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At least 307 records · Page 17Linked to original sources

Transmissivity estimated from brief aquifer tests of domestic wells and compared with bedrock lithofacies and position on hillsides in the Appalachian Plateau of New York

Procedures for undertaking and analyzing recovery from aquifer tests of 13 to 132 seconds (described in reports cited herein) were applied to 51 domestic drilled wells that penetrated bedrock outside major valleys in the part of the Appalachian Plateau of New York drained by the Susquehanna River. Transmissivities calculated from these tests ranged over three orders of magnitude in both the Catskill-Cattaraugus lithofacies (shales, mudstones, siltstones, medium to coarse sandstones, pebbly sandstones) and the Chemung-Hamilton lithofacies (shales, mudstones, siltstones, fine to medium sandstones). Median transmissivity values were 0.000425 foot squared per second (36.7 feet squared per day) in the Catskill-Cattaraugus lithofacies and 0.00055 foot squared per second (47.5 feet squared per day) in the Chemung-Hamilton lithofacies. The distributions of transmissivity values within the two lithofacies were likewise similar. The range and median values of transmissivity were also nearly the same on lower and midlevel hillsides and were only slightly greater on a few upper hillsides. Transmissivities estimated from such easily arranged and analyzed tests may be appropriate for estimating groundwater flux under the small gradients that prevail under natural conditions, but not under larger drawdowns and steeper gradients near clusters of domestic wells. Four of the 51 wells tested were also pumped for 10 to 32 minutes; analysis by the Theis recovery method yielded transmissivities consistent with the brief tests for 2 wells, but 7 to 9 times smaller for 2 wells. Transmissivity values estimated by the PICKINGmodel were not significantly different from values estimated by an automated application of the Picking method (PPC-Recovery) at a probability of 95 percent. Transmissivities calculated by either method from data for time intervals of 120 seconds or less may be of limited practical value because they apply only to a small volume of bedrock close to the pumped well.

New York

Groundwater quality and simulation of sources of water to wells in the Marsh Creek valley at the U.S. Geological Survey Northern Appalachian Research Laboratory, Tioga County, Pennsylvania

This report provides a November 2010 snapshot of groundwater quality and an analysis of the sources of water to wells at the U.S. Geological Survey (USGS) Northern Appalachian Research Laboratory (NARL) near Wellsboro, Pennsylvania. The laboratory, which conducts fisheries research, currently (2011) withdraws 1,000 gallons per minute of high-quality groundwater from three wells completed in the glacial sand and gravel aquifer beneath the Marsh Creek valley; a fourth well that taps the same aquifer provides the potable supply for the facility. The study was conducted to document the source areas and quality of the water supply for this Department of Interior facility, which is surrounded by the ongoing development of natural gas from the Marcellus Shale. Groundwater samples were collected from the four wells used by the NARL and from two nearby domestic-supply wells. The domestic-supply wells withdraw groundwater from bedrock of the Catskill Formation. Samples were analyzed for major ions, nutrients, trace metals, radiochemicals, dissolved gases, and stable isotopes of oxygen and hydrogen in water and carbon in dissolved carbonate to document groundwater quality. Organic constituents (other than hydrocarbon gases) associated with hydraulic fracturing and other human activities were not analyzed as part of this assessment. Results show low concentrations of all constituents. Only radon, which ranged from 980 to 1,310 picocuries per liter, was somewhat elevated. These findings are consistent with the pristine nature of the aquifer in the Marsh Creek valley, which is the reason the laboratory was sited at this location. The sources of water and areas contributing recharge to wells were identified by the use of a previously documented MODFLOW groundwater-flow model for the following conditions: (1) withdrawals of 1,000 to 3,000 gallons per minute from the NARL wells, (2) average or dry hydrologic conditions, and (3) withdrawals of 1,000 gallons per minute from a new well 3,500 feet to the southwest that was drilled to provide water for Marcellus gas-well operations. Results of simulations indicate that during average hydrologic conditions, infiltration from Straight Run, a tributary to Marsh Creek, provides nearly all the water to the NARL wells. During dry conditions, the areas contributing recharge expand such that Asaph Run contributes about half of the water to the NARL wells when withdrawals are 1,000 or 2,000 gallons per minute. The addition of a simulated withdrawal of 1,000 gallons per minute from the nearby new well does not substantially affect the sources of water captured by the NARL wells. These results are subject to some limitations. The water-quality samples represent a snapshot of groundwater chemistry for only one hydrologic condition; the concentrations of some constituents may change temporally. In addition, samples were collected and analyzed for hydrocarbon gases, but not organic constituents associated with hydraulic fracturing; additional sampling for these constituents would provide a more complete water-quality baseline. The sources contributing water to the NARL wells and the new well were simulated by use of a simplified one-layer model of the glacial sand and gravel aquifer for steady-state conditions that in reality are never achieved. Steady-state simulations of dry hydrologic conditions show that it is possible for the NARL wells to capture water from Asaph Run; however, maps of simulated groundwater time-of-travel indicate that a dry period of unusually long duration would be required. A better analysis could be done by recalibrating the groundwater-flow model with a finite-difference grid having multiple layers, cells smaller than the 200-foot by 200-foot cells used in this study, and transient stress periods.

Pennsylvania

Analytical framework to estimate water use associated with continuous oil and gas development

An analytical framework was designed to estimate water use associated with continuous oil and gas (COG) development in support of the U.S. Geological Survey Water Availability and Use Science Program. This framework was developed to better understand the relation between the production of COG resources for energy and the amount of water needed to sustain this type of energy development in the United States. The total mean undiscovered, technically recoverable volume of COG has increased, highlighting the continued need to develop approaches to better characterize water use associated with COG development. The analytical framework can be used to estimate water use associated with COG development for three water-use components—direct, indirect, and ancillary water use—that are related to the life cycle of COG development. Direct water use is defined as water used in a wellbore to complete a well, including the water used for drilling, cementing, stimulating, and maintaining the well during production. Indirect water use is the water used at or near the well site, including water used for dust abatement, for cleaning equipment, and for crew and staff use. Ancillary water use is all other water used during the life cycle of COG development that is not categorized as direct or indirect, such as additional local or regional water use resulting from a change (for example, population) related to COG development. The analytical framework includes the data inputs, the processes involved in estimating the water-use coefficients and analyzing their uncertainties, and the outputs. The analytical framework was developed as an R script, which contains the statistical models used to estimate water-use components. The availability of data across COG reservoirs in the United States is variable and presents challenges for estimating water use for extracting COG from their reservoirs; thus, the R script can be modified for the types of data available within a COG reservoir, the extent and resolution of data available for each water-use component, and the desired output of the water-use assessment. The script was written so that the units of the data in the script were standardized. Water-use estimates were simulated for the mean and 10th, 50th, and 90th percentiles of the data distributions. Uncertainties were quantified with confidence intervals for the estimated coefficients. Uncertainty for estimated or simulated data can be calculated with the R script by providing a range of representative values that are within the appropriate confidence intervals of the mean of the data.

