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At least 37 records · Page 2Linked to original sources
USGS2008

Atmospheric Deposition and Surface-Water Chemistry in Mount Rainier and North Cascades National Parks, U.S.A., Water Years 2000 and 2005-2006

High-elevation aquatic ecosystems in Mount Rainier and North Cascades National Parks are highly sensitive to atmospheric deposition of nitrogen and sulfur. Thin, rocky soils promote fast hydrologic flushing rates during snowmelt and rain events, limiting the ability of basins to neutralize acidity and assimilate nitrogen deposited from the atmosphere. Potential effects of nitrogen and sulfur deposition include episodic or chronic acidification of terrestrial and aquatic ecosystems. In addition, nitrogen deposition can cause eutrophication of water bodies and changes in species composition in lakes and streams. This report documents results of a study performed by the U.S. Geological Survey, in cooperation with the National Park Service, of the effects of atmospheric deposition of nitrogen and sulfur on surface-water chemistry in Mount Rainier and North Cascades National Parks. Inorganic nitrogen in wet deposition was highest in the vicinity of North Cascades National Park, perhaps due to emissions from human sources and activities in the Puget Sound area. Sulfur in wet deposition was highest near the Pacific coast, reflecting the influence of marine aerosols. Dry deposition generally accounted for less than 30 percent of wet plus dry inorganic nitrogen and sulfur deposition, but occult deposition (primarily fog) represents a potentially substantial unmeasured component of total deposition. Trend analyses indicate inorganic nitrogen in wet deposition was relatively stable during 1986-2005, but sulfur in wet deposition declined substantially during that time, particularly after 2001, when emissions controls were added to a large powerplant in western Washington. Surface-water sulfate concentrations at the study site nearest the powerplant showed a statistically significant decrease between 2000 and 2005-06, but there was no statistically significant change in alkalinity, indicating a delayed response in surface-water alkalinity. Seasonal patterns in surface-water chemistry and streamflow are strongly influenced by melting of seasonal snowpacks, which release large amounts of dilute, slightly acidic water to terrestrial and aquatic ecosystems during spring snowmelt. Concentrations of sulfate, alkalinity, and base cations in surface water declined rapidly during snowmelt, then gradually recovered during summer and fall. Preferential elution of acidic solutes from the snowpack at the beginning of snowmelt may cause episodic acidification in small alpine streams; evidence is provided by a stream sample collected at one of the sites during spring 2006 that was acidic (pH = 4.8, alkalinity = -18 microequivalents per liter) and had high concentrations of nitrate and sulfate and low concentrations of weathering products. Rain-on-snow events caused sharp declines in specific conductance, which was measured continuously using an in-stream sensor. A strong correlation was observed between measured specific conductance and measured alkalinity (r2 = 0.76), permitting estimation of alkalinity from specific-conductance data using a regression equation. Estimated alkalinity declined by an order of magnitude during the rain-on-snow events, in one case to 8 microequivalents per liter. Actual declines in alkalinity might be greater because the regression equation accounts only for dilution effects; at low concentrations, the relation between specific conductance and alkalinity is likely to be nonlinear and have a negative intercept (negative alkalinity). Thus, episodic acidification is possible during rain-on-snow events. The scale of episodic acidification is unknown, but if it occurs, it could have detrimental effects on aquatic life and amphibians. Historical lake-survey data indicate that most lakes are oligotrophic and have low nitrogen and phosphorus concentrations. Nitrogen limitation is more common in lakes in Mount Rainier National Park than in North Cascades National Park due to higher nitrate concentrations at North Cascades. T

Scientific Investigations Report↗
USGS2006

Geohydrology and water chemistry of the Alexander Valley, Sonoma County, California

This study of the geohydrology and water chemistry of the Alexander Valley, California, was done to provide an improved scientific basis for addressing emerging water-management issues, including potential increases in water demand and changes in flows in the Russian River. The study tasks included (1) evaluation of existing geohydrological, geophysical, and geochemical data; (2) collection and analysis of new geohydrologic data, including subsurface lithologic data, ground-water levels, and streamflow records; and (3) collection and analysis of new water-chemistry data. The estimated total water use for the Alexander Valley for 1999 was approximately 15,800 acre-feet. About 13,500 acre-feet of this amount was for agricultural use, primarily vineyards, and about 2,300 acre-feet was for municipal/industrial use. Ground water is the main source of water supply for this area. The main sources of ground water in the Alexander Valley are the Quaternary alluvial deposits, the Glen Ellen Formation, and the Sonoma Volcanics. The alluvial units, where sufficiently thick and saturated, comprise the best aquifer in the study area. Average recharge to the Alexander Valley is estimated from a simple, basinwide water budget. On the basis of an estimated annual average of 298,000 acre-feet of precipitation, 160,000 acre-feet of runoff, and 113,000 to 133,000 acre-feet of evapotranspiration, about 5,000 to 25,000 acre-feet per year is available for ground-water recharge. Because this estimate is based on differences between large numbers, there is significant uncertainty in this recharge estimate. Long-term changes in ground-water levels are evident in parts of the study area, but because of the sparse network and lack of data on well construction and lithology, it is uncertain if any significant changes have occurred in the northern part of the study area since 1980. In the southern half of the study area, ground-water levels generally were lower at the end of the 2002 irrigation season than at the end of the 1980 season, which suggests that a greater amount of ground water is being pumped in the southern half of the study area in recent years compared with that pumped in the early 1980s. Water-chemistry data for samples collected from 11 wells during 2002-04 indicate that water quality in the study area generally is acceptable for potable use. Two wells, however, each contained one constituent (241 ?g/L of manganese and 1,350 ?g/L of boron) in excess of the recommended standards for drinking water (50 ?g/L and 1,000 ?g/L, respectively). The chemical composition of water from most of the wells sampled for major ions plot as a mixed cation-bicarbonate, magnesium-bicarbonate, or calcium-bicarbonate type water. The ionic composition of the historical and recent samples from wells in the Alexander Valley is similar to that of the historical surface-water samples collected from the Russian River near Healdsburg. This suggests a similar source of water, particularly for wells that are less than 200 feet total depth and perforated in Quaternary alluvial deposits. Water from deeper, non-alluvial wells may contain slightly higher concentrations of sodium as a result of cation exchange. Water samples collected from several wells over an approximately 30-year period suggest a progressive change in water chemistry over time. Samples from the southern part of the valley show a trend towards higher ionic concentrations and increasing concentrations of particular constituents such as sulfate.

