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At least 37 records · Page 2Linked to original sources

Mineral potential mapping in an accreted island-arc setting using aeromagnetic data: An example from southwest Alaska

The distribution of volcanogenic massive sulfide (VMS), porphyry-epithermal, Alaska-type ultramafic-mafic complexes, intrusion-related Au, and granitoid Sn-W ore deposits in southwest Alaska supports current metallogenic models linking the formation of these deposit types to the emplacement of different suites of igneous rocks during the evolution of this convergent plate margin. Regional-scale aeromagnetic data provide a continuous set of observations over the deposits and show contrasting patterns over the igneous rock suites hosting the various deposit types. Combined with surface geologic data and regional metallogenic constraints, aeromagnetic data—filtered to enhance the anomalous magnetic field and map magnetic domains—were used to produce a mineral potential map across this accreted island-arc setting. The reduced-to-pole, upward continuation, and total horizontal gradient transform maps show anomalies that could represent porphyry-epithermal deposits within the intraoceanic- and continental-arc terranes. The tilt derivative transform highlights lineaments within the back arc that may represent zones with potential for VMS deposits. The truncations of tilt derivative lineaments outline a major magnetic domain boundary between the back-arc and craton margin, which is prospective for granitoid Sn-W deposits. Annular tilt derivative highs outline granitoids that could be associated with intrusion-related Au deposits within the craton margin. Shallow, magnetite-rich Alaska-type ultramafic-mafic complexes are mapped by their short-wavelength, high-amplitude anomalies. Successful mineral potential mapping across southwestern Alaska as performed in the present study suggests that filtered aeromagnetic data can be effectively used in mineral exploration in convergent continental margin settings.

Alaska↗

The May 2003 eruption of Anatahan volcano, Mariana Islands: Geochemical evolution of a silicic island-arc volcano

The first historical eruption of Anatahan volcano began on May 10, 2003. Samples of tephra from early in the eruption were analyzed for major and trace elements, and Sr, Nd, Pb, Hf, and O isotopic compositions. The compositions of these tephras are compared with those of prehistoric samples of basalt and andesite, also newly reported here. The May 2003 eruptives are medium-K andesites with 59–63 wt.% SiO 2 , and are otherwise homogeneous (varying less than 3% 2 σ about the mean for 45 elements). Small, but systematic, chemical differences exist between dark (scoria) and light (pumice) fragments, which indicate fewer mafic and oxide phenocrysts in, and less degassing for, the pumice than scoria. The May 2003 magmas are nearly identical to other prehistoric eruptives from Anatahan. Nonetheless, Anatahan has erupted a wide range of compositions in the past, from basalt to dacite (49–66 wt.% SiO 2 ). The large proportion of lavas with silicic compositions at Anatahan (> 59 wt.% SiO 2 ) is unique within the active Mariana Islands, which otherwise erupt a narrow range of basalts and basaltic andesites. The silicic compositions raise the question of whether they formed via crystal fractionation or crustal assimilation. The lack of 87 Sr/ 86 Sr variation with silica content, the MORB-like δ 18 O, and the incompatible behavior of Zr rule out assimilation of old crust, altered crust, or zircon-saturated crustal melts, respectively. Instead, the constancy of isotopic and trace element ratios, and the systematic variations in REE patterns are consistent with evolution by crystal fractionation of similar parental magmas. Thus, Anatahan is a type example of an island-arc volcano that erupts comagmatic basalts to dacites, with no evidence for crustal assimilation. The parental magmas to Anatahan lie at the low 143 Nd/ 144 Nd, Ba/La, and Sm/La end of the spectrum of magmas erupted in the Marianas arc, consistent with 1–3 wt.% addition of subducted sediment to the mantle source, or roughly one third of the sedimentary column. The high Th/La in Anatahan magmas is consistent with shallow loss of the top ∼ 50 m of the sedimentary column during subduction.

