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Programed oil generation of the Zubair Formation, Southern Iraq oil fields: Results from Petromod software modeling and geochemical analysis

1D petroleum system modeling was performed on wells in each of four oil fields in South Iraq, Zubair (well Zb-47), Nahr Umr (well NR-9), West Qurna (well WQ-15 and 23), and Majnoon (well Mj-8). In each of these fields, deposition of the Zubair Formation was followed by continuous burial, reaching maximum temperatures of 100°C (equivalent to 0.70%Ro) at depths of 3,344–3,750 m of well Zb-47 and 3,081.5–3,420 m of well WQ-15, 120°C (equivalent to 0.78%Ro) at depths of 3,353–3,645 m of well NR-9, and 3,391–3,691.5 m of well Mj-8. Generation of petroleum in the Zubair Formation began in the late Tertiary, 10 million years ago. At present day, modeled transformation ratios (TR) indicate that 65% TR of its generation potential has been reached in well Zb-47, 75% TR in well NR-9 and 55-85% TR in West Qurna oil field (wells WQ-15 and WQ-23) and up to 95% TR in well Mj-8, In contrast, younger source rocks are immature to early mature (<20% TR), whereas older source rocks are mature to overmature (100% TR). Comparison of these basin modeling results, in Basrah region, are performed with Kifle oil field in Hilla region of western Euphrates River whereas the Zubair Formation is immature within temperature range of 65–70°C (0.50%Ro equivalent) with up to 12% (TR = 12%) hydrocarbon generation efficiency and hence poor generation could be assessed in this last location. The Zubair Formation was deposited in a deltaic environment and consists of interbedded shales and porous and permeable sandstones. In Basrah region, the shales have total organic carbon of 0.5–7.0 wt%, Tmax 430–470°C and hydrogen indices of up to 466 with S2 = 0.4–9.4 of kerogen type II & III and petroleum potential of 0.4–9.98 of good hydrocarbon generation, which is consistent with 55–95% hydrocarbon efficiency. These generated hydrocarbons had charged (in part) the Cretaceous and Tertiary reservoirs, especially the Zubair Formation itself, in the traps formed by Alpine collision that closed the Tethys Ocean between Arabian and Euracian Plates and developed folds in Mesopotamian Basin 15–10 million years ago. These traps are mainly stratigraphic facies of sandstones with the shale that formed during the deposition of the Zubair Formation in transgression and regression phases within the main structural folds of the Zubair, Nahr Umr, West Qurna and Majnoon Oil fields. Oil biomarkers of the Zubair Formation Reservoirs are showing source affinity with mixed oil from the Upper Jurassic and Lower Cretaceous strata, including Zubair Formation organic matters, based on presentation of GC and GC-MS results on diagrams of global petroleum systems.

Arabian Journal of Geosciences↗

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology↗

Implications of aggregating and smoothing daily production data on estimates of the transition time between flow regimes in horizontal hydraulically fractured Bakken oil wells

The level to which data are aggregated or smoothed can impact analytical and predictive modeling results. This paper discusses findings regarding such impacts on estimating change points in production flow regimes of horizontal hydraulically fractured shale oil wells producing from the middle member of the Bakken Formation. Change points that signal transitions in flow regimes are important because they subsequently affect estimates of ultimate recovery from wells producing from shale plays. Extending our earlier work, we employ two different statistical approaches, Bacon–Watts Bayesian regression and nonlinear constrained least squares regression, and a designed computational experiment to estimate the time of transition from the transient to the boundary-dominated flow regime for 14 different wells using daily production data rather than aggregated monthly data, as previously considered. The daily data were also smoothed to reduce noise. Computational experiments suggest that both statistical approaches can lead to plausible estimates of the transition point under different data aggregation or smoothing regimes, but that daily data are likely too granular to produce credible estimates. Although the expected value of transition points using smoothed daily data and monthly disaggregated data are generally comparable, the confidence intervals bounding the estimates based on smoothed daily data are generally wider. Our results not only inform the operational practices of oil producers engaged in economic evaluation of their shale resources and additional play development activities, but also the activities of petroleum research groups, government agencies, and financial organizations seeking to improve the trustworthiness of resource projections.

