Bibliography of North American geology, paleontology, petrology, and mineralogy, for the years 1892-1900 inclusive
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The George Ashley Block (GAB) is a rockslide block located in the Pala pegmatite district of Southern California. It is layered, asymmetric, pocket containing, and peraluminous. The GAB consists of quartz (42 vol%), Na-rich plagioclase (27%), potassium feldspar (24%), muscovite (7%), Mn-rich garnet (2%), biotite (1%), and a trace of tourmaline and gahnite. It contains only small amounts of the incompatible elements that characterize differentiated pegmatite bodies. P2O5, MnO, and F are present in amounts of < 1 wt% each; B, Be, Ce, Li, Nb, Nd, and Th are < 100 ppm each. More than 90% of the garnet grains in the GAB are zoned toward Mn-rich rims, and a symmetrical change in garnet-core composition occurs across the body. The mean X site contents for garnet (in at%) are 57% Fe, 40% Mn, 3.1% Mg, and 0.4% Ca. The Mn contents of garnet range from 30 to 55 at%; Fe contents vary inversely with Mn and range from about 66 to 43 at%. It is concluded that the bulk chemistry yields little information about fractionation, but the garnet, muscovite, and biotite mineral chemistry is more useful. There may have been two separate injections of magma to form the GAB.
Some of the olivine cumulates of the Ultramafic zone of the Stillwater Complex, Montana, are progressively altered to serpentine minerals and thompsonite. Lizardite and chrysotile developed in the cumulus olivine and postcumulus pyroxenes; thompsonite developed in postcumulus plagioclase. The detailed mineralogy, petrology, and chemistry indicate that olivine and plagioclase react to form the alteration products, except for H 2 O, without changes in the bulk composition of the rocks.
Utilizing both sensitive high-resolution ion microprobe (SHRIMP) and conventional isotope dilution–thermal ionization mass spectrometry (ID-TIMS) methods, crystallization and/or emplacement ages have been obtained for a suite of Cretaceous intermediate-composition plutonic samples collected along a roughly E-W–trending traverse through the northern Peninsular Ranges batholith. Previously noted petrologic, mineralogic, and textural differences delineated four major zonations from west to east and raised the need for detailed geochemical and isotopic work. U-Pb zircon geochronology establishes that these zonations are essentially temporally separate. Mean 206 Pb/ 238 U ages date the three older zones from west to east at 126–107 Ma, 107–98 Ma, and 98–91 Ma. Despite petrologic differences, a relatively smooth progression of magmatism is seen from west to east. A fourth zone is defined by magmatism at ca. 85 Ma, which represents emplacement of deeper-level plutons east of the Eastern Peninsular Ranges mylonite zone in an allochthonous thrust sheet in the northeastern Peninsular Ranges batholith. The age data presented here differ slightly from those presented in earlier work for similar rocks exposed across the middle and southern portions of the Peninsular Ranges batholith in that our data define a relatively smooth progression of magmatism from west to east, and that the transition from western-type to eastern-type plutonism is interpreted to have occurred at ca. 98 Ma and not at ca. 105 Ma. The progressive involvement of older crustal components in the enrichment of eastern Peninsular Ranges batholith–type magma sources is documented by the occurrence of Proterozoic zircon inheritance within samples of the eastern part of the batholith.
The Energy Resources Program of the U.S. Geological Survey promotes and supports coal research to improve the understanding of the coal endowment of the United States. This results in geologically based, non-biased energy information products for policy and decision makers, land and resource managers, other federal and state agencies, the domestic energy industry, foreign governments, nongovernmental groups, academia, and other scientists. A more integrated approach to our coal quality work involves what we call a 'cradle to grave' approach. These types of studies focus not on just one aspect of the coal but rather on how or where different quality parameters form and (or) occur and what happens to them through the mining, production, transport, utilization and waste disposal process. An extensive suite of coal quality analyses, mineralogical, petrology, and leaching investigations are determined on samples taken from the different phases of the coal utilization process. This report consists of a tutorial that was given on June 10, 2007 at the 32nd International Technical Conference on Coal Utilization & Fuel Systems, The Power of Coal, Clearwater Coal Conference in Clearwater, Florida, USA. This tutorial covers how these studies are conducted and the importance of providing improved, comprehensive, science-based data sets for policy and decision makers.