Anatahan volcano, Mariana Islands↗

Late Proterozoic island-arc complexes and tectonic belts in the southern part of the Arabian Shield, Kingdom of Saudi Arabia

Two main subdivisions of layered rocks are recognized in the southern Arabian Shield south of lat 22? N. These are an older ensimatic-arc complex, which formed 1100-800 m.y. ago, and a younger marginal-arc complex, which formed 800-690 m.y. ago. The older ensimatic-arc complex, located in the southwestern part of the Shield, includes graywacke and mafic to intermediate volcanic rocks of the essentially contemporaneous Baish, Bahah, and Jiddah groups. Although the younger arc complex is also dominantly ensimatic in character, it is also partly superimposed over the older ensimaticarc complex. The superimposed portions of the younger arc complex are represented by the Ablah, Samran, and possibly the Ararat groups. The ensimatic portion of the younger arc group is represented by the Halaban group, which was deposited to the east and northeast of the older ensimatic-arc complex. The Halaban group includes andesitic and dacitic volcanic rocks and associated clastic sedimentary rocks. The layered rocks of both arc complexes are intruded by dioritic (quartz diorite, tonalite, trondhjemite) plutonic rocks. The southern Shield is also subdivided into a number of structurally bounded, north-trending tectonic belts. Within the older ensimatic complex, three belts are recognized. From west to east, these are the Lith, Bidah, and Tayyah belts. Within these three belts, progressive facies changes indicate a gradation from deep-water facies in the south to shallow-water or-terrestrial facies in the north. The distribution of dioritic batholiths, as well as the distribution of layered-rock facies, suggests a northwest-trending axis for the older ensimatic-arc complex. The younger arc complex is present within six belts, the Makkah source papers. In Fleck and others (1980), the term 'quartz diorite' includes both tonalite and quartz diorite as defined in the International Union of Geological Sciences (IUGS) system of plutonic rock classification (Streckeisen, 1973). Initial 87Sr/86Sr ratios are not included in the appendix, but all rocks more than 660 m.y. old have initial ratios in the range 0.7021-0.7035, with only two greater than 0.7030. Thus, nothing in the Rb-Sr data suggests involvement of an older continental crust during the evolution of the southern Shield. A lead isotope study of ore minerals and potassium feldspars of the Arabian Shield by Stacey and others (1980) also suggests that no older (Archean to early Proterozoic) evolved continental-type crust underlies the southern Shield. An early summary of mapping (Schmidt and others, 1973) suggests that older sialic basement underlies the late Proterozoic layered rocks in the southern Shield. However, subsequent-mapping and the isotopic studies cited above have established that all of these rocks are of late Proterozoic age and that all rocks of the southern Shield that are more than 660 m.y. old have ensimatic or mantle isotopic characteristics. Figure 2 shows, with only two exceptions, that rocks more than 800 m.y. old are present west of the boundary separating the Tayyah and Khadra belts. The exceptions are two poorly controlled Rb-Sr ages obtained by Fleck (1980) on two quartz diorite plutons in the Malahah region (appendix 1, localities 26 and 27). Preliminary uranium-thorium zircon data of Stacey now suggest that one of these quartz diorite plutons (locality 26) has an age of approximately 640 m.y. Therefore, we prefer to discount the two dates of Fleck until further information is available. As noted earlier and as described below, most of the rocks of the southern Arabian Shield have characteristics typical of those formed in the island-arc environment by subduction-related processes. We shall refer to the group of rocks in the western part of the southern Shield, which formed from 1100 to 800 m.y. ago, as the 'older ensimatic-arc complex' and those in the eastern and northwestern parts, which formed from 800 to 690 m.y. ago, as the 'younger marginal-arc compl

Open-File Report↗

Structure of the collision zone between Bougainville guyot and the accretionary wedge of the New Hebrides Island arc, southwest Pacific

Multichannel seismic reflection data show the structure that develops within an island arc-guyot collision zone. The Bougainville guyot fills the New Hebrides trench, stands about 3 km above the abyssal ocean plain, and is capped by a broad platform that is underlain by a parallel bedded sequence, probably lagoon and reef rocks. A thick debris apron made up of unconsolidated sediment underlies the unsubducted part of the lower guyot flank and possibly the subducted flank as well. The contact zone between the arc and the north and east sides of the guyot is marked by discontinuous antiforms that include reflective, thrust faulted rocks that may have been derived from the guyot. The extent of collision deformation to the arc and guyot depends in part on the contrast in compressibility and viscosity between these features. We propose that the high-drag, subcircular guyot evolves during collision into a more streamlined shape. Streamlining may be achieved by processes like: (1) bulk deformation of the guyot by thrust faulting and sediment compaction; (2) ripping away of projecting parts of the guyot and blunting sharp edges (tectonic erosion), like that formed by the limestone cap; and (3) formation of a boundary layer, between the guyot and the arc, that is made up of water-rich, mobilized units of soft sediment. We draw an analogy between some features of glacial origin and the subducted part of a guyot. If the bulk of the guyot is low strength, especially in view of the thick debris apron, then the guyot may behave like till that was overridden by a glacier and forms a drumlin, an elongated, blunt-faced, streamlined feature. Thrust faults evident in the guyot may indicate deformation that leads toward a streamlined shape and not necessarily to accretion of guyot rocks.

