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USGS1964

Chemical quality of surface waters in the Brazos River basin in Texas

The Brazos River basin, which makes up 15 percent of the land area of Texas, extends from the High Plains, where altitudes reach 4,200 feet and the average precipitation ranges from 15 to 20 inches a year, to the Gulf of Mexico where the annual rainfall is 45-^50 inches. Large reservoirs have been built in the Brazos River basin, but the use of the stored water has been limited because the salinity often makes the water undesirable for municipal and industrial use. However, the water is generally satisfactory for irrigation. Records for the Brazos River show that the salinity of the water was a problem even as early as 1906 and that the water more often than not failed to meet today's chemical-quality standards for a municipal supply. The salt load of the Brazos River comes from the entire basin and is the result of solution, accretion of undetermined amounts of oil-field brine, and accretion of brine from springs and seeps such as those in Salt Croton Creek which contribute about 400 tons of chloride a day. Much of the salinity of the Brazos River is due to inflow of brines above Possum Kingdom Dam. The area above Possum Kingdom Dam is about 52 percent of the total area in the Brazos River basin but contributes only about 17 percent of the total runoff; however, about 50 percent of the annual salt load comes from this part of the basin. Quality-of-water records show a wide difference in the salinity of the steams in different parts of the basin, Dissolved-solids concentrations ranged from about 100 ppm (parts per million) for flood water to 300,000 ppm for saturated brines from springs. The quality of the surface water in the Brazos River basin is discussed by areas and by stream reaches. This study indicates that the water of the Salt Fork Brazos River is too saline for most uses. The water of the Double Mountain Fork Brazos River is less saline and might be used for irrigation; however, it probably could not be used as a municipal supply or as a supply for most industries. The water of the dear Fork Brazos River is generally good but is adversely affected by brine pollution. Chemical-quality records for the Lampasas, Leon, and Navasota Rivers indicate that the water of these streams is of excellent quality; however, more data are needed to determine variations. The quality of the water in other tributaries could only be inferred from the results of miscellaneous sampling and from the probable effect of the underlying rocks. The weighted-average concentration of constituents in the Brazos River at Richmond indicated that inflow below Whitney Reservoir has a dilution effect on the river. For 12 of the 14 years of record, the weighted-average dissolved-solids concentration of the Brazos River at Richmond was lessi than, the 500 ppm maximum limit recommended by the U.S. Public Health Service (1961). This study indicates that water stored in Possum Kingdom and Whitney Reservoirs tends to become stratified, with the more saline water being at the greater depths. Samples collected in 1956 at Whitney Reservoir showed that the chloride concentration at the bottom was almost twice that at the surface. After a flood in June 1957, the dissolved-solids concentrations of bottom releases at Possum Kingdom were almost double those of surface releases through the spillway even though the flood volume had been more than twice the capacity of the reservoir. The quality of water in the lower main stem can be improved by control and disposal of brines in the upper basin. Also, the maximum concentrations in the water of the lower main stem can be lowered by dilution with water stored in reservoirs on tributaries that yield water of good quality.

Water Supply Paper↗

USGS2014

Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from < 1 to 100 μg/L, but total PAHs (the dominant compound class for most CBM samples) range from 50 to 100 μg/L. Total dissolved organic carbon (TOC) in CBM produced water is generally in the 1–4 mg/L range. Excursions from this general pattern in produced waters from individual wells arise from contaminants introduced by production activities (oils, grease, adhesives, etc.). Organic substances in produced and formation water from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

