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Hydrologic modifications challenge bottomland hardwood forest management

Bottomland hardwoods are floodplain forests along rivers and streams throughout the southeastern United States. The interrelations among hydrology, soils, geomorphic landforms, and tree species composition are the foundation of forest management in bottomland hardwoods, and historically their correspondence has allowed for somewhat predictable forest responses based upon the hydrogeomorphic setting. However, extensive hydrologic and geomorphic modifications in floodplains have disrupted these interrelations and, on many sites, have created novel disturbance regimes resulting in unpredictable forest responses. Reduced or altered timing of surface flooding and groundwater declines are common in the region and have favored increases in stem densities, particularly of species less tolerant of flooding and more tolerant of shade. In these highly modified systems, more process-level understanding of floodplain hydrology, soil moisture dynamics, interspecific tree competition, and regeneration is needed to develop more effective management prescriptions and for forestry to be represented in integrated water-resource management decisions.

Journal of Forestry

Description of the physical environment and coal-mining history of west-central Indiana, with emphasis on six small watersheds

Information on the geology, geomorphology, soils, climate, hydrology, water use, land use, population, and coal mining history of Clay, Owen, Sullivan, and Vigo Counties in Indiana is summarized. Site-specific information is given on the morphology , geology, soils, land use, coal mining history, and hydrologic instrumentation of the six watersheds which are each less than 3 sq mi in area. The Wabash, White, and Eel Rivers are the major drainages in west-central Indiana. Average annual precipitation is about 39.5 in/yr and average annual runoff is about 13 in/yr. The most productive aquifers are confined or unconfined outwash aquifers located along the major rivers. Bedrock aquifers are regionally insignificant but are the sole source of groundwater for areas that lack outwash, alluvium, or sand and gravel lenses in till. Indiana has more than 17 billion short tons of recoverable coal reserves; about 11% can be mined by surface methods. Almost half of Indiana's surface reserves are in Clay, Owen, Sullivan, and Vigo Counties. More than 50,000 acres in west-central Indiana have been disturbed by surface coal mining from 1941 through 1980. Big Slough and Hooker Creek are streams that drain unmined, agricultural watersheds. Row-crop corn and soybeans are the principal crops. Soils are moderately well drained silt loams, and the watersheds well developed dendritic drainage systems. Unnamed tributaries drain mined and reclaimed watersheds. Ridges of mine spoil have been graded to a gently rolling topography. Soils are well drained and consist of 6 to 12 inches of silt-loam topsoil that was stockpiled and then replaced over shale and sandstone fragments of the graded mine spoil. Grasses and legumes form the vegetative cover in each watershed. Pond Creek and an unnamed tributary to Big Branch are streams that drain mined and unreclaimed watersheds. Soils are very well drained shaly silty loams that have formed on steeply sloping banks. Both watersheds contain numerous impoundments of water and have enclosed areas that do not contribute surface runoff to streamflow. The ridges of mine spoil are covered with pine trees, but much of the soil surface is devoid of vegetation. (Lantz-PTT)

Indiana

Documentation of input datasets for the soil-water balance groundwater recharge model of the Upper Colorado River Basin

The Colorado River and its tributaries supply water to more than 35 million people in the United States and 3 million people in Mexico, irrigating more than 4.5 million acres of farmland, and generating about 12 billion kilowatt hours of hydroelectric power annually. The Upper Colorado River Basin, encompassing more than 110,000 square miles (mi 2 ), contains the headwaters of the Colorado River (also known as the River) and is an important source of snowmelt runoff to the River. Groundwater discharge also is an important source of water in the River and its tributaries, with estimates ranging from 21 to 58 percent of streamflow in the upper basin. Planning for the sustainable management of the Colorado River in future climates requires an understanding of the Upper Colorado River Basin groundwater system. This report documents input datasets for a Soil-Water Balance groundwater recharge model that was developed for the Upper Colorado River Basin.

