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Arctic continental shelf morphology related to sea-ice zonation, Beaufort Sea, Alaska

Landsat-1 and NOAA satellite imagery for the winter 1972–1973, and a variety of ice and sea-floor data were used to study sea-ice zonation and dynamics and their relation to bottom morphology and geology on the Beaufort Sea continental shelf of arctic Alaska. In early winter the location of the boundary between undeformed fast ice and westward-drifting pack ice of the Pacific Gyre is controlled by major coastal promontories. Pronounced linear pressure- and shear-ridges, as well as hummock fields, form along this boundary and are stabilized by grounding, generally between the 10- and 20-m isobaths. Slippage along this boundary occurs intermittently at or seaward of the grounded ridges, forming new grounded ridges in a widening zone, the stamukhi zone, which by late winter extends out to the 40-m isobath. Between intermittent events along the stamukhi zone, pack-ice drift and slippage is continuous along the shelf edge, at average rates of 3–10 km/day. Whether slippage occurs along the stamukhi zone or along the shelf edge, it is restricted to a zone several hundred meters wide, and ice seaward of the slip face moves at uniform rates without discernible drag effects. A causal relationship is seen between the spatial distribution of major ice-ridge systems and offshore shoals downdrift of major coastal promontories. The shoals appear to have migrated shoreward under the influence of ice up to 400 m in the last 25 years. The sea floor seaward of these shoals within the stamukhi zone shows high ice-gouge density, large incision depths, and a high degree of disruption of internal sedimentary structures. The concentration of large ice ridges and our sea floor data in the stamukhi zone indicate that much of the available marine energy is expended here, while the inner shelf and coast, where the relatively undeformed fast ice grows, are sheltered. There is evidence that anomalies in the overall arctic shelf profile are related to sea-ice zonation, ice dynamics, and bottom processes. A proposed ice zonation, including zones of (1) bottom-fast ice, (2) floating fast ice, (3) stamukhi, and (4) seasonal pack ice, emphasizes ice interaction with the shelf surface and differs from previous zonation. Certain aspects of the results reported here are directly applicable to planned offshore developments in the Prudhoe Bay oil field. Properly placed artificial structures similar to offshore shoals should be able to withstand the forces of the ice, serve to modify the observed ice zonation, and might be used to make the environment less hostile to human activities.

Alaska

Ecotoxicology of Amphibians and Reptiles

For many years, ecological research on amphibians and reptiles has lagged behind that of other vertebrates such as fishes, birds, and mammals, despite the known importance of these animals in their environments. The lack of study has been particularly acute in the he area of ecotoxicology where the number of published scientific papers is a fraction of that found for the other vertebrate classes. Recently, scientists have become aware of severe crises among amphibian populations, including unexplained and sudden extinctions, worldwide declines, and hideous malformations. In many of these instances, contaminants have been listed as probable contributors. Data on the effects of contaminants on reptiles are so depauperate that even the most elementary interpretations are difficult. This state-of-the-science review and synthesis of amphibian and reptile ecotoxicology demonstrates the inter-relationships among distribution, ecology, physiology, and contaminant exposure, and interprets these topics as they pertain to comparative toxicity, population declines, malformations, and risk assessment . In this way, the book identifies and serves as a basis for the most pressing research needs in the coming years. The editors have invited 27 other internationally respected experts to examine the state of existing data in specific areas, interpret it in light of current problems, and identify research gaps and needs. Through its emphasis on recent research, extensive reviews and synthesis, Ecotoxicology of Amphibians and Reptiles will remain a definitive reference work well into the new century.

SETAC Technical Publications Series.

Science mission requirements for a globally ranging, riserless drilling vessel for U.S. Scientific Ocean Drilling