Lower 48 states

Land Disturbance Associated with Oil and Gas Development and Effects of Development-Related Land Disturbance on Dissolved-Solids Loads in Streams in the Upper Colorado River Basin, 1991, 2007, and 2025

Oil and gas resource development in the Upper Colorado River Basin (UCRB) has increased substantially since the year 2000. The UCRB encompasses several significant oil and gas producing areas that have the potential for continued oil and gas resource development. Land disturbance associated with oil and gas resource development is caused by activities related to constructing drill pads to contain drilling and well maintenance equipment and roads to access the drill pad. Land disturbed by oil and gas development has the potential to cause increased erosion, stream degradation, habitat fragmentation and alteration, and increase public use of areas that may be environmentally sensitive. Land disturbance resulting from oil and gas resource development has not been monitored and mapped on a regional scale in the UCRB. However, information on the location and age of oil and gas wells in the UCRB is available. These data combined with geographic data analysis and modeling techniques were used to estimate the total area of disturbed land associated with oil and gas resource development in 1991 and in 2007 in the UCRB. Additional information about anticipated oil and gas development in the UCRB was used to project land disturbance to the year 2025. Results of the analysis indicate that approximately 117,500 acres (183 mi2) of total land disturbance was associated with drill pads and related roads in the UCRB in 1991. The estimated area of disturbed land associated with oil and gas development increased 53 percent to 179,400 acres (280 mi2) in 2007. Projecting oil and gas development through 2025 results in a potential near doubling of the land surface disturbance to approximately 319,300 acres (500 mi2). Estimated land disturbance for 1991 and 2007 were input to a contaminant transport model developed for the UCRB to assess the statistical significance of energy-related land disturbance to contributing dissolved solids to basin streams. The statistical assessment was an observational study based on an existing model and available water-quality monitoring data for the basin. No new data were collected for the analysis. The source coefficient calibrated for the disturbed lands associated with oil and gas development in 2007 was zero, which indicated that estimated land disturbance from oil and gas development is not statistically significant in explaining dissolved solids in UCRB streams. The lack of significance in the contaminant transport modeling framework may be due to the amount of available monitoring data, the spatial distribution of monitoring sites with respect to land disturbance, or the overall quantity of land disturbance associated with oil and gas development basin wide. Finally, dissolved-solids loads derived from natural landscapes may be similar to loads derived from lands disturbed by oil and gas resource development. The model recalibration done for this study confirms calibration results from Kenney and others (2009): the most significant contributor to dissolved solids in the UCRB is irrigated agricultural land, which covers an area substantially larger than the estimated area disturbed by oil and gas development and is subjected to artificially applied water.

Scientific Investigations Report

Characterization of the hydrologic resources of San Miguel County, New Mexico, and identification of hydrologic data gaps, 2011

The U.S. Geological Survey (USGS), in cooperation with San Miguel County, New Mexico, conducted a study to assess publicly available information regarding the hydrologic resources of San Miguel County and to identify data gaps in that information and hydrologic information that could aid in the management of available water resources. The USGS operates four continuous annual streamgages in San Miguel County. Monthly discharge at these streamgages is generally bimodally distributed, with most runoff corresponding to spring runoff and to summer monsoonal rains. Data compiled since 1951 on the geology and groundwater resources of San Miguel County are generally consistent with the original characterization of depth and availability of groundwater resources and of source aquifers. Subsequent exploratory drilling identified deep available groundwater in some locations. Most current (2011) development of groundwater resources is in western San Miguel County, particularly in the vicinity of El Creston hogback, the hogback ridge just west of Las Vegas, where USGS groundwater-monitoring wells indicate that groundwater levels are declining. Regarding future studies to address identified data gaps, the ability to evaluate and quantify surface-water resources, both as runoff and as potential groundwater recharge, could be enhanced by expanding the network of streamgages and groundwater-monitoring wells throughout the county. A series of seepage surveys along the lengths of the rivers could help to determine locations of surface-water losses to and gains from the local groundwater system and could help to quantify the component of streamflow attributable to irrigation return flow; associated synoptic water-quality sampling could help to identify potential effects to water quality attributable to irrigation return flow. Effects of groundwater withdrawals on streamflow could be assessed by constructing monitoring wells along transects between production wells and stream reaches of interest to monitor decline or recovery of the water table, to quantify the timing and extent of water-table response, and to identify the spatial extent of capture zones. Assessment of groundwater potential could be aided by a county-wide distribution of water-level information and by a series of maps of groundwater potential, compiled for each individual aquifer, including saline aquifers, for which the potential for municipal use through desalination could be explored. A county-wide geographic information system hydrologic geodatabase could provide a comprehensive picture of water use in San Miguel County and could be used by San Miguel County as a decision-support tool for future management decisions.

New Mexico

Geology and undiscovered resource assessment of the potash-bearing, Middle Devonian (Givetian), Prairie Evaporite, Elk Point Basin, Canada and United States

