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Sedimentology of the lower part of the upper Triassic Chinle Formation and its relationship to uranium deposits, White Canyon area, southeastern Utah

Closely spaced measured stratigraphic sections of the lower part of the Late Triassic Chinle Formation in the White Canyon area of southeastern Utah depict a fluvial-deltaic-lacustrine depositional sequence that hosts uranium deposits in basal fluvial sandstones. The basal Shinarump Member consists of predominantly trough-crossbedded, coarse-grained sandstone and minor gray, carbonaceous mudstone and is interpreted as a valley-fill sequence overlain by deposits of a braided stream system. The overlying Monitor Butte Member is composed of cyclic- and foreset-bedded siltstone, sandstone, and mudstone and is interpreted as a succession of low-energy fluvial, deltaic and orqanicrich, lacustrine-marsh sediments. The overlying Moss Back Member is composed of a laterally extensive, coarse- to medium-grained, conglomeratic sandstone and is interpreted as a braided-stream system that flowed north to northwest. The entire sequence was deposited in response to changes in local base level associated with a large lake that lay to the west. Isopachs of lithofacies indicate distinct lacustrine basins and a correspondence between these facies and modern structural synclines. Facies changes and coincidence of isopach thicks suggest that structural synclines were active in the Late Triassic and influenced the pattern of sediment distribution within the basins. Uranium mineralization appears to be related to certain low-energy depositional environments in that uranium is localized in fluvial sandstones that lie beneath organic-rich lacustrine-marsh mudstones and carbonaceous delta-front sediments. The reducing environment preserved in these facies may have played an important role in the localization of uranium.

Utah

Quaternary geology of Alameda County, and parts of Contra Costa, Santa Clara, San Mateo, San Francisco, Stanislaus, and San Joaquin Counties, California: A digital database

Alameda County is located at the northern end of the Diablo Range of Central California. It is bounded on the north by the south flank of Mount Diablo, one of the highest peaks in the Bay Area, reaching an elevation of 1173 meters (3,849 ft). San Francisco Bay forms the western boundary, the San Joaquin Valley borders it on the east and an arbitrary line from the Bay into the Diablo Range forms the southern boundary. Alameda is one of the nine Bay Area counties tributary to San Francisco Bay. Most of the country is mountainous with steep rugged topography. Alameda County is covered by twenty-eight 7.5' topographic Quadrangles which are shown on the index map. The Quaternary deposits in Alameda County comprise three distinct depositional environments. One, forming a transgressive sequence of alluvial fan and fan-delta facies, is mapped in the western one-third of the county. The second, forming only alluvial fan facies, is mapped in the Livermore Valley and San Joaquin Valley in the eastern part of the county. The third, forming a combination of Eolian dune and estuarine facies, is restricted to the Alameda Island area in the northwestern corner of the county.

California

Upper Cenozoic deposits of the central Delmarva Peninsula, Maryland and Delaware

The surface and shallow subsurface sediments of the lower Delmarva Peninsula include beds ranging in age from Miocene to Holocene. The oldest beds appear to be typical shelf deposits of the Chesapeake Group (Calvert-Choptank age). These marine units are overlain by deltaic deposits, which range from fluviatile facies in the north (Pensauken Formation) to marginal marine and marine beds in the south ('Yorktown(?) and Cohansey(?)' Formations as used by Rasmussen and Slaughter in 1955). This large deltaic mass underlies most of the Delmarva Peninsula. Fossil age determinations supplemented by some radiometric dates indicate the delta to be largely late Miocene in age. The nonmarine facies of the delta, the Pensauken Formation, previously was considered to be Pleistocene in age. The late Miocene delta and possibly the Yorktown Formation (lower to middle Pliocene) are overlain by a feldspathic sand, the Beaverdam, which is at least in part marginal marine. Microflora recovered from this formation include species no longer indigenous to the Delmarva region ('exotics'). On the basis of existing information, microfloral assemblages containing 'exotics' are pre-Pleistocene in age. The Beaverdam therefore is pre-Pleistocene in age, probably late Pliocene. A highly dissected and weathered unit, the Walston Silt, caps the uplands of the central Delmarva Peninsula, where it overlies the Beaverdam. The Walston has a microflora containing 'exotics' and therefore is considered to be the youngest Tertiary unit (uppermost Pliocene) in this area. Sediments forming a barrier-back-barrier sequence fringe most of the southern Maryland-Delaware part of the Delmarva Peninsula and are found at altitudes of as much as 15 m (50 ft) above sea level. This sequence, the Omar Formation, is Sangamon in age and has been dated radiometrically as 60,000 to about 100,000 years old. The microflora in these beds contains no 'exotics,' and the assemblage suggests a warm-temperate environment. The Omar represents the highest stand of the Quaternary seas in the Delmarva region. The Ironshire and Kent Island Formations overlie or cut into the Omar Formation and are probably late Sangamon and middle Wisconsin, respectively, in age. Near Ocean City, the Ironshire forms a seaward-facing scarp with a toe nearly 4.5 m (15 ft) above sea level. A warm-temperate microfloral assemblage from the fluviatile-estuarine facies of the Ironshire Formation in the Delaware Bay region suggests that the formation is interglacial, probably late Sangamon in age. The Ironshire and Omar Formations are overlain unconformably by the Sinepuxent Formation. The top of this marine unit is slightly above present sea level and has been dated by radiocarbon as about 30,000 years old or middle Wisconsin. The microflora from this formation is a cold to cool-temperate assemblage (high proportion of spruce pollen). The outer fringes of the Delmarva Peninsula are being overlapped by deposits of a Holocene marine transgression.

