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USGS2025

A review of abrupt permafrost thaw: Definitions, usage, and a proposed conceptual framework

Purpose of Review We review how ‘abrupt thaw’ has been used in published studies, compare these definitions to abrupt processes in other Earth science disciplines, and provide a definitive framework for how abrupt thaw should be used in the context of permafrost science. Recent Findings We address several aspects of permafrost systems necessary for abrupt thaw to occur and propose a framework for classifying permafrost processes as abrupt thaw in the future. Based on a literature review and our collective expertise, we propose that abrupt thaw refers to thaw processes that lead to a substantial persistent environmental change within a few decades. Abrupt thaw typically occurs in ice-rich permafrost but may be initiated in ice-poor permafrost by external factors such as hydrologic change (i.e., increased streamflow, soil moisture fluctuations, altered groundwater recharge) or wildfire. Summary Permafrost thaw alters greenhouse gas emissions, soil and vegetation properties, and hydrologic flow, threatening infrastructure and the cultures and livelihoods of northern communities. The term ‘abrupt thaw’ has emerged in scientific discourse over the past two decades to differentiate processes that rapidly impact large depths of permafrost, such as thermokarst, from more gradual, top-down thaw processes that impact centimeters of near-surface permafrost over years to decades. However, there has been no formal definition for abrupt thaw and its use in the scientific literature has varied considerably. Our standardized definition of abrupt thaw offers a path forward to better understand drivers and patterns of abrupt thaw and its consequences for global greenhouse gas budgets, impacts to infrastructure and land-use, and Arctic policy- and decision-making.

Current Climate Change Reports↗
USGS2025

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California↗
USGS2024

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey↗
USGS2026

Hyperspectral narrowband imaging spectroscopy: A new paradigm for Earth observation

This editorial introduces the Special Issue entitled “Hyperspectral Narrowband Imaging Spectroscopy: A New Paradigm for Earth Observation” in the August 2026 issue of Photogrammetric Engineering & Remote Sensing (PE&RS), the flagship journal of the American Society for Photogrammetry and Remote Sensing (ASPRS). This volume represents the fourth dedicated hyperspectral special issue published in PE&RS, following earlier contributions by Thenkabail et al. (2025, 2024a, 2024b), and continues ASPRS’s commitment to advancing cutting‑edge imaging spectroscopy research and its applications across Earth system science. Remote sensing is undergoing one of the most profound transformations in its history. The emergence of hyperspectral narrowband (HNB) imaging spectroscopy data, capable of acquiring hundreds of contiguous, narrow spectral bands, has shifted the discipline from observing Earth in a handful of broad spectral windows to capturing continuous spectral signatures of the Planet. This transition marks a decisive break from the multispectral paradigm that has dominated satellite remote sensing for nearly five decades, driven by the advent of new orbital imaging spectrometers such as EnMAP, PRISMA, and NASA’s EMIT, and by the forthcoming Surface Biology and Geology (SBG) mission ((Pires Silva et al., 2026; Bourriz et al., 2025; Thenkabail et al., 2025; Chabrillat et al., 2024; Aneece et al., 2024; Dave et al., 2024; Thenkabail et al., 2024a; Thenkabail et al., 2024b; Thenkabail, 2024a; Thenkabail, 2024b; Thompson et al., 2022; Kokaly et al., 2022; Aneece & Thenkabail, 2022; Cawse Nicholson et al., 2021; Guanter et al., 2021; Vangi et al., 2021; Thenkabail et al., 2021). These missions (e.g., Table 1) deliver unprecedented spectral fidelity, improved signal to noise ratios, and global coverage capabilities, enabling a new era of quantitative, spectroscopy based Earth observation. Where multispectral broadbands (MBBs) provide only a few discrete measurements along the electromagnetic spectrum, HNB systems deliver rich, diagnostic information that enables scientists to characterize Earth’s surface with unprecedented biochemical, biophysical, and structural detail (Figure 1a, 1b). The implications for environmental monitoring, agriculture, water resources, and mineral exploration are profound. Several overarching themes emerge: • Spectral fidelity matters. The ability to preserve subtle absorption features is essential for mineral mapping, vegetation trait retrieval, and biochemical modeling. • AI and deep learning are indispensable. From destriping to classification, modern analytics must be scalable, label‑efficient, and capable of exploiting the full spectral–spatial richness of HNB data. • Physics‑based and data‑driven approaches must converge. Radiative transfer models such as PROSAIL, enhanced with localized soil parameterizations, remain foundational for biophysical retrievals and model‑based inference. • Dimensionality reduction and feature extraction are critical. Techniques such as L1‑ISOMAP demonstrate that intelligent manifold learning can unlock the structure of fused, high‑dimensional datasets. • Next‑generation architectures must be interactive and multimodal. ICTNet exemplifies the future of hyperspectral classification: hybrid, synergistic, and capable of modeling both local textures and global spectral dependencies.

