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At least 37 records · Page 2Linked to original sources

The cali meteorite fell: A new H/L ordinary chondrite

The fall of the Cali meteorite took place on 6 July 2007 at 16 h 32 ?? 1 min local time (21 h 32 ?? 1 min UTC). A daylight fireball was witnessed by hundreds of people in the Cauca Valley in Colombia from which 10 meteorite samples with a total mass of 478 g were recovered near 3??24.3'N, 76??30.6'W. The fireball trajectory and radiant have been reconstructed with moderate accuracy. From the computed radiant and from considering various plausible velocities, we obtained a range of orbital solutions that suggest that the Cali progenitor meteoroid probably originated in the main asteroid belt. Based on petrography, mineral chemistry, magnetic susceptibility, fhermoluminescence, and bulk chemistry, the Cali meteorite is classified as an H/L4 ordinary chondrite breccia.

Meteoritics and Planetary Science

Intrinsic oxygen fugacity measurements on seven chondrites, a pallasite, and a tektite and the redox state of meteorite parent bodies

Intrinsic oxygen-fugacity ( f O 2 ) measurements were made on five ordinary chondrites, a carbonaceous chondrite, an enstatite chondrite, a pallasite, and a tektite. Results are of the form of linear log f O 2 − 1 T "> fO 2 −1T plots. Except for the enstatite chondrite, measured results agree well with calculated estimates by others. The tektite produced f O 2 values well below the range measured for terrestrial and lunar rocks. The lowpressure atmospheric regime that is reported to follow large terrestrial explosions, coupled with a very high temperature, could produce glass with f O 2 in the range measured. The meteorite Salta (pallasite) has low f O 2 and lies close to Hvittis (E6). Unlike the other samples, results for Salta do not parallel the iron-wüstite buffer, but are close to the fayalite-quartz-iron buffer in slope. Minor reduction by graphite appears to have taken place during metamorphism of ordinary chondrites. f O 2 values of unequilibrated chondrites show large scatter during early heating suggesting that the constituent phases were exposed to a range of f O 2 conditions. The samples equilibrated with respect to f O 2 in relatively short time on heating. Equilibration with respect to f O 2 in ordinary chondrites takes place between grades 3 and 4 of metamorphism. Application of P − T − f O 2 relations in the system C-CO-CO 2 indicates that the ordinary chondrites were metamorphosed at pressures of 3–20 bars, as it appears that they lay on the graphite surface. A steep positive thermal gradient in a meteorite parent body lying at the graphite surface will produce thin reduced exterior, an oxidized near-surface layer, and an interior that is increasingly reduced with depth; a shallow thermal gradient will produce the reverse. A body heated by accretion on the outside will have a reduced exterior and oxidized interior. Meteorites from the same parent body clearly are not required to have similar redox states.

Geochimica et Cosmochimica Acta

Luminescence dating of the Wabar meteorite craters, Saudi Arabia

Luminescence dating has been used to find the age of meteorite impact craters at Wabar (Al Hadida) in Saudi Arabia. The luminescence characteristics of the shocked material were determined. Using a variety of luminescence dating techniques applied to impactite formed by the meteorite, and to the underlying sand, the age is found to be 290 ± 38 years. A comparison is made with two possible historically recorded ages. An impact as young as this has implications for the assessment of hazards from the impact on Earth of small meteorites.

Al Hadida, Ar-Rub' Al-Khali (Empty Quarter)

Time differences in the formation of meteorites as determined from the ratio of lead-207 to lead-206

Measurements of the lead isotopic composition and the uranium, thorium, and lead concentrations in meteorites were made in order to obtain more precise radiometric ages of these members of the solar system. The newly determined value of the lead isotopic composition of Canyon Diablo troilite is as follows: 206 Pb/ 204 Pb = 9.307, 207 Pb/ 2O4 Pb = 10.294, and 208 Pb/ 204 Pb = 29.476. The leads of Angra dos Reis, Sioux County, and Nuevo Laredo achondrites are very radiogenic, the 206 Pb/ 204 Pb values are about 200, and the uranium-thorium-lead systems are nearly concordant. The ages of the meteorites as calculated from a single-stage 207 Pb/ 206 Pb isochron based on the newly determined primordial lead value and the newly reported 235 U and 838 U decay constants, are 4.528 x 10 9 years for Sioux County and Nuevo Laredo and 4.555 x 10 9 years for Angra dos Reis. When calculated with the uranium decay constants used by Patterson, these ages are 4.593 x 10 9 years and 4.620 x 10 9 years, respectively, and are therefore 40 to 70 x 10 6 years older than the 4.55 x 10 9 years age Patterson reported. The age difference of 27 x 10 6 years between Angra dos Reis and the other two meteorites is compatible with the difference between the initial 87 Sr/ 86 Sr ratio of Angra dos Reis and that of seven basaltic achondrites observed by Papanastassiou and Wasserburg. The time difference is also comparable to that determined by 129 1- 129 Xe chronology. The ages of ordinary chondrites (H5 and L6) range from 4.52 to 4.57 x 10 9 years, and, here too, time differences in the formation of the parent bodies or later metamorphic events are indicated. Carbonaceous chondrites(C2 and C3) appear to contain younger lead components.

