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Hydrocarbons in sediment of the Weddell Sea, Antarctica

Heavy hydrocarbons (about C15+) are ubiquitous but minor components in sediment from three sites (692, 693, and 694) drilled during Ocean Drilling Program (ODP) Leg 113. This preliminary report is the first to describe the distribution of some of these hydrocarbons in sediment of the Weddell Sea. Samples from Sites 692 and 693, located on a mid-slope bench along the margin of Queen Maud Land, span a time interval from Early Cretaceous to Pleistocene. In samples from the Tertiary portion of the record, having an average organic-carbon content of about 0.2%, n-alkanes are common and are characterized by populations that indicate both marine and terrigenous sources. In contrast, samples from the Cretaceous portion of the record, having an average organic carbon content of about 4%, contain mixtures of hydrocarbons in which n-alkanes are secondary in abundance to the isoprenoid hydrocarbons, pristane and phytane. Diasterenes, sterenes, and hopenes are present in anomalously high concentrations and indicate immaturity. The Cretaceous hydrocarbons appear to be mainly primary, whereas the Tertiary hydrocarbons contain compounds which indicate that the sediment, along with its organic content, has been recycled. Samples from Site 694, located in the Weddell Sea on the abyssal plain, range in age from late Miocene to early Pliocene.

Proceedings of the Ocean Drilling Program: Scienti

Depositional history, nannofossil biostratigraphy, and correlation of Argo Abyssal Plain Sites 765 and 261

Sediments from the Argo Abyssal Plain (AAP), northwest of Australia, are the oldest known from the Indian Ocean and were recovered from ODP Site 765 and DSDP Site 261. New biostratigraphic and sedimentologic data from these sites, as well as reinterpretations of earlier findings, indicate that basal sediments at both localities are of Late Jurassic age and delineate a history of starved sedimentation punctuated by periodic influx of calcareous pelagic turbidites. Biostratigraphy and correlation of Upper Jurassic-Lower Cretaceous sediments is based largely on calcareous nannofossils. Both sites yielded variably preserved nannofossil successions ranging from Tithonian to Hauterivian at Site 765 and Kimmeridgian to Hauterivian at Site 261. The nannofloras are comparable to those present in the European and Atlantic Boreal and Tethyan areas, but display important differences that reflect biogeographic differentiation. The Argo region is thought to have occupied a position at the southern limit of the Tethyan nannofloral realm, thus yielding both Tethyan and Austral biogeographic features. Sedimentary successions at the two sites are grossly similar, and differences largely reflect Site 765 's greater proximity to the continental margin. Jurassic sediments were deposited at rates of about 2 m/m.y. near the carbonate compensation depth (CCD) and contain winnowed concentrations of inoceramid prisms and nannofossils, redeposited layers rich in calcispheres and calcisphere debris, manganese nodules, and volcanic detritus. Lower Cretaceous and all younger sediments accumulated below the CCD at rates that were highest (about 20 m/m.y.) during mid-Cretaceous and Neogene time. Background sediment in this interval is noncalcareous claystone; turbidites dominate the sequence and are thicker and coarser grained at Site 765. AAP turbidites consist mostly of calcareous and siliceous biogenic components and volcanogenic smectite clay; they were derived from relatively deep parts of the continental margin that lay below the photic zone, but above the CCD. The Jurassic-Lower Cretaceous section is about the same thickness across the AAP; turbidites in this interval appear to have had multiple sources along the Australian margin. The Upper Cretaceous-Cenozoic section, however, is three times thicker at Site 765 than at Site 261; turbidites in this interval were derived predominantly from the south. Patterns of sedimentation across the AAP have been influenced by shifts in sea level, the CCD, and configuration of the continental margin. Major pulses of calcareous turbidite deposition occurred during Valanginian, Aptian, and Neogene time—all periods of eustatic lowstands and depressed CCD levels. Sediment redeposited on the AAP has come largely from the Australian outer shelf, continental slope, or rise, rather than the continent itself. Most terrigenous detritus was trapped in epicontinental basins that have flanked northwestern Australia since the early Mesozoic.

Proceedings of the Ocean Drilling Program: Scienti

Late Paleocene and early Eocene calcareous nannofossils from three boreholes in an onshore-offshore transect from New Jersey to the Atlantic Continental Rise

Closely spaced, upper Paleocene and lower Eocene samples from three boreholes near Clayton, NJ, at Island Beach, NJ, and at Site 605 on the Atlantic Ocean continental rise were examined for their calcareous nannofossil content. This study documents calcareous nannofossil occurrences in Zones NP9 and NP10 and identifies biostratigraphically useful species, presents unexpected upbasin-downbasin distributional patterns of calcareous nannofossils, discusses the gradual evolutionary transition between two calcareous nannofossil species, and clarifies the relationship between the genera Rhomboaster and Tribrachiatus . One new species, Rhomboaster weii , is described, and two new combinations, Blackites herculesii and Rhomboaster digitalis , are established.