Photogrammetric Engineering and Remote Sensing (PE↗
USGS2024

A methodology to estimate CO2 and energy gas storage resources in depleted conventional gas reservoirs

Depleted hydrocarbon reservoirs are subsurface geological structures capable of sequestering vast quantities of carbon dioxide (CO 2 ) as well as storing other energy gases for later usage, such as natural gas, and potentially hydrogen (H 2 ). Here we outline a methodology to quantify multi-gas storage resources in depleted conventional gas reservoirs for usage in assessments by the United States Geological Survey (USGS) at the scale of sedimentary basins. The methodology consists first of quantifying accessible pore volume in a depleted reservoir for natural gas storage using up to three equations. Input data are derived from commonly reported or estimated reservoir parameters and natural gas production volumes, and equations may be combined in linear models to improve pore volume estimates. Storage estimates from these equations are tested and validated for 31 reservoirs in the Michigan Basin Province, USA that were previously converted to underground gas storage facilities and have known (federally reported) natural gas storage capacities. Secondly, natural gas storage capacities can be transformed via fluid substitution calculations to estimate the storage resources for non-native fluids, applied here for, CO 2 , H 2 , and methane-H 2 blends, accounting for molecule-specific deviations from ideal gas behavior at reservoir pressures and temperatures as well as differing storage efficiencies. Importantly, the storage of non-native fluids may not be appropriate in all depleted gas reservoir settings due to potential risks like leakage, in particular in the case of H 2 storage, requiring additional knowledge of caprock sealing capacity. Given this caveat, we demonstrate the fluid substitution method for natural gas reservoirs of the Northern Niagaran Reef and Southern Niagaran Reef USGS plays in the Michigan Basin Province, as these trends of Silurian pinnacle reefs are capped with tight-sealing evaporite facies. The deterministic equations outlined from this methodology can be incorporated into future probabilistic USGS gas storage assessments for CO 2 , H 2 , and natural gas resources in the United States.

Michigan↗
USGS2026

Bottom-up characterization of geologic methane emissions in the San Juan Basin in the southwestern USA

Methane is a potent greenhouse gas that plays an important role in atmospheric chemistry and global warming. The current global methane budget has large uncertainties, and a better understanding of the budget would help to guide strategies for reducing anthropogenic emissions to fight climate change. Natural geologic methane emissions are a particularly poorly constrained source, with top-down estimates from 14 C in ice cores suggesting much lower geologic emissions than bottom-up scaling of direct flux measurements. Our study aims to contribute to resolving this discrepancy through improved bottom-up characterization of geologic methane seepage in the San Juan Basin in southwestern Colorado and northwestern New Mexico, USA. We performed 983 new flux chamber measurements in this basin during summer 2022 and winter 2023 field campaigns. Our results, in combination with prior measurements, suggest that natural seepage in the San Juan Basin only occurs on or near the Fruitland coal outcrop. Specifically, our new measurements confirm previous measurements of seepage along the northwestern exposure of the Fruitland outcrop in Colorado (a known hydrodynamic overpressure region) and for the first time, identified seepage locations along the southernmost Fruitland outcrop exposure in New Mexico, in association with a coal cleat and a fault. Overall, seepage along the Fruitland coal outcrop is heterogeneously distributed, with both positive and negative (interpreted as microbial soil sink) methane fluxes. Features that are hypothesized to be predictive of seepage (e.g., faults) were not associated with positive methane fluxes in areas outside of the Fruitland outcrop. Our best estimate for total geologic methane seepage in the San Juan Basin from spatial interpolation and statistical upscaling is approximately 0.14 Tg CH 4 /yr, with a range from 0.029 to 0.48 Tg CH 4 /yr. This best-estimate value is lower than a previous bottom-up estimate from a gridded seepage inventory, but higher than a previous top-down estimate.

