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Scoresum - A technique for displaying and evaluating multi-element geochemical information, with examples of its use in regional mineral assessment programs

A technique called SCORESUM was developed to display a maximum of multi-element geochemical information on a minimum number of maps for mineral assessment purposes. The technique can be done manually for a small analytical data set or can be done with a computer for a large data set. SCORESUM can be used with highly censored data and can also weight samples so as to minimize the chemical differences of diverse lithologies in different parts of a given study area. The full range of reported analyses for each element of interest in a data set is divided into four categories. Anomaly scores — values of O (background), 1 (weakly anomalous), 2 (moderately anomalous), and 3 (strongly anomalous) — are substituted for all of the analyses falling into each of the four categories. A group of elements based on known or suspected association in altered or mineralized areas is selected for study and the anomaly scores for these elements are summed for each sample site and then plotted on a map. Some of the results of geochemical studies conducted for mineral assessments in two areas are briefly described. The first area, the Mokelumne Wilderness and vicinity, is a relatively small and geologically simple one. The second, the Walker Lake 1° × 2° quadrangle, is a large area that has extremely complex geology and that contains a number of different mineral deposit environments. These two studies provide examples of how the SCORESUM technique has been used (1) to enhance relatively small but anomalous areas and (2) to delineate and rank areas containing geochemical signatures for specific suites of elements related to certain types of alteration or mineralization.

Journal of Geochemical Exploration↗

Using stream-side groundwater discharge for geochemical exploration in mountainous terrain

Groundwater chemistry has been predominantly used in geochemical exploration studies to identify mineralized targets concealed under transported cover in areas with gentle topography. Another potentially valuable ap-plication that has received little attention is using groundwater chemistry to identify deposits concealed within mountain ridges. A number of geochemical exploration studies have employed surface water chemistry in hilly and mountainous terrain and have demonstrated mixed success. However, groundwater chemistry is potentially a more refined and powerful tool because groundwater sample locations can be selected to target a specific hillslope zone, whereas surface water integrates the geochemical signature of the entire watershed area above the sample site. In this study, we propose an approach that utilizes shallow groundwater samples collected from near-stream, hand-installed sampling points. We tested this approach in Handcart Gulch, an unmined catchment in the Montezuma Mining District, Colorado, USA, where previous studies suggested the possible presence of a concealed mineral occurrence. Seventeen near-stream mini-boreholes were drilled in a stream-parallel 3.3-km-long transect to depths of ~2 m in ferricrete (iron-oxide cemented colluvium and alluvium) using a handheld rock-coring drill. Groundwater in the mini-boreholes was sampled for major and trace element chemistry, as well as environmental tracers including stable water isotopes, dissolved noble gases, helium isotopes, and tritium, to identify possible variations in groundwater age and recharge conditions/sources. Chemistry data delineate a well-defined 900-m-wide zone of elevated SO4, Cu, and other metal concentrations on the east side of the stream. In this zone, Cu concentrations up to 2670 μg/L are 1–3 orders of magnitude greater than concentrations in upstream and downstream areas. Environmental tracer data show no corresponding anomalies in groundwater age or recharge conditions/sources within the zone, suggesting that the source of the elevated metals is a change in bedrock mineralogy as opposed to other hydrologic factors. The groundwater samples therefore successfully identify and refine the location of a potential concealed high-Cu mineral occurrence in the watershed, de-monstrating that near-stream groundwater discharge may be a valuable medium for geochemical exploration in mountainous areas.