International Journal of Coal Geology↗

USGS1975

Impacts of chemicals on waterfowl reproduction and survival

Residues of organochlorine pesticides, PCB's, heavy metals, and other toxic chemicals are ubiquitous in the biosphere and are commonly found in tissues and eggs of wild birds. This paper reviews research on the effects of these chemicals, with particular reference to waterfowl. Extensive mortality of waterfowl has occurred in the Gulf Coast region as a result of ingestion of aldrin-treated rice seed. Populations of fulvous tree ducks (Dendrocygna bicolor) have declined in recent years in that area. DDE impaired reproduction of both mallards (Anas platyrhynchos) and black ducks (Arias rubripes) in experimental studies, resulting in thin shells, cracked eggs, and poor hatching success. Eggs incubated by the hens broke and cracked more frequently than those in incubators. In the field, residues are higher in ducks that feed on animal material than in vegetarians; differences are pronounced both geographically and among species. Mercury at levels that occur in certain heavily polluted areas in the United States and Canada has, in experimental studies, lowered the reproductive success of mallards and black ducks and reduced the survival of ducklings. Oil spills have killed many waterfowl as a result of oiled feathers and the intake of oil and more indirect physiological effects have been shown experimentally. Pollutants may affect waterfowl indirectly by changing the habitat and directly as a result of intake of toxic substances. They are unlikely to have been directly limiting factors in populations of such species as mallards. Their involvement with problem of other species, including canvasbacks (Aythya valisineria) and mergansers has still to be explored.

International Waterfowl Symposium↗

USGS1997

Characterization of stormwater runoff from the Naval Air Station and Naval Wepons Industrial Reserve Plant, Dallas, Texas, 1994-96

The characterization of stormwater runoff from the Naval Air Station (NAS) and the Naval Weapons Industrial Reserve Plant (NWIRP), Dallas, Texas, is necessary to determine if runoff from the facilities is contributing to off-site contamination of surface waters, A network of five fixed sites and four grab sites was established to collect stormwater-runoff samples from a substantial part of the drainage area of each facility. Fixed sites were instrumented to measure and store precipitation, stage, discharge, and runoff-volume data and to collect flow-weighted composite samples during a storm. Grab and composite samples were collected for six storms at each of the five fixed sites from October 1994 to March 1996. The grab samples were analyzed for about 100 properties and constituents including specific conductance, pH, water temperature, bacteria, trace elements, oil and grease, total phenols, and volatile organic compounds. The composite samples were analyzed for about 220 properties and constituents including specific conductance, pH, chemical oxygen demand, biochemical oxygen demand, major ions, suspended and dissolved solids, nutrients, trace elements, total organic carbon, volatile organic compounds, semivolatile organic compounds, and organochlorine and organophosphorus pesticides. Grab samples were collected for two storms (September 18,1995, and October 2,1995) at each of the four grab sites. The grab samples were analyzed for about 80 constituents including specific conductance, pH, water temperature, trace elements, and volatile organic compounds. Composite samples were collected for two of the six storms sampled at the fixed sites and analyzed for aquatic toxicity. Fathead minnow growth and survival toxicity tests and water flea reproduction and survival toxicity tests were done. Median event-mean concentrations computed for 12 selected constituents in samples from NAS and NWIRP fixed sites were compared to median event-mean concentrations for residential, commercial, industrial, and highway land uses within the Dallas-Fort Worth area computed from data collected for the National Pollutant Discharge Elimination System program. NAS and NWIRP median event-mean concentrations also were compared to those for residential and commercial land uses from the Nationwide Urban Runoff Program.

Open-File Report↗

USGS1982

Embryotoxic and biochemical effects of waste crankcase oil on birds' eggs

Waste crankcase oil (WCO) is a major source of oil pollution in both the aquatic and terrestrial environment and has been implicated in the poisoning of mammals and fish. It is also mutagenic. Since birds' eggs are highly sensitive to external microliter applications of environmentally polluting oils, we examined the developmental effects of external applications of WCO on eggs of the mallard duck (Anas platyrhynchos) and the bobwhite quail (Colinus virginianus). At 48 hr of development, mallard eggs were exposed externally to 2, 5, or 15 :l of WCO or 15 :l of clean crankcase oil (CCO) while bobwhite eggs received proportional doses of 0.5, 1, or 3 :l of WCO and 3 :l of CCO in a similar manner. WCO was highly embryotoxic to both species compared to CCO and resulted in dose-dependent mortality, reduced growth, and abnormal survivors. Application of 15 :l WCO resulted in 84% mortality in mallards and 3 :l WCO resulted in 88% mortality in bobwhites. Abnormal survivors included embryos with subcutaneous edema, incomplete ossification, and eye and brain defects. Red blood cell *-aminolevulinic acid dehydratase (ALAD) activity, liver ALAD activity, and hemoglobin concentration were significantly lower after treatment with WCO in embryos and hatchlings of both species. Plasma uric acid, plasma alanine aminotransferase (ALT), and plasma aspartate aminotransferese (AST) were significantly elevated in WCO-treated mallards after hatching. Biochemical effects, growth retardation, and mortality at proportionally lower dose levels were more pronounced in mallards than in bobwhites. Chemical analysis of the WCO and CCO revealed a considerably higher content of aromatic hydrocarbons in WCO than in CCO. Lead levels were highly elevated in WCO (4600 ppm) compared to CCO (2 ppm).