The U.S. Geological Survey (USGS) assessed undiscovered potash resources in the Elk Point Basin in Canada and the United States as part of a global mineral resource assessment. The Elk Point Basin is a large, Middle Devonian (Givetian) intracratonic evaporite basin covering approximately 1,200,000 square kilometers (km 2 ) and filled mainly with marine evaporite and minor clastic sedimentary rocks that contain stratabound potash-bearing salt. The potash-bearing salt is concentrated in four stratigraphic members (Patience Lake, Belle Plaine, White Bear, and Esterhazy) in the upper 100 meters (m) of the Prairie Evaporite and are separated by beds of halite (NaCl) that contain lesser—presently non-economic—amounts of sylvite (KCl) and carnallite (KMgCl 3 ·6H 2 O). The principal ore-bearing salt contains mainly sylvite. Four permissive tracts were defined that permit the presence of undiscovered stratabound potash (both sylvite- and carnallite-bearing salt) using geological criteria. Permissive tracts are defined by the spatial extent of each stratigraphic member that is at least 1 m thick, are less than 3 kilometers (km) from the surface, contain at least 4 percent equivalent potassium oxide (K 2 O), and contain the currently known resources. The permissive tracts include known potash deposits and potash occurrences as wells or mines not in production and show where undiscovered potash resources may be present. Well data are used to define the extent, thickness, average K 2 O equivalent grades, and volumes of each member. Data were supplied by the Saskatchewan Geological Survey or were obtained from published National Instrument (NI) 43-101 technical reports and other published reports, such as annual 10-K reports or news releases. The Elk Point Basin is the world’s largest source of potash, producing 23.0 million metric tons (Mt) of potassium chloride (KCl) (the equivalent of about 14.4 Mt of K 2 O) in 2018. In terms of global importance, the Elk Point Basin may contain 40 to greater than 50 percent of the world’s potash resources. Since 1962, potash companies have mined more than 1.5 trillion metric tons of ore containing 605 Mt of KCl (the equivalent of about 380 Mt of K 2 O). The total value of the ore produced through 2018 is on the order of $70 trillion (CAD). Potash is currently produced from eight conventional and three underground solution mines at depths ranging from 900 m to nearly 1,800 m. Estimates of the amount of potash in the Elk Point Basin vary considerably and the data and methods used in those estimations are not well documented. Known potash resources are approximately 99 billion metric tons (Bt) of ore containing 22 Bt of K 2 O equivalent. As a result of new mine openings and increased production capacity at existing mines, the total production capacity of mines in the Elk Point Basin has increased significantly (to about 32.8 Mt of KCl or 22.8 Mt of K 2 O equivalent per year). Additional production capacity of about 31 Mt of KCl (or 17 Mt of K 2 O equivalent) per year could be realized over the next decade if several current (as of 2019) exploration and development projects reach production status. Stratabound potash-bearing salt of the Prairie Evaporite presently underlies a total area of about 188,000 km 2 and has a total volume of about 2,690 cubic kilometers (km 3 ). Post-depositional solution processes considerably modified the mineralogy and presence of the potash-bearing salt. These changes had a profound effect on the volume and grade of potash resources that remained in the Prairie Evaporite and are a major consideration of exploration and mining operations as well as in this assessment of undiscovered potash resources. This USGS assessment includes the locations and possible amounts of undiscovered potash resources in the Prairie Evaporite. Volumes for each stratigraphic member were computed using member thicknesses and areal extent modified by actual, estimated geologic loss owing to salt dissolution and extraction ratios, as well as estimated distribution of carnallite and sylvite. Both sylvite- and carnallite-bearing salts were assessed for potash in this study. The assessment uses modern published grade and tonnage data. The amount of undiscovered potash is estimated by using Monte Carlo simulations to combine volume estimates of the potash-bearing members with probability distributions for average grade and bulk density. Mean potash grades (expressed as percentage of K 2 O equivalent) calculated using drill core analyses are 17.76 for the Patience Lake Member, 15.98 for the Belle Plaine Member, 10.66 for the White Bear Member, and 15.30 for the Esterhazy Member. Geologic losses reported as extraction ratios during mining may range from 27.5 to 41.6 percent and are dependent on mining method and local geologic conditions. The assessment determined that mean estimated undiscovered K 2 O equivalent resources for the Patience Lake, Belle Plaine, White Bear, and Esterhazy Members are 340, 220, 34, and 190 Bt, respectively, and estimated a total mean of 790 Bt for the entire Prairie Evaporite above a depth of 3 km. The total mineralized rock tonnage is estimated to be about 5,000 Bt. Most of the assessed potash is located within Saskatchewan with lesser amounts in Alberta and Manitoba as well as Montana and North Dakota within the United States. Although carnallite is mined for potash in Europe, it has historically been avoided in mining plans for potash-producing companies in Saskatchewan because of mining, processing, and grade considerations. Carnallite-rich salt is locally present in concentrations and volumes that could be a significant resource of magnesium chloride (MgCl 2 ) obtained as a byproduct of processing the carnallite for potash. Previously estimated reserves (not NI 43-101 compliant) of mineralized material from 1955 to 2019 are 695 Mt at 22.1 percent MgCl 2 . The total amount of K 2 O equivalent as carnallite was estimated during this USGS assessment to be about 120 Bt (or 180 Bt KCl). With uncertainties in defining the areal extent of carnallite in each of the potash-bearing members, the amount of MgCl 2 as carnallite in the Elk Point Basin could be approximately 180 Bt.

Elk Point basin

Sandstone copper assessment of the Chu-Sarysu Basin, Central Kazakhstan: Chapter E in Global mineral resource assessment

Mineral resource assessments represent a synthesis of available information to estimate the location, quality, and quantity of undiscovered mineral resources in the upper part of the Earth’s crust. This report presents a probabilistic mineral resource assessment of undiscovered sandstone copper deposits within the late Paleozoic Chu-Sarysu Basin in central Kazakhstan by the U.S. Geological Survey as a contribution to a global assessment of mineral resources. The purposes of this study are to: (1) provide a database of known sandstone copper deposits and significant prospects in this area, (2) delineate permissive areas (tracts) for undiscovered sandstone copper deposits within 2 km of the surface at a scale of 1:1,000,000, (3) estimate numbers of undiscovered deposits within these permissive tracts at several levels of confidence, and (4) provide probabilistic estimates of amounts of copper (Cu), silver (Ag), and mineralized rock that could be contained in undiscovered deposits within each tract. The assessment uses the three-part form of mineral resource assessment based on mineral deposit models (Singer, 1993; Singer and Menzie, 2010). Delineation of permissive tracts for resources is based on the distribution of a Carboniferous oxidized nonmarine clastic (red bed) stratigraphic sequence that lies between overlying Permian and underlying Devonian evaporite-bearing sequences. Subsurface information on the extent and depth of this red bed sequence and structural features that divide the basin into sub-basins was used to define four permissive tracts. Structure contour maps, mineral occurrence databases, drill hole lithologic logs, geophysical maps, soil geochemical maps, locations of producing gas fields, and evidence for former gas accumulations were considered in conjunction with descriptive deposit models and grade and tonnage models to guide the assessment team’s estimates of undiscovered deposits in each tract. The four permissive tracts are structural sub-basins of the Chu-Sarysu Basin and range in size from 750 to 65,000 km². Probabilistic estimates of numbers of undiscovered sandstone copper deposits were made for the four tracts by a group of experts. Using these probabilistic estimates, Monte Carlo simulation was used to estimate the amount of metal contained within each tract. The results of the simulation serve as the basis for estimates of the metal endowment. The team estimates that 26 undiscovered deposits occur within the Chu-Sarysu Basin, and that these deposits contain an arithmetic mean of at least 21.5 million metric tons (Mt) of copper and 21,900 metric tons (t) of silver. The undiscovered deposits are in addition to the 7 known deposits that contain identified resources of 27.6 Mt of copper. Sixty percent of the estimated mean undiscovered copper resources are associated with the two permissive tracts that contain the identified resources; the remaining estimated resources are associated with the two tracts that have no known deposits. For the three tracts that contain 95 percent of the estimated undiscovered copper resources, the probability that each tract contains its estimated mean or more is about 40 percent. For the tract with 5 percent of the estimated undiscovered cop-per resources, the probability that it contains that amount or more is 25 percent.