Professional Paper

The Accotink Schist, Lake Barcroft Metasandstone, and Popes Head Formation— Keys to an understanding of the tectonic evolution of the northern Virginia Piedmont

The newly named Accotink Schist and Lake Barcroft Metasandstone of the Eastern Fairfax sequence are the structurally lowest metamorphic rocks in the northernmost Piedmont of Virginia. The Accotink consists of beds of pelitic schist that have thin basal intervals containing graded, very fine grained metasiltstone, as well as interbeds of metasandstone like that in the overlying Lake Barcroft Metasandstone. The unit is characterized by the Bouma turbidite sequences Te and Tde and can be assigned to turbidite facies D and E. The thickness of the Accotink is not known because its base is not exposed. The Accotink Schist grades up into the Lake Barcroft Metasandstone, which consists of two types of metasandstone. Type I metaarenite is quartzofeldspathic granofels which forms thick sequences of amalgamated beds that can best be described as belonging to the Bouma turbidite sequence Ta and to turbidite facies B 2 . Type II metagraywacke of the Lake Barcroft Metasandstone consists of micaceous metagraywacke in thin to medium beds, which can be described as belonging to the Buoma turbidite sequences Tabe and (or) Tae and to turbidite facies C. The Lake Barcroft Metasandstone appears to be about 400 m thick. It and the Accotink Schist are thought to represent a coarsening-upward sequence of an outer submarine-fan association of rocks. The Eastern Fairfax sequence is overlain by the Sykesville Formation. We believe that this contact is a movement surface upon which the Sykesville was emplaced by subaqueous sliding. The Sykesville contains isoclinally folded fragments, thought to be rip-ups, of Accotink and Lake Barcroft rocks. The Eastern Fairfax sequence is intruded by rocks of the Occoquan Granite batholith, which contains pendants of isoclinally folded schist and metagraywacke. Mter intrusion, the metasedimentary and plutonic rocks were folded together. Gamet and chlorite porphyroblasts within the Eastern Fairfax sequence appear to be related to the emplacement of the batholith. The minimum age of the Eastern Fairfax sequence is that of the Occoquan Granite batholith, currently thought to be about 560 m.y. The sequence, then, is considered to be of Early Cambrian age or older. The Accotink Schist and Lake Barcroft Metasandstone have some lithic similarity to the Loch Raven Schist and Oella Formation of Crowley (1976) of the Baltimore area, but a correlation is very uncertain at this time. The newly named Popes Head Formation overlies all other metasedimentary and transported meta-igneous rocks in northernmost Virginia west ofthe Occoquan Granite batholith and is intruded by the batholith. The Popes Head consists of a lower Old Mill Branch Metasiltstone Member and an upper Station Hills Phyllite Member. The Old Mill Branch consists largely of alternating coarser and finer grained strata that are mostly fine- to very fine grained, mineralogically quite mature graded metasiltstone, which can be described as belonging to Bouma turbidite sequence Tbde and (or) Tde, more rarely Tcde. The metasiltstone contains interbedded intervals in which both felsic and mafic metatuff contain pristine euhedral crystals of igneous minerals. We believe that the metatuff represents ash-fall deposits. The Old Mill Branch appears to be about 730 m thick. The Old Mill Branch grades up into the Station Hills Phyllite Member, which consists of thin- to medium-bedded pelitic phyllite and smaller amounts of very fine grained metasiltstone. The metasiltstone beds are graded, and many phyllite beds appear to have basal in- tervals containing graded, very fine grained metasiltstone. These beds can be described as belonging to Bouma turbidite sequence Tde. The Station Hills has intervals containing chlorite-rich phyllite, which probably represents mafic metatuff. No felsic metatuff has been recognized. The top of the Station Hills is not known, neither therefore, is its thickness. This unit appears to have a maximum thickness of about 300 m in northern

Virginia

Correlation of the Eocene formations in Mississippi and Alabama

During Eocene time the site of the boundary between the States of Mississippi and Alabama fell within the transition zone between the Mississippi embayment and the open Gulf of Mexico. That different types of deposition proceeded simultaneously within these two regions may be inferred from the different facies which deposits of the same age exhibit on opposite sides of the State line. In general, much clay and carbonaceous material were laid down in Mississippi, while shell marl, laminated sand, and limestone were being formed in Alabama. The purpose of this paper is to point out the equivalences of formations of different facies in the two States. The formations of different facies in the two States. The correlation adopted in shown in the following table, all the formation names in which have been previously used, except Kosciusko sandstone, a new name proposed for a member of the Lisbon formation.

Alabama;Mississippi

Geology and hydrogeology of the Caribbean Islands aquifer system of the Commonwealth of Puerto Rico and the U.S. Virgin Islands