Tectonics↗

Origin of the oceanic basalt basement of the Solomon Islands arc and its relationship to the Ontong Java Plateau-insights from Cenozoic plate motion models

Cenozoic global plate motion models based on a hotspot reference frame may provide a useful framework for analyzing the tectonic evolution of the Solomon Islands convergent margin. A postulated late Miocene collision of the Ontong Java Plateau (OJP) with a NE-facing arc is consistent with the predicted path of the OJP across the Pacific Basin and its Miocene arrival at the trench. Late-stage igneous activity (65-30 Ma) predicted for the OJP as it rode over the Samoan hotspot occurred in correlative stratigraphic sections on Malaita, the supposed accreted flake of OJP in the Solomon Islands arc. Convergence similar to the present velocities between Australia and the Pacific plates was characteristic of the last 43 million years. Prior to 43 Ma Pacific-Australia plate motions were divergent, seemingly at odds with geologic evidence for early Tertiary convergence, particularly in Papua New Guinea. A postulated South Pacific plate may have existed between Australia and the Pacific plate and would have allowed implied northward subduction along the northeastern Australia plate boundary that lasted into the early Eocene. Subsequent reorganization of plate motions in the middle Eocene correlates with middle Eocene marginal basin formation along ridges oblique to the main plate boundary. Cessation of spreading on the Pacific-South Pacific Ridge and its subsequent subduction beneath Asia followed the change in Pacific plate motion at 43 Ma. A trapped remnant of the extinct, NW-trending ridge may still lie beneath the western Philippine Sea. The terminal deformation, metamorphism and ophiolite obduction in the Eocene orogen of the southwest Pacific also correlates with the major change in Pacific plate motion at 43 Ma and the subsequent compression of the dying Eocene arc against outlying continental and oceanic crustal blocks of the Australian plate. The Solomon Islands oceanic basement may represent juxtaposition of oceanic plateaus of the Australian plate beneath overthrust, dismembered ophiolite derived from adjacent marginal basin crust.

Tectonophysics↗

Igneous history of the Koyukuk terrane, western Alaska: Constraints on the origin, evolution, and ultimate collision of an accreted island arc terrane

The Koyukuk terrane of western Alaska consists of volcanic, volcaniclastic, and plutonic rocks which range from Late Paleozoic to Early Cretaceous in age. The terrane crops out in a U-shaped belt which is roughly paralleled by outer belts of ultramafic rocks, oceanic plate basalts and cherts, and retrograded blueschist facies rocks of continental protolith. These rocks have been interpreted as components of a volcanic arc terrane that collided with the North American continental margin in Early Cretaceous time. The Koyukuk terrane consists of four time-stratigraphic units: (1) pre-Middle Jurassic basalts, (2) Middle and Late Jurassic granitic rocks, (3) lower Lower Cretaceous volcanic rocks, and (4) upper Lower Cretaceous volcanic rocks. Limited chemical data from the basalts of unit 1 indicate that they were erupted in a nonarc tectonic environment, possibly in an oceanic island or back arc setting. Units 2, 3, and 4 have the characteristics of subduction-related volcanic rocks (i.e., depleted Nb and Ta and enriched alkaline elements, relative to the light rare earth elements). Unit 3 contains tholeiitic, calc-alkaline, and alkaline rocks with chondrite-normalized rare earth element patterns that range from flat (La N /Yb N = 1) to highly light rare earth element enriched (La N /Yb N > 15). The highly alkaline or shoshonitic lavas were erupted toward the end of unit 3 time (Valanginian) during the final stages of arc-continent collision. These alkaline lavas could have been derived by very small degrees of partial melting of a similar source to that of the earlier arc lavas. Unit 4 lavas are also alkaline or shoshonitic, but their incompatible element composition indicates that they were derived from a different source than that of the earlier arc lavas. These late alkaline lavas are chemically similar to crosscutting mid-Cretaceous plutons whose isotopic compositions (Arth et al., this issue ( a )) suggest derivation by partial melting of distinctly older subcontinental lithosphere. We speculate that the parental magmas of unit 4 lavas may also have been derived by partial melting of this subcontinental mantle which was underthrust beneath the Koyukuk arc terrane during the final stage of arc-continent collision.