Through the collection and analysis of shallow and deep subseafloor sediments, rocks, fluids, and life, scientific ocean drilling has enriched our understanding of the complex Earth system. Among other achievements, scientific ocean drilling has documented the history of Earth’s climate, the waxing and waning of polar ice sheets, the past changes in ocean and atmospheric circulation, the existence and function of microbial life in the subseafloor, the compositional variations in Earth’s crust and underlying mantle, and the physical and chemical processes acting at subduction zones, including those associated with tsunamigenic earthquakes. Over the decades, more than 12,000 articles that depend on analyses of scientific ocean drilling samples and geophysical data have been published, many detailing breakthrough contributions to global knowledge about the Earth system. Approximately 45% of these publications were led by U.S.-affiliated authors (International Ocean Discovery Program Publication Services, 2021). Since the mid-1980s, the workhorse of this multidisciplinary, international research effort has been the riserless D/V JOIDES Resolution, operated by Texas A&M University with funding from the U.S. National Science Foundation (NSF). D/V JOIDES Resolution has conducted the vast majority of scientific ocean drilling expeditions and collected most of the scientific cores over that period, including 82% of the expeditions and 93% of the cores in the last decade alone, despite being one of three platforms that is operated within the International Ocean Discovery Program. However, D/V JOIDES Resolution is approaching the end of its useful life. With a strong commitment to continue scientific ocean drilling beyond the end of the current phase, the community developed a document outlining the research frontiers that should be pursued. Exploring Earth by Scientific Ocean Drilling: 2050 Science Framework (Koppers and Coggon, 2020) describes seven scientific strategic objectives that focus on understanding interconnections within the Earth system and five flagship initiatives that integrate these objectives into long-term research efforts that address issues facing society. Additional elements in the 2050 Science Framework, including STEM education, workforce development, technology development, and innovative applications of data analytics, will advance the goals of scientific ocean drilling. Addressing the 2050 Science Framework also requires building partnerships with allied U.S. and international science programs and strengthening existing ones. To implement a significant portion of the 2050 Science Framework, the U.S. scientific community seeks to lease or acquire a newly built, globally ranging, state-of-the art, riserless drilling vessel. The many and varied technical and human resources requirements for successful accomplishment of scientific and educational goals summarized in this document and described in detail in the 2050 Science Framework require broad community input and careful consideration. Following receipt of NSF’s formal Request for Assistance to the United States Science Support Program (USSSP), the U.S. scientific ocean drilling community conducted a one-year exercise to identify its national scientific needs and priorities in order to determine the Science Mission Requirements (SMRs) presented here. This community effort included: (1) a U.S. community-wide survey to identify the specific operational and technical capabilities critical to addressing science in the 2050 Science Framework; (2) a series of online workshops focusing on critical capabilities identified by the survey; and (3) a large in-person workshop to synthesize the results of the survey and the virtual workshops (Appendix 1). The approach was designed to reach as many participants as possible. Overall, 278 survey responses were received from U.S. community members, representing 104 unique institutions from 39 states and the District of Columbia, and 137 unique individuals participated in the workshops (Appendix 2). The results of this effort comprise two classes of SMRs: Foundational Science Mission Requirements and Primary Science Mission Requirements. Foundational SMRs define minimum criteria for a new riserless drilling vessel that can address significant portions of the 2050 Science Framework. Primary SMRs build upon the Foundational SMRs and will create more robust science opportunities and data collection capabilities, will increase progress in addressing the 2050 Science Framework objectives, and will provide more real-time ship-to-shore interaction to improve science productivity, engagement, and outreach. Modern safety and environmental standards, including meeting standards to access protected waters such as exclusive economic zones, extended continental shelves, or high latitudes, while being cognizant of the vessel’s environmental footprint. Safe and efficient operations in global locations and in water depths from 70 m to 6000+ m, with total drill string length of at least 7000 m. High-quality core and data collection from a range of key subseafloor environments. Advanced heave compensation, dynamic positioning, and drill pipe stability. Modern mud and cement/casing systems. Critical onboard measurements for safety, operational decision-making, documentation of ephemeral properties, mission-specific science, and long-term science goals that extend beyond a single expedition. Designated and appropriate space for sample and data preservation. Highly skilled onboard personnel, including technical staff for curation and core handling; support for safety, time-sensitive, and critical shipboard measurements; computer support; equipment and instrument repair; application support; and data assurance. Primary Science Mission Requirements include: Flexible shipboard space for laboratories and on deck to ensure safe, successful implementation of diverse science objectives and operations. Minimizing contamination of recovered samples. Over-the-side capabilities for science-supporting technology (e.g., remotely operated vehicles, water- column sampling, sediment-water interface sampling). Downhole logging and measurements. Expanded borehole observatory capabilities. Reliable and consistent ship-to-shore communications. NSF’s investment in a new globally ranging, riserless drilling vessel will have a powerful economic multiplier effect, including the infusion of additional science support funds in the United States for training and research, the development of new technologies and tools, and the associated scientific and technical workforce development. The skills and knowledge gained through scientific ocean drilling are translatable to careers in fields such as sustainable energy development (e.g., geothermal and offshore wind), carbon sequestration, data management and cyberinfrastructure, biotechnology, communications, science education, policy, hazard mitigation, and environmental management. The United States is a leader in a well-established and internationally collaborative scientific ocean drilling community. A modern, globally ranging, riserless drilling vessel will allow the United States to expand its leadership position, address broad scientific questions that current capabilities preclude, and cultivate equitable international, multidisciplinary collaborations that will ensure scientific ocean drilling’s future success.

Report

A promising tool for subsurface permafrost mapping-An application of airborne geophysics from the Yukon River Basin, Alaska