California↗
USGS2006

Hydraulic and field water-chemistry characteristics of piedmont alluvial deposits in the Middle Tyger River near Lyman, Spartanburg County, South Carolina, 2005

This study explores the possibility of developing a bank-filtration process to improve water quality in which alluvial deposits serve as a natural sand filter to pretreat water to be used as a secondary drinking-water source in a small piedmont reservoir along the Middle Tyger River near Lyman in Spartanburg County, South Carolina. From January 2004 to September 2005, data from 10 auger borings, 2 sediment cores, 29 ground-penetrating radar transects, and 3 temporary observation wells, and field water-chemistry data were collected and analyzed. These data were collected and used to characterize the lithology, geometry, hydraulic properties, yield potential, and water-chemistry characteristics of the alluvial deposits in the channel and on the right bank of the reservoir. The assessment was undertaken to determine if an adequate amount of water could be withdrawn from the alluvial deposits to sustain a bank-filtration process and to characterize the water chemistry of the surface water and pore water. The heterogeneous alluvial and fill material at the study site--clay, silty clay, clayey sand, fine- to coarse-grained sand, and mica--on the right bank of the Middle Tyger River ranges in thickness from 0.6 to 7 meters, has a calculated horizontal hydraulic conductivity of 1 meter per day, and yields approximately 0.07 liter per second of water. The small calculated horizontal hydraulic conductivity and water yield for these deposits restrict the use of the right bank as a potential bank-filtration site. The coarse-grained alluvial sand deposit in the channel of the Middle Tyger River, however, may be used for a limited bank-filtration process. The discharge during pumping of the channel deposit yielded water at the rate of 1.9 liters per second. The coarse-grained channel deposit is approximately 49 meters wide and 3 meters thick near the dam. At approximately 183 meters upstream from the dam, the channel narrows to roughly 9 meters and the channel deposits thin to approximately 0.1 meter. Slug tests conducted in the channel deposits near the dam produced a calculated horizontal hydraulic conductivity of 60 meters per day. The limited thickness and aerial extent of the coarse-grained channel deposits coupled with large horizontal hydraulic conductivity likely would allow rapid transmission of water and may degrade the effectiveness of some water-chemistry improvements typical of a bank-filtration process. Field water-chemistry data were collected for approximately 1 hour and 45 minutes at 10 to 15 minute intervals to compare the surface-water and pore-water quality in and beneath the channel of the Middle Tyger River. The waterchemistry data indicate that (1) the mean water temperature was higher in surface water (22.5 degrees Celsius) than in pore water (18.5 degrees Celsius), (2) the mean specific conductance was less in surface water (56.9 microsiemens per centimeter at 25 degrees Celsius) than in pore water (125.7 microsiemens per centimeter at 25 degrees Celsius), (3) alkalinity was lower in surface water (22.5 milligrams per liter) than in pore water (44.6 milligrams per liter), and (4) recorded pH values ranged between 6.2 and 6.3 in the surface water and pore water during the sampling period. The flow velocity was orders of magnitude slower in the pore water than in the surface water; therefore, the pore water interacts with the alluvial sediment for a longer period of time producing the variation in water-chemistry data between the two waters.

South Carolina↗
USGS2022

Hydrogeologic characteristics of Hourglass and New Years Cave Lakes at Jewel Cave National Monument, South Dakota, from water-level and water-chemistry data, 2015–21