Mathematical Geosciences↗

Identification of lithofacies using Kohonen self-organizing maps

Lithofacies identification is a primary task in reservoir characterization. Traditional techniques of lithofacies identification from core data are costly, and it is difficult to extrapolate to non-cored wells. We present a low-cost automated technique using Kohonen self-organizing maps (SOMs) to identify systematically and objectively lithofacies from well log data. SOMs are unsupervised artificial neural networks that map the input space into clusters in a topological form whose organization is related to trends in the input data. A case study used five wells located in Appleton Field, Escambia County, Alabama (Smackover Formation, limestone and dolomite, Oxfordian, Jurassic). A five-input, one-dimensional output approach is employed, assuming the lithofacies are in ascending/descending order with respect to paleoenvironmental energy levels. To consider the possible appearance of new logfacies not seen in training mode, which may potentially appear in test wells, the maximum number of outputs is set to 20 instead of four, the designated number of lithosfacies in the study area. This study found eleven major clusters. The clusters were compared to depositional lithofacies identified by manual core examination. The clusters were ordered by the SOM in a pattern consistent with environmental gradients inferred from core examination: bind/boundstone, grainstone, packstone, and wackestone. This new approach predicted lithofacies identity from well log data with 78.8% accuracy which is more accurate than using a backpropagation neural network (57.3%). The clusters produced by the SOM are ordered with respect to paleoenvironmental energy levels. This energy-related clustering provides geologists and petroleum engineers with valuable geologic information about the logfacies and their interrelationships. This advantage is not obtained in backpropagation neural networks and adaptive resonance theory neural networks. ?? 2002 Elsevier Science Ltd. All rights reserved.

Computers & Geosciences↗

Environmental probabilistic quantitative assessment methodologies

In this paper, four petroleum resource assessment methodologies are presented as possible pollution assessment methodologies, even though petroleum as a resource is desirable, whereas pollution is undesirable. A methodology is defined in this paper to consist of a probability model and a probabilistic method, where the method is used to solve the model. The following four basic types of probability models are considered: 1) direct assessment, 2) accumulation size, 3) volumetric yield, and 4) reservoir engineering. Three of the four petroleum resource assessment methodologies were written as microcomputer systems, viz. TRIAGG for direct assessment, APRAS for accumulation size, and FASPU for reservoir engineering. A fourth microcomputer system termed PROBDIST supports the three assessment systems. The three assessment systems have different probability models but the same type of probabilistic method. The type of advantages of the analytic method are in computational speed and flexibility, making it ideal for a microcomputer. -from Author

Computers & Geosciences↗

FASP, an analytic resource appraisal program for petroleum play analysis

An analytic probabilistic methodology for resource appraisal of undiscovered oil and gas resources in play analysis is presented in a FORTRAN program termed FASP. This play-analysis methodology is a geostochastic system for petroleum resource appraisal in explored as well as frontier areas. An established geologic model considers both the uncertainty of the presence of the assessed hydrocarbon and its amount if present. The program FASP produces resource estimates of crude oil, nonassociated gas, dissolved gas, and gas for a geologic play in terms of probability distributions. The analytic method is based upon conditional probability theory and many laws of expectation and variance. ?? 1986.

Computers & Geosciences↗

Impacts of petroleum production on ground and surface waters: Results from the Osage-Skiatook Petroleum Environmental Research A site, Osage County Oklahoma

Kharaka has been a research hydrogeochemist with the U.S. Geological Survey since1975. His current research covers the fields of water-rock-gas interactions, CO 2 sequestration, contamination from agricultural drainage and petroleum produced water, and fluid-fault interactions. Kharaka has authored more than 100 scientific papers and book chapters and has delivered about 200 presentations. He received his Ph.D. from the University of California, Berkeley, in 1971. Thordsen is a geologist, employed with the U.S. Geological Survey since 1981 and presently working in the project team Hydrogeochemistry of Fine Grained Sediments, in the Water Resources Division, National Research Program. His recent research covers water-rock interactions and geochemical modeling in geothermal systems, fault-fluid systems, and petroleum produced water brine impacts. He received his M.S. in geology from the Ohio State University in 1988. Kakouros has been a hydrogeologist in the U.S. Geological Survey Water Resources Division in Menlo Park, California, since 1999. His current research covers the fields of Se contamination from agricultural drainage, CO 2 sequestration, and contamination from petroleum and petroleum-produced water. Kakouros received his M.Sc. from the San Jose State University in 2001. Herkelrath is a physicist in the U.S. Geological Survey's Water Resources Division National Research Program in Menlo Park, California. Herkelrath received his Ph.D. in physics from the University of Wisconsin at Madison. His recent research interests include multiphase flow and solute transport modeling in shallow ground-water systems where oil or brine is present.