Toxicology and Applied Pharmacology↗

USGS2001

Use of radium isotopes to determine the age and origin of radioactive barite at oil-field production sites

Radium-bearing barite (radiobarite) is a common constituent of scale and sludge deposits that form in oil-field production equipment. The barite forms as a precipitate from radium-bearing, saline formation water that is pumped to the surface along with oil. Radioactivity levels in some oil-field equipment and in soils contaminated by scale and sludge can be sufficiently high to pose a potential health threat. Accurate determinations of radium isotopes (226Ra+228Ra) in soils are required to establish the level of soil contamination and the volume of soil that may exceed regulatory limits for total radium content. In this study the radium isotopic data are used to provide estimates of the age of formation of the radiobarite contaminant. Age estimates require that highly insoluble radiobarite approximates a chemically closed system from the time of its formation. Age estimates are based on the decay of short-lived 228Ra (half-life=5.76 years) compared to 226Ra (half-life=1600 years). Present activity ratios of 228Ra/226Ra in radiobarite-rich scale or highly contaminated soil are compared to initial ratios at the time of radiobarite precipitation. Initial ratios are estimated by measurements of saline water or recent barite precipitates at the site or by considering a range of probable initial ratios based on reported values in modern oil-field brines. At sites that contain two distinct radiobarite sources of different age, the soils containing mixtures of sources can be identified, and mixing proportions quantified using radium concentration and isotopic data. These uses of radium isotope data provide more description of contamination history and can possibly address liability issues. Copyright ?? 2000 .

Environmental Pollution↗

USGS1976

Saline water in the Little Arkansas River Basin area, south-central Kansas

Ground water in unconsolidated deposits of Pleistocene age in part of the Little Arkansas River basin has been polluted by the influx of saline water. The source of the saline water generally is oil-field brine that leaked from disposal ponds on the land surface. Locally, pollution by saline water also has been caused by upwelling of oil-field brine injected under pressure into the "lost-circulation zone" of the Lower Permian Wellington Formation and, possibly, by leakage of brine from corroded or improperly cased disposal wells. Anomalously high concentrations of chloride ion in some reaches of the Little Arkansas River probably can be attributed to pollution by municipal wastes rather than from inflow of saline ground water. Hydraulic connection exists between the "lost-circulation zone" and unconsolidated deposits, as evidenced by the continuing development of sinkholes, by the continuing discharge of saline water through springs and seeps along the Arkansas River south of the Little Arkansas River basin and by changes in the chloride concentration in water pumped from wells in the "lost-circulation zone." The hydraulic head in the "lost-circulation zone" is below the base of the unconsolidated deposits, and much below the potentiometric surface of the aquifer in those deposits. Any movement of water, therefore, would be downward from the "fresh-water" aquifer to the saline "lost-circulation zone."

Kansas↗

USGS2019

Early life exposure to triphenyl phosphate: Effects on thyroid function, growth, and resting metabolic rate of Japanese quail (Coturnix japonica) chicks

