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At least 325 records · Page 18Linked to original sources

Monitoring of livestock grazing effects on Bureau of Land Management land

Public land management agencies, such as the Bureau of Land Management (BLM), are charged with managing rangelands throughout the western United States for multiple uses, such as livestock grazing and conservation of sensitive species and their habitats. Monitoring of condition and trends of these rangelands, particularly with respect to effects of livestock grazing, provides critical information for effective management of these multiuse landscapes. We therefore investigated the availability of livestock grazing-related quantitative monitoring data and qualitative region-specific Land Health Standards (LHS) data across BLM grazing allotments in the western United States. We then queried university and federal rangeland science experts about how best to prioritize rangeland monitoring activities. We found that the most commonly available monitoring data were permittee-reported livestock numbers and season-of-use data (71% of allotments) followed by repeat photo points (58%), estimates of forage utilization (52%), and, finally, quantitative vegetation measurements (37%). Of the 57% of allotments in which LHS had been evaluated as of 2007, the BLM indicated 15% had failed to meet LHS due to livestock grazing. A full complement of all types of monitoring data, however, existed for only 27% of those 15%. Our data inspections, as well as conversations with rangeland experts, indicated a need for greater emphasis on collection of grazing-related monitoring data, particularly ground cover. Prioritization of where monitoring activities should be focused, along with creation of regional monitoring teams, may help improve monitoring. Overall, increased emphasis on monitoring of BLM rangelands will require commitment at multiple institutional levels.

Society for Range Management↗

Estimated water use, by county, in North Carolina, 1990

Data on water use in North Carolina were compiled for 1990 as part of a cooperative agreement between the U.S. Geological Survey and the Division of Water Resources of the North Carolina Department of Environment, Health, and Natural Resources. Data were compiled from a number of Federal, State, and private sources for the offstream water-use categories of public supply, domestic, commercial, industrial, mining, livestock, irrigation, and thermoelectric-power generation. Data also were collected for instream use from hydroelectric facilities. Total estimated offstream water use in the State for 1990 was about 8,940 million gallons per day. About 95 percent of the water withdrawn was from surface-water sources. Thermoelectric-power generation accounted for about 81 percent of all withdrawals. Data for instream water use for hydroelectric-power generation also were compiled. This instream water use totaled about 66,900 million gallons per day. eAch water-use category is summarized in this report by county and source of water supply.

North Carolina↗

Chapter A6. Section 6.7. Turbidity

Turbidity is one of the indicators used to assess the environmental health of water bodies. Turbidity is caused by the presence of suspended and dissolved matter, such as clay, silt, finely divided organic matter, plankton and other microscopic organisms, organic acids, and dyes. This section of the National Field Manual (NFM) describes the USGS protocols for determining turbidity in surface and ground waters, including extensive guidance for equipment selection and data reporting. It includes the revised approach to turbidity measurement and reporting that was implemented by the U.S. Geological Survey (USGS) in October 2004 to account for technological advances and consequent measurement complexities. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Research on pathogens at Great Lakes beaches: sampling, influential factors, and potential sources

The overall mission of this work is to provide science-based information and methods that will allow beach managers to more accurately make beach closure and advisory decisions, understand the sources and physical processes affecting beach contaminants, and understand how science-based information can be used to mitigate and restore beaches and protect the public. The U.S. Geological Survey (USGS), in collaboration with many Federal, State, and local agencies and universities, has conducted research on beach health issues in the Great Lakes Region for more than a decade. The work consists of four science elements that align with the USGS Beach Health Initiative Mission: real-time assessments of water quality; coastal processes; pathogens and source tracking; and data analysis, interpretation, and communication. The ongoing or completed research for the pathogens and source tracking topic is described in this fact sheet.

Great Lakes;Lake Erie;Lake Huron;Lake Michigan↗

Concentrations of lead and other inorganic constituents in samples of raw intake and treated drinking water from the municipal water filtration plant and residential tapwater in Chicago, Illinois, and East Chicago, Indiana, July–December 2017