Journal of Geophysical Research Solid Earth↗

Gneissic amphibolite at Las Palmas, Puerto Rico, and its significance in the early history of the greater antilles island arc

The basal complex of Puerto Rico consists principally of serpentinite, minor amounts of chert and spilite, and locally small blocks of amphibolite . A detailed structural and metamorphic study of a relatively large block of gneissic amphibolite at Las Palmas reveals that the rock has undergone repeated deformation and regional metamorphism prior to contact metamorphism by intrusive serpentinite. The first event recorded by the amphibolite is amphibolite facies regional metamorphism. Foliation and some hornblende lineation were formed at this time. An increase in the intensity of regional metamorphism then produced quartzo-feldspathic segregations from the host rock, and was accompanied by small-scale folding and development of several types of lineation oblique (o the early hornblende lineation. The metamorphic intensity then decreased slightly and tectonic movement radically decreased, as nonfoliated but metamorphosed mafic dikes cut the gneissic amphibolite . As the metamorphic grade decreased further, late-stage kink-bands were developed at high angles to the earlier small-scale folding. Later, the amphibolite was intruded by serpen-tinite, causing incipient low-grade contact metamorphism and some calcium metasomatism. H. H. Hess has maintained that Puerto Rico and other islands in the Greater Antilles rest directly on oceanic crust, and that the intrusive serpentinite is derived from the bottom layer of the crust. In the Las Palmas area, the amphibolite formed prior to intrusion of serpentinite, indicating a complex preserpentinite history . Three interpretations of the gneissic amphibolite are considered. It may represent: (1) metamorphosed gabbroic rocks genetically related to the serpentinite, (2) regionally metamorphosed mafic rocks that are part of the oceanic crust, or (3) older mafic rocks regionally metamorphosed as part of an extensive pre-Late Cretaceous orogeny. The evidence from Las Palmas is not conclusive, but when considered in the regional framework, either of the last two interpretations seems reasonable.

Puerto Rico↗

Phanerozoic tectonic evolution of the Circum-North Pacific

The Phanerozoic tectonic evolution of the Circum-North Pacific is recorded mainly in the orogenic collages of the Circum-North Pacific mountain belts that separate the North Pacific from the eastern part of the North Asian Craton and the western part of the North American Craton. These collages consist of tectonostratigraphic terranes that are composed of fragments of igneous arcs, accretionary-wedge and subduction-zone complexes, passive continental margins, and cratons; they are overlapped by continental-margin-arc and sedimentary-basin assemblages. The geologic history of the terranes and overlap assemblages is highly complex because of postaccretionary dismemberment and translation during strike-slip faulting that occurred subparallel to continental margins.We analyze the complex tectonics of this region by the following steps. (1) We assign tectonic environments for the orogenic collages from regional compilation and synthesis of stratigraphic and faunal data. The types of tectonic environments include cratonal, passive continental margin, metamorphosed continental margin, continental-margin arc, island arc, oceanic crust, seamount, ophiolite, accretionary wedge, subduction zone, turbidite basin, and metamorphic. (2) We make correlations between terranes. (3) We group coeval terranes into a single tectonic origin, for example, a single island arc or subduction zone. (4) We group igneous-arc and subduction- zone terranes, which are interpreted as being tectonically linked, into coeval, curvilinear arc/subduction-zone complexes. (5) We interpret the original positions of terranes, using geologic, faunal, and paleomagnetic data. (6) We construct the paths of tectonic migration. Six processes overlapping in time were responsible for most of the complexities of the collage of terranes and overlap assemblages around the Circum-North Pacific, as follows. (1) During the Late Proterozoic, Late Devonian, and Early Carboniferous, major periods of rifting occurred along the ancestral margins of present-day Northeast Asia and northwestern North America. The rifting resulted in the fragmentation of each continent and the formation of cratonal and passive continental-margin terranes that eventually migrated and accreted to other sites along the evolving margins of the original or adjacent continents. (2) From about the Late Triassic through the mid-Cretaceous, a succession of island arcs and tectonically paired subduction zones formed near the continental margins. (3) From about mainly the mid-Cretaceous through the present, a succession of igneous arcs and tectonically paired subduction zones formed along the continental margins. (4) From about the Jurassic to the present, oblique convergence and rotations caused orogenparallel sinistral and then dextral displacements within the upper-plate margins of cratons that have become Northeast Asia and North America. The oblique convergences and rotations resulted in the fragmentation, displacement, and duplication of formerly more nearly continuous arcs, subduction zones, and passive continental margins. These fragments were subsequently accreted along the expanding continental margins. (5) From the Early Jurassic through Tertiary, movement of the upper continental plates toward subduction zones resulted in strong plate coupling and accretion of the former island arcs and subduction zones to the continental margins. Accretions were accompanied and followed by crustal thickening, anatexis, metamorphism, and uplift. The accretions resulted in substantial growth of the North Asian and North American Continents. (6) During the middle and late Cenozoic, oblique to orthogonal convergence of the Pacifi c plate with present-day Alaska and Northeast Asia resulted in formation of the modern-day ring of volcanoes around the Circum-North Pacific. Oblique convergence between the Pacific plate and Alaska also resulted in major dextral-slip faulting in interior and southern Alaska and along the western p