Permafrost is a predominant physical feature of the Earth's Arctic and Subarctic clines and a major consideration encompassing ecosystem structure to infrastructure engineering and placement. Perennially frozen ground is estimated to cover about 85 percent of the state of Alaska where northern reaches are underlain with continuous permafrost and parts of interior Alaska are underlain by areas of discontinuous and (or) sporadic permafrost (fig. 1). The region of Interior Alaska, where permafrost is scattered among unfrozen ground, is a complex mosaic of terrains and habitats. Such diversity creates arrays of lakes and surface-water and groundwater patterns that continental populations of migratory waterfowl and internationally significant fisheries have adapted to over time. A road or pipeline might pass over frozen and unfrozen ground, affecting the types of materials and engineering approaches needed to sustain the infrastructure. Effective mapping of discontinuous permafrost at scales meaningful ecologically and (or) from an engineering perspective has been a long-standing challenge. Using techniques such as borehole logging for site-specific assessments or botanical techniques that can suggest underlying permafrost distributions can be labor intensive and difficult to accomplish at the scale and remoteness of much of Alaska. The climate is changing in the Arctic and Subarctic regions. The warming observed throughout much of Alaska could create widespread changes in permafrost. How the warming of the permafrost affects near-surface processes, ecosystems, and community infrastructure and ecosystems is not clear. A better understanding of the dynamic distribution and physical properties of permafrost, from continuous to discontinuous, will provide knowledge of how the permafrost environment may change in the future and help inform engineering and natural resource response strategies. Here we discuss an application of an airborne remote sensing methodology for mapping and shade imaging permafrost characteristics at various scales. This work provides the first look into three-dimensional distribution of permafrost in the areas around Fort Yukon and is a demonstration of the application of airborne electromagnetic (AEM) to permafrost mapping. Such an approach is attractive, particularly in Arctic and Subarctic studies, where ground access is difficult and ecosystems are fragile. In June 2010, the U.S. Geological Survey (USGS) conducted an AEM survey near Fort Yukon, Alaska. The primary focus of this survey was to map the distribution of permafrost in selected areas in order to supply information for the development of groundwater models of the Yukon River Basin. However, the methodologies have more far-reaching ecological and engineering applications. Approximately 1,800 line kilometers were acquired in a combination of typical block style surveying in the immediate area of Fort Yukon and in long reconnaissance lines over a broader area. The widely spaced lines were flown to cross the modern Yukon River in "X" like patterns with intersections at features that have been previously studied (fig. 2). AEM is used to gather data on the electrical resistivity of materials in the subsurface below the flight path of the helicopter, which are then analyzed to interpret the subsurface lithology and the location and extent of permafrost. For this survey, the electrical resistivity was imaged to depths on the order of 50-100 meters. Images from the survey can be qualitatively compared with known permafrost features and suggest new permafrost features. Electrical properties of earth materials are affected by lithology as well as temperature and the presence of ice; frozen materials become substantially more resistive. This allows for the identification of permafrost from the resistivity image (Abraham and others, 2011). In the area of Fort Yukon, the AEM survey shows elevated resistivities extending to depth, likely indicative of thick permafrost. This depth corresponds well to observations from a borehole drilled in the area in the late 1990s, which detected permafrost to a depth of about 100 meters (Clark and others, 2009). In contrast to the area of Fort Yukon, the Yukon River and its floodplain are not associated with deep resistive sediments, suggesting a lack of deep permafrost, at least within the depth range of the AEM mapping (fig. 3).

Yukon River Basin

Adaptation and response in drylands: A dryland research agenda and campaign strategy

Dryland ecosystems cover 41% of Earth's land surfaces, account for 44% of cultivated lands and 60% of food sources, and make large contributions to the global water and carbon cycles. However, these ecosystems are experiencing unprecedented extremes including heatwaves, floods, and droughts as well as hotter temperatures and often declining water resource availability. These ecosystems are some of the most challenging to monitor given their high temporal variability with rapid response to their environment as well as vast spatial variability with intermixing of different plant species and life forms amongst bare soil coverage. The Adaptation and Response in Drylands (ARID) campaign was selected by National Aeronautics and Space Administration (NASA) as a scoping study to develop a research agenda for a dryland field campaign. Here, we detail our ARID science research agenda and implementation plan that were developed based on an extensive community engagement effort in over 160 events with over a thousand scientists, land managers, and Tribal communities between 2023 and 2024. The selected science themes cover drought and climate variability, ecosystem structure, function, and biodiversity, carbon cycle interannual variability and trends, and social ecological systems (land management and adaptation). We then detail our remote sensing, modeling, and field-based strategies to capture high temporal and high spatial resolution processes. Finally, our implementation strategy is presented which includes focus area selections in a core intensive western U.S. domain and distributed international domains. This strategy includes our overarching guiding principles of using multi-temporal airborne acquisitions and super sites as well as enhancing land management in co-development with end-user partners. While originally developed for NASA, our ARID report creates a blueprint for any future dryland field campaign, at any scale, that can be implemented widely for foundational and applied science objectives.

Global Change Biology

The weight of New York City: Possible contributions to subsidence from anthropogenic sources

New York City faces accelerating inundation risk from sea level rise, subsidence, and increasing storm intensity from natural and anthropogenic causes. Here we calculate a previously unquantified contribution to subsidence from the cumulative mass and downward pressure exerted by the built environment of the city. We enforce that load distribution in a multiphysics finite element model to calculate expected subsidence. Complex surface geology requires multiple rheological soil models to be applied; clay rich soils and artificial fill are calculated to have the highest post-construction subsidence as compared with more elastic soils. Minimum and maximum calculated building subsidence ranges from 0 to 600 mm depending on soil/rock physical parameters and foundation modes. We compare modeled subsidence and surface geology to observed subsidence rates from satellite data (Interferometric Synthetic Aperture Radar and Global Positioning System). The comparison is complicated because the urban load has accumulated across a much longer period than measured subsidence rates, and there are multiple causes of subsidence. Geodetic measurements show a mean subsidence rate of 1–2 mm/year across the city that is consistent with regional post-glacial deformation, though we find some areas of significantly greater subsidence rates. Some of this deformation is consistent with internal consolidation of artificial fill and other soft sediment that may be exacerbated by recent building loads, though there are many possible causes. New York is emblematic of growing coastal cities all over the world that are observed to be subsiding (Wu et al., 2022, https://doi.org/10.1029/2022GL098477 ), meaning there is a shared global challenge of mitigation against a growing inundation hazard.

New York

The Landsat Image Mosaic of Antarctica

The Landsat Image Mosaic of Antarctica (LIMA) is the first true-color, high-spatial-resolution image of the seventh continent. It is constructed from nearly 1100 individually selected Landsat-7 ETM+ scenes. Each image was orthorectified and adjusted for geometric, sensor and illumination variations to a standardized, almost seamless surface reflectance product. Mosaicing to avoid clouds produced a high quality, nearly cloud-free benchmark data set of Antarctica for the International Polar Year from images collected primarily during 1999-2003. Multiple color composites and enhancements were generated to illustrate additional characteristics of the multispectral data including: the true appearance of the surface; discrimination between snow and bare ice; reflectance variations within bright snow; recovered reflectance values in regions of sensor saturation; and subtle topographic variations associated with ice flow. LIMA is viewable and individual scenes or user defined portions of the mosaic are downloadable at http://lima.usgs.gov. Educational materials associated with LIMA are available at http://lima.nasa.gov.