The U.S. Geological Survey (USGS) Environmental Health Mission Area (EHMA) is providing comprehensive science on sources, movement, and transformation of contaminants and pathogens in watershed and aquifer drinking-water supplies and in built water and wastewater infrastructure (referred to as the USGS Water and Wastewater Infrastructure project) in the Greater Chicago Area and elsewhere in the United States, to fill data gaps identified by stakeholders and collaborators in drinking water and public health. EHMA Water and Wastewater Infrastructure research specifically provides insight into natural factors in the environment as well as those water-infrastructure components and processes (such as source-water corrosivity, treatment, plumbing, and so forth) that might influence human exposure to chemical and microbial contaminants at the residential tap. This infrastructure-exposure research role is fulfilled uniquely by the USGS and not by the U.S. Environmental Protection Agency (EPA), other agencies, or municipalities that focus on regulatory and policy activities and related compliance. The USGS approach to assessing the possible links between human health and chemical contaminant and pathogen exposure in drinking water is conducted in collaboration with public health experts and includes comprehensive characterization of the presence/absence and concentrations of more than 500 organic and 27 inorganic chemical constituents at the point of use (tap). Laboratory results for lead and other inorganic contaminants in Chicago, Illinois, and East Chicago, Indiana, residential tapwater are being released to ensure the timely release of quality-assured data to participants in the study. Concentrations of lead and other inorganic constituents were assessed in drinking water at the point of use (kitchen tap or filter) in 45 residential locations and in two locations within each of the two Chicago water purification plants and the two East Chicago water filtration plants during July–December 2017. Three methods were used for analyzing lead. The most sensitive method had a reporting limit of 0.020 micrograms per liter (µg/L). When using the most sensitive analytical method, lead was detected in 39 of 45 residential tapwater samples, with concentrations ranging from less than 0.020 µg/L to 5.31 µg/L (median of the detected values = 0.481 µg/L). Concentrations of lead also were detected in Lake Michigan intake water at all water purification/filtration plant facilities at concentrations ranging from 0.083 to 0.330 µg/L, but were not detected above the reporting limit in any samples of treated, pre-distribution drinking water at any of the water purification/filtration plant facilities. Because the USGS Water and Wastewater Infrastructure project in the Greater Chicago Area is focused on the potential human exposure to a broad suite of organic and inorganic contaminants in drinking water and is not focused specifically on lead, the sampling protocol did not include “first-draw,” stagnant sampling and samples were collected with point-of-use treatment in place, if present. Thus, the lead results reported herein are not appropriate for assessment of compliance with the EPA 1991 Lead and Copper Rule. Information resources for lead mitigation and water filtration are provided.

Illinois, Indiana↗

The quality of our Nation's waters: Water quality in the Northern Atlantic Coastal Plain surficial aquifer system, Delaware, Maryland, New Jersey, New York, North Carolina, and Virginia, 1988-2009

The surficial aquifer system of the Northern Atlantic Coastal Plain is made up of unconfined aquifers that underlie most of the area. This aquifer system is a critical renewable source of drinking water and is the source of most flow to streams and of recharge to underlying confined aquifers. Millions of people rely on the surficial aquifer system for public and domestic water supply, in particular in the densely populated areas of Long Island, New York, and in southern New Jersey, but also in more rural areas. Because the aquifer sediments are permeable and the water table is shallow, the surficial aquifer system is vulnerable to contamination from chemicals that are applied to the land surface and carried into groundwater with infiltrating rainfall and snowfall. Major Findings The quality of most groundwater produced for public and domestic water supply is suitable for drinking, although contaminants at concentrations greater than human-health benchmarks have been detected in some places Nitrate is one of the most widespread contaminants in groundwater Radium occurs commonly in groundwater as a result of the degradation of uranium and thorium minerals naturally present in aquifer sediments Chemicals in groundwater move slowly and can be detected in the environment for several decades after they enter the surficial aquifer system

Delaware, Maryland, New Jersey, New York, North Ca↗

Groundwater quality data for the northern Sacramento Valley, 2007: Results from the California GAMA Program