Professional Paper↗

Proceedings of the Symposium on Mineral Deposits of the Pacific Northwest: Geological Society of America, Cordilleran Section meeting at Corvallis, Oregon, March 20-21, 1980

Stratiform and volcanogenic zinc-lead-barium deposits occur within the pelagic Kagvik sequence in the Red Dog Creek and Drenchwater Creek areas in the DeLong Mountains and Howard Pass quadrangles. The sulfide deposits occur together with barite, tuff, sandstone, shale, chert, and keratophyre flows and sills. The three main occurrences of the stratiform zinc-lead-barium deposits in the Red Dog Creek area are: (1) thinly-bedded stratiform sulfide minerals in organic-rich Mississippian shale and chert; (2) massive sulfide vein and breccia fillings in Mississippian shale; and (3) massive stratiform barite lenses and nodules in chert and shale of the Siksikpuk Formation. The Drenchwater Creek area has only the first type. Sulfide-bearing zones of up to several thousand meters long occur in both areas with up to 19.5 percent Zn, 9.5 percent Pb, and locally more than 150 ppm Ag. Radiolaria from sulfide-bearing chert indicate in the Red Dog Creek area a Mississippian age of sulfide deposition. K/Ar ages of 319 + 10 m.y. and 330 + 17 m.y. obtained from biotite in keratophyre associated with sulfide-bearing tuff and chert in the Drenchwater Creek area indicate a Mississippian age of sulfide deposition. Sulfur isotope analyses of sulfur-bearing minerals from the Red Dog Creek area indicate that a combination of sea water sulfate and deep-seated sulfur was probably the source of the barite sulfate whereas sulfur in the sulfide minerals may have had a deep-seated source. Sulfur isotope values for sphalerite and galena are similar in vein and stratiform occurrences. Using sulfur isotope geothermetry, spalerite-galena pairs yield paleotemperatures of between 115° and 305° C. Lead isotope analyses of galena from both the Red Dog Creek and Drenchwater Creek areas yield Triassic model ages of approximately 200 m.y. Lead isotope data from both areas approximate typical orogene, i.e., Andean-type arc, or mature island-arc values and exclude ocean floor rifting for the generation of lead. The isotopic, petrologic, and field data indicate the stratiform zinc-lead-barium deposits in the Red Dog Creek and Drenchwater Creek areas formed during a short-lived period of Mississippian submarine volcanism in either an incipient Andean-type arc, or mature island arc environment.