Oklahoma↗

EMD Gas Hydrates Committee annual report

Global research on the potential commercial viability of gas extraction from gas hydrates is continuing, predominantly in Asia and in the United States, where recent efforts have focused on the exploration and characterization of gas hydrate petroleum systems and conducting controlled production tests of gas hydrate deposits hosted in mostly sand-rich reservoir systems. In 2017, gas hydrate production testing was conducted in marine settings in the offshore of Japan and China. An additional test was conducted in the Shenhu region of the South China Sea in 2020 to further evaluate the effectiveness of various well completion technologies to produce gas from gas hydrates. Late in 2018, a research partnership led by the U.S. Department of Energy National Energy Technology Laboratory and the Japan Oil, Gas and Metals National Corporation established a new Alaska North Slope test site for an extended gas hydrate production pilot with the completion of a stratigraphic test well. With the successful completion of the Prudhoe Bay Unit Hydrate-01 stratigraphic test well, planning is now underway for drilling of three additional wells at the Alaska test site, which will include a geoscience data well and two production test wells. In 2019, the Government of India released the results of one of the most comprehensive gas hydrate scientific drilling investigations ever undertaken, the leadership of the Indian National Gas Hydrate Program Expedition 02 reported on the discovery of several significant gas hydrate accumulations that were considered suitable for future gas hydrate production testing. In September of 2019, the U.S. Geological Survey released a new assessment of the technically recoverable gas hydrate resources on the Alaska North Slope. In 2018, the University of Texas at Austin released a comprehensive report describing the operational and initial technical results of the UT-GOM2-1 Hydrate Pressure Coring Expedition, which drilled and partially cored two wells in Green Canyon Block 955 in the deepwater Gulf of Mexico. The results of these recently complete gas hydrate geologic and production studies have been further reviewed in this AAPG-EMD Gas Hydrate Committee report.

Alaska↗

U.S. Geological Survey Karst Interest Group Proceedings, San Antonio, Texas, May 16–18, 2017

