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Low-level radioactive-waste burial at the Palos Forest Preserve, Illinois: Geology and hydrology of the glacial drift, as related to the migration of tritium

A low-level radioactive-waste burial site is located in Palos Forest Preserve, about 22 kilometers southwest of Chicago, Illinois. Between 1943 and 1949 the site, named Plot M, was filled with radioactive waste from the first Argonne National Laboratory and from the University of Chicago Metallurgical Laboratory. Since 1973, tritium concentration levels up to 14 nanocuries per liter have been measured in water samples collected from a well 360 meters from the burial site. The U.S. Geological Survey is studying the geologic, hydrologic, and geochemical properties of the glacial drift and underlying bedrock at the Plot M site to determine the factors that control the movement of radionuclides. Test wells were drilled into the drift to collect water and core samples for laboratory analysis, to gather geologic and hydrologic data, and to conduct geophysical surveys. Plot M is located in drift that ranges in thickness from 25 to 45 meters. The drift is a stratified sequence of clay- and silt-rich sediments that contain thin, interstratified sand layers. The silt content of the drift increases with depth. The permeability of the drift, as indicated by field and laboratory hydraulic conductivity tests, ranges from 1.0 x 10 -6 to 1.0 ? 10 -8 centimeters per second. A tritium plume, the contaminated zone in the drift in which tritium concentration levels exceed 10 nanocuries per liter of water, extends horizontally northward from Plot M at least 50 meters and vertically downward to bedrock. The center of the plume, where tritium concentration levels are as high as 50,000 nanocuries per liter, is approximately 15 meters beneath the burial site. The size, shape, and 'bull's-eye' concentration pattern indicate that the plume is a single slug and that the site no longer releases tritium into the drift. The leading edge, or front, of the plume (the 10 nanocuries per liter boundary) left the burial site in either the late 1940's or the early 1950's and intersected the underlying bedrock surface before 1973. The calculated movement rate of the front is 6.3 x 10 -6 centimeters per second. Several key factors that control both the concentration level and the extent of migration of tritium in the drift at Plot M are 1. The limited amount of tritiated waste buried at Plot M. 2. The long period of time that has elapsed since the waste was buried (30-35 years) relative to the radioactive half-life of tritium (12.3 years). 3. The great thickness and low permeability of the glacial drift at the site.

Illinios

Assessment of active sand volumes at Rockaway Beach and Fire Island in New York and Seven Mile Island in New Jersey

Between 2018 and 2023, the U.S. Geological Survey assessed shoreface sediment availability at three Atlantic Coast barrier island study sites in support of a National Fish and Wildlife Foundation project entitled, “Monitoring Hurricane Sandy Beach and Marsh Resilience in New York and New Jersey.” The three study sites are Seven Mile Island, New Jersey, Rockaway Beach peninsula, New York, and Fire Island, N.Y. Previously interpreted geologic boundaries from shoreface geophysical surveys and data from repeat bathymetric surveys at each of the study sites were integrated to quantify the active sediment volume, or the volume of sediment that could contribute to beach and shoreline behavior over annual to decadal time scales. This report describes the methods used to calculate these volumes and the variability of active sediment volume for each survey at the three study sites. Our data show that when shoreface volumes account for varying alongshore extent of each study site, Seven Mile Island and Rockaway Beach peninsula have about 1.5 times the active sediment volume measured at Fire Island.

New York, New Jersey

Introduction to the JEEG Agricultural Geophysics Special Issue

Near-surface geophysical methods have become increasingly important tools in applied agricultural practices and studies. The great advantage of geophysical methods is their potential rapidity, low cost, and spatial continuity when compared to more traditional methods of assessing agricultural land, such as sample collection and laboratory analysis. Agricultural geophysics investigations commonly focus on obtaining information within the soil profile, which generally does not extend much beyond 2 meters beneath the ground surface. Although the depth of interest oftentimes is rather shallow, the area covered by an agricultural geophysics survey can vary widely in scale, from experimental plots (10 s to 100 s of square meters), to farm fields (10 s to 100 s of hectares), up to the size of watersheds (10 s to 100 s of square kilometers). To date, three predominant methods—resistivity, electromagnetic induction (EMI), and ground-penetrating radar (GPR)—have been used to obtain surface-based geophysical measurements within agricultural settings. However, a recent conference on agricultural geophysics (Bouyoucos Conference on Agricultural Geophysics, September 8–10, 2009, Albuquerque, New Mexico; www.ag-geophysics.org) illustrated that other geophysical methods are being applied or developed. These include airborne electromagnetic induction, magnetometry, seismic, and self-potential methods. Agricultural geophysical studies are also being linked to ground water studies that utilize deeper penetrating geophysical methods than normally used.