Colorado↗

Conceptual models in exploration geochemistry-The Basin and Range Province of the Western United States and Northern Mexico

This summary of geochemical exploration in the Basin and Range Province is another in the series of reviews of geochemical-exploration applications covering a large region; this series began in 1975 with a summary for the Canadian Cordillera and Canadian Shield, and was followed in 1976 by a similar summary for Scandinavia (Norden). Rather than adhering strictly to the type of conceptual models applied in those papers, we have made use of generalized landscape geochemistry models related to the nature of concealment of ore deposits. This study is part of a continuing effort to examine and evaluate geochemical-exploration practices in different areas of the world. Twenty case histories of the application of geochemical exploration in both district and regional settings illustrate recent developments in techniques and approaches. Along with other published reports these case histories, exemplifying generalized models of concealed deposits, provide data used to evaluate geochemical-exploration programs and specific sample media. Because blind deposits are increasingly sought in the Basin and Range Province, the use of new sample media or anomaly-enhancement techniques is a necessity. Analysis of vapors or gases emanating from blind deposits is a promising new technique. Certain fractions of stream sediments show anomalies that are weak or not detected in conventional minus 80-mesh fractions. Multi-element analysis of mineralized bedrock may show zoning patterns that indicate depth or direction of ore. Examples of the application of these and other, more conventional methods are indicated in the case histories. The final section of this paper contains a brief evaluation of the applications of all types of sample media to geochemical exploration in the arid environment of the Basin and Range Province. ?? 1978.

Journal of Geochemical Exploration↗

Ge/Si and 87Sr/86Sr tracers of weathering reactions and hydrologic pathways in a tropical granitoid system

Ge/Si and 87Sr/86Sr data from primary and secondary minerals, soil waters, and stream waters in a tropical granitoid catchment quantitatively reflect mineral alteration reactions that occur at different levels within the bedrock-saprolite-soil zone. Near the bedrock-saprolite interface, plagioclase to kaolinite reaction yields low Ge/Si and 87Sr/86Sr. Higher in the regolith column, biotite weathering and kaolinite dissolution drive Ge/Si and 87Sr/86Sr to high values. Data from streams at base flow sample the bedrock-saprolite interface zone, while at high discharge solutes are derived from upper saprolite-soil zone. Coupled Ge/Si and 87Sr/86Sr can be effective tools for quantifying the importance of specific weathering reactions, and for geochemical hydrograph separation. ?? 2005 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

The partitioning of copper among selected phases of geologic media of two porphyry copper districts, Puerto Rico

In experiments designed to determine the manner in which copper is partitioned among selected phases that constitute geologic media, we have applied the five-step sequential extraction procedure of Chao and Theobald to the analysis of drill core, soils, and stream sediments of the Rio Vivi and Rio Tanama porphyry copper districts of Puerto Rico. The extraction procedure affords a convenient means of determining the trace-metal content of the following fractions: (1) Mn oxides and “reactive” Fe oxides; (2) “amorphous” Fe oxides; (3) “crystalline” Fe oxides; (4) sulfides and magnetite; and (5) silicates. An additional extraction between steps (1) and (2) was performed to determine organic-related copper in stream sediments. The experimental results indicate that apportionment of copper among phases constituting geologic media is a function of geochemical environment. Distinctive partitioning patterns were derived from the analysis of drill core from each of three geochemical zones: (a) the supergene zone of oxidation; (b) the supergene zone of enrichment; and (c) the hypogene zone; and similarly, from the analysis of; (d) soils on a weakly leached capping; (e) soils on a strongly leached capping; and (f) active stream sediment. The experimental results also show that geochemical contrasts (anomaly-to-background ratios) vary widely among the five fractions of each sampling medium investigated, and that at least one fraction of each medium provides substantially stronger contrast than does the bulk medium. Fraction (1) provides optimal contrast for stream sediments of the district; fraction (2) provides optimal contrast for soils on a weakly leached capping; fraction (3) provides optimal contrast for soils on a strongly leached capping. Selective extraction procedures appear to have important applications to the orientation and interpretive stages of geochemical exploration. Further investigation and testing of a similar nature are recommended.