Introduction and Acknowledgments Karst aquifer systems are present throughout parts of the United States and some of its territories, and have developed in carbonate rocks (primarily limestone and dolomite) and evaporites (gypsum, anhydrite, and halite) that span an interval of time encompassing more than 550 million years. The depositional environments, diagenetic processes, post-depositional tectonic events, and geochemical weathering processes that form karst aquifers are varied and complex. These factors involve biological, chemical, and physical changes that when combined with the diverse climatic regimes in which karst development has taken place, result in the unique dual- or triple-porosity nature of karst aquifers. These complex hydrogeologic systems typically represent challenging and unique conditions to scientists attempting to study groundwater flow and contaminant transport in these terrains. The dissolution of carbonate rocks and the subsequent development of distinct and beautiful landscapes, caverns, and springs have resulted in the most exceptional karst areas being designated as national or state parks. Tens of thousands of similar areas in the United States have been developed into commercial caverns and known privately owned caves. Both public and private properties provide access for scientists to study the flow of groundwater in situ . Likewise, the range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than for any other aquifer type. Karst aquifers and landscapes that form in tropical areas, such as the cockpit karst along the north coast of Puerto Rico, differ greatly from karst landforms in more arid climates, such as the Edwards Plateau in west-central Texas or the Guadalupe Mountains near Carlsbad, New Mexico, where hypogenic processes have played a major role in speleogenesis. Many of these public and private lands also contain unique flora and fauna associated with these karst hydrogeologic systems. As a result, numerous federal, state, and local agencies have a strong interest in the study of karst terrains. Many of the major springs and aquifers in the United States have developed in carbonate rocks, such as the Floridan aquifer system in Florida and parts of Alabama, Georgia, and South Carolina; the Ozark Plateaus aquifer system in parts of Arkansas, Kansas, Missouri, and Oklahoma; and the Edwards-Trinity aquifer system in west-central Texas. These aquifers, and the springs that discharge from them, serve as major water-supply sources and form unique ecological habitats. Competition for the water resources of karst aquifers is common, and urban development and the lack of attenuation of contaminants in karst areas due to dissolution features that form direct pathways into karst aquifers can impact the ecosystem and water quality associated with these aquifers. The concept for developing a platform for interaction among scientists within the U.S. Geological Survey (USGS) working on karst-related studies evolved from the November 1999 National Groundwater Meeting of the USGS. As a result, the Karst Interest Group (KIG) was formed in 2000. The KIG is a loose-knit, grass-roots organization of USGS and non-USGS scientists and researchers devoted to fostering better communication among scientists working on, or interested in, karst science. The primary mission of the KIG is to encourage and support interdisciplinary collaboration and technology transfer among scientists working in karst areas. Additionally, the KIG encourages collaborative studies between the different mission areas of the USGS as well as with other federal and state agencies, and with researchers from academia and institutes. To accomplish its mission, the KIG has organized a series of workshops that have been held near nationally important karst areas. To date (2017) seven KIG workshops, including the workshop documented in this report, have been held. The workshops typically include oral and poster sessions on selected karst-related topics and research, as well as field trips to local karst areas. To increase non-USGS participation an effort was made for the workshops to be held at a university or institute beginning with the fourth workshop. Proceedings of the workshops are published by the USGS and are available online at the USGS publications warehouse https://pubs.er.usgs.gov/ by using the search term “karst interest group.” The first KIG workshop was held in St. Petersburg, Florida, in 2001, in the vicinity of the large springs and other karst features of the Floridan aquifer system. The second KIG workshop was held in 2002, in Shepherdstown, West Virginia, in proximity to the carbonate aquifers of the northern Shenandoah Valley, and highlighted an invited presentation on karst literature by the late Barry F. Beck of P.E. LaMoreaux and Associates. The third KIG workshop was held in 2005, in Rapid City, South Dakota, near evaporite karst features in limestones of the Madison Group in the Black Hills of South Dakota. The Rapid City KIG workshop included field trips to Wind Cave National Park and Jewel Cave National Monument, and featured a presentation by Thomas Casadevall, then USGS Central Region Director, on the status of Earth science at the USGS. The fourth KIG workshop in 2008 was hosted by the Hoffman Environmental Research Institute and Center for Cave and Karst Studies at Western Kentucky University in Bowling Green, Kentucky, near Mammoth Cave National Park and karst features of the Chester Upland and Pennyroyal Plateau. The workshop featured a late-night field trip into Mammoth Cave led by Rickard Toomey and Rick Olsen, National Park Service. The fifth KIG workshop in 2011 was a joint meeting of the USGS KIG and University of Arkansas HydroDays, hosted by the Department of Geosciences at the University of Arkansas in Fayetteville. The workshop featured an outstanding field trip to the unique karst terrain along the Buffalo National River in the southern Ozarks, and a keynote presentation on paleokarst in the United States was delivered by Art and Peggy Palmer. The sixth KIG workshop was hosted by the National Cave and Karst Research Institute (NCKRI) in 2014, in Carlsbad, New Mexico. George Veni, Director of the NCKRI, served as a co-chair of the workshop with Eve Kuniansky of the USGS. The workshop featured speaker Dr. Penelope Boston, Director of Cave and Karst Studies at New Mexico Tech, Socorro, and Academic Director at the NCKRI, who addressed the future of karst research. The field trip on evaporite karst of the lower Pecos Valley was led by Lewis Land (NCKRI karst hydrologist), and the field trip on the geology of Carlsbad Caverns National Park was led by George Veni. This current seventh KIG workshop is being held in San Antonio at the University of Texas at San Antonio (UTSA). This 2017 workshop is being hosted by the Department of Geological Sciences’ Student Geological Society (SGS), and student chapters of the American Association of Petroleum Geologists (AAPG) and Association of Engineering Geologists (AEG), with support by the UTSA Department of Geological Sciences and Center for Water Research. The UTSA student chapter presidents, Jose Silvestre (SGS), John Cooper (AAPG), and Tyler Mead (AEG) serve as co-chairs of the 2017 workshop with Eve Kuniansky of the USGS. The technical session committee is chaired by Eve Kuniansky, USGS, and includes Michael Bradley, Tom Byl, Rebecca Lambert, John Lane, and James Kaufmann, all USGS, and Patrick Tucci, retired USGS. The logistics committee includes Amy Clark, Yongli Gao, and Lance Lambert (Department Chair), UTSA Department of Geological Sciences; and Ryan Banta and Allan Clark, USGS, San Antonio, Texas. The field trip committee is chaired by Allan Clark and includes Amy Clark, Yongli Gao, and Keith Muehlestein, UTSA; Marcus Gary, Edwards Aquifer Authority and University of Texas at Austin; Ron Green, Southwest Research Institute; Geary Schindel, Edwards Aquifer Authority; and George Veni, NCKRI. Additionally, two organizations have assisted the UTSA student chapters in hosting the meeting by donating funds to the chapters: the Edwards Aquifer Authority, San Antonio, Texas, and the Barton Springs Edwards Aquifer Authority, Austin, Texas. Additionally, Yongli Gao, Center for Water Research and Department of Geological Sciences, UTSA, helped develop sessions on cave and karst research in China for this workshop. These proceedings could not have been accomplished without the assistance of Lawrence E. Spangler as co-editor who not only has subject matter expertise, but also serves as an editor with the USGS Science Publishing Network. We sincerely hope that this workshop continues to promote future collaboration among scientists of varied and diverse backgrounds, and improves our understanding of karst aquifer systems in the United States and its territories. The extended abstracts of USGS authors were peer reviewed and approved for publication by the USGS. Articles submitted by university researchers and other federal and state agencies did not go through the formal USGS peer review and approval process, and therefore may not adhere to USGS editorial standards or stratigraphic nomenclature. However, all articles had a minimum of two peer reviews and were edited for consistency of appearance in the proceedings. The use of trade, firm or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. The USGS Water Availability and Use Science Program funded the publication costs of the proceedings.

