and lead (Pb) ore smelting] mean larch tree ring Hg concentrations were significantly elevated relative to background sites. Changes in larch tree ring Hg concentrations were temporally coherent with known activities at the sites that would alter Hg emissions; the nearly simultaneous response in tree rings indicated little or no translocation of Hg within the larch bole. Based on the present-day atmospheric Hg concentration of 1.63 ng m –3 at the intensively monitored Czech Global Mercury Observation System site and the most recent mean tree ring Hg concentration of 2.8 μg kg –1 in co-located larch trees, we developed a simple distribution model of Hg between the atmosphere and larch tree rings. We applied the model using observed changes of Hg in larch tree rings from the countrywide background sites to reconstruct past atmospheric Hg concentrations in central Europe. Modeled Hg concentrations were in agreement with annual means from the European Monitoring and Evaluation Programme observatories.

Environmental Science & Technology↗

Flexible models for analysing ring recovery data to estimate survival rates

We describe MULT, a flexible procedure for analysing ring recovery data. The procedure starts with parametric structures similar to, but more general than, those described by Brownie et al. (1985). Particular models, including those in Brownie et al. (1965), can be obtained by imposing constraints on the general parametric structures. Examples of models that are available in MULT include: analysis of ringing data when no birds are ringed in some years; analysis of twice-yearly ringing to estimate interval survivorship; and analysis of ringing data when survivorship is hypothesised to be a function of a covariate measured annually. We use North American ringings of Atlantic Brant (Branta bernicla hrota), Mallard (Anas platyrhynchos), and Ring-necked Ducks (Aythya collaris) to illustrate the above models. MULT is a menu-driven, IBM-PC compatible program, and is available from the second author.

Ring↗

Coastal Tree-Ring Records for Paleoclimate and Paleoenvironmental Applications in North America

For more than a century, tree-ring research has identified relationships between climatic and ecological conditions and tree growth to describe past environments and constrain future ecosystem vulnerabilities. Tree-ring records are frequently used as environmental proxies that extend knowledge of past climate and ecology on millennial scales. Many of the most pressing global change questions facing North America concern the rate of climate change and vulnerability of ecosystems and society along the coast. The opportunities and applications in dendrochronology continue to grow with advancing methodologies, faster computational ability, and the cost-reduction of many chemical and anatomical analyses. Here, we propose that many pressing global change questions that affect coastal communities can be addressed using dendrochronological techniques. We review coastal tree-ring studies that demonstrate the utility and potential for future tree-ring studies in the northeastern, southeastern, northwestern, and southwestern North American coasts. Additionally, we show that tree-ring chronologies along the coast give insight into local and regional climate phenomena that are distinct from nearby, inland tree-ring chronologies of the same species. Lastly, we identify opportunities for coastal dendrochronology and encourage the collection of more tree-ring records that are directly impacted by coastal phenomena.

Quaternary Science Reviews↗

Short- and long-term responses of riparian cottonwoods (Populus spp.) to flow diversion: Analysis of tree-ring radial growth and stable carbon isotopes

Long duration tree-ring records with annual precision allow for the reconstruction of past growing conditions. Investigations limited to the most common tree-ring proxy of ring width can be difficult to interpret, however, because radial growth is affected by multiple environmental processes. Furthermore, studies of living trees may miss important effects of drought on tree survival and forest changes. Stable carbon isotopes can help distinguish drought from other environmental factors that influence tree-ring width and forest stand condition. We quantified tree-ring radial expansion and stable carbon isotope ratios (δ 13 C) in riparian cottonwoods ( Populus angustifolia and P. angustifolia x P. trichocarpa) along Snake Creek in Nevada, USA. We investigated how hydrological drought affected tree growth and death at annual to half-century scales in a partially dewatered reach (DW) compared to reference reaches immediately upstream and downstream. A gradual decline in tree-ring basal area increment (BAI) began at DW concurrent to streamflow diversion in 1961. BAI at DW diverged from one reference reach immediately but not from the other until nearly 50 years later. In contrast, tree-ring δ 13 C had a rapid and sustained increase following diversion at DW only, providing the stronger and clearer drought signal. BAI and δ 13 C were not significantly correlated prior to diversion; after diversion they both reflected drought and were correlated for DW trees only. Cluster analyses distinguished all trees in DW from those in reference reaches based on δ 13 C, but BAI patterns left trees intermixed across reaches. Branch and tree mortality were also highest and canopy vigor was lowest in DW. Results indicate that water scarcity strongly limited cottonwood photosynthesis following flow diversion, thus reducing carbon assimilation, basal growth and survival. The dieback was not sudden, but occurred over decades as carbon deficits mounted and depleted streamflow left trees increasingly vulnerable to local meteorological drought.