Puerto Rico↗

Regional geochemical studies in the Patagonia Mountains, Santa Cruz County, Arizona

The Patagonia Mountains in southern Arizona contain the deeply buried porphyry copper system at Red Mountain as well as a number of other base- and precious-metal mines and prospects. The range contains complex Basin and Range geology with units ranging in age from Precambrian to Holocene. Rock types present include igneous intrusive and extrusive units as well as sedimentary and metamorphic units, most of which have been tectonically disturbed. A total of 264 stream-sediment samples were collected and analyzed for 32 elements. Geochemical maps for Sb, Ag, Pb, Te, B, Mn, Au, Zn, Cu (total), Cu (cold-extractable), and Mo, as well as for Cu (cold-extractable)/Cu (total) and Fe/Mn, are presented. Anomaly patterns for these elements generally occur over the Red Mountain deposit and (or) along a north-northwest trend parallel to the major Harshaw Creek Fault. Much of the entire area sampled contains widespread anomalies for Pb, Te, and Cu; the other elements are only locally anomalous. Various plots of ratios of Cu (cold-extractable) to Cu (total) did not produce any new information not readily apparent on either one of the two copper maps. A plot of ratios of Fe to Mn delineated many areas of pyrite mineralization. Several of these areas may represent the pyritic halos around deeply buried porphyry copper systems. The best ore guide for the Red Mountain porphyry system is the coincidence of positive anomalies of Mo, Pb, and Te and a negative anomaly of Mn. Other areas with anomalies of the same suite of elements are present within the Patagonia Mountains. It is concluded that geochemical sampling, even in a highly contaminated area, can be useful in delineating major geologic features, such as porphyry copper belts and major faults. Multielement geochemical surveys on a regional scale can effectively locate large, deeply buried, zoned mineral systems such as that at Red Mountain. Plots of element ratios, where adequately understood, can provide geochemical information not readily discernible from plots of single elements alone.

Arizona↗

Hydrogeochemical prospecting for porphyry copper deposits in the tropical-marine climate of Puerto Rico

A hydrogeochemical survey utilizing waters from streams and springs was conducted in the area of two known porphyry copper deposits in the tropical-marine climate of westcentral Puerto Rico. The most important pathfinder for regional hydrogeochemical surveys is sulfate which reflects the associated pyrite mineralization. Because of increased mobility due to intense chemical weathering and the low pH environment, dissolved copper can also be used as a pathfinder for regional surveys and has the advantage of distinguishing barren pyrite from pyrite associated with copper mineralization. For follow-up surveys, the most important pathfinders are copper, sulfate, pH, zinc, and fluoride. High concentrations of dissolved copper and moderate concentrations of sulfate is a diagnostic indication of nearby sources of copper minerals. An understanding of the geochemical processes taking place in the streambeds and the weathering environment, such as the precipitation of secondary copper minerals, contributes to the interpretation of the geochemical data and the selection of the most favorable areas for further exploration.

Puerto Rico↗

A comparison of iron oxide-rich joint coatings and rock chips as geochemical sampling media in exploration for disseminated gold deposits

We evaluated the effectiveness of iron oxide-rich fracture coatings as a geochemical sampling medium for disseminated gold deposits, as compared with conventional lithogeochemical methods, for samples from the Pinson mine and Preble prospect in southeastern Humboldt County, Nevada. That disseminated gold mineralization is associated with Hg, As, and Sb is clearly demonstrated in these deposits for both fracture coatings and rock chip samples. However, the relationship is more pronounced for fracture coatings. Fracture coatings at Pinson contain an average of 3.61, 5.13, 14.37, and 3.42 times more Au, As, Sb and Hg, respectively, than adjacent rock samples. At Preble, fracture coatings contain 3.13, 9.72, 9.18, and 1.85 times more Au, As, Sb and Hg, respectively, than do adjacent rock samples. Geochemical anomalies determined from fracture coatings are thus typically more intense than those determined from rock samples for these elements. The sizes of anomalies indicated by fracture coatings are also somewhat larger, but this is less obvious. In both areas, Sb anomalies are more extensive in fracture coatings. At Preble, some Hg and Au anomalies are also more extensive in fracture coatings. In addition to halos formed by the Hg, As and Sb, high values for Au/Ag and Zn/(Fe + Mn) are closely associated with gold mineralization at the Pinson mine. The large enhancement in geochemical response afforded by fracture coatings indicates a definite potential in the search for buried disseminated gold deposits.