Alaska, British Columbia, California↗

Chemistry of the subalkalic silicic obsidians

Nonhydrated obsidians are quenched magmatic liquids that record in their chemical compositions details of the tectonic environment of formation and of the differentiation mechanisms that affected their subsequent evolution. This study attempts to analyze, in terms of geologic processes, the compositional variations in the subalkalic silicic obsidians (Si0 2 ≥70 percent by weight, molecular (Na 2 O+K 2 0)>Al 2 O 3 ). New major- and trace-element determinations of 241 samples and a compilation of 130 published major-element analyses are reported and interpreted. Obsidians from five different tectonic settings are recognized: (1) primitive island arcs, (2) mature island arcs, (3) continental margins, (4) continental interiors, and (5) oceanic extensional zones. Tectonomagmatic discrimination between these groups is successfully made on Nb-Ta, Nb-FeO t and Th-Hf-Ta plots, and compositional ranges and averages for each group are presented. The chemical differences between groups are related to the type of crust in which magmas were generated. With increasingly sialic (continental type) crust, the obsidians show overall enrichment in F, Be, Li, Mo, Nb, Rb, Sn, Ta, U, W, Zn, and the rare-earth elements, and depletion in Mg, Ca, Ba, Co, Sc, Sr, and Zr. They become more potassic, have higher Fe/Mg and F/Cl ratios, and lower Zr/Hf, Nb/Ta, and Th/U ratios. Higher values of total rare-earth elements are accompanied by light rare-earth-element enrichment and pronounced negative Eu anomalies. An attempt is made to link obsidian chemistry to genetic mechanlism. Two broad groups of rocks are distinguished: one generated where crystal-liquid processes dominated (CLPD types), which are the products of crustal anatexis, possibly under conditions of low halogen fugacity, ± crystal fractionation ± magma mixing; and a second group represented by rocks formed in the upper parts of large magma chambers by interplays of crystal fractionation, volatile transfer, magma mixing, and possibly various liquid-state differentiation mechanisms, or in other words a complex interaction of petrogenetic processes (CIPP types). Such rocks may also form by volatile-fluxed partial melting of the wallrocks, and subsequent mixing into the magma reservoir. Compositional ranges and averages for CLPD and CIPP obsidians are given. It is shown by analogy with well-documented, zoned ash-flow ruffs that obsidians fractionated by CIPP have very low Mg, P, Ba, and Sr contents, flat rare-earth-element patterns with extensive Eu anomalies, low K/Rb and Zr/Nb ratios, and relatively high Na 2 O/K 2 O ratios. There is, however, considerable compositional overlap between CLPD and CIPP obsidians. The effects of magma mixing, assimilation, and vapor-phase transport in producing compositional variations in the obsidians are briefly assessed. The geochemistry of the subalkalic silicic obsidians is described on an element-by-element basis, in order to provide a database for silicic magma compositions that will hopefully contribute to studies of granitic rocks. Attempts are also made to isolate the geochemical effects of tectonic environment and genetic mechanism for each element, by comparison with data from crystal-liquid equilibria-controlled systems, from ash-flow sheets zoned by CIPP, and from mixed-magma series. A final tabulation relates the complexities of obsidian geochemistry to all the tectonic and genetic variables.

Professional Paper↗

Geochemical and tectonic evolution of the Ordovician Bronson Hill arc and Silurian and Devonian Connecticut Valley–Gaspé trough: Eastern Vermont and western New Hampshire, USA