Poorly lithified to unconsolidated carbonate and clastic sedimentary rocks of Tertiary (Oligocene to Pliocene) and Quaternary (Pleistocene to Holocene) age compose the South Coast aquifer and the North Coast limestone aquifer system of Puerto Rico; poorly lithified to unlithified carbonate rocks of late Tertiary (early Miocene to Pliocene) age make up the Kingshill aquifer of St. Croix, U.S. Virgin Islands. The South Coast aquifer, North Coast limestone aquifer system, and Kingshill aquifer are the most areally extensive and function as the major sources of ground water in the U.S. Caribbean Islands Regional Aquifer-System Analysis (CI-RASA) study area. In Puerto Rico's South Coast ground-water province, more than 1,000 meters of clastic and carbonate rocks of Oligocene to Pliocene age infill the South Coast Tertiary Basin. The pattern of lithofacies within this basin appears to have been controlled by changes in base level that were, at times, dominated by tectonic movement (uplift and subsidence), but were also influenced by eustasy. Deposition of the 70-kilometer long and 3- to 8-kilometer wide fan-delta plain that covers much of the South Coast ground-water province occurred largely in response to glacially-induced changes in sea level and climate during the Quaternary period. Tectonic movement played a much less important role during the Quaternary. The North Coast ground-water province of Puerto Rico is underlain by homoclinal coastal plain wedge of carbonate and siliciclastic rocks that infill the North Coast Tertiary Basin and thicken to more than 1,700 meters. A thin basal siliciclastic sequence of late Oligocene age is overlain by a thick section of mostly carbonate rocks of Oligocene to middle Miocene age. Globigerinid limestone of late Miocene to Pliocene age crops out and lies in the shallow subsurface areas of northwestern Puerto Rico. Oligocene to middle Miocene age rocks tentatively can be divided into five depositional sequences and associated systems tracts; these rocks record carbonate and minor siliciclastic deposition that occurred in response to changes in relative sea level. The Cibao Formation represents the most complex of these sequences and contains a varied facies of carbonate, mixed carbonate-siliciclastic, and siliciclastic rocks that reflect differential uplift, subsidence, and transgression of the sea. Uplift, graben formation, and gradual shallowing of the sea are reflected within the bathyal-dominated sedimentary facies of the Kingshill Limestone in St. Croix, U.S. Virgin Islands. Reef-tract limestone beds of Pliocene age were subject to exposure, resubmergence, and meteoric leaching of aragonitic skeletal debris; these beds contain patchy lenses of dolomite that are restricted to a small, structurally-controlled embayment. The South Coast aquifer, the principal water-bearing unit of Puerto Rico's South Coast ground-water province, consists of boulder- to silt-size detritus formed by large and small coalescing fan deltas of Pleistocene to Holocene age. Deep well data indicates that it is possible to vertically separate and group a highly complex and irregular-bedded detrital sequence that underlies distal parts of the fan-delta plain into discrete water-bearing units if correlated with 30- to 40-meter thick, eustatically-controlled depositional cycles. Lithofacies maps show that greatest hydraulic conductivity within the fan-delta plain is generally associated with proximal fan and midfan areas. Distal and interfan areas are least permeable. Alluvial valley aquifers located in the western part of the South Coast ground-water province are important local sources of water supply and appear to contain some of the same physical and hydraulic characteristics as the South Coast aquifer. Older sedimentary rocks within the basin are poor aquifers; conglomeratic beds are well-cemented, and carbonate beds do not contain well-developed solution features, except locally where the beds are overlain by alluvium. Ground-water occurs under unconfined conditions in proximal and midfan areas. Confined conditions within deeper parts of the system and in interfan and some midfan areas are created largely by the intercalated nature of discontinuous fine-grained beds that retard vertical ground-water movement. The development of water resources in southern Puerto Rico has modified the hydrologic system of the South Coast aquifer considerably. Under predevelopment conditions, the South Coast aquifer was recharged in the unconfined, proximal fan and some midfan areas by infrequent rainfall and seepage from streams near the fan apex. Discharge occurred as seabed seepage, baseflow discharge along the lower coastal reach of streams, seepage to coastal wetlands, or evapotranspiration in areas underlain by a shallow water table. Under development conditions, seepage from irrigation canals and areal recharge from furrow irrigation represented a principal mechanism for recharge to the aquifer. Increased ground-water withdrawals in the 1960's and 1970's resulted in declines in the water table to below sea level in some places and intrusion of salt water into the aquifer. By the middle 1980's, a reduction in ground-water withdrawals and a shift from furrow irrigation to drip-irrigation techniques resulted in the recovery of water levels. Under present-day (1986) conditions, regional ground-water flow is coastward but with local movement to some well fields. In addition to the discharge mechanisms described above, ground-water discharges also to coastal canals. The North Coast limestone aquifer system consists of limestone, lesser amounts of dolomite, and minor clastic detritus of Oligocene to Pliocene age that form an unconfined upper aquifer and a confined lower aquifer; these aquifers are separated by a clay, mudstone, and marl confining unit. Topographic relief and incision of carbonate coastal plain rocks by streams are the principal factors controlling the direction of ground-water flow. The North Coast limestone aquifer system is recharged principally by precipitation that enters the upper and lower aquifers where they crop out. Regional groundwater movement from the upper aquifer is to the major rivers, wells, coastal wetlands, coastal, nearshore, and offshore springs, or as seabed seepage. Regional discharge from the lower aquifer is to the major rivers along its unconfined parts or where the confining unit has been breached by streams. Discharge from the lower aquifer also occurs in the San Juan area where the Mucarabones Sand provides an avenue for diffuse upward ground-water flow. Transmissivity within the upper limestone aquifer appears to be largely regulated by the thickness of the freshwater lens. The lens is thickest and transmissivity is greatest in interstream areas that lie in a zone that closely corresponds to the landwardmost extent of the underlying saltwater wedge. Hydraulic conductivity of the upper aquifer generally increases in a coastward direction and reflects lithologic control, karstification in the upper 30 to 100 meters of the section, and enhanced permeability in a zone of freshwater and saltwater mixing. Transmissivity of the lower aquifer is an order of magnitude smaller than that of the upper aquifer; highest transmissivities in the lower aquifer largely correspond to a coarse grainstone-packstone and coral-patch-reef depositional facies contained within the outcropping parts of the Montebello Limestone Member and its subsurface equivalents. Porosity within the North Coast limestone aquifer system is high in grainstone-packstones and low in wackestone and marl. Dolomitized zones and moldic grainstone-packstone strata are the most porous carbonate rocks, but occur in thin beds that usually are only a few meters thick. Processes of karstification that include the development of caverous zones and large vugs, and dissolution along possible regional fracture sets has enhanced permeability within the upper part of the aquifer system. Stratigraphic and lithologic control play an important role controlling permeability within the lower part of the system. The Kingshill aquifer of St. Croix, in large part, is composed of deepwater limestone that contains only microscopic pores and is poorly permeable; however, the upper part of the aquifer, a shallow-water skeletal and reef limestone, is fairly permeable, but restricted in areal extent. Permeability within these uppermost beds of the aquifer has been enhanced by meteoric leaching, dissolution within a mixing zone of saltwater and fresh water, and dolomitization. However, most large-yield wells completed in the Kingshill aquifer are also screened in alluvium that overlies or infills incised channels. The alluvial deposits serve as a temporary storage zone for rainfall, runoff, and ground water slowly entering the Kingshill aquifer.

Puerto Rico

Mid-Tertiary isopach and lithofacies maps for the Los Angeles region, California: Templates for palinspastic reconstruction to 17.4 Ma

A preliminary palinspastic reconstruction is presented of the region of the Los Angeles Basin at its 17.4 Ma inception. To create this reconstruction, pertinent paleomagnetic declination data are combined with new maps of the areal extent, thickness variations, and depositional facies of the >17.4 Ma Sespe-Vaqueros Formations and their equivalents. Opening of the Neogene Los Angeles Basin began abruptly about 17.4 Ma. Extensional rifting, with local basaltic volcanism, began the process and accompanied its early stages. Crustal detachment, followed by clockwise tectonic rotation and translation of large crustal blocks has been shown by previous paleomagnetic declination measurements in the western Transverse Ranges Province northwest of the basin and by large strike-slip and dip-slip separations on several major faults transecting it. Successful palinspastic reconstruction of the region to its arrangement before 17.4 Ma depends on understanding and integration of many stratigraphic and structural components. Before 17.4 Ma, fluviatile, alluvial and floodplain deposits, interstratified in the younger part with shallow marine to deeper shelf transgressive equivalents, accumulated to thicknesses as great as several kilometers. This report maps the surface and subsurface extents, thickness variations, and facies patterns of these strata, the Sespe plus Vaqueros and Trancas Formations or equivalents. Separate southeast and northwest sectors are revealed, each with distinctive internal thickness and facies patterns, which must have been related before rifting and transrotation. Terrestrial vertebrate and marine molluscan and foraminiferal fossils, plus magnetostratigraphic profiles of other workers and a few dates of igneous rocks, provide timing for key depositional and structural events. Our preliminary reconstruction of the region brings the internal patterns of the northwest and southeast sectors toward congruity but leaves unsatisfied discrepancies that suggest important information is missing. The reconstruction focuses attention on critical elements, specific uncertainties, and defi- ciencies of prior reconstructions. It also provides a new foundation for further work.

