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Glacial and nonglacial sediment contributions to Wisconsin episode loess in the Central United States

The relative contributions of various glacial and nonglacial sediments to Wisconsin Episode loess units along the lower Illinois and central Mississippi Valleys are estimated on the basis of a comparison of magnetic susceptibility and silt and clay mineralogy. A mathematical method of source area calculation, using four compositional parameters, was guided by current knowledge of the regional glacial history. On the basis of this technique, the Roxana Silt, along the Illinois and Mississippi River Valleys, is composed of significant Superior lobe sediment (35%-40%) as well as Wadena or Des Moines lobe sediment (about 35%). This can account for its high magnetic susceptibility, feldspar content, kaolinite content, and pink hue. Lower Peoria Silt contains about 25%-35% Lake Michigan lobe sediment with reduced contributions of the other sources. After the Mississippi River's diversion (20.4 ka), the supply of Superior, Des Moines, and Wadena lobe sediment was cut off from the Illinois Valley in favor of Lake Michigan lobe sediment (75%- 80% contribution). This major source area shift accounts for higher dolomite and illite contents and a more yellow hue in approximately the upper two-thirds of Peoria Silt in the study area. In loess south of St. Louis, less pronounced compositional shifts occur because Superior lobe sediment was not cut off and because Des Moines lobe, Wadena lobe, and Missouri River sediments, having more intermediate composition, compose 40%-50% of the loess, thereby diluting other source area changes. Nonglacial sediment, from fluvial and periglacial sources, is estimated to compose 10%-40% of loess in both regions.

Illinois, Indiana, Iowa, Michigan, Minnesota, Nebr↗

Episodic intrusion, internal differentiation, and hydrothermal alteration of the Miocene Tatoosh intrusive suite south of Mount Rainier, Washington

The Miocene Tatoosh intrusive suite south of Mount Rainier is composed of three broadly granodioritic plutons that are manifestations of ancestral Cascades arc magmatism. Tatoosh intrusive suite plutons have individually diagnostic characteristics, including texture, mineralogy, and geochemistry, and apparently lack internal contacts. New ion-microprobe U-Pb zircon ages indicate crystallization of the Stevens pluton ca. 19.2 Ma, Reflection-Pyramid pluton ca. 18.5 Ma, and Nisqually pluton ca. 17.5 Ma. The Stevens pluton includes rare, statistically distinct ca. 20.1 Ma zircon antecrysts. Wide-ranging zircon rare earth element (REE), Hf, U, and Th concentrations suggest late crystallization from variably evolved residual liquids. Zircon Eu/Eu*–Hf covariation is distinct for each of the Reflection-Pyramid, Nisqually, and Stevens plutons. Although most Tatoosh intrusive suite rocks have been affected by weak hydrothermal alteration, and sparse mineralized veins cut some of these rocks, significant base or precious metal mineralization is absent. At the time of shallow emplacement, each of these magma bodies was largely homogeneous in bulk composition and petrographic features, but, prior to final solidification, each of the Tatoosh intrusive suite plutons developed internal compositional variation. Geochemical and petrographic trends within each pluton are most consistent with differential loss of residual melt, possibly represented by late aplite dikes or erupted as rhyolite, from crystal-rich magma. Crystal-rich magma that formed each pluton evidently accumulated in reservoirs below the present level of exposure and then intruded to a shallow depth. Assembled by episodic intrusion, the Tatoosh intrusive suite may be representative of midsized composite plutonic complexes beneath arc volcanoes.