Jewel Cave National Monument is in the western Black Hills of South Dakota and contains an extensive cave network, including various subterranean water bodies (cave lakes) that are believed to represent the regionally important Madison aquifer. Recent investigations have sought to improve understanding of hydrogeologic characteristics of cave lakes in Jewel Cave. The U.S. Geological Survey, in cooperation with the National Park Service, collected water-level and water-chemistry data within and near Jewel Cave to better understand groundwater interactions in Jewel Cave and to evaluate recharge characteristics of cave lakes. Continuous water-level data were collected at two cave lakes (Hourglass and New Years Lakes) from 2018 to 2021, and discrete measurements were collected by National Park Service staff from 2015 to 2021. Water samples were collected from one stream, one rain collector, three springs, and two cave lakes. The approach for this study included comparing water-level data collected from two cave lakes to historical climate data and using multivariate statistical analyses to evaluate water samples collected during this study and from previous investigations. This study builds on interpretations from previous investigations that collected similar datasets and performed similar analyses. Hydrographs of Hourglass and News Years Lakes from 2015 to 2021 demonstrated the variability of groundwater levels in Jewel Cave in response to dry and wet climate conditions. Hourglass Lake displayed small (up to 4.8 feet), gradual water-level changes, whereas New Years Lake displayed relatively large (up to at least 27.5 feet) and rapid water-level changes. Hourglass and New Years Lakes are about 0.4 mile apart at the land surface, and the water-level elevation between the lakes varied from 61 to 93.5 feet from 2016 to 2021. The proximity and relatively small elevation difference of Hourglass and New Years Lakes indicated different recharge sources and (or) mechanisms were responsible for hydrograph dissimilarities. Water-level changes at Hourglass Lake were similar to water-level changes at a well completed in the Madison aquifer about 9 miles south of Jewel Cave National Monument, which indicated Hourglass Lake may be recharged similar to the regional Madison aquifer along outcrops north of Jewel Cave. New Years Lake displayed almost no similarities to the well completed in the Madison aquifer—indicating a more direct connection to local recharge rather than solely from outcrops recharging the regional Madison aquifer. Results from multivariate statistical analyses of water-chemistry data were used to evaluate recharge observations from water-level data. The water chemistry of Hourglass Lake indicated its water was chemically more similar to precipitation than other groundwater sites sampled. A conceptual karst recharge model indicated that the dominant recharge source to Hourglass Lake was diffuse allogenic recharge from vertical movement of infiltrated precipitation through vertical or near-vertical fractures that extend through the Minnelusa Formation and unsaturated zone of the Madison Limestone. The water chemistry of New Years Lake was chemically similar to Hell Canyon Creek about 0.2 mile from New Years Lake at the land surface. Streamflow loss zones (concentrated allogenic recharge) along Hell Canyon Creek have not been mapped, but their presence in the Jewel Cave area has been speculated by previous investigations. A fault observed in the cave ceiling above New Years Lake by National Park Service staff could provide a natural conduit for direct recharge from Hell Canyon Creek to New Years Lake if the fault is extensive. Additional water-chemistry and water-level data, as well as streamflow data upstream and downstream of the potential streamflow loss zone along Hell Canyon Creek, are needed to prove the presence of this loss zone and discern further correlations between streamflow and water levels in New Years Lake. Observations from previous investigations and this study indicated recharge to Jewel Cave is complex and occurs on various timescales that are affected temporally by precipitation patterns and spatially by hydrologic connection with the overlying Minnelusa aquifer of the Minnelusa Formation.

South Dakota↗
USGS1982

Guidelines and techniques for obtaining water samples that accurately represent the water chemistry of an aquifer

Obtaining ground-water samples that accurately represent the water chemistry of an aquifer is a complex task. Before a ground-water sampling program can be started, an understanding of the kind of chemical data needed and the potential changes in water chemistry resulting from various drilling, well-completion, and sampling techniques is needed. This report provides a basis for such an evaluation and permits a choice of techniques that will result in obtaining the best possible data for the time and money allocated.

Open-File Report↗
USGS1996

Temperature, water chemistry, and optical properties of Crater Lake

Water temperature, water chemistry, and optical properties of Crater Lake were studied from 1983 to 1991. In winter and spring, wind energy and convection mixed the water column to a depth of 200 to 250 m. The lake was thermally stratified in summer and early fall; however, the epilimnion was only 5 to 20 m thick, and most of the 589 m deep water column was a cold hypolimnion. The lake was slightly basic, with moderate alkalinity and conductivity. The water column was oxygenated, although slight decreases in dissolved oxygen concentration were noticed near the lake bottom in late summer and early fall. Phosphorus and nitrogen concentrations were low. Orthophosphorus-P concentrations increased slightly with increased lake depth, whereas nitrate-N was below detection limits in the upper 200 m of the water column and then increased with increased lake depth. Secchi disk clarity typically varied from the high-20-m to low-30-m range. The depth of 1 % surface incident light (425–655 nm) in July and August typically ranged between 80 and 100 m. The results also indicated that water temperature, water chemistry, and optical properties of the lake between 1983 and 1991 were consistent with those observed between 1896 and 1982.