Nevada↗

Relation of nickel concentrations in tree rings to groundwater contamination

Increment cores were collected from trees growing at two sites where groundwater is contaminated by nickel. Proton-induced X ray emission spectroscopy was used to determine the nickel concentrations in selected individual rings and in parts of individual rings. Ring nickel concentrations were interpreted on the basis of recent concentrations of nickel in aquifers, historical information about site use activities, and model simulations of groundwater flow. Nickel concentrations in rings increased during years of site use but not in trees outside the contaminated aquifers. Consequently, it was concluded that trees may preserve in their rings an annual record of nickel contamination in groundwater. Tulip trees and oaks contained higher concentrations of nickel than did sassafras, sweet gum, or black cherry. No evidence was found that nickel accumulates consistently within parts of individual rings or that nickel is translocated across ring boundaries.

Water Resources Research↗

Digital image measurement of the area and anatomical structure of tree rings

A microcomputer coupled to a video digitizer was used to develop methods for measuring areas of tree rings and for delineating and measuring microscopic anatomical features. Digitally imaged areas of individual rings of a loblolly pine cross section were within 2.6% of areas measured with a planimeter and were more accurate than areas calculated from radius widths. Various anatomical features were "mapped" within digitized images of consecutive rings, individual rings, and highly magnified parts of the rings of green ash. Fibers within various ring zones, including those known to have formed when trees were flooded, were readily differentiated on the basis of image brightness. The image-determined ratio of lumen to wall material within different groups of fibers was considered a measure of structural comparability. These techniques thus provide a rapid, accurate method to study relationships between tree rings and factors affecting their development. Methods could be improved by increasing both spatial and brightness resolution.

Canadian Journal of Botany↗

Fidelity and persistence of Ring-billed ( Larus delawarensis ) and Herring ( Larus argentatus ) gulls to wintering sites

While the breeding ecology of gulls (Laridae) has been well studied, their movements and spatial organization during the non-breeding season is poorly understood. The seasonal movements, winter-site fidelity, and site persistence of Ring-billed ( Larus delawarensis ) and Herring ( L. argentatus ) gulls to wintering areas were studied from 2008–2012. Satellite transmitters were deployed on Ring-billed Gulls ( n = 21) and Herring Gulls ( n = 14). Ten Ring-billed and six Herring gulls were tracked over multiple winters and > 300 wing-tagged Ring-billed Gulls were followed to determine winter-site fidelity and persistence. Home range overlap for individuals between years ranged between 0–1.0 (95% minimum convex polygon) and 0.31–0.79 (kernel utilization distributions). Ringbilled and Herring gulls remained at local wintering sites during the non-breeding season from 20–167 days and 74–161 days, respectively. The probability of a tagged Ring-billed Gull returning to the same site in subsequent winters was high; conversely, there was a low probability of a Ring-billed Gull returning to a different site. Ring-billed and Herring gulls exhibited high winter-site fidelity, but exhibited variable site persistence during the winter season, leading to a high probability of encountering the same individuals in subsequent winters.

Waterbirds↗

Some geometric constraints on ring-width trend

Simulations of tree rings from trees of undisturbed forest sites are used to describe natural, long-term width trends. Ring-width trends of canopy-sized white oak are simulated from regressions of BAI (ring area) data of real trees. Examples are given of a tree from a typical re-growth forest in Illinois and of a more slowly growing tree from an old-growth forest in Kentucky. The long-term width trend was simulated as being toward constant ring width regardless of growth rate of the tree. Conditions by which either increasing or decreasing ring-width trends could be simulated from the same linear BAI trend are examined. I conclude that curvilinear width trends, either increasing or decreasing, represent width adjustments to changes in growth rate ( BAI trend) after which the width trend stabilizes to a near-constant value. Interpretation of ring-width trends of trees from undisturbed stands may be useful in assessing stand disturbance history.