Journal of Environmental & Engineering Geophysics

Characterizing the subsurface geology in and around the U.S. Army Camp Stanley Storage Activity, south-central Texas

Several U.S. Geological Survey projects, supported by the National Cooperative Geologic Mapping Program, have used multi-disciplinary approaches over a 14-year period to reveal the surface and subsurface geologic frameworks of the Edwards and Trinity aquifers of central Texas and the Arbuckle-Simpson aquifer of south-central Oklahoma. Some of the project achievements include advancements in hydrostratigraphic mapping, three-dimensional subsurface framework modeling, and airborne geophysical surveys as well as new methodologies that link geologic and groundwater flow models. One area where some of these milestones were achieved was in and around the U.S. Army Camp Stanley Storage Activity, located in north­western Bexar County, Texas, about 19 miles north­west of downtown San Antonio.

Texas

Geologic, hydrologic, and water-quality data from selected boreholes and wells in and near Belvidere, Illinois, 1989-96

This report presents selected geologic, hydrologic, and water-quality data collected in and near Belvidere, Ill., during 1989-96. The data were collected primarily by the U.S. Geological Survey and U.S. Environmental Protection Agency in support of an ongoing ground-water study of the glacial drift aquifer and bedrock aquifers of Ordovician and Cambrian age underlying the area. These data were collected from 8 boreholes and 52 wells within a 4 square-mile urbanized part of the 80 square-mile study area. Data include stratigraphic, lithologic, and physical descriptions of rock cores from 5 boreholes; geophysical logs of 23 boreholes; surface-geophysical surveys at 3 sites; ground-water levels at 46 wells; horizontal hydraulic conductivity estimated from slug tests at 32 boreholes and wells; and ground-water-quality information at 26 boreholes and wells. Ground-water-quality information include field characteristics and laboratory analyses of inorganic constituents, tritium, volatile organic compounds, and semivolatile organic compounds. Also included are construction logs for 11 monitoring wells and descriptions of the methods used for data collection.

Illinois

A deep research drill hole at the summit of an active volcano, Kilauea, Hawaii

Drilling and geophysical logging data for a 1,262 m‐deep bore hole in the area inferred to overlie the magma reservoir of Kilauea Volcano, Hawaii, support earlier interpretations based on surface geophysical surveys that a zone of brackish or saline water lies above the reservoir. Temperatures encountered within the hole are not sufficiently high to warrant commercial interest; the maximum temperature, 137°C, is at the hole bottom. However, the temperature gradient toward the bottom of the hole (approximately 160 m below sea level) increases sharply to about 370°C/km, perhaps partly reflecting the effect of decreased water circulation as suggested by the geophysical logging data. If this gradient persists or increases with depth, magmatic temperatures would be attained within 3 km from the hole bottom (i.e., approximately 4 km from ground surface)—a depth in accord with data from ground‐deformation and seismic studies.

Hawaii

Suitability of river delta sediment as proppant, Missouri and Niobrara Rivers, Nebraska and South Dakota, 2015