Science

The Rock Elm meteorite impact structure, Wisconsin: Geology and shock-metamorphic effects in quartz

The Rock Elm structure in southwest Wisconsin is an anomalous circular area of highly deformed rocks, ∼6.5 km in diameter, located in a region of virtually horizontal undeformed sedimentary rocks. Shock-produced planar microstructures (PMs) have been identified in quartz grains in several lithologies associated with the structure: sandstones, quartzite pebbles, and breccia. Two distinct types of PMs are present: P1 features, which appear identical to planar fractures (PFs or cleavage), and P2 features, which are interpreted as possible incipient planar deformation features (PDFs). The latter are uniquely produced by the shock waves associated with meteorite impact events. Both types of PMs are oriented parallel to specific crystallographic planes in the quartz, most commonly to c(0001), xi{11 (2) over bar2}, and r/k{10 (1) over bar1} . The association of unusual, structurally deformed strata with distinct shock-produced microdeformation features in their quartz-bearing rocks establishes Rock Elm as a meteorite impact structure and supports the view that the presence of multiple parallel cleavages in quartz may be used independently as a criterion for meteorite impact. Preliminary paleontological studies indicate a minimum age of Middle Ordovician for the Rock Elm structure. A similar age estimate (450-400 Ma) is obtained independently by combining the results of studies of the general morphology of complex impact structures with estimated rates of sedimentation for the region. Such methods may be applicable to dating other old and deeply eroded impact structures formed in sedimentary target rocks.

Wisconsin

An extremely low UPb source in the Moon: U Th Pb, Sm Nd, Rb Sr, and 40Ar 39Ar isotopic systematics and age of lunar meteorite Asuka 881757

We have undertaken U Th Pb, Sm Nd, Rb Sr, and 40 Ar 39 Ar "> 40 Ar 39 Ar isotopic studies on Asuka 881757, a coarse-grained basaltic lunar meteorite whose chemical composition is close to low-Ti and very low-Ti (VLT) mare basalts. The Pb Pb internal isochron obtained for acid leached residues of separated mineral fractions yields an age of 3940 ± 28 Ma, which is similar to the U-Pb (3850 ± 150 Ma) and Th-Pb (3820 ± 290 Ma) internal isochron ages. The Sm-Nd data for the mineral separates yield an internal isochron age of 3871 ± 57 Ma and an initial 143 Nd 144 Nd "> 143 Nd 144 Nd value of 0.50797 ± 10. The Rb-Sr data yield an internal isochron age of 3840 ± 32 Ma ( λ( 87 Rb) = 1.42 × 10 −11 yr −1 "> λ( 87 Rb) = 1.42 × 10 −11 yr −1 ) and a low initial 87 Sr 86 Sr "> 87 Sr 86 Sr ratio of 0.69910 ± 2. The 40 Ar 39 Ar "> 40 Ar 39 Ar age spectra for a glass fragment and a maskelynitized plagioclase are relatively flat and give a weighted mean plateau age of 3798 ± 12 Ma. We interpret these ages to indicate that the basalt crystallized from a melt 3.87 Ga ago (the Sm-Nd age) and an impact event disturbed the Rb-Sr system and completely reset the K-Ar system at 3.80 Ga. The slightly higher Pb-Pb age compared to the Sm-Nd age could be due to the secondary Pb (from terrestrial and/or lunar surface Pb contamination) that remained in the residues after acid leaching. Alternatively, the following interpretation is also possible; the meteorite crystallized at 3.94 Ga (the Pb-Pb age) and the Sm-Nd, Rb-Sr, and K-Ar systems were disturbed by an impact event at 3.80 Ga. The crystallization age obtained here is older than those reported for low-Ti basalts (3.2–3.5 Ga) and for VLT basalts (3.4 Ga), but similar to ages of some mare basalts, indicating that the basalt may have formed from a magma related to a basin-forming event (Imbrium?). The age span for VLT basalts from different sampling sites suggest that they were erupted over a wide area during an interval of at least ~500 million years. The impact event that thermally reset the K-Ar system of Asuka 881757 must have been post-Imbrium (perhaps Orientale) in age. The lead isotopic composition of Asuka 881757 is nonradiogenic compared with typical Apollo mare basalts and the estimated 238 U 204 Pb "> 238 U 204 Pb (μ) value for the basalt source is 10 ± 3. This source-μ value is the lowest so far measured for lunar rocks. A large positive ϵ Nd value (7.4 ± 0.5) and the time averaged 147 Sm 144 Nd "> 1 47 147 Sm 144 Nd "> Sm 144 Nd ratio for the basalt source are similar to those for some Apollo 12, 15, and 17 basalts, suggesting a LREE-depleted mantle, which is consistent with the global magma ocean hypothesis. The U-Th-Pb, Sm-Nd, and Rb-Sr data on Asuka 881757 suggest that the basalt was derived from a low U Pb "> UPb , low Rb Sr "> RbSr , and high Sm Nd "> SmNd source region, mainly composed of olivine and orthopyroxene with minor amounts of plagioclase (or clinopyroxene) and with sulfides enriched in volatile chalcophile elements. The basalt source may be deep in origin and different in chemistry from those previously estimated from studies of Apollo and Luna mare basalts, indicating heterogeneous sources for mare basalts.