Groundwater quality in the approximately 1,180-square-mile Northern Sacramento Valley study unit (REDSAC) was investigated in October 2007 through January 2008 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within REDSAC and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 66 wells in Shasta and Tehama Counties. Forty-three of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 23 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial constituents. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of nitrogen and oxygen in nitrate, stable isotopes of hydrogen and oxygen of water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. In total, over 275 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and sampmatrix spikes) were collected at approximately 8 to 11 percent of the wells, and the results for these samples were used to evaluate the quality of the data obtained from the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a noticeable source of bias in the data for the groundwater samples. Differences between replicate samples were within acceptable ranges for nearly all compounds, indicating acceptably low variability. Matrix-spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate compliance or noncompliance with those thresholds. The concentrations of most constituents detected in groundwater samples from REDSAC were below drinking-water thresholds. Volatile organic compounds (VOC) and pesticides were detected in less than one-quarter of the samples and were generally less than a hundredth of any health-based thresholds. NDMA was detected in one grid well above the NL-CA. Concentrations of all nutrients and trace elements in samples from REDSAC wells were below the health-based thresholds except those of arsenic in three samples, which were above the USEPA maximum contaminant level (MCL-US). However, none of these wells were public-supply wells. Concentrations of all radioactive constituents were below health-based thresholds except radon-222, which was detected above the proposed MCL-US of 300 pCi/L in samples from 11 grid wells. Most of the samples from REDSAC wells had concentrations of major elements, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic or technical concerns. A few samples contained iron, manganese, or pH at levels above the SMCL-CA or SMCL-US thresholds.

California↗

Understanding beach health throughout the Great Lakes -- continuing research

The overall mission of U.S. Geological Survey (USGS) Beach Health Initiative is to provide science-based information and methods that will allow beach managers to more accurately make beach closure and advisory decisions, understand the sources and physical processes affecting beach contaminants, and understand how science-based information can be used to mitigate and restore beaches and protect the public. The USGS, in collaboration with many Federal, State, and local agencies and universities, has conducted research on beach-health issues in the Great Lakes Region for more than a decade. The work consists of four science elements that align with the initiative's mission: real-time assessments of water quality; coastal processes; pathogens and source tracking; and data analysis, interpretation, and communication. The ongoing or completed research for each of these elements is described in this fact sheet.

Wisconsin;New York;Michigan;Ohio;Indiana↗

Chapter A6. Section 6.2. Dissolved oxygen

Accurate data for the concentration of dissolved oxygen in surface and ground waters are essential for documenting changes in environmental water resources that result from natural phenomena and human activities. Dissolved oxygen is necessary in aquatic systems for the survival and growth of many aquatic organisms and is used as an indicator of the health of surface-water bodies. This section of the National Field Manual (NFM) includes U.S. Geological Survey (USGS) guidance and protocols for four methods to determine dissolved-oxygen concentrations: the amperometric, luminescent-sensor, spectrophotometric, and iodometric (Winkler) methods. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Latency and geofence testing of wireless emergency alerts intended for the ShakeAlert® earthquake early warning system for the West Coast of the United States of America

ShakeAlert, the earthquake early warning (EEW) system for the West Coast of the United States, attempts to provides crucial warnings before strong shaking occurs. However, because the alerts are triggered only when an earthquake is already in progress, and the alert latencies and delivery times are platform dependent, the time between these warnings and the arrival of shaking is variable. The ShakeAlert system uses, among other public alerting platforms like a mobile phone operating system, smartphone apps, and the Federal Emergency Management Agency Integrated Public Alert & Warning System (IPAWS). IPAWS sends Wireless Emergency Alerts (WEAs) informing people via their smartphones and other mobile devices about various events, such as natural hazards, child abductions, or public health information about COVID-19. However, little is known about the IPAWS delivery latencies. Given that people may have only a few seconds of notice after they receive an alert to take a protective action before they feel earthquake shaking, quantifying latencies is critical to understanding whether the IPAWS system is useful for EEW. In this study, we developed new methods to test the IPAWS distribution system's performance, both with devices in a controlled environment and as well as with a 2019 community-based feedback form, in Oakland and San Diego County, California, respectively. The controlled environment test used mobile phones (including smart and non-smart phones) and associated devices to determine alert receipt times; the community research form had participants self-report their receipt times. By triangulating the data between the controlled test environment and the community research, we determined the latency statistics as well as whether the geofence (the geographic area where the alert was intended to be sent) held broadly. We found that the latencies were similar between the two tests despite the large differences in population sizes. WEA messages were received within a median time frame of 6–12 s, and the geofence held with only a few exceptions. We use this latency to assess how the system would have performed in two large earthquakes, the 1989 M6.9 Loma Prieta and 2019 M7.1 Ridgecrest earthquakes, which both occurred near our WEA test locations. Our analysis revealed that had IPAWS been available during those earthquakes, particularly Loma Prieta, it would have provided crucial seconds of notice that damaging shaking was imminent in some locations relatively far from the epicenter. Further, we find affordable non-smart phones can receive WEAs as fast as smartphones. Finally, our new method can be used for latency and geospatial testing going forward for IPAWS and other similar alerting systems.