Scientific Investigations Report↗

Comparison of two methods used to model shape parameters of Pareto distributions

Two methods are compared for estimating the shape parameters of Pareto field-size (or pool-size) distributions for petroleum resource assessment. Both methods assume mature exploration in which most of the larger fields have been discovered. Both methods use the sizes of larger discovered fields to estimate the numbers and sizes of smaller fields: (1) the tail-truncated method uses a plot of field size versus size rank, and (2) the log–geometric method uses data binned in field-size classes and the ratios of adjacent bin counts. Simulation experiments were conducted using discovered oil and gas pool-size distributions from four petroleum systems in Alberta, Canada and using Pareto distributions generated by Monte Carlo simulation. The estimates of the shape parameters of the Pareto distributions, calculated by both the tail-truncated and log–geometric methods, generally stabilize where discovered pool numbers are greater than 100. However, with fewer than 100 discoveries, these estimates can vary greatly with each new discovery. The estimated shape parameters of the tail-truncated method are more stable and larger than those of the log–geometric method where the number of discovered pools is more than 100. Both methods, however, tend to underestimate the shape parameter. Monte Carlo simulation was also used to create sequences of discovered pool sizes by sampling from a Pareto distribution with a discovery process model using a defined exploration efficiency (in order to show how biased the sampling was in favor of larger fields being discovered first). A higher (more biased) exploration efficiency gives better estimates of the Pareto shape parameters.

Mathematical Geosciences↗

The use of U.S. Geological Survey CD-ROM-based petroleum assessments in undergraduate geology laboratories

Domestic oil production is declining and United States reliance on imported oil is increasing. America will be faced with difficult decisions that address the strategic, economic, and political consequences of its energy resources shortage. The geologically literate undergraduate student needs to be aware of current and future United States energy issues. The U.S. Geological Survey periodically provides energy assessment data via digitally-formatted CD-ROM publications. These publications are free to the public, and are well suited for use in undergraduate geology curricula. The U.S. Geological Survey (USGS) 1995 National Assessment of United States Oil and Gas Resources (Digital Data Series or DDS-30) (Gautier and others, 1996) is an excellent resource for introducing students to the strategies of hydrocarbon exploration and for developing skills in problem-solving and evaluating real data. This paper introduces the reader to DDS-30, summarizes the essential terminology and methodology of hydrocarbon assessment, and offers examples of exercises or questions that might be used in the introductory classroom. The USGS contact point for obtaining DDS-30 and other digital assessment volumes is also provided. Completing the sample exercises in this report requires a copy of DDS-30.