Tree-Ring Research↗

Hydrologic inferences from ring widths of flood-damaged trees, Potomac River, Maryland

Year-to-year variability in the ring widths of trees on flood plains along two reaches of the Potomac River near Washington, D.C., seems in large part to be related to differences in flood-flow regimes. Trees directly exposed to high flood velocities are damaged more often than sheltered trees and thus exhibit more variable ring-width patterns. The ring-width variability of unsheltered trees on low levels of flood plains is greater than that of trees on high levels, indicating that variability values are positively correlated with flood frequency. Sheltered trees, however, have less variable ring-width patterns than those of unsheltered trees, and variability is not correlated with flood frequency. As a result, ring-width variations may be used to estimate the probability of flood damage along local channel reaches of a stream. Growth responses after hydrologic catastrophies in 1948 and 1972 indicate that rings of flood-plain trees can be used to document the occurrence and crest altitude of high-magnitude floods. ?? 1982 Springer-Verlag New York Inc.

Environmental Geology↗

Tree-ring dated landslide movements and their relationship to seismic events in southwestern Montana, USA

To determine periods of incremental landslide movement and their possible relationship to regional seismic events, the tree-ring records of 32 titled and damaged conifers at three sites on landslides in the Gravelly Range of southwestern Montana were examined. Several signs of disturbance in the tree-ring record indicating landslide movement were observed. Commonly, the tree-ring record displayed a marked reduction in annual ring width and/or the reaction wood formation. The tree-ring records from the three landslide sites indicate multiple periods of movement during the 20th century. Many of the periods of movement indicated by the strongest signals (most trees) at the sites occurred the year following significant earthquakes in the region. Those seismic events for which evidence in the tree-ring record was found at one or more of the three sites are the 1983 Borah Peak, 1959 Hebgen Lake, 1935 Helena, 1925 Clarkson, and 1908 Virginia City earthquakes. This study suggests that many of the landslide movements were triggered by, or are coincident with, earthquakes as much as 200 km from the study area.

Montana↗

Self-gravity wake structures in Saturn's a ring revealed by Cassini vims

During the summer of 2005, the Visual and Infrared Mapping Spectrometer onboard the Cassini spacecraft observed a series of occultations of the star o Ceti (Mira) by Saturn's rings. These observations revealed pronounced variations in the optical depth of the A ring with longitude, which can be attributed to oriented structures in the rings known as self-gravity wakes. While the wakes themselves are only tens of meters across and below the resolution of the measurements, we are able to obtain information about the orientation and shapes of these structures by comparing the observed transmission at different longitudes with predictions from a simple model. Our findings include the following: (1) The orientation of the wakes varies systematically with radius, trailing by between 64?? and 72?? relative to the local radial direction. (2) The maximum transmission peaks at roughly 8% for B = 3.45?? in the middle A ring (???129,000 km). (3) Both the wake orientation and maximum transmission vary anomalously in the vicinity of two strong density waves (Janus 5:4 and Mimas 5:3). (4) The ratio of the wake vertical thickness H to the wake pattern wavelength ?? (assuming infinite, straight, regularly-spaced wake structures) varies from 0.12 to 0.09 across the A ring. Gravitational instability theory predicts ?? ??? 60 m, which suggests that the wake structures in the A ring are only ???6 m thick. ?? 2007. The American Astronomical Society. All rights reserved.

Astronomical Journal↗

A reference genome assembly for the continentally distributed ring-necked snake, Diadophis punctatus

