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At least 325 records · Page 18Linked to original sources
USGS2008

Microbial and chemical factors influencing methane production in laboratory incubations of low-rank subsurface coals

Lignite and subbituminous coals were investigated for their ability to support microbial methane production in laboratory incubations. Results show that naturally-occurring microorganisms associated with the coals produced substantial quantities of methane, although the factors influencing this process were variable among different samples tested. Methanogenic microbes in two coals from the Powder River Basin, Wyoming, USA, produced 140.5-374.6 mL CH 4 /kg ((4.5-12.0 standard cubic feet (scf)/ton) in response to an amendment of H 2 /CO 2 . The addition of high concentrations (5-10 mM) of acetate did not support substantive methane production under the laboratory conditions. However, acetate accumulated in control incubations where methanogenesis was inhibited, indicating that acetate was produced and consumed during the course of methane production. Acetogenesis from H 2 /CO 2 was evident in these incubations and may serve as a competing metabolic mode influencing the cumulative amount of methane produced in coal. Two low-rank (lignite A) coals from Fort Yukon, Alaska, USA, demonstrated a comparable level of methane production (131.1-284.0 mL CH4/kg (4.2-9.1 scf/ton)) in the presence of an inorganic nutrient amendment, indicating that the source of energy and organic carbon was derived from the coal. The concentration of chloroform-extractable organic matter varied by almost three orders of magnitude among all the coals tested, and appeared to be related to methane production potential. These results indicate that substrate availability within the coal matrix and competition between different groups of microorganisms are two factors that may exert a profound influence on methanogenesis in subsurface coal beds.

International Journal of Coal Geology↗
USGS2016

Contemporary deformation in the Yakima fold and thrust belt estimated with GPS

Geodetic, geologic and palaeomagnetic data reveal that Oregon (western USA) rotates clockwise at 0.3 to 1.0° Ma −1 (relative to North America) about an axis near the Idaho–Oregon–Washington border, while northeast Washington is relatively fixed. This rotation has been going on for at least 15 Ma. The Yakima fold and thrust belt (YFTB) forms the boundary between northern Oregon and central Washington where convergence of the clockwise-rotating Oregon block is apparently accommodated. North–south shortening across the YFTB has been thought to occur in a fan-like manner, increasing in rate to the west. We obtained high-accuracy, high-density geodetic GPS measurements in 2012–2014 that are used with earlier GPS measurements from the 1990s to characterize YFTB kinematics. The new results show that the deformation associated with the YFTB starts at the Blue Mountains Anticline in northern Oregon and extends north beyond the Frenchman Hills in Washington, past the epicentre of the 1872 M w 7.0 Entiat earthquake to 49°N. The north–south strain rate across the region is 2 to 3 × 10 −9 yr −1 between the volcanic arc and the eastern edge of the YFTB (241.0°E); east of there it drops to about 10 −9 yr −1 . At the eastern boundary of the YFTB, faults and earthquake activity are truncated by a north-trending, narrow zone of deformation that runs along the Pasco Basin and Moses Lake regions near 240.9°E. This zone, abutting the Department of Energy Hanford Nuclear Reservation, accommodates about 0.5 mm yr −1 of east to northeast shortening. A similar zone of N-trending transpression is seen along 239.9°E where there is a change in the strike of the Yakima folds. The modern deformation of the YFTB is about 600 km wide from south to north and internally may be controlled by pre-existing crustal structure.

Geophysical Journal International↗
USGS2011

Estimates of electricity requirements for the recovery of mineral commodities, with examples applied to sub-Saharan Africa

To produce materials from mine to market it is necessary to overcome obstacles that include the force of gravity, the strength of molecular bonds, and technological inefficiencies. These challenges are met by the application of energy to accomplish the work that includes the direct use of electricity, fossil fuel, and manual labor. The tables and analyses presented in this study contain estimates of electricity consumption for the mining and processing of ores, concentrates, intermediate products, and industrial and refined metallic commodities on a kilowatt-hour per unit basis, primarily the metric ton or troy ounce. Data contained in tables pertaining to specific currently operating facilities are static, as the amount of electricity consumed to process or produce a unit of material changes over time for a great number of reasons. Estimates were developed from diverse sources that included feasibility studies, company-produced annual and sustainability reports, conference proceedings, discussions with government and industry experts, journal articles, reference texts, and studies by nongovernmental organizations.

