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Relations between sinkhole density and anthropogenic contaminants in selected carbonate aquifers in the eastern United States

The relation between sinkhole density and water quality was investigated in seven selected carbonate aquifers in the eastern United States. Sinkhole density for these aquifers was grouped into high (>25 sinkholes/100 km 2 ), medium (1–25 sinkholes/100 km 2 ), or low (<1 sinkhole/100 km 2 ) categories using a geographical information system that included four independent databases covering parts of Alabama, Florida, Missouri, Pennsylvania, and Tennessee. Field measurements and concentrations of major ions, nitrate, and selected pesticides in samples from 451 wells and 70 springs were included in the water-quality database. Data were collected as a part of the US Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program. Areas with high and medium sinkhole density had the greatest well depths and depths to water, the lowest concentrations of total dissolved solids and bicarbonate, the highest concentrations of dissolved oxygen, and the lowest partial pressure of CO 2 compared to areas with low sinkhole density. These chemical indicators are consistent conceptually with a conduit-flow-dominated system in areas with a high density of sinkholes and a diffuse-flow-dominated system in areas with a low density of sinkholes. Higher cave density and spring discharge in Pennsylvania also support the concept that the high sinkhole density areas are dominated by conduit-flow systems. Concentrations of nitrate-N were significantly higher ( p < 0.05) in areas with high and medium sinkhole density than in low sinkhole-density areas; when accounting for the variations in land use near the sampling sites, the high sinkhole-density area still had higher concentrations of nitrate-N than the low sinkhole-density area. Detection frequencies of atrazine, simazine, metolachlor, prometon, and the atrazine degradate deethylatrazine indicated a pattern similar to nitrate; highest pesticide detections were associated with high sinkhole-density areas. These patterns generally persisted when analyzing the detection frequency by land-use groups, particularly for agricultural land-use areas where pesticide use would be expected to be higher and more uniform areally compared to urban and forested areas. Although areas with agricultural land use and a high sinkhole density were most vulnerable (median nitrate-N concentration was 3.7 mg/L, 11% of samples exceeded 10 mg/L, and had the highest frequencies of pesticide detection), areas with agricultural land use and low sinkhole density still were vulnerable to contamination (median nitrate-N concentration was 1.5 mg/L, 8% of samples exceeded 10 mg/L, and had some of the highest frequencies of detections of pesticides). This may be due in part to incomplete or missing data regarding karst features (such as buried sinkholes, low-permeability material in bottom of sinkholes) that do not show up at the scales used for regional mapping and to inconsistent methods among states in karst feature delineation.

Missouri

Development of flood-inundation maps for the West Branch Susquehanna River near the Borough of Jersey Shore, Lycoming County, Pennsylvania

Streamflow data, water-surface-elevation profiles derived from a Hydrologic Engineering Center River Analysis System hydraulic model, and geographical information system digital elevation models were used to develop a set of 18 flood-inundation maps for an approximately 5-mile reach of the West Branch Susquehanna River near the Borough of Jersey Shore, Pa. The inundation maps were created by the U.S. Geological Survey in cooperation with the Susquehanna River Basin Commission and Lycoming County as part of an ongoing effort by the National Oceanic and Atmospheric Administration's National Weather Service to focus on continued improvements to the flood forecasting and warning abilities in the Susquehanna River Basin and to modernize flood-forecasting methodologies. The maps, ranging from 23.0 to 40.0 feet in 1-foot increments, correspond to river stage at the U.S. Geological Survey streamgage 01549760 at Jersey Shore. The electronic files used to develop the maps were provided to the National Weather Service for incorporation into their Advanced Hydrologic Prediction Service website. The maps are displayed on this website, which serves as a web-based floodwarning system, and can be used to identify areas of predicted flood inundation associated with forecasted flood-peak stages. During times of flooding or predicted flooding, these maps can be used by emergency managers and the public to take proactive steps to protect life and reduce property damage caused by floods.