California

Late Cenozoic geology and lacustrine history of Searles Valley, Inyo and San Bernardino Counties, California

Searles Valley is an arid, closed basin lying 70 km east of the south end of the Sierra Nevada, California. It is bounded on the east and northeast by the Slate Range, on the west by the Argus Range and Spangler Hills, and on the south by the Lava Mountains; Searles (dry) Lake occupies the north-central part of the valley. During those parts of late Pliocene and Pleistocene time when precipitation and runoff from the east side of the Sierra Nevada into the Owens River were much greater than at present, a chain of as many as five large lakes was created, of which Searles Lake was third. The stratigraphic record left in Searles Valley when that lake expanded, contracted, or desiccated, is fully revealed by cores from beneath the surface of Searles (dry) Lake and partly recorded by sediments cropping out around the edge of the valley. The subsurface record is described elsewhere. This volume includes six geologic maps (scales: 1:50,000 and 1:10,000) and a text that describes the outcrop record, most of which represents sedimentation since 150 ka. Although this outcrop record is discontinuous, it provides evidence indicating the lake's water depths during each expansion, which the subsurface record does not. Maximum-depth lakes rose to the 2,280-ft (695 m) contour, the level of the spillway that led overflowing waters to Panamint Valley; that spillway is about 660 ft (200 m) above the present dry-lake surface. Several rock units of Tertiary and early Quaternary ages crop out in Searles Valley. Siltstone and sandstone of Tertiary age, mostly lacustrine in nature and locally deformed to near-vertical dips, are exposed in the southern part of the valley, as is the younger(?) upper Miocene Bedrock Spring Formation. Unnamed, mostly mafic volcanic rocks of probable Miocene or Pliocene age are exposed along the north and south edges of the basin. Slightly deformed lacustrine sandstones are mapped in the central-southwestern and southern parts of the study area. The Christmas Canyon Formation and deposits mapped as older gravel and older tufa are extensively exposed over much of the basin floor. The older gravel unit and the gravel facies of the Christmas Canyon Formation are boulder alluvial gravels; parts of these units are probably correlative. The lacustrine facies of the Christmas Canyon Formation includes the Lava Creek ash, which is dated at 0.64 Ma; the older tufa deposits may be equivalent in age to those sediments. Most of this study concerns sediments of the newly described Searles Lake Formation, whose deposition spanned the period between about 150 ka and 2 ka. Most of this formation is lacustrine in origin, but it includes interbedded alluvium. To extract as much geologic detail as possible, criteria were developed that permitted (1) intrabasin correlation of some thin outcrop units representative of only a few thousand years (or less), (2) identification of unconformities produced by subaerial erosion, (3) identification of unconformities produced by sublacustrine erosion, and (4) correlation of outcrop units with subsurface units. The Searles Lake Formation is divided into seven main units, many of which are subdivided on the five larger scale geologic maps. Units A (oldest), B, C, and D are dominantly lacustrine in origin. The Pleistocene-Holocene boundary is placed at the top of unit C. In areas that were a kilometer or more from shore at the time of deposition, deposits of units A,B, and C consist of fine, highly calcareous sand, silt, or clay; nearer to shore they consist of well-sorted coarse sand and gravel. Unit A has been locally subdivided into as many as four subunits, unit B into six subunits, and unit C into six subunits. The finer facies of units A, B, and C contain such high percentages of Caco3 that they are best described as marl. Sediments of unit C, and to a lesser extent those of unit B, are laminated with light- to white-colored layers of aragonite, calcite, or dolomite(?) that may repre

California

Lithofacies, age, depositional setting, and geochemistry of the Otuk Formation in the Red Dog District, northwestern Alaska

