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USGS1995

Chronic bioassays of rainbow trout fry with compounds representative of contaminants in Great Lakes fish

To evaluate the hazard of organic compounds detected in Great Lakes fish by gas chromatography/mass spectrometry, we tested compounds representative of heterocyclic nitrogen compounds, polycyclic aromatic hydrocarbons, and cyclic alkanes and alkenes. Sixty-day bioassays on the effects of nicotine, phenanthrene, pinane, and pinene on the behavior, growth, and survival of rainbow trout fry, Oncorhynchus mykiss , were conducted in a large, constant-flow, temperature-controlled water system. The following 60-day LCSO's were determined (mg/L): nicotine 5.0, phenanthrene 0.2, pinane 0.8, and pinene 1.2. Values of lowest observed effects level (LOEL) and no observed effects level (NOEL) showed that growth was generally as sensitive an endpoint as behavior and was more sensitive than time of swim-up. The 60-day LC50 values for rainbow trout were compared with earlier acute bioassays with Daphnia pulex and rainbow trout and chronic bioassays with D.pulex conducted at the Great Lakes Science Center. Rainbow trout fry were less sensitive than daphnids in all tests, indicating that toxicity tests with daphnids should be protective of salmonid fry for these types of compounds. The results for representative compounds indicate that these classes of compounds should be included in aquatic risk assessments at sites in the Great Lakes.

Journal of Great Lakes Research↗

USGS2011

Tumor prevalence and biomarkers of genotoxicity in brown bullhead (Ameiurus nebulosus) in Chesapeake Bay tributaries

We surveyed four Chesapeake Bay tributaries for skin and liver tumors in brown bullhead ( Ameiurus nebulosus ). We focused on the South River, where the highest skin tumor prevalence (53%) in the Bay watershed had been reported. The objectives were to 1) compare tumor prevalence with nearby rivers (Severn and Rhode) and a more remote river (Choptank); 2) investigate associations between tumor prevalence and polynuclear aromatic hydrocarbons (PAHs) and alkylating agents; and 3) statistically analyze Chesapeake Bay bullhead tumor data from 1992 through 2008. All four South River collections exhibited high skin tumor prevalence (19% to 58%), whereas skin tumor prevalence was 2%, 10%, and 52% in the three Severn collections; 0% and 2% in the Choptank collections; and 5.6% in the Rhode collection. Liver tumor prevalence was 0% to 6% in all but one South River collection (20%) and 0% to 6% in the three other rivers. In a subset of samples, PAH-like biliary metabolites and 32 P-DNA adducts were used as biomarkers of exposure and response to polycyclic aromatic compounds (PACs). Adducts from alkylating agents were detected as O6-methyl-2′-deoxyguanosine (O6Me-dG) and O6-ethyl-2′-deoxyguanosine (O6Et-dG) modified DNA. Bullheads from the contaminated Anacostia River were used as a positive control for DNA adducts. 32 P-DNA adduct concentrations were significantly higher in Anacostia bullhead livers compared with the other rivers. We identified alkyl DNA adducts in bullhead livers from the South and Anacostia, but not the Choptank. Neither the PAH-like bile metabolite data, sediment PAH data, nor the DNA adduct data suggest an association between liver or skin tumor prevalence and exposure to PACs or alkylating agents in the South, Choptank, Severn, or Rhode rivers. Logistic regression analysis of the Chesapeake Bay database revealed that sex and length were significant covariates for liver tumors and length was a significant covariate for skin tumors.

Chesapeake Bay watershed, South River↗

USGS2018

Unifying concepts linking dissolved organic matter composition to persistence in aquatic ecosystems

The link between composition and reactivity of dissolved organic matter (DOM) is central to understanding the role aquatic systems play in the global carbon cycle; yet, unifying concepts driving molecular composition have yet to be established. We characterized 37 DOM isolates from diverse aquatic ecosystems, including their stable and radiocarbon isotopes (δ 13 C-dissolved organic carbon (DOC) and Δ 14 C-DOC), optical properties (absorbance and fluorescence), and molecular composition (ultrahigh resolution mass spectrometry). Isolates encompassed end-members of allochthonous and autochthonous DOM from sites across the United States, the Pacific Ocean, and Antarctic lakes. Modern Δ 14 C-DOC and optical properties reflecting increased aromaticity, such as carbon specific UV absorbance at 254 nm (SUVA 254 ), were directly related to polyphenolic and polycyclic aromatic compounds, whereas enriched δ 13 C-DOC and optical properties reflecting autochthonous end-members were positively correlated to more aliphatic compounds. Furthermore, the two sets of autochthonous end-members (Pacific Ocean and Antarctic lakes) exhibited distinct molecular composition due to differences in extent of degradation. Across all sites and end-members studied, we find a consistent shift in composition with aging, highlighting the persistence of certain biomolecules concurrent with degradation time.