Snakes in the family Colubridae include more than 2,000 currently recognized species, and comprise roughly 75% of the global snake species diversity on Earth. For such a spectacular radiation, colubrid snakes remain poorly understood ecologically and genetically. Two subfamilies, Colubrinae (788 species) and Dipsadinae (833 species), comprise the bulk of colubrid species richness. Dipsadines are a speciose and diverse group of snakes that largely inhabit Central and South America, with a handful of small-body-size genera that have invaded North America. Among them, the ring-necked snake, Diadophis punctatus , has an incredibly broad distribution with 14 subspecies. Given its continental distribution and high degree of variation in coloration, diet, feeding ecology, and behavior, the ring-necked snake is an excellent species for the study of genetic diversity and trait evolution. Within California, six subspecies form a continuously distributed “ring species” around the Central Valley, while a seventh, the regal ring-necked snake, Diadophis punctatus regalis is a disjunct outlier and Species of Special Concern in the state. Here, we report a new reference genome assembly for the San Diego ring-necked snake, D. p. similis , as part of the California Conservation Genomics Project. This assembly comprises a total of 444 scaffolds spanning 1,783 Mb and has a contig N50 of 8.0 Mb, scaffold N50 of 83 Mb, and BUSCO completeness score of 94.5%. This reference genome will be a valuable resource for studies of the taxonomy, conservation, and evolution of the ring-necked snake across its broad, continental distribution.

Journal of Heredity↗

No ring fracture in Mono Basin, California

In Mono Basin, California, USA, a near-circular ring fracture 12 km in diameter was proposed by R.W. Kistler in 1966 to have originated as the protoclastic margin of the Cretaceous Aeolian Buttes pluton, to have been reactivated in the middle Pleistocene, and to have influenced the arcuate trend of the chain of 30 young (62−0.7 ka) rhyolite domes called the Mono Craters. In view of the frequency and recency of explosive eruptions along the Mono chain, and because many geophysicists accepted the ring fracture model, we assembled evidence to test its plausibility. The shear zone interpreted as the margin of the Aeolian Buttes pluton by Kistler is 50−400 m wide but is exposed only along a 7-km-long set of four southwesterly outcrops that subtend only a 70° sector of the proposed ring. The southeast end of the exposed shear zone is largely within the older June Lake pluton, and at its northwest end, the contact of the Aeolian Buttes pluton with a much older one crosses the shear zone obliquely. Conflicting attitudes of shear structures are hard to reconcile with intrusive protoclasis. Also inconsistent with the margin of the ovoid intrusion proposed by Kistler, unsheared salients of the pluton extend ∼1 km north of its postulated circular outline at Williams Butte, where there is no fault or other structure to define the northern half of the hypothetical ring. The shear zone may represent regional Cretaceous transpression rather than the margin of a single intrusion. There is no evidence for the Aeolian Buttes pluton along the aqueduct tunnel beneath the Mono chain, nor is there evidence for a fault that could have influenced its vent pattern. The apparently arcuate chain actually consists of three linear segments that reflect Quaternary tectonic influence and not Cretaceous inheritance. A rhyolitic magma reservoir under the central segment of the Mono chain has erupted many times in the late Holocene and as recently as 700 years ago. The ring fracture idea, however, prompted several geophysical investigations that sought a much broader magma body, but none identified a low-density or low-velocity anomaly beneath the purported 12-km-wide ring, which we conclude does not exist.

California↗

Validation of daily ring deposition in the otoliths of age-0 channel catfish

We developed and validated methods for estimating the daily age of age-0 channel catfish Ictalurus punctatus. Two clutches of channel catfish eggs were hatched in the laboratory; subsequently, one was stocked in a 186-m2 earthen nursery pond and the other in a 757-L outdoor circular tank. Before stocking, subsamples of fish were collected at swim-up and 3 d after swim-up to evaluate early ring formation. Fish were sampled from the pond and tank on eight occasions ranging from 30 to 119 d posthatch. Distinct differences in early ring formation were found between yolk sac and free-swimming larval stages. Mean ring count and known age were closely related for tank- and pond-raised fish, indicating that daily ring deposition occurred in the otoliths of age-0 channel catfish up to 119 d posthatch. The accuracy of daily age estimation was similar between tank and pond samples, and daily ring counts were considerably accurate up to 60 d posthatch. Pond-raised fish were more difficult to age than tank-raised fish, which we attributed to ring compression resulting from slower growth among pond-raised fish after 30 d. The total length of tank- and pond-raised fish was positively related to otolith size; however, the slopes of the relationships between fish length and otolith radius were different between treatments. Therefore, we could not confirm that the relationship between fish length and otolith size was directly proportional for age-0 channel catfish. We encourage researchers to use this aging technique to determine how abiotic and biotic factors influence early life history characteristics and ultimately the population dynamics of catfishes (Ictaluridae). ?? Copyright by the American Fisheries Society 2008.