Complete penetration of the Otuk Formation in a continuous drill core (diamond-drill hole, DDH 927) from the Red Dog District illuminates the facies, age, depositional environment, source rock potential, and isotope stratigraphy of this unit in northwestern Alaska. The section, in the Wolverine Creek plate of the Endicott Mountains Allochthon (EMA), is ~82 meters (m) thick and appears structurally uncomplicated. Bedding dips are generally low and thicknesses recorded are close to true thicknesses. Preliminary synthesis of sedimentologic, paleontologic, and isotopic data suggests that the Otuk succession in DDH 927 is a largely complete, albeit condensed, marine Triassic section in conformable contact with marine Permian and Jurassic strata. The Otuk Formation in DDH 927 gradationally overlies gray siliceous mudstone of the Siksikpuk Formation (Permian, based on regional correlations) and underlies black organic-rich mudstone of the Kingak(?) Shale (Jurassic?, based on regional correlations). The informal shale, chert, and limestone members of the Otuk are recognized in DDH 927, but the Jurassic Blankenship Member is absent. The lower (shale) member consists of 28 m of black to light gray, silty shale with as much as 6.9 weight percent total organic carbon (TOC). Thin limy layers near the base of this member contain bivalve fragments (Claraia sp.?) consistent with an Early Triassic (Griesbachian-early Smithian) age. Gray radiolarian chert dominates the middle member (25 m thick) and yields radiolarians of Middle Triassic (Anisian and Ladinian) and Late Triassic (Carnian-late middle Norian) ages. Black to light gray silty shale, like that in the lower member, forms interbeds that range from a few millimeters to 7 centimeters in thickness through much of the middle member. A distinctive, 2.4-m-thick interval of black shale and calcareous radiolarite ~17 m above the base of the member has as much as 9.8 weight percent TOC, and a 1.9-m-thick interval of limy to cherty mudstone immediately above this contains radiolarians, foraminifers, conodonts, and halobiid bivalve fragments. The upper (limestone) member (29 m thick) is lime mudstone with monotid bivalves and late Norian radiolarians, overlain by gray chert that contains Rhaetian (latest Triassic) radiolarians; Rhaetian strata have not previously been documented in the Otuk. Rare gray to black shale interbeds in the upper member have as much as 3.4 weight percent TOC. At least 35 m of black mudstone overlies the limestone member; these strata lack interbeds of oil shale and chert that are characteristic of the Blankenship, and instead they resemble the Kingak Shale. Vitrinite reflectance values (2.45 and 2.47 percent Ro) from two samples of black shale in the chert member indicate that these rocks reached a high level of thermal maturity within the dry gas window. Regional correlations indicate that lithofacies in the Otuk Formation vary with both structural and geographic position. For example, the shale member of the Otuk in the Wolverine Creek plate includes more limy layers and less barite (as blades, nodules, and lenses) than equivalent strata in the structurally higher Red Dog plate of the EMA, but it has fewer limy layers than the shale member in the EMA ~450 kilometers (km) to the east at Tiglukpuk Creek. The limestone member of the Otuk is thicker in the Wolverine Creek plate than in the Red Dog plate and differs from this member in EMA sections to the east in containing an upper cherty interval that lacks monotids; a similar interval is seen at the top of the Otuk Formation ~125 km to the west (Lisburne Peninsula). Our observations are consistent with the interpretations of previous researchers that Otuk facies become more distal in higher structural positions and that within a given structural level more distal facies occur to the west. Recent paleogeographic reconstructions indicate that the Otuk accumulated at a relatively high paleolatitude with a bivalve fauna typical of the Boreal realm. A suite of δ 13 C org (carbon isotopic composition of carbon) data (n=38) from the upper Siksikpuk Formation through the Otuk Formation and into the Kingak(?) Shale in DDH 927 shows a pattern of positive and negative excursions similar to those reported elsewhere in Triassic strata. In particular, a distinct negative excursion at the base of the Otuk (from ‒23.8 to ‒31.3‰ (permil, or parts per thousand)) likely correlates with a pronounced excursion that marks the Permian-Triassic boundary at many localities worldwide. Another feature of the Otuk δ 13 C org record that may correlate globally is a series of negative and positive excursions in the lower member. At the top of the Otuk in DDH 927, the δ 13 C org values are extremely low and may correlate with a negative excursion that is widely observed at the Triassic-Jurassic boundary.

Alaska

Arctic Alaska’s Lower Cretaceous (Hauterivian and Barremian) mudstone succession—Linking lithofacies, texture, and geochemistry to marine processes

We present new images and descriptions of the lithofacies and organic facies of the pebble shale unit and lower part of the Hue Shale (Lower Cretaceous) of Arctic Alaska at a high magnification that illustrates their textural characteristics. Our aims were to describe and determine the distribution of facies in these petroleum source rocks and to identify the processes that formed them. We sampled at high-resolution and applied new petrographic techniques combined with scanning electron microscopy and geochemical analyses to samples collected from three widely spaced sections—located in exposures along the Canning River and continuous core from the Mikkelsen Bay State 1 and Orion 1 wells. Results from these three locations indicate that this succession consists primarily of clay-rich mudstones that are variously silt- or sand-bearing and clay-dominated mudstones that exhibit mainly relict, 2–5 millimeter thick bedding and common but variable microbioturbation, rare macrobioturbation, and common fabrics of pelleted clay and silt. These mudstones contain rare, poorly sorted, silt-rich basal laminae that are often discontinuous and have wavy, sharp bases and crude upward fining. In addition, mud-supported, outsized clasts (dropstones) of fine sand to pebble size are present throughout the succession as isolated clasts or in clusters. We interpret these textures and much of this succession to result from intermittent deposition by suspension settling from melting seasonal sea ice—sometimes sediment-laden—and associated primary productivity. Overall, this mudstone succession fines and deepens upward from the pebble shale unit into the Hue Shale. In the Hue Shale of the Orion well, however, different processes intermittently deposited thin, discrete intervals of coarser sediment that probably represent deposition from density currents. Also in the Hue Shale of the Orion well, several thicker sandstone and silt-dominated mudstone units with discordant, scoured bases and cut and fill structures represent erosion during higher energy events such as major storms. Other lithofacies within the succession are graded tuffs/bentonites and tuffaceous/bentonitic mudstones from episodic volcanic ash falls; these are abundant in the Hue Shale, and very rare in the pebble shale unit of the two wells. Organic-carbon rich strata associated with volcanic ash intervals of the pebble shale unit and Hue Shale in the Mikkelsen 1 well have some of the best petroleum source rock potential determined for this succession. Authigenic pyrite and carbonate-cement-dominated mudstone are also present in both units of all three sections. The carbonate-cemented units indicate breaks in sedimentation and are common in the Hue Shale and in sections of the pebble shale unit interpreted to be more distal, such as along the Canning River. Our results document the variation in facies and textures of the Hauterivian and Barremian Lower Cretaceous mudstone succession of Arctic Alaska. Comparison of these characteristics to the products of modern processes on the North Slope of Alaska, in the Beaufort Sea, and elsewhere suggest that this succession formed primarily from depositional processes related to seasonal sea ice with intermittent fluvial-sourced sediment deposited by density currents and episodic erosion and reworking by storms and other currents.