Chu-Sarysu Basin

Rates of evapotranspiration, recharge from precipitation beneath selected areas of native vegetation, and streamflow gain and loss in Carson Valley, Douglas County, Nevada, and Alpine County, California

Rapid growth and development in Carson Valley is causing concern over the continued availability of water resources to sustain such growth into the future. A study to address concerns over water resources and to update estimates of water-budget components in Carson Valley was begun in 2003 by the U.S. Geological Survey, in cooperation with Douglas County, Nevada. This report summarizes micrometeorologic, soil-chloride, and streambed-temperature data collected in Carson Valley from April 2003 through November 2004. Using these data, estimates of rates of discharge by evapotranspiration (ET), rates of recharge from precipitation in areas of native vegetation on the eastern and northern sides of the valley, and rates of recharge and discharge from streamflow infiltration and seepage on the valley floor were calculated. These rates can be used to develop updated water budgets for Carson Valley and to evaluate potential effects of land- and water-use changes on the valley's water budget. Data from eight ET stations provided estimates of annual ET during water year 2004, the sixth consecutive year of a drought with average or below average precipitation since 1999. Estimated annual ET from flood-irrigated alfalfa where the water table was from 3 to 6 feet below land surface was 3.1 feet. A similar amount of ET, 3.0 feet, was estimated from flood-irrigated alfalfa where the water table was about 40 feet below land surface. Estimated annual ET from flood-irrigated pasture ranged from 2.8 to 3.2 feet where the water table ranged from 2 to 5 feet below land surface, and was 4.4 feet where the water table was within 2 feet from land surface. Annual ET estimated from nonirrigated pasture was 1.7 feet. Annual ET estimated from native vegetation was 1.9 feet from stands of rabbitbrush and greasewood near the northern end of the valley, and 1.5 feet from stands of native bitterbrush and sagebrush covering alluvial fans along the western side of the valley. Uncertainty in most ET estimates is about 12 percent, but ranged from +30 and +50 percent to -20 and -40 percent for nonirrigated pasture and native bitterbrush and sagebrush. Estimated rates for water year 2004 likely are less than those during years of average, or above average precipitation when the water table would be closer to land surface. Test holes drilled in areas of native vegetation on the northern and eastern sides of Carson Valley had high concentrations of soil chloride at depths ranging from 4 to 18 feet below land surface at six locations on the eastern side of the valley. The high chloride concentrations indicate that modern-day precipitation at the six locations does not percolate deeper than the root zone of native vegetation. Estimates of the time required to accumulate the measured amount of chloride to depths of about 30 feet below land surface at the six test holes ranged from about 3,000 to 12,000 years. Low concentrations of soil chloride in two test holes on the northern end of Carson Valley and in a test hole on the eastern side of Fish Spring Flat indicate that a small amount of recharge from modern-day precipitation is taking place. Estimated annual recharge from precipitation at the two locations was 0.03 and 0.04 foot on the northern end of the valley and 0.02 foot on the eastern side of Fish Spring Flat. Uncertainty in the estimated recharge rates was about ?0.01 foot. Estimates of the time required to accumulate the measured amount of chloride to depths of about 30 feet below land surface at the three test holes ranged from about 100 to 700 years. The two test holes near the northern end of the valley are in gravel and eolian sand deposits and recharge from precipitation may be taking place at similar rates in other areas with gravel and eolian sand deposits. Based on results from other test holes, recharge at the rate estimated for the test hole on the eastern side of Fish Spring Flat is not likely applicable to a large area. Data from 37 site

Scientific Investigations Report

Critical minerals in subduction-related magmatic-hydrothermal systems of the United States

During the World War and Cold War eras (1910s–1990s), domestic consumption of numerous mineral commodities relied increasingly on imported supplies. Consumption reliance has since expanded to include 50 “critical minerals” (elements and mineral commodities) that are mostly to entirely imported and subject to curtailment by suppliers or supply chain disruption. New domestic supplies of critical minerals are being pursued by mining companies and by several federal departments and agencies. Information on domestic deposits and resources of critical minerals is being compiled by the U.S. Geological Survey Mineral Resources Program, which has organized investigations by mineral system, deposit type, and commodity. Production, reserves, resources, and inventories of 21 critical minerals in domestic magmatic-hydrothermal deposits related to subduction-generated magmatism, and in tailings, slag, slimes, and electrolyte from copper concentrators, smelters, and refineries that processed some deposits, are largely restricted to Western States and Alaska. The critical mineral commodities Al, Sb, As, Bi, Co, fluorite, Ga, Ge, In, Mn, Ni, Nb, Pd, Pt, potash, Re, Ta, Te, Sn, W, and V are variably concentrated in porphyry/skarn copper-(molybdenum), skarn-replacement-vein (S-R-V) tungsten, polymetallic sulfide S-R-V intermediate sulfidation (IS), high-sulfidation gold-silver, low-sulfidation gold-silver, and lithocap alunite deposit types. These deposit types occur in porphyry copper-molybdenum-gold, alkalic porphyry, porphyry tin (granite related), and reduced intrusion-related mineral systems. Production, reserves, and resources of Co, Ni, Nb, Pd, Pt, Ta, Sn, and V in subduction-related deposits in Western States are insignificant to small, mostly equivalent to months to a few years of recent annual domestic consumption (2016–2020). Significant inventories, equivalent to 2 or more years of consumption of aluminum, antimony, potash, and tungsten in unmined S-R-V tungsten, polymetallic sulfide S-R-V-IS, and lithocap alunite deposits vary from approximately 2 to 8 years. Several decades of consumption of arsenic, bismuth, fluorite, gallium, germanium, and indium exist in some polymetallic sulfide S-R-V-IS and lithocap alunite deposit types. Based on concentrations of critical minerals in reserves, resources, drill holes, and deposit domains (ore types), and in captive refinery records, the largest domestic inventories of Sb, As, Bi, Re, and Te, and possibly Ga, Ge, In, Sn, and W, are in porphyry copper-molybdenum (Cu-Mo) deposits in Alaska, Idaho, Utah, and Arizona, and in interim products of processing porphyry Cu-Mo deposit ores for recovery of copper and molybdenum. Concentrations of critical minerals in archival specimens and sample collections, although somewhat biased by collection and conservation decisions and categorization, are broadly proportionate to those in reserves, resources, and drill holes. These concentrations imply significant inventories of some critical minerals in deposits for which production, resources, and refinery records are unavailable or incomplete. Because of the large masses of ores mined and processed annually (hundreds of millions of metric tons) and in reserves and resources (hundreds of millions of metric tons to billions of metric tons), calculated inventories of critical minerals in porphyry Cu-Mo deposits are equivalent to decades and centuries of recent consumption. However, these inventories should not be considered consumable supplies without reserve definition and development of economically viable mining plans and recovery techniques. An expeditious strategy for elimination or reduction of import reliance is recovery, and improved recovery efficiency, of Sb, As, Bi, Re, and Te, and possibly Ga, Ge, In, Ni, Sn, Ti, and W; during concentration and refining of copper and molybdenum minerals in ores of operating porphyry Cu-Mo mines; and in unmined porphyry Cu-Mo resources. These chalcophile, siderophile, and lithophile critical minerals, often undetectable in ore, are concentrated (hundreds of parts per million to percents) in slimes and electrolyte during copper electrorefining or could be recovered, in part, during sulfide concentration and smelting. Other than rhenium (recovered during molybdenum refining) and tellurium, all have been routinely discarded. Subsidization (for example, commodity price guarantees, tax credits, recovery technology development), political initiative, and (or) sustained market favorability could support new production of critical mineral commodities from subduction-related magmatic-hydrothermal deposits in Western States. In addition, insufficient domestic refining capacity could relegate the large inventories of critical minerals in porphyry Cu-Mo reserves and resources (for example, Pebble, Alaska; Resolution and Copper World [Rosemont], Arizona) to exportation in concentrates and importation insecurity, fortifying their present status.