The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is studying the fate and transport of waste solutes in the eastern Snake River Plain (ESRP) aquifer at the Idaho National Laboratory (INL) in eastern Idaho. This effort requires an understanding of the natural and anthropogenic geochemistry of groundwater at the INL and of the important physical and chemical processes controlling the geochemistry. In this study, the USGS applied geochemical modeling to investigate the geochemistry of groundwater in the Beaver and Camas Creek drainage basins, which provide groundwater recharge to the ESRP aquifer underlying the northeastern part of the INL. Data used in this study include petrology and mineralogy from 2 sediment and 3 rock samples, and water-quality analyses from 4 surface-water and 18 groundwater samples. The mineralogy of the sediment and rock samples was analyzed with X-ray diffraction, and the mineralogy and petrology of the rock samples were examined in thin sections. The water samples were analyzed for field parameters, major ions, silica, nutrients, dissolved organic carbon, trace elements, tritium, and the stable isotope ratios of hydrogen, oxygen, carbon, sulfur, and nitrogen. Groundwater geochemistry was influenced by reactions with rocks of the geologic terranes—carbonate rocks, rhyolite, basalt, evaporite deposits, and sediment comprised of all of these rocks. Agricultural practices near and south of Dubois and application of road anti-icing liquids on U.S. Interstate Highway 15 were likely sources of nitrate, chloride, calcium, and magnesium to groundwater. Groundwater geochemistry was successfully modeled in the alluvial aquifer in Camas Meadows and the ESRP fractured basalt aquifer using the geochemical modeling code PHREEQC. The primary geochemical processes appear to be precipitation or dissolution of calcite and dissolution of silicate minerals. Dissolution of evaporite minerals, associated with Pleistocene Lake Terreton, is an important contributor of solutes in the Mud Lake-Dubois area. Oxidation-reduction reactions are important influences on the chemistry of groundwater at Camas Meadows and the Camas National Wildlife Refuge. In addition, mixing of different groundwaters or surface water with groundwater appears to be an important physical process influencing groundwater geochemistry in much of the study area, and evaporation may be an important physical process influencing the groundwater geochemistry of the Camas National Wildlife Refuge. The mass-balance modeling results from this study provide an explanation of the natural geochemistry of groundwater in the ESRP aquifer northeast of the INL, and thus provide a starting point for evaluating the natural and anthropogenic geochemistry of groundwater at the INL.
The content and crystal forms of pyrite and sulfur isotope composition of pyrite sulfur as well as its vertical distribution near the Permian-Triassic (P/T) boundary in the Meishan section, Changxing county, Zhejiang province, China were studied using geological, petrological, mineralogical and geochemical methods (techniques). The result showed that the genesis of abundant pyrites in bed 24e2 at the uppermost part of the Changxing Formation in the Meishan section may be related to volcanic activity. In bed 24e2 of the Meishan section, pyrite has its highest content of 1.84% and the sulfur isotope composition has the highest ??34S value at + 2.2??? which is very similar to that of the average value of volcanic gas. There are some volcanic products such as ??-quartz, siliceous cylinders and siliceous spherules which coexisted with pyrites in beds 24e2 and 24f. It can be concluded that a large quantity of volcanic ash fell into the South China Sea and was incorporated into marine sediments during the formation of limestone at the uppermost part of the Changxing Formation. The volcanic eruption with massive amounts of H2S and S02 gas at the end of the Permian period resulted in the enrichment of H2S in the South China Sea areas. The reaction of H2S with reactive iron minerals formed the mass of abundant pyrites.