Alaska

Cambrian and Ordovician stratigraphy, conodont biostratigraphy, and microfacies analysis to support 1:24,000-scale geologic mapping of the southern Lake Champlain valley, New York and Vermont

Introduction Geologic mapping in the southern Lake Champlain valley of New York and Vermont (fig. 1) has required evaluation of stratigraphic nomenclature used since the early 1900s. The paleogeography of the Cambrian and Ordovician adjacent to the Adirondack Highlands, the high-relief mountains of Proterozoic igneous and metamorphic rocks of northern New York, has impacted the lithostratigraphic succession, facies changes, and several hiatuses that occur within the package of clastic and carbonate rocks that demonstrates overall deepening consistent from the southern to northern Appalachians. The stratigraphic nomenclature used for the geologic mapping of the Cambrian and Ordovician strata of the study area is derived from evaluation of names put forth by previous workers from areas of northern New York and western Vermont. Descriptions of type localities or type sections and other criteria set forth by the North American Stratigraphic Code (North American Commission on Stratigraphic Nomenclature [NACSN], 2021) were consulted. The North American Stratigraphic Code states that lithostratigraphic units, such as the fundamental unit, the formation, be defined by lithic character and be mappable (NACSN, 2021, Article 24). However, some early workers (Walcott, 1912; Kay, 1937; Fisher and Hanson, 1951; Oxley and Kay, 1959) have defined stratigraphic units based on fossil content, which may or may not be facies dependent, and hence may not be mappable as lithostratigraphic units. Although preservation of older names takes priority in stratigraphic nomenclature (NACSN, 2021, Article 7), some do not have adequately defined stratotypes or are located a distance away with different lithologies than that in the study area. Biostratigraphy can be a helpful tool for understanding correlations and facies changes. Herein, conodont biostratigraphy is utilized to date and correlate separate lithologic units. Further, microfacies analyses of units through inspection of petrographic thin sections provide paleogeographic information that helps in understanding the genesis of geologic units.

New York, Vermont

Geologic Map of the Kings Mountain and Grover Quadrangles, Cleveland and Gaston Counties, North Carolina, and Cherokee and York Counties, South Carolina

This geologic map of the Kings Mountain and Grover 7.5-min quadrangles, N.C.-S.C., straddles a regional geological boundary between the Inner Piedmont and Carolina terranes. The Kings Mountain sequence (informal name) on the western flank of the Carolina terrane in this area includes the Neoproterozoic Battleground and Blacksburg Formations. The Battleground Formation has a lower part consisting of metavolcanic rocks and interlayered schist and an upper part consisting of quartz-sericite phyllite and schist interlayered with quartz-pebble metaconglomerate, aluminous quartzite, micaceous quartzite, manganiferous rock, and metavolcanic rocks. The Blacks-burg Formation consists of phyllitic metasiltstone interlayered with thinner units of marble, laminated micaceous quartzite, hornblende gneiss, and amphibolite. Layered metamorphic rocks of the Inner Piedmont terrane include muscovite-biotite gneiss, muscovite schist, and amphibolite. The Kings Mountain sequence has been intruded by metatonalite and metatrondhjemite (Neoproterozoic), metagabbro and metadiorite (Paleozoic?), and the High Shoals Granite (Pennsylvanian). Layered metamorphic rocks of the Inner Piedmont in this area have been intruded by the Toluca Granite (Ordovician?), the Cherryville Granite and associated pegmatite (Mississippian), and spodumene pegmatite (Mississippian). Diabase dikes (early Jurassic) are locally present throughout the area. Ductile fault zones of regional scale include the Kings Mountain and Kings Creek shear zones. In this area, the Kings Mountain shear zone forms the boundary between the Inner Piedmont and Carolina terranes, and the Kings Creek shear zone separates the Battleground Formation from the Blacksburg Formation. Structural styles change across the Kings Mountain shear zone from steeply dipping layers, foliations, and folds on the southeast to gently and moderately dipping layers, foliations, and recumbent folds on the northwest. Mineral assemblages in the Kings Mountain sequence show a westward decrease from upper amphibolite facies (sillimanite zone) near the High Shoals Granite in the eastern side of the map area to upper greenschist (epidote-amphibolite) facies in the south-central part of the area near the Kings Mountain shear zone. Amphibolite-facies mineral assemblages in the Inner Piedmont terrane increase in grade from the kyanite zone near the Kings Mountain shear zone to the sillimanite zone in the northwestern part of the map area. Surficial deposits include alluvium in the stream valleys and colluvium along ridges and steep slopes. These quadrangles are unusual in the richness and variety of the mineral deposits that they contain, which include spodumene (lithium), cassiterite (tin), mica, feldspar, silica, clay, marble, kyanite and sillimanite, barite, manganese, sand and gravel, gold, pyrite, and iron.

Scientific Investigations Map

Bedrock geologic map of the Hartland and North Hartland quadrangles, Windsor County, Vermont, and Sullivan and Grafton Counties, New Hampshire

The bedrock geology of the 7.5-minute Hartland and North Hartland quadrangles, Vermont-New Hampshire, consists of highly deformed and metamorphosed lower Paleozoic metasedimentary, metavolcanic, and metaplutonic rocks of the Bronson Hill anticlinorium (BHA) and the Connecticut Valley trough (CVT). Rocks of the Orfordville anticlinorium on this map occupy the western part of the broader BHA. In the BHA, the Ordovician Ammonoosuc Volcanics and graphitic, sulfidic metapelite of the Partridge Formation are intruded by Ordovician plutonic rocks of the Oliverian Plutonic Suite. The Ordovician rocks are collectively referred to as the Bronson Hill arc. The Ordovician rocks are overlain by the Silurian to Devonian Clough, Fitch, and Littleton Formations. On this map, rocks of the CVT occupy the eastern part of the broader CVT. In the CVT in Vermont, the Silurian to Devonian Shaw Mountain, Waits River, and Gile Mountain Formations form an unconformable autochthonous to parautochthonous cover sequence on the pre-Silurian rocks of the Rowe-Hawley zone above Precambrian basement rocks of the Mount Holly Complex. On this map, however, only the Waits River and Gile Mountain Formations are exposed. Syn- to postmetamorphic rocks include quartz veins and Cretaceous dikes of the White Mountain Igneous Suite. Rocks of the BHA occur in a thrust sheet floored by the Monroe fault, which carried a deformed section of plutonic rocks, Ammonoosuc Volcanics, Partridge Formation, Clough Quartzite, and the Fitch and Littleton Formations. The Monroe thrust sheet placed the BHA rocks over the CVT during an early Acadian F 1 nappe-stage event prior to peak metamorphism at lower amphibolite facies conditions. Upper and lower plate truncations, mylonite, and local mélange characterize the Monroe fault. F 2 doming deformed the Monroe thrust sheet, folded earlier isograds, and created the Meriden antiform and Lebanon dome. Lower greenschist facies (Acadian to Alleghanian) faults such as the Sumner Falls shear zone truncated peak-metamorphic assemblages, isograds, and older F 1 folds and faults. Late-stage F 3 folds show preferred left-lateral rotation sense and are probably related to late dome-stage Alleghanian deformation or motion along lower greenschist facies faults. The youngest deformation is characterized by Mesozoic brittle faulting and spatially associated kink bands along the Ammonoosuc fault zone, followed by subsequent jointing. Currently major economic natural resource activities are related to aggregate quarrying in the Ammonoosuc Volcanics at Twin State Sand and Gravel in Hartford, Vt., and Lebanon Crushed Stone in Lebanon, N.H. This report consists of sheets 1 and 2 as well as an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, structural geologic information, and photographs. Sheet 2 of this report shows three cross sections, a tectonic map, and two brittle features maps that show measured outcrop-scale strike and dip results with summary stereonets and rose diagrams.