Journal of Lake and Reservoir Management↗
USGS2005

Effects of emission reductions at the Hayden powerplant on precipitation, snowpack, and surface-water chemistry in the Mount Zirkel Wilderness Area, Colorado, 1995-2003

Precipitation, snowpack, and surface-water samples collected during 1995-2003 were analyzed to evaluate the effects of emission reductions at the Hayden powerplant on water chemistry in the Mount Zirkel Wilderness Area. The Hayden powerplant, one of two large coal-fired powerplants in the Yampa Valley, was retrofitted with control systems during late 1998 and 1999 to reduce emissions of sulfur dioxide and nitrogen oxide--the primary precursors of haze and acidic precipitation. The U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, evaluated three water-chemistry data sets: wet-only precipitation chemistry from the National Atmospheric Deposition Program, snowpack chemistry from the Rocky Mountain snowpack network, and surface-water chemistry from a U.S. Geological Survey long-term lakes monitoring program. Concentrations and deposition rates of selected constituents were compared for the periods before and after emission reductions at the Hayden powerplant. Data collected during 1995-98 were used to represent the pre-control period, and data collected during 2000-2003 were used to represent the post-control period. Ten stations in the National Atmospheric Deposition Program were evaluated including two that were directly downwind from the Hayden powerplant (Dry Lake and Buffalo Pass) and eight that were upwind or more distant (more than 100 kilometers) from the powerplant. Precipitation amount at all 10 precipitation stations was lower in the post-control period than the pre-control period as a result of a regional drought that persisted during the post-control period. In contrast to precipitation amount, there was no consistent pattern of change in sulfate concentrations between periods, indicating that the drought did not have a concentrating effect on sulfate or that trends in regional sulfur dioxide emissions masked its influence. Sulfate concentrations increased at three stations between periods, remained the same at three stations, and decreased at four stations. The largest change in average annual sulfate concentrations occurred at the two precipitation stations downwind from the Hayden powerplant, decreasing by 3.3 microequivalents per liter at Dry Lake and by 2.2 microequivalents per liter at Buffalo Pass. Declines in annual sulfate deposition also were greater at Dry Lake (3.4 kilograms per hectare) and Buffalo Pass (3.3 kilograms per hectare) than at the other stations, which ranged from 0.2 to 1.7 kilograms per hectare. These results indicate that emission reductions at the Hayden powerplant have been a factor in declines in atmospheric deposition of sulfate downwind from the powerplant. Nitrate, ammonium, and base-cation concentrations, in contrast to sulfate, were higher in the post-control period than the pre-control period at all 10 stations, most likely due to a concentrating effect of the drought. Twenty-two snowpack sites in the Rocky Mountain snowpack network were evaluated including 4 sites that were located directly downwind from the Hayden powerplant and 18 sites that were upwind or more distant (as much as 200 kilometers) from the powerplant. The water content of the snowpack at maximum accumulation was lower in the post-control period than the pre-control period, reflecting the regional drought. Although there were small declines in snowpack sulfate concentrations at the downwind stations between the pre- and post-control periods, the difference was not statistically significant, indicating emission reductions had a weaker effect on snowpack chemistry than precipitation chemistry. Sulfate deposition decreased at all four downwind sites in the post-control period, primarily reflecting both lower water content and concentrations in the snowpack. As observed at the precipitation stations, nitrate, ammonium, and base-cation concentrations at all 22 sites were significantly higher in the post-control period than the pre-control period, reflecting drier conditions caused by drought. The chemistry at six surface-water sites in and near the Mount Zirkel Wilderness Area and five control sites in the Flat Tops Wilderness Area was examined. No response to emission reductions was detectable in chemistry of the surface water in the Mount Zirkel Wilderness Area. Detection of a response to changes in emissions and deposition in the lake-chemistry data may have been confounded by drought conditions during the period after emission reductions occurred. The magnitude of reduced sulfate in atmospheric deposition indicates that at some time in the future, a reduction in lake sulfate attributable to Yampa Valley emission reduction should be detectable. The trend of decreasing sulfur dioxide emissions throughout western North America over the past 20 years is reflected in reduced concentrations of sulfate in lakes that were part of this study, as well as other lakes in the Rocky Mountains. However, detection of the surface-water response to changes in deposition requires a sufficiently long record to minimize effects of climate variability and to allow for lag time as sulfate moves through storage in soil, ground water, and lake reservoirs.

Colorado↗
USGS2000

Relations between basin characteristics and stream water chemistry in alpine/subalpine basins in Rocky Mountain National Park, Colorado

Relations between stream water chemistry and topographic, vegetative, and geologic characteristics of basins were evaluated for nine alpine/subalpine basins in Rocky Mountain National Park, Colorado, to identify controlling parameters and to better understand processes governing patterns in stream water chemistry. Fractional amounts of steep slopes (≥30°), unvegetated terrain, and young surficial debris within each basin were positively correlated to each other. These terrain features, which commonly occur on steep valley side slopes underlain by talus, were negatively correlated with concentrations of base cations, silica, and alkalinity and were positively correlated with nitrate, acidity, and runoff. These relations might result from the short residence times of water and limited soil development in the talus environment, which limit chemical weathering and nitrogen uptake. Steep, unvegetated terrains also tend to promote high Ca/Na ratios in stream water, probably because physical weathering rates in those areas are high. Physical weathering exposes fresh bedrock that contains interstitial calcite, which weathers relatively quickly. The fractional amounts of subalpine meadow and, to a lesser extent, old surficial debris in the basins were positively correlated to concentrations of weathering products and were negatively correlated to nitrate and acidity. These relations may reflect more opportunities for silicate weathering and nitrogen uptake in the lower‐energy environments of the valley floor, where soils are finer‐grained, older, and better developed and slopes are relatively flat. These results indicate that in alpine/subalpine basins, slope, vegetation (or lack thereof), and distribution and age of surficial materials are interrelated and can have major effects on stream water chemistry.