New Jersey

Upper Eocene sequence stratigraphy and the Absecon Inlet Formation, New Jersey Coastal Plain

We evaluate the age, benthic biofacies, and sequence stratigraphy of thick and well-recovered upper Eocene sediments from the New Jersey Coastal Plain. These strata are herein defined as a lithostratigraphic unit and named the Absecon Inlet Formation. The formation is divided into upper and lower portions. At its type locality in the Atlantic City borehole, the lower portion of the Absecon Inlet Formation consists of 171 ft (52 m) of glauconitic silts and silty clays and is assigned to calcareous nannoplankton Zone NP 19/20 (late Eocene). At the ACGS#4 borehole, the type locality for its upper portion, the formation consists of slightly sandy clays and is assigned to Zone NP 21 (late Eocene to earliest Oligocene). The continuous stratigraphic occurrence of Hantkenina spp. in these sediments is evidence of an Eocene age for the upper portion of the Absecon Inlet Formation. Benthic foraminiferal analysis reveals five biofacies in the Absecon Inlet Formation, three of which can be related to paleowater depth: a Siphonina biofacies inhabited water depths of 75 ± 25 m; a Cibicidoides biofacies inhabited water depths of 100 ± 30 m; and a Globobulimina biofacies inhabited water depths of 125 ± 30 m. In addition, a Gyroidinoides biofacies occurs only within transgressive systems tracts. A Bulimina jacksonensis biofacies is believed to be related to a circum-Atlantic paleoceanographic event unrelated to depth changes on the shelf. Gamma-log, lithologic, and faunal/floral data are used to interpret the sequence stratigraphic architecture of the Absecon Inlet Formation. We conclude that the timing of unconformities (sequence boundaries) and maximum flooding surfaces within the Absecon Inlet Formation is consistent with the eustatic record of Exxon and the global δ 18 O record.

New Jersey

Gas hydrates amount estimated from acoustic logs at the Blake Ridge, Sites 994, 995, and 997

The amount of in situ methane hydrates present in marine sediments is estimated at Ocean Drilling Program (ODP) Leg 164 drill sites on the Blake Ridge using acoustic logs. A weighted equation developed for relating the amount of hydrates concentrated in the pore space of unconsolidated sediments to the increase of acoustic velocities is applied to the acoustic logs using three sets of porosity distribution (porosity derived from bulk density logs, core porosity, and linear approximation of core porosity). Generally, the gas hydrate concentration increases with increasing depth toward the bottom-simulating reflector (BSR). The average gas hydrate concentration in the pore space varies between 12.1%, using porosity from the bulk density, and 3.8%, using core-derived porosity. The average hydrate concentrations in the pore space using core porosities are 3.9% (2.2 vol% of sediment), 5.7% (3.3 vol%) and 3.8% (2.2 vol%) at Sites 994, 995, and 997 respectively. These estimated concentrations are comparable to those calculated from chloride anomalies at these sites.

Proceedings of the Ocean Drilling Program: Scienti

Data report: Mid-Pliocene diatom assemblages at sites 1016, 1021, and 1022

Diatom assemblages from the middle part of the Pliocene (3.2-2.5 Ma) were investigated from Ocean Drilling Program Sites 1016, 1021, and 1022 in an effort to infer paleotemperature fluctuations off California. Diatoms are very sparse in virtually all of the samples that were examined from Sites 1016 and 1021. This is presumably because these sites were seaward (west) of the coastal zone of diatom productivity during the middle part of the Pliocene. Diatoms are relatively common in the vast majority of samples that were examined from Hole 1022A. Diatom assemblages are dominated by Chaetoceros spores (a coastal upwelling component), the cold-water (subarctic) taxa Neodenticula kamtschatica and its descendant Neodenticula koizumii, and Thalassionema nitzschioides, a temperate taxon that is typically found at the seaward edge of coastal upwelling zones. Paleotemperature interpretations, however, are not possible at this time because of the scarcity of comparative modern core-top data.