Environmental Science & Technology↗

USGS2013

Quantity and quality of stormwater collected from selected stormwater outfalls at industrial sites, Fort Gordon, Georgia, 2012

An assessment of the quantity and quality of stormwater runoff associated with industrial activities at Fort Gordon was conducted from January through August 2012. The assessment was provided to satisfy the requirements from a general permit that authorizes the discharge of stormwater under the National Pollutant Discharge Elimination System from a site associated with industrial activities. The stormwater quantity refers to the runoff discharge at the point and time of the runoff sampling. The study was conducted by the U.S. Geological Survey, in cooperation with the U.S. Department of the Army Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon. Stormwater runoff samples were collected from five stations at four industrial sites, including two landfills (SWR11–1 and SWR11–2) and three heating and cooling sites, SWR11–3, SWR11–4, and SWR11–5. The assessment included the collection of physical properties, such as dissolved oxygen and pH; the detection of suspended materials (total suspended solids, total fixed solids, and total volatile solids), nutrients and organic compounds, and major and trace inorganic compounds (metals); and for the three heating and cooling sites, the detection of volatile and semivolatile organic compounds. Landfill site SWR11–2 had the greatest total suspended solid concentration (214 milligrams per liter) of all sites and exceeded the daily maximum effluent limit for landfills. Heating and cooling site SWR11–3 had the greatest total suspended solid concentration (169 milligrams per liter), total fixed solids (101 milligrams per liter), and total volatile solids (68 milligrams per liter) when compared to the three heating and cooling sites. Total nitrogen and phosphorus concentrations were 1.02 and 0.09, and 1.74 and 0.21 milligrams per liter, respectively, at landfill sites SWR11–1 and SWR11–2. At heating and cooling sites, total nitrogen and phosphorus concentrations ranged from 0.53 to 1.08 milligrams per liter and 0.07 to 0.1 milligram per liter, respectively, with the highest concentrations measured at site SWR11–3. Additionally, oil and grease concentrations at all sites were compared to applicable benchmark standards; no sample concentrations exceeded these standards. The estimated dissolved concentrations of cadmium, lead, nickel, zinc, mercury, and silver, and the total recoverable concentrations of arsenic and selenium were compared to applicable benchmark levels and to acute and chronic effect aquatic-life criteria for further screening purposes. The estimated dissolved zinc concentration (105 micrograms per liter) at site SWR11–3 was the only constituent to exceed a benchmark standard (40 micrograms per liter). Estimated dissolved zinc concentrations at sites SWR11–4 and SWR11–5 exceeded acute and chronic effect aquatic-life criteria. Estimated dissolved concentrations of lead exceeded the chronic effect aquatic-life criteria at all sites and exceeded the acute effect criteria at site SWR11–3. Acute and chronic effect aquatic-life criteria for dissolved cadmium were exceeded at site SWR11–3. Samples from sites SWR11–3, SWR11–4, and SWR11–5 were analyzed for 83 volatile and semivolatile organic compounds. Eight polycyclic aromatic hydrocarbon compounds, benzo[ a ]pyrene, benzo[ b ]fluoranthene, benzo[ ghi ]perylene, benzo[ k ]fluoranthene, chrysene, indeno[1,2,3- cd ]pyrene, phenanthrene, and pyrene, were detected at all three sites. Of the 86 volatile and semivolatile organic compounds that were analyzed in stormwater samples from heating and cooling sites, 15 (18 percent) were detected at site SWR11–3, 12 (14 percent) were detected at site SWR11–4, and 17 (20 percent) were detected at site SWR11–5.

Georgia↗

USGS2025

Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma↗

USGS2020

Effects of stormwater runoff from selected bridge decks on conditions of water, sediment, and biological quality in receiving waters in South Carolina, 2013 to 2018