We present major and trace element whole-rock geochemistry of 94 samples from the Bronson Hill arc (BHA) and Connecticut Valley–Gaspé trough (CVGT). These data, when combined with recent zircon U-Pb geochronology and a reexamination of existing whole-rock geochemistry, enable a new analysis of the tectonic history of the ancient Laurentian-Ganderian margin in the northern Appalachians of New England, USA, and southeastern Canada. The whole-rock geochemical data from the Ordovician BHA in western New Hampshire indicate that metamorphosed extrusive and intrusive rocks share the same temporally variable geochemical fingerprint. Mafic and felsic rocks form a bimodal distribution and plot as island arc magmas on geochemical discrimination diagrams. Approximately 80% of mafic greenstone and amphibolite samples plot as island arc tholeiites with a subset of samples that trend toward a more within-plate basalt geochemical signature. Where ages are known, older felsic rocks (ca. 475–460 Ma) in the BHA tend to be more sodic and less potassic than their younger (ca. 460–445 Ma) counterparts, and the geochemical results trend from volcanic arc granites toward syn-collisional granites through time. Prior to recent geochronology, it was thought that an age gap existed between the island arc magmas and the syn collisional granites. This led to the separation of felsic plutons into the predominantly older trondhjemitic magmas assigned to the Ammonoosuc Volcanics and a younger suite of granites designated as the Oliverian Plutonic Suite. This age gap was thought to represent a flip in subduction polarity which would also account for observed changes in pluton chemistry. With the addition of more recent U-Pb isotopic age data, we now know there is a continuum of ages, and a polarity flip is no longer required. When the isotopic ages are combined with the new geochemical data presented here, they suggest that as the BHA approached and collided with Laurentia ca. 455 Ma, continental material was assimilated into the magma, and there was a transition from trondhjemite to granodiorite and granite magmas in felsic rocks and from island arc tholeiite toward more alkali-rich basalt with a continental signature in mafic magmas. The similarities in whole-rock and trace element geochemistry, rock type, and range of isotopic ages from the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic Suite, suggest they originated from the same magma source and were part of one evolving island arc system that persisted throughout the Ordovician, and the need to separate the Oliverian Plutonic Suite from the Ammonoosuc Volcanics is not necessary. Most magmatism in the BHA ceased ca. 440 Ma. Following the Taconic orogeny, Silurian basin development was widespread along the length of the Laurentian-Ganderian suture. In New England and Québec, this resulted in the formation of the CVGT. The BHA and the CVGT are generally studied separately: the BHA in the context of arc-continent collision during the Taconic orogeny, and the CVGT as it relates to post-orogenic extension or the distal effects of the Salinic disturbance. When viewed collectively, the igneous geochemistry of the BHA and CVGT reveals an overlap between the waning stages of Taconic orogenesis and the onset of Silurian to Devonian basin development in the northern Appalachians. Metamorphosed bimodal volcanic and intrusive rocks are present in the CVGT (ca. 434–407 Ma) and Silurian cover sequence, which unconformably overlies the BHA. Mafic rocks in the CVGT are mostly tholeiitic basalts with a subset of alkali basalt in the Waits River Formation. Tectonic discrimination diagrams show that the mafic rocks are a mix of mid-ocean ridge basalt to within-plate basalt. The felsic rocks in the CVGT are mostly metamorphosed volcanic rocks that vary from island arc granite to within-plate granite. The geochemical signature of the CVGT is consistent with a post-collisional intra-arc basin, where slab breakoff or crustal attenuation played a key role before transitioning to a deepening foreland basin at the beginning of the Acadian orogeny.

New Hampshire, Vermont↗

Porphyry copper assessment of British Columbia and Yukon Territory, Canada: Chapter C in Global mineral resource assessment