Sediment management is a challenge faced by reservoir managers who have several potential options, including dredging, for mitigation of storage capacity lost to sedimentation. As sediment is removed from reservoir storage, potential use of the sediment for socioeconomic or ecological benefit could potentially defray some costs of its removal. Rivers that transport a sandy sediment load will deposit the sand load along a reservoir-headwaters reach where the current of the river slackens progressively as its bed approaches and then descends below the reservoir water level. Given a rare combination of factors, a reservoir deposit of alluvial sand has potential to be suitable for use as proppant for hydraulic fracturing in unconventional oil and gas development. In 2015, the U.S. Geological Survey began a program of researching potential sources of proppant sand from reservoirs, with an initial focus on the Missouri River subbasins that receive sand loads from the Nebraska Sand Hills. This report documents the methods and results of assessments of the suitability of river delta sediment as proppant for a pilot study area in the delta headwaters of Lewis and Clark Lake, Nebraska and South Dakota. Results from surface-geophysical surveys of electrical resistivity guided borings to collect 3.7-meter long cores at 25 sites on delta sandbars using the direct-push method to recover duplicate, 3.8-centimeter-diameter cores in April 2015. In addition, the U.S. Geological Survey collected samples of upstream sand sources in the lower Niobrara River valley. At the laboratory, samples were dried, weighed, washed, dried, and weighed again. Exploratory analysis of natural sand for determining its suitability as a proppant involved application of a modified subset of the standard protocols known as American Petroleum Institute (API) Recommended Practice (RP) 19C. The RP19C methods were not intended for exploration-stage evaluation of raw materials. Results for the washed samples are not directly applicable to evaluations of suitability for use as fracture sand because, except for particle-size distribution, the API-recommended practices for assessing proppant properties (sphericity, roundness, bulk density, and crush resistance) require testing of specific proppant size classes. An optical imaging particle-size analyzer was used to make measurements of particle-size distribution and particle shape. Measured samples were sieved to separate the dominant-size fraction, and the separated subsample was further tested for roundness, sphericity, bulk density, and crush resistance. For the bulk washed samples collected from the Missouri River delta, the geometric mean size averaged 0.27 millimeters (mm), 80 percent of the samples were predominantly sand in the API 40/70 size class, and 17 percent were predominantly sand in the API 70/140 size class. Distributions of geometric mean size among the four sandbar complexes were similar, but samples collected from sandbar complex B were slightly coarser sand than those from the other three complexes. The average geometric mean sizes among the four sandbar complexes ranged only from 0.26 to 0.30 mm. For 22 main-stem sampling locations along the lower Niobrara River, geometric mean size averaged 0.26 mm, an average of 61 percent was sand in the API 40/70 size class, and 28 percent was sand in the API 70/140 size class. Average composition for lower Niobrara River samples was 48 percent medium sand, 37 percent fine sand, and about 7 percent each very fine sand and coarse sand fractions. On average, samples were moderately well sorted. Particle shape and strength were assessed for the dominant-size class of each sample. For proppant strength, crush resistance was tested at a predetermined level of stress (34.5 megapascals [MPa], or 5,000 pounds-force per square inch). To meet the API minimum requirement for proppant, after the crush test not more than 10 percent of the tested sample should be finer than the precrush dominant-size class. For particle shape, all samples surpassed the recommended minimum criteria for sphericity and roundness, with most samples being well-rounded. For proppant strength, of 57 crush-resistance tested Missouri River delta samples of 40/70-sized sand, 23 (40 percent) were interpreted as meeting the minimum criterion at 34.5 MPa, or 5,000 pounds-force per square inch. Of 12 tested samples of 70/140-sized sand, 9 (75 percent) of the Missouri River delta samples had less than 10 percent fines by volume following crush testing, achieving the minimum criterion at 34.5 MPa. Crush resistance for delta samples was strongest at sandbar complex A, where 67 percent of tested samples met the 10-percent fines criterion at the 34.5-MPa threshold. This frequency was higher than was indicated by samples from sandbar complexes B, C, and D that had rates of 50, 46, and 42 percent, respectively. The group of sandbar complex A samples also contained the largest percentages of samples dominated by the API 70/140 size class, which overall had a higher percentage of samples meeting the minimum criterion compared to samples dominated by coarser size classes; however, samples from sandbar complex A that had the API 40/70 size class tested also had a higher rate for meeting the minimum criterion (57 percent) than did samples from sandbar complexes B, C, and D (50, 43, and 40 percent, respectively). For samples collected along the lower Niobrara River, of the 25 tested samples of 40/70-sized sand, 9 samples passed the API minimum criterion at 34.5 MPa, but only 3 samples passed the more-stringent criterion of 8 percent postcrush fines. All four tested samples of 70/140 sand passed the minimum criterion at 34.5 MPa, with postcrush fines percentage of at most 4.1 percent. For two reaches of the lower Niobrara River, where hydraulic sorting was energized artificially by the hydraulic head drop at and immediately downstream from Spencer Dam, suitability of channel deposits for potential use as fracture sand was confirmed by test results. All reach A washed samples were well-rounded and had sphericity scores above 0.65, and samples for 80 percent of sampled locations met the crush-resistance criterion at the 34.5-MPa stress level. A conservative lower-bound estimate of sand volume in the reach A deposits was about 86,000 cubic meters. All reach B samples were well-rounded but sphericity averaged 0.63, a little less than the average for upstream reaches A and SP. All four samples tested passed the crush-resistance test at 34.5 MPa. Of three reach B sandbars, two had no more than 3 percent fines after the crush test, surpassing more stringent criteria for crush resistance that accept a maximum of 6 percent fines following the crush test for the API 70/140 size class. Relative to the crush-resistance test results for the API 40/70 size fraction of two samples of mine output from Loup River settling-basin dredge spoils near Genoa, Nebr., four of five reach A sample locations compared favorably. The four samples had increases in fines composition of 1.6–5.9 percentage points, whereas fines in the two mine-output samples increased by an average 6.8 percentage points.

Nebraska, South Dakota

Technical overview of the U.S. Geological Survey Earth Mapping Resources Initiative (Earth MRI)

The Earth Mapping Resources Initiative (Earth MRI) was developed by the U.S. Geological Survey in response to a Federal directive calling on various Federal agencies to address potential vulnerabilities in the Nation’s supply of critical mineral resources. The primary purpose of this initiative is to identify potentially mineralized areas containing critical minerals by gathering new basic geologic data about the United States and its territories and to make these data publicly available through the Earth MRI web portal ( https://usgs.gov/earthmri ). The gathering of data is accomplished through geophysical surveys, geologic mapping, and the collection of topographical (light detection and ranging, or lidar) data. In addition to identifying areas permissive for hosting critical minerals, the new data collected are likely to be helpful in addressing other societal needs as well, such as by helping to locate groundwater resources, providing information needed to mitigate effects of natural hazards, and identifying locations of the mineral resources useful for restoring and rebuilding aging infrastructure in the United States.