Journal of Geochemical Exploration↗

Decomposition techniques

Sample decomposition is a fundamental and integral step in the procedure of geochemical analysis. It is often the limiting factor to sample throughput, especially with the recent application of the fast and modern multi-element measurement instrumentation. The complexity of geological materials makes it necessary to choose the sample decomposition technique that is compatible with the specific objective of the analysis. When selecting a decomposition technique, consideration should be given to the chemical and mineralogical characteristics of the sample, elements to be determined, precision and accuracy requirements, sample throughput, technical capability of personnel, and time constraints. This paper addresses these concerns and discusses the attributes and limitations of many techniques of sample decomposition along with examples of their application to geochemical analysis. The chemical properties of reagents as to their function as decomposition agents are also reviewed. The section on acid dissolution techniques addresses the various inorganic acids that are used individually or in combination in both open and closed systems. Fluxes used in sample fusion are discussed. The promising microwave-oven technology and the emerging field of automation are also examined. A section on applications highlights the use of decomposition techniques for the determination of Au, platinum group elements (PGEs), Hg, U, hydride-forming elements, rare earth elements (REEs), and multi-elements in geological materials. Partial dissolution techniques used for geochemical exploration which have been treated in detail elsewhere are not discussed here; nor are fire-assaying for noble metals and decomposition techniques for X-ray fluorescence or nuclear methods be discussed.

Journal of Geochemical Exploration↗

Flameless atomic-absorption determination of gold in geological materials

Gold in geologic material is dissolved using a solution of hydrobromic acid and bromine, extracted with methyl isobutyl ketone, and determined using an atomic-absorption spectrophotometer equipped with a graphite furnace atomizer. A comparison of results obtained by this flameless atomic-absorption method on U.S. Geological Survey reference rocks and geochemical samples with reported values and with results obtained by flame atomic-absorption shows that reasonable accuracy is achieved with improved precision. The sensitivity, accuracy, and precision of the method allows acquisition of data on the distribution of gold at or below its crustal abundance.

Journal of Geochemical Exploration↗

Geochemistry of glacial sediments in the area of the Bend massive sulfide deposit, north-central Wisconsin

Geochemical exploration in northern Wisconsin has been problematic because of thick glacial overburden and complex stratigraphic record of glacial history. To assess till geochemical exploration in an area of thick glacial cover and complex stratigraphy samples of glacial materials were collected from cores from five rotasonic boreholes near a known massive sulfide deposit, the Bend deposit in north-central Wisconsin. Diamond drilling in the Bend area has defined a long, thin zone of mineralization at least partly intersected at the bedrock surface beneath 30-40 m of unconsolidated glacial sediments. The bedrock surface has remnant regolith and saprolite resulting from pre-Pleistocene weathering. Massive sulfide and mineralized rock collected from diamond drill core from the deposit contain high (10s to 10,000s ppm) concentrations of Ag, As, Au, Bi, Cu, Hg, Se, Te, and Tl. Geochemical properties of the glacial stratigraphic units helped clarify the sequence and source areas of several glacial ice advances preserved in the section. At least two till sheets are recognized. Over the zone of mineralization, saprolite and preglacial alluvial and lacustrine samples are preserved on the bedrock surface in a paleoriver valley. The overlying till sheet is a gray, silty carbonate till with a source hundreds of kilometers to the northwest of the study area. This gray till is overlain by red, sandy till with a source to the north in Proterozoic rocks of the Lake Superior area. The complex glacial stratigraphy confounds down-ice geochemical till exploration. The presence of remnant saprolite, preglacial sediment, and far-traveled carbonate till minimized glacial erosion of mineralized material. As a result, little evidence of down-ice glacial dispersion of lithologic or mineralogic indicators of Bend massive sulfide mineralization was found in the samples from the rotasonic cores. This study points out the importance of determining glacial stratigraphy and history, and identifying favorable lithologies required for geochemical exploration. Drift prospecting in Wisconsin and other areas near the outer limits of the Pleistocene ice sheets may not be unsuccessful, in part, because of complex stratigraphic sequences of multiple glaciations where deposition dominates over erosion. ?? 2004 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