Arizona, Colorado, New Mexico, Utah, Wyoming

Denitrification across landscapes and waterscapes: A synthesis

Denitrification is a critical process regulating the removal of bioavailable nitrogen (N) from natural and human-altered systems. While it has been extensively studied in terrestrial, freshwater, and marine systems, there has been limited communication among denitrification scientists working in these individual systems. Here, we compare rates of denitrification and controlling factors across a range of ecosystem types. We suggest that terrestrial, freshwater, and marine systems in which denitrification occurs can be organized along a continuum ranging from (1) those in which nitrification and denitrification are tightly coupled in space and time to (2) those in which nitrate production and denitrification are relatively decoupled. In aquatic ecosystems, N inputs influence denitrification rates whereas hydrology and geomorphology influence the proportion of N inputs that are denitrified. Relationships between denitrification and water residence time and N load are remarkably similar across lakes, river reaches, estuaries, and continental shelves. Spatially distributed global models of denitrification suggest that continental shelf sediments account for the largest portion (44%) of total global denitrification, followed by terrestrial soils (22%) and oceanic oxygen minimum zones (OMZs; 14%). Freshwater systems (groundwater, lakes, rivers) account for about 20% and estuaries 1% of total global denitrification. Denitrification of land-based N sources is distributed somewhat differently. Within watersheds, the amount of land-based N denitrified is generally highest in terrestrial soils, with progressively smaller amounts denitrified in groundwater, rivers, lakes and reservoirs, and estuaries. A number of regional exceptions to this general trend of decreasing denitrification in a downstream direction exist, including significant denitrification in continental shelves of N from terrestrial sources. Though terrestrial soils and groundwater are responsible for much denitrification at the watershed scale, per-area denitrification rates in soils and groundwater (kg N·km −2 ·yr −1 ) are, on average, approximately one-tenth the per-area rates of denitrification in lakes, rivers, estuaries, continental shelves, or OMZs. A number of potential approaches to increase denitrification on the landscape, and thus decrease N export to sensitive coastal systems exist. However, these have not generally been widely tested for their effectiveness at scales required to significantly reduce N export at the whole watershed scale.

Ecological Applications

Airborne biogeophysical mapping of hidden mineral deposits

Airborne survey techniques have been developed to detect and map forest canopies affected by metal-induced stress. A high spectral resolution airborne spectroradiometer system, used over a known forest-covered copper soil anomaly, has revealed previously unknown spectral changes in the near-infrared chlorophyll absorption spectrum. The metal-induced spectral shifts have subsequently been reproduced in the laboratory at Columbia University. Waveform analysis techniques specifically designed for computer analysis of the high spectral resolution aircraft data filter out the very strong background noise introduced by variations in normal, unstressed vegetation canopy and by topographic effects. The wave-form method proves most effective in extracting the subtle spectral indicators of metal-induced stress. The analytic method is a unique frequency domain technique made possible by the high spectral resolution of the 500-channel spectroradiometer system. The biogeophysical technique is demonstrated by three mapping surveys of Cotter Basin, Montana, and Spirit Lake, Washington. This airborne mapping technique presents new application opportunities in large areas of the world where heavy forest cover has in the past made geologic and geophysical exploration tedious and expensive. The tree cover with widespreading and deeply penetrating root systems is turned to an advantage in the airborne biogeophysical technique by detecting metal-induced changes in the chlorophyll reflectance spectrum.

Montana

Changes in vegetation and biological soil crust communities on sand dunes stabilizing after a century of grazing on San Miguel Island, Channel Island National Park, California

San Miguel Island is the westernmost of the California Channel Islands and one of the windiest areas on the west coast of North America. The majority of the island is covered by coastal sand dunes, which were stripped of vegetation and subsequently mobilized due to droughts and sheep ranching during the late 19th century and early 20th century. Since the removal of grazing animals, vegetation and biological soil crusts have once again stabilized many of the island's dunes. In this study, historical aerial photographs and field surveys were used to develop a chronosequence of the pattern of change in vegetation communities and biological soil crust levels of development (LOD) along a gradient of dune stabilization. Historical aerial photographs from 1929, 1954, 1977, and 2009 were georeferenced and used to delineate changes in vegetation canopy cover and active (unvegetated) dune extent among 5 historical periods (pre-1929, 1929–1954, 1954–1977, 1977–2009, and 2009–2011). During fieldwork, vegetation and biological soil crust communities were mapped along transects distributed throughout San Miguel Island's central dune field on land forms that had stabilized during the 5 time periods of interest. Analyses in a geographic information system (GIS) quantified the pattern of changes that vegetation and biological soil crust communities have exhibited on the San Miguel Island dunes over the past 80 years. Results revealed that a continuing increase in total vegetation cover and a complex pattern of change in vegetation communities have taken place on the San Miguel Island dunes since the removal of grazing animals. The highly specialized native vascular vegetation (sea rocket, dunedelion, beach-bur, and locoweed) are the pioneer stabilizers of the dunes. This pioneer community is replaced in later stages by communities that are dominated by native shrubs (coastal goldenbush, silver lupine, coyote-brush, and giant coreopsis), with apparently overlapping or cyclical succession pathways. Many of the dunes that have been stabilized the longest (since before 1929) are dominated by exotic grasses. Stands of biological soil crusts (cyanobacteria) are found only on dunes where vascular vegetation is already present. Biological soil crusts are not found on dunes exhibiting a closed vascular plant canopy, which may indicate that the role of soil crusts in dune stabilization on the island is transitory. Particle-size analyses of soil samples from the study area reveal that higher biological soil crust LOD is positively correlated with increasing fine grain content. The findings indicate that changes in vegetation communities may be the most rapid at earlier and later stages of dune stabilization and that regular monitoring of dunes may help to identify the interactions between vegetation and soil crusts, as well as the potential transitions between native and exotic plant communities.