Fact Sheet

Geostatistical estimation of the bottom altitude and thickness of the Mississippi River Valley alluvial aquifer

The Mississippi River Valley alluvial aquifer (MRVA) caps a shallow system of aquifers and confining units in the Mississippi Alluvial Plain (MAP) that extends across 45,000 square miles of the midwestern and southern United States from Illinois to Louisiana. Irrigation water from the MRVA is required to sustain extensive crop production, which has resulted in groundwater-level declines since the late 1920s equal to nearly half of its thickness and in reduced baseflow of streams. Increased groundwater withdrawal for irrigation is expected to continue and threatens complete and irreversible aquifer dewatering (depletion). The exact amount of dewatering in the MRVA is uncertain because its vertical extent is poorly defined and the effects of groundwater withdrawal on the aquifer are not well understood. To provide stakeholders and managers with information and tools that promote understanding of the hydrogeologic framework of the MAP extent and its role in water-resource management, the U.S. Geological Survey (USGS) Water Availability and Use Science Program has funded a 5-year effort to assess groundwater availability and project future sustainability of water resources. Part of this study involves mapping the bottom altitude and thickness of the aquifer by using compilations of hydrogeologic data and applications of geostatistical analytics. Results of this mapping effort, presented here, are intended to enhance characterization of the shallow hydrogeologic framework and direct future airborne, ground-based, and waterborne geophysical surveys. Data used in support of the findings presented in this report are available as a USGS data release ( https://doi.org/10.5066/P9D9XR5F ).

Scientific Investigations Map

Analysis of the Shallow Groundwater Flow System at Fire Island National Seashore, Suffolk County, New York

Fire Island National Seashore (FIIS) occupies 42 kilometers of the barrier island for which it is named that lies off the southern shore of Suffolk County, N.Y. Freshwater in the highly permeable, sandy aquifer underlying Fire Island is bounded laterally by marine surface waters and at depth by saline groundwater. Interspersed throughout FIIS are 17 pre-existing residential communities that in summer months greatly increase in population through the arrival of summer residents and vacationers; in addition, the National Park Service (NPS) has established several facilities on the island to accommodate visitors to FIIS. The 2.2 million people estimated by the NPS to visit Fire Island annually impact groundwater quality through the release of waste-derived contaminants, such as nutrients, pathogens, and organic compounds, into the environment. Waste-contaminated groundwater can move through the aquifer and threaten the ecological health of the adjacent back-barrier estuaries to which much of the groundwater ultimately discharges. In 2004, the U.S. Geological Survey (USGS), in cooperation with the NPS, began a 3-year investigation to (1) collect groundwater levels and water-quality (nutrient) samples, (2) develop a three-dimensional model of the shallow (water-table) aquifer system and adjacent marine surface waters, and (3) calculate nitrogen loads in simulated groundwater discharges from the aquifer to back-barrier estuaries and the ocean. The hydrogeology of the shallow aquifer system was characterized from the results of exploratory drilling, geophysical surveying, water-level monitoring, and water-quality sampling. The investigation focused on four areas-the communities of Kismet and Robbins Rest, the NPS Visitor Center at Watch Hill, and the undeveloped Otis Pike Fire Island High Dune Wilderness. Thirty-five observation wells were installed within FIIS to characterize subsurface hydrogeology and establish a water-table monitoring network in the four study areas. A variable-density model of the shallow aquifer system and adjacent marine surface waters was developed to simulate groundwater flow patterns and rates. Nitrogen loads from the shallow aquifer system were calculated from representative total nitrogen (TN) concentrations and simulated groundwater discharges to back-barrier estuaries and the ocean. The model simulates groundwater directions, velocities, and discharge rates under 2005 mean annual conditions. Groundwater budgets were developed for recharge areas of similar land use that contribute freshwater to back-barrier estuaries, the ocean, and subsea-discharge zones. Total freshwater discharge from the shallow aquifer system is about 43,500 cubic meters per day (m3/d) (79.8 percent) to back-barrier estuaries and about 10,200 m3/d (18.7 percent) to the ocean; about 836 m3/d (1.5 percent) may exit the system as subsea underflow. The total contribution of fresh groundwater to shoreline discharge zones amounts to about 53,700 m3/d (98.5 percent). The median age of freshwater discharged to back-barrier estuaries and the ocean was 3.4 years, and the 95th-percentile age was 20 years. The TN concentrations and loads under 2005 mean annual conditions for areas that contribute fresh groundwater to back-barrier estuaries and the ocean were calculated for the principal land uses on Fire Island. The overall TN load from the shallow aquifer system to shoreline discharge zones is about 16,200 kilograms per year (kg/yr) (82.2 percent) to back-barrier estuaries and about 3,500 kg/yr (17.8 percent) to the ocean. The overall TN load to marine surface waters amounts to about 19,700 kg/yr-roughly 6 percent of the annual TN load from shallow groundwater entering the South Shore Estuary Reserve (SSER) from the Suffolk County mainland, which is about 345,000 kg/yr. In contrast to the TN load from shallow groundwater for the SSER watershed, which annually yields about 353 kilograms per square kilometer (kg/km2), the overall TN loa