Geochimica et Cosmochimica Acta

Rhenium-osmium concentration and isotope systematics in group IIAB iron meteorites

Rhenium and osmium abundances, and osmium isotopic compositions were measured by negative thermal ionization mass spectrometry in thirty samples, including replicates, of five IIA and eight IIB iron meteorites. Concentrations in HA irons range from 4800 ppb Re and 66000 ppb Os (Negrillos) to 160 ppb Re and 800 ppb Os (Lombard). In the IIB subgroup, concentrations vary from 28 ppb Re and 180 ppb Os (Navajo) down to 0.8 ppb Re and 9 ppb Os (São Julião de Moreira and Santa Luzia). Log plots of Os vs. Re abundances for HA and IIB irons describe straight lines that approximately converge on Lombard, which has the lowest Re and Os abundances and highest 187 Re/ 188 Os measured in a IIA iron to date. The linear HA trend may be exactly reproduced by fractional crystallization with constant k Re and k Os , but is not well fitted using variable partition coefficients. The IIB iron trend, however, cannot be entirely explained by simple fractional crystallization. One explanation is that small amounts of Re and Os were added to the asteroid core during the final stages of crystallization. Another possibility is that diffusional enrichment of Os may have occurred in samples most depleted in Re and Os. The combined Re-Os isotopic data for HA irons give the following results: slope = 0.07803 ± 0.00076; intercept = 0.09609 ± 0.00045; age = 4584 ± 43 Ma (neglecting the uncertainty in the decay constant of ±3%). Four IIB iron meteorites (Mount Joy, Central Missouri, DRPA 78009, Santa Luzia) also plot within the analytical uncertainty of the HA isochron. These results are consistent with rapid (probably <50 Ma) core segregation, differentiation, and crystallization in the IIAB parent. Several IIB irons (Navajo, Sandia Mountains, Smithsonian Iron, and perhaps São Julião de Moreira) lie beyond analytical uncertainty above the IIA iron isochron, averaging 8 ± 2% higher in 187 Os/ 188 Os. These irons may have crystallized significantly after the HA irons and Mount Joy, but only if the 187 Re/ 188 Os of the melt was ≥2.2. There is no evidence for a IIA iron crystallizing in equilibrium with a melt having such a high ratio. Alternatively, the osmium isotopic systematics of these irons may have been slightly disturbed long after crystallization at ca. 3.3 Ga ago.