Colorado↗
USGS2021

Spring types and contributing aquifers from water-chemistry and multivariate statistical analyses for seeps and springs in Theodore Roosevelt National Park, North Dakota, 2018

Water resources in Theodore Roosevelt National Park, North Dakota, support wildlife, visitors, and staff, and play a vital role in supporting the native ecology of the park. The U.S. Geological Survey, in cooperation with the National Park Service, completed field work in 2018 for a study to address concerns about water availability and possible sources of groundwater contamination for seeps and springs in Theodore Roosevelt National Park. The objective of the study was to improve hydrologic knowledge and determine the water composition of 11 seeps and springs in the park by collecting water-chemistry data at springs, streams, wells, and rain collectors. Water samples were collected at 26 sites at springs, streams, wells, and rain collectors in the North and South Units of Theodore Roosevelt National Park. Samples in the North Unit were collected at 5 springs, 1 stream, 2 wells, and 1 rain collector. Samples in the South Unit were collected at 6 springs, 2 streams, 8 wells, and 1 rain collector. Samples from springs, streams, and wells were collected in May, July, and September 2018. Samples from rain collectors were collected when enough daily precipitation accumulated in the collectors. Sampled precipitation events during the study period were in May, June, July, August, and September 2018. Physical properties of sampled water—temperature, pH, and specific conductance—were measured in the field. Water samples were analyzed for stable isotopes of oxygen and hydrogen and for chloride concentration. Recharge rates for aquifers supplying springs were determined using precipitation volume and chloride concentrations for a 12-day period before the sample-collection date. Multivariate statistical analysis methods used on water-chemistry data included principal component analysis, cluster analysis, and end-member mixing analysis. Water composition was used to determine the spring type and contributing aquifers for 11 springs in the North and South Units of Theodore Roosevelt National Park from analyses of water-chemistry data between May and September 2018. In the North Unit, Achenbach Spring was classified as a filtration spring with water from an unconfined part of the upper Fort Union aquifer and infiltration of precipitation. Hagen Spring, Mandal Spring, and Stevens Spring were classified as contact springs supplied by semiconfined parts of the upper Fort Union aquifer. Overlook Spring at one time may have been a natural spring or seep but now is a developed spring that behaves like a flowing artesian well completed in a confined part of the upper Fort Union aquifer. In the South Unit, six springs were classified into two spring types: filtration and contact springs. Boicourt Spring and Sheep Butte Spring were classified as filtration springs that have water supplied by unconfined parts of the upper Fort Union aquifer and infiltrated precipitation. Big Plateau Spring, Lone Tree Spring, Sheep Pasture Spring, and Southeast Corner Spring were classified as contact springs that receive waters from a semiconfined part of the upper Fort Union aquifer.

North Dakota↗
USGS2006

Questa baseline and pre-mining ground-water quality investigation. 20. Water chemistry of the Red River and selected seeps, tributaries, and precipitation, Taos County, New Mexico, 2000-2004

As part of a multi-year project to infer the pre-mining ground-water quality at Molycorp's Questa mine site, surface-water samples of the Red River, some of its tributaries, seeps, and snow samples were collected for analysis of inorganic solutes and of water and sulfate stable isotopes in selected samples. The primary aim of this study was to document diel, storm event, and seasonal variations in water chemistry for the Red River and similar variations in water chemistry for Straight Creek, a natural analog site similar in topography, hydrology, and geology to the mine site for inferring pre-mining water-quality conditions. Red River water samples collected between 2000 and 2004 show that the largest variations in water chemistry occur during late summer rainstorms, often monsoonal in nature. Within hours, discharge of the Red River increased from 8 to 102 cubic feet per second and pH decreased from 7.80 to 4.83. The highest concentrations of metals (iron, aluminum, zinc, manganese) and sulfate also occur during such events. Low-pH and high-solute concentrations during rainstorm runoff are derived primarily from alteration 'scar' areas of naturally high mineralization combined with steep topography that exposes continually altered rock because erosion is too rapid for vegetative growth. The year 2002 was one of the driest on record, and Red River discharge reflected the low seasonal snow pack. No snowmelt peak appeared in the hydrograph record, and a late summer storm produced the highest flow for the year. Snowmelt was closer to normal during 2003 and demonstrated the dilution effect of snowmelt on water chemistry. Two diel sampling events were conducted for the Red River, one during low flow and the other during high flow, at two locations, at the Red River gaging station and just upstream from Molycorp's mill site. No discernible diel trends were observed except for dissolved zinc and manganese at the upstream site during low flow. Straight Creek drainage water was sampled periodically from 2001 to 2004 at the down stream end of surface drainage near the point at which it disappeared into the debris fan. This water has a minimal range in pH (2.7 to 3.2) but a substantial concentration range in many solutes; for example, sulfate concentrations varied from 525 to 2,660 mg/L. Many elements covary with sulfate suggesting that dilution is the primary control of the range in solute concentrations. A transect of water samples higher in the scar area were collected in October of 2003. They had a lower range in pH (2.44 to 3.05) and higher solute concentrations than those collected periodically from lower in the catchment. Water isotopes for the upper transect samples indicated slight evaporation, and in part, may account for the higher solute concentrations. Drainage waters also were collected from Hottentot, Junebug, Hansen, Little Hansen, and Goat Hill Gulch drainages. Most constituents from other scar drainage waters showed ranges of concentration similar to those of the Straight Creek waters. An exception was water collected from Goat Hill Gulch, which has some of the highest concentrations of any surface-water sample collected but also contained waste-rock leachates.