Proceedings of the Ocean Drilling Program: Scienti

Climate variability of the Holocene, Site 1098, Palmer Deep, Antarctica

Detailed study of four Holocene sediment intervals from Ocean Drilling Program Site 1098 (Palmer Deep, Antarctic Peninsula) reveals that in situ dissolution of calcareous foraminifers in the core repository has significantly altered and in some cases eliminated calcareous foraminifers. Despite dissolution, the foraminifer and supporting diatom data show that the most open-ocean and reduced sea-ice conditions occurred in the early Holocene. The influence of Circumpolar Deep Water was greatest during the early Holocene but continued to be important throughout the Holocene. An increase in sea-ice proximal diatoms at 3500 cal. BP documents an expansion in the amount of persistent sea ice. The inferred increase in sea ice corresponds with an overall increase in magnetic susceptibility values. Benthic foraminifers are present in all samples from the Palmer Deep, including the middle Holocene pervasively laminated sediments with low magnetic susceptibility values. The consistent presence of mobile epifaunal benthic foraminifers in the laminated sediments demonstrates that the laminations do not represent anoxic conditions. The uniform composition of the agglutinated foraminifer fauna throughout the late Holocene suggests that the Palmer Deep did not experience bottom-water-mass changes associated with the alternating deposition of bioturbated or laminated sediments.

Antarctica, Antarctic Peninsula, Palmer Deep

Magnetobiochronologic synthesis of ODP Leg 178 rise sediments from the Pacific sector of the Southern Ocean: Sites 1095, 1096, and 11011

During Ocean Drilling Program (ODP) Leg 178, eight holes were drilled at three sites (1095, 1096, and 1101) on the continental rise along the western Antarctic Peninsula. The rise sediments proved to be good paleomagnetic recorders and provided continuous magnetostratigraphic records at all three sites. Biosiliceous microfossils, particularly diatoms and radiolarians, were present in the upper Miocene through lower Pliocene sections. In the upper Pliocene to Pleistocene sections, biosiliceous microfossils were rare but calcareous nannofossils and foraminifers were present. This paper summarizes the biostratigraphy and magnetostratigraphy of Leg 178 continental rise sites and is the first attempt at direct calibration of Antarctic biostratigraphic events to the geomagnetic polarity timescale in the Pacific sector of the Southern Ocean.

Proceedings of the Ocean Drilling Program: Scienti

Seismic stratigraphic correlations between ODP sites 742 and 1166: Implications for depositional paleoenvironments in Prydz Bay, Antarctica

New high-resolution seismic reflection data recorded between Ocean Drilling Program Sites 1166 and 742 are interpreted to link acoustic features to lithologic units at the two drill sites. New findings include: (1) Site 1166 drilled a deeper (older) section than Site 742; (2) Paleogene units mostly do not extend between the two sites, except the deformed sand unit (Units III [1166] and VI [742]); (3) the preglacial to glacial unconformity sampled at Site 1166 lies ~50 m below Site 742; (4) the Paleogene flooding surface at Site 1166 lies on top of Unit III, not within, as previously reported; and (5) Pliocene diatomaceous horizons correlated between the sites based on downhole logging cannot be traced between the two sites in seismic data. For the study region, we infer a progression from a preglacial setting on a low-relief alluvial plain to glaciomarine and subglacial settings. Late Cretaceous alluvial plain and lagoonal environments evolved to a late Eocene broad fluvial channel system or outwash plain. Marine transgression infilled and buried the channel system with glacial deposits that were extensively eroded during the Oligocene to late Miocene. Late Neogene environments were mostly subglacial with episodes of reduced ice and biogenic deposition.

Proceedings of the Ocean Drilling Program: Scienti

Prydz channel fan and the history of extreme ice advances in Prydz Bay

During the late Neogene, the Lambert Glacier-Amery Ice Shelf drainage system flowed across Prydz Bay in an ice stream that reached the shelf edge and built a trough mouth fan on the upper continental slope. The adjacent banks saw mostly subglacial till deposition beneath slower-moving ice. The fan consists mostly of debris flow deposits derived from the melting out of subglacial debris at the grounding line at the continental shelf edge. Thick debris flow intervals are separated by thin mudstone horizons deposited when the ice had retreated from the shelf edge. Age control at Ocean Drilling Program Site 1167 indicates that the bulk of the trough mouth fan was deposited prior to ~780 ka with as few as three debris flow intervals deposited since then. This stratigraphy indicates that extreme advances of the Lambert Glacier-Amery Ice Shelf system ceased during the mid-Pleistocene. Possible causes for this change are progressive over-deepening of the inner shelf, a reduction in maximum ice volumes in the interior of the East Antarctic Ice Sheet caused by temperature change, and a change in the interaction of Milankovich cycles and the response time of the ice sheet.