New Hampshire, Vermont

Geologic map of the Buckner 7.5-Minute quadrangle, Louisa County, Virginia

The Buckner 7.5-minute quadrangle straddles three terrane boundaries in the Piedmont Physiographic Province in central Virginia: the Chopawamsic terrane, the Elk Hill Complex, and the Goochland terrane. In much of the map area, the Elk Hill Complex separates the Chopawamsic and Goochland terranes. Rocks of the Chopawamsic terrane include Ordovician metavolcanic and metasedimentary rocks of the Chopawamsic Formation, Ordovician to Silurian granodiorite sheet intrusions, and Paleozoic mafic intrusions. Silurian to Devonian rocks of the Quantico Formation, mostly garnet-mica schist, crop out in the northwesternmost part of the map area, and are in unconformable contact with rocks of the Chopawamsic Formation on the southeastern limb of the Quantico synclinorium. The main map unit in the Elk Hill Complex is Neoproterozoic mica gneiss, which is in pre-metamorphic fault contact with rocks of the Chopawamsic Formation to the west. The main map unit of the Goochland terrane is the Maidens Gneiss. Except for Jurassic diabase dikes, all rocks on the Buckner 7.5-minute quadrangle were metamorphosed to amphibolite facies during the Alleghanian orogeny and preserve multiple compositional and phyllosilicate penetrative foliations. Evidence of amphibolite-facies metamorphism during the Taconic orogeny is preserved in rocks of the Elk Hill Complex. The entire width of the Maidens Gneiss on the Buckner 7.5-minute quadrangle is within the Spotsylvania high-strain zone and amphibolite-facies mylonitic textures are pervasive. Quartz veins and Jurassic diabase dikes crosscut all older rocks of the quadrangle. Multiple levels of terrace deposits are present along and near the major streams of the quadrangle. The lower terrace deposits are likely remnants of former positions of the Little River on the landscape, whereas higher deposits may be remnants of former deposits of the Atlantic Coastal Plain that covered this portion of the Piedmont Province. A linear cluster of aftershocks from the magnitude 5.8 earthquake that occurred near Mineral, Virginia, in 2011 defines the Fredericks Hall fault, which is at depth on the Buckner quadrangle. Most of the aftershocks occurred in the core of the Elk Creek antiform and have no relation to faults mapped at the surface. Several abandoned crushed stone and building stone quarries, as well as a mica prospect, exist in the quadrangle.

Virginia

Stratigraphy and tectonic history of the Tucson Basin, Pima County, Arizona, based on the Exxon state (32)-1 well

The Tucson Basin is a relatively large late Cenozoic extensional basin developed in the upper plate of the Catalina detachment fault in the southern Basin and Range Province, southeastern Arizona. In 1972, Exxon Company, U.S.A., drilled an exploration well (Exxon State (32)-1) near the center of the Tucson Basin that penetrated 3,658 m (12,001 ft) of sedimentary and volcanic rocks above granitoid basement. Detailed study of cuttings and geophysical logs of the Exxon State well has led to revision of the previously reported subsurface stratigraphy for the basin and provided new insight into its depositional and tectonic history. There is evidence that detachment faulting and uplift of the adjacent Catalina core complex on the north have affected the subsurface geometry of the basin. The gravity anomaly map of the Tucson Basin indicates that the locations of subbasins along the north-trending axis of the main basin coincide with the intersection of this axis with west-southwest projections of synforms in the adjacent core complex. In other words, the subbasins overlie synforms and the ridges between subbasins overlie antiforms. The Exxon State well was drilled near the center of one of the subbasins. The Exxon well was drilled to a total depth of 3,827 m (12,556 ft), and penetrated the following stratigraphic section: Pleistocene(?) to middle(?) Miocene upper basin-fill sedimentary rocks (0-908 m [0-2,980 ft]) lower basin-fill sedimentary rocks (908-1,880 m [2,980-6,170 ft]) lower Miocene and upper Oligocene Pantano Formation (1,880-2,516 m [6,170-8,256 ft]) upper Oligocene to Paleocene(?) volcanic and sedimentary rocks (2,516-3,056 m [8,256-10,026 ft]) Lower Cretaceous to Upper Jurassic Bisbee Group (3,056-3,658 m [10,026-12,001 ft]) pre-Late Jurassic granitoid plutonic rock (3,658-3,827 m [12,001- 12,556 ft]). Stratigraphy and Tectonic History of the Tucson Basin, Pima County, Arizona, Based on the Exxon State (32)-1 Well The 1,880 m (6,170 ft) of basin-fill sedimentary rocks consist of alluvial-fan, alluvial-plain, and playa facies. The uppermost unit, a 341-m-thick (1,120-ft) lower Pleistocene and upper Pliocene alluvial-fan deposit (named the Cienega Creek fan in this study), is an important aquifer in the Tucson basin. The facies change at the base of the alluvial fan may prove to be recognizable in well data throughout much of the basin. The well data show that a sharp boundary at 908 m (2,980 ft) separates relatively unconsolidated and undeformed upper basin fill from denser, significantly faulted lower basin fill, indicating that there were two stages of basin filling in the Tucson basin as in other basins of the region. The two stages apparently occurred during times of differing tectonic style in the region. In the Tucson area the Pantano Formation, which contains an andesite flow dated at about 25 Ma, fills a syntectonic basin in the hanging wall of the Catalina detachment fault, reflecting middle Tertiary extension on the fault. The formation in the well is 636 m thick (2,086 ft) and consists of alluvial-fan, playa, and lacustrine sedimentary facies, a lava flow, and rock- avalanche deposits. Analysis of the geophysical logs indicates that a K-Ar date of 23.4 Ma reported previously for the Pantano interval of the well was obtained on selected cuttings collected from a rock-avalanche deposit near the base of the unit and, thus, does not date the Pantano Formation. The middle Tertiary volcanic and sedimentary rocks have an aggregate thickness of 540 m (1,770 ft). We obtained a new 40Ar/ 39Ar age of 26.91+0.18 Ma on biotite sampled at a depth of 2,584-2,609 m (8,478-8,560 ft) from a 169-m-thick (554-ft) silicic tuff in this interval. The volcanic rocks probably correlate with other middle Tertiary volcanic rocks of the area, and the sedimentary rocks may correlate with the Cloudburst and Mineta Formations exposed on the flanks of the San Pedro Basin to the northeast. The Bisbee Group in the Exxon well is 602 m (1,975 f