Pennsylvania

Assessment of severity and distribution of corrosive ground water in Pennsylvania

Relations between corrosive ground water, water chemistry, and geology in Pennsylvania were evaluated by use of a modified version of the Langelier Saturation Index (LSIsn) and a geologic contact dataset in a Geographic Information System. Water-chemistry information for water samples collected from 4,839 combined private and public-supply wells from 1900 to 1993 was used to calculate the LSIsn. Thirty-eight lithologic subgroups within four major rock types-carbonate, siliciclastic, crystalline, and unconsolidated-in Pennsylvania were grouped together if the mean of ranked LSIsn values were not significantly different. A water is considered corrosive if the LSIsn value is negative, preventing the precipitation of calcium carbonate, therefore, allowing corrosive reactions with the interior of piping systems. Statistical tests of the LSIsn values show the least corrosive waters are in the carbonate lithologic subgroup, and the most corrosive waters are in the quartzite lithologic subgroup. Approximately 58 percent of the 4,839 LSIsn values were considered moderately to extremely corrosive. A map showing the location of 4,839 wells and associated corrosivity range within 11 lithologic subgroups will aid in identifying potential areas of corrosive ground water in Pennsylvania.

Open-File Report

Systematic variation in evapotranspiration trends and drivers across the Northeastern United States

The direction and magnitude of responses of evapotranspiration (ET) to climate change are important to understand, as ET represents a major water and energy flux from terrestrial ecosystems, with consequences that feed back to the climate system. We inferred multidecadal trends in water balance in 11 river basins (1940–2012) and eight smaller watersheds (with records ranging from 18 to 61 years in length) in the Northeastern United States. Trends in river basin actual ET (AET) varied across the region, with an apparent latitudinal pattern: AET increased in the cooler northern part of the region (Maine) but decreased in some warmer regions to the southwest (Pennsylvania–Ohio). Of the four small watersheds with records longer than 45 years, two fit this geographic pattern in AET trends. The differential effects of the warming climate on AET across the region may indicate different mechanisms of change in more‐ vs. less‐energy‐limited watersheds, even though annual precipitation greatly exceeds potential ET across the entire region. Correlations between AET and time series of temperature and precipitation also indicate differences in limiting factors for AET across the Northeastern U.S. climate gradient. At many sites across the climate gradient, water‐year AET correlated with summer precipitation, implying that water limitation is at least transiently important in some years, whereas correlations with temperature indices were more prominent in northern than southern sites within the region.

Hydrological Processes

Water budgets and groundwater volumes for abandoned underground mines in the Western Middle Anthracite Coalfield, Schuylkill, Columbia, and Northumberland Counties, Pennsylvania: Preliminary estimates with identification of data needs

This report, prepared in cooperation with the Pennsylvania Department of Environmental Protection (PaDEP), the Eastern Pennsylvania Coalition for Abandoned Mine Reclamation, and the Dauphin County Conservation District, provides estimates of water budgets and groundwater volumes stored in abandoned underground mines in the Western Middle Anthracite Coalfield, which encompasses an area of 120 square miles in eastern Pennsylvania. The estimates are based on preliminary simulations using a groundwater-flow model and an associated geographic information system that integrates data on the mining features, hydrogeology, and streamflow in the study area. The Mahanoy and Shamokin Creek Basins were the focus of the study because these basins exhibit extensive hydrologic effects and water-quality degradation from the abandoned mines in their headwaters in the Western Middle Anthracite Coalfield. Proposed groundwater withdrawals from the flooded parts of the mines and stream-channel modifications in selected areas have the potential for altering the distribution of groundwater and the interaction between the groundwater and streams in the area. Preliminary three-dimensional, steady-state simulations of groundwater flow by the use of MODFLOW are presented to summarize information on the exchange of groundwater among adjacent mines and to help guide the management of ongoing data collection, reclamation activities, and water-use planning. The conceptual model includes high-permeability mine voids that are connected vertically and horizontally within multicolliery units (MCUs). MCUs were identified on the basis of mine maps, locations of mine discharges, and groundwater levels in the mines measured by PaDEP. The locations and integrity of mine barriers were determined from mine maps and groundwater levels. The permeability of intact barriers is low, reflecting the hydraulic characteristics of unmined host rock and coal. A steady-state model was calibrated to measured groundwater levels and stream base flow, the latter at many locations composed primarily of discharge from mines. Automatic parameter estimation used MODFLOW-2000 with manual adjustments to constrain parameter values to realistic ranges. The calibrated model supports the conceptual model of high-permeability MCUs separated by low-permeability barriers and streamflow losses and gains associated with mine infiltration and discharge. The simulated groundwater levels illustrate low groundwater gradients within an MCU and abrupt changes in water levels between MCUs. The preliminary model results indicate that the primary result of increased pumping from the mine would be reduced discharge from the mine to streams near the pumping wells. The intact barriers limit the spatial extent of mine dewatering. Considering the simulated groundwater levels, depth of mining, and assumed bulk porosity of 11 or 40 percent for the mined seams, the water volume in storage in the mines of the Western Middle Anthracite Coalfield was estimated to range from 60 to 220 billion gallons, respectively. Details of the groundwater-level distribution and the rates of some mine discharges are not simulated well using the preliminary model. Use of the model results should be limited to evaluation of the conceptual model and its simulation using porous-media flow methods, overall water budgets for the Western Middle Anthracite Coalfield, and approximate storage volumes. Model results should not be considered accurate for detailed simulation of flow within a single MCU or individual flooded mine. Although improvements in the model calibration were possible by introducing spatial variability in permeability parameters and adjusting barrier properties, more detailed parameterizations have increased uncertainty because of the limited data set. The preliminary identification of data needs includes continuous streamflow, mine discharge rate, and groundwater levels in the mines and adjacent areas. Data collected whe