New Mexico↗
USGS2024

Carbon dioxide toxicity to zebra mussels (Dreissena polymorpha) is dependent on water chemistry

Carbon dioxide (CO 2 ) is gaining interest as a tool to combat aquatic invasive species, including zebra mussels ( Dreissena polymorpha ). However, the effects of water chemistry on CO 2 efficacy are not well described. We conducted five trials in which we exposed adult zebra mussels to a range of CO 2 in water with adjusted total hardness and specific conductance. We compared dose–responses and found differences in lethal concentration to 50% of organisms (LC50) estimates ranging from 108.3 to 179.3 mg/L CO 2 and lethal concentration to 90% of organisms (LC90) estimates ranging from 163.7 to 216.6 mg/L CO 2 . We modeled LC50 and LC90 estimates with measured water chemistry variables from the trials. We found sodium (Na + ) concentration to have the strongest correlation to changes in the LC50 and specific conductance to have the strongest correlation to changes in the LC90. Our results identify water chemistry as an important factor in considering efficacious CO 2 concentrations for zebra mussel control. Additional research into the physiological responses of zebra mussels exposed to CO 2 may be warranted to further explain mode of action and reported selectivity. Further study could likely develop a robust and relevant model to refine CO 2 applications for a wider range of water chemistries. Environ Toxicol Chem 2024;00:1–8. Published 2024. This article is a U.S. Government work and is in the public domain in the USA. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.

Environmental Toxicology and Chemistry↗
USGS2008

Ground- and surface-water chemistry of Handcart Gulch, Park County, Colorado, 2003-2006

As part of a multidisciplinary project to determine the processes that control ground-water chemistry and flow in mineralized alpine environments, ground- and surface-water samples from Handcart Gulch, Colorado were collected for analysis of inorganic solutes and water and dissolved sulfate stable isotopes in selected samples. The primary aim of this study was to document variations in ground-water chemistry in Handcart Gulch and to identify changes in water chemistry along the receiving stream of Handcart Gulch. Water analyses are reported for ground-water samples collected from 12 wells in Handcart Gulch, Colorado. Samples were collected between August 2003 and October 2005. Water analyses for surface-water samples are reported for 50 samples collected from Handcart Gulch and its inflows during a low-flow tracer injection on August 6, 2003. In addition, water analyses are reported for three other Handcart Gulch stream samples collected in September 2005 and March 2006. Reported analyses include field parameters (pH, specific conductance, temperature, dissolved oxygen, and Eh), major and trace constituents, oxygen and hydrogen isotopic composition of water and oxygen and sulfur isotopic composition of dissolved sulfate. Ground-water samples from this study are Ca-SO4 type and range in pH from 2.5 to 6.8. Most of the samples (75 percent) have pH values between 3.3 and 4.3. Surface water samples are also Ca-SO4 type and have a narrower range in pH (2.7?4.0). Ground- and surface-water samples vary from relatively dilute (specific conductance of 68 ?S/cm) to concentrated (specific conductance of 2,000 ?S/cm).

Colorado↗
USGS2000

Relations of habitat-specific algal assemblages to land use and water chemistry in the Willamette Basin, Oregon

Benthic algal assemblages, water chemistry, and habitat were characterized at 25 stream sites in the Willamette Basin, Oregon, during low flow in 1994. Seventy-three algal samples yielded 420 taxa - Mostly diatoms, blue-green algae, and green algae. Algal assemblages from depositional samples were strongly dominated by diatoms (76% mean relative abundance), whereas erosional samples were dominated by blue-green algae (68% mean relative abundance). Canonical correspondence analysis (CCA) of semiquantitative and qualitative (presence/absence) data sets identified four environmental variables (maximum specific conductance, % open canopy, pH, and drainage area) that were significant in describing patterns of algal taxa among sites. Based on CCA, four groups of sites were identified: Streams in forested basins that supported oligotrophic taxa, such as Diatoma mesodon; small streams in agricultural and urban basins that contained a variety of eutrophic and nitrogen-heterotrophic algal taxa; larger rivers draining areas of mixed land use that supported planktonic, eutrophic, and nitrogen-heterotrophic algal taxa; and streams with severely degraded or absent riparian vegetation (> 75% open canopy) that were dominated by other planktonic, eutrophic, and nitrogen-heterotrophic algal taxa. Patterns in water chemistry were consistent with the algal autecological interpretations and clearly demonstrated relationships between land use, water quality, and algal distribution patterns.