Scientific Investigations Report

Ground-water flow directions and estimation of aquifer hydraulic properties in the lower Great Miami River Buried Valley aquifer system, Hamilton Area, Ohio

The Great Miami River Buried Valley Aquifer System is one of the most productive sources of potable water in the Midwest, yielding as much as 3,000 gallons per minute to wells. Many water-supply wells tapping this aquifer system are purposely placed near rivers to take advantage of induced infiltration from the rivers. The City of Hamilton's North Well Field consists of 10 wells near the Great Miami River, all completed in the lower Great Miami River Buried Valley Aquifer System. A well-drilling program and a multiple-well aquifer test were done to investigate ground-water flow directions and to estimate aquifer hydraulic properties in the lower part of the Great Miami River Buried Valley Aquifer System. Descriptions of lithology from 10 well borings indicate varying amounts and thickness of clay or till, and therefore, varying levels of potential aquifer confinement. Borings also indicate that the aquifer properties can change dramatically over relatively short distances. Grain-size analyses indicate an average bulk hydraulic conductivity value of aquifer materials of 240 feet per day; the geometric mean of hydraulic conductivity values of aquifer material was 89 feet per day. Median grain sizes of aquifer material and clay units were 1.3 millimeters and 0.1 millimeters, respectively. Water levels in the Hamilton North Well Field are affected by stream stage in the Great Miami River and barometric pressure. Bank storage in response to stream stage is evident. Results from a multiple-well aquifer test at the well field indicate, as do the lithologic descriptions, that the aquifer is semiconfined in some areas and unconfined in others. Transmissivity and storage coefficient of the semiconfined part of the aquifer were 50,000 feet squared per day and 5x10-4, respectively. The average hydraulic conductivity (450 feet per day) based on the aquifer test is reasonable for glacial outwash but is higher than calculated from grain-size analyses, implying a scale effect. Although the part of the lower Great Miami River Buried Valley Aquifer System where the Hamilton North Well Field is located is semiconfined, unconfined, or locally confined and not directly connected to the Great Miami River, the discontinuity of the clay/till layers beneath the river indicates that other, deeper parts of the aquifer system may be directly connected to the Great Miami River.

Scientific Investigations Report

Two-dimensional resistivity investigation of the North Cavalcade Street site, Houston, Texas, August 2003

The North Cavalcade Street site was first developed for wood treating in 1946. By 1955, pentachlorophenol wood preservation services and other support facilities, such as creosote ponds, pentachlorophenol and creosote storage structures, various tanks, lumber sheds, a treatment facility, and other buildings had been added. In 1961, the property was closed. To protect public health and welfare and the environment from release or threatened releases of hazardous substances, the U.S. Environmental Protection Agency added the North Cavalcade Street site to the National Priorities List on October 5, 1984. Between September 1985 and November 1987, the U.S. Environmental Protection Agency conducted a remedial investigation which, through exploratory drilling, determined the locations of two contaminated source areas and a normal fault. During August 2003, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, conducted a two-dimensional (2D) resistivity investigation at the North Cavalcade Street site to provide additional characterization of the dense non-aqueous phase liquids and the lithologies that can influence contaminant migration. The 2D resistivity investigation used a capacitively coupled (CC) resistivity method as a reconnaissance tool to locate geophysical anomalies that could be associated with possible areas of creosote contamination. The inversion results of the CC resistivity survey identified resistive anomalies in the subsurface near the eastern and western contaminated source areas. A direct-current (DC) resistivity survey conducted near the CC resistivity survey confirmed the occurrence of subsurface resistive anomalies. The inversion results of the DC resistivity survey were used to define the subsurface distribution of resistivity at each line. Forward modeling was used as an interpretative tool to relate the subsurface distribution of resistivity from four DC resistivity lines to known, assumed, and hypothetical information on subsurface lithologies. The final forward models were used as an estimate of the true resistivity structure for the field data. The forward models and the inversion results of the forward models show the depth, thickness, and extent of strata as well as the resistive anomalies occurring along the four lines and the displacement of strata resulting from the Pecore Fault along two of the four DC resistivity lines. Ten additional DC resistivity lines show similarly distributed shallow subsurface lithologies of silty sand and clay strata. Eight priority areas of resistive anomalies were identified for evaluation in future studies. The interpreted DC resistivity data allowed subsurface stratigraphy to be extrapolated between existing boreholes resulting in an improved understanding of lithologies that can influence contaminant migration.