The distribution of selected elements and minerals in soil of the conterminous United States

In 2007, the U.S. Geological Survey initiated a low-density (1 site per 1600 km 2 , 4857 sites) geochemical and mineralogical survey of soil of the conterminous United States as part of the North American Soil Geochemical Landscapes Project. Three soil samples were collected, if possible, from each site; (1) a sample from a depth of 0 to 5 cm, (2) a composite of the soil A-horizon, and (3) a deeper sample from the soil C-horizon or, if the top of the C-horizon was at a depth greater than 100 cm, from a depth of approximately 80–100 cm. The < 2 mm fraction of each sample was analysed for a suite of 45 major and trace elements following near-total multi-acid digestion. The major mineralogical components in samples from the soil A- and C-horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling ended in 2010 and chemical and mineralogical analyses were completed in May 2013. Maps of the conterminous United States showing predicted element and mineral concentrations were interpolated from actual soil data for each soil sample type by an inverse distance weighted (IDW) technique using ArcGIS software. Regional- and national-scale map patterns for selected elements and minerals apparent in interpolated maps are described here in the context of soil-forming factors and possible human inputs. These patterns can be related to (1) soil parent materials, for example, in the distribution of quartz, (2) climate impacts, for example, in the distribution of feldspar and kaolinite, (3) soil age, for example, in the distribution of carbonate in young glacial deposits, and (4) possible anthropogenic loading of phosphorus (P) and lead (Pb) to surface soil. This new geochemical and mineralogical data set for the conterminous United States represents a major step forward from prior national-scale soil geochemistry data and provides a robust soil data framework for the United States now and into the future.

Journal of Geochemical Exploration↗

Gas-water-rock interactions in sedimentary basins: CO2 sequestration in the Frio Formation, Texas, USA

To investigate the potential for the geologic storage of CO2 in saline sedimentary aquifers, 1600??ton of CO2 were injected at ???1500 m depth into a 24-m sandstone section of the Frio Formation - a regional reservoir in the US Gulf Coast. Fluid samples obtained from the injection and observation wells before, during and after CO2 injection show a Na-Ca-Cl type brine with 93,000??mg/L TDS and near saturation of CH4 at reservoir conditions. As injected CO2 gas reached the observation well, results showed sharp drops in pH (6.5 to 5.7), pronounced increases in alkalinity (100 to 3000??mg/L as HCO3) and Fe (30 to 1100??mg/L), and significant shifts in the isotopic compositions of H2O and DIC. Geochemical modeling indicates that brine pH would have dropped lower, but for buffering by dissolution of calcite and Fe oxyhydroxides. Post-injection results show the brine gradually returning to its pre-injection composition. ?? 2006 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

Estimation of the geochemical threshold and its statistical significance

A statistic is proposed for estimating the geochemical threshold and its statistical significance, or it may be used to identify a group of extreme values that can be tested for significance by other means. The statistic is the maximum gap between adjacent values in an ordered array after each gap has been adjusted for the expected frequency. The values in the ordered array are geochemical values transformed by either ln( χ - α ) or ln( α - χ ) and then standardized so that the mean is zero and the variance is unity. The expected frequency is taken from a fitted normal curve with unit area. The midpoint of an adjusted gap that exceeds the corresponding critical value may be taken as an estimate of the geochemical threshold, and the associated probability indicates the likelihood that the threshold separates two geochemical populations. The adjusted gap test may fail to identify threshold values if the variation tends to be continuous from background values to the higher values that reflect mineralized ground. However, the test will serve to identify other anomalies that may be too subtle to have been noted by other means.