California↗

Groundwater quality in the Antelope Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Antelope Valley is one of the study areas being evaluated. The Antelope study area is approximately 1,600 square miles (4,144 square kilometers) and includes the Antelope Valley groundwater basin (California Department of Water Resources, 2003). Antelope Valley has an arid climate and is part of the Mojave Desert. Average annual rainfall is about 6 inches (15 centimeters). The study area has internal drainage, with runoff from the surrounding mountains draining towards dry lakebeds in the lower parts of the valley. Land use in the study area is approximately 68 percent (%) natural (mostly shrubland and grassland), 24% agricultural, and 8% urban. The primary crops are pasture and hay. The largest urban areas are the cities of Palmdale and Lancaster (2010 populations of 152,000 and 156,000, respectively). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. The primary aquifers in Antelope Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Antelope Valley are completed to depths between 360 and 700 feet (110 to 213 meters), consist of solid casing from the land surface to a depth of 180 to 350 feet (55 to 107 meters), and are screened or perforated below the solid casing. Recharge to the groundwater system is primarily runoff from the surrounding mountains, and by direct infiltration of irrigation and sewer and septic systems. The primary sources of discharge are pumping wells and evapotranspiration near the dry lakebeds.

California↗

Groundwater quality in Coachella Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Coachella Valley is one of the study areas being evaluated. The Coachella study area is approximately 820 square miles (2,124 square kilometers) and includes the Coachella Valley groundwater basin (California Department of Water Resources, 2003). Coachella Valley has an arid climate, with average annual rainfall of about 6 inches (15 centimeters). The runoff from the surrounding mountains drains to rivers that flow east and south out of the study area to the Salton Sea. Land use in the study area is approximately 67 percent (%) natural, 21% agricultural, and 12% urban. The primary natural land cover is shrubland. The largest urban areas are the cities of Indio and Palm Springs (2010 populations of 76,000 and 44,000, respectively). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. The primary aquifers in Coachella Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Coachella Valley are completed to depths between 490 and 900 feet (149 to 274 meters), consist of solid casing from the land surface to a depth of 260 to 510 feet (79 to 155 meters), and are screened or perforated below the solid casing. Recharge to the groundwater system is primarily runoff from the surrounding mountains, and by direct infiltration of irrigation. The primary sources of discharge are pumping wells, evapotranspiration, and underflow to the Salton Sea and Imperial Valley areas.

California↗

Reconnaissance water sampling for radium-226 in central and northern Florida, December 1974-March 1976

Analyses of 115 water samples collected from December 1974 through March 1976 in eight Florida Counties indicated that 22 samples (19 percent) had radium-226 activities equal to or in excess of 3 piC/liter (picocuries per liter), the concentration limit recommended for drinking water by the U.S. Public Health Service. The maximum radium-226 activity was 90 piC/liter in water from a shallow well in Polk County. The sampling reconnaissance was generally limited to areas of active phosphate mining and areas of undisturbed phosphate deposits. Most of the sampling was from water wells. Thirteen surface-water samples were collected in the Peace River drainage basin. The maximum radium-226 detected in surface-water samples was 3.6 piC/liter in Little Charlie Creek at State Road 664A in Hardee County. (Woodard-USGS)

Florida↗

Assessing models of arsenic occurrence in drinking water from bedrock aquifers in New Hampshire

Three existing multivariate logistic regression models were assessed using new data to evaluate the capacity of the models to correctly predict the probability of groundwater arsenic concentrations exceeding the threshold values of 1, 5, and 10 micrograms per liter (µg/L) in New Hampshire, USA. A recently released testing dataset includes arsenic concentrations from groundwater samples collected in 2004–2005 from a mix of 367 public-supply and private domestic wells. The use of this dataset to test three existing logistic regression models demonstrated enhanced overall predictive accuracy for the 5 and 10 μg/L models. Overall accuracies of 54.8, 76.3, and 86.4 percent were reported for the 1, 5, and 10 μg/L models, respectively. The state was divided by counties into northwest and southeast regions. Regional differences in accuracy were identified; models had an average accuracy of 83.1 percent for the counties in the northwest and 63.7 percent in the southeast. This is most likely due to high model specificity in the northwest and regional differences in arsenic occurrence. Though these models have limitations, they allow for arsenic hazard assessment across the region. The introduction of well-type (public or private), well depth, and casing length as explanatory variables may be appropriate measures to improve model performance. Our findings indicate that the original models generalize to the testing dataset, and should continue to serve as an important vehicle of preventative public health that may be applied to other groundwater contaminants in New Hampshire.