Scientific Investigations Report

Completion summary for boreholes TAN-2271 and TAN‑2272 at Test Area North, Idaho National Laboratory, Idaho

In 2015, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, drilled and constructed boreholes TAN-2271 and TAN-2272 for stratigraphic framework analyses and long-term groundwater monitoring of the eastern Snake River Plain aquifer at the Idaho National Laboratory in southeast Idaho. Borehole TAN-2271 initially was cored to collect continuous geologic data, and then re-drilled to complete construction as a monitor well. Borehole TAN-2272 was partially cored between 210 and 282 feet (ft) below land surface (BLS) then drilled and constructed as a monitor well. Boreholes TAN-2271 and TAN-2272 are separated by about 63 ft and have similar geologic layers and hydrologic characteristics based on geologic, geophysical, and aquifer test data collected. The final construction for boreholes TAN-2271 and TAN-2272 required 10-inch (in.) diameter carbon-steel well casing and 9.9-in. diameter open-hole completion below the casing to total depths of 282 and 287 ft BLS, respectively. Depth to water is measured near 228 ft BLS in both boreholes. Following construction and data collection, temporary submersible pumps and water-level access lines were placed to allow for aquifer testing, for collecting periodic water samples, and for measuring water levels. Borehole TAN-2271 was cored continuously, starting at the first basalt contact (about 33 ft BLS) to a depth of 284 ft BLS. Excluding surface sediment, recovery of basalt and sediment core at borehole TAN-2271 was better than 98 percent. Based on visual inspection of core and geophysical data, material examined from 33 to 211ft BLS primarily consists of two massive basalt flows that are about 78 and 50 ft in thickness and three sediment layers near 122, 197, and 201 ft BLS. Between 211 and 284 ft BLS, geophysical data and core material suggest a high occurrence of fractured and vesicular basalt. For the section of aquifer tested, there are two primary fractured aquifer intervals: the first between 235 and 255 ft BLS and the second between 272 and 282 ft BLS. Basalt texture for borehole TAN-2271 generally was described as aphanitic, phaneritic, and porphyritic. Sediment layers, starting near 122 ft BLS, generally were composed of fine-grained sand and silt with a lesser amount of clay. Basalt flows generally ranged in thickness from 2 to 78 ft and varied from highly fractured to dense with high to low vesiculation. Geophysical data and limited core material collected from TAN-2272 show similar lithologic sequences to those reported for TAN-2271. Geophysical and borehole video logs were collected during certain stages of the drilling and construction process at boreholes TAN-2271 and TAN-2272. Geophysical logs were examined synergistically with available core material to confirm geologic and hydrologic similarities and suggest possible fractured network interconnection between boreholes TAN-2271 and TAN-2272. Natural gamma log measurements were used to assess the completeness of the vapor port lines behind 10-in. diameter well casing. Electromagnetic flow meter results were used to identify downward flow conditions that exist for boreholes TAN-2271 and TAN-2272. Furthermore, gyroscopic deviation measurements were used to measure horizontal and vertical displacement at all depths in boreholes TAN-2271 and TAN-2272. After borehole construction was completed, single‑well aquifer tests were done within wells TAN-2271 and TAN ‑ 2272 to provide estimates of transmissivity and hydraulic conductivity. The transmissivity and hydraulic conductivity were estimated for the pumping well and observation well during the aquifer tests conducted on August 25 and August 27, 2015. Estimates for transmissivity range from 4.1 . 10 3 feet squared per day (ft 2 /d) to 8.1 . 10 3 ft 2 /d; estimates for hydraulic conductivity range from 5.8 to 11.5 feet per day (ft/d). Both TAN-2271 and TAN ‑ 2272 show sustained pumping rates of about 30 gallons per minute (gal/min) with measured drawdown in the pumping well of 1.96 ft and 1.14 ft, respectively. The transmissivity estimates for wells tested were within the range of values determined from previous aquifer tests in other wells near Test Area North. Groundwater samples were collected from both wells and were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Groundwater samples for most of the inorganic constituents showed similar water chemistry in both wells. Groundwater samples for strontium-90, trichloroethene, and vinyl chloride exceeded maximum contaminant levels for public drinking water supplies in one or both wells.

Idaho

Revisions to the Virginia Coastal Plain hydrogeologic framework southwest of the James River

New drilling information reveals that altitudes of some hydrogeologic units of the Virginia Coastal Plain aquifer system differ by as much as 50 feet (ft) from those previously known, namely the Aquia and Potomac aquifers, the Potomac confining zone, and the Nanjemoy-Marlboro and Saint Marys confining units. In addition, the lateral margins of some hydrogeologic units are located as much as several miles from previously estimated locations. The largest revisions to unit margins were for the Aquia aquifer and the Nanjemoy-Marlboro and Saint Marys confining units. Interpretation of new geophysical logs, sediment core, and cuttings as well as revised interpretations to existing data indicate channels and embayments are also preserved on eroded top surfaces of the shallowest hydrogeologic units including the Yorktown confining zone, Yorktown-Eastover aquifer, Saint Marys confining unit, Potomac confining zone, and Potomac aquifer. Enhanced details on the configuration of part of the aquifer system southwest of the James River are provided by sediment cores and cuttings as well as geophysical logs from 36 recently drilled boreholes. These, along with reinterpretation of data from 93 preexisting boreholes, form the basis for revised top-surface altitudes and margins of hydrogeologic units beneath parts of Prince George, Surry, Sussex, Isle of Wight, and Southampton Counties and the cities of Franklin and Suffolk. Groundwater withdrawals in the Virginia Coastal Plain cause widespread water-level declines, create the potential for saltwater intrusion, and contribute to regionwide land subsidence. A description of the aquifer system, termed a hydrogeologic framework, was developed by the U.S. Geological Survey in 2006 and provides information needed to base withdrawal-permitting decisions by the Virginia Department of Environmental Quality. This revision of part of the hydrogeologic framework southwest of the James River is based on interpretations of both new and previously analyzed borehole data. The revision is strictly confined to the study area extent and hydrogeologic units not found within the study area were not revised and are not discussed in this report. The newly determined hydrogeologic-unit altitudes and margins have implications for groundwater-withdrawal permitting. New interpretations have found that the Yorktown Eastover aquifer is absent in the southwestern part of the City of Suffolk, owing to what is most likely an isolated area of sediment-texture facies change. Most notably, the top-surface altitudes of the Aquia and Potomac aquifers have been lowered by as much as 50 ft from previous interpretations. This means that wells previously believed to be screened in the top of the Potomac aquifer could, based on these new interpretations, be screened in the bottom of the Aquia aquifer. These changes to aquifers in which wells are screened means that there is potentially more room in the groundwater withdrawal permitting for the Potomac aquifer, the largest and most productive aquifer in Virginia, and overpumping occurring in the Aquia aquifer.