Conference Paper↗
USGS1986

Sources of coal-mine drainage and their effects on surface-water chemistry in the Claybank Creek basin and vicinity, north-central Missouri, 1983-84

Eighteen sources of drainage related to past coal-mining activity were identified in the Claybank Creek, Missouri, study area, and eight of thew were considered large enough to have detectable effects on receiving streams. However, only three sources, coal wastes at Keota and Binkley, and drainage from underground coal mines near Keota, significantly affected the chemistry of water in receiving streams. Coal wastes in the Claybank Creek basin contributed large quantities of acid drainage to receiving streams during storm runoff; pH of coal-waste runoff ranged from 2.1 to 2.8. At these small pH values, concentrations of some dissolved metals and dissolved sulfate were a few to several hundred times larger than Federal and State water-quality standards established for these constituents. Effects of acid storm runoff were detected near the mouth of North Fork Claybank Creek where the pH during a small storm was 3.9. Coal wastes in the streambeds and seepage from coal wastes also had significant effects on receiving streams during base flows. The receiving waters had pH values between 2.8 and 3.5 and concentrations of some dissolved metals and dissolved sulfate were a few to several hundred times larger than Federal and State water-quality standards. Most underground mines in the North Fork Claybank Creek basin are hydraulically connected and about 80 percent of their discharge surfaced at one site. Drainage from the underground mines contributed most of the dissolved constituents in North Fork Claybank Creek during dry weather. Underground-mine water always had a pH near 5.9, was well-buffered, had a dissolved-sulfate concentration of about 2,400 milligrams per liter, dissolved-manganese concentrations ranging from 4.0 to 5.3 milligrams per liter, and large concentrations of ferrous iron. Iron was in the ferrous state due to reducing conditions in the mines. When underground-mine drainage reached the ground surface, the ferrous iron was oxidized and precipitated to form large, orange deposits of ferric hydroxide around the site and in streambeds. Generally, drainage from strip mines had dissolved-sulfate concentrations several times larger than drainage from unmined areas. However, effects of drainage from strip mines on receiving streams were minimal when compared to the drainage from coal wastes and underground mines. No appreciable effects of mine-related drainage were detected in the water of the Claybank Creek arm of Thomas Hill Reservoir at the time of sampling because beaver bogs upstream had trapped suspended coal wastes and moderated the effects. However, the concentration of coal in the bottom material was 60 percent of the coal concentration in coal wastes at Keota, indicating that the reservoir had received these wastes during the past.

Missouri↗
USGS2007

Vertical gradients in water chemistry and age in the Northern High Plains Aquifer, Nebraska, 2003

The northern High Plains aquifer is the primary source of water used for domestic, industrial, and irrigation purposes in parts of Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Despite the aquifer’s importance to the regional economy, fundamental ground-water characteristics, such as vertical gradients in water chemistry and age, remain poorly defined. As part of the U.S. Geological Survey’s National Water-Quality Assessment Program, water samples from nested, short-screen monitoring wells installed in the northern High Plains aquifer were analyzed for major ions, nutrients, trace elements, dissolved organic carbon, pesticides, stable and radioactive isotopes, dissolved gases, and other parameters to evaluate vertical gradients in water chemistry and age in the aquifer. Chemical data and tritium and radiocarbon ages show that water in the aquifer was chemically and temporally stratified in the study area, with a relatively thin zone of recently recharged water (less than 50 years) near the water table overlying a thicker zone of older water (1,800 to 15,600 radiocarbon years). In areas where irrigated agriculture was an important land use, the recently recharged ground water was characterized by elevated concentrations of major ions and nitrate and the detection of pesticide compounds. Below the zone of agricultural influence, major-ion concentrations exhibited small increases with depth and distance along flow paths because of rock/water interactions. The concentration increases were accounted for primarily by dissolved calcium, sodium, bicarbonate, sulfate, and silica. In general, the chemistry of ground water throughout the aquifer was of high quality. None of the approximately 90 chemical constituents analyzed in each sample exceeded primary drinking-water standards. Mass-balance models indicate that changes in groundwater chemistry along flow paths in the aquifer can be accounted for by small amounts of feldspar and calcite dissolution; goethite and clay-mineral precipitation; organic-carbon and pyrite oxidation; oxygen reduction and denitrification; and cation exchange. Mixing with surface water affected the chemistry of ground water in alluvial sediments of the Platte River Valley. Radiocarbon ages in the aquifer, adjusted for carbon mass transfers, ranged from 1,800 to 15,600 14C years before present. These results have important implications with respect to development of ground-water resources in the Sand Hills. Most of the water in the aquifer predates modern anthropogenic activity so excessive removal of water by pumping is not likely to be replenished by natural recharge in a meaningful timeframe. Vertical gradients in ground-water age were used to estimate long-term average recharge rates in the aquifer. In most areas, the recharge rates ranged from 0.02 to 0.05 foot per year. The recharge rate was 0.2 foot per year in one part of the aquifer characterized by large downward hydraulic gradients. Nitrite plus nitrate concentrations at the water table were 0.13 to 3.13 milligrams per liter as nitrogen, and concentrations substantially decreased with depth in the aquifer. Dissolved-gas and nitrogen-isotope data indicate that denitrification in the aquifer removed 0 to 97 percent (average = 50 percent) of the nitrate originally present in recharge. The average amount of nitrate removed by denitrification in the aquifer north of the Platte River (Sand Hills) was substantially greater than the amount removed south of the river (66 as opposed to 0 percent), and the extent of nitrate removal appears to be related to the presence of thick deposits of sediment on top of the Ogallala Group in the Sand Hills that contained electron donors, such as organic carbon and pyrite, to support denitrification. Apparent rates of dissolved-oxygen reduction and denitrification were estimated on the basis of decreases in dissolved-oxygen concentrations and increases in concentrations of excess nitrogen gas and ground-water ages along flow paths from the water table to deeper wells. Median rates of dissolved-oxygen reduction and denitrification south of the Platte River were at least 10 times smaller than the median rates north of the river in the Sand Hills. The relatively large denitrification rates in the Sand Hills indicate that the aquifer in that area may have a greater capacity to attenuate nitrate contamination than the aquifer south of the river, depending on rates of ground-water movement in the two areas. Small denitrification rates south of the river indicate that nitrate contamination in that part of the aquifer would likely persist for a longer period of time.