Triphenyl phosphate (TPHP; CAS # 115-86-6), a commonly used plasticizer and flame retardant, has been reported in wild birds and identified as a potential high-risk chemical. We exposed Japanese quail ( Coturnix japonica ) by in ovo injection, and once hatched, orally each day for 5 days to safflower oil (controls) or TPHP dissolved in vehicle at low (5 ng TPHP/g), mid (50 ng TPHP/g), or high (100 ng TPHP/g) nominal TPHP doses. The low TPHP dose reflected concentrations in wild bird eggs, with mid and high doses 10x and 20x greater to reflect potential increases in environmental TPHP concentrations in the future. Despite no effects on mRNA expression in thyroid-related genes, TPHP exposure enhanced thyroid gland structure in high TPHP males, but in females, suppressed thyroid gland structure and activity (all TPHP females), and circulating free triiodothyronine (high TPHP females only). Consistent with thyroidal changes, and compared to controls, mid and high TPHP chicks experienced significantly reduced resting metabolic rate (≤13%) and growth (≤53%); mid TPHP males and high TPHP females were significantly smaller. The observed thyroidal effects and suppressed growth and metabolic rate of the quail chicks suggest that TPHP may adversely affect the health of wild birds.

Environmental Pollution↗

USGS2025

Refining PAH and PCB bioavailability predictions in industrial sediments using source-fingerprinting, particle size, and bulk carbon, Puget Sound, Washington

Nearshore marine sediments in a Puget Sound, Washington industrial embayment had elevated levels of PAHs, PCBs and DDTs. Chemical fingerprints implicated nearshore sources including creosote, industrial oil and tar waste, and a landfill. Elevated concentrations were confined to an approximate 300-m shoreline buffer in the industrial waterfront, suggesting high site fidelity and limited along-shore or off-shore transport. Total PAH concentrations approximately doubled when including alkylated compounds. The industrial sediments often exceeded toxicity criteria; however, chemicals were likely less bioavailable than predicted, in part, due to assumed strong sorption to anthropogenic carbon like coal tar. Analyses of separated particle-size fractions showed that approximately half of PAHs were associated with particles greater than 500 μm, suggesting that a wide range of particle sizes are relevant to occurrence and transport. Predicted freely dissolved chemical concentrations in sediment pore water were unrealistically high using a bulk organic carbon sorption coefficient. When reduced to environmentally reasonable levels by applying a high-sorption partition coefficient applicable to contaminated sediments, predicted freely dissolved concentrations in some industrial sediments exceeded sublethal effect levels or surface water quality standards. Chemical assemblages predicted in the freely dissolved aqueous fraction, which is relevant for biotic uptake from water, shifted to predominantly low molecular weight as compared to sediment, highlighting the role of exposure pathways in bioavailability. Insights from chemical fingerprinting coupled with co-analysis of bulk carbon and grain size allowed refinement of bioavailability assessments of complex chemical mixtures in contaminated nearshore environments that are relevant for ecosystem health and restoration.

Washington↗

USGS1963

Ground-water contamination and legal controls in Michigan

The great importance of the fresh ground-water resources of Michigan is evident because 90 percent of the rural and about 70 percent of the total population of the State exclusive of the Detroit metropolitan area are supplied from underground sources. The water-supply and public-health problems that have been caused by some cases of ground-water contamination in the State illustrate the necessity of protecting this vital resource. Manmade and natural contaminants, including many types of chemical and organic matter, have entered many of the numerous aquifers of the State. Aquifers have been contaminated by waste-laden liquids percolating from the surface or from the zone of aeration and by direct injection to the aquifer itself. Industrial and domestic wastes, septic tanks, leaking sewers, flood waters or other poor quality surface waters, mine waters, solids stored or spread at the surface, and even airborne wastes all have been sources of ground-water contamination in Michigan. In addition, naturally occurring saline waters have been induced into other aquifers by overpumping or unrestricted flow from artesian wells, possibly by dewatering operations, and by the deepening of surface stream channels. Vertical migration of saline waters through open holes from formations underlying various important aquifers also has spoiled some of the fresh ground waters in the State. In spite of the contamination that has occurred, however, the total amount of ground water that has been spoiled is only a small part of the total resource. Neither is the contamination so widespread as that of the surface streams of Michigan. Overall legal authority to control most types of ground-water contamination in the State has been assigned by the Michigan Legislature to the Water Resources Commission, although the Department of Conservation and the Health Department also exercise important water-pollution control functions. The Michigan Supreme Court, in an important case upholding the power of the Water Resources Commission to control pollution of ground water, in effect has introduced the doctrine of reasonable use into the law of the State. Excluding controls administered by the Department of Conservation on activities of the oil and gas industry, however, legal controls have not been used abate intrusion of natural saline waters into fresh-water aquifers in response to pumping and other manmade changes in the hydrologic regimen.