This report summarizes the research work of the Trace Elements Section, Geochemistry and Petrology Branch, from the organization of the Section in April 1948 to December 31, 1950. The research undertaken thus far consists of laboratory and related field studies in the following fields: 1. Mineralogic and petrologic investigations of radioactive rocks, minerals, and ores. 2. Investigations of chemical methods of analysis for uranium, thorium, and other elements and compounds in radioactive materials, and related chemical problems. 3. Investigations of spectrographic methods of analysis for a wide variety of elements in radioactive materials. 4. Investigations of radiometric methods of analysis as applied to radioactive materials. It should be emphasized that the work undertaken thus far, described under the headings "Future work", is almost entirely in the nature of investigations supporting the field appraisal of known important uraniferous deposits. A comprehensive program of more fundamental research was submitted in April 1949 in a report entitled "Proposed program of desirable research in the geochemistry of uranium," but funds for this work have not been authorized. It is hoped, however, that funds to support basic research of the type indicated in that report may be available in the future. This report does not cover the analytical work of the Section nor the public-sample program. The analytical work has been summarized for the fiscal year 1950 in the report, "Numerical summary of the analytical work of the Trace Elements Section, Geochemistry and Petrology Branch, for the fiscal year 1950," by John C. Rabbit, U.S. Geol. Survey Trace Elements Memorandum Rept. 174, October 1950. A report on the public-sample program is in preparation. Much of the material in this report has been paraphrased from reports prepared by members of the Section. My special thanks are due them; to Earl Ingerson, chief of the Geochemistry and Petrology Branch of the Survey, for his critical review; to my secretary, Marie Woolihan, for her aid in collecting material; and to Virginia Layne of the editorial staff of the Section for typing the manuscript and the multilith mats.
This report summarized the research work of the Trace Elements Section, Geochemistry and Petrology Branch for the period January 1 - March 31, 1951. Work before that is summarized in an earlier report, "Summary of the research work of the Trace Elements Section, Geochemistry and Petrology Branch, for the period April 1, 1948 - December 31, 1950," by John C. Rabbitt (U.S. Geol. Survey Trace Elements Investigations Rept. 148, January 1951). This report will be referred to as TEIR 148. In TEIR 148 the purpose of each project was described and it is not thought necessary to repeat that material. The research work of the section consists of laboratory and related field studies in the following fields: 1. Mineralogic and petrologic investigations of radioactive rocks, minerals, and ores. 2. Investigations of chemical methods of analysis for uranium, thorium, and other elements and compounds in radioactive materials, and related chemical problems. 3. Investigations of spectographic method of analysis for a wide variety of elements in radioactive materials. 4. Investigation of radiometric methods of analysis is applied to radioactive materials. It should be emphasized that the work undertaken so far is almost entirely in the nature of investigations supporting the field appraisal of known uraniferous deposits. A program of more fundamental research, particularly in the mineralogy and geochemistry of uranium, is now being drawn up and will be submitted for approval soon. This report does not deal with the routine analytical work of the Section nor the public-sample program. The analytical work will be summarized in a report to be issued after the end of fiscal year 1951, and a report on the public-sample program is in process. Special thanks are due members of the Section who are engaged in the research work and who have supplied material for this report, the Early Ingerson, Chief of the Geochemistry and Petrology Branch for his critical review, to Jane Titcomb of the editorial staff of the Section for editing the report, and to Virginia Layne of the same staff, for typing the manuscript and the multilith mats.
The petrographic microscope, designed to observe and measure the optical properties of minerals as a means of identifying them, has provided a foundation for mineralogical and petrological research for more than 120 years. Much of what is known today in these fields is attributable to this instrument, the development of which paralleled an evolution of fundamental optical theory and its correlation with mineral structure and composition. This instrument and its related accessories have evolved through a range of models and designs, which are in themselves distinctive for their scientific function and elegant construction, and are today prized by collectors of scientific instruments.