Nebraska↗
USGS2000

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—1999

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and a precipitation of only about 6 to 12 inches per year. The monitoring program in Black Mesa has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, and (5) ground-water chemistry. In 1999, total ground-water withdrawals were 7,110 acre-feet, industrial use was 4,210 acre-feet, and municipal use was 2,900 acre-feet. From 1998 to 1999, total withdrawals increased by 0.7 percent, industrial use increased by 4 percent, and municipal use decreased by 4 percent. From 1998 to 1999, water levels declined in 11 of 15 wells in the unconfined part of the aquifer, and the median decline was 0.7 foot. Water levels declined in 14 of 16 wells in the confined part of the aquifer, and the median decline was 1.2 feet. From the prestress period (prior to 1965) to 1999, the median water-level decline in 31 wells was 10.6 feet. Median water-level changes were 0.0 foot for 15 wells in the unconfined part of the aquifer and a decline of 45.5 feet in 16 wells in the confined part. From 1998 to 1999, discharges were measured annually at four springs. Discharges declined 30 percent and 3 percent at 2 springs, did not change at 1 spring, and increased by 11 percent at 1 spring. For the past 10 years, discharges from the four springs have fluctuated; however, an increasing or decreasing trend was not observed. Continuous records of surface-water discharge have been collected from July 1976 to 1999 at Moenkopi Wash, July 1996 to 1999 at Laguna Creek, June 1993 to 1999 at Dinnebito Wash, and April 1994 to 1999 at Polacca Wash. Median flows for November, December, January, and February of each water year are used as an index of ground-water discharge to those streams. Increasing or decreasing trends are not apparent in these median winter flows for the periods of record. In 1999, water samples were collected from 12 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 91 to 630 milligrams per liter. Water samples from 10 of the wells and the 4 springs had less than 350 milligrams per liter of dissolved solids. Water-chemistry data are available for nine wells and four springs from about the mid-1980s. For that time period, the data from those sites have remained fairly stable. From 1987 to 1999, concentrations of dissolved solids, chloride, and sulfate may have increased slightly in samples from Moenkopi School Spring.

Arizona↗
USGS2000

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona: 1998

The Black Mesa monitoring program is designed to document long-term effects of ground-water pumping from the N aquifer by industrial and municipal users. The N aquifer is the major source of water in the 5,400-square-mile Black Mesa area, and the ground water occurs under confined and unconfined conditions. Monitoring activities include continuous and periodic measurements of (1) ground-water pumpage from the confined and unconfined parts of the aquifer, (2) ground-water levels in the confined and unconfined parts of the aquifer, (3) surface-water discharge, (4) flowmeter tests, and (5) ground-water and surface-water chemistry. In 1998, ground-water withdrawals for industrial and municipal use totaled about 7,060 acre-feet, which is less than a 1 percent decrease from 1997. Pumpage from the confined part of the aquifer decreased by less than 1 percent to 5,470 acre-feet, and pumpage from the unconfined part of the aquifer increased by less than 1 percent to 1,590 acre-feet. Water-level declines in the confined part of the aquifer were recorded in 10 of 14 wells during 1998, and the median change from 1997 was a decline of 3.0 feet as opposed to a rise of 0.2 feet for the change from 1996 to 1997. Water-level declines in the unconfined part of the aquifer were recorded in 9 of 16 wells, and the median change from 1997 was 0.0 feet, which is the same as the median change from 1996 to 1997. Of the 35 pumpage meters on municipal wells that were tested, the difference between metered and tested discharge ranged from +6.3 to -19.6 percent. The average difference was about -3.4 percent. Five of the meters exceeded the allowable difference (10 percent) and should be repaired or replaced. The low-flow discharge at the Moenkopi streamflow-gaging station ranged from 2.6 to 4.7 cubic feet per second in 1998. Streamflow-discharge measurements also were made at Laguna Creek, Dinnebito Wash, and Polacca Wash during 1998. The low-flow discharge ranged from 0.41 to 5.1 cubic feet per second at Laguna Creek, 0.32 to 0.44 cubic feet per second at Dinnebito Wash, and 0.13 to 0.36 cubic feet per second at Polacca Wash. Discharge was measured at four springs. Discharge from Moenkopi School Spring decreased by about 1.1 gallons per minute from the measurement in 1997. Discharge from an unnamed spring near Dennehotso decreased by 4.6 gallons per minute from the measurement made in 1997. Discharge increased slightly at Burro Spring and decreased by about 1 gallon per minute at Pasture Canyon Spring. Regionally, long-term water-chemistry data for wells and springs have remained stable.

Arizona↗