Pennsylvania

Simulation of Runoff and Reservoir Inflow for Use in a Flood-Analysis Model for the Delaware River, Pennsylvania, New Jersey, and New York, 2004-2006

A model was developed to simulate inflow to reservoirs and watershed runoff to streams during three high-flow events between September 2004 and June 2006 for the main-stem subbasin of the Delaware River draining to Trenton, N.J. The model software is a modified version of the U.S. Geological Survey (USGS) Precipitation-Runoff Modeling System (PRMS), a modular, physically based, distributed-parameter modeling system developed to evaluate the impacts of various combinations of precipitation, climate, and land use on surface-water runoff and general basin hydrology. The PRMS model simulates time periods associated with main-stem flooding that occurred in September 2004, April 2005, and June 2006 and uses both daily and hourly time steps. Output from the PRMS model was formatted for use as inflows to a separately documented reservoir and riverrouting model, the HEC-ResSim model, developed by the U.S. Army Corps of Engineers Hydrologic Engineering Center to evaluate flooding. The models were integrated through a graphical user interface. The study area is the 6,780 square-mile watershed of the Delaware River in the states of Pennsylvania, New Jersey, and New York that drains to Trenton, N.J. A geospatial database was created for use with a geographic information system to assist model discretization, determine land-surface characterization, and estimate model parameters. The USGS National Elevation Dataset at 100-meter resolution, a Digital Elevation Model (DEM), was used for model discretization into streams and hydrologic response units. In addition, geospatial processing was used to estimate initial model parameters from the DEM and other data layers, including land use. The model discretization represents the study area using 869 hydrologic response units and 452 stream segments. The model climate data for point stations were obtained from multiple sources. These sources included daily data for 22 National Weather Service (NWS) Cooperative Climate Station network stations, hourly data for 15 stations from the National Climatic Data Center, hourly data for 1 station from the NWS Middle Atlantic River Forecast Center records, and daily and hourly data for 7 stations operated by the New York City Department of Environmental Protection. The NWS Multisensor Precipitation Estimate data set for 2001-2007 was used for computing daily precipitation for the model and for computing hourly precipitation for storm simulation periods. Calibration of the PRMS model included regression and optimization algorithms, as well as manual adjustments of model parameters. The general goal of the calibration procedure was to minimize the difference between discharge measured at USGS streamgages and the corresponding discharge simulated by the model. Daily streamflow data from 35 USGS streamgages were used in model calibration. The streamflow data represent areas draining from 20.2 to 6,780 square miles. The PRMS model simulates reservoir inflow and watershed runoff for use as input into HECResSim for the purpose of evaluating and comparing the effects of different watershed conditions on main-stem flooding in the Delaware River watershed draining to Trenton, N.J. The PRMS model is useful as a planning tool to simulate the effects of land-use changes and different antecedent conditions on local runoff and reservoir inflow and, as input to the HEC-ResSim model, on flood flows in the main stem of the Delaware River.