California

Tidal flushing of mercury from the Bremerton Naval Complex through the PSNS015 stormwater drain system to Sinclair Inlet, Kitsap County, Washington, 2011 -12

The sediments of Sinclair Inlet, in Puget Sound, Washington, have elevated levels of contaminants including mercury. The Bremerton Naval Complex is adjacent to Sinclair Inlet, and has known areas of historical soil mercury contamination. The U.S. Geological Survey, in cooperation with the U.S. Navy, has been investigating the potential for mercury sources on the Bremerton Naval Complex to recontaminate recently remediated marine sediment. In 2011–12, the U.S. Geological Survey conducted three tidal- related sampling campaigns to characterize mercury dynamics in the largest stormwater drain system on the Bremerton Naval Complex, which passes through the soils of an area known as Site 2 that has elevated soil mercury concentrations. The sampling campaigns confirmed that the stormwater drain system, PSNS015, serves as a conduit for seawater transport more than 250 m landward of the contaminated soils that subsequently facilitates mercury transport to Sinclair Inlet. During the December 2011 reconnaissance sampling campaign, no freshwater source of mercury to PSNS015 was identified. There was heavy precipitation preceding and stormwater runoff generated during the reconnaissance survey, which suggests that the primary source of mercury in PSNS015 is not precipitation-induced. During the May 2012 spring-tide sampling campaign, the water in PSNS015 drained to Sinclair Inlet during a negative low tide, and the highest filtered total mercury concentration in the stormwater drain system (60 ng/L) was measured during the lower-low tide in the freshwater flowing into the seaward-most stormwater drain vault from either up-pipe or local groundwater intrusion. Similar conditions were not observed during the June 2012 companion neap-tide sampling campaign, when the water-level elevation of the positive low tide in Sinclair Inlet dropped only slightly below the stormwater drain vault elevation, the water in the seaward-most stormwater vault was brackish rather than fresh, and the filtered total mercury concentration never exceeded 24 ng/L. Particulate total mercury concentrations and dynamics during the spring- and neap-tide sampling campaigns were variable, with higher concentrations (as much as 133 ng/L) measured throughout the neap-tide study compared to those measured during the spring-tide study (as much as 4.34 ng/L). The highest filtered total mercury concentration of all sampling campaigns (1,140 ng/L) was measured during ebb tide in a nearshore monitoring well that represents groundwater discharging from the contaminated soils directly to Sinclair Inlet along an unwalled part of the shoreline. The results suggest that mercury extracted from Site 2 soils can be carried to Sinclair Inlet during ebb tides by at least two mechanisms: (1) through groundwater directly to Sinclair Inlet along an unwalled part of the shoreline or (2) through the stormwater drain system when the water level in Sinclair Inlet drops below the water level in the stormwater drain system. The data can be used to guide future modifications to the seawall and stormwater drain system that aim to hydraulically disconnect the stormwater drain system from the surrounding contaminated soils.

Washington

The implications of microbial and substrate limitation for the fates of carbon in different organic soil horizon types of boreal forest ecosystems: a mechanistically based model analysis

The large amount of soil carbon in boreal forest ecosystems has the potential to influence the climate system if released in large quantities in response to warming. Thus, there is a need to better understand and represent the environmental sensitivity of soil carbon decomposition. Most soil carbon decomposition models rely on empirical relationships omitting key biogeochemical mechanisms and their response to climate change is highly uncertain. In this study, we developed a multi-layer microbial explicit soil decomposition model framework for boreal forest ecosystems. A thorough sensitivity analysis was conducted to identify dominating biogeochemical processes and to highlight structural limitations. Our results indicate that substrate availability (limited by soil water diffusion and substrate quality) is likely to be a major constraint on soil decomposition in the fibrous horizon (40–60% of soil organic carbon (SOC) pool size variation), while energy limited microbial activity in the amorphous horizon exerts a predominant control on soil decomposition (>70% of SOC pool size variation). Elevated temperature alleviated the energy constraint of microbial activity most notably in amorphous soils, whereas moisture only exhibited a marginal effect on dissolved substrate supply and microbial activity. Our study highlights the different decomposition properties and underlying mechanisms of soil dynamics between fibrous and amorphous soil horizons. Soil decomposition models should consider explicitly representing different boreal soil horizons and soil–microbial interactions to better characterize biogeochemical processes in boreal forest ecosystems. A more comprehensive representation of critical biogeochemical mechanisms of soil moisture effects may be required to improve the performance of the soil model we analyzed in this study.