Scientific Investigations Report

Water resources in basin-fill deposits in the Tularosa Basin, New Mexico

The Tularosa Basin, a faulted intermontane depression in south-central New Mexico, contains a thick sequence of alluvial and lacustrine deposits of Tertiary and Quaternary age. Most of these sediments are saturated with very saline water. Freshwater supplies (dissolved solids concentration < 1000 mg/L) principally are found in alluvial fans located around the basin margin. On the eastern side of the Tularosa Basin, fresh groundwater supplies are limited to alluvial fan deposits from Grapevine Canyon to about 3 mi south of Alamogordo. Data from surface geophysical surveys indicate that about 1.4 to 2.1 million acre-ft of freshwater may be in storage in this area, not all of which is recoverable. An additional 3.6 to 5.4 million acre-ft of slightly saline water (dissolved solids concentration 1000 to 3000 mg/L) may be in storage in the same area, again not all of which is recoverable. On the western side of the Tularosa Basin, alluvial fans in the vicinity of Rhodes Canyon may contain freshwater. Geophysical data indicate the freshwater zone may be as thick as 1500 ft in places; however, the limited number of wells in this area precludes a precise definition of the volume of freshwater in storage. To the south, freshwater is present in alluvial fans associated with the Ash Canyon drainage system. Geophysical data indicate that perhaps as much as 450,000 acre-ft of freshwater, not all recoverable, may be in storage in this area. Fan deposits between Ash Canyon and Rhodes canyon may contain additional freshwater supplies. Possibly 10.7 million acre-ft of freshwater, not all of which is recoverable, may be in storage on the western side of the Tularosa Basin. Possibly 180 million acre-ft of brine (concentrations of dissolved solids exceeding 35,000 mg/L), not all of which is recoverable, may be in storage in the Tularosa Basin. Information is sparse concerning the capability of saline aquifers in the Tularosa Basin to store and transmit fluid. (Author 's abstract)

Water-Resources Investigations Report

Sediment data from vibracores collected in 2016 from Fire Island, New York

Researchers from the U.S. Geological Survey (USGS) conducted a long-term coastal morphologic-change study at Fire Island, New York, prior to and after Hurricane Sandy impacted the area in October 2012. The Fire Island Coastal Change project objectives include understanding the morphologic evolution of the barrier island system on a variety of time scales (months to centuries) and resolving storm-related effects, post-storm beach response, and recovery. In April 2016, scientists from the USGS St. Petersburg Coastal and Marine Science Center conducted sediment sampling and geophysical surveys on Fire Island to characterize and quantify spatial variability in the subaerial geology with the goal of subsequently integrating onshore geology with other surf zone and nearshore datasets. This report, along with the accompanying USGS data release , serves as an archive of sediment data from 14 vibracores collected on April 10 and 11, 2016 (USGS Field Activity Number 2016–322–FA ), along 6 transects that extend from the upper to lower subaerial shoreface at Fire Island. Sedimentologic and stratigraphic metrics (for example, sediment texture or unit thicknesses) derived from these data can be used to assess spatial and temporal trends and may aid in understanding beach evolution. Data products include sample location tables, descriptive core logs, core photographs, results of sediment grain-size analyses, and geographic information system data files with accompanying formal Federal Geographic Data Committee metadata.

New York

Physical characteristics of dungeness crab and halibut habitats in Glacier Bay

In Glacier Bay National Park, Alaska there are ongoing studies of Dungeness Crab (Cancer magister) and Pacific Halibut (Hippoglosus stenolepis). Scientists of the United States Geological Survey (USGS) are attempting to ascertain life history, distribution, and abundance, and to determine the effects of commercial fishing in the park (Carlson et al., 1998). Statistical sampling studies suggest that seafloor characteristics and bathymetry affect the distribution, abundance and behavior of benthic species. Examples include the distribution of Dungeness crab which varies from 78 to 2012 crabs/ha in nearshore areas to depths of 18 m (O'Clair et al., 1995), and changes in halibut foraging behavior according to bottom type (Chilton et al., 1995). This report discusses geophysical data collected in six areas within the park in 1998. The geophysical surveying done in this and previous studies will be combined with existing population and sonic-tracking data sets as well as future sediment sampling, scuba, submersible, and bottom video camera observations to better understand Dungeness crab and Pacific halibut habitat relationships.