Open-File Report↗
USGS2001

Crocoite: An unusual mode of occurrence for lead in coal

What is believed to be a very unusual mode of occurrence for lead in coal has been identified as crocoite (PbCrO4). As part of a larger study on trace elements and mineralogy in the Cretaceous Main Seam in New Zealand, crocoite was found in raw coal samples within the lower part of the coal seam. X-ray diffraction (XRD) and bulk chemical data from a SEM equipped with an energy dispersive X-ray analyser (EDXA) have confirmed the identity of this mineral. This is apparently the first time that crocoite has been reported in coal. Crocoite usually occurs only in the oxidised zone of lead mineral deposits. The occurrence of this mineral in the Main Seam coal implies that the deposit was exposed to an oxidising environment at some stage, most likely after coalification. Published by Elsevier Science B.V.

International Journal of Coal Geology↗
USGS2011

Stopover ecology of a migratory ungulate

1. Birds that migrate long distances use stopover sites to optimize fuel loads and complete migration as quickly as possible. Stopover use has been predicted to facilitate a time-minimization strategy in land migrants as well, but empirical tests have been lacking, and alternative migration strategies have not been considered. 2. We used fine-scale movement data to evaluate the ecological role of stopovers in migratory mule deer Odocoileus hemionus — a land migrant whose fitness is strongly influenced by energy intake rather than migration speed. 3. Although deer could easily complete migrations (range 18–144 km) in several days, they took an average of 3 weeks and spent 95% of that time in a series of stopover sites that had higher forage quality than movement corridors. Forage quality of stopovers increased with elevation and distance from winter range. Mule deer use of stopovers corresponded with a narrow phenological range, such that deer occupied stopovers 44 days prior to peak green-up, when forage quality was presumed to be highest. Mule deer used one stopover for every 5∙3 and 6∙7 km travelled during spring and autumn migrations, respectively, and used the same stopovers in consecutive years. 4. Study findings indicate that stopovers play a key role in the migration strategy of mule deer by allowing individuals to migrate in concert with plant phenology and maximize energy intake rather than speed. Our results suggest that stopover use may be more common among non-avian taxa than previously thought and, although the underlying migration strategies of temperate ungulates and birds are quite different, stopover use is important to both. 5. Exploring the role of stopovers in land migrants broadens the scope of stopover ecology and recognizes that the applied and theoretical benefits of stopover ecology need not be limited to avian taxa.

Journal of Animal Ecology↗
USGS2012

Observed source parameters for dynamic rupture with non-uniform initial stressand relatively high fracture energy

We have conducted dynamic rupture propagation experiments to establish the relations between in-source stress drop, fracture energy and the resulting particle velocity during slip of an unconfined 2 m long laboratory fault at normal stresses between 4 and 8 MPa. To produce high fracture energy in the source we use a rough fault that has a large slip weakening distance. An artifact of the high fracture energy is that the nucleation zone is large such that precursory slip reduces fault strength over a large fraction of the total fault length prior to dynamic rupture, making the initial stress non-uniform. Shear stress, particle velocity, fault slip and acceleration were recorded coseismically at multiple locations along strike and at small fault-normal distances. Stress drop increases weakly with normal stress. Average slip rate depends linearly on the fault strength loss and on static stress drop, both with a nonzero intercept. A minimum fracture energy of 1.8 J/m 2 and a linear slip weakening distance of 33 μm are inferred from the intercept. The large slip weakening distance also affects the average slip rate which is reduced by in-source energy dissipation from on-fault fracture energy. Because of the low normal stress and small per event slip (∼86 μm), no thermal weakening such as melting or pore fluid pressurization occurs in these experiments. Despite the relatively high fracture energy, and the very low heat production, energy partitioning during these laboratory earthquakes is very similar to typical earthquake source properties. The product of fracture energy and fault area is larger than the radiated energy. Seismic efficiency is low at ∼2%. The ratio of apparent stress to static stress drop is ∼27%, consistent with measured overshoot. The fracture efficiency is ∼33%. The static and dynamic stress drops when extrapolated to crustal stresses are 2–7.3 MPa and in the range of typical earthquake stress drops. As the relatively high fracture energy reduces the slip velocities in these experiments, the extrapolated average particle velocities for crustal stresses are 0.18–0.6 m/s. That these experiments are consistent with typical earthquake source properties suggests, albeit indirectly, that thermal weakening mechanisms such as thermal pressurization and melting which lead to near complete stress drops, dominate earthquake source properties only for exceptional events unless crustal stresses are low.