Open-File Report

Ground-water quality in the Chemung River Basin, New York, 2003

Water samples were collected from 24 public-supply wells and 13 private residential wells during the summer of 2003 and analyzed to describe the chemical quality of ground water throughout the Chemung River basin, upgradient from Waverly, N.Y, on the Pennsylvania border. Wells were selected to represent areas of heaviest ground-water use and greatest vulnerability to contamination, and to obtain a geographical distribution across the 1,130 square-mile basin. Samples were analyzed for physical properties, inorganic constituents, nutrients, metals and radionuclides, pesticides, volatile organic compounds, and bacteria. The cations that were detected in the highest concentrations were calcium and sodium; the anions that were detected in the greatest concentrations were bicarbonate, chloride, and sulfate. The predominant nutrient was nitrate. Nitrate concentrations in samples from wells finished in sand and gravel were greater than in those from wells finished in bedrock, except for one bedrock well, which had the highest nitrate concentration of any sample in this study. The most commonly detected metals were aluminum, barium, iron, manganese, and strontium. The range of tritium concentrations (0.6 to 12.5 tritium units) indicates that the water ages ranged from less than 10 years old to more than 50 years old. All but one of the 15 pesticides detected were herbicides; those detected most frequently were atrazine, deethylatrazine, and two degradation products of metolachlor (metachlor ESA and metachlor OA), which were the pesticides detected at the highest concentrations. Not every sample collected was analyzed for pesticides, and pesticides were detected only in wells finished in sand and gravel. Volatile organic compounds were detected in 15 samples, and the concentrations were at or near the analytical detection limits. Total coliform were detected in 12 samples; fecal coliform were detected in 7 samples; and Escherichia coli was detected in 6 samples. These bacteria were detected in water from bedrock as well as sand-and-gravel aquifers. Federal and State water-quality standards were exceeded in several samples. Two samples exceeded the chloride U.S. Environmental Protection Agency Secondary Maximum Contaminant Level of 250 milligrams per liter. The U.S. Environmental Protection Agency Drinking Water Advisory for sodium (30 to 60 milligrams per liter) was exceeded in 11 samples. The upper limit of the Secondary Maximum Contaminant Level range for aluminum (200 micrograms per liter) was exceeded in one sample. The Maximum Contaminant Level for barium (2,000 micrograms per liter) was exceeded in one sample. The Secondary Maximum Contaminant Level for iron (300 micrograms per liter) was exceeded in 11 samples. The Secondary Maximum Contaminant Level for manganese (50 micrograms per liter) was exceeded in 20 samples. The proposed Maximum Contaminant Level for radon (300 picocuries per liter) was exceeded in 34 samples.

Open-File Report

A comparison of hydrocarbon-related landscape disturbance patterns along the New York-Pennsylvania border, 2004–2013

Executive Summary The New York-Pennsylvania area has a long history of hydrocarbon extraction, and the addition of shale gas extraction methods contributes to landscape disturbance borne by previously developed oil and non-shale gas resources. The main unconventional extraction method used to extract shale gas from the Marcellus Shale located in New York and Pennsylvania is hydraulic fracturing, or “fracking,” although other conventional methods are used extensively. All forms of hydrocarbon extraction disturb the surrounding landscape to some extent, primarily in the form of land clearance and degradation, road construction, and pipeline development, although the effects of these disturbances are not fully understood. In this study, landscape-change metrics and indicators are used to analyze change in a 10-county region along the New York-Pennsylvania border—the New York counties of Allegany, Steuben, Chemung, Tioga, and Broome, and the Pennsylvania counties of McKean, Potter, Tioga, Bradford, and Susquehanna. This 10-county region was selected due to the differences in policies between the States of New York and Pennsylvania. While fracking occurred extensively in Pennsylvania over the past 10 years or more, the State of New York issued a temporary moratorium against hydraulic fracturing in 2010—citing repercussions that might affect air quality, water quality, and public health—and officially banned hydraulic fracturing in June 2015. The quantification of landscape disturbance due to hydrocarbon extraction activities is presented in this report as land-use and land-cover (LULC) change between 2004 and 2013 and defined using specific disturbance categories (including well sites, roads, and pipelines) to compare the disturbances and changes, by county, on both sides of the New York-Pennsylvania border. The quantification was accomplished by gathering the signatures of disturbance from high-resolution aerial images, comparing the derived totals of disturbance, and then computing landscape metrics in a geographic information system (GIS) environment. The collected data represent a summation of landscape disturbance from oil and gas development, as some of the data represented were established decades earlier. The Analytical Tools Interface for Landscape Assessments (ATtILA) software was used to calculate land-cover area and landscape metrics for each shale gas, non-shale gas, oil, and other infrastructure types associated with hydrocarbons across each county and both five-county regions in the study area. The three primary metrics used to describe changes in forest structure were (1)forest area, (2) interior forest area, and (3) forest edge area. The changes in metrics were subsequently evaluated using the Pearson correlation coefficient. Overall, the disturbed-area footprint in the Pennsylvania region is considerably larger than the disturbed-area footprint in the New York region (13,687.9 hectares [ha] in Pennsylvania; 3,840.5 ha in New York). Disturbance per site is similar, with 1.2 disturbed ha per site in New York and 1.6 disturbed ha per site in Pennsylvania. In the New York-Pennsylvania 10-county region, hydrocarbon-development and extraction disturbance strongly correlate with a reduction in the percentage of forest for the entire region. This observation also appears to be true in the New York five-county region for forest area. This form of disturbance in the New York five-county region shows significantly correlated changes in forest metrics (–0.4 percent total forest area), particularly in the percentage of interior forest (–1.2 percent total area) and forest edge (+0.7 percent total area). On the other hand, gas and hydrocarbon-development and extraction disturbance (1.0 percent total area) in the Pennsylvania five-county region strongly correlates with a total decline in forest area and agricultural land area (–0.8 percent combined total area) but not with either land-cover class separately.