The U.S. Geological Survey, in cooperation with the South Carolina Department of Transportation, investigated the effects of stormwater runoff from bridge decks on stream water quality conditions in South Carolina. The investigation assessed 5 bridges in 3 physiographic provinces in South Carolina (Piedmont, Upper Coastal Plain, and Lower Coast Plain) that had a range of bridge, traffic, and hydrologic characteristics. The five selected South Carolina bridge sites (coincident with U.S. Geological Survey stations) and corresponding highways were Lynches River at Effingham (station 02132000; U.S. Highway 52), North Fork Edisto River at Orangeburg (station 02173500; U.S. Highway 301), Turkey Creek above Huger (station 02172035; South Carolina Highway 41), South Fork Edisto River near Denmark (station 02173000; U.S. Highway 321), and Fishing Creek at Highway 5 below York (station 021473415; South Carolina Highway 5). Bridge decks at the selected sites used open chutes, scuppers, and downspouts to drain stormwater directly into the receiving water at evenly spaced intervals. Stream water, sediment, and biological samples were collected and analyzed for a variety of constituents to evaluate the stream conditions for this study. Five to six stream samples were collected at transects upstream and downstream from each selected bridge site using the equal-width-increment technique during observable stormwater runoff. Routine samples of the receiving waters were collected 12 to 14 times at the upstream transect during nonstorm conditions. Samples were analyzed for physical properties, suspended sediment, nutrients, major ions, trace metals, polycyclic aromatic hydrocarbons, and Escherichia coli . Bridge-deck sediment and streambed sediment at upstream and downstream transects were collected once at each bridge site and analyzed for metals and semivolatile organic compounds that include polycyclic aromatic hydrocarbons. Benthic macroinvertebrate community surveys were conducted once using Hester-Dendy multiplate artificial substrate samplers deployed at multiple upstream and downstream transects concurrently. Statistical analysis of the water-quality data determined that stormwater runoff from bridges did not significantly degrade physical properties, nor nutrient, trace-metal, Escherichia coli , and suspended-sediment concentrations at the selected sites beyond the variability at the upstream transect (no bridge influence) during the study period. During storm sampling at the bridge sites, water-quality conditions were statistically similar upstream and downstream from each bridge, except for greater turbidity, total nitrogen, and total organic nitrogen plus ammonia concentrations found downstream from the bridge site on Fishing Creek; higher total chromium concentrations detected downstream from the bridge site on Turkey Creek; and increased Escherichia coli concentrations found downstream from the bridge site on the North Fork Edisto River. Total recoverable lead, cadmium, and copper concentrations were the only trace metals that periodically exceeded the South Carolina Department of Health and Environmental Control freshwater aquatic-life criteria at some bridge sites (lead, copper, and cadmium in Turkey Creek; cadmium and lead in Fishing Creek; lead in the South Fork Edisto River and Lynches River), but the exceedances occurred more frequently during routine sampling upstream from the bridge sites than during storm sampling at upstream and downstream transects. In general, stormwater runoff from the bridge decks did not seem to be the major source of metal enrichment in receiving waters during the study period. North Fork and South Fork Edisto Rivers and Turkey Creek had only one storm sample that exceeded South Carolina Department of Health and Environmental Control recreational criterion for Escherichia coli at both the upstream and downstream locations, while Fishing Creek had more frequent exceedances. Polycyclic aromatic hydrocarbons were detected infrequently in the stream samples. In general, sediment trace-metal concentrations were below the threshold and probable effect concentration at all bridge sites, except for the chromium concentration (45.1 milligrams per kilogram) detected upstream from the bridge site on Fishing Creek that exceeded the threshold effect concentration of 43.4 milligrams per kilogram. Based on enrichment ratios less than 1.5, bridge-deck runoff did not seem to be affecting trace-metal accumulation in the streambed sediment downstream from the bridge sites, except for lead at the bridge site on the Lynches River and manganese at the bridge site on Fishing Creek. Individual polycyclic aromatic compound concentrations and the sum of 18 compounds did not exceed any threshold and probable effect concentrations, indicating polycyclic aromatic hydrocarbon concentrations in the streambed sediment at downstream and upstream transects were not likely to affect the health of benthic macroinvertebrate communities. Although the cumulative polycyclic aromatic hydrocarbon concentrations in downstream sediment at the sites on Turkey and Fishing Creeks were well below the threshold effect concentration of 1,610 micrograms per kilogram, the 3- to 100-fold increase in downstream concentrations indicated a strong probability of a bridge-deck runoff source. Overall, benthic macroinvertebrate community health downstream from the bridge sites did not seem to be affected by bridge-deck runoff based on several multivariate analyses that indicated statistically similar benthic macroinvertebrate communities at upstream and downstream transects. Of the five bridge sites in this study, the site on Turkey Creek seemed to have the least healthy benthic macroinvertebrate communities because of the lowest Ephemeroptera, Plecoptera, and Trichoptera spp. (mayflies, stoneflies, and caddisflies, respectively) taxa, species richness, and diversity; and the highest biotic indices, indicative of poorer ecological health, at upstream and downstream transects. This ecological finding was not unexpected because of seasonal periods of negligible flow when dissolved-oxygen concentrations fell below 4 milligrams per liter during the study period. Of the five bridge sites in this study, the site on the South Fork Edisto River seemed to have healthier benthic macroinvertebrate communities because of the greater mean Ephemeroptera, Plecoptera, and Trichoptera spp. taxa; and lower mean biotic indices at upstream and downstream transects.

Scientific Investigations Report↗

USGS2020

Anthropogenic pollutants and biomarkers for the identification of 2011 Tohoku-oki tsunami deposits (Japan)

Organic geochemistry is commonly used in environmental studies. In tsunami research, however, its applications are in their infancy and it is still rarely used. We present results for two types of organic geochemical markers, biomarkers and anthropogenic markers, present in deposits left by 2011 Tohoku-oki tsunami on the Sendai Plain, Japan. As the tsunami inundated the coastal lowland up to 4.85 km inland, sediments from various sources were eroded, transported and deposited. This led to the distribution of biomarkers from different sources across the Sendai Plain creating a unique geochemical signature in the tsunami deposits. The tsunami also caused destruction along the Sendai coastline, leading to the release of large quantities of environmental pollutants (e.g., fossil fuels, tarmac, pesticides, plastics, etc.) that were distributed across the inundated area. These anthropogenic markers, represented by three main compound groups (polycyclic aromatic hydrocarbons, pesticides, and halogenated compounds), were preserved in tsunami deposits (at least until 2013, prior to land clearing). Their concentrations differed significantly from the pre- and post-tsunami background contamination levels. Organic proxy concentrations can differ for sand and mud deposits due to various factors (e.g., preservation, dilution, microbial alteration). However, it can be concluded that anthropogenic markers and biomarkers have the potential to be a valuable proxy for future studies of recent tsunami deposits because of their high source specificity and relatively good preservation potential providing information about sediment sources and transport pathways (e.g., marine source, evidence of backwash).