Journal of Structural Geology↗
USGS2019

Globally detected volcanic lightning and umbrella dynamics during the 2014 eruption of Kelud, Indonesia

Volcanic lightning shows considerable promise as a monitoring and research tool to characterize explosive eruptions. Its key strengths are rapid and remote detection, because the radio signals produced by lightning can propagate thousands of km at the speed of light. Despite these tantalizing properties, the scientific work on volcanic lightning has only recently started gaining momentum. Much more is needed to understand what lightning reveals about the evolution of an eruption in near-real time. Here we examine the timing and energy release of lightning generated by the eruption of Kelud volcano in Indonesia on 13 February 2014, as detected by the World Wide Lightning Location Network (WWLLN). The eruption column reached at least 26 km above sea level, representing the highest plume since the advent of global lightning networks in the last decade. Therefore, it provides valuable constraints on the electrification of end-member, sustained Plinian columns. We investigate the lightning in context with satellite images, photographs, and other published studies. Results show that the earliest satellite-detected activity was a thermal anomaly at ~15:46 UTC, corresponding to a directed blast at the onset of eruption (and only a few lightning strokes). Following a brief pause, the eruption produced a sustained column and umbrella cloud that spread outward into the tropical stratosphere. Rates of umbrella expansion provide an average mass eruption rate (MER) in the range of 8 × 10 7 –1 × 10 8 kg s −1 . A more nuanced picture emerges from the time-varying MERs (determined between each satellite pass), which show rapid intensification during the first hour of eruption, followed by constant MER for about an hour, and waning toward the end (after ~17:50 UTC). At this stage, decreasing flux into the umbrella cloud coincides with column instability and formation of pyroclastic density currents, as recorded by photos from the ground ~17:45 UTC. We infer that some of the erupted mass partitioned into ground-hugging currents, leading to a lower apparent MER. Interestingly, there is not a 1:1 correlation between lightning intensity and MER over the course of eruption. Stroke rates increase sharply within the first 30–40 min (during rapid intensification of the plume), and then drop below 2 strokes per min once the MER remains constant. This suggests that electrification was controlled by the rate of increase in MER—in other words, the acceleration of particles out of the vent. We also show that lightning stroke-rates and energies are greatest within 50 km of the vent, even when the ash cloud extends >200 km downwind, indicating that lightning was focused in the regions of highest particle concentration and turbulence. Overall, we conclude that abrupt changes in lightning rates are clearly linked to changes in eruption behavior, and that rapid detection could aid monitoring efforts to characterize eruption rates or styles.

Journal of Volcanology and Geothermal Research↗
USGS2022

Molt patterns, aging criteria, and molt-breeding seasonality of 8 native forest birds from the Island of Hawaiʻi