New York, Pennsylvania

Geologic cross section A–A′ through the Appalachian basin from the southern margin of the Ontario Lowlands province, Genesee County, western New York, to the Valley and Ridge province, Lycoming County, north-central Pennsylvania

Introduction Geologic cross section A–A′ is the fifth in a series of cross sections constructed by the U.S. Geological Survey (USGS) to document and improve understand­ing of the geologic framework and petroleum systems of the Appalachian basin. Cross section A–A′ provides a regional view of the structural and stratigraphic frame­work of the Appalachian basin from the southern mar­gin of the Ontario Lowlands province in western New York, across the Allegheny Plateau province of central New York and north-central Pennsylvania, to the Valley and Ridge province in north-central Pennsylvania, a dis­tance of approximately 176 miles. This cross section is a companion to cross sections E–E′, D–D′, C–C′ , and I–I′ that are located approximately 100 to 500 miles to the southwest. Cross section A–A′ complements earlier geologic or strati­graphic cross sections through the central New York and north-central Pennsylvania part of the Appalachian basin. Although some of these other cross sections show more structural and stratigraphic detail, they are of more limited extent geographically and stratigraphically. Cross section A–A′ contains much information that is useful for evaluating energy resources in the Appalachian basin. Although the Appalachian basin petroleum systems are not shown on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Important oil- and gas-bearing formations like the Oriskany Sandstone, Medina Group sandstones, Tuscarora Sandstone, and the Marcellus and Utica Shales are present on cross-section A–A′ .

New York, Pennsylvania

Evaluation of airborne thermal infrared imagery for locating mine drainage sites in the Lower Youghiogheny River Basin, Pennsylvania, USA

Nighttime high-resolution airborne thermal infrared imagery (TIR) data were collected in the predawn hours during Feb 5-8 and March 11-12, 1999, from a helicopter platform for 72.4 km of the Youghiogheny River, from Connellsville to McKeesport, in southwestern Pennsylvania. The TIR data were used to identify sources of mine drainage from abandoned mines that discharge directly into the Youghiogheny River. Image-processing and geographic information systems (GIS) techniques were used to identify 70 sites within the study area as possible mine drainage sources. The combination of GIS datasets and the airborne TIR data provided a fast and accurate method to target the possible sources. After field reconnaissance, it was determined that 24 of the 70 sites were mine drainage. This paper summarizes: the procedures used to process the TIR data and extract potential mine-drainage sites; methods used for verification of the TIR data; a discussion of factors affecting the TIR data; and a brief summary of water quality.

Pennsylvania

Benefits and limitations of installing driving surface aggregate at two federal lands sites