Biogeosciences

Agronomic and environmental implications of enhanced s-triazine degradation

Novel catabolic pathways enabling rapid detoxification of s -triazine herbicides have been elucidated and detected at a growing number of locations. The genes responsible for s -triazine mineralization, i.e. atzABCDEF and trzNDF , occur in at least four bacterial phyla and are implicated in the development of enhanced degradation in agricultural soils from all continents except Antarctica. Enhanced degradation occurs in at least nine crops and six crop rotation systems that rely on s -triazine herbicides for weed control, and, with the exception of acidic soil conditions and s -triazine application frequency, adaptation of the microbial population is independent of soil physiochemical properties and cultural management practices. From an agronomic perspective, residual weed control could be reduced tenfold in s -triazine-adapted relative to non-adapted soils. From an environmental standpoint, the off-site loss of total s -triazine residues could be overestimated 13-fold in adapted soils if altered persistence estimates and metabolic pathways are not reflected in fate and transport models. Empirical models requiring soil pH and s -triazine use history as input parameters predict atrazine persistence more accurately than historical estimates, thereby allowing practitioners to adjust weed control strategies and model input values when warranted.

Pest Management Science

Decomposition of soil organic matter from boreal black spruce forest: Environmental and chemical controls

Black spruce forests are a dominant covertype in the boreal forest region, and they inhabit landscapes that span a wide range of hydrologic and thermal conditions. These forests often have large stores of soil organic carbon. Recent increases in temperature at northern latitudes may be stimulating decomposition rates of this soil carbon. It is unclear, however, how changes in environmental conditions influence decomposition in these systems, and if substrate controls of decomposition vary with hydrologic and thermal regime. We addressed these issues by investigating the effects of temperature, moisture, and organic matter chemical characteristics on decomposition of fibric soil horizons from three black spruce forest sites. The sites varied in drainage and permafrost, and included a “Well Drained” site where permafrost was absent, and “Moderately well Drained” and “Poorly Drained” sites where permafrost was present at about 0.5 m depth. Samples collected from each site were incubated at five different moisture contents (2, 25, 50, 75, and 100% saturation) and two different temperatures (10°C and 20°C) in a full factorial design for two months. Organic matter chemistry was analyzed using pyrolysis gas chromatography-mass spectrometry prior to incubation, and after incubation on soils held at 20°C, 50% saturation. Mean cumulative mineralization, normalized to initial carbon content, ranged from 0.2% to 4.7%, and was dependent on temperature, moisture, and site. The effect of temperature on mineralization was significantly influenced by moisture content, as mineralization was greatest at 20°C and 50–75% saturation. While the relative effects of temperature and moisture were similar for all soils, mineralization rates were significantly greater for samples from the “Well Drained” site compared to the other sites. Variations in the relative abundances of polysaccharide-derivatives and compounds of undetermined source (such as toluene, phenol, 4-methyl phenol, and several unidentifiable compounds) could account for approximately 44% of the variation in mineralization across all sites under ideal temperature and moisture conditions. Based on our results, changes in temperature and moisture likely have similar, additive effects on in situ soil organic matter (SOM) decomposition across a wide range of black spruce forest systems, while variations in SOM chemistry can lead to significant differences in decomposition rates within and among forest sites.

Biogeochemistry

Using logistic regression to predict a probability of debris flows in areas burned by wildfires, southern California, 2003-2006

Logistic regression was used to develop statistical models that can be used to predict the probability of debris flows in areas recently burned by wildfires by using data from 14 wildfires that burned in southern California during 2003-2006. Twenty-eight independent variables describing the basin morphology, burn severity, rainfall, and soil properties of 306 drainage basins located within those burned areas were evaluated. The models were developed as follows: (1) Basins that did and did not produce debris flows soon after the 2003 to 2006 fires were delineated from data in the National Elevation Dataset using a geographic information system; (2) Data describing the basin morphology, burn severity, rainfall, and soil properties were compiled for each basin. These data were then input to a statistics software package for analysis using logistic regression; and (3) Relations between the occurrence or absence of debris flows and the basin morphology, burn severity, rainfall, and soil properties were evaluated, and five multivariate logistic regression models were constructed. All possible combinations of independent variables were evaluated to determine which combinations produced the most effective models, and the multivariate models that best predicted the occurrence of debris flows were identified. Percentage of high burn severity and 3-hour peak rainfall intensity were significant variables in all models. Soil organic matter content and soil clay content were significant variables in all models except Model 5. Soil slope was a significant variable in all models except Model 4. The most suitable model can be selected from these five models on the basis of the availability of independent variables in the particular area of interest and field checking of probability maps. The multivariate logistic regression models can be entered into a geographic information system, and maps showing the probability of debris flows can be constructed in recently burned areas of southern California. This study demonstrates that logistic regression is a valuable tool for developing models that predict the probability of debris flows occurring in recently burned landscapes.