Colorado, New Mexico↗
USGS2024

U.S.-Mexico Borderland & vegetation community map

People on both sides of the United States-Mexico border need a high-resolution, binational vegetation community map that spans the entire United States-Mexico borderlands. Traditionally, mapping efforts in this region were impeded by complex logistics related to the international border, differing national needs and plans, and resource allocations and priorities. To address this need, scientists from the U.S. Geological Survey (USGS) Southwest Biological Science Center partnered with the Sonoran Joint Venture, the U.S. Fish and Wildlife Service (FWS) Migratory Bird Program, data engineers from the Department of Biosystems Engineering at the University of Arizona, and collaborators from the Wildlands Network, the Borderlands Program to produce the first prototype land cover map within the overlapping Mojave Desert, Sonoran Desert, and the North American Bird Conservation Initiative’s Bird Conservation Region 33 (BCR33) using Landsat satellite data . BCR33 is an area of high biodiversity, providing habitat for bird species of concern and other wildlife. The land cover map supports FWS recovery plan efforts related to conservation planning activities for many species, including Yellow-billed Cuckoo ( Coccyzus americanus ), Cactus Ferruginous Pygmy-Owl ( Glaucidium brasilianum cactorum ), Southwestern Willow Flycatcher ( Empidonax traillii extimus ), Yuma Ridgway’s Rail ( Rallus obsoletus yumanensis ), Bendire’s thrasher ( Toxostoma bendirei ), LeConte’s thrasher ( Toxostoma lecontei ), Masked Bobwhite ( Colinus virginianus ridgwayi ), jaguar ( Panthera onca ), and endangered plants such as Bartram’s stonecrop ( Graptopetalum bartramii ) and the Pima pineapple cactus ( Coryphantha robustispina ssp. robustispina ). In 2024, a Phase-II map for the full BCR33 region was completed, increasing the understanding of the binational nature of natural communities. The published map and associated paper can be found here .

Borderland↗
USGS2025

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan↗
USGS2024

New methodology for assessing underground natural gas storage resources – Example from Michigan Basin, United States

Energy consumption in the United States (U.S.) and across the world is shifting away from traditional fossil fuels like coal and oil, and towards natural gas and renewable sources, including hydrogen. Because gas demand is typically greatest during cold seasons and renewable sources sometimes produce variable supplies, it is important to store energy for use when demand exceeds supply. Whereas batteries and tanks typically store energy above ground, geologic (underground) storage may be able to retain much greater quantities of energy over much longer durations (e.g., Matos et al. 2019; Buursink et al. 2023). Consequently, the U.S. Geological Survey (USGS) is developing a methodology to locate new geologic energy storage sites with an initial focus on depleted hydrocarbon reservoirs followed by estimates of associated pore space or gas storage capacity. Depleted hydrocarbon fields in Michigan Basin in the U.S. already host large quantities of injected natural gas (about 681 billion cubic feet of seasonal gas capacity in 42 gas storage facilities; U.S. Energy Information Administration 2024). Therefore, we used this basin as an example to assess potential new storage resources alongside existing storage capacity and carbon dioxide sequestration resources (e.g., Katz and Coats 1968; Haagsma et al. 2020). In Michigan Basin gas storage is taking place in reservoirs within several key hydrocarbon producing formations with different lithologies, including the informal Stray sandstone of the Michigan Formation and the pinnacle reefs of the Niagara Group (Gautier et al. 1995; Swezey et al. 2015). The assessment methodology introduced here consists of two steps relying on both well information and reservoir data.

Michigan↗
USGS2026

Repeated coral bleaching events have eroded reef accretion potential in the Florida Keys

Coral bleaching is now the primary driver of coral-reef degradation globally, threatening the persistence of coral-reef functions and the invaluable ecosystem services they support. The Florida Keys have been impacted by four severe, regional-scale coral-bleaching events, which occurred in 1997–1998, 2005, 2014–2015, and 2023. Our aim in this study was to quantify the effects of those thermal-stress events on the persistence of coral-reef structures. We leveraged long-term coral-reef monitoring data to quantify the impacts of coral bleaching on coral cover, carbonate production, and reef-accretion potential throughout the Florida Keys from 1996–2024. Our study indicates that coral bleaching drove significant declines of reef-building corals, which successively diminished regional-scale reef-accretion potential (from 1.65 ± 0.33 mm y -1 in 1996) and culminated with a regional-scale transition to net reef erosion (-0.12 ± 0.08 mm y -1 ) following the 2023 event. Coral bleaching was the primary driver of declining reef-building capacity, with the cumulative impacts of the four coral-bleaching events accounting for >75% of total declines since 1996. The 1997–1998 event alone drove ~50% of overall declines, largely due to losses of the shallow-water ecosystem engineer, Acropora palmata . More moderate impacts of thermal stress on regional reef-accretion potential in 2005 (6%) and 2014–2015 (9%) could lend some support to the hypothesis that the remaining corals were more thermally tolerant; however, the unprecedented thermal stress event in 2023 caused widespread coral-bleaching and bleaching-related mortality, and caused an additional 12% of the total decline in reef-accretion potential. Stony-coral tissue loss disease accounted for an additional 6% of the decline, with the remaining 19% unexplained. Coral bleaching has already dramatically reshaped the structure and function of coral reefs in the Florida Keys over the last three decades. With the high likelihood that thermal stress will accelerate moving forward, the persistence of Florida’s essential coral-reef functions and services is uncertain.