The worldwide network of unpaved roads is estimated to include at least 14 million km (8.7 million miles; 1). Although they are vital for local communities, these roads are expensive to maintain and may cause environmental damage through sediment and dust pollution (e.g., 2). Among aggregate-surfaced roads, locally available materials are often used as a surface wearing course, with little or no testing and sometimes no formal specification. The materials vary widely in quality and may deteriorate quickly. As a result, road managers may be forced to increase the frequency of maintenance grading and aggregate replacement to compensate for the poor performance. Improving the quality of surface aggregate on unpaved roads is one strategy for increasing road performance while also reducing environmental impacts. Although higher-quality aggregates require greater up-front investment, they can result in lower overall life-cycle costs by extending road life and reducing maintenance costs. Driving Surface Aggregate (DSA) is an aggregate specification developed by the Pennsylvania State University Center for Dirt and Gravel Road Studies that is designed to achieve maximum compaction and resist erosion. The gradation of DSA, coupled with recommended optimum moisture and placement guidelines, results in a smoother, more tightly bound surface that preserves fine material rather than allowing it to escape as sediment or dust. In previous studies, DSA has been shown to reduce sediment runoff by 80-90% (3) and dust production by up to 90% (4) compared to existing road surface gradations. Although DSA has been used extensively in the state of Pennsylvania, USA, the specification is almost unknown elsewhere. The objective of this study was to demonstrate the benefits and limitations of DSA when deployed across a wider geographic area. We installed road sections of DSA at two federal lands sites in the eastern United States. Sediment runoff, dust production, and road surface condition on these sections were measured approximately 12 months post-construction. At both sites, DSA reduced sediment runoff by up to 91%, relative to traditional aggregates. At one site in Indiana, DSA also reduced dust production and aggregate loss. At the other site in Vermont, DSA and traditional aggregate sections performed similarly in dust production and road condition. Overall, this study 1) demonstrates that DSA can be an effective and environmentally responsible aggregate choice for unpaved roads, and 2) provides information on site conditions (e.g., roads near headwater streams) under which DSA is likely to be particularly beneficial.

Indiana, Vermont

Nitrate in ground water in the Great Valley carbonate subunit of the Potomac River Basin

Agriculture is the major land use in the carbonate part of the Great Valley of the Potomac River Basin. Applied fertilizer and manure are potential sources of nitrate that can contaminate Groundwater. Nitrate concentrations in Groundwater increased with increasing percentage of cropland but did not decrease with increasing well depth, as has been found in previous studies elsewhere. Samples from 28 wells contained nitrate concentrations ranging from 0.29 to 29 mg/L (milligrams per liter) as nitrogen, with a median concentration of 4.55 mg/L, compared to a median of 1.8 mg/L for 1,056 Groundwater samples from the entire Potomac River Basin. Median nitrate concentrations in Groundwater samples were higher in the Maryland, Pennsylvania, and West Virginia part of the valley, and were lower in the Virginia part (7.45 and 2.95 mg/L, respectively), probably as a result of differences in agricultural land-use patterns; this geographical difference was also noted in surface-water samples (6.65 and 2.3 mg/L, respectively). The area of contribution to each well could not be delineated by surface topography or distance to the well, because Groundwater flow and nitrate transport can be unpredictable in the carbonate region because of fractures and solution channels present.

Water-Resources Investigations Report

Sequence stratigraphy and a revised sea-level curve for the Middle Devonian of eastern North America

The well-exposed Middle Devonian rocks of the Appalachian foreland basin (Onondaga Formation; Hamilton Group, Tully Formation, and the Genesee Group of New York State) preserve one of the most detailed records of high-order sea-level oscillation cycles for this time period in the world. Detailed examination of coeval units in distal areas of the Appalachian Basin, as well as portions of the Michigan and Illinois basins, has revealed that the pattern of high-order sea-level oscillations documented in the New York–Pennsylvania section can be positively identified in all areas of eastern North America where coeval units are preserved. The persistence of the pattern of high-order sea-level cycles across such a wide geographic area suggests that these cycles are allocyclic in nature with primary control on deposition being eustatic sea-level oscillation, as opposed to autocylic controls, such as sediment supply, which would be more local in their manifestation. There is strong evidence from studies of cyclicity and spectral analysis that these cycles are also related to Milankovitch orbital variations, with the short and long-term eccentricity cycles (100 kyr and 405 kyr) being the dominant oscillations in many settings. Relative sea-level oscillations of tens of meters are likely and raise considerable issues about the driving mechanism, given that the Middle Devonian appears to record a greenhouse phase of Phanerozoic history. These new correlations lend strong support to a revised high-resolution sea-level oscillation curve for the Middle Devonian for the eastern portion of North America. Recognized third-order sequences are: Eif-1 lower Onondaga Formation, Eif-2: upper Onondaga and Union Springs formations; Eif–Giv: Oatka Creek Formation; Giv-1: Skaneateles, Giv-2: Ludlowville, Giv-3: lower Moscow, Giv-4: upper Moscow–lower Tully, and Giv-5: middle Tully–Geneseo formations. Thus, in contrast with the widely cited eustatic curve of Johnson et al. (1985), which recognizes just one major transgressive–regressive (T–R) cycle in the early–mid Givetian (If) prior to the major late Givetian Taghanic unconformity (IIa, upper Tully–Geneseo Shale), we recognize four T–R cycles: If (restricted), Ig, Ih, and Ii. We surmise that third-order sequences record eustatic sea-level fluctuations of tens of meters with periodicities of 0.8–2 myr, while their medial-scale (fourth-order) subdivisions record lesser variations primarily of 405 kyr duration (long-term eccentricity). This high-resolution record of sea-level change provides strong evidence for high-order eustatic cycles with probable Milankovitch periodicities, despite the fact that no direct evidence for Middle Devonian glacial sediments has been found to date.