Sendai↗

USGS2014

Data compilation for assessing sediment and toxic chemical loads from the Green River to the lower Duwamish Waterway, Washington

Between February and June 2013, the U.S. Geological Survey collected representative samples of whole water, suspended sediment, and (or) bed sediment from a single strategically located site on the Duwamish River, Washington, during seven periods of different flow conditions. Samples were analyzed by Washington-State-accredited laboratories for a large suite of compounds, including polycyclic aromatic hydrocarbons and other semivolatile compounds, polychlorinated biphenyl Aroclors and the 209 congeners, metals, dioxins/furans, volatile organic compounds, pesticides, butyltins, hexavalent chromium, and total organic carbon. Chemical concentrations associated with bulk bed sediment (<2 mm) and fine bed sediment (<62.5 μm) fractions were compared to chemical concentrations associated with suspended sediment. Bulk bed sediment concentrations generally were lower than fine bed sediment and suspended-sediment concentrations. Concurrent with the chemistry sampling, additional parameters were measured, including instantaneous river discharge, suspended-sediment concentration, sediment particle-size distribution, and general water-quality parameters. From these data, estimates of instantaneous sediment and chemical loads from the Green River to the Lower Duwamish Waterway were calculated.

Washington↗

USGS2017

An evaluation of the zooplankton community at the Sheboygan River Area of Concern and non-Area of Concern comparison sites in western Lake Michigan rivers and harbors in 2016

The Great Lakes Areas of Concern (AOCs) are considered to be the most severely degraded areas within the Great Lakes basin, as defined in the Great Lakes Water Quality Agreement and amendments. Among the 43 designated AOCs are four Lake Michigan AOCs in the State of Wisconsin. The smallest of these AOCs is the Sheboygan River AOC, which was designated as an AOC because of sediment contamination from polychlorinated biphenyl compounds (PCBs), polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs), and heavy metals. The Sheboygan River AOC has 9 of 14 possible Beneficial Use Impairments (BUIs), which must be addressed to improve overall water-quality, and to ultimately delist the AOC. One of the BUIs associated with this AOC is the “degradation of phytoplankton and zooplankton populations,” which can be removed from the list of impairments when it has been determined that zooplankton community composition and structure at the AOC do not differ significantly from communities at non-AOC comparison sites. In 2012 and 2014, the U.S. Geological Survey collected plankton (phytoplankton and zooplankton) community samples at the Sheboygan River AOC and selected non-AOC sites as part of a larger Great Lakes Restoration Initiative study evaluating both the benthos and plankton communities in all four of Wisconsin’s Lake Michigan AOCs. Although neither richness nor diversity of phytoplankton or zooplankton in the Sheboygan River AOC were found to differ significantly from the non-AOC sites in 2012, results from the 2014 data indicated that zooplankton diversity was significantly lower, and so rated as degraded, when compared to the Manitowoc and Kewaunee Rivers, two non-AOC sites of similar size, land use, and close geographic proximity. As a follow-up to the 2014 results, zooplankton samples were collected at the same locations in the AOC and non-AOC sites during three sampling trips in spring, summer, and fall 2016. An analysis of similarity indicated no significant difference between the zooplankton community composition and structure in the AOC and non-AOC sites. Zooplankton taxa richness in the AOC was rated as “not degraded” in 2016 because of significantly higher taxa richness values in samples collected from the Sheboygan River AOC, compared with the non-AOC sites as a group (that is, data pooled from both non-AOC sites). Zooplankton diversity in 2016, however, was characterized as “degraded” in the AOC on the basis of significantly lower (p<0.05) values in samples collected from the AOC compared with those collected from the non-AOC sites as a group. Annual variation in zooplankton community composition and structure at the Sheboygan River AOC was significantly different among all 3 years sampled, as indicated by an analysis of similarity test. Zooplankton richness was significantly higher in 2014 than in both 2012 and 2016, and diversity was significantly higher in 2012 than in both 2014 and 2016. Postremediation recovery can often be complicated by non-AOC-related stressors such as nutrients, invasive species, and extremes in flow, which could affect the recovery of zooplankton communities in the Sheboygan River AOC. The effect of the stressors on postremediation recovery underscores the importance of sampling multiple years when assessing the effectiveness of remediation activities. The results from this study will be used by the Wisconsin Department of Natural Resources and the U.S. Environmental Protection Agency to determine if restoration efforts have been effective in removing the plankton BUI and to monitor future conditions in the AOC.