Alaska

Streams, springs, and volcanic lakes for volcano monitoring

Introduction Volcanic unrest can trigger appreciable change to surface waters such as streams, springs, and volcanic lakes. Magma degassing produces gases and soluble salts that are absorbed into groundwater that feeds streams and lakes. As magma ascends, the amount of heat and degassing will increase, and so will any related geochemical and thermal signal. Subsurface magma movement can cause pressurization that alters hydrostatic head and may induce groundwater discharge. Fluid-pressure changes have been linked to distal volcano-tectonic earthquakes (White and McCausland, 2016; Coulon and others, 2017) and phreatic eruptions (for example, Yamaoka and others, 2016). Clearly, changes in groundwater and surface waters are both indicators of unrest and clues to how and where magma is rising toward the surface. Where possible, it is prudent to incorporate real-time hydrologic data into multiparameter monitoring of restless volcanoes. Hydrologic dynamics can also be tracked by changes in groundwater levels that are commonly measured in shallow boreholes (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume, on boreholes; Hurwitz and Lowenstern, 2024). Although inferred to be common, relatively few volcano-hydrology anomalies are well documented, and many are essentially anecdotal (Newhall and others, 2001), reflecting the fact that high-resolution time series remain rare. Extreme examples include the 2008 eruption of Nevado del Huila, Colombia, where relatively minor phreatomagmatic eruptions were accompanied by expulsion of as much as 300 million cubic meters of groundwater from fissures high on the volcano (Worni and others, 2011), generating large lahars. Substantial decreases in flow rate from springs about 8 kilometers from the summit of Mayon Volcano, Philippines, have been noted before most eruptions in the 20th century (Newhall and others, 2001). Stream monitoring at Redoubt Volcano in 2009 allowed Werner and others (2012) to recognize that groundwater was unable to absorb (or scrub) the high flux of volcanic gas and that a high CO 2 /SO 2 precursor signal had been evident for 5 months prior to the eruption. A key to better interpreting hydrologic anomalies—or even identifying them—is therefore obtaining adequate baseline data. Most hydrologic monitoring at U.S. volcanoes has been accomplished by intermittent sampling surveys with annual or less frequent sampling (for example, https://hotspringchem.wr.usgs.gov/index.php ). More frequent sampling, however, generally is needed to establish reliable baselines. A recent hydrologic and hydrothermal monitoring experiment at 25 sites and 10 of the 12 level 4 (very high threat) volcanoes in the U.S. portion of the Cascade Range demonstrated that there is sufficient temporal variability in hydrothermal fluxes, even during quiescent periods, that one-time measurements will commonly have limited interpretive value (Crankshaw and others, 2018). Thus, surveys are best augmented with data from streamgages (for example, Evans and others, 2004; Bergfeld and others, 2008). Streamflow (water discharge) data allow measured temperature and specific conductance to be converted to heat and solute mass fluxes, which could be insightful parameters for detecting anomalous activity (McCleskey and others, 2012). At the Yellowstone Caldera, long-term monitoring of river solutes has allowed calculation of the chloride flux, a proxy for heat discharge (Hurwitz and others, 2007; McCleskey and others, 2016) from the subsurface magma. This is readily accomplished because data from streamgages are continuously recorded and archived by the U.S. Geological Survey (USGS) National Water Information System (NWIS) (USGS, 2024). Similar studies on stratovolcanoes or shield volcanoes would be scientifically useful, and yet are logistically challenging, requiring streamgages on numerous radial drainages complemented by either frequent manual sampling or numerous deployments of equipment to measure water temperature and specific conductance as a proxy for water chemistry. Another challenge is that some volcanic areas, especially shield volcanoes, are characterized by near-surface porous rocks and soils, such that surface streams are rare and replaced by distant, dilute large-volume springs with only a trace of any original volcanically sourced water (Manga, 2001; Hurwitz and others, 2021). Volcanic lakes are worthy of special attention for monitoring efforts, as their temperature and composition can provide evidence of increased flux of volatile-rich fluids from below. Quantifying changes in volatile and heat release from magma can be simpler in lakes than for volcanoes with radial drainages and no major lakes. Moreover, volcanic lakes pose a range of hazards themselves, including phreatomagmatic eruptions, debris flows, flank collapse, tsunamis, and toxic gas release (Mastin and Witter, 2000; Delmelle and others, 2015; Manville, 2015; Rouwet and others, 2015)—hazards that have historically been responsible for substantial loss of life at many volcanoes worldwide (Manville, 2015). Catastrophic CO 2 release at Lake Nyos, Cameroon, in 1986 suffocated about 1,750 people and about 3,500 livestock and was probably triggered by a large landslide into the gas-saturated lake (Kling and others, 