Florida↗
USGS2025

Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization

Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.

South Dakota, Wyoming↗
USGS2024

Insights on gas hydrate formation and growth within an interbedded sand reservoir from well logging at the Qiongdongnan Basin, South China Sea

Although variable well log resolution and its control on saturation estimation has been studied, it has not been directly applied to a specific location to explore the nature of gas hydrate within a sand reservoir. We applied in-situ measurements of resistivities, neutron porosity, and gamma ray at two sites in the Qiongdongnan Basin, South China Sea (QDN-W05–2021 and QDN-W08–2021) to investigate the reservoir parameters of a hydrate-bearing sand reservoir. Our results show that gas hydrate is distributed in 5 zones with a total thickness of 10.7 m and an average saturation of 69% at the QDN-W05–2021 site, while they are distributed in 2 zones with a total thickness of 4.3 m and an average saturation of 49% at the QDN-W08–2021 site. We found that variances in saturations estimated from lateral-extra deep button (RX), phase shift (P40H-P40L), and attenuation (A40H-A40L) resistivities within the laterally mapped continuous sand body were affected by the nature of gas hydrate occurrences. Results indicate gas hydrate forms and accumulates at the center of the sand layer and tends to be less or not present toward the top and base. Integrated with seismic data, the in-situ measurements provide insights in the evolution of a mushroom-shaped, hydrate-gas reservoir system. In the system, free gas is likely horizontally transported from the top-center of the gas chimney to the surrounding areas in the early stage dominated by a warm-gas environment, whereas hydrate forms in the opposite pathway starting from the surrounding areas in the following stage with temperature reducing. Our study suggests that high-resolution in-situ measurements not only are a tool to identify the physical properties, but also can be used to help explain the physical process of hydrate growth and accumulation.

Marine Geology↗
USGS2024

Influence of inherited structure on flexural extension in foreland basin systems: Evidence from the northern Arkoma basin and southern Ozark dome, USA

Extensional faults are key components of foreland basin systems. They form within the upper crust in response to flexure of the lithosphere and accommodate subsidence within the foredeep and forebulge depozones. Such faults are excellent proxies for orogenic system evolution and control the distribution of natural resources and hazards. However, the spatiotemporal evolution of flexural extension has not been documented previously at a regional scale, thereby limiting our understanding of underlying geodynamic controls. Here, we resolve late Paleozoic flexural extension in the northern Arkoma basin and southern Ozark dome, USA. We synthesize a large database of previous mapping, existing research, subsurface data, and geophysical data into 3D geologic and 2D kinematic models. Mesh surfaces representing several key horizons from the Carboniferous Period (ca. 335-306 Ma) were constructed. These surfaces were built from oil and gas well tops (n = ∼10,000) and surface geologic map contacts using an advanced kriging method. The mesh surfaces are offset by a complex 3D fault network, allowing detailed analysis of along-strike and down-dip variations in fault displacement. Analysis of the 3D model reveals a regular and repeated fault segmentation pattern wherein E -W striking, left- and foreland-stepping en échelon normal faults are segmented by inherited NE striking basement faults. Maximum vertical separation along the E -W normal faults is generally focused between the inherited NE-trending faults. This suggests that the inherited basement faults delocalized extensional strain during late Paleozoic normal faulting. Maximum vertical separation and fault localization may correlate to areas with high-amplitude positive magnetic anomalies interpreted as Mesoproterozoic granitic rocks. Speculative covariance of magnetic anomalies and fault displacements implies that the relatively strong basement granite concentrated stress, leading to localized faulting within the relatively thin sedimentary cover. Lastly, we show that flexural extension migrated southeast to northwest from the Chesterian-Morrowan (ca. 335-319 Ma) to the Desmoinesian (ca. 306 Ma). The migratory flexural extension may be explained by diachronous loading during Pangean assembly, or by synchronous loading but variable load compensation due to inherent factors.