Remote Sensing of Environment

Atmospheric nitrogen in the Mississippi River Basin: Amissions, deposition and transport

Atmospheric deposition of nitrogen has been cited as a major factor in the nitrogen saturation of forests in the north-eastern United States and as a contributor to the eutrophication of coastal waters, including the Gulf of Mexico near the mouth of the Mississippi River. Sources of nitrogen emissions and the resulting spatial patterns of nitrogen deposition within the Mississippi River Basin, however, have not been fully documented. An assessment of atmospheric nitrogen in the Mississippi River Basin was therefore conducted in 1998-1999 to: (1) evaluate the forms in which nitrogen is deposited from the atmosphere; (2) quantify the spatial distribution of atmospheric nitrogen deposition throughout the basin; and (3) relate locations of emission sources to spatial deposition patterns to evaluate atmospheric transport. Deposition data collected through the NADP/NTN (National Atmospheric Deposition Program/National Trends Network) and CASTNet (Clean Air Status and Trends Network) were used for this analysis. NO(x) Tier 1 emission data by county was obtained for 1992 from the US Environmental Protection Agency (Emissions Trends Viewer CD, 1985-1995, version 1.0, September 1996) and NH3 emissions data was derived from the 1992 Census of Agriculture (US Department of Commerce. Census of Agriculture, US Summary and County Level Data, US Department of Commerce, Bureau of the Census. Geographic Area series, 1995:1b) or the National Agricultural Statistics Service (US Department of Agriculture. National Agricultural Statistics Service Historical Data. Accessed 7/98 at URL, 1998. http://www.usda.gov/nass/pubs/hisdata.htm). The highest rates of wet deposition of NO3- were in the north-eastern part of the basin, downwind of electric utility plants and urban areas, whereas the highest rates of wet deposition of NH4+ were in Iowa, near the center of intensive agricultural activities in the Midwest. The lowest rates of atmospheric nitrogen deposition were on the western (windward) side of the basin, which suggests that most of the nitrogen deposited within the basin is derived from internal sources. Atmospheric transport eastward across the basin boundary is greater for NO3- than NH4+, but a significant amount of NH4+ is likely to be transported out of the basin through the formation of (NH4)2SO4 and NH4NO3 particles - a process that greatly increases the atmospheric residence time of NH4+. This process is also a likely factor in the atmospheric transport of nitrogen from the Midwest to upland forest regions in the North-East, such as the western Adirondack region of New York, where NH4+ constitutes 38% of the total wet deposition of N.

Science of Total Environment

Water quality in the Arthur R. Marshall Loxahatchee National Wildlife Refuge — Trends and spatial characteristics of selected constituents, 1974-2004

Water quality in the interior marsh of the Arthur R. Marshall Loxahatchee National Wildlife Refuge is characterized by low concentrations of major ions, principally sodium and chloride, and is affected primarily by natural seasonal processes, such as evapotranspiration, rainfall, and biological activity. During the dry season, evapotranspiration exceeds precipitation, and specific conductance and conservative ion concentrations at marsh background sites typically increase by 40-70 percent between the end of the rainy season in September and the end of the dry season in May. Water enters the Refuge mainly from rainfall and perimeter canals. Water is pumped into the perimeter canals from large pumping stations, such as S-5A and S-6. In recent years, much of the water pumped into the Refuge passes through Stormwater Treatment Areas (STAs) before being released into the perimeter canals that surround the Refuge. Since 2001, water at S-6 has been diverted south toward STA-2, away from the Refuge perimeter canals. Water from S-5A and S-6 flows through agricultural lands with intense agricultural activity and typically contains relatively high concentrations of major ions, nutrients, and pesticides. Specific conductance, major-ion concentrations, and nutrient concentrations are an order of magnitude higher at S-5A and S-6 canal sites than at interior marsh sites. Water quality in the marsh bordering the canals can be affected substantially by the canal water, and these effects can extend several miles or more into the marsh depending on location in the Refuge and on the water level in the canals. As canal water flows into the marsh, processes such as uptake by periphyton and rooted vegetation and settling of particulate matter reduce the concentrations of nutrients to a greater extent than conservative ions such as chloride. Long- and short-term trends for specific conductance, chloride ion, sulfate ion, total phosphorus, and total nitrogen at five sites were evaluated primarily using an uncensored seasonal Kendall test with a water-level adjustment to reduce the effects of long wet or dry periods. Significant long-term trends (1974-2003) for specific conductance, chloride, total phosphorus, and total nitrogen at canal sites S-5A and S-6 were generally downward. Of the five sites, S-5A had the most pronounced decline for specific conductance at about -340 microsiemens per centimeter (?S/cm), followed by S-6 with a decline of about -280 ?S/cm. The two internal marsh sites, LOX8 and LOX13, had significant long-term trends in specific conductance of about +37 and -36 ?S/cm, respectively. Long-term trends for other constituents at the two internal marsh sites were generally small in magnitude or not measurable between 1978 and 2003. Marsh site LOX15 near the Hillsboro Canal showed no long-term trends, although specific conductance and sulfate concentration increased about 560 ?S/cm and 30 milligrams per liter, respectively, from 1998 to 2002. Site LOX15 is influenced strongly by intrusions of canal water, and increases in specific conductance and sulfate at this site coincided with increased canal-water inflows from STA-1W between 2001 and 2003. Median concentrations at LOX13 and S-5A were used to represent background and canal concentrations, respectively. Based on these values, the median chloride concentration at LOX15 indicates that the water is typically about 31 percent canal water and 69 percent ?natural? background water. Using median sulfate concentrations, similarly to chloride, the fraction of water at LOX15 was estimated to be 17 percent from canals and 83 percent from ?natural? background water. This finding suggests that in the low sulfate environment of the Refuge, sulfate is not conservative and only about half of the sulfate from canal water typically reaches LOX15; the rest presumably is removed by marsh plants, algae, and bottom sediments. Concentrations of pesticides and other organic compounds were measured