1987; Evans and others, 1993). Gas-charged springs in Soda Bay within Clear Lake (California) have caused almost a dozen deaths to bathers in the past hundred years (ABC News, 2000). A 2005 example of lake overturn and abundant gas release was documented at Mount Chiginagak in Alaska (Schaefer and others, 2008) but did not result in any human casualties. Although thermally stratified lakes, which promote trapping of exsolved magmatic gas, tend to develop in tropical regions, the phenomenon can also arise where salinity creates meromixis (a condition in which a lake does not mix completely), as occurs in Mono Lake, California (Jellison and Melack, 1993; Jellison and others, 1998). If magma erupts or flows into a lake, the interaction between hot magma and cold water can be explosive (Mastin and others, 2004; Zimanowski and others, 2015) and substantially expand the area affected by the eruption. Another hazard is the breaching of crater rims by landslides triggered by volcanic and (or) seismic activity. Under some circumstances, substantial volumes of water can be displaced, leading to large floods and lahars. Late Holocene lake flooding from Aniakchak Crater in the Alaska Peninsula (Waythomas, 2022) and from Paulina Lake in Newberry Crater, Oregon (Chitwood and Jensen, 2000), caused by the failure of outlet sills, testify to the substantial hazards at lake-filled calderas. Several volcanic systems in the United States host lakes known to receive heat and gas from underlying magma. These lakes vary widely in area, depth, and chemical composition. Lakes are present at level 4 volcanoes, including Crater Lake and Newberry Volcano in Oregon; Yellowstone Caldera in Wyoming; Long Valley Caldera, Clear Lake volcanic field, Medicine Lake, and Salton Buttes in California; and Aniakchak Crater, Mount Katmai, Fisher Caldera, Mount Okmok, and Kaguyak Crater, among others, in Alaska. A water lake was present in Halemaʻumaʻu, the crater of Kīlauea, Hawai‘i (fig. F1), from October 2019 to December 2020. Level 3 volcanoes with lakes include Mono Lake volcanic field (Calif.), Mount Bachelor (Ore.), Ukinrek Maars and Mount Chiginagak (Alaska), and Soda Lake (Nevada). In addition, there are lakes at many levels 1 and 2 volcanoes. In the United States, there are no strongly acidic lakes that receive abundant input of magmatic gas, such as those found at Mount Ruapehu (New Zealand), Ijen and Kelud (Indonesia), and Poás (Costa Rica). Nevertheless, many contain fluids that provide clues to magmatic processes below. Since publication of a previous report on recommended instrumentation for volcano monitoring (Moran and others, 2008), continuous hydrologic monitoring has become increasingly feasible. However, changes in water pressure, temperature, and chemistry remain, in general, poorly studied phenomena at volcanoes (Sparks, 2003; National Academies of Sciences, Engineering, and Medicine, 2017). Recent efforts by the USGS have included the temporary study of Cascade Range volcanoes, which included frequent (15 minute to hourly) temporal sampling of temperature, depth, and conductivity (Crankshaw and others, 2018; Ingebritsen and Evans, 2019). At Yellowstone Caldera, many streamgages have now added thermistors and specific conductance sensors, allowing estimation of time-dependent chloride flux as a proxy for variations in subsurface heat flux (McCleskey and others, 2012, 2016). Efforts to better understand lakes have also accelerated, with bathymetric mapping and sampling carried out at several locations in the United States. Especially thorough work was done at Yellowstone Lake thanks to the Hydrothermal Dynamics of Yellowstone Lake (HD-YLAKE, https://hdylake.org ) project, funded primarily by the National Science Foundation. In addition to geophysical surveys and recovery of cores and other samples, HD-YLAKE investigations included remotely operated vehicle (ROV) investigations of hydrothermal vents on the lake floor (fig. F2). Data collected by the ROV provided a better understanding of the thermal and chemical influx from lake-bottom hydrothermal systems (Sohn and others, 2017). In this chapter, we focus on detecting changes in the chemistry, temperature, discharge, or water levels of streams, springs, and lakes that can be caused by seismicity, volumetric strains, or increases in gas flux associated with ascending magma. There is unavoidable overlap with other chapters of this report. Samples of water and gas can also be obtained in boreholes ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume; Hurwitz and Lowenstern, 2024), both shallow and deep. Gas monitoring ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–E, 11 p., https://doi.org/10.3133/sir20245062e.">chapter E , this volume; Lewicki and others, 2024) relies in part on samples from springs and wells, particularly where measurable gas plumes are absent. Water acts as a trigger and lubricant for landslides and sediment-rich floods, and so hydrology has obvious relevance for lahar monitoring, as discussed in of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–H, 6 p., https://doi.org/10.3133/sir20245062h. ">chapter H (this volume; Thelen and others, 2024). Shared situational awareness among scientists engaged in geophysical, gas, and hydrologic monitoring will improve overall understanding of the volcanic hazard.