Michigan↗

USGS1986

Shallow ground-water conditions, Tom Green County, Texas

Most of the water needs of Tom Green County, Texas, are supplied by ground water; however, the city of San Angelo is supplied by surface water. Groundwater withdrawals during 1980 (latest year for which data are available) in Tom Green County totaled about 15,300 acre-feet, all derived from shallow aquifers. Shallow aquifers in this report refer to the ground-water system generally less than 400 feet deep that contains water with less than a 10,000 milligrams per liter concentration of dissolved solids; aquifers comprising this system include: The Leona, Comanche Peak, Trinity, Blaine, San Angelo, Choza, Bullwagon, Vale, Standpipe, and Arroyo aquifers. The current (1983) water levels in shallow aquifers in Tom Green County are relatively unchanged from those levels listed in previous reports. In most wells, the change in water level is less than 10 feet, and only a few isolated wells or areas have changes of more than 20 feet. Based on long-term hydrographs of selected wells and precipitation, water levels are directly related to precipitation and associated pumpage for irrigation. Current (1983) water levels probably are higher than normal due to the above-normal precipitation during 1980-81. Ground water in Tom Green County commonly is very hard (greater than 180 milligrams per liter as calcium carbonate), and chemical types vary in the aquifers and in different parts of the county. The concentrations of dissolved solids range from 200 to 3,000 milligrams per liter, the dissolved-chloride concentrations range from about 40 to 1,000 milligrams per liter, and the dissolved-sulfate concentrations normally range from about 25 to 600 milligrams per liter. The dissolved-nitrate concentrations in samples from eight wells ranged from 2 to 37 milligrams per liter. Five of these samples exceeded the maximum contaminant level of 10 milligrams per liter set by the U.S. Environmental Protection Agency. Of the eight water samples analyzed for minor elements, two exceeded the maximum contaminant level for selenium, and one exceeded the maximum contaminant level for manganese. Samples from three wells were analyzed for selected pesticides; no pesticides were detected. Two groups of ground-water samples were tested for bacteria in April and August 1983. The first group consisted of samples from 25 wells; no samples contained fecal-coliform bacteria, but 15 samples contained fecal-streptococci bacteria. The second group consisted of samples from 29 wells and 1 spring; twelve of these samples contained fecal-coliform bacteria and all 30 contained fecal-streptococci bacteria. Water samples from seven wells were common to both groups, and the samples tested in August contained more bacteria. Counts of fecal-coliform bacteria ranged from 0 to 26 colonies per 100 milliliters with most less than 5 colonies per 100 milliliters. Counts of fecal-streptococci bacteria ranged from 0 to 400 colonies per 100 milliliters with most less than 20 colonies per 100 milliliters. The presence of fecal-coliform and fecalstreptococci bacteria in water is only an indicator that pollution from septic systems may be present and is not a positive check for fecal pollution. Generally, the aquifers are not contaminated by septic-system effluent, however, some individual wells or localized areas could be contaminated by nearby septic systems. Using dissolved-solids concentrations as an indicator, historical and current (1983) water-quality records were compared to determine if any changes in water quality had occurred. The quality of water from Cretaceous rocks underlying the Edwards Pleateau has not changed significantly; this water is the least mineralized ground water in the county. The quality of water from the Arroyo and Bullwagon aquifers in the eastern most part of the county also has not changed significantly; dissolved-solids concentrations range from 1,500 to 2,000 milligrams per liter. In the remainder of the county, dissolved-solids concentrations have increased from 10 to 500 milligrams per liter in ground water along the river valleys and in the Li pan Flat area and increases of 500 to 1,100 milligrams per liter have occurred in ground water southeast of San Angelo, west of Twin Buttes Reservoir, and about 10 miles east of San Angelo. Locally, dissolved-solids concentrations have increased by as much as 4,530 milligrams per liter in water from individual wells. Pollution from oil-field activities may affect the quality of water in some isolated wells and in some areas in the county. No historical records are available for determining any changes in pesticides, minor elements, or bacteria.

Texas↗