Wisconsin, Illinois, Michigan, Indiana, Kentucky,

Bathymetric Surveys of Lake Arthur and Raccoon Lake, Pennsylvania, June 2007

In spring of 2007, bathymetric surveys of two Pennsylvania State Park lakes were performed to collect accurate data sets of lake-bed elevations and to develop methods and techniques to conduct similar surveys across the state. The lake-bed elevations and associated geographical position data can be merged with land-surface elevations acquired through Light Detection and Ranging (LIDAR) techniques. Lake Arthur in Butler County and Raccoon Lake in Beaver County were selected for this initial data-collection activity. In order to establish accurate water-surface elevations during the surveys, benchmarks referenced to NAVD 88 were established on land at each lake by use of differential global positioning system (DGPS) surveys. Bathymetric data were collected using a single beam, 210 kilohertz (kHz) echo sounder and were coupled with the DGPS position data utilizing a computer software package. Transects of depth data were acquired at predetermined intervals on each lake, and the shoreline was delineated using a laser range finder and compass module. Final X, Y, Z coordinates of the geographic positions and lake-bed elevations were referenced to NAD 83 and NAVD 88 and are available to create bathymetric maps of the lakes.

Data Series

Methodology for Estimation of Flood Magnitude and Frequency for New Jersey Streams

Methodologies were developed for estimating flood magnitudes at the 2-, 5-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals for unregulated or slightly regulated streams in New Jersey. Regression equations that incorporate basin characteristics were developed to estimate flood magnitude and frequency for streams throughout the State by use of a generalized least squares regression analysis. Relations between flood-frequency estimates based on streamflow-gaging-station discharge and basin characteristics were determined by multiple regression analysis, and weighted by effective years of record. The State was divided into five hydrologically similar regions to refine the regression equations. The regression analysis indicated that flood discharge, as determined by the streamflow-gaging-station annual peak flows, is related to the drainage area, main channel slope, percentage of lake and wetland areas in the basin, population density, and the flood-frequency region, at the 95-percent confidence level. The standard errors of estimate for the various recurrence-interval floods ranged from 48.1 to 62.7 percent. Annual-maximum peak flows observed at streamflow-gaging stations through water year 2007 and basin characteristics determined using geographic information system techniques for 254 streamflow-gaging stations were used for the regression analysis. Drainage areas of the streamflow-gaging stations range from 0.18 to 779 mi2. Peak-flow data and basin characteristics for 191 streamflow-gaging stations located in New Jersey were used, along with peak-flow data for stations located in adjoining States, including 25 stations in Pennsylvania, 17 stations in New York, 16 stations in Delaware, and 5 stations in Maryland. Streamflow records for selected stations outside of New Jersey were included in the present study because hydrologic, physiographic, and geologic boundaries commonly extend beyond political boundaries. The StreamStats web application was developed cooperatively by the U.S. Geological Survey and the Environmental Systems Research Institute, Inc., and was designed for national implementation. This web application has been recently implemented for use in New Jersey. This program used in conjunction with a geographic information system provides the computation of values for selected basin characteristics, estimates of flood magnitudes and frequencies, and statistics for stream locations in New Jersey chosen by the user, whether the site is gaged or ungaged.

Scientific Investigations Report

Coking coal of the United States—Modern and historical coking coal mining locations and chemical, rheological, petrographic, and other data from modern samples