California

Mercury in waters, soils, and sediments of the New Jersey Coastal Plain: A comparison of regional distribution and mobility with the mercury contamination at the William J. Hughes Technical Center, Atlantic County, New Jersey

Mercury in soils, surface water, and groundwater at the William J. Hughes Technical Center , Atlantic County, New Jersey, has been found at levels that exceed established background concentrations in Coastal Plain waters, and, in some cases, New Jersey State standards for mercury in various media. As of 2012, it is not known whether this mercury is part of regional mercury contamination or whether it is related to former military activities. Regionally, groundwater supplying about 700 domestic wells in the New Jersey Coastal Plain is contaminated with mercury that appears to be derived from anthropogenic inputs, such as agricultural pesticide use and atmospheric deposition. High levels of mercury occasionally are found in Coastal Plain soils, but disturbance during residential development on former agricultural land is thought to have mobilized any mercury applied during farming, a hypothesis borne out by experiments leaching mercury from soils. In the unsewered residential areas with mercury-contaminated groundwater, septic-system effluent is believed to create reducing conditions in which mercury sorbed to subsoils is mobilized to groundwater. In comparing the levels of mercury found in soils, sediments, streamwater, and groundwater at the William J. Hughes Technical Center site with those found regionally, mercury concentrations in groundwater in the region are, in some cases, substantially higher than those found in groundwater at the William J. Hughes Technical Center site. Nevertheless, concentrations of mercury in streamwater at the site are, in some instances, higher than most found regionally. The mercury contents in soils and sediment at the William J. Hughes Technical Center site are substantially higher than those found to date (2012) in the region, indicating that a source other than regional sources may be present at the site.

New Jersey

Groundwater/surface-water interactions in the Bad River Watershed, Wisconsin

A groundwater-flow model was developed for the Bad River Watershed and surrounding area by using the U.S. Geological Survey (USGS) finite-difference code MODFLOW-NWT. The model simulates steady-state groundwater-flow and base flow in streams by using the streamflow routing (SFR) package. The objectives of this study were to: (1) develop an improved understanding of the groundwater-flow system in the Bad River Watershed at the regional scale, including the sources of water to the Bad River Band of Lake Superior Chippewa Reservation (Reservation) and groundwater/surface-water interactions; (2) provide a quantitative platform for evaluating future impacts to the watershed, which can be used as a starting point for more detailed investigations at the local scale; and (3) identify areas where more data are needed. This report describes the construction and calibration of the groundwater-flow model that was subsequently used for analyzing potential locations for the collection of additional field data, including new observations of water-table elevation for refining the conceptualization and corresponding numerical model of the hydrogeologic system. The study area can be conceptually divided into three primary hydrogeologic environments. The first encompasses the southern uplands with relatively low topographic relief, where groundwater-flow is unconfined and occurs primarily in sandy till and glacial outwash overlying Archean-aged crystalline bedrock. The second includes a transitional area of higher topographic relief and shallow depth to bedrock, in the vicinity of ridges formed by steeply dipping, early-Proterozoic aged metasedimentary units of the Marquette Range Supergroup (including the Ironwood Formation), and late-Proterozoic igneous units associated with the Midcontinent Rift System (MRS). Groundwater-flow in this area likely occurs primarily through connected networks of bedrock fractures that are not well characterized, and also in isolated pockets of Quaternary deposits. The third and last hydrogeologic environment includes lowlands along Lake Superior where a deep sandstone aquifer is confined by thick deposits of clay-rich till. Model input was compiled by using both published and unpublished data. Constant flux boundary conditions for the model perimeter were developed from a regional analytic element model described in appendix 1 of this report. Pumping from 26 high-capacity wells within the model area was included. The SFR stream network was developed from the National Hydrography Dataset (NHDPlus Version 2) and hydrography from the Wisconsin Department of Natural Resources (WDNR). Hydraulic conductivity values were determined for each model cell by interpolation from a network of pilot points, within zones representing major hydrogeologic units. Recharge to the groundwater system was estimated on a cell-by-cell basis by using the Soil Water Balance code (SWB), with gridded daily temperature and precipitation data for the period 1980–2011, and GIS coverages of soil and land-surface conditions. Estimated recharge varies considerably, following spatial patterns in the precipitation and soil hydrologic group inputs. The lowest recharge values occur in the Superior lowlands, whereas the highest values occur in the upland areas, especially those underlain by sandy soils, and in the vicinity of bedrock hills. The model was calibrated to groundwater-levels and base flows obtained from the USGS National Water Information System (NWIS) database, and groundwater-levels obtained from the WDNR and Band River Band well-construction databases. Calibration was performed via nonlinear regression by using the parameter-estimation software suite PEST. Groundwater levels and base-flow observations in the calibration dataset were well simulated by the calibrated model, with reasonable values of hydraulic conductivity. The pilot-point parameters that were most constrained by observations during model calibration coincided with the locations containing the most wells (head observations)—especially the population centers of Ashland, Mellen, and other communities along the major highway corridors. Results from the calibrated model illustrate differences in the nature of groundwater-flow within the watershed. In the southern part of the watershed, where bedrock is shallow, groundwater flow paths are relatively short, extending from local recharge areas to adjacent first and second-order streams. In contrast, laterally continuous deposits of clay-rich till covering the Superior Lowlands isolate most smaller streams from the sandstone aquifer, allowing for longer flow paths toward larger streams such as the Bad, Marengo, and White Rivers. Approximately three-quarters of all first-order stream cells were dry in the Superior Lowlands, compared to only half of first-order stream cells in the southern bedrock uplands. The model was used to delineate the groundwatershed for the Bad and Kakagon Rivers. “Groundwatershed” is defined as the area contributing groundwater discharge to one of these streams and their tributaries. The groundwatershed was found to align closely with the surface-watershed, with the most notable exception occurring along the southwestern half of Birch Hill, where surface water drains southwest towards the Potato River, and groundwater flows north and east towards Lake Superior. Similarly, the contributing area of groundwater-flow to the Reservation was delineated. Results indicate the off-Reservation groundwater contributing area to be limited in comparison to the extent of the watershed, extending southward into the highlands underlain by MRS igneous rock units, but not further into the area underlain by the Marquette Range Supergroup. Stable isotope samples were collected from 54 wells within the watershed, to investigate sources of groundwater. Oxygen-18 (δ 18 O) values lower than -13.0 per mil were documented in the sampling, and likely indicate the presence of recharge water from the last glacial period (>9,500 years old) beneath the northern portion of the Reservation, in the vicinity of Odanah, Wisconsin. Finally, a new data-worth analysis of potential new monitoring-well locations was performed by using the model. The relative worth of new measurements was evaluated based on their ability to increase confidence in model predictions of groundwater levels and base flows at 35 locations, under the condition of a proposed open-pit iron mine. Results of the new data-worth analysis, and other inputs and outputs from the Bad River model, are available through an online dynamic web mapping service at ( http://wim.usgs.gov/badriver/ ).