Florida

The EnMAP spaceborne imaging spectroscopy mission: Initial scientific results two years after launch

Imaging spectroscopy has been a recognized and established remote sensing technology since the 1980s, mainly using airborne and field-based platforms to identify and quantify key bio- and geo-chemical surface and atmospheric compounds, based on characteristic spectral reflectance features in the visible-near infrared (VNIR) and short-wave infrared (SWIR). Spaceborne missions, a leap in technology, were sparse, starting with the CHRIS/PROBA and EO1/Hyperion missions in the early 2000s, and providing spectroscopy data with limited spectral coverage and/or low data quality in the SWIR. Since 2019, several countries and agencies have successfully launched a number of spaceborne imaging spectroscopy systems into orbit or deployed them on the International Space Station (ISS) such as DESIS, PRISMA, HISUI, GF-5, EnMAP and EMIT. Among these recent missions, the German Environmental Mapping and Analysis Program (EnMAP) stands for its long-term development, sophisticated design with on-board calibration, high data quality requirements, and extensive accompanying science program. EnMAP was launched in April 2022 and, following a successful commissioning phase, started its operational activities in November 2022. The EnMAP mission encompasses global coverage from 80° N to 80° S through on-demand data acquisitions. Data are free and open access with 30 m spatial resolution, a high spectral resolution with a spectral sampling distance of 6.5 nm and 10 nm in the VNIR and SWIR regions respectively, and a high signal-to-noise ratio. In this paper, we aim to present the mission's current status, coverage, science capabilities and performance two years after launch. We show the potential of EnMAP for space-based imaging spectroscopy to operate in various environments, including high and low light levels, dense forests, Antarctic glaciers, and arid agricultural areas. EnMAP enables various applications in fields such as agriculture and forestry, soil compositional, raw materials, and methane mapping, as well as water quality assessment, and snow and ice properties. The results show that EnMAP's performance exceeds the mission requirements, and highlights the significant potential for contribution to scientific exploitation in various geo- and biochemical sciences. EnMAP is also expected to serve as a key tool for the development and testing of data processing algorithms for upcoming global operational missions.

Remote Sensing of Environment

USA: Glacier National Park, Biosphere Reserve and GLORIA Site

The National Park Service of the United States has 388 designated protected areas and parks that include historic and cultural sites as well as ‘natural resource’ parks set aside for their unique and outstanding natural features. Early efforts to create parks were focused on areas of beauty or unusual features but later efforts increasingly aimed to protect biodiversity and intact ecosystems. Protected areas in the National Park Service are found in nearly all the fifty states from Florida to Alaska, with examples of preserved natural environments ranging from coral reefs to the icy summit of Mt. McKinley in Alaska, at 6,187 m. Many of the larger parks have been designated as Biosphere Reserves under the United Nations Educational, Scientific and Cultural Organization (UNESCO) Man and the Biosphere Programme. The area now managed as Glacier National Park was first set aside as a Forest Reserve in 1897 and then designated as a national park in 1910, six years before a national park service was created to oversee the growing number of parks that the US Congress was establishing. Waterton National Park was created by Canada immediately north of the US–Canada border during the same period. In 1932, a joint lobbying effort by private citizens and groups convinced both the United States and Canada to establish the world’s first trans-boundary park to explicitly underscore and symbolize the neighbourly relationship between these two countries. This became the world’s first ‘peace’ park and was named Waterton–Glacier International Peace Park. The combined park is managed collaboratively on many issues but each national park is separately funded and operates under different national statutes and laws. It was, however, jointly named a Biosphere Reserve in 1976 and a World Heritage Site in 1995. There have been recent efforts to significantly increase the size of Waterton National Park by adding publicly owned forests on the western side of the continental divide in British Columbia, Canada. For the purposes of this chapter, I will emphasize the US portion of the Waterton-Glacier International Peace Park and refer to it as the Glacier Mountain Biosphere Reserve (MBR).

Montana

Emplacement of Holocene silicic lava flows and domes at Newberry, South Sister, and Medicine Lake volcanoes, California and Oregon

This field guide for the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly 2017 focuses on Holocene glassy silicic lava flows and domes on three volcanoes in the Cascade Range in Oregon and California: Newberry, South Sister, and Medicine Lake volcanoes. Although obsidian-rich lava flows have been of interest to geologists, archaeologists, pumice miners, and rock hounds for more than a century, many of their emplacement characteristics had not been scientifically observed until two very recent eruptions in Chile. Even with the new observations, several eruptive processes discussed in this field trip guide can only be inferred from their final products. This makes for lively debates at outcrops, just as there have been in the literature for the past 30 years. Of the three volcanoes discussed in this field guide, one (South Sister) lies along the main axis defined by major peaks of the Cascade Range, whereas the other two lie in extensional tectonic settings east of the axis. These two tectonic environments influence volcano morphology and the magmatic and volcanic processes that form silicic lava flows and domes. The geomorphic and textural features of glass-rich extrusions provide many clues about their emplacement and the magma bodies that fed them. The scope of this field guide does not include a full geologic history or comprehensive explanation of hazards associated with a particular volcano or volcanic field. The geochemistry, petrology, tectonics, and eruption history of Newberry, South Sister, and Medicine Lake volcanic centers have been extensively studied and are discussed on other field excursions. Instead, we seek to explore the structural, textural, and geochemical evolution of well-preserved individual lava flows—the goal is to understand the geologic processes, rather than the development, of a specific volcano.