Wisconsin↗

USGS2007

Gasoline-Related Compounds in Lakes Mead and Mohave, Nevada, 2004-06

The distribution of man-made organic compounds, specifically gasoline-derived compounds, was investigated from 2004 to 2006 in Lakes Mead and Mohave and one of its tributary streams, Las Vegas Wash. Compounds contained in raw gasoline (benzene, toluene, ethylbenzene, xylenes; also known as BTEX compounds) and those produced during combustion of gasoline (polycyclic aromatic hydrocarbon compounds; also known as PAH compounds) were detected at every site sampled in Lakes Mead and Mohave. Water-quality analyses of samples collected during 2004-06 indicate that motorized watercraft are the major source of these organic compounds to the lakes. Concentrations of BTEX increase as the boating season progresses and decrease to less than detectable levels during the winter when few boats are on the water. Volatilization and microbial degradation most likely are the primary removal mechanisms for BTEX compounds in the lakes. Concentrations of BTEX compounds were highest at sampling points near marinas or popular launching areas. Methyl tert-butyl ether (MTBE) was detected during 2004 but concentrations decreased to less than the detection level during the latter part of the study; most likely due to the removal of MTBE from gasoline purchased in California. Distribution of PAH compounds was similar to that of BTEX compounds, in that, concentrations were highest at popular boating areas and lowest in areas where fewer boats traveled. PAH concentrations were highest at Katherine Landing and North Telephone Cove in Lake Mohave where many personal watercraft with carbureted two-stroke engines ply the waters. Lake-bottom sediment is not a sink for PAH as indicated by the low concentrations detected in sediment samples from both lakes. PAH compounds most likely are removed from the lakes by photochemical degradation. PAH compounds in Las Vegas Wash, which drains the greater Las Vegas metropolitan area, were present in relatively high concentrations in sediment from the upstream reaches. Concentrations of PAH compounds were low in water and sediment samples collected farther downstream, thus the bottom sediment in the upstream part of the wash may be an effective trap for these compounds. Bioavailable PAH compounds were present in all samples as determined using the Fluoroscan method. Microtox acute toxicity profiles indicated that Callville Bay in Lake Mead and the two Lake Mohave sites had only minor evidence that toxic compounds are present.

Scientific Investigations Report↗

USGS2015

Chemical concentrations and instantaneous loads, Green River to the Lower Duwamish Waterway near Seattle, Washington, 2013–15

In November 2013, U.S. Geological Survey streamgaging equipment was installed at a historical water-quality station on the Duwamish River, Washington, within the tidal influence at river kilometer 16.7 (U.S. Geological Survey site 12113390; Duwamish River at Golf Course at Tukwila, WA). Publicly available, real-time continuous data includes river streamflow, stream velocity, and turbidity. Between November 2013 and March 2015, the U.S. Geological Survey collected representative samples of water, suspended sediment, or bed sediment from the streamgaging station during 28 periods of differing flow conditions. Samples were analyzed by Washington-State-accredited laboratories for a large suite of compounds, including metals, dioxins/furans, semivolatile compounds including polycyclic aromatic hydrocarbons, pesticides, butytins, polychlorinated biphenyl (PCB) Aroclors and the 209 PCB congeners, volatile organic compounds, hexavalent chromium, and total and dissolved organic carbon. Metals, PCB congeners, and dioxins/furans were frequently detected in unfiltered-water samples, and concentrations typically increased with increasing suspended-sediment concentrations. Chemical concentrations in suspendedsediment samples were variable between sampling periods. The highest concentrations of many chemicals in suspended sediment were measured during summer and early autumn storm periods. Median chemical concentrations in suspended-sediment samples were greater than median chemical concentrations in fine bed sediment (less than 62.5 µm) samples, which were greater than median chemical concentrations in paired bulk bed sediment (less than 2 mm) samples. Suspended-sediment concentration, sediment particle-size distribution, and general water-quality parameters were measured concurrent with the chemistry sampling. From this discrete data, combined with the continuous streamflow record, estimates of instantaneous sediment and chemical loads from the Green River to the Lower Duwamish Waterway were calculated. For most compounds, loads were higher during storms than during baseline conditions because of high streamflow and high chemical concentrations. The highest loads occurred during dam releases (periods when stored runoff from a prior storm is released from the Howard Hanson Dam into the upper Green River) because of the high river streamflow and high suspended-sediment concentration, even when chemical concentrations were lower than concentrations measured during storm events.

Washington↗

USGS2010

Applying GORE-TEX technology for rapid contaminant assessments at Fort Gordon, Georgia

The U.S. Geological Survey, in cooperation with the U.S. Department of the Army at Fort Gordon, Georgia, deployed GORE1 adsorbent samplers along creeks and floodplains to rapidly assess potential contamination at abandoned facilities and in adjacent surface water. The samplers provide screening-level data to determine the presence or absence of volatile organic compounds, semi-volatile organic compounds, and polycyclic aromatic hydrocarbons and were deployed in saturated creek and floodplain sediments adjacent to four abandoned waste-disposal/warfare-training sites. Fuelrelated compounds, not solvents, are the most prevalent organic compounds detected along segments of McCoys Creek adjacent to the 19th Street landfill; South Prong Creek adjacent to the South Prong Creek waste-disposal area; an unnamed tributary to Butler Creek adjacent to the old hospital landfill; and the Brier Creek floodplain adjacent to the Patterson anti-tank range. All 37 samplers deployed in these assessments had detections of total petroleum hydrocarbons ranging from just above 3 (laboratory method detection level) to 344 micrograms per liter. Detections of octane that ranged from 1 to 7.6 micrograms per liter were common in all assessments, except for South Prong Creek. Calculated concentrations of benzene are at or just above the National Primary Drinking Water Standard maximum contaminant level for all samplers deployed in the floodplain at the Patterson anti-tank range. The highest calculated concentration of a specific fuel-related compound was for toluene collected at one sampling site on McCoys Creek adjacent to the 19th Street landfill, but the concentration was below the National Primary Drinking Water Standard. These results are being used by Fort Gordon environmental compliance personnel to decide if further assessments are needed at these abandoned waste-disposal/warfare-training sites

Georgia↗

USGS2006

Concentrations, loads, and yields of particle-associated contaminants in urban creeks, Austin, Texas, 1999-2004