Scientific Investigations Report

Assessment of undiscovered copper resources associated with the Permian Kupferschiefer, Southern Permian Basin, Europe

This study synthesizes available information and estimates the location and quantity of undiscovered copper associated with a late Permian bituminous shale, the Kupferschiefer, of the Southern Permian Basin in Europe. The purpose of this study is to (1) delineate permissive areas (tracts) where undiscovered reduced-facies sediment-hosted stratabound copper deposits could occur within 2.5 kilometers of the surface, (2) provide a database of known reduced-facies-type sediment-hosted stratabound copper deposits and significant prospects, and (3) provide probabilistic estimates of amounts of undiscovered copper that could be present within each tract. This assessment is a contribution to a global assessment conducted by the U.S. Geological Survey (USGS). Permissive tracts are delineated by mapping the extent of the Kupferschiefer that overlies reservoir-facies red beds of the lower Permian Rotliegend Group. More than 78 million metric tons (Mt) of copper have been produced or delineated as resources in the assessed tracts, with more than 90 percent of the known mineral endowment located in Poland. Mines in Poland are developing the deposit at depths ranging from about 500 to 1,400 meters. Two approaches are used to estimate in-situ amounts of undiscovered copper. The three-part form of assessment was applied to the entire study area. In this approach, numbers of undiscovered deposits are estimated and combined with tonnage-grade models to probabilistically forecast the amount of undiscovered copper. For Poland, drill-hole data were available, and Gaussian geostatistical simulation techniques were used to probabilistically estimate the amount of undiscovered copper. The assessment was done in September 2010 using a three-part form of mineral resource assessment and in January 2012 using Gaussian geostatistical simulation. Using the three-part form of assessment, a mean of 126 Mt of undiscovered copper is predicted in 4 assessed permissive tracts. Seventy-five percent of the mean amount of undiscovered copper (96 Mt) is associated with a tract in southwest Poland. For this same permissive tract in Poland, Gaussian geostatistical simulation techniques indicate a mean of 62 Mt of copper based on copper surface-density data from drill holes.

Scientific Investigations Report

Three-dimensional seismic characterization of karst in the Floridan aquifer system, southeastern Miami-Dade County, Florida

Two three-dimensional seismic surveys totaling 3.4 square miles were acquired in southeastern Miami-Dade County during 2015 as part of an ongoing broad regional investigation by the U.S. Geological Survey, in cooperation with the Miami-Dade Water and Sewer Department, that includes mapping and karst characterization of the Floridan aquifer system in southeastern Florida. Twenty columniform seismic-sag structures were identified in the three-dimensional seismic data acquired at the South Miami Heights study area in Miami-Dade County, Florida. The seismic-sag structures are commonly composed of a lower and upper seismic facies, where the lower facies is interpreted to be a high permeability column-shaped volume of intense karstification composed of faults, fractures, and collapsed caves, and the upper facies is interpreted to be a lower permeability column-shaped volume composed of sagging suprastratal reflections having little or no faulting, fracturing, or caves. The seismic-sag structures are columniform karst-collapse structures that formed by cave collapse or stoping (upward void migration caused primarily by the mechanical process of ceiling collapse) or both in carbonate rocks of the early Eocene Oldsmar Formation and in some cases in the lowermost part of the middle Eocene Avon Park Formation. Columniform subsidence and sagging of overburden succeeded karst collapse in the lower part of the structures. At the study area, there may be relatively higher potential for the columniform karst-collapse structures to provide cross-formational fluid migration upward from the Boulder Zone into the lower part of middle confining unit 2 as compared to a lower potential for cross-formational fluid migration from the upper part of middle confining unit 2 upward to the Upper Floridan aquifer.

Florida

Background and geologic model for the 2024 U.S. Geological Survey assessment of undiscovered conventional petroleum resources in the Norphlet Formation, U.S. Gulf Coast

The Upper Jurassic Norphlet Formation is a stratigraphic unit located in the subsurface of the United States Gulf coastal plain and offshore Gulf of America (Gulf of Mexico). The Norphlet consists of clastic sediments derived from the southern Appalachian highlands, and was deposited in a continental dryland setting on the margins of the early Gulf of America rift basin. The formation contains a variety of sedimentary facies, including facies representing updip alluvial fans, wadis, red beds, and a widespread erg, or eolian sand sea. The erg facies form the primary reservoirs from which hydrocarbons sourced from the overlying Smackover Formation are produced. Development of the Norphlet began in earnest in the late 1960s, with new discoveries, including large fields at Flomaton, Hatters Pond, and Mobile Bay, continuing through the 2000s–2010s with the discovery of major oil fields in the offshore Desoto Canyon area. Onshore, Norphlet hydrocarbon traps typically are faulted salt anticlines, although many fields also have a stratigraphic trapping component because of the preservation of dune-scale bedforms. Thermal maturity across the Norphlet play varies significantly with depth, resulting in oil production transitioning downdip to natural gas liquids production, then dry gas production; production depths reach to greater than 21,000 feet. A 2024 U.S. Geological Survey assessment divided the Norphlet into four conventional assessment units defined by the type and frequency of trapping mechanisms, sedimentology, and thermal maturity of each area, with little potential for hydrocarbon development observed west of the Mississippi River. Although petroleum resources in the Norphlet were revised downward, it is probable that significant resources remain to be discovered.

Alabama, Florida, Mississippi