Scientific Investigations Report

An experimental ground-magnetic and VLF-EM traverse over a buried paleochannel near Salisbury, Maryland

Since, 1963, the Maryland Geological Survey and the U.S. Geological Survey have been engaged in a study of the Pleistocene Series beneath a 230 square kilometer area around Salisbury, Maryland. (Hansen, 1966; Weigle, 1972; Zohdy and others, 1974, p.56) North of Salisbury a deep Pleistocene paleochannel was discovered; this channel was carved into an erosional plain at the top of the Miocene deposit, was filled and blanketed subsequently with deposits (mostly sand and gravel) of Pleistocene age. The channel is a prolific source of ground water, and has been outlined for a least 15 kilometers by means of power-augering and gamma-logging. A geophysical survey using ground magnetics and VLF-EM was made over the channel in an attempt to see if a more efficient method than augering could be developed to map the paleochannel at depth; the survey traverse was made over one of the better defined parts of the paleochannel (see figure 1.) where airborne magnetics and VLF studies could easily be done as a potential follow-up. We hoped to be able to map resistivity changes between aquifer and aquiclude facies with the VLF-EM, and perhaps identify other facies changes in black-sand concentrations with ground magnetics. The data is presented in Table 1 and plotted in figure 2. The traverse extended from north to south, with station spacing of 100 meters, for an over all length of 4.5 kilometers.

Maryland

Ground magnetic and VLF studies at Midnite uranium mine, Stevens County, Washington

Ground magnetic and E-mode VLF measurements were made at more than 200 stations at the Midnite uranium Mine, Stevens County, Washington. The equipment was found to be light and foolproof, and each set of data was collected in one day, exclusive of surveying and marking the station points. The maps of contoured magnetic and VLF data resembled geologic maps of the area, showing many common features, as well as a few unique features on each map. Each showed some evidence of a small normal fault cutting the region; taken together, the evidence for this fault was judged to be much stronger, so that further structural details were inferred. Because of soil cover and inadequate outcrops, the presence of this fault had hitherto been unsuspected. A target area for further uranium mineralization north of the fault was indicated by this quick, inexpensive geophysical survey. The drilling program which Midnite Mine management had underway at that time had already outlined a mineralized zone in the indicated area.

Washington

Cruise report for A1-02-SC southern California CABRILLO project, Earthquake Hazards Task

A two-week marine geophysical survey obtained sidescan-sonar images and multiple sets of high-resolution seismic-reflection profiles in the southern California offshore area between Point Arguello and Point Dume. The data were obtained to support two project activities of the United States Geological Survey (USGS) Coastal and Marine Geology (CMG) Program: (1) the evaluation of the geologic hazards posed by earthquake faults and landslides in the offshore areas of Santa Barbara Channel and western Santa Monica Basin and (2) determine the location of active hydrocarbon seeps in the vicinity of Point Conception as part of a collaborative study with the Minerals Management Service (MMS). The 2002 cruise, A1-02- SC, is the fourth major data-collection effort in support of the first objective (Normark et al., 1999a, b; Gutmacher et al., 2000). A cruise to obtain sediment cores to constrain the timing of deformation interpreted from the geophysical records is planned for the summer of 2003.

California

Bedrock, Borehole, and Water-Quality Characterization of a Methane-Producing Water Well in Wolfeboro, New Hampshire

In August 2004, a commercial drill rig was destroyed by ignition of an explosive gas released during the drilling of a domestic well in granitic bedrock in Tyngsborough, MA. This accident prompted the Massachusetts Department of Environmental Protection (MassDEP) to sample the well water for dissolved methane - a possible explosive fuel. Water samples collected from the Tyngsborough domestic well in 2004 by the MassDEP contained low levels of methane gas (Pierce and others, 2007). When the U.S. Geological Survey (USGS) sampled this well in 2006, there was no measurable amount of methane remaining in the well water (Pierce and others, 2007). Other deep water wells in nearby south-central New Hampshire have been determined to have high concentrations of naturally occurring methane (David Wunsch, New Hampshire State Geologist, 2004, written commun.). Studying additional wells in New England crystalline bedrock aquifers that produce methane may help to understand the origin of methane in crystalline bedrock. Domestic well NH-WRW-37 was chosen for this study because it is a relatively deep well completed in crystalline bedrock, it is not affected by known anthropogenic sources of methane, and it had the highest known natural methane concentration (15.5 mg/L, U.S. Geological Survey, 2007) measured in a study described by Robinson and others (2004). This well has been in use since it was drilled in 1997, and it was originally selected for study in 2000 as part of a 30 well network, major-aquifer study by the USGS' New England Coastal Basins (NECB) study unit of the National Water-Quality Assessment (NAWQA) Program. Dissolved methane in drinking water is not considered an ingestion health hazard, although the occurrence in ground water is a concern because, as a gas, its buildup in confined spaces can cause asphyxiation, fire, or explosion hazards (Mathes and White, 2006). Methane occurrence in the fractured crystalline bedrock is not widely reported or well understood. Borehole-geophysical surveys, bedrock outcrop observations, and water-quality analyses were used to define the geologic and hydrologic characteristics of NH-WRW-37. Collection of additional information on the hydraulic and geologic characteristics of the fractured bedrock and on water quality was initiated in an attempt to understand the setting where methane gas occurs in the bedrock ground water. The origin of dissolved methane in this and other wells in New Hampshire is the subject of ongoing investigations by the State of New Hampshire, the New Hampshire Geological Survey and the USGS.

Open-File Report