New Hampshire↗

Public water supplies in Gloucester County, New Jersey

Gloucester County is in the southwestern part of New Jersey, below Camden, and is a part of the Lower Delaware River Valley. This area is attracting new industry and has shown a population increase of about 47 percent from 1950 to 1960, mostly urban. With the economic growth of the county, the availability and quality of water become increasingly important. The county is in the Coastal Plain of New Jersey. It is underlain by unconsolidated sands and clays of Quaternary, Tertiary, and Cretaceous age. The Raritan and Magothy Formations constitute the most important aquifers and yield more than 95 percent of the water pumped by the public water systems in the county. These formations are capable of yielding 1,400 gpm (gallons per minute) or more to large diameter wells. High yielding wells generally can be drilled anywhere in the county, although the formations are deeper toward the Atlantic Ocean. The Cohansey Sand, second most important aquifer, yields up to 800 gpm or more from large diameter wells. This aquifer is present only in the sparsely populated southeastern half of the county. The Wenonah Formation and Mount Laurel Sand are capable of yielding 100 to 200 gpm in certain areas. The overall chemical quality of the naturally occurring ground water is good. The water generally meets the U.S. Public Health Service's (1962) suggested limit for dissolved solids; however, in some areas, the water carries objectionable amounts of iron and nitrate in solution and has a low pH. Contamination of ground water by salt-water encroachment or by pollution from industrial activity or organic waste in densely populated areas should be prevented. The quality rather than the quantity of water may be the important factor in future ground-water developments. The 21 public water systems in Gloucester County pumped about 1.3 billion gallons of water during 1948 and some 2.7 billion gallons during 1959. This is slightly more than a hundred percent increase in pumpage in 12 year s. The average per capita public water supply consumption in 1959 was approximately 75 gallons per day. This report includes a summary of the history of the present installations, groundwater conditions, quality and availability of water, and potential future yield for the 2 public water systems in Gloucester County.

New Jersey↗

Mercury in birds of San Francisco Bay-Delta, California: trophic pathways, bioaccumulation, and ecotoxicological risk to avian reproduction

San Francisco Bay Estuary in northern California has a legacy of mercury contamination, which could reduce the health and reproductive success of waterbirds in the estuary. The goal of this study was to use an integrated field and laboratory approach to evaluate the risks of mercury exposure to birds in the estuary. We examined mercury bioaccumulation, and other contaminants of concern, in five waterbird species that depend heavily on San Francisco Bay Estuary for foraging and breeding habitat: American avocets ( Recurvirostra americana ), black-necked stilts ( Himantopus mexicanus ), Forster’s terns ( Sterna forsteri ), Caspian terns ( Hydroprogne caspia ), and surf scoters ( Melanitta perspicillata ). These species have different foraging habitats and diets that represent three distinct foraging guilds within the estuary’s food web. In this report, we provide an integrated synthesis of the primary findings from this study and results are synthesized from 54 peer-reviewed publications generated to date with other unpublished results.

California↗

Analysis of the impact of African dust storms on the presence of enteric viruses in the atmosphere in Tenerife, Spain

Airborne viruses and their relation to dust storms, as a possible route for dispersion, have not been widely investigated. There are, however, studies that have described the airborne dispersal of pathogenic viruses and their potential impact on public and agronomical health. Atmospheric samples were collected in an urban area of Tenerife during 2009, 2010, 2012 and 2013 and screened for the presence of enteric viruses using PCR and sequencing. The potential relationship of viral data with African dust storms and other climatic variables (viz., the seasonality, origin of the air mass and PM levels) was analyzed. Enteroviruses and Rotaviruses were detected in 15.4% (20/130) and 36.9% (48/130) of the samples, respectively. No significant statistical relationships were observed with African dust storms or the origin of the air masses, although higher percentages of positives were obtained for dust storm days. Enterovirus detection was significantly linked to warmer seasons, and PM 2.5 levels showed an inverse correlation with a rotaviral presence. This is the first multi-year report to describe the presence of Enterovirus and Rotavirus genetic sequences in air samples collected in an outdoor urban environment. The data illustrates the need for source region sampling to determine links and the influence of the weather and climatic and regional wind patterns on long-range atmospheric dispersion of viruses in future research efforts.