Concentrations, loads, and yields of particle-associated (hydrophobic) contaminants (PACs) in urban runoff in creeks in Austin, Texas, were characterized using an innovative approach: large-volume suspended-sediment sampling. This approach isolates suspended sediment from the water column in quantities sufficient for direct chemical analysis of PACs. During 1999-2004, samples were collected after selected rain events from each of five stream sites and Barton Springs for a study by the U.S. Geological Survey, in cooperation with the City of Austin. Sediment isolated from composited samples was analyzed for major elements, metals, organochlorine compounds, and polycyclic aromatic hydrocarbons (PAHs). In addition, at the Shoal Creek and Boggy Creek sites, individual samples for some events were analyzed to investigate within-event variation in sediment chemistry. Organochlorine compounds detected in suspended sediment included chlordane, dieldrin, DDD, DDE, DDT, and polychlorinated biphenyls (PCBs). Concentrations of PACs varied widely both within and between sites, with higher concentrations at the more urban sites and multiple nondetections at the least-urban sites. Within-site variation for metals and PAHs was smaller than between-site variation, and concentrations and yields of these and the organochlorine compounds correlated positively to the percentage of urban land use in the watershed. Loads of most PACs tested correlated significantly with suspended-sediment loads. Concentrations of most PACs correlated strongly with three measures of urban land use. Variation in suspended-sediment chemistry during runoff events was investigated at the Shoal and Boggy Creek sites. Five of the eight metals analyzed, dieldrin, chlordane, PCBs, and PAHs were detected at the highest concentrations in the first sample collected at the Shoal Creek site, a first-flush effect, but not at the Boggy Creek site. Temporal patterns in concentrations of DDT and its breakdown products varied from one event to the next. In spite of the first-flush effect in concentrations at the Shoal Creek site, most of the contaminant load was transported at peak discharge, when suspended-sediment concentration and load are maximum.

Scientific Investigations Report↗

USGS1983

Terpenoid marker compounds derived from biogenic precursors in volcanic ash from Mount St. Helens, Washington

A volcanic-ash sample obtained after the 1980 eruption of Mount St. Helens, Washington, was analyzed for cyclic terpenoid organic compounds and polycyclic aromatic hydrocarbons using capillary gas chromatography-mass spectrometry-computer techniques. Various tricyclic diterpenoid acids and hydrocarbons were identified including dehydroabietic acid, dehydroabietin, dehydroabietane, simonellite, and retene. Preliminary evidence indicates that these compounds were derived from forest soils or atmospheric aerosols or both in the vicinity of coniferous forests. A diagenetic scheme involving three possible pathways for the conversion of abietic acid to retene is presented.

Washington↗

USGS2021

Assessing the biological reactivity of organic compounds on volcanic ash: Implications for human health hazard

Exposure to volcanic ash is a long-standing health concern for people living near active volcanoes and in distal urban areas. During transport and deposition, ash is subjected to various physicochemical processes that may change its surface composition and, consequently, bioreactivity. One such process is the interaction with anthropogenic pollutants; however, the potential for adsorbed, deleterious organic compounds to directly impact human health is unknown. We use an in vitro bioanalytical approach to screen for the presence of organic compounds of toxicological concern on ash surfaces and assess their biological potency. These compounds include polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo- p -dioxins and dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (dlPCBs). Analysis of ash collected in or near urbanised areas at five active volcanoes across the world (Etna, Italy; Fuego, Guatemala; Kelud, Indonesia; Sakurajima, Japan; Tungurahua, Ecuador) using the bioassay inferred the presence of such compounds on all samples. A relatively low response to PCDD/Fs and the absence of a dlPCBs response in the bioassay suggest that the measured activity is dominated by PAHs and PAH-like compounds. This study is the first to demonstrate a biological potency of organic pollutants associated with volcanic ash particles. According to our estimations, they are present in quantities below recommended exposure limits and likely pose a low direct concern for human health.

Bulletin of Volcanology↗

USGS2012

Occurrence of pharmaceuticals, hormones, and organic wastewater compounds in Pennsylvania waters, 2006-09