California, Oregon

The Sonju Lake layered intrusion, northeast Minnesota: Internal structure and emplacement history inferred from magnetic fabrics

The Sonju Lake intrusion (SLI), in northeastern Minnesota, is a layered mafic complex of Keweenawan age (1096.1 ?? 0.8 Ma) related to the Midcontinent rift. The cumulate paragenesis of the intrusion is recognized as broadly similar to the Skaergaard intrusion, a classic example of closed-system differentiation of a tholeiitic mafic magma. The SLI represents nearly closed-system differentiation through bottom-up fractional crystallization. Geochemical studies have identified the presence of a stratabound, 50-100 m thick zone anomalously enriched in Au + PGE. Similar to the PGE reefs of the Skaergaard intrusion, this PGE-enriched zone is hosted within oxide gabbro cumulates, about two-third of the way up from the base of the intrusion. We present a petrofabric study using the anisotropy of magnetic susceptibility (AMS) to investigate the emplacement and flow patterns within the Sonju Lake intrusion. Petrographic and electron microprobe studies, combined with AMS and hysteresis measurements indicate the primary source of the magnetic signal is pseudo-single domain (PSD) magnetite or titanomagnetite. Low field AMS was measured at 32 sites within the Sonju Lake intrusion, which provided information about primary igneous fabrics. The magnetic fabrics in the layered series of the Sonju Lake intrusion are consistent with sub-horizontal to inclined emplacement of the intrusion and show evidence that the cumulate layers were deposited in a dynamic environment. Well-aligned magnetic lineations, consistently plunging shallowly toward the southwest, indicate the source of the magma is a vertical sill-like feeder, presumably located beneath the Finland granite. The Finland granite acted as a density trap for the Sonju Lake magmas, forcing lateral flow of magma to the northeast. The strongly oblate magnetic shape fabrics indicate the shallowly dipping planar fabrics were enhanced by compaction of the crystal mush. ?? 2007 Elsevier B.V. All rights reserved.

Precambrian Research

Internal nutrient sources and nutrient distributions in Alviso Pond A3W, California

Within the Alviso Salt Pond complex, California, currently undergoing avian-habitat restoration, pore-water profilers (U.S. Patent 8,051,727 B1) were deployed in triplicate at two contrasting sites in Pond A3W (“Inlet”, near the inflow, and “Deep”, near the middle of the pond; figs. 1 and 2; table 1, note that tables in this report are provided online only as a .xlsx workbook at http://pubs.usgs.gov/of/2013/1128/). Deployments were conducted in 2010 and 2012 during the summer algal-growth season. Specifically, three deployments, each about 7 weeks apart, were undertaken each summer. This study provides the first measurements of the diffusive flux of nutrients across the interface between the pond bed and water column (that is, benthic nutrient flux). These nutrient fluxes are crucial to pond restoration efforts because they typically represent a major (if not the greatest) source of nutrients to the water column in both ponds and other lentic systems. For soluble reactive phosphorus (SRP, the most biologically available form in solution), benthic flux was positive both years (that is, out of the sediment into the water column; table 2), with the exception of the August 2010 deployment, which exhibited nearly negligible but negative flux. Overall, the average SRP flux was significantly greater at Deep (23.9 ± 8.6 micromoles per square meter per hour (µmol-m -2 -h -1 ); all errors shown reflect the 95-percent confidence interval) than Inlet (12.6 ± 4.9 µmol-m -2 -h -1 ). There was much greater temporal variability in SRP flux in the pond than reported for the lower estuary (Topping and others, 2001). For dissolved ammonia, benthic flux was consistently positive on all six sampling trips, and similar to SRP, the fluxes at Deep (258 ± 49 µmol-m -2 -h -1 ) were consistently greater than those at Inlet (28 ± 11 µmol-m -2 -h -1 ). Dissolved ammonia fluxes reported for South San Francisco Bay by Topping and others (2001) fall in between these values. Once again, greater variability for benthic fluxes determined in the pond was observed relative to adjacent South San Francisco Bay. With the near absence of any measurable concentration gradient, dissolved-nitrate fluxes were consistently negligible in the pond. Silica fluxes are often used to represent sediment diagenetic processes that biogeochemically cycle silica (an important algal macronutrient) between biogenic and inorganic phases (Fanning and Pilson, 1974; Emerson and others, 1984). For South San Francisco Bay, those values are consistently positive from core-incubation experiments. In Pond A3W, dissolved-silica fluxes averaged 49 ± 25 µmol-m -2 -h -1 at Inlet and were much higher at Deep (482 ± 370 µmol-m -2 -h -1 ), similar to the spatially variability observed for SRP and dissolved ammonia. An elevated silica flux can stimulate diatom production and subsequent eutrophication effects. Variability in these silica fluxes is consistent with season patterns in pond primary productivity. On the basis of comparisons of dissolved-oxygen flux measurements by profilers and core incubations, it appears that diffusive flux estimates for the sediment in this pond, as one might expected in such benthically productive environments, result in a significant underestimation of true sediment oxygen demand. Therefore, a core incubation experiment was conducted to better quantify the demand. To complement these benthic-flux studies, a diurnal study of nutrient advective flux into and out of the pond was measured during neap and spring tides to provide comparative estimates for allochthonous solute transport (Garret, 2012). Using the two different tides as the probable upper and lower boundaries, we can estimate a range of probable values throughout the year. After converting this advective flux into kg/yr, we can compare it directly to benthic flux estimates for the pond extrapolated over the 2.27 square kilometer (km 2 ) pond surface. Benthic flux of nitrogen species, averaged over all sites and dates, was about 80,000 kilograms per year (kg/yr), well above the adjective flux range of -50 to 1,500 kg/yr. By contrast, the average benthic flux of orthophosphate was about 12,000 kg/yr, well below the advective flux range of 21,500 to 30,000 kg/yr. Initial benthic flux estimates were also made for trace metals, including copper, nickel, iron, and manganese. These analyses indicated that the two sites, Inlet and Deep, have different pore-water profiles, with Inlet exhibiting much higher benthic flux estimates for nickel, iron, and manganese. These initial benthic-flux values reported for macronutrients are particularly impressive in magnitude when one considers that diffusive flux of dissolved solutes based on pore-water profiles provides a conservative determination that may be enhanced by other biogeochemical processes. These enhancement processes (Boudreau and Jorgensen, 2001) include bioturbation, bioirrigation, wind resuspension, and potential groundwater inflows, some of which are captured in core-incubation experiments (Kuwabara and others, 2009). Hence, the values reported herein represent lower bounds to indicate the potential importance of such internal solute sources. The elevated diffusive fluxes for nutrients in the pond relative to the adjacent estuary indicate that vertical nutrient transport between the pond bed and water column is consistently an important (and at times the most important) source of nutrients that stimulate phytoplankton growth in the water column. One might therefore reasonably hypothesize that this benthic transport of biologically reactive solutes (both nutrients and toxicants) represents the most important step at the base of the food web for trophic transfer.