Geochimica et Cosmochimica Acta

Spectral nature of CO 2 adsorption onto meteorites

Previous studies have identified carbon dioxide (CO 2 ) on the surfaces of Jovian and Galilean satellites in regions of non-ice material that are too warm for CO 2 ice to exist. CO 2 ice would quickly sublimate if not retained by a less-volatile material. To ascertain what non-ice species may be responsible for stabilizing this CO 2 , we performed CO 2 gas adsorption experiments on thirteen powdered CM, CI, and CV carbonaceous chondrite meteorites. Reflectance spectra of the &nu; 3 feature associated with adsorbed CO 2 near 4.27 &mu;m were recorded. Results show that many meteorites adsorbed some amount of CO 2 , as evidenced by an absorption feature that was stable over several hours at ultra-high vacuum (UHV) and high vacuum, (1.0&times;10 &minus;8 and 1.0&times;10 &minus;7 Torr, respectively). Ivuna, the only CI chondrite studied, adsorbed significantly more CO 2 than the others. We found that CO 2 abundance did not vary with &lsquo;water&rsquo; abundance, organics, or carbonates as inferred from the area of the 3-&mu;m band, the 3.2-3.4 &mu;m C-H feature, and the &sim;3.8-&mu;m band respectively, but did correlate with hydrous/anhydrous phyllosilicate ratios. Furthermore, we did not observe CO 2 ice because the position of the CO 2 feature was generally shifted 3-10 nm from that of the 4.27 &mu;m absorption characteristic of ice. The strongest compositional relationship observed was a possible affinity of CO 2 for total FeO abundance and complex clay minerals, which make up the bulk of the CI chondrite matrix. This finding implies that the most primitive refractory materials in the Solar System may also act as reservoirs of CO 2 , and possibly other volatiles, delivering them to parts of the Solar System where their ices would not be stable.

Icarus

Lunar highland meteorite Dhofar 026 and Apollo sample 15418: Two strongly shocked, partially melted, granulitic breccias

Studies of lunar meteorite Dhofar 026, and comparison to Apollo sample 15418, indicate that Dhofar 026 is a strongly shocked granulitic breccia (or a fragmental breccia consisting almost entirely of granulitic breccia clasts) that experienced considerable post-shock heating, probably as a result of diffusion of heat into the rock from an external, hotter source. The shock converted plagioclase to maskelynite, indicating that the shock pressure was between 30 and 45 GPa. The post-shock heating raised the rock's temperature to about 1200 °C; as a result, the maskelynite devitrified, and extensive partial melting took place. The melting was concentrated in pyroxene-rich areas; all pyroxene melted. As the rock cooled, the partial melts crystallized with fine-grained, subophitic-poikilitic textures. Sample 15418 is a strongly shocked granulitic breccia that had a similar history, but evidence for this history is better preserved than in Dhofar 026. The fact that Dhofar 026 was previously interpreted as an impact melt breccia underscores the importance of detailed petrographic study in interpretation of lunar rocks that have complex textures. The name “impact melt” has, in past studies, been applied only to rocks in which the melt fraction formed by shock-induced total fusion. Recently, however, this name has also been applied to rocks containing melt formed by heating of the rocks by conductive heat transfer, assuming that impact is the ultimate source of the heat. We urge that the name “impact melt” be restricted to rocks in which the bulk of the melt formed by shock-induced fusion to avoid confusion engendered by applying the same name to rocks melted by different processes.

Meteoritics and Planetary Science

Comment on: “New” lunar meteorites: Impact melt and regolith breccias and large‐scale heterogeneities of the upper lunar crust, by P. H. Warren, F. Ulff‐Møller, and G. W. Kallemeyn

We described lunar meteorite Dhofar 026 (Cohen et al. 2004) and interpreted this rock as a strongly shocked granulitic breccia (or fragmental breccia consisting almost entirely of granulitic‐breccia clasts) that was partially melted by post‐shock heating. Warren et al. (2005) objected to many aspects of our interpretation: they were uncertain whether or not the bulk rock had been shocked; they disputed our identification of the precursor as granulitic breccia; and they suggested that mafic, igneous‐textured globules within the breccia, which we proposed were melted by post‐shock heating, are clasts with relict textures. The major evidence for shock of the bulk rock is the fact that the plagioclase in the lithologic domains that make up 80–90% of the rock is devitrified maskelynite. The major evidence for a granulitic‐breccia precursor is the texture of the olivine‐plagioclase domain that constitutes 40—45% of the rock; Warren et al. apparently overlooked or ignored this lithology. Textures of the mafic, igneous‐textured globules, and especially of the vesicles they contain, demonstrate that these bodies were melted and crystallized in situ. Warren et al. suggested that the rock might have originally been a regolith breccia, but the textural homogeneity of the rock and the absence of solar wind—derived noble gases preclude a regolith‐breccia precursor. Warren et al. classified the rock as an impact‐melt breccia, but they did not identify any fraction that was impact melt.