Concern over the presence of contaminants of emerging concern, such as pharmaceutical compounds, hormones, and organic wastewater compounds (OWCs), in waters of the United States and elsewhere is growing. Laboratory techniques developed within the last decade or new techniques currently under development within the U.S. Geological Survey now allow these compounds to be measured at concentrations in nanograms per liter. These new laboratory techniques were used in a reconnaissance study conducted by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection, to determine the occurrence of contaminants of emerging concern in streams, streambed sediment, and groundwater of Pennsylvania. Compounds analyzed for in the study are pharmaceuticals (human and veterinary drugs), hormones (natural and synthetic), and OWCs (detergents, fragrances, pesticides, industrial compounds, disinfectants, polycyclic aromatic hydrocarbons, fire retardants and plasticizers). Reconnaissance sampling was conducted from 2006 to 2009 to identify contaminants of emerging concern in (1) groundwater from wells used to supply livestock, (2) streamwater upstream and downstream from animal feeding operations, (3) streamwater upstream from and streamwater and streambed sediment downstream from municipal wastewater effluent discharges, (4) streamwater from sites within 5 miles of drinking-water intakes, and (5) streamwater and streambed sediment where fish health assessments were conducted. Of the 44 pharmaceutical compounds analyzed in groundwater samples collected in 2006 from six wells used to supply livestock, only cotinine (a nicotine metabolite) and the antibiotics tylosin and sulfamethoxazole were detected. The maximum concentration of any contaminant of emerging concern was 24 nanograms per liter (ng/L) for cotinine, and was detected in a groundwater sample from a Lebanon County, Pa., well. Seven pharmaceutical compounds including acetaminophen, caffeine, carbamazepine, and the four antibiotics tylosin, sulfadimethoxine, sulfamethoxazole, and oxytetracycline were detected in streamwater samples collected in 2006 from six paired stream sampling sites located upstream and downstream from animal-feeding operations. The highest reported concentration of these seven compounds was for the antibiotic sulfamethoxazole (157 ng/L), in a sample from the downstream site on Snitz Creek in Lancaster County, Pa. Twenty-one pharmaceutical compounds were detected in streamwater samples collected in 2006 from five paired stream sampling sites located upstream or downstream from a municipal wastewater-effluent-discharge site. The most commonly detected compounds and maximum concentrations were the anticonvulsant carbamazepine, 276 ng/L; the antihistamine diphenhydramine, 135 ng/L; and the antibiotics ofloxacin, 329 ng/L; sulfamethoxazole, 1,340 ng/L; and trimethoprim, 256 ng/L. A total of 51 different contaminants of emerging concern were detected in streamwater samples collected from 2007 through 2009 at 13 stream sampling sites located downstream from a wastewater-effluent-discharge site. The concentrations and numbers of compounds detected were higher in stream sites downstream from a wastewater-effluent-discharge site than in stream sites upstream from a wastewater-effluent-discharge site. This finding indicates that wastewater-effluent discharges are a source of contaminants of emerging concern; these contaminants were present more frequently in the streambed-sediment samples than in streamwater samples. Antibiotic compounds were often present in both the streamwater and streambed-sediment samples, but many OWCs were present exclusively in the streambed-sediment samples. Compounds with endocrine disrupting potential including detergent metabolites, pesticides, and flame retardants, were present in the streamwater and streambed-sediment samples. Killinger Creek, a stream where wastewater-effluent discharges contribute a large percentage of the total flow, stands out as a stream with particularly high numbers of compounds detected and detected at the highest concentrations measured in the reconnaissance sampling. Nineteen contaminants of emerging concern were detected in streamwater samples collected quarterly from 2007 through 2009 at 27 stream sites within 5 miles of a drinking-water intake. The number of contaminants and the concentrations detected at the stream sites within 5 miles of drinking-water intakes were generally very low (concentrations less than 50 ng/L), much lower than those at sites downstream from a wastewater-effluent discharge. The most commonly detected compounds and maximum concentrations were caffeine, 517 ng/L; carbamazepine, 95 ng/L; sulfamethoxazole, 146 ng/L; and estrone, 3.15 ng/L. The concentrations and frequencies of detection of some of the contaminants of emerging concern appear to vary by season, which could be explained by compound use, flow regime, or differences in degradation rates. Concentrations of some contaminants were associated with lower flows as a result of decreased in-stream dilution of wastewater effluents or other contamination sources. Twenty-two contaminants of emerging concern were detected once each in streamwater samples collected in 2007 and 2008 from 16 fish-health stream sites located statewide. The highest concentrations were for the OWCs, including flame retardants tri(2-butoxyethyl)phosphate (604 ng/L) and tri(2-chloroethyl)phosphate (272 ng/L) and the fragrance isoquinoline (330 ng/L). Far fewer numbers of contaminants of emerging concern were detected at the fish-health sites than at the wastewater-effluent-discharge sites. Most of the fish-health sites were not located directly downstream from a wastewater-effluent discharge, but there were multiple wastewater-effluent discharges in the drainage basins upstream from the sampling sites. No distinct pattern of contaminant occurrence could be discerned for the fish-health stream sites

Pennsylvania↗

USGS2011

Water-quality monitoring for a pilot piling removal field evaluation, Coal Creek Slough, Washington, 2008-09