Much of our knowledge on the patterns and timing of breeding and molting come from studies of temperate region birds, yet tropical birds can have markedly different phenologies. The Hawaiian Islands support multiple endemic bird species that have evolved for millions of years in isolation to a tropical environment with minimal seasonality. We examined data from multiple studies (1994–2020) conducted across the avian annual cycle, from multiple locations, to evaluate molt patterns and establish criteria for assignment of age and sex based on the WRP, or molt-cycle age classification system designed specifically for tropical species. In addition, we describe the phenologies of molt and breeding and quantify the differences in males and females based on plumage coloration and morphometrics for 8 native species. We were able to validate the WRP tropical bird aging system as an appropriate method for aging forest birds from the Island of Hawaiʻi and separate all 8 species examined into juvenile, formative, and definitive plumages based on feather patterns and molt limits. Additionally, 2 species had distinctive second basic plumages. All 8 species examined also had extended periods of breeding and molting unlike their familial temperate counterparts, but these high energy activities are largely partitioned into separate time periods. Each species had some degree of overlap in breeding and molting, but the frequency of individuals that were simultaneously in breeding condition and molting was low with only 2 species displaying a proportion of overlap greater than 10% among all captures. Accurate aging and sexing techniques improve the quality of data from banding studies and provide important information on how species adapt to their environments.

Hawai'i↗
USGS2009

Influence of shell morphology on distributions of unionids in the upper Mississippi River

Attempts to predict the distribution of unionids from readily measurable microhabitat descriptors (i.e. water depth, current velocity, stream size, sediment type) have been largely unsuccessful, but certain biological and calculated hydraulic variables have recently shown some predictive power. We used historic and recent data on unionids (from 1987 to 2003) and hydraulic conditions at 438 sample locations over a 38-km reach of the Upper Mississippi River (Navigation Pool 8) to compare the distribution of unionids with different shell morphologies. We evaluated whether sculptured, thick-shelled (STK) species would be found in areas with higher velocity and shear stress, compared to nonsculptured, thin-shelled (NSTN) species. We used classification trees to model the presence and absence of STK and NSTN species to determine which variables were most likely to predict their distribution. Candidate predictor variables included sampling gear, field substrate, water depth (bathymetry), slope, velocity, shear stress and Froude number under low, moderate and high discharges. Our models predicted that STK mussels would occupy a larger portion of the total aquatic area in this reach of the river than NSTN mussels. However, our data demonstrated that NSTN species used areas of higher shear stress and velocity than STK species, but were also present in backwaters with low energy, thus rejecting our hypothesis. The presence of NSTN species over a wide range of shear stress and velocity was probably due to the wide array of life histories displayed within this guild. Overall, these results are consistent with the flow refuge concept in which unionids are more prevalent in areas with low to moderate hydraulic stresses, regardless of shell morphology, and demonstrate the importance of incorporating abiotic and biotic variables into predictive models.

Journal of Molluscan Studies↗
USGS2007

Quantifying foodweb interactions with simultaneous linear equations: Stable isotope models of the Truckee River, USA

Aquatic foodweb models for 2 seasons (relatively high- [March] and low-flow [August] conditions) were constructed for 4 reaches on the Truckee River using ??13C and ??15N data from periphyton, macroinvertebrate, and fish samples collected in 2003 and 2004. The models were constructed with isotope values that included measured periphyton signatures and calculated mean isotope values for detritus and seston as basal food sources of each food web. The pseudo-optimization function in Excel's Solver module was used to minimize the sum of squared error between predicted and observed stable-isotope values while simultaneously solving for diet proportions for all foodweb consumers and estimating ??13C and ??15N trophic enrichment factors. This approach used an underdetermined set of simultaneous linear equations and was tested by running the pseudo-optimization procedure for 500 randomly selected sets of initial conditions. Estimated diet proportions had average standard deviations (SDs) of 0.03 to 0.04??? and SDs of trophic enrichment factors ranged from <0.005 to 0.05??? based on the results of the 500 runs, indicating that the modeling approach was very robust. However, sensitivity analysis of calculated detritus and seston ??13C and ??15N values indicated that the robustness of the approach is dependent on having accurate measures of all observed foodweb-component ??13c and ??15N values. Model results from the 500 runs using the mean isotope values for detritus and seston indicated that upstream food webs were the simplest, with fewer feeding groups and trophic interactions (e.g., 21 interactions for 10 feeding groups), whereas food webs for the reach downstream of the Reno-Sparks metropolitan area were the most complex (e.g., 58 interactions for 16 feeding groups). Nonnative crayfish were important omnivores in each reach and drew energy from multiple sources, but appeared to be energetic dead ends because they generally were not consumed. Predatory macroinvertebrate diets varied along the river and affected estimated trophic positions of fish that consumed them. Differences in complexity and composition of the food webs appeared to be related to season, but could also have been caused by interactions with nonnative species, especially invasive crayfish. ?? 2007 by The North American Benthological Society.