Journal of Geochemical Exploration↗

Fractionation of palladium and platinum in a Mesozoic diabase sheet, Gettysburg basin, Pennsyvania: Implications for mineral exploration

The York Haven diabase sheet displays clear-cut evidence of fractionation of Pd and Pt during differentiation of a high-Ti (about 1.1%) quartz-normative tholeiitic magma (York Haven type). At York Haven the sheet is about 750 m thick. It is characterized by abundant cumulus MgO-rich orthopyroxene (bronzite), and is markedly depleted in incompatible elements relative to the chilled margins. In contrast, at Reesers Summit, 16 km to the northwest, the sheet is about 500 m thick and consists of evolved rocks that have contents of incompatible elements two to three times greater than in the enclosing chilled margins. These evolved rocks represent complementary fractions to the cumulate rocks at York Haven. Mineralogic, petrologic and geochemical variations suggest considerable lateral migration and fractionation of the initial magma. Chilled margins of both sections have essentially the same Pd and Pt contents (10 ppb each) and similar Pd to Pt ratios (1.2). During differentiation, the cumulate rocks at York Haven were enriched in Pt and depleted in Pd, whereas at Reesers Summit, the low-MgO diabase and ferrogabbro zone were enriched in Pd relative to Pt. Anomalously high contents of Pd (to 165 ppb), Au (to 54 ppb), and Te (to 26 ppb) were found in an iron- (to 18%) and chlorine- (to 0.44%) rich ferrogabbro at Reesers Summit, suggesting possible late or post-magmatic enrichment of precious metals. Field relations, geochemical and petrographic data provide guides for further exploration for Pd and Pt in differentiated high-Ti quartz-normative diabase sheets. Based on present information, the most favorable sites for economic deposits are late-stage differentiates enriched in Fe and Cl. ?? 1990.

Pennsylvania↗

Reconnaissance exploration geochemistry in the central Brooks Range, northern Alaska: Implications for exploration of sediment-hosted zinc-lead-silver deposits

A reconnaissance geochemical survey was conducted in the southern Killik River quadrangle, central Brooks Range, northern Alaska. The Brooks Range lies within the zone of continuous permafrost which may partially inhibit chemical weathering and oxidation. The minus 30-mesh and nonmagnetic heavy-mineral concentrate fractions of sediment samples were chosen as the sample media for the survey so that mechanical rather than chemical dispersion patterns would be enhanced. A total of 263 sites were sampled within the southern half of the Killik River quadrangle at an average sample density of approximately one sample per 12 km 2 . All samples were submitted for multi-element analyses. In the western and central Brooks Range, several known sediment-hosted Zn-Pb-Ag(-Ba) deposits occur within a belt of Paleozoic rocks of the Endicott Mountains allochthon. Exploration for this type of deposit in the Brook Range is difficult, due to the inherently high background values for Ba, Zn and Pb in shale and the common occurrence of metamorphic quartz-calcite veins, many of which contain traces of sulfide minerals. Stream sediments derived from these sources produce numerous geochemical anomalies which are not necessarily associated with significant mineralization. R-mode factor analysis provides a means of distinguishing between element associations related to lithology and those related to possible mineralization. Factor analysis applied to the multi-element data from the southern Killik River quadrangle resulted in the discovery of two additional Zn-Pb-Ag mineral occurrences of considerable areal extent which are 80–100 km east of any previously known deposit. These have been informally named the Kady and Vidlee. Several lithogeochemical element associations, or factors, and three factors which represent sulfide mineralization were identified: Ag-Pb-Zn (galena and sphalerite) and Fe-Ni-Co-Cu (pyrite ± chalcopyrite) in the concentrate samples and Cd-Zn-Pb-As-Mn in the sediment samples. The distribution of high scores for each individual mineralization factor outlined several relatively large (200–250 km 2 ) geochemically favorable areas. When the distribution of high scores for all three factors were superimposed, samples characterized by high scores for one or both of the concentrate mineralization factors and the mineralization factor in sediments define basin areas of approximately 48 and 64 km 2 surrounding Kady and Vidlee, respectively.