Meteoritics and Planetary Science

Thermomagnetic analysis of meteorites, 3. C3 and C4 chondrites

Thermomagnetic analysis was made on samples of all known C3 and C4 chondrites in a controlled oxygen atmosphere. Considerable variation was noted in the occurrence of magnetic minerals, comparable to the variation observed earlier in the C2 chondrites. Magnetite was found as the only major magnetic phase in samples of only three C3 chondrites (2–4 wt.%) and the Karoonda C4 chondrite (7.7 wt.%). The magnetite content of these three C3 chondrites is only about one-third that observed in the C1 and C2 chondrites which were found to contain magnetite as the only magnetic phase. Five C3 chondrites were observed to undergo chemical change during heating, producing magnetite: this behavior is characteristic of troilite oxidation. Upper limits on initial magnetite content of about 1–9% were established for these meteorites. Samples of the remaining five C3 chondrites and the Coolidge C4 chondrite were found to contain both magnetite and metallic iron. In two samples, iron containing ≤2% Ni was observed, while in the other four, the iron contained 6–8 wt.% Ni. In addition to containing both magnetite and iron metal, three of these samples reacted during heating to form additional magnetite. Variations in the magnetic mineralogy and, hence by inference bulk mineralogy, of C3 and C4 chondrites indicate a more complex genesis than is evident from whole-rock elemental abundance patterns.

Earth and Planetary Science Letters

Isotopic determinations of rhenium and osmium in meteorites by using fusion, distillation and ion-exchange separations

A stable isotope-dilution method using resonance ionization mass spectrometry is suitable for the determination of rhenium and osmium abundances and osmium isotopic composition in carbonaceous chondrites and iron meteorites. The chemical procedure involves sodium peroxide fusion, followed by distillation of osmium from sulfuric acid/hydrogen peroxide and subsequent anion-exchange separation of rhenium from the same solution. ?? 1989.

Analytica Chimica Acta

Lu-hf total-rock isochron for the eucrite meteorites

The isotope 176Lu (2.6% of natural lutetium) decays by ??- to 176Hf, with a long half life. We present here the first Lu-Hf isochron. The eucrite meteorites, a suite of planetary igneous rocks of known age, 4,550 Myr, define a 10-point total-rock isochron with a slope of 0.0934 ?? 40, leading to a value of 3.53 ?? 0.14 ??1010yr for the ??--decay half life of 176Lu. The isochron intercept of 0.27973 ?? 12 gives the initial 176Hf/177Hf for the inner Solar System at the time of accretion. ?? 1980 Nature Publishing Group.

Nature

Rapid methods of determining cooling rates of iron and stony iron meteorites

Two rapid and simple methods have been developed for determining the approximate cooling rates of iron and stony-iron meteorites in which kamacite formed by diffusion-controlled growth along planar fronts. The first method requires only measurements of the mean kamacite bandwidth and the bulk nickel content. The second method requires the determination of the nickel composition near the taenite-kamacite interface with an electron microprobe.

Science

Origin of the Sudbury Complex by meteoritic impact: Neodymium isotopic evidence

Samarium-neodymium isotopic data on whole rocks and minerals of the Sudbury Complex in Canada gave an igneous crystallization age of 1840 ± 21 × 10 6 years. The initial epsilon neodymium values for 15 whole rocks are similar to those for average upper continental crust, falling on the crustal trend of neodymium isotopic evolution as defined by shales. The rare earth element concentration patterns of Sudbury rocks are also similar to upper crustal averages. These data suggest that the Sudbury Complex formed from melts generated in the upper crust and are consistent with a meteoritic impact.

Ontario

Using the potassium-argon laser experiment (KArLE) to date ancient, low-K chondritic meteorites

Several laboratories have been investigating the feasibility of in situ K-Ar dating for use in future landing planetary missions. One drawback of these laboratory demonstrations is the insufficient analogy of the analyzed analog samples with expected future targets. We present the results obtained using the K-Ar laser experiment (KArLE) on two old and K-poor chondritic samples, Pułtusk and Hvittis, as better lunar analogs. The KArLE instrument uses laser ablation to vaporize rock samples and quantifies K content by laser-induced breakdown spectroscopy (LIBS), Ar by quadrupole mass spectrometry (QMS), and ablated mass by laser profilometry. We performed 64 laser ablations on the chondrites to measure spots with a range of K 2 O and Ar content and used the data to construct isochrons to determine the chondrite formation age. The KArLE isochron ages on Pułtusk and Hvittis are 5059 ± 892 Ma and 4721 ± 793 Ma, respectively, which is within the uncertainty of published reference ages, and interpreted as the age of their formation. The uncertainty (2 σ ) on the KArLE ages obtained in this study is better than 20% (18% for Pułtusk and 17% for Hvittis). The precision, which compares our obtained ages to the reference ages, is also better than 20% (11% for Pułtusk and 4% for Hvittis). These results are encouraging for understanding the limits of this technique to measure ancient planetary samples and for guiding future improvements to the instrument.

Meteoritics & Planetary Science (MAPS)