Wisconsin

Development of vegetation based soil quality indices for mineralized terrane in arid and semi-arid regions

Soil quality indices (SQIs) are often management driven and attempt to describe key relationships between above- and below-ground parameters. In terrestrial systems, indices that were initially developed and modified for agroecosystems have been applied to non-agricultural systems in increasing number. We develop an SQI in arid and semi-arid ecosystems of the Western US impacted by different types of geologic mineralization using the relationship between vegetation community parameters and soil abiotic and biotic properties. We analyze these relations in soils associated with three different mineralization types: podiform chromite, Cu/Mo porphyry, and acid-sulfate gold vein systems at four different sites in California and Nevada. Soil samples were collected from undisturbed soils in both mineralized and nearby unmineralized substrates as well as from waste rock and tailings. Aboveground net primary productivity (ANPP), canopy cover and shrub density were measured for the vegetative communities. Minimum data sets were developed based on correlations between the soil and vegetation parameters, refined using principal components analysis, scored using non-linear functions, and combined into an overall SQI. The indices are comprised of one or two microbial parameters and three to six abiotic parameters, the latter consisting of nutrients and metals. Given the preliminary development of this approach, the parameters and combinations to arrive at an SQI for a given site cannot at this time be correlated or compared with that of another site. This SQI approach provides a means of quantifying disturbed ecosystem recovery resulting from mining, and could be applied to other disturbances in a way that readily distills the information for potential use by land managers. However, severely disturbed areas with little to no aboveground biomass, such as unreclaimed tailings, have likely crossed an ecological threshold that precludes the use of this type of monitoring tool.