Virginia

A conceptual site model of contaminant transport pathways from the Bremerton Naval Complex to Sinclair Inlet, Washington, 2011–21

Historical activities on the Bremerton Naval Complex (BNC) in Puget Sound, Washington, have resulted in Sinclair Inlet sediments with elevated concentrations of contaminants, including organic contaminants such as polychlorinated biphenyls and trace elements including mercury. Six U.S. Geological Survey–U.S. Navy datasets have been collected since the last major assessment, in 2013, of soil and groundwater contaminant transport pathways and mercury loading estimates from the BNC to Sinclair Inlet. These include: mercury isotope analysis to support sourcing of mercury in Sinclair Inlet; mercury sampling within the dry dock systems; nearshore thermal surveys to identify potential groundwater discharge locations to Sinclair Inlet; time-series monitoring in nearshore wells to understand the inland extent and dynamics of the tidal mixing zone; tidal studies of mercury in nearshore monitoring wells in an area of contaminated fill material called Site 1; and a spatial survey of trace elements and other parameters in nearshore monitoring wells, pore water, seeps, surface water, and sediment along unwalled shorelines in the western part of the BNC. The results were incorporated into an updated Conceptual Site Model and used to update contaminant load estimates from the terrestrial BNC to Sinclair Inlet. The results from these studies provide data to the U.S. Navy to support prioritization of on-going remediation actions to manage contamination on the BNC that reduce potential impacts to Sinclair Inlet sediment, surface water, and fish and shellfish tissue. Mercury isotope analysis of surface sediments and particulate material indicated that a similar industrial mercury profile is present throughout Puget Sound, including terrestrial and marine BNC samples and in other Sinclair Inlet sediments and persists across regions with low and elevated mercury concentrations. Two sources of mercury at the BNC are Sites 1 and 2 subsurface soils/fill material, with total mercury concentrations in particulates collected from the bottom of monitoring wells drilled in these materials ranging from 18,000 to 44,000 nanograms per gram (as compared to the Washington State Marine Sediment Cleanup Screening Level of 590 nanograms per gram). Contaminants are transported from the terrestrial BNC to Sinclair Inlet via three primary pathways, (1) stormwater outfalls, (2) dry dock discharges, and (3) direct discharge along unwalled shorelines. Previous loading estimates (based on filtered total mercury) ranked stormwater outfalls, particularly outfall PSNS015 in Site 2 soils, as the largest soil and groundwater contaminant transport pathway from the terrestrial BNC to Sinclair Inlet. Updated loading estimates in this report suggest that the dry dock systems may be a larger pathway of mercury from the terrestrial BNC to Sinclair Inlet than previously thought, within the same order of magnitude as the PSNS015 storm-drain system. Trace-element loads via direct shoreline discharge are difficult to estimate due to the large and dynamic tidal mixing zone of groundwater and seawater in the nearshore along unwalled shorelines. However, current best estimated ranges suggest that direct shoreline discharge is one of the three main pathways and may contribute smaller mercury loads than the stormwater and the dry dock systems. Along unwalled shorelines, direct groundwater discharge of terrestrial contaminants may be less important than recirculating seawater in the nearshore mixing zone that can extract contaminants from nearshore subsurface material. Total estimated mercury loads from the terrestrial BNC to Sinclair Inlet range from approximately 40 to 200 grams of filtered total mercury per year and a minimum of 70–350 grams of particulate total mercury per year, for a minimum total of 110–525 grams of whole (filtered plus particulate) total mercury per year. Data gaps are identified that, if filled, would further refine the Conceptual Site Model and contaminant loading estimates from the terrestrial BNC to Sinclair Inlet.

Washington

Petroleum system and production characteristics of the Muddy (J) Sandstone (Lower Cretaceous) Wattenberg continuous gas field, Denver basin, Colorado

Wattenberg field is a continuous-type gas accumulation. Estimated ultimate recovery from current wells is 1.27 tcf of gas from the Lower Cretaceous Muddy (J) Sandstone. Mean gas resources that have the potential to be added to these reserves in the next 30 yr are 1.09 tcf; this will be primarily through infill drilling to recover a greater percentage of gas in place and to drain areas that are isolated because of geologic compartmentalization. Greatest gas production from the Muddy (J) Sandstone in Wattenberg field occurs (1) from within the most permeable and thickest intervals of Fort Collins Member delta-front and nearshore-marine sandstones, (2) to a lesser extent from the Horsetooth Member valley-fill channel sandstones, (3) in association with a large thermal anomaly that is delineated by measured temperatures in wells and by vitrinite reflectance contours of 0.9% and greater, (4) in proximity to the bounding Mowry, Graneros, and Skull Creek shales that are the hydrocarbon source rocks and reservoir seals, and (5) between the Lafayette and Longmont right-lateral wrench fault zones (WFZs) with secondary faults that act as conduits in areas of the field. The axis of greatest gas production is north 25 to 35 degrees northeast, which parallels the basin axis. Recurrent movement along five right-lateral WFZs that crosscut Wattenberg field shifted the Denver basin axis to the northeast and influenced depositional and erosional patterns of the reservoir and seal intervals. Levels of thermal maturity within the Wattenberg field are anomalously high compared to other areas of the Denver basin. The Wattenberg field thermal anomaly may be due to upward movement of fluids along faults associated with probable igneous intrusions. Areas of anomalous high heat flow within the field correlate with an increased and variable gas-oil ratio. Debra Higley has 5 years experience in uranium exploration and 20 years as a petroleum geologist with the U.S. Geological Survey. Her research interests include and integrate reservoir characterization, thermal maturation studies, and petroleum resource assessment in basins in North and South America. She received a B.S. degree in geology from Mesa State College (Colorado) and an M.S. degree in geochemistry and Ph.D. in geology from the Colorado School of Mines.Dave Cox is vice president of Reservoir Engineering for Questa Engineering in Golden, Colorado. He has 25 years experience in the oil and gas industry, primarily in reservoir engineering and property evaluations, and has analyzed reservoirs in 31 states of the United States and 19 other countries. He is an expert in coalbed methane, tight gas reservoirs, and enhanced oil recovery. He has B.S. and M.S. degrees in petroleum engineering from the Colorado School of Mines. Robert Weimer has taught courses in stratigraphy, regional and field geology, and energy resource exploration and development for 43 years. He earned B.A. and M.A. degrees from the University of Wyoming and his Ph.D. from Stanford University. He has been a visiting professor at universities in Calgary, Canada; Adelaide, Australia; and Bandung, Indonesia. He is currently professor emeritus, Colorado School of Mines. Weimer has been honored for teaching excellence, blending basic and applied research, national and international continuing education, and service to scientific societies and to state and national boards.