Tenerife↗

Groundwater-quality data in the South Coast Range-Coastal study unit, 2008: Results from the California GAMA Program

Groundwater quality in the approximately 766-square-mile South Coast Range–Coastal (SCRC) study unit was investigated from May to December 2008, as part of the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project was developed in response to legislative mandates (Supplemental Report of the 1999 Budget Act 1999-00 Fiscal Year; and, the Groundwater Quality Monitoring Act of 2001 [Sections 10780-10782.3 of the California Water Code, Assembly Bill 599]) to assess and monitor the quality of groundwater in California, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The SCRC study unit was the 25th study unit to be sampled as part of the GAMA Priority Basins Project. The SCRC study unit was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined as that part of the aquifer corresponding to the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the SCRC study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the SCRC study unit, groundwater samples were collected from 70 wells in two study areas (Basins and Uplands) in Santa Barbara and San Luis Obispo Counties. Fifty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 15 wells were selected to aid in evaluation of specific water-quality issues (understanding wells). In addition to the 70 wells sampled, 3 surface-water samples were collected in streams near 2 of the sampled wells in order to better comprehend the interaction between groundwater and surface water in the area. The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, polar pesticides and metabolites, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-TCP), naturally occurring inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], and alkalinity), and radioactive constituents (gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stable isotopes of nitrogen and oxygen in dissolved nitrate, stable isotopes of sulfur in dissolved sulfate, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance), and dissolved gases (including noble gases) also were measured to help identify the sources and ages of the sampled groundwater. In total, 298 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and matrix-spikes) were collected at approximately 3 to 12 percent of the wells in the SCRC study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Differences between replicate samples generally were less than 10 percent relative and/or standard deviation, indicating acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and/or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-regulatory thresholds established for aesthetic concerns by CDPH. Comparisons between data collected for this study and thresholds for drinking water are for illustrative purposes only and are not indicative of compliance or noncompliance with those thresholds. Most organic and inorganic constituents that were detected in groundwater samples from the 55 grid wells in the SCRC study unit were detected at concentrations less than drinking-water thresholds. In addition, all detections of organic constituents in SCRC grid well samples were less than health-based thresholds. In total, VOCs were detected in 33 percent of the 55 grid wells sampled and pesticides and pesticide degradates were detected in 27 percent of grid wells sampled in the SCRC study unit. In the Basins study area, VOCs and pesticides and pesticide degradates were detected in approximately 33 percent of the 39 grid wells. In the Uplands study area, VOCs were detected in approximately 31 percent and pesticides and pesticide degradates were detected in approximately 13 percent of the 16 grid wells. Trace elements and minor ions were sampled for at 32 grid wells and nutrients at 33 grid wells in the SCRC study unit, and most detections were less than health-based thresholds. Exceptions in the Basins study area include one detection of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 µg/L and three detections of nitrite plus nitrate, as nitrogen (NO2-+NO3-) greater than the MCL-US of 10 mg/L. Exceptions in the Uplands study area include two detections of arsenic greater than the MCL-US and eight detections of molybdenum greater than the USEPA lifetime health advisory level (HAL-US) of 40 µg/L. All detections of major and minor ions and gross alpha and gross beta radioactivity from the SCRC grid wells were less than health-based thresholds. Results for trace elements, major ions, and TDS with non-enforceable thresholds set for aesthetic concerns from 16 Basins study area grid wells showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 µg/L were detected in grid wells. Manganese concentrations greater than the SMCL-CA of 50 µg/L were detected in six grid wells. Chloride concentrations greater than the recommended SMCL-CA threshold of 250 mg/L were detected in one grid well. Sulfate concentrations greater than the recommended SMCL-CA threshold of 250 mg/L were measured in 12 grid wells and 3 of these wells also were greater than the upper SMCL-CA threshold of 500 mg/L. TDS concentrations greater than the SMCL-CA recommended threshold of 500 mg/L were measured in 14 of the 16 Basins study area grid wells and concentrations in 5 of these wells also were greater than the SMCL-CA upper threshold of 1,000 mg/L. In the Uplands study area, iron concentrations greater than the SMCL-CA were detected in 2 of 16 grid wells and manganese concentrations greater than the SMCL-CA were detected in 3 grid wells. TDS and sulfate concentrations greater than the recommended SMCL-CA thresholds were detected in 11 and 2 grid wells, respectively, but none of these concentrations were greater than the SMCL-CA upper thresholds.

California↗