California

Relationships between 222Rn dissolved in ground water supplies and indoor 222Rn concentrations in some Colorado front range houses

Indoor 222Rn concentrations were measured in 37 houses with alpha track detectors placed in water-use rooms near water sources (bathrooms, laundry rooms, and kitchens) and in non-water-use living rooms, dining rooms, and bedrooms away from water sources. Results show that relative contributions of 222Rn to indoor air from water use are insignificant when soil-gas concentrations are high but become increasingly important as the ratio of 222Rn-in-water:222Rn-in-soil gas increases. High soil-gas 222Rn concentrations may mask 222Rn contributions from water even when waterborne 222Rn concentrations are as high as 750 kBq m-3. Ground water in Precambrian Pikes Peak granite averages 340 kBq m-3222Rn, vs. 170 kBq m-3 in Precambrian migmatite, but average 222Rn concentrations in soil gas are also lower in migmatite. Because the ratio of 222Rn-in- water:222Rn-in-soil gas may be consistently higher for houses in migmatite than in Pikes Peak granite, indoor air in houses built on migmatite may have a greater relative contribution from water use even though average 222Rn concentrations in the water are lower. Continuous monitoring of 222Rn concentrations in air on 15-min intervals also indicates that additions to indoor concentrations from water use are significant and measurable only when soil-gas concentrations are low and concentrations in water are high. When soil-gas concentrations were mitigated to less than 150 Bq m-3 in one house, water contributes 20-40% of the annual indoor 222Rn concentration in the laundry room (222Rn concentration in water of 670 kBq m-3). Conversely, when the mitigation system is inactive, diurnal fluctuations and other variations in the soil-gas 222Rn contribution swamp the variability due to water use in the house. Measurable variations in indoor concentrations from water use were not detected in one house despite a low soil-gas contribution of approximately 150 Bq m-3 because waterborne 222Rn concentrations also are low (80 kBq m-3). This result suggests that 222Rn concentrations in water near the recommended EPA limit in drinking water of 11 kBq m-3 may not contribute measurable amounts of 222Rn to indoor air in most houses.

Health Physics

Elements in Mud and Snow in the Vicinity of the DeLong Mountain Regional Transportation System Road, Red Dog Mine, and Cape Krusenstern National Monument, Alaska, 2005-06

A small number of mud, road bed soil, and snow samples were collected in 2005 and 2006 to assess metal concentrations and loadings to areas adjacent to the DeLong Mountain Regional Transportation System (DMTS) road in northwest Alaska. The DMTS road is used by large trucks to transport lead and zinc concentrates from Red Dog Mine to the shipping facility at Red Dog Port; it traverses 32 kilometers of land in Cape Krusenstern National Monument (CAKR). Mud collected in the summer of 2005 from wheel-wells of two passenger vehicles used for transport between Red Dog Mine and the port facility were enriched in cadmium, lead, and zinc by factors of about 200 to 800 as compared with mud collected from a vehicle stationed in Kotzebue, Alaska, whereas DMTS road bed soil samples were enriched by factors of 6 to 12. Thus, as of 2005, dispersal of mine ore wastes or concentrates by vehicles appeared to remain a potential source of metals along the DMTS road. Compared to snow samples obtained near a gravel road located near Kotzebue, Alaska, metal loadings estimated from individual snow samples collected in CAKR in April 2006 near three creeks, 13 to 50 meters from the road, were greater by factors of 13 to 316 for cadmium, 28 to 589 for lead, and 8 to 195 for zinc. When averaged for all three creek locations, mean loadings of cadmium, lead, and zinc calculated from snow samples collected at a nominal distance of 15 meters to the north of the road were 0.63, 34, and 89 milligrams of metal per square meter, respectively. Variability of particulate and metal loadings between individual samples and the three creek locations probably was affected by localized meteorological conditions and micro-topography on the snow drift and scour patterns, but road orientation on attainable truck speeds also might have been a factor. Results indicated that the ?port effect?, previously attributed to fugitive metal-enriched dusts stemming from concentrate transfer operations at the port facility, was not necessarily an important factor affecting spatial differences of metals deposition in snow along the road in CAKR during winter 2005?06. The average metal content of particulates in 2005?06 snow samples was slightly less than that of snow samples collected by the U.S. Geological Survey in CAKR at three near-road locations in April 2003. Mean metals concentrations in 2006 snow particulates were about three times greater than in the road bed soils that were sampled in 2005; however, the fraction of annual metals loadings occurring in winter as compared to the remainder of the year was not readily determined by these data. Although procedures have been implemented in recent years to reduce the quantities of metal-enriched fugitive dusts, particulates dispersed near the road during the winter of 2005?06 were enriched in metals and these particulates contributed considerable metal loadings to the nearby terrain.