Washington↗

Iron formation and associated rocks in the Iron River district, Michigan

The iron formation of the Iron River district is part of a Precambrian sequence of strata characterized by a high iron content and varied mineralogy. The iron formation, where unoxidized, consists largely of interlaminated chert and siderite. It is underlain by a graphitic slate containing about 20 per cent iron in the form of very finely disseminated pyrite. Graywacke overlies the iron formation with at least local disconformity; this rock consists of clastic grains in a matrix of siderite or iron-rich chlorite. Above the gray-wacke is a magnetic ironstone, a laminated rock that now consists of iron-rich chlorite, magnetite, chert, and siderite, each layer being an intermixture of two or more of these constituents. The average iron content of the entire sequence, including the iron formation, is approximately 20 per cent. The rocks are only slightly metamorphosed, although the area is one of intense structural deformation. The origin of the rocks is discussed, and it is concluded that the high iron content is primary. The rocks are believed to be the products of an era of iron-rich sedimentation in which the specific iron mineral formed —sulfide, carbonate, or silicate—depended upon the immediate depositional environment. Inasmuch as the formation of iron-rich minerals continued despite extensive changes in both the basin of deposition and the adjacent land areas, the ultimate cause for such an epoch is one that transcended such factors. Evidence is presented to show that the climate of the era, when linked with certain other factors, is entirely adequate to explain the formation of these iron-rich rocks.

Michigan↗

Metamorphism of Precambrian granitic xenoliths in a mica peridotite at Rose Dome, Woodson County, Kansas: Part 2, petrologic and mineralogic studies

Field, drill-core, petrographic, and mineralogic studies show that the Precambrian granitic rocks exposed on Rose Dome, Woodson County, Kansas, were emplaced as inclusions of basement rock in a mica peridotite magma that intruded the Pennsylvanian section of Rose Dome during Late Cretaceous time. High temperatures of the alkaline ultramafic magma (probably greater than 800° C) led to metamorphism of the granitic inclusions and the formation of high sanidine and high albite from original microcline and albite. Contact metamorphic effects on country rock include the development of buchite-like sanidine-magnesian biotite hornfels from Weston Shale (Pennsylvanian) that was intruded by the mica peridotite. The high temperatures of the peridotite magma also led to partial melting of the granitic rocks; a quartzofeldspathic matrix shows volcanic textures and binds mineral and rock fragments together to produce the varied range of textures and structures of the granitic xenoliths. Partial melting of the granitic rocks accounts for those features that led earlier workers to conclude that the “granite” on Rose Dome had intruded the Pennsylvanian section. Those features included xenoliths of hornfels enclosed by granitic material and apparently intrusive relationships between the granitic rocks and metamorphosed shale. The lack of concordance in the Rb-Sr ages of the granitic rocks (Part 1) may stem partly from melting of the “granite” and exchange of ions with the mica peridotite magma, from the “sampling” of different levels of granitic crust by the upwelling peridotite magma, or from weathering.

Kansas↗

Contrasting magma types and steady-state, volume-predictable, basaltic volcanism along the Great Rift, Idaho

The Great Rift is an 85-km-long, 2- to 8-km-wide volcanic rift zone in the Snake River Plain, Idaho. Three latest Pleistocene to Holocene basaltic lava fields, Craters of the Moon, Kings Bowl, and Wapi, are located along the Great Rift. The Craters of the Moon lava field is a composite of more than 60 lava flows, 25 cinder cones, and at least 8 eruptive fissure systems. It covers 1,600 km 2 and contains ∼30 km 3 of lava flows and associated pyroclastic deposits. Field, radiocarbon, and paleomagnetic data show that the Craters of the Moon lava field formed in eight eruptive periods, each of which was typically several hundred years or less in duration and was separated from others before and after by intervals of several hundred to several thousand years. The first eruptive period began ∼15,000 yr B.P., and the latest eruptive period ended ∼2100 yr B.P. The small Kings Bowl lava field (3.3 km 2 , 0.01 km 3 ) and the larger Wapi lava field (330 km 2 , 6 km 3 ) both formed ∼2250 yr B.P. Three magma types have fed flows along the Great Rift. The types are (1) a contaminated type that has a SiO 2 range of ∼49%–64% and commonly shows petrographic evidence of contamination, (2) a fractionated type that has a SiO 2 range of ∼44%–54% and shows no evidence of contamination and whose chemical and mineralogical variation can be accounted for mainly by crystal fractionation, and (3) a Snake River Plain type that has a SiO 2 range of ∼45%–48%, shows little evidence of fractionation, and is represented by Kings Bowl–Wapi flows and olivine basalts of the Snake River Plain. The contaminated and fractionated magma types were erupted at the Craters of the Moon lava field, and the Snake River Plain magma type was erupted at the Kings Bowl and Wapi lava fields. These relations imply that the magma reservoirs are spatially isolated. The magma output rate for the Craters of the Moon segment of the Great Rift was constant at ∼1.5 km 3 /1,000 yr for the period from 15,000 to 7000 yr B.P. The rate increased to ∼2.8 km 3 /1,000 yr from 7000 to 2000 yr B.P., mainly as a result of the addition of contaminated magma to the nearly constant output rate of fractionated magma. The Craters of the Moon segment of the Great Rift has experienced quasi-steady-state, volume-predictable volcanism for the last 15,000 yr. The recurrence interval of eruptive activity for the Craters of the Moon lava field ranges from several hundred to ∼3,000 yr. Because the present interval has lasted ∼2,100 yr, another eruptive period seems likely to occur within the next 1,000 yr. The steady-state, volume-predictable relationship suggests that 5–6 km 3 of lava will be erupted in the next eruptive period.