North American Journal of Fisheries Management↗

Climatic significance of the bristlecone pine latewood frost-ring record at Almagre Mountain, Colorado, U.S.A.

From 1900 to 1993, latewood frost rings occurred in 1903, 1912, 1941, 1961, and 1965 in 10 to 21% of the sampled bristlecone pines at Almagre Mountain, Colorado. In early to mid September in each of those years, a severe outbreak of unseasonably cold air from higher latitudes produced a memorable or historic late-summer snowstorm in the western United States. Record subfreezing temperatures during these snowstorms probably caused the latewood frost rings, shortened (by about 1 mo in 1912) already colder than normal growing seasons, and caused crop damage in parts of the Western United States. Latewood frost rings recorded in relatively high percentages of the sampled trees (such as the 1805 event in 61% of sampled trees) were probably caused by multiple severe outbreaks of unseasonably cold air from higher latitudes that occurred from early September (possibly as early as mid- or late August) to mid-September. Analyses of 1900-1992 temperature data for two widely separated Colorado stations, Fort Collins and Colorado Springs, show that average summer (June-September) temperatures during latewood frost-ring years in this century were 1.5 and 2.0°C cooler than normal, respectively. Mountain snowpack probably persisted through these cool summers and was subsequently buried by the earlier than normal snowfall in September. Latewood frost-ring, ring-width, historical, and other data suggest that severe to cataclysmic volcanic eruptions from 1812 to 1835 triggered (1) an extended period of climatic cooling from as early as 1816 or 1817 through the early 1850s in the Southern Rocky Mountains, (2) catastrophic winters in Colorado and Wyoming in 1842-43 and 1844-45, and in the Great Salt Lake Basin in 1836-37, that caused large-scale destruction of bison and other large plains animals, and (3) Little Ice Age alpine glacial advances in about 1850-60 in the western United States.

Colorado↗

Cottonwoods, water, and people-Integrating analysis of tree rings with observations of elders from the Eastern Shoshone and Northern Arapaho Tribes of the Wind River Reservation, Wyoming

We assessed the history of flow and riparian ecosystem change along the Wind River using cottonwood tree-ring data, streamgage records, historical temperature and precipitation data, drought indices, and local observations and Traditional Ecological Knowledge from elders of the Eastern Shoshone and Northern Arapaho Tribes of the Wind River Reservation, Wyoming. This assessment identified impacts that have occurred to riparian resources of concern to the Tribes, which will assist in prioritizing drought planning efforts. Impacts included reduced abundance, reduced regeneration, and increased mortality in cottonwoods ( Populus deltoides and P. angustifolia ); an increase in invasive species, especially Russian olive ( Elaeagnus angustifolia ), that are gradually replacing cottonwoods and other native woody plants; decreased abundance of native and culturally important plants; reduced abundance of culturally important fish; reduced volume and changes to the timing of flows; and changes in river course. This assessment documented the biophysical and social factors that have contributed to riparian ecosystem change and to reduced water availability and flows, including agricultural diversion, drought, and fire. Cottonwoods along the Wind River are as much as 300 years old. By relating tree-ring width to recorded streamflows, we were able to reconstruct streamflows confidently back to the 1850s and speculatively back to the mid-1700s. Extending the historical record of streamflows allows for a more-complete understanding of hydroclimatic variability and provides a foundation for developing preparedness and response strategies for drought management. Ring width of cottonwood trees at the Boysen Site was more strongly correlated to river flow than to local precipitation or temperature, indicating that growth of trees is controlled more by montane snowmelt than by local weather. Therefore, tree rings are a better indicator of water supply than of the local conditions controlling water demand. The extended flow record from tree rings revealed the occurrence of a major period of low flow from 1870 to 1910 that was not evident in the shorter instrumental records of flow and weather. Information from tree rings, streamflow measurements, drought indices, and elder observations all suggest that the early 2000s drought was the most severe, sustained drought in the last century. Our results illustrate how drought is experienced in different ways across locations and sectors, which underscores the importance of using multiple indicators for drought management. These results will contribute to ongoing assessment, monitoring, and planning efforts at the Wind River Reservation.

Wyoming↗