Coking coal, or metallurgical coal, has been produced in the United States for nearly 200 years. Coking coal is primarily used in the production of coke for use in the steel industry, and for other uses (for example, foundries, blacksmithing, heating buildings, and brewing). Currently, U.S. coking coal is produced in Alabama, Arkansas, Pennsylvania, Virginia , and West Virginia. Historically, coking coal has also been produced in 15 other states (Alaska, Colorado, Georgia, Illinois, Indiana, Kentucky, Maryland, Montana, New Mexico, Ohio, Oklahoma, Tennessee, Utah, Washington, and Wyoming), but currently is not. Coals from the Appalachian, Arkoma, and Illinois basins are Pennsylvanian in age, while coals in Alaska, Colorado, Montana, New Mexico, Utah, Washington, and Wyoming range in age from Early Cretaceous through Eocene. This Open-File Report presents the geographic locations of current and historical coking coal deposits of the United States, with additional information about recent and historical mining and exploration activities. Chemical, rheological, petrographic, and other criteria for evaluating the coking potential of coals are discussed, and historical data for coking coals in the United States are presented. In addition, new coking coal samples from Alabama, Arkansas, Kentucky, and Oklahoma were collected and analyzed for this report, and the data are presented in multiple tables, including proximate and ultimate analyses; calorific value; sulfur forms; major-, minor-, and trace-element abundances; Free-Swelling Index; Gieseler Plastometer analyses; American Society for Testing and Materials (ASTM) dilatation; coal petrography; and predicted values of Coal Stability Factor and Coal Strength after Reaction with CO 2 (pCSF and pCSR, respectively). Data from previously analyzed coking coal samples in Kentucky, Pennsylvania, Virginia, and West Virginia were supplied by three companies, including results from all the tests listed above, plus oxidation, Hardgrove Grindability Index, and ash fusion (in a reducing environment) temperatures are also presented in tables in the report. Geographic Information System (GIS) data compiled for this project are available for download for public and private utilization and may be used to create maps for a variety of energy resource studies. These GIS data are in shapefile format, and metadata files are included describing all GIS processing. Additional geographic information about coking coal areas of the United States are also presented in tabular format in the report, including the following: names of coal basins, fields, regions, districts, and areas; coal beds or zones; geographic locations including States, counties, towns, rivers, mountains, etc.; stratigraphic hierarchy and age of the coal-bearing interval; coking characteristics including sulfur content, ash yield, volatile matter, moisture, calorific value, and Free-Swelling Index; coal rank; names of coal mines and coal-mining companies; current and past mining activity; and references for reports about the coal.

Open-File Report

Shale gas development has limited effects on stream biology and geochemistry in a gradient-based, multiparameter study in Pennsylvania

The number of horizontally drilled shale oil and gas wells in the United States has increased from nearly 28,000 in 2007 to nearly 127,000 in 2017, and research has suggested the potential for the development of shale resources to affect nearby stream ecosystems. However, the ability to generalize current studies is limited by the small geographic scope as well as limited breadth and integration of measured chemical and biological indicators parameters. This study tested the hypothesis that a quantifiable, significant relationship exists between the density of oil and gas (OG) development, increasing streamwater concentrations of known geochemical tracers of OG extraction, and the composition of benthic macroinvertebrate and microbial communities. 25 headwater streams that drain lands across a gradient of shale gas development intensity were sampled. Our strategy included comprehensive measurements across multiple seasons of sampling to account for temporal variability of geochemical parameters, including known shale OG geochemical tracers, and microbial and benthic macroinvertebrate communities. No significant relationships were found between the intensity of OG development, shale OG geochemical tracers, or benthic macroinvertebrate or microbial community composition, whereas significant seasonal differences in stream chemistry were observed. These results highlight the importance of considering spatial and temporal variability in stream chemistry and biota and not only the presence of anthropogenic activities in a watershed. This comprehensive, integrated study of geochemical and biological variability of headwater streams in watersheds undergoing OG development provides a robust framework for examining the effects of energy development at a regional scale.

Pennsylvania

Seasonal changes in atmospheric noise levels and the annual variation in pigeon homing performance

Repeated releases of experienced homing pigeons from single sites were conducted between 1972 and 1974 near Cornell University in upstate New York and between 1982 and 1983 near the University of Pittsburgh in western Pennsylvania, USA. No annual variation in homing performance was observed at these sites in eastern North America, in contrast to results from a number of similar experiments in Europe. Assuming pigeons home using low-frequency infrasonic signals (~0.1–0.3 Hz), as has been previously proposed, the annual and geographic variability in homing performance within the northern hemisphere might be explained, to a first order, by seasonal changes in low-frequency atmospheric background noise levels related to storm activity in the North Atlantic Ocean, and by acoustic waveguides formed between the surface and seasonally reversing stratospheric winds. In addition, increased dispersion among departure bearings of test birds on some North American release days was possibly caused by infrasonic noise from severe weather events during tornado and Atlantic hurricane seasons.

Journal of Comparative Physiology A