Idaho↗

An Appalachian isochron: A kaolinized Carboniferous air-fall volcanic-ash deposit (tonstein)

The Fire Clay tonstein is a kaolinized, airfall volcanic ash bed that was deposited in a widespread late Carboniferous peat-forming mire. Eleven samples from Kentucky and West Virginia, spanning a distance of 200 km, and two samples from Tennessee and Virginia indicate a characteristic mineralogical signature, as compared with other Appalachian tonsteins, consisting of well-crystallized kaolinite, beta-quartz crystal paramorphs, sanidine, ilmenite, zircon, and brookite. Detrital illite and quartz are rarely present or are in very small amounts, which indicates rapid deposition in a mire. Several normal graded cycles in this tonstein suggest repeated episodes of pyroclastic activity that produced a composite ash layer. A high-silica alkalic rhyolitic source is suggested by the geochemistry of immobile elements and by electron-probe analyses of glass inclusions in volcanic quartz from the Fire Clay tonstein. The rare-earth-element plots (chondrite normalized) of the tonstein show a pronounced negative Eu anomaly and relatively high concentrations of Zr and Th, which are both indicative of a rhyolitic source. Probe analyses of the Fire Clay glass inclusions from four states indicate a chemically identical high-silica rhyolite with peraluminous affinities. 40 Ar/ 39 Ar sanidine plateau dating indicates an age of 312 ± 1 Ma for the Fire Clay tonstein, which is consistent with previous 40 Ar/ 39 Ar dates for this tonstein. This age is in agreement with a late Westphalian B age in the European Carboniferous chronostratigraphy on the basis of an age of 311 Ma for the Westphalian B/C boundary. A new isopachous map of the Fire Clay ash-fall deposit indicates an area of 37,000 km 2 and a probable source to the present-day southwest. The deposit has a minimum preserved compacted volume of 2.8 km 3 , which corresponds to an original uncompacted volume of about 20 km 3 . This preserved volume indicates an ultraplinian volcanic explosion. Pindell and Dewey (1982) proposed an Andean-type arc in this block during the late Carboniferous, prior to South American-North American plate collision. We hypothesize an associated back-arc caldera system in the Yucatan block to explain the high-silica, potassic rhyolitic ash that gave rise to the Fire Clay tonstein.