Journal of the North American Benthological Societ↗
USGS2017

Spatial demographic models to inform conservation planning of golden eagles in renewable energy landscapes

Spatial demographic models can help guide monitoring and management activities targeting at-risk species, even in cases where baseline data are lacking. Here, we provide an example of how site-specific changes in land use and anthropogenic stressors can be incorporated into a spatial demographic model to investigate effects on population dynamics of Golden Eagles ( Aquila chrysaetos ). Our study focused on a population of Golden Eagles exposed to risks associated with rapid increases in renewable energy development in southern California, U.S.A. We developed a spatially explicit, individual-based simulation model that integrated empirical data on demography of Golden Eagles with spatial data on the arrangement of nesting habitats, prey resources, and planned renewable energy development sites. Our model permitted simulated eagles of different stage-classes to disperse, establish home ranges, acquire prey resources, prospect for breeding sites, and reproduce. The distribution of nesting habitats, prey resources, and threats within each individual's home range influenced movement, reproduction, and survival. We used our model to explore potential effects of alternative disturbance scenarios, and proposed conservation strategies, on the future distribution and abundance of Golden Eagles in the study region. Results from our simulations suggest that probable increases in mortality associated with renewable energy infrastructure (e.g., collisions with wind turbines and vehicles, electrocution on power poles) could have negative consequences for population trajectories, but that site-specific conservation actions could reduce the magnitude of negative effects. Our study demonstrates the use of a flexible and expandable modeling framework to incorporate spatially dependent processes when determining relative effects of proposed management options to Golden Eagles and their habitats.

California↗
USGS1994

Emission rates of sulfur dioxide and carbon dioxide from Redoubt Volcano, Alaska during the 1989-1990 eruptions

Airborne measurements of sulfur dioxide emission rates in the gas plume emitted from fumaroles in the summit crater of Redoubt Volcano were started on March 20, 1990 using the COSPEC method. During the latter half of the period of intermittent dome growth and destruction, between March 20 and mid-June 1990, sulfur dioxide emission rates ranged from approximately 1250 to 5850 t/d, rates notably higher than for other convergent-plate boundary volcanoes during periods of active dome growth. Emission rates following the end of dome growth from late June 1990 through May 1991 decreased steadily to less than 75 t/d. The largest mass of sulfur dioxide was released during the period of explosive vent clearing when explosive degassing on December 14-15 injected at least 175,000 ?? 50,000 tonnes of SO2 into the atmosphere. Following the explosive eruptions of December 1989, Redoubt Volcano entered a period of intermittent dome growth from late December 1989 to mid-June 1990 during which Redoubt emitted a total mass of SO2 ranging from 572,000 ?? 90,000 tonnes to 680,000 ?? 90,000 tonnes. From mid-June 1990 through May 1991, the volcano was in a state of posteruption degassing into the troposphere, producing approximately 183,000 ?? 50,000 tonnes of SO2. We estimate that Redoubt Volcano released a minimum mass of sulfur dioxide of approximately 930,000 tonnes. While COSPEC data were not obtained frequently enough to enable their use in eruption prediction, SO2 emission rates clearly indicated a consistent decline in emission rates between March through October 1990 and a continued low level of emission rates through the first half of 1991. Values from consecutive daily measurements of sulfur dioxide emission rates spanning the March 23, 1990 eruption decreased in the three days prior to eruption. That decrease was coincident with a several-fold increase in the frequency of shallow seismic events, suggesting partial sealing of the magma conduit to gas loss that resulted in pressurization of the shallow magma system and an increase in earthquake activity. Unlike the short-term SO2 decrease in March 1990, the long-term decrease of sulfur dioxide emission rates from March 1990 through May 1991 was coincident with low rates of seismic energy release and was interpreted to reflect gradual depressurization of the shallow magma reservoir. The long-term declines in seismic energy release and in SO2 emission rates led AVO scientists to conclude on April 19, 1991 that the potential for further eruptive activity from Redoubt Volcano had diminished, and on this basis, the level of concern color code for the volcano was changed from code yellow (Volcano is restless; earthquake activity is elevated; activity may include extrusion of lava) to code green (Volcano is in its normal 'dormant' state). ?? 1994.