Significant Findings Water and sediment quality monitoring was conducted before and after the removal of a piling field located in Coal Creek Slough near Longview, Washington. Passive chemical samplers and continuous water-quality monitoring instruments were deployed at the piling removal site, Coal Creek Slough Site 1 (CCS1), and at a comparison site, Coal Creek Slough Site 2 (CCS2), before (2008) and after (2009) piling removal. Surface and subsurface (core) sediment samples were collected before and after piling removal and were analyzed for grain size, organic carbon content, and chemicals of concern. Significant findings from this study include: * Phenanthrene was the only compound detected in wood piling samples analyzed for a large suite of semivolatile organic compounds and polycyclic aromatic hydrocarbons (PAHs). Metals potentially associated with wood treatment were detected in the wood piling samples at low concentrations. * Organic carbon was slightly lower in core samples from CCS1 in pre-removal (2008) and post-removal (2009) samples than in surface samples from both sites in both years. * Grain-size class distributions were relatively uniform between sites and years. * Thirty-four out of 110 chemicals of concern were detected in sediments. Eight of those detected were anthropogenic waste indicator (AWI) compounds, 18 were PAHs, 4 were sterols, and 4 were metals potentially associated with wood treatment. * Nearly all reported concentrations of chemicals of concern in sediments are qualified as estimates, primarily due to interferences in extracts resulting from complex sample matrices. Indole, perylene, and fluoranthene are reported without qualification for some of the samples, and the metals are reported without qualification for all samples. * The highest frequency of detection of chemicals of concern was seen in the pre-removal surface samples at both sites. * AWI compounds were detected less frequently and at lower concentrations during the post-removal sampling compared to the pre-removal sampling. * Several PAHs were detected at relatively high concentrations in core samples, likely indicating historical sources. * Most commonly detected PAHs in sediments were 2,6-dimethylnaphthalene, fluoranthene, perylene, and pyrene. * Most commonly detected AWIs in sediments were 3-methyl-1h-indole (skatol), acetophenone, indole, phenol, and paracresol. * Sedimentary concentrations of perylene exceeded available sediment quality guidelines. Perylene is widespread in the environment and has large potential natural sources in addition to its anthropogenic sources. * Concentrations of metals did not exceed sediment quality guidelines. * Multiple organochlorine pesticides, both banned and currently used, were detected at each site using passive samplers. * Commonly detected pesticides included hexachlorobenzene, pentachloroanisole (a degradation product of pentachlorophenol), diazinon, cis-chlordane, endosulfan, DDD, and endosulfan sulfate. * PBDE concentrations detected in passive sampler extracts were less than the method detection limit at all sites with the exception of PBDE-99, detected at a concentration less than the reporting limit. * The fragrance galaxolide was detected at a concentration greater than the method detection limit. * Common PAHs, such as phenanthrene, fluoranthene, and pyrene, were detected in every passive sampler. * Dissolved oxygen concentration was slightly higher at site CCS1 compared to site CCS2 in both years. * Overall, there was no systematic increase in chemicals of concern at the restoration site during post-removal monitoring compared to conditions during pre-removal monitoring. Any immediate, short-duration effects of piling removal on water quality could not be determined because monitoring was not conducted during the removal.

Open-File Report↗

USGS2012

Assessment of soil-gas and groundwater contamination at the Gibson Road landfill, Fort Gordon, Georgia, 2011

Soil-gas and groundwater assessments were conducted at the Gibson Road landfill in 201 to provide screening-level environmental contamination data to supplement the data collected during previous environmental studies at the landfill. Passive samplers were used in both assessments to detect volatile and semivolatile organic compounds and polycyclic aromatic hydrocarbons in soil gas and groundwater. A total of 56 passive samplers were deployed in the soil in late July and early August for the soil-gas assessment. Total petroleum hydrocarbons (TPH) were detected at masses greater than the method detection level of 0.02 microgram in all samplers and masses greater than 2.0 micrograms in 13 samplers. Three samplers located between the landfill and a nearby wetland had TPH masses greater than 20 micrograms. Diesel was detected in 28 of the 56 soil-gas samplers. Undecane, tridecane, and pentadecane were detected, but undecane was the most common diesel compound with 23 detections. Only five detections exceeded a combined diesel mass of 0.10 microgram, including the highest mass of 0.27 microgram near the wetland. Toluene was detected in only five passive samplers, including masses of 0.65 microgram near the wetland and 0.85 microgram on the southwestern side of the landfill. The only other gasoline-related compound detected was octane in two samplers. Naphthalene was detected in two samplers in the gully near the landfill and two samplers along the southwestern side of the landfill, but had masses less than or equal to 0.02 microgram. Six samplers located southeast of the landfill had detections of chlorinated compounds, including one perchloroethene detections (0.04 microgram) and five chloroform detections (0.05 to0.08 microgram). Passive samplers were deployed and recovered on August 8, 2011, in nine monitoring wells along the southwestern, southeastern and northeastern sides of the landfill and down gradient from the eastern corner of the landfill. Six of the nine samplers had TPH concentrations greater than 100 micrograms per liter. TPH concentrations declined from 320 micrograms per liter in a sampler near the landfill to 18 micrograms in a sampler near the wetland. Five of the samplers had detections of one or more diesel compounds but detections of individual diesel compounds had concentrations below a method detection level of 0.01 microgram per liter. Benzene was detected in three samplers and exceeded the national primary drinking-water standard of 5 micrograms per liter set by the U.S. Environmental Protection Agency. The concentrations of benzene, and therefore BTEX, were 6.1 micrograms per liter in the sampler near the eastern corner of the landfill, 27 micrograms per liter in the sampler near the wetland, and 37 micrograms per liter in the sampler at the southern corner of the landfill. Nonfuel-related compounds were detected in the four wells that are aligned between the eastern corner of the landfill and the wetland. The sampler deployed nearest the eastern corner of the landfill had the greatest number of detected organic compounds and had the only detections of two trimethylbenzene compounds, naphthalene, 2-methyl naphthalene, and 1,4-dichlorobenzene. The two up gradient samplers had the greatest number of chlorinated compounds with five compounds each, compared to detections of four compounds and one compound in the two down gradient samplers. All four samplers had detections of 1,1-dichloroethane which ranged from 42 to 1,300 micrograms per liter. Other detections of chlorinated compounds included trichloroethene, perchloroethene, cis-1,2-dichloroethene, 1,1,1-trichloroethane and chloroform.

Georgia↗