Geological Society of America Bulletin↗

Petrologic and geophysical nature of serpentinites

Mineralogically, serpentinites consist predominantly of lizardite, clinochrysotile, and antigorite. Recent work has shown that these minerals are not polymorphs. Chrysotile is the only mineral recognized as a synthetic product in experimental studies of the system MgO-SiO 2 -H 2 O. Antigorite seems to be stable at higher temperatures than lizardite or chrysotile. The density of individual serpentine species is dependent on their morphology; the low-density serpentinites (<2.55g/cc) consist predominantly of clino-chrysotile. Seismic velocities and magnetic susceptibilities of serpentinites are related to the degree of serpentinization. The transition of massive serpentinites from ductile to brittle behavior in laboratory experiments at high confining pressures and temperatures above 300°C has been related to dehydration which may provide a mechanism for developing deep-focus earthquakes along Benioff zones. Serpentinite is formed by direct hydration of ultramafic protolith in the crust. The most common ultramafic protoliths are harzburgite, dunite, and Iherzolite. The assemblage generally developed from these is lizardite + chrysotile + brucite + magnetite. In areas of high-grade metamorphism, antigorite is the predominant serpentine mineral. The common, large, alpine-type serpentinized ultramafic masses contain brucite and have MgO/SiO 2 ratios similar to those of their protolith, resulting in volume increase during serpentinization. Metamorphic serpentinites and some highly sheared alpine-type serpentinites have lower MgO/SiO 2 ratios than their protolith, lack brucite, and appear t o have been formed by volume-for-volume replacement with concomitant loss of magnesium or addition of silica. Many large, young masses of peridotite appear to be slabs of oceanic mantle over-thrust onto continental edges. Subsequent sedimentation, serpentinization, and tectonism have greatly modified these original slabs so that their recognition in older orogenic zones is equivocal. The concept of the tectonic evolution of ultramafic rocks from oceanic crust-mantle slabs invading continental margins and being incrementally serpentinized and moved by later tectonic events provides a working hypothesis that allows a better explanation of the many peculiar and varied occurrences of serpentinite. The evidence does not support Hess' suggestion that the third layer of the oceanic crust consists of partly serpentinized mantle peridotite.

Bulletin of the Geological Society of America↗

Mineralogy and chemistry of massive sulfide deposits from the Juan de Fuca Ridge

Six hydrothermal vent sites and associated benthic communities were located in the axial valley of the southern Juan de Fuca Ridge using transponder-navigated bottom photography. The hydrothermal deposits form ledges and shallow mounds within a central zone characterized by a linear bathymetric depression and numerous collapse features. The flat valley floor adjacent to the central zone consists of ferrobasalt lobate flows and sheet flows; sediment cover is minimal. Vent sites are characterized by concentrations of tube worms, clams, benthic siphonophores, and several unidentified fauna. Two types of massive sulfide were dredged from one of the vent sites. Type A samples are angular slabs of dark gray Zn-rich sulfide with interlayers and a thin, partly oxidized crust of Fe sulfide. These layered sulfide aggregates appear to be fragments of a sulfide wall enclosing an active hydrothermal vent. The outer sulfide wall is composed mainly of colloform Fe sulfide and Fe-poor sphalerite deposited under lower-temperature conditions whereby sea water and hydrothermal fluid mix above the discharge point. With continued sulfide deposition, the wall inhibits mixing of sea water and hydrothermal fluid. Inside the wall, the intensifying hydrothermal system deposits a higher-temperature assemblage of granular Fe-rich sphalerite, wurtzite, pyrite, and minor Cu-Fe sulfide. The zonation in wurtzite from Fe-rich cores to Fe-poor rims may result from a late-stage cooling of the hydrothermal fluid and(or) a change in fluid chemistry. The sulfide wall grows outward where a rupture in it permits the escape of high-temperature fluid and then deposition of a secondary shell over the breakthrough point. As temperature increases, earlier-formed minerals dissolve, and Zn, Fe, and Pb migrate toward the outer sulfide wall. Tube worms flourished in the outer wall of type A samples, and abandoned tube structures served as conduits for the late-stage hydrothermal fluids. Type B sulfide samples are subrounded, spongy-textured fragments composed almost entirely of dendritic aggregates of pale, Fe-poor colloform sphalerite and opaline silica. This type of sulfide is deposited in open space by moderate- to low-temperature fluid discharging at a slow but variable rate; the fluid becomes increasingly oxidizing, resulting in late-stage deposition of hematite, barite, and sulfur. Type B samples show little evidence of burrowing animals; this type of sulfide may be deposited in settings peripheral to sites of focused discharge.

Geological Society of America Bulletin↗