Prydz Bay

Data report: Compressibility, permeability, and grain size of shallow sediments, sites 1194 and 1198

Uniaxial strain consolidation experiments were conducted to determine elastic and plastic properties and to estimate the permeability of sediments from 0 to 200 meters below seafloor at Ocean Drilling Program Sites 1194 and 1198. Plastic deformation is described by compression indices, which range from 0.19 to 0.37. Expansion indices, the elastic deformation measured during unload/reload cycles on samples, vary from 0.02 to 0.029. Consolidation experiments provide lower bounds on permeability between 5.4 x 10 –16 m 2 and 1.9 x 10 –18 m 2 , depending on the consolidation state of the sample.

Proceedings of the Ocean Drilling Program: Scienti

Leg 197 synthesis: Southward motion and geochemical variability of the Hawaiian hotspot

The bend in the Hawaiian-Emperor volcanic chain is an often-cited example of a change in plate motion with respect to a stationary hotspot. Growing evidence, however, suggests that the bend might instead record variable drift of the Hawaiian hotspot within a convecting mantle. Paleomagnetic and radiometric age data from samples recovered during Ocean Drilling Program (ODP) Leg 197 define an age-progressive paleolatitude history, indicating that the Emperor Seamounts volcanic trend was formed principally by rapid (4–5 cm/yr) southward motion of the Hawaiian hotspot during Late Cretaceous to early Tertiary time (81–47 Ma). Paleointensity data derived from Leg 197 suggest an inverse relationship between field strength and reversal frequency, consistent with an active lower mantle that controls the efficiency of the geodynamo. Petrochemical data and observations of volcanic products (lava flows and volcaniclastic sediments) from Detroit, Nintoku, and Koko Seamounts provide records of the evolution of these volcanic systems for comparison with recent activity in the Hawaiian Islands. We find that the Emperor Seamounts formed from similar mantle sources for melting (plume components and lithosphere) and in much the same stages of volcanic activity and time span as the Hawaiian volcanoes. Changes in major and trace element and Sr isotopic compositions of shield lavas along the lineament can be related to variations in thickness of the lithosphere overlying the hotspot that control the depth and extent of partial melting. Other geochemical tracers, such as He, Pb, and Hf isotopic compositions, indicate persistent contributions to melting from the plume throughout the volcanic chain.

Proceedings of the Ocean Drilling Program: Scienti

Oligocene and earliest Miocene diatom biostratigraphy of ODP leg 199 site 1220, equatorial Pacific

Completion of studies on material collected during Ocean Drilling Program Leg 199 at Site 1220 in the equatorial Pacific allows calibration of the ranges of >35 stratigraphically important diatoms to paleomagnetic stratigraphy for the Oligocene and earliest Miocene (~33.5–21.5 Ma). The taxonomy of these taxa is reviewed, and age estimates of their first and last occurrences are compiled. The diatom zonation for the Oligocene and earliest Miocene of the equatorial Pacific is revised and correlated with paleomagnetic stratigraphy. This biostratigraphy is likely to be applicable throughout the low-latitude regions of the world's oceans.

Proceedings of the Ocean Drilling Program: Scienti

Data Report: Acetate and Hydrogen Concentrations in Pore Fluids Associated with a Large Gas Hydrate Reservoir, Southern Hydrate Ridge, offshore Oregon, USA

Acetate and hydrogen concentrations in pore fluids were measured in samples taken at seven sites from southern Hydrate Ridge (SHR) offshore Oregon, USA. Acetate concentrations ranged from 3.17 to 2515 µM. The maximum acetate concentrations occurred at Site 1251, which was drilled on a slope basin to the east of SHR at depths just above the bottom-simulating reflector (BSR) that marks the boundary of gas hydrate stability. Acetate maxima and localized high acetate concentrations occurred at the BSR at all sites and frequently corresponded with areas of gas hydrate accumulation, suggesting an empirical relationship. Acetate concentrations were typically at a minimum near the seafloor and above the sulfate/methane interface, where sulfate-reducing bacteria may consume acetate. Hydrogen concentrations in pressure core samples ranged from 16.45 to 1036 parts per million by volume (ppmv). In some cases, hydrogen and acetate concentrations were elevated concurrently, suggesting a positive correlation. However, sampling of hydrogen was limited in comparison to acetate, so any relationships between the two analytes, if present, were difficult to discern.

Oregon