Scientific Investigations Report

Are soils of Iowa USA currently a carbon sink or source? Simulated changes in SOC stock from 1972 to 2007

Upscaling the spatial and temporal changes in carbon (C) stocks and fluxes from sites to regions is a critical and challenging step toward improving our understanding of the dynamics of C sources and sinks over large areas. This study simulated soil organic C (SOC) dynamics within 0–100 cm depth of soils across the state of Iowa in the USA from 1972 to 2007 using the General Ensemble biogeochemical Modeling System (GEMS). The model outputs with variation coefficient were analyzed and assembled from simulation unit to the state scale based upon major land use types at annual step. Results from this study indicate that soils (within a depth of 0–100 cm) in Iowa had been a SOC source at a rate of 190 ± 380 kg C ha −1 yr −1 . This was likely caused by the installation of a massive drainage system which led to the release of SOC from deep soil layers previously protected under poor drainage conditions. The annual crop rotation was another major force driving SOC variation and resulted in spatial variability of annual budgets in all croplands. Annual rate of change of SOC stocks in all land types depended significantly on the baseline SOC levels; soils with higher SOC levels tended to be C sources, and those with lower levels tended to be C sinks. Management practices (e.g., conservation tillage and residue management practices) slowed down the C emissions from Iowa soils, but could not reverse the general trend of net SOC loss in view of the entire state due mainly to a high level of baseline SOC stocks.

Agriculture, Ecosystems and Environment

Preliminary geohydrologic assessment of Buenos Aires National Wildlife Refuge, Altar Valley, southeastern Arizona

The Buenos Aires National Wildlife Refuge is located in the southern part of Altar Valley, southwest of Tucson in southeastern Arizona. The primary water-supply well at the Buenos Aires National Wildlife Refuge has experienced a two-decade decrease in groundwater levels in the well, as have other wells in the southern part of Altar Valley. In part to understand this trend, a study was undertaken by the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, to summarize what is known about the geohydrologic system on the refuge and analyze groundwater-level trends and precipitation-groundwater correlations. In addition, available data were compiled where possible on the climate, land cover, soils, geology, and hydrology to provide a foundation for future modeling of the system. Altar Valley is a sedimentary basin bounded by a mixture of Paleozoic to Tertiary sedimentary, volcanic, granitic, and metamorphic rocks. The valley fill is undifferentiated Tertiary to Quaternary sediments underlain by middle Miocene to Pliocene rocks that consist of moderately to strongly consolidated conglomerate and sandstone. Surface water, when present in the predominantly ephemeral streams of the valley, flows from south to north. Arivaca Creek has a cienega (or wetland) where groundwater surfaces before it flows as a short perennial reach out of Arivaca Basin. Groundwater maps compiled between 1934 and 2016 showed groundwater flowing from south to north. Before the 1980s, temporal patterns of groundwater levels in wells in Altar Valley varied substantially from one well to another. In the mid-1980s, comparatively high levels of precipitation occurred: the 1980s median value was 15.3 inches, whereas the median for the period of record was 13.2 inches. In addition, apparently corresponding groundwater level increases were seen in nearly all wells studied. After this initial increase, two different groundwater-level trends began to be observed in two spatially distinct sets of wells: in the northern part, groundwater levels were relatively steady, whereas in the southern part, groundwater levels declined from 10 to 20 feet between 1990 and 2019. Annual groundwater pumpage declined substantially in the northern part of the valley beginning in the early 1980s, but it began to increase again in the 1990s. Pumpage in the southern part has remained low and relatively steady compared to the northern part. Although the precise reasons for the declining groundwater levels in the southern part remain unclear, groundwater levels may be affected by factors such as climate cycles, long-term drought, and temperature-induced declines in recharge, resulting in increased evapotranspiration. Preliminary analyses of two wells, one selected from each part of the valley, using linear regression and lag correlation to investigate correlation between annual precipitation and groundwater levels, showed a maximum correlation at a lag of about 17 years in the southern part of the valley and about 25 years in the northern part, indicating that, although variable sources and traveltimes of recharged water may be needed to propagate to each location, the strongest correlation at each well is with precipitation that was recharged 17 and 25 years prior to the groundwater response in that well. Assuming a constant flow of groundwater from the southern to the northern part of the valley, a decrease in recharge is expected to lead to a decrease in aquifer storage. As to the comparatively stable groundwater levels in the northern part, pumpage is still only about one-half what it was in the early 1980s, even though pumpage has increased there since the 1990s. Water levels in most wells in the northern part were drawn down prior to the decrease in pumping in the early 1980s, possibly owing to a combination of pumping and the nearly 20-year midcentury drought that occurred between 1940 and 1960. Water levels were in the process of recovering when the increase in pumping occurred in the 1990s. Because the water levels were recovering (increasing) instead of remaining static, the increased pumping may have only limited the recovery rather than causing a decrease in water levels, as a new quasi-equilibrium state may have been reached. Additional possible causes for the stable groundwater levels include (1) upgradient aquifer transmissivity that was high enough to offset pumping, (2) a low-permeability barrier, such as bedrock or clay, at the north end of the valley that caused groundwater pooling, (3) higher lateral inflow of groundwater in the northern part of the valley, (4) a delay in the effect of storage declines propagating from the south, or (5) some combination thereof.

Arizona