The U.S. Geological Survey does regional, national, and global assessments of resources (mineral, energy, water, biologic) to provide science in support of land management and decision making. Mineral resource assessments provide a synthesis of available information about where mineral deposits are known and suspected to be in the Earth’s crust, which commodities may be present, and estimates of amounts of resources that may be present in undiscovered deposits. Canada is an important source of copper, consistently ranking as one of the top 10 world producers during the past decade (2000–2010). The preponderance of this production has been from porphyry-copper-type deposits in the western Canadian Cordillera. A probabilistic mineral resource assessment of undiscovered resources associated with porphyry copper deposits in western Canada was completed as part of a global mineral resource assessment. The purpose of the assessment was to (1) compile a database of known deposits and significant prospects, (2) delineate permissive areas (tracts) for undiscovered porphyry copper deposits that may be present in the upper kilometer (minimally) of the Earth’s crust, and (3) provide probabilistic estimates of amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in undiscovered porphyry copper deposits in the tracts. The study was done by the U.S. Geological Survey (USGS) in collaboration with geologists from the British Columbia Geological Survey, Yukon Geological Survey, and industry consultants. The database of known deposits and significant prospects includes an inventory of mineral resources in 89 known porphyry copper (and 2 related copper-bearing polymetallic vein) ore zones, representing 50 porphyry copper deposits, and lists key characteristics of 280 additional porphyry copper and related copper-bearing prospects, as indicated by currently available exploration results, which also are summarized. Resource and exploration and development activity are updated with information current through April 2010. The delineation of permissive tracts and probabilistic estimation of resources in undiscovered deposits were done using the USGS three-part mineral resource assessment approach. Permissive tracts are defined in accordance with descriptive models for porphyry copper deposits to include igneous rocks and known deposits and prospects within magmatic arcs related to convergent plate-margin boundary zones. Frequency distributions of total tonnages and average grades of thoroughly explored deposits were used as models for undiscovered deposits and include a new grade and tonnage model for calc-alkaline porphyry Cu±Mo±Au deposits in western Canada. Five permissive tracts for the occurrence of porphyry copper deposits were delineated: 2 island-arc tracts, 1 tract of transitional, mixed island-arc and continental arc affinities, and 2 continental arc tracts. In permissive tract 003pCu2001, calc-alkaline igneous rocks of Middle Triassic to Late Jurassic age in accreted island-arc terranes of the Intermontane belt are assessed for calc-alkaline porphyry Cu±Mo±Au deposits. The area of this tract is 175,250 km 2 . In 12 known deposits, the total reported tonnage of ore is 8,100 million metric tons (Mt) containing 24.6 Mt copper. An estimated 6.9 undiscovered deposits contain a calculated mean of 8.9 Mt copper and a median of 6.9 Mt copper. The spatial density for the 18.9 known plus estimated undiscovered deposits in this tract is approximately 11 deposits per 100,000 km 2 . In permissive tract 003pCu2002, alkaline igneous rocks of Middle Triassic to Late Jurassic age within the Intermontane accreted island-arc terranes are assessed for alkaline porphyry Cu-Au deposits. The area of this tract is 109,290 km 2 . In 12 known deposits the total reported tonnage of ore is 6,440 Mt, containing 20.9 Mt copper. An estimated 7 undiscovered deposits contain a calculated mean of 22 Mt copper and a median of 13 Mt copper. The spatial density for the 19 known plus estimated undiscovered deposits in this tract is approximately 17 deposits per 100,000 km 2 . In permissive tract 003pCu2003, calc-alkaline igneous rocks of Late Triassic to Early Cretaceous age within the accreted Insular terranes of mixed island-arc and continental arc affinities are assessed for calc-alkaline porphyry Cu±Mo±Au deposits. The area of this tract is 58,360 km 2 . The total tonnage of ore reported in the 2 known deposits is 1,160 Mt containing 3.17 Mt copper. An estimated 2.3 undiscovered deposits contain a calculated mean of 3 Mt copper and a median of 1.9 Mt copper. The spatial density for the 4.3 known plus estimated undiscovered deposits in this tract is approximately 7 deposits per 100,000 km 2 . In permissive tract 003pCu2004, calc-alkaline igneous rocks in continental magmatic arcs of Jurassic to Eocene age are assessed for porphyry Cu±Mo±Au deposits. The area of this tract is 639,500 km 2 . The total tonnage of ore reported for the 23 known deposits is 6,520 Mt containing 17.9 Mt copper. An estimated 9.6 undiscovered deposits contain a calculated mean of 13 Mt copper and a median of 11 Mt copper. The spatial density for the 32.6 known deposits plus the estimated undiscovered deposits in this tract is approximately 5 deposits per 100,000 km 2 . In permissive tract 003pCu2005, calc-alkaline igneous rocks in continental magmatic arcs of Oligocene to Pliocene age are assessed for porphyry Cu±Mo±Au deposits. The area of this tract is 32,840 km 2 . The total tonnage of ore reported for the 1 known deposit is 44.8 Mt containing 0.224 Mt copper. An estimated 1.4 undiscovered deposits contain a calculated mean of 1.8 Mt copper and a median of 0.72 Mt copper. The spatial density for the 2.4 known plus estimated undiscovered deposits in this permissive tract is approximately 7 deposits per 100,000 km 2 . Western Canada has been thoroughly explored for porphyry copper deposits. The total estimated copper contained in known deposits is about 66.8 Mt (based on 2010 data), as compared to a 49 Mt mean of estimated copper in undiscovered deposits and a 34 Mt median of estimated copper in undiscovered deposits. The copper contained in known porphyry copper deposits represents about 58 percent of the total of known and undiscovered porphyry copper deposits (based on mean values). About 86 percent of the increase in estimated copper resources between 1993 and 2009 resulted from the discovery of extensions to known deposits. Nevertheless, exploration for undiscovered deposits continues, especially in and around significant prospects and in parts of permissive tracts that are mostly hidden beneath younger volcanic, sedimentary, or vegetated surficial cover.

British Columbia, Yukon Territory↗