This study of the Pikes Peak batholith includes the mineralogy and petrology of quartz syenite at West Creek and of fayalite-bearing and fayalite-free biotite granite near Mount Rosa; major element chemistry of the batholith; comparisons with similar postorogenic, intracratonic, sodic to potassic intrusives; and genesis of the batholith. The batholith is elongate in plan, 50 by 100 km, composite, and generally subalkalic. It was emplaced at shallow depth 1,040 m. y. ago, sharply transects its walls and may have breached its roof. Biotite granite and biotite—hornblende granite are predominant; quartz syenite, fayalite granite and riebeckite granite are present in minor amounts. Fayalite-bearing and fayalite-free quartz syenite, fayalite-biotite granite and riebeckite granite show a well-defined sodic differentiation trend; the less sodic fayalite-free granites exhibit a broader compositional range and no sharp trends. Crystallization was largely at P H2O < P total ; P H2O approached P total only at late stages. Aplite residual to fayalite-free biotite granite in the north formed at about 1,500 bars, or 5 km depth. Feldspar assemblages indicate late stages of crystallization at about 720°C. In the south ilmenite and manganian fayalite indicate f O2 of 10 −17 or 10 −18 bars. Biotite and fayalite compositions and the ‘granite minimum’ imply completion of crystallization at about 700°C and 1,500 bars. Nearby fayalite-free biotite granite crystallized at higher water fugacity. All types of syenite and granite contain 5–6% K 2 O through a range of SiO 2 of 63–76%. Average Na 2 O percentages in quartz syenite are 6.2, fayalite granite 4.2, and fayalite-free granite 3.3 MgO contents are low, 0.03–0.4%; FeO averages 1.9–2.5%. FeO/Fe 2 O 3 ratios are high. Fluorine ranges from 0.3 to 0.6%. The Pikes Peak intrusives are similar in mode of emplacement, composition, and probably genesis to rapakivi intrusives of Finland, the Younger Granites of Nigeria, Cape Ann Granite and Beverly Syenite, Mass., and syenite of Kungnat, Greenland, among others — allowing for different levels of erosion. A suite that includes gabbro or basalt, anorthosite, quartz syenite, fayalite granite, riebeckite granite, and biotite and/or hornblende granites is of worldwide occurrence. A model is proposed in which mantle-derived, convecting alkali olivine basaltic magma first reacts with K 2 O-poor lower crust of granulite facies to produce magma of quartz syenitic composition. The syenitic liquid in turn reacts with granodioritic to granitic intermediate crust of amphibolite facies to produce the predominant fayalite-free biotite and biotite-hornblende granites of the batholith. This reaction of magma and roof involves both partial melting and the reconstitution and precipitation of refractory phases, as Bowen proposed. Intermediate liquids include MgO-depleted and Na 2 O-enriched gabbro, which precipitated anorthosite, and alkali diorite. The heat source is the basaltic magma; the heat required for partial melting of the roof is supplied largely by heats of crystallization of phases that settle out of the liquid — mostly olivine, clinopyroxene and plagioclase.
The authors investigated statistical distributions for concentrations of chemical elements from the National Geochemical Survey (NGS) database of the U.S. Geological Survey. At the time of this study, the NGS data set encompasses 48,544 stream sediment and soil samples from the conterminous United States analyzed by ICP-AES following a 4-acid near-total digestion. This report includes 27 elements: Al, Ca, Fe, K, Mg, Na, P, Ti, Ba, Ce, Co, Cr, Cu, Ga, La, Li, Mn, Nb, Nd, Ni, Pb, Sc, Sr, Th, V, Y and Zn. The goal and challenge for the statistical overview was to delineate chemical distributions in a complex, heterogeneous data set spanning a large geographic range (the conterminous United States), and many different geological provinces and rock types. After declustering to create a uniform spatial sample distribution with 16,511 samples, histograms and quantile-quantile (Q-Q) plots were employed to delineate subpopulations that have coherent chemical and mineral affinities. Probability groupings are discerned by changes in slope (kinks) on the plots. Major rock-forming elements, e.g., Al, Ca, K and Na, tend to display linear segments on normal Q-Q plots. These segments can commonly be linked to petrologic or mineralogical associations. For example, linear segments on K and Na plots reflect dilution of clay minerals by quartz sand (low in K and Na). Minor and trace element relationships are best displayed on lognormal Q-Q plots. These sensitively reflect discrete relationships in subpopulations within the wide range of the data. For example, small but distinctly log-linear subpopulations for Pb, Cu, Zn and Ag are interpreted to represent ore-grade enrichment of naturally occurring minerals such as sulfides. None of the 27 chemical elements could pass the test for either normal or lognormal distribution on the declustered data set. Part of the reasons relate to the presence of mixtures of subpopulations and outliers. Random samples of the data set with successively smaller numbers of data points showed that few elements passed standard statistical tests for normality or log-normality until sample size decreased to a few hundred data points. Large sample size enhances the power of statistical tests, and leads to rejection of most statistical hypotheses for real data sets. For large sample sizes (e.g., n > 1000), graphical methods such as histogram, stem-and-leaf, and probability plots are recommended for rough judgement of probability distribution if needed. ?? 2005 Elsevier Ltd. All rights reserved.