Journal of Geoscience Education↗

Use of XML and Java for collaborative petroleum reservoir modeling on the Internet

The GEMINI (Geo-Engineering Modeling through INternet Informatics) is a public-domain, web-based freeware that is made up of an integrated suite of 14 Java-based software tools to accomplish on-line, real-time geologic and engineering reservoir modeling. GEMINI facilitates distant collaborations for small company and academic clients, negotiating analyses of both single and multiple wells. The system operates on a single server and an enterprise database. External data sets must be uploaded into this database. Feedback from GEMINI users provided the impetus to develop Stand Alone Web Start Applications of GEMINI modules that reside in and operate from the user's PC. In this version, the GEMINI modules run as applets, which may reside in local user PCs, on the server, or Java Web Start. In this enhanced version, XML-based data handling procedures are used to access data from remote and local databases and save results for later access and analyses. The XML data handling process also integrates different stand-alone GEMINI modules enabling the user(s) to access multiple databases. It provides flexibility to the user to customize analytical approach, database location, and level of collaboration. An example integrated field-study using GEMINI modules and Stand Alone Web Start Applications is provided to demonstrate the versatile applicability of this freeware for cost-effective reservoir modeling. ?? 2005 Elsevier Ltd. All rights reserved.

Computers & Geosciences↗

A microcomputer program for energy assessment and aggregation using the triangular probability distribution

A general risk-analysis method was developed for petroleum-resource assessment and other applications. The triangular probability distribution is used as a model with an analytic aggregation methodology based on probability theory rather than Monte-Carlo simulation. Among the advantages of the analytic method are its computational speed and flexibility, and the saving of time and cost on a microcomputer. The input into the model consists of a set of components (e.g. geologic provinces) and, for each component, three potential resource estimates: minimum, most likely (mode), and maximum. Assuming a triangular probability distribution, the mean, standard deviation, and seven fractiles (F100, F95, F75, F50, F25, F5, and F0) are computed for each component, where for example, the probability of more than F95 is equal to 0.95. The components are aggregated by combining the means, standard deviations, and respective fractiles under three possible siutations (1) perfect positive correlation, (2) complete independence, and (3) any degree of dependence between these two polar situations. A package of computer programs named the TRIAGG system was written in the Turbo Pascal 4.0 language for performing the analytic probabilistic methodology. The system consists of a program for processing triangular probability distribution assessments and aggregations, and a separate aggregation routine for aggregating aggregations. The user's documentation and program diskette of the TRIAGG system are available from USGS Open File Services. TRIAGG requires an IBM-PC/XT/AT compatible microcomputer with 256kbyte of main memory, MS-DOS 3.1 or later, either two diskette drives or a fixed disk, and a 132 column printer. A graphics adapter and color display are optional. ?? 1991.

Computers & Geosciences↗

Environmental impacts of oil production on soil, bedrock, and vegetation at the U.S. Geological Survey Osage-Skiatook Petroleum Environmental Research site A, Osage County, Oklahoma

The U.S. Geological Survey is investigating the impacts of oil and gas production on soils, groundwater, surface water, and ecosystems in the United States. Two sites in northeastern Oklahoma (sites A and B) are presently being investigated under the Osage–Skiatook Petroleum Environmental Research project. Oil wells on the lease surrounding site A in Osage County, Oklahoma, produced about 100,000 bbl of oil between 1913 and 1981. Prominent production features on the 1.5-ha (3.7-ac) site A include a tank battery, an oil-filled trench, pipelines, storage pits for both produced water and oil, and an old power unit. Site activities and historic releases have left open areas in the local oak forest adjacent to these features and a deeply eroded salt scar downslope from the pits that extends to nearby Skiatook Lake. The site is underlain by surficial sediments comprised of very fine-grained eolian sand and colluvium as much as 1.4 m (4.6 ft) thick, which, in turn, overlie flat-lying, fractured bedrock comprised of sandstone, clayey sandstone, mudstone, and shale. A geophysical survey of ground conductance and concentration measurements of aqueous extracts (1:1 by weight) of core samples taken in the salt scar and adjacent areas indicate that unusual concentrations of NaCl-rich salt are present at depths to at least 8 m (26 ft) in the bedrock; however, little salt occurs in the eolian sand. Historic aerial photographs, anecdotal reports from oil-lease operators, and tree-ring records indicate that the surrounding oak forest was largely established after 1935 and thus postdates the majority of surface damage at the site. Blackjack oaks adjacent to the salt scar have anomalously elevated chloride ( 400 ppm) in their leaves and record the presence of NaCl-rich salt or salty water in the shallow subsurface. The geophysical measurements also indicate moderately elevated conductance beneath the oak forest adjoining the salt scar.

Oklahoma↗