Journal of Volcanology and Geothermal Research↗
USGS2005

Reply to “Commentary: Assessment of past infiltration fluxes through Yucca Mountain on the basis of the secondary mineral record—Is it a viable methodology?” by Y.V. Dublyansky and S.Z. Smirnov

Many of the comments by Dublyansky and Smirnov (2005) on Marshall et al. (2003) reflect a longstanding debate over the origin of secondary calcite and opal deposits found in cavities and on fracture surfaces at Yucca Mountain, Nevada, site of a proposed high-level nuclear waste repository (US Department of Energy, 2001). These comments require consideration of data and interpretations beyond the scope of Marshall et al. (2003). Dublyansky et al. (2004) and Dublyansky et al. (2005) also have commented on papers published by Whelan et al. (2002) and Wilson et al. (2003), and we will refer to the replies to those comments (Whelan et al., 2004, Wilson and Cline, 2005) in addressing the comments that go beyond the scope of Marshall et al. (2003).

Nevada↗
USGS1997

Power distribution in complex environmental negotiations: Does balance matter?

We studied six interagency negotiations covering Federal Energy Regulatory Commission (FERC) hydroelectric power licenses. Negotiations occurred between state and federal resource agencies and developers over project operations and natural resource mitigation. We postulated that a balance of power among parties was necessary for successful negotiations. We found a complex relationship between balanced power and success and conclude that a balance of power was associated with success in these negotiations. Power played a dynamic role in the bargaining and illuminates important considerations for regulatory design.

Journal of Public Administration Research and Theo↗
USGS2001

Life in the fast lane: Fish and foodweb structure in the main channel of large rivers

We studied the main channel of the lower Illinois River and of the Mississippi River just upstream and downstream of its confluence with the Illinois River to describe the abundance, composition, and/or seasonal appearance of components of the main-channel community. Abundance of fishes in the main channel was high, especially adults. Most adult fishes were present in the main channel for either 3 or 4 seasons/y, indicating that fishes regularly reside in the main channel. We documented abundant zooplankton and benthic invertebrates in the main channel, and the presence of these food types in the diets of channel catfish and freshwater drum. All trophic levels were well represented in the main channel, indicating that the main channel supports a unique food web. The main channel also serves as an important energetic link with other riverine habitats (e.g., floodplains, secondary channels, backwater lakes) because of the mobility of resident fishes and because of the varied energy sources supplying this food web. It may be more realistic to view energy flow in large-river systems as a combination of 3 existing concepts, the river continuum concept (downstream transport), the flood pulse concept (lateral transport to the floodplain), and the riverine productivity model (autochthonous production). We urge additional research to quantify the links between the main channel and other habitat types in large rivers because of the apparent importance of main-channel processes in the overall structure and function of large-river ecosystems.

Illinois↗
USGS2015

Soil disturbance as a driver of increased stream salinity in a semiarid watershed undergoing energy development