California

Response to comment on “Persistence of pharmaceutical compounds and other organic wastewater contaminants in a conventional drinking-water-treatment plant”

The U.S. Geological Survey (USGS) and the Centers for Disease Control thank Dr. Till for her comments concerning our research ( Till, 2005 ) and welcome the opportunity to respond. The primary objective of our study was to evaluate the potential for organic wastewater-related contaminants (OWCs), including pharmaceuticals, to survive a conventional drinking-water-treatment process and persist in potable-water supplies ( Stackelberg et al., 2004 ). Our study was supported by two USGS laboratories: the National Water Quality Laboratory (NWQL), which provided the HPLC/ESI-MS and CLLE GC/MS data and the Ocala Water Quality and Research Laboratory (OWQRL), which provided the LC/MS data ( Stackelberg et al., 2004 ). Although discussed as distinct techniques by Dr. Till and indicated by differing acronyms to distinguish the laboratories producing the data, as described in our paper, the two LC/MS methods are very similar; they consist of a solid-phase extraction method with analysis of the extract produced using high-performance liquid chromatography coupled to an electrospray ionization mass spectrometer operated in the positive mode. The NWQL and OWQRL report ‘trace’ and ‘ultratrace’ determinations of analytes that provide significant benefit for describing the presence and fate of low-level contaminants. For mass spectral methods, an analyte is qualitatively identified by its retention time on the chromatographic column as well as the presence of two or more confirming ions with area ratios that match that of the reference standard compounds. Because of a recognized increased risk of false positives, these qualitative identification criteria are used in conjunction with abundant quality-control samples (detailed below) to confirm detection prior to making an estimate of the concentration. These qualitative identification criteria must be met before a compound is considered present (or detected) in a sample ( Oblinger Childress et al., 1999 ). When a compound has been qualitatively identified in an environmental sample (whether above or below its reporting level [RL]), it is assessed in context with associated field and laboratory blanks, field and laboratory replicates, and other data, such as appropriate laboratory reagent spikes. An environmental concentration is calculated only after determining that field and laboratory procedures did not contaminate the samples. The concentrations are then calculated from 5- to 8-point calibration curves using internal standard quantitation. Our lowest calibration standard is intentionally much lower than the RL, typically 10 times lower. The most abundant molecular or fragment ion is used for quantitation, and, for the two LC/MS methods, at least one, and where possible two, qualifier ions are used for confirmation. For the GC/MS method, with its greater degree of fragmentation, one quantitation and two qualifier ions are used. When any of the abovementioned qualitative identification criteria are not met, the analyte is considered not present and is reported as “less than” the RL.

Science of the Total Environment

Public and private tapwater: Comparative analysis of contaminant exposure and potential risk, Cape Cod, Massachusetts, USA

Background Humans are primary drivers of environmental contamination worldwide, including in drinking-water resources. In the United States (US), federal and state agencies regulate and monitor public-supply drinking water while private-supply monitoring is rare; the current lack of directly comparable information on contaminant-mixture exposures and risks between private- and public-supplies undermines tapwater (TW) consumer decision-making. Methods We compared private- and public-supply residential point-of-use TW at Cape Cod, Massachusetts, where both supplies share the same groundwater source. TW from 10 private- and 10 public-supply homes was analyzed for 487 organic, 38 inorganic, 8 microbial indicators, and 3 in vitro bioactivities. Concentrations were compared to existing protective health-based benchmarks, and aggregated Hazard Indices (HI) of regulated and unregulated TW contaminants were calculated along with ratios of in vitro exposure-activity cutoffs. Results Seventy organic and 28 inorganic constituents were detected in TW. Median detections were comparable, but median cumulative concentrations were substantially higher in public supply due to 6 chlorine–disinfected samples characterized by disinfection byproducts and corresponding lower heterotrophic plate counts. Public-supply applicable maximum contaminant (nitrate) and treatment action (lead and copper) levels were exceeded in private-supply TW samples only. Exceedances of health-based HI screening levels of concern were common to both TW supplies. Discussion These Cape Cod results indicate comparable cumulative human-health concerns from contaminant exposures in private- and public-supply TW in a shared source-water setting. Importantly, although this study’s analytical coverage exceeds that currently feasible for water purveyors or homeowners, it nevertheless is a substantial underestimation of the full breadth of contaminant mixtures documented in the environment and potentially present in drinking water. Conclusion Regardless of the supply, increased public engagement in source-water protection and drinking-water treatment, including consumer point-of-use treatment, is warranted to reduce risks associated with long-term TW contaminant exposures, especially in vulnerable populations.

Massachusetts

Use of large-scale, multi-species surveys to monitor gyrfalcon and ptarmigan populations

We evaluated the ability of three large-scale, multi-species surveys in the Arctic to provide information on abundance and habitat relationships of Gyrfalcons ( Falco rusticolus ) and ptarmigan. The Program for Regional and International Shorebird Monitoring (PRISM) has surveyed birds widely across the arctic regions of Canada and Alaska since 2001. The Arctic Coastal Plain survey has collected abundance information on the North Slope of Alaska using fixed-wing aircraft since 1992. The Northwest Territories-Nunavut Bird Checklist has collected presence-absence information from little-known locations in northern Canada since 1995. All three surveys provide extensive information on Willow Ptarmigan (Lagopus lagopus) and Rock Ptarmigan (L. muta). For example, they show that ptarmigan are most abundant in western Alaska, next most abundant in northern Alaska and northwest Canada, and least abundant in the Canadian Archipelago. PRISM surveys were less successful in detecting Gyrfalcons, and the Arctic Coastal Plain Survey is largely outside the Gyrfalcon's breeding range. The Checklist Survey, however, reflects the expansive Gyrfalcon range in Canada. We suggest that collaboration by Gyrfalcon and ptarmigan biologists with the organizers of large scale surveys like the ones we investigated provides an opportunity for obtaining useful information on these species and their environment across large areas.

Alaska, Northern Canada

Depositional setting, petrology and chemistry of Permian coals from the Paraná Basin: 2. South Santa Catarina Coalfield, Brazil

In Brazil economically important coal deposits occur in the southern part of the Paraná Basin, where coal seams occur in the Permian Rio Bonito Formation, with major coal development in the states of Rio Grande de Sul and Santa Catarina. The current paper presents results on sequence stratigraphic interpretation of the coal-bearing strata , and petrological and geochemical coal seam characterization from the South Santa Catarina Coalfield, Paraná Basin. In terms of sequence stratigraphic interpretation the precursor mires of the Santa Catarina coal seams formed in an estuarine-barrier shoreface depositional environment , with major peat accumulation in a high stand systems tract (Pre-Bonito and Bonito seams), a lowstand systems tract (Ponta Alta seam, seam A, seam B) and a transgressive systems tract (Irapuá, Barro Branco and Treviso seams). Seam thicknesses range from 1.70 to 2.39 m, but high proportions of impure coal (coaly shale and shaley coal), carbonaceous shale and partings reduce the net coal thickness significantly. Coal lithoypes are variable, with banded coal predominant in the Barro Branco seam, and banded dull and dull coal predominantly in Bonito and Irapuá seams, respectively. Results from petrographic analyses indicate a vitrinite reflectance range from 0.76 to 1.63 %Rrandom (HVB A to LVB coal). Maceral group distribution varies significantly, with the Barro Branco seam having the highest vitrinite content (mean 67.5 vol%), whereas the Irapuá seam has the highest inertinite content (33.8 vol%). Liptinite mean values range from 7.8 vol% (Barro Branco seam) to 22.5 vol% (Irapuá seam). Results from proximate analyses indicate for the three seams high ash yields (50.2 – 64.2 wt.%). Considering the International Classification of in-Seam Coals, all samples are in fact classified as carbonaceous rocks (> 50 wt.% ash). Sulfur contents range from 3.4 to 7.7 wt.%, of which the major part occurs as pyritic sulfur. Results of X-ray diffraction indicate the predominance of quartz and kaolinite (also pyrite). Gypsum , gibbsite , jarosite and calcite were also identified in some samples. Feldspar was noted but is rare. The major element distribution in the three seams (coal basis) is dominated by SiO 2 (31.3 wt.%, mean value), Al 2 O 3 (14.5 wt.%, mean value) and Fe 2 O 3 (6.9 wt.%, mean value). Considering the concentrations of trace elements that are of potential environmental hazards the Barro Branco, Bonito and Irapuá seams (coal base) are significantly enriched in Co (15.7 ppm), Cr (54.5 ppm), Li (59.3 ppm), Mn (150.4 ppm), Pb (58.0 ppm) and V (99.6 ppm), when compared to average trace elements contents reported for U. S. coals. Hierarchical cluster analysis identified, based on similarity levels, three groups of major elements and seven groups of trace elements. Applying discriminant analyses using trace and major element distribution, it could be demonstrated that the three seams from Santa Catarina show distinct populations in the discriminant analyses plots, and also differ from the coals of Rio Grande do Sul analyzed in a previous study.

Santa Catarina