Journal of Geochemical Exploration↗

A rapid, partial leach and organic separation for the sensitive determination of Ag, Bi, Cd, Cu, Mo, Pb, Sb, and Zn in surface geologic materials by flame atomic absorption

A solution of dilute hydrochloric acid, ascorbic acid, and potassium iodide has been found to dissolve weakly bound metals in soils, stream sediments, and oxidized rocks. Silver, Bi, Cd, Cu, Mo, Pb, Sb, and Zn are selectively extracted from this solution by a mixture of Aliquat 336 (tricaprylyl methyl ammonium chloride) and MIBK (methyl isobutyl ketone). Because potentially interfering major and minor elements do not extract, the organic separation allows interference-free determinations of Ag and Cd to the 0.05 ppm level, Mo, Cu, and Zn to 0.5 ppm, and Bi, Pb, and Sb to 1 ppm in the sample using flame atomic absorption spectroscopy. The analytical absorbance values of the organic solution used in the proposed method are generally enhanced more than threefold as compared to aqueous solutions, due to more efficient atomization and burning characteristics. The leaching and extraction procedures are extremely rapid; as many as 100 samples may be analyzed per day, yielding 800 determinations, and the technique is adaptable to field use. The proposed method was compared to total digestion methods for geochemical reference samples as well as soils and stream sediments from mineralized and unmineralized areas. The partial leach showed better anomaly contrasts than did total digestions. Because the proposed method is very rapid and is sensitive to pathfinder elements for several types of ore deposits, it should be useful for reconnaissance surveys for concealed deposits.

Journal of Geochemical Exploration↗

Anomalous gold, antimony, arsenic, and tungsten in ground water and alluvium around disseminated gold deposits along the Getchell Trend, Humboldt County, Nevada

Ground-water, alluvium, and bedrock samples were collected from drill holes near the Chimney Creek, Preble, Summer Camp, and Rabbit Creek disseminated gold deposits in northern Nevada to determine if Au and ore-related metals, such as As, Sb, and W, are being hydromorphically mobilized from buried mineralized rock, and, if they are, to determine whether the metal-enriched ground water is reacting with the alluvial material to produce a geochemical anomaly within the overburden. Results of chemical analyses of drill-hole water samples show the presence of hydromorphic dispersion anomalies of Au, As, Sb, and W in the local ground-water systems associated with these deposits. Background concentrations for Au in the ground water up-gradient from the buried deposits was less than 1 nanogram per liter (ng/L), near the deposits the Au values ranged from 1 to 140 ng/ L, and in drill holes penetrating mineralized rock, concentrations of Au in the ground water were as high as 4700 ng/L. Highest concentrations of Au were found in ground-water samples where the measured E h and the distribution of arsenic species, arsenite [As(III)] and arsenate [As(V)], indicated oxidizing redox potentials. Similarly, As, Sb, and W concentrations in the ground water near the deposits were significantly enriched relative to concentrations in the ground water up-gradient from the deposits. In general, however, the highest concentrations of As, Sb, and W occurred in ground-water samples where the measured E h and the distribution of arsenic species indicated reducing conditions. Arsenic concentrations ranged from 9 to 710 micrograms per liter (μg/L); Sb, from less than 0.1 to 250 μg/L; and W, from 1 to 260 μg/L. In addition, analysis of sequential dissolution and extraction solutions of drill cuttings of alluvium and bedrock indicate geochemical anomalies of gold and ore-related metals in the overburden at depths corresponding to the location of the present-day water table. This relationship suggests that water-rock reactions around these buried deposits are active and that this information could be very useful in exploration programs for concealed disseminated gold deposits.

Journal of Geochemical Exploration↗