Arkansas, Oklahoma↗
USGS2024

Land-use interactions, Oil-Field infrastructure, and natural processes control hydrocarbon and arsenic concentrations in groundwater, Poso Creek Oil Field, California, USA

Like many hydrocarbon production areas in the U.S., the Poso Creek Oil Field in California includes and is adjacent to other land uses (agricultural and other developed lands) that affect the hydrology and geochemistry of the aquifer overlying and adjacent to oil development. We hypothesize that the distributions of hydrocarbons and arsenic in groundwater in such areas will be controlled by complex interactions between mixed land uses, oil-field infrastructure, and natural processes. In 2020–2021, samples of groundwater and surface water were collected and analyzed for a large suite of inorganic and organic chemicals and isotope and gas tracers to test this hypothesis. Those data are supplemented with ancillary data on historical geochemistry, hydrology, geology, and oil-field infrastructure. Hydrocarbons in groundwater (e.g., methane through pentane gases and benzene) are associated with natural processes (e.g., fault offsets or transition in sediment depositional environment) and oil-field infrastructure (e.g., fluid-migration pathways associated with uncemented annulus in oil wells or unlined pits). Arsenic concentrations >10 μg per liter (μg/L; maximum concentration 12.9 μg/L) are associated with natural processes in old, high-pH groundwater, and more recent recharge of water from natural and/or engineered recharge processes. Along the southwest margin of the oil field, pumping for drinking-water and irrigation supplies in combination with engineered groundwater recharge produce a depression in groundwater elevations where groundwater with elevated sulfate concentrations from agricultural areas and groundwater with hydrocarbons from the oil field mix to produce a zone of sulfate reduction that removes hydrocarbons and arsenic from groundwater but produces elevated sulfide (S 2- ) concentrations (maximum concentration 29 mg per liter, mg/L). In this study, multiple approaches were required to resolve the overlapping effects of land uses, oil-field infrastructure, and natural processes on the distributions of hydrocarbons and arsenic in groundwater. The combined use of geographic, historical, physical, chemical, isotopic, and other information to constrain processes could be a useful approach for studies in other hydrocarbon-production areas. This is particularly important where land uses affect aquifer hydrology to an extent that causes mixing of groundwaters with different chemical compositions.

California↗
USGS2025

Evaluating mass flow meter measurements from chambers for greenhouse gas emissions from orphan wells and other point sources

This study evaluates the performance of a rigid gas flux chamber equipped with a mass flow meter (MFM) for measuring gas emissions from leaking orphan wells and similar pressure-driven gas point sources. We conducted a series of laboratory and field experiments to evaluate the sensitivity, stability, and dynamic range of an MFM chamber system and found an optimal method for sealing the chamber to the ground to isolate the emission source. From these results, we estimate the effects of different soil gas permeabilities on measurements and identify the uncertainty of environmental processes that can impact measurements. Simulations of an MFM chamber are compared to those of a dynamic flux chamber to contrast the data derived with both methodologies and illustrate the potential for measuring high variability leaks with the MFM chamber. Using a low flow resistance MFM and a chamber well-sealed to the ground, it is possible to measure leaks down to 1.08 x 10 -3 cubic meters per hour (m 3 h −1 ) (refenced to 25°/1 atm), corresponding to 0.77 grams per hour (g h −1 ) methane or 2.11 g h −1 carbon dioxide, with a mean uncertainty of 0.89 % relative standard deviation. Environmental processes such as heated gas inside the chamber from solar gain, wind blowing across the chamber vent, and changing humidity in the chamber, can cause variation in MFM measurements. Over 11 d of continuous monitoring under varying weather conditions, the standard deviation of the environmentally sourced signals was found to be 7.40 x 10 -3 m 3 h −1 (equivalent to or 5.27 g h −1 methane or 14.45 g h −1 carbon dioxide). Strategies to obtain the highest quality data from MFM chambers include burying the edges of the chamber below the surface sufficiently deep to seal the chamber edges against gas flow and soaking the dirt with water to lower the chances of escaping gases, while monitoring the gas flow and adjusting the chamber seal to achieve a maximum flow rate.

Atmospheric Measurement Techniques↗