Salinization is a global threat to the quality of streams and rivers, but it can have many causes. Oil and gas development were investigated as one of several potential causes of changes in the salinity of Muddy Creek, which drains 2470 km2 of mostly public land in Wyoming, U.S.A. Stream discharge and salinity vary with seasonal snowmelt and define a primary salinity-discharge relationship. Salinity, measured by specific conductance, increased substantially in 2009 and was 53-71% higher at low discharge and 33-34% higher at high discharge for the years 2009-2012 compared to 2005-2008. Short-term processes (e.g., flushing of efflorescent salts) cause within-year deviations from the primary relation but do not obscure the overall increase in salinity. Dissolved elements associated with increased salinity include calcium, magnesium, and sulfate, a composition that points to native soil salts derived from marine shales as a likely source. Potential causes of the salinity increase were evaluated for consistency by using measured patterns in stream chemistry, slope of the salinity-discharge relationship, and inter-annual timing of the salinity increase. Potential causes that were inconsistent with one or more of those criteria included effects from precipitation, evapotranspiration, reservoirs, grazing, irrigation return flow, groundwater discharge, discharge of energy co-produced waters, and stream habitat restoration. In contrast, surface disturbance of naturally salt-rich soil by oil and gas development activities, such as pipeline, road, and well pad construction, is a reasonable candidate for explaining the salinity increase. As development continues to expand in semiarid lands worldwide, the potential for soil disturbance to increase stream salinity should be considered, particularly where soils host substantial quantities of native salts.

Journal of Hydrology: Regional Studies↗
USGS1998

Coalbed methane: from hazard to resource

Coalbed gas, which mainly consists of methane, has remained a major hazard affecting safety and productivity in underground coal mines for more than 100 yr. Coalbed gas emissions have resulted in outbursts and explosions where ignited by open lights, smoking or improper use of black blasting powder, and machinery operations. Investigations of coal gas outbursts and explosions during the past century were aimed at predicting and preventing this mine hazard. During this time, gas emissions were diluted with ventilation by airways (eg, tunnels, vertical and horizontal drillholes, shsfts) and by drainage boreholes. The 1970s 'energy crisis' led to studies of the feasibility of producing the gas for commercial use. Subsequent research on the origin, accumulation, distribution, availability, and recoverability has been pursued vigorously during the past two decades. Since the 1970s research investigations on the causes and effects of coal mine outbursts and gas emissions have led to major advances towards the recovery and development of coalbed methane for commercial use. Thus, coalbed methane as a mining hazard was harnessed as a conventional gas resource.Coalbed gas, which mainly consists of methane, has remained a major hazard affecting safety and productivity in underground coal mines for more than 100 years. Coalbed gas emissions have resulted in outbursts and explosions where ignited by open lights, smoking or improper use of black blasting powder, and machinery operations. Investigations of coal gas outbursts and explosions during the past century were aimed at predicting and preventing this mine hazard. During this time, gas emissions were diluted with ventilation by airways (e.g., tunnels, vertical and horizontal drillholes, shafts) and by drainage boreholes. The 1970's `energy crisis' led to studies of the feasibility of producing the gas for commercial use. Subsequent research on the origin, accumulation, distribution, availability, and recoverability has been pursued vigorously during the past two decades. Since the 1970's research investigations on the causes and effects of coal mine outbursts and gas emissions have led to major advances towards the recovery and development of coalbed methane for commercial use. Thus, coalbed methane as a mining hazard was harnessed as a conventional gas resource.

International Journal of Coal Geology↗
USGS1990

Solid-solution aqueous-solution equilibria: Thermodynamic theory and representation

Thorstenson and Plummer's (1977) "stoichiometric saturation' model is reviewed, and a general relation between stoichiometric saturation Kss constants and excess free energies of mixing is derived for a binary solid-solution B1-xCxA: GE = RT[ln Kss - xln(xKCA) - (l-x)ln((l-x)KBA)]. This equation allows a suitable excess free energy function, such as Guggenheim's (1937) sub-regular function, to be fitted from experimentally determined Kss constants. Solid-phase free energies and component activity-coefficients can then be determined from one or two fitted parameters and from the endmember solubility products KBA and KCA. A general form of Lippmann's (1977,1980) "solutus equation is derived from an examination of Lippmann's (1977,1980) "total solubility product' model. Lippmann's II or "total solubility product' variable is used to represent graphically not only thermodynamic equilibrium states and primary saturation states but also stoichiometric saturation and pure phase saturation states.

American Journal of Science↗