Colorado

Hydrogeologic characterization of the Hualapai Plateau on the western Hualapai Indian Reservation, northwestern Arizona

This study was developed to assess if groundwater from the western Hualapai Plateau could be used to supply developments in the Grand Canyon West area of the Hualapai Indian Reservation and to collect hydrogeologic data for future use in a numerical groundwater model for the reservation. Ground-based geophysical surveys; existing well, spring, and other hydrogeologic information from previous studies; and new well and spring data collected for this study were used to provide a better understanding of the hydrogeology of the western Hualapai Plateau. Surface geophysical data provided information on the depth and geologic structure of lower Paleozoic rock units and Proterozoic crystalline and metamorphic rocks that underlie the western Hualapai Plateau. The surface geophysical data and discharge information from springs were used to select a site to drill and develop the U.S. Geological Survey Hualapai Test Well. The Hualapai Test Well was drilled to understand the geophysical properties of geologic formations at depth. These data were used to verify the results of surface geophysical data and to evaluate if sufficient water was present in the Hualapai Test Well for potential groundwater development. The Hualapai Test Well was drilled to a depth of 2,468 feet and bottomed in Proterozoic granite. Water was expected in the lower part of the Muav Limestone, but water was not observed until the Tapeats Sandstone at a depth of 2,400 feet. The Tapeats Sandstone was determined to be confined with a hydrostatic head of over 900 feet. A 48-hour pumping test was conducted to determine aquifer properties. Low specific capacity indicated that although groundwater is present in the Tapeats Sandstone, well yields are likely to be small. A water-quality sample indicated the sample had a calcium, magnesium-bicarbonate water type with a total dissolved-solids concentration of 371 milligrams per liter. Alpha radioactivity of the sample, 18.3 picocuries per liter, exceeded the U.S. Environmental Protection Agency maximum contaminant level of 15 picocuries per liter for drinking water. Concentrations of iron and manganese in the water sample also exceeded the U.S. Environmental Protection Agency secondary maximum contaminant levels for drinking water. An inventory of wells and springs provided insight into the occurrence of groundwater on the western Hualapai Plateau. Data from 56 springs on and adjacent to the western Hualapai Plateau were compiled for this study, and new data were collected at 31 springs. Discharge from springs visited for this study ranged from dry to about 345 gallons per minute. The temporal data from springs, where repeat measurements were available, indicated that spring flow is highly variable and likely related to seasonal and annual precipitation. Water levels from 36 wells on and adjacent to the western Hualapai Plateau were compiled for this study, and new water levels were collected at 5 wells. The spring and well data in conjunction with the Hualapai Test Well results indicated that on the western Hualapai Plateau, bedrock aquifers have limited discrete flow paths that make extensive groundwater development unlikely.

Arizona

Predevelopment Water-Level Contours for Aquifers in the Rainier Mesa and Shoshone Mountain area of the Nevada Test Site, Nye County, Nevada

Contaminants introduced into the subsurface of the Nevada Test Site at Rainier Mesa and Shoshone Mountain by underground nuclear testing are of concern to the U.S. Department of Energy and regulators responsible for protecting human health and safety. Although contaminants were introduced into low-permeability rocks above the regional flow system, the potential for contaminant movement away from the underground test areas and into the accessible environment is greatest by ground-water transport. The primary hydrologic control on this transport is evaluated and examined through a series of contour maps developed to represent the water-level distribution within each of the major aquifers underlying the area. Aquifers were identified and their extents delineated by merging and analyzing multiple hydrostratigraphic framework models developed by other investigators from existing geologic information. The contoured water-level distribution in each major aquifer was developed from a detailed evaluation and assessment of available water-level measurements. Multiple spreadsheets that accompany this report provide pertinent water-level and geologic data by well or drill hole. Aquifers are mapped, presented, and discussed in general terms as being one of three aquifer types?volcanic aquifer, upper carbonate aquifer, or lower carbonate aquifer. Each of these aquifer types was subdivided and mapped as independent continuous and isolated aquifers, based on the continuity of its component rock. Ground-water flow directions, as related to the transport of test-generated contaminants, were developed from water-level contours and are presented and discussed for each of the continuous aquifers. Contoured water-level altitudes vary across the study area and range from more than 5,000 feet in the volcanic aquifer beneath a recharge area in the northern part of the study area to less than 2,450 feet in the lower carbonate aquifer in the southern part of the study area. Variations in water-level altitudes within any single continuous aquifer range from a few hundred feet in a lower carbonate aquifer to just more than 1,100 feet in a volcanic aquifer. Flow directions throughout the study area are dominantly southward with minor eastward or westward deviations. Primary exceptions are westward flow in the northern part of the volcanic aquifer and eastward flow in the eastern part of the lower carbonate aquifer. Northward flow in the upper and lower carbonate aquifers in the northern part of the study area is possible but cannot be substantiated because data are lacking. Interflow between continuous aquifers is evaluated and mapped to define major flow paths. These flow paths delineate tributary flow systems, which converge to form the regional ground-water flow system. The implications of these tributary flow paths in controlling transport away from the underground test areas at Rainier Mesa and Shoshone Mountain are discussed. The obvious data gaps contributing to uncertainties in the delineation of aquifers and development of water-level contours are identified and evaluated.

Scientific Investigations Report

Gas hydrate prospecting using well cuttings and mud-gas geochemistry from 35 wells, North Slope, Alaska

Gas hydrate deposits are common on the North Slope of Alaska around Prudhoe Bay; however, the extent of these deposits is unknown outside of this area. As part of a U.S. Geological Survey (USGS) and Bureau of Land Management gas hydrate research collaboration, well-cutting and mud-gas samples have been collected and analyzed from mainly industry-drilled wells on the North Slope for the purpose of prospecting for gas hydrate deposits. On the Alaska North Slope, gas hydrates are now recognized as an element within a petroleum systems approach or "total petroleum system." Since 1979, 35 wells have been sampled from as far west as Wainwright to Prudhoe Bay in the east. Regionally, the USGS has assessed the gas hydrate resources of the North Slope and determined that there is about 85.4 trillion cubic feet of technically recoverable hydrate-bound gas within three assessment units. The assessment units are defined mainly by three separate stratigraphic sections and constrained by the physical temperatures and pressures where gas hydrate can form. Geochemical studies of known gas hydrate occurrences on the North Slope have shown a link between gas hydrate and more deeply buried conventional oil and gas deposits. The link is established when hydrocarbon gases migrate from depth and charge the reservoir rock within the gas hydrate stability zone. It is likely gases migrated into conventional traps as free gas and were later converted to gas hydrate in response to climate cooling concurrent with permafrost formation. Results from this study indicate that some thermogenic gas is present in 31 of the wells, with limited evidence of thermogenic gas in four other wells and only one well with no thermogenic gas. Gas hydrate is known to occur in one of the sampled wells, likely present in 22 others on the basis of gas geochemistry, and inferred by equivocal gas geochemistry in 11 wells, and one well was without gas hydrate. Gas migration routes are common in the North Slope and include faults and widespread, continuous shallowly dipping permeable sand sections that are potentially in communication with deeper oil and gas sources. The application of the petroleum system model with the geochemical evidence suggests that gas hydrate deposits may be